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By Mei-Yan Yang, Qiu-Ying Wang, Ltd. Yunnan Yuntong Zinc Co., Guo-Mu Chen, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"Historically, alot of jarosite was found in the leaching residue when leaching indium from secondary zinc oxide materials. The reasons for the formation of indium bearing jarosite were theoretically analyzed. The influence of controlling the acidity and the addition of reagents on the indium leaching yield during secondary zinc oxide processing was investigated. In order to increase the leaching yield of indium, a measure of controlling the creation and destruction of jarosite was proposed. The production data shows that the leaching yield of indium was increased from 60 to 96%, and the content of indium in leaching residue simultaneously decreased from 900g/t to 100–200g/t when implementing such controlling measures.INTRODUCTIONIndium does not occur as independent minerals in the earth’s crust and is mainly associated with complex sulphide minerals. Specifically some sphalerites can contain as much as 900g/t of indium. Most indium is recovered from by-products of copper, lead or zinc metallurgy. Therefore, the research on the recovery of by-products in non-ferrous metallurgy is important(Sinclair et al, 2006). The main technologies used for this objective in China include: •,pre-neutralization-reduction-precipitation indium process(Yu et al, 2008), •,countercurrent oxidizing acid leaching process and sulphation roasting-water leaching process(Cao, 2005), •,oxygen pressure acid leaching of zinc concentrate-P204 extraction process(Yang et al, 2006), •,doubleacid leaching-solvent extraction process on lead dross from a reverbatory furnace flue dust(Liu, 2003),•,an acid leaching-solvent extraction process on smelting ash(Zhouet al, 2005). Although high pressure and extreme conditions can be used to improve extraction from high iron bearing indium residues(autoclave processing), mild extraction with lower cost and lower environmental impact are preferred.This paper describes both how the indium extraction using mild conditions in a secondary zinc circuit was quite low and, how through XRD and chemical analysis jarosite formation was found as the main cause. The paper then proceeds to discuss a method for improving the leaching yield and the application of this method in industrial practice."

Jan 1, 2016

By Collin Bartlett, H. Storch

"Modern metallurgical processes operating with oxygen enriched air, such as the Outotec Flash Smelter and Flash Converter, generate very concentrated SO2 off-gas, which in combination with Outotec sulphuric acid plant technology allows the production of high pressure steam to be used for power generation. Outotec combines well proven technology of sulphur burning plants for this purpose with metallurgical plants.The application of Outotec’s proven LURECTM process enables processing of SO2 gas of up to 25 vol.-%. This process maximizes the energy recovery from the SO2 oxidation at a suitable high temperature level which can be turned into high pressure steam. The application of the Outotec HEROSTM heat recovery system enables the generation of low pressure steam from the absorption energy released at the intermediate absorption step. Additionally, energy is also recovered in the acid coolers for boiler feedwater pre-heating.The concept of integration of high and low pressure steam in combination with the pressurized operation of the boiler feedwater deaerator, thus heating up the boiler feed water to temperatures around 160…170°C, enables indirect transfer of low pressure steam (for deaerator operation) into more valuable high pressure steam, which improves the degree of heat recovery. This is the characteristic of Outotec’s HEROS+TM process.The increased generation of high pressure steam will in turn enable the generation of more electricity when compared to a standard traditional sulphuric acid process."

Jan 1, 2014

By J. A. Brusset

THE Greenhill mine of West Canadian Collieries, Limited, is situated at Blairmore, Alberta, and produces 2,500 tons per day of bituminous coal. On Monday, October 25th, 1943, smoke was discovered by a party of firebosses on their regular weekly inspection of air-ways. Probably the fire had been smouldering for several days but, as it had started on the outcrop at the top of an old raise filled with dirt, only a small quantity of smoke could filter through, and the plume of mist that crowns the fan at that season had prevented the fan-man from noticing it. This raise is only about 200 feet from the fan, and is 70 feet long between the fan-drift and the outcrop. It was impossible to prove the origin of the fire, as it had probably started several days before it was discovered, but it is possible that a careless smoker may have thrown a match into the opening at the outcrop, and that the old, dry timber had caught fire. The airways are in No. 2 seam, a bituminous seam 18 to 25 feet thick surmounted by shales and sandstones. Only 45 feet vertically above it is No. 1 seam, 12 feet thick, overlain by a strong conglomerate. In that vicinity, No. 1 seam had been worked out about ten years ago and the strata between the two seams are undoubtedly fissured. The pitch of both seams is 43 degrees.

Jan 1, 1945

By D Martín, G. Díaz, F. Cubeddu, A. B. Mejias

The Modified ZINCEXTM Process (MZP), developed by Técnicas Reunidas, is an industrially proven flexible process. It can handle a wide range of primary and secondary raw materials, producing SHG zinc. The core of the Modified ZINCEXTM Process is the zinc solvent extraction unit. This unit is an effective barrier for any leachable impurities present in the raw material. As a result of this an ultra-pure zinc solution is always obtained. The high versatility of the process makes the application of the technology in different scenarios possible. MZP can be effectively applied when developing a whole new plant (Skorpion) or adapting its scheme to an existing refinery (Akita), in both cases giving the same results. Flexibility in terms of capacity of the plant is a great advantage of the MZP, there is the possibility to adapt the global process to a wide range of production capacities. Zinc production capacities of over 150 000 t/a may be achieved with a single solvent extraction plant train. The robustness of the Modified ZINCEXTM Process has been recently proven on two new plants currently in operation: Portovesme (Italy) and Horsehead (USA) after start up during 2013. The status of both plants is described in this paper.

Jan 1, 2014

By B. W. Raymond, D. W. Zandee

"IntroductionCoal deposits are found in many regions in Canada and vary widely in their age, quality and rank. All classifications of coal except anthracite are found in significant quantities in this country.Deposits in the Maritimes are mainly bituminous; Lignite is found in Saskatchewan and Ontario and sub-bituminous coal in the plains region of Alberta. The Rocky Mountain coalfields of Alberta and British Columbia contain low and high-volatile bituminous coal and, in a few places, semi-anthracite. The British Columbia interior contains deposits of semi-anthracite, bituminous, sub-bituminous coals and lignite. The Yukon and Northwest Territories also contain substantial deposits of bituminous coal and lignite.Currently Nova Scotia produces both thermal and metallurgical coal, Saskatchewan produces lignite and Alberta produces both sub-bituminous and bituminous coal for thermal purposes. Large deposits of metallurgical coal are now being exploited in the Rockies arefl of British Columbia and Alberta by open pit methods. The raw coal is treated in large capacity preparation plants to remove refuse and upgrade the product to a consistent metallurgical quality with respect to ash, moisture, volatile matter and coking properties.The treatment of coal involves crushing, screening and cleaning by dense medium, jigs, water-only cyclones, tables and froth flotation to produce a diverse range of coal products differing in quality and size for various end uses.The chapter on Crushing and Screening Circuits was concerned mainly with crushing of metalliferous ores to produce a concentrate of one or more valuable minerals which normally constitute a small portion of the original mass of the material treated.Coal differs physically from ores in many ways such as lower specific gravity, relatively large volumes but low tonnage of product, and its habit of absorbing moisture requires extensive dewatering processes more complicated than settlement and filtration. Most significant, for this paper at least, is the fact that crushing coal is not as energy intensive and much smaller equipment is applicable.Crushing and screening of ores is intended to reduce the size of all constituents as quickly and efficiently as possible to allow liberation of the mineral particles. The crushing of coal is different in that the coal is not the minor constituent and the production of fines, in the initial stages at least, is highly undesirable. The basic objectives of crushing coal are the reduction of run-of-mine material to sizes suitable for cleaning or further reduction of coal to market sizes."

Jan 1, 1989

By John A. Meech, Irene E. Cristoveanu

"The separation of hematite fines (100% - 38 um) from quartz fines (100% -75 um) was investigated using coarse hematite (-212 + 150 um) as a carrier in an oleic acid collector system. Oleic acid additions, per cent coarse additions, combined conditioning time and ferric chloride additions were examined.It was found that carrier flotation is a dominant mechanism for fine hematite recovery at oleic acid levels greater than 200 g/t and coarse additions of 10 per cent. Hetero-aggregation is favoured under conditions of lower levels of oleic acid in the presence of ferric chloride and at conditioning times greater than ten minutes.Ferric chloride acts as a depressant for pre-reagentized coarse hematite at oleic acid levels below 150 g/t. At concentration levels above 500 g/t, ferric chloride interferes significantly with the success of carrier flotation of fine hematite.The sensitivity of carrier flotation to changes in oleic acid addition, ratios of fine and coarse material, conditioning time and the presence of an inorganic electrolyte emphasizes that its application is only suitable when flotation conditions can be stabilized.IntroductionThe production of fine material is unavoidable during the comminution of iron ore . Due to the difficulty of recovering iron from this fine material by various gravity separation methods, flotation can often be a more attractive process producing high-grade material at high recovery. One variation of the flotation process, that can be useful for recovering ultra fine minerals (<10 um) , is known as carrier flotation. This process involves the utilizat ion of coarse particles ( > 150 p.m) which act as flocculation centres to which the fine hematite particles (10 - 40 u.m) become attached and are carried or "" piggy-backed"" into the froth phase."

Jan 1, 1985

By T. Robson

"A multi-seam underground mining operation employing mechanized room-and-pillar methods provides 35 per cent of Smoky River's annual ROM coal production (2 million tonnes) from the Smoky River coal field. Surface mines provide the balance. Tectonic activity, which has resulted in deformed coal seams and a rugged relief to the area, has provided natural boundaries to discrete mining areas. Coal transportation to the central preparation plant incorporates a 3 km long underground conveying system. The company is committed to efficient resource recovery and a safe and healthy working environment. Introduction The Smoky River Coal operations (SRC) are centered in the Smoky River coal field located in west central Alberta, some 360 km west of Edmonton and 20 km from the Town of Grande Cache (Fig. 1). Combined mining operations produce 2 million tonnes per year run-of-mine coal from which 1.65 million tonnes of high quality, low volatile, coking coal are obtained. The underground mining operation, employing mechanized room-and-pillar methods, provides 35 per cent of SRC's annual ROM coal production (2 million tonnes). Surface mines provide the balance. Tectonic activity has resulted in deformed coal seams and a rugged relief in the area. This has provided natural boundaries to discrete mining areas. Background Exploration of the Smoky River coal field took place over four decades commencing in 1926. McIntyre Mines Limited (parent to Smoky River Coal Ltd.}, commenced development of the property in 1968 having secured a long-term contract for the delivery of coal to Japan. Production of underground coal at Smoky River commenced toward the end of 1969 and has been continuous on the property since that time. Originally, two underground mines were opened. Original planning envisaged the use of room-and-pillar techniques to develop blocks of coal for subsequent extraction by longwall retreat mining. Following initial development, two longwall units were established, the first in November 1970 in No. 5 Mine and the second in February 1971 in No. 2 Mine. Difficulties were experienced on both units, and production commitments could not be achieved. The longwalls were discontinued, and mechanized room-and-pillar was subsequently used for all underground mining."

Jan 1, 1985

By J. R. Perumareddi, V. S. Sastri, M. Elboujdaini

It is well known that high strength steels used in aerospace industry, are generally susceptible to hydrogen embrittlement during surface treatment such as electroplating with zinc on cadmium. Hydrogen embrittlement reduces ductility and results in brittle fracture rather than failure by plastic deformation. Hydrogen embrittlement of high strength steels is mitigated by surface treatment such as plating with other metals. Data on the hydrogen contents of steels before and after surface treatment by hot extraction-thermal conductivity, secondary ion mass spectrometry (SIMS) and UV-visible spectroscopy along with the mechanism are presented.

Jan 1, 2006

By John E. Udd, Peter Leinberger, Roman Kozarycz

"This paper is based on work done by the authors in a study of the structural features at a quarry excavated in Chazy limestone on the Island of Montreal. Observations on failures on the quarry walls and benches were recorded, and back analyses of small-scale failures were carried out, thus enabling an assessment to be made of the in-situ strength properties of the rock. Using this information, and data from shear tests in the laboratory, the authors made an analysis of the stability of the south wall of the quarry.IntroductionQuarrying, and excavating for foundations, in the Montreal area involves the removal of million s of tonnes of rock on an annual basis. Even when compared with the quantities mined at major open-pit mining operations, the production figures are impressive. At present, for example, crushed stone is produced at almost 20 quarrying operations either on, or near, the Island of Montreal. The annual capacities of the larger quarries are in excess of one million tonnes each. Lesser, but still substantial, production is achieved at the smaller quarries.Excavations, for foundations , especially during periods of peak construction activity, must also involve large quantities of rock . The writers, however , are not able to produce an estimate of the actual annual tonnages originating from excavations."

Jan 1, 1981

By P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. With the development and growing use of DEM charge motion simulators for mill optimisation and design, it is possible to describe the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics and in developing solutions to industrial practice. The main challenge to bringing this DEM technology to the mill operator however was the need for substantial computing power and time. However, what about a simplified DEM charge motion model running in real-time? What about the use of sensor technologies to correct any possible drift in simulator prediction? Could such a technological system be used to predict mill performance and eventually be used for mill control and optimisation? Some of these questions are answered with the development of an "on-line" DEM charge motion simulator package (SAGTools?) along with that of a number of sensor technologies (liner wear, acoustic, instrumented ball) that can contribute to simulator precision. With the objective of bringing this modelling and sensor technology into the concentrator control room to assist operators, this paper aims to describe the main elements of this emerging and developing technology and discuss how it can lead to online mill performance prediction and eventual control.

Jan 1, 2007

By E. C. Keeley

THE property of Buffalo Ankerite Gold Mines, Limited, is in Delora township, Porcupine area, Ontario. The southwestern part of the property is ground formerly owned by Marbuan Gold Mines, Limited, which was acquired by Buffalo Ankerite in January, 1936. Until 1938, the Ankerite (or North) mine and the Marbuan (or South) mine continued as separate operations, each developed through a surface shaft and winze to the 1050 level and each having its own mill. This meant high hoisting costs, which, in 1936 and 1937, amounted to 36 cents per ton. In 1938, the underground workings of the two mines were connected on the 1050 level, and ore from both mines was hoisted at the main, or No. 2, shaft of the North mine, location of which is shown in Figure l. This shaft was discontinued at a depth of 1150 feet because, owing to the soft nature of the talc (serpentine) rock in which it was sunk, it had to be concreted throughout, and also because of its great distance--1,100 feet and 1,400 feet, respectively-from the North and South orebodies.

Jan 1, 1945

By Leopoldo Gutierrez, Sergio Castro, Lina M. Uribe, Janusz S. Laskowski

"The effect of sulfite and metabisulfite ions on the amyl xanthate flotation of copper-activated pyrite, in distilled water and seawater, has been studied by micro-flotation tests and redox potential measurements. The activation of pyrite was carried out varying copper ions concentration. It was found that in the presence of copper ions in solution, sulfite and metabisulfite are able to depress copper-activated pyrite at neutral or slightly acid pH. After the addition of sulfite or metabisulfite ions the resulting pH is more acidic with metabisulfite ions. A significant increase of the redox potential of the solution was observed as copper ions concentration increased. Then, the initial reducing conditions brought about by sulfite and metabisulfite ions, change abruptly to oxidizing conditions in the presence of copper ions. Under these oxidizing conditions, the metabisulfite showed to be an effective depressant for pyrite mainly in seawater. However, sulfite was a pyrite depressant in both distilled water and seawater. Based on these results, the pyrite depression by sulfoxy-depressants during the flotation of Cu/Mo ores in distilled water and seawater is discussed.INTRODUCTIONDepression of pyrite by sulfoxy-depressants (sulfite and metabisulfite) in the presence of copper ions is an important issue. This is particularly true when pyrite depression in the flotation of Cu/Mo sulfide ores is carried out in seawater. The use of lime in seawater must be avoided because the formation of magnesium hydroxy-complexes and precipitating magnesium hydroxide strongly depresses molybdenite flotation (Castro et al., 2014). In order to solve this problem, one large plant in Chile uses sodium metabisulfite (MBS) instead of lime to depress pyrite in seawater. In plant practice, this also improves molybdenite flotation since with the use of MBS the pyrite depression is carried out at pH 6-7, instead the pH 11-12 usually employed with lime.From a general point of view, pyrite exhibits some natural floatability over acidic pH ranges and may be partially floated without thiol collectors (a coating of sulfur/polysulfides has been claimed). Therefore, pyrite flotation with xanthates is usually high in the acidic pH region, but decreases greatly at alkaline pH (Leppinen, 1990; Fornasiero and Ralston, 1992; Zhang et al., 1997)."

Jan 1, 2016

By F. H. Samuel, J. E. Gruzleski, S. Valtierra, H. W. Doty, N. Andrade

In this work, the age-hardening behavior of cast Al-Si base alloys was investigated. It was found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu-Mg alloys. TEM observations reveal that the age-hardening behavior is related to the precipitation sequence of the alloy. For the Al-Si-Cu-Mg alloy, the first aging peak is the result from the high-density GP zones, while the subsequent are from metastable phases. The transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks.

Jan 1, 2006

By Robert R. MacLachlan

New underground mining technology is evolving through the use of large-diameter bore holes containing individually restricted charge weights. This article presents summary observations on cube-root scaling trials using single and rows of charge blasting in sand and in frozen ground. These observations have some bearing on the evolving underground practice, especially where charges of appropriate geometry are used.

Jan 1, 1978

By Navid Bahrani

Introduction ? Today?s economic market is motivating underground mining companies to increase development advance rates and enhance their NPVs. ? For example, block cave mining involves development of kilometers of drifts with multiple pillars. ? The cyclic nature of drill and blast, and its inherent tendency to damage the surrounding excavation rock mass and increase support demand often result in poor advance rates ? This has motivated mining companies to replace the conventional drill-and-blast as the main excavation method with alternative methods such as mechanized excavation. ? There is little experience with mechanized or non-explosive excavation methods in hard rock metalliferous underground mining.

Oct 1, 2010

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By P. Fellner, A. Sýkorová, J. Thonstad, J. Jurišová, V. Khandl

Adsorption of S02 on alumina used in the aluminium industry, so-called smelter grade alumina, was studied in the temperature range 15 C-120 C. The specific surface area of the smelter grade alumina was 88 m2/g. It was found that at temperatures lower than 40 C, sulphur dioxide is bonded to alumina reversibly by physical forces, and the adsorption can be described satisfactorily by the Langmuir adsorption isotherm. The heat of adsorption was estimated to be -33 kJ.mor1. At temperatures in the range 80 C- 120 C, which prevail in dry scrubbers in the aluminium industry, the heat of adsorption was determined to be -56 kJ.mor1. When S02 was adsorbed at temperatures higher than 80 C, about 30 % of the S02 could not be desorbed when heating the samples up to 250 C. In the presence of S02 and oxygen, the formation of sulphate was determined at temperatures above 90 C.

Jan 1, 2006

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016

By Godfrey W. McDonald, Dennis E. Fredrickson

"Commercial coal mining has been recorded in Nova Scotia since 1863 and during this period an estimated 60,000,000 short tons of mine discard containing 10 1030% coal has been accumulated, Approximately 70% of these dumps are in the Cape Breton region and most are owned by the Cape Breton Development Corporation (CBDC), formerly DEVCO.The explosion of oil produced energy costs which created an increase in thermal coal demand as well as the desire to rehabilitate abandoned mine dumps encouraged coal reclamation. CBDC was receptive to a proposal from the Selminco Joint Venture and encouraged the building of the Princess Recovery Plant (1980) and The Summit Plant (1982).The mine dump contains scrap, waste rocks, coal and substantial quantities of fine shale. The scrap and oversize are removed and the remaining material slurried with water to a density of 1.45. The slurry is cycloned to separate the saleable thermal coal from the rejects which are returned to designated areas of the dump for contouring and revegetation.BackgroundThe recorded coal production in Nova Scotia from 1863 to 1980 was 390,000,000 short tons. This extraction was associated with an estimated 60,000,000 short tons of discarded material. This mining discard and coal washing plant reject are located in numerous, varying sized dumps throughout the mining areas. Approximately 70% of these dumps are in the Sydney coal field region of Nova Scotia. The coal content of these dumps varies from 10 to 30% coal with an average of 18%.Energy CostsThe explosion o f energy costs in the mid-1970s greatly increased the sale price of thermal coal which made recovery of coal from some of the dumps economical. The environmental benefit of these operations will be the rehabilitation of the dumps upon cessation of the coal reclamation operation."

Jan 1, 1983

By S. M. Fatemi-Varzaneh

The AZ31 magnesium alloy is considered as a promising alloy in various applications and industries. Furthermore, to design a proper hot working process (rolling, forging and extrusion), the assessment of hot working behaviour of the alloy is necessitated. Accordingly, the hot deformation behaviour of AZ31 alloy was studied through hot compression testing method. The latter was carried out in a wide range of temperature (523 K to 783 K) and strain rates. The obtained true stress-true strain curves and final microstructures were examined and a partial melting was realized at 740 K. It was concluded that the presence of liquid did change the deformation mechanisms thereby affecting the flow behaviour.

Jan 1, 2005