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By Ernest A. Hersam

"INTRODUCTION.Luring the year 1923 a complete survey was made of the condition of research in the reduction (milling) and concentration of ores and nonmetallic minerals - that is, up to the stage where the ores or concentrates were ready for hydro- or pyro-metallurgical treatment. This survey was carried on under the general supervision of L. A. Lyon, assistant director and chief metallurgist of the Bureau of mines, in cooperation with the milling committee of the American Institute of mining and metallurgical Engineers, the Massachusetts Institute of Technology, and the University of California. Other institutions, including the National Research council, were of assistance and outlined recommendations during the study.While this report is on ""ore dressing"", it contains short sections on coal and clay. The mechanical handling that these minerals undergo is ""dressing"", so that ore dressing is inclusive of metallic and nonmetallic minerals. ""milling"", in its broadest sense, includes with ore dressing certain other metallurgical treatment which the report is not designed to cover.The survey revealed that considerable experimentation is being carried on great cost to the mining industry, but that the research is in general poorly coordinated while companies and firms are adequately taking care of routine tests and the mechanical features involved in their own operations, no comprehensive study of the fundamental principles of ore reduction is now in progress or contemplated. Many industries, besides mining, are interested in the preparation of materials for final treatment, rendering this investigation of value also to them. This class of fundamental research is neglected by industry unless there is some agency which can bring together at least a majority of this interested in a cooperative effort. It can not be effectively handled by a single company; and, moreover, no company can be expected to bear the whole burden of an investigation to benefit the entire industry or a number of industries hence there is need for concerted study within reasonable limits. Furthermore, co-operation eliminates duplication, which is largely a waste of effort and capital."

Mar 1, 1925

By Iván Monteagudo

El presente texto señala la mineralización y zoneamiento en el distrito minero de Colquijirca. En ese sentido, los zoneamientos, tanto de mineralización como alteración para los tres yacimientos (Gregorio, Colquijirca y Marcapunta) de dicha zona, apoyan la hipótesis de que estos se han formado a partir de un mismo sistema hidrotermal y que las mineralizaciones de Colquijirca y San Gregorio, se originaron por procesos de reemplazamiento polimetálico. De forma, que el Complejo de Volcánico de Marcapunta, centro de la actividad hidrotermal, presenta dos tipos de mineralizaciones distinguibles en tiempo y espacio. La primera mineralización de plata y oro se encuentra en los cuerpos de vuggy silica desarrollados en rocas volcánicas y la segunda, está relacionada a cuerpos de enargita-pirita (Cu±Au, Ag) que alcanzan su máximo desarrollo en sedimentos de la Formación Calera. Asimismo otros trabajos, señalan que la plata se encuentra asociada al cobre, así como también al zinc-plomo y los valores más altos de plata se encuentran en la zona de transición.

Jul 31, 2003

Dado que el Perú es un país que cuenta con una variedad de recursos hidro-eléctricos, es necesario realizar un estimado del valor de los mismos para mejorar las condiciones de su distribución en el país. Por tal motivo, el objetivo del texto es describir las ventajas de funcionamiento de este recurso y el desarrollo de los proyectos hidroeléctricos de la costa, sierra y selva alta. Se conoce que el recurso hidroeléctrico por sí solo no genera riqueza y necesita de la explotación del recurso natural que pueda ser vendido en el mercado. En este sentido, se produce dos beneficios. El primero, refiere que los productos resultantes del binomio energía- recurso industrializable, desarrollan mercados naciones como internacionales, originando una serie de divisas que permiten el desarrollo local en algunos aspectos. El segundo radica en que los proyectos hidroeléctricos de la Costa, permiten mejorar las obras de irrigación de los valles, producción agraria y la industrialización de los recursos minerales. Por tanto, para acceder al mercado internacional, es necesario que los proyectos de industrialización de los recursos, contemplen un planeamiento a partir del desarrollo de las mismas empresas. De forma que el desarrollo de los recursos naturales se realice en condiciones óptimas, satisfaciendo las necesidades básicas de la población.

Jul 20, 1959

Law of the Sea. - The Ninth Session of the Law of the Sea Conference resumed July 28 at Geneva and will run for 5 weeks. The 160-nation Conference began in 1973. Two of the major factors to be discussed are the transfer of technology to the UN-controlled Enterprise or mining authority, and how the 36-member Council will make decisions. As the session completed its third week, delegates expressed little hope of completing a treaty text this year. There was a feeling, though, that substantive issues might be settled so that a treaty text can be completed next year. The Deep Seabed Hard Mineral Resources Act signed by the President on June 28, provides an interim regulatory procedure for ocean mining activities conducted by U.S. nationals that may be superseded by a law of the sea treaty.

Jan 1, 1980

Applications of helium in aerostatics, cryogenics, space, and undersea work are described in papers from the Helium Applications Symposium. Specific subjects include investigations of X-ray sources by means of balloon-borne instruments, meteorological soundings by balloons, powered lighter-than-air flight, tethered balloons, refrigeration techniques, large superconductive magnets, electronic devices, superconducting transmission lines, high-precision thermal conductivity analysis, He3-He4 dilution refrigerators, uses of helium in the atomic energy program, helium-cooled nuclear reactors, power- plant applications for high-temperature gas-cooled reactors, helium welding of stainless steel tubing and pipe, development of helium-shielded arc welding, helium as a diluent in spacecraft atmospheres, helium utilization in the Saturn-Apollo program, and helium utilization in diving environments. Papers from the Helium Centennial Symposium at the national meeting of the American Chemical Society cover the history of the discovery of helium, the history of its development by the Bureau of Mines from a laboratory curiosity to an important item of commerce, the source of helium in natural gases, the world of liquid helium, and liquid helium-3.

Jan 1, 1969

By Jaime Fernández Concha

El presente texto señala la ubicación, fisiografía, geología general y cubicación del depósito de Fierro del Cerro Tarpuy y Cerro Mirador ubicado en el departamento de Arequipa.

Jul 1, 1956

A new mine has begun production of antimony ore and concentrates in Serbia, Yugoslavia. The mine is operated by the mining and metallurgical enterprise "Aajaca." Initial production is running at approximately 45 thousand tons of ore per year, yielding about 1,500 tons of concentrate. The mine is located on the mountain Kopaonik-Raiceyoj Gori. It is planned to expand production eventually to approach the level of 300,000 tons of ore per year. This level will be a significant addition to the world supply of antimony and will place Yugoslavia among the world's major producers. Currently the United States produces only about 6 percent of its primary requirement for antimony. COBALT -Anglo American Corporation, Ltd. reportedly is considering restarting the Tenke-Fungurume copper-cobalt project in Zaire. Construction on the project was suspended in January because of inadequate financing and political uncertainties. Technical feasibility and financing on a smaller scale than previously envisioned are now being considered. However, an increased copper price may be necessary before any decision to proceed is made.

Jan 1, 1976

By Haizea Arratibel, Diana Méndez, Jhuliana Macas, Michelle Peñaherrera

La forma en la que las empresas ingresan a un territorio sienta las bases para las dinámicas de relacionamiento a futuro. El diálogo multiactor es una herramienta que permite, desde un inicio, formar relaciones de confianza y acción colectiva, pasando así de una dinámica transaccional a una transformacional. Esto alcanza resultados que van mucho más allá de la gestión de conflictos, enfocados a crear un territorio sostenible bajo un modelo de gobernanza sólido. Se presenta el caso del proceso de diálogo multiactor en Los Encuentros, Ecuador, bajo el marco del proyecto Fruta del Norte de Lundin Gold.

May 10, 2023

By D. A. Singer, J. C. Griffiths

"One of the most useful approaches to a complex problem is to model the system which gives rise to the problem and to perform simulations through the model to find appropriate solutions. The Engel Model may be used as such a simulator to investigate the problem of the exploration for natural resources.The Engel Model is based on a two-stage search procedure in which a known area (A) which contains m prizes is subjected to search by n coverings. During the first-stage search the sensor system records signals which may be a response from prizes (that is, true signals) or may be false. Signals tend to cluster around a prize and a cluster size consists of s signals. If a circle of radius R is drawn around each signal some will overlap and the overlap from s signals contains a prize. The cost of a single covering in which each point of the area comes under observation once, is designated E1. Second-stage detailed search is expensive and is confined to areas of overlap of s circles; it leads to the location of prizes. Second-stage search of the whole area costs Ea units. The expected value, V, of a prize is known and its development cost is E3 units.The sensor system characteristics are defined by the circle of radius R around a signal, which should be small compared with the total area A and enters the model as a parameter a x R2/A. The probability of a false signal during a single covering of a circle of radius I is a known constant, A.This model was applied to the search for uranium ore bodies using two different types of occurrence. In the first, the Wyoming Basin type, the area is relatively large (A = 1 496 square miles) and a few (m = 4) large prizes occur (expected value V = $30 million). In the second area, which represents the Ambrosia Lake region of New Mexico, the area is smaller (A = 212 square miles) and contains many (m = 200) smaller prizes (expectedvalue of a prize V,$2 million). The three costs, E1, E2, E3, are adjusted to the different circumstances in the two areas.Simulations were performed using n = 1 to 40 coverings with cluster sizes s = 0 to 19; the radius R was varied from 0.52 to 3 miles (and, therefore, a = 0.002 to 0.133 0, respectively, dependent on the area of interest). The value of A was varied from 0.01 to 0.10.Profitable programs were found over a wide range of the parameters; the two areas required different strategies to achieve maximum profit. In the Ambrosia Lake region a few passes (n = 4 to 6) with small cluster sizes (s = 2 to 6) are more profitable, whereas in the Wyoming Basin region a large number of passes (n = 35 to 40) and cluster sizes of s = 5 to 10 are most profitable.As pointed out by Allais (1957) the larger prizes are the most important in deciding the successful outcomes of exploration programs, and the profit margin in the search for a few large prizes is sufficient to yield success over a wide range of programs. Such programs require very large investments if they are to be successful.To refine the Engel Simulator as a decision-maker in selecting the most profitable exploration programs it is necessary to obtain firm estimates of the sensor system characteristics, that is, of R, a and ? (lambda)."

Jan 1, 2014

By C. W., Davie

"DEFINITIONDiatomaceous earth consists almost entirely of the silicious remains of minute flowerless aquatic plants known as diatoms. The name diatomaceous earth, therefore, is to be preferred to others such as trade names, inappropriate terms, or names correctly applied to some other product. The following names should, therefore, not be used for diatomaceous earth,-- kieselguhr, infusorial earth, diatomite, celite, moler, bergnehl, English rottenstone, tripoli, tripolite, fossil earth, desmid earth, white peat, tellurine, randanite, ceyssatite, or any trade name.FORMATIONDiatoms live in practically all kinds of water, fresh or salt, hot or cold, still or running and under different conditions of depth and pressure. These minute plants assimilate inorganic salts from their environment and produce skeletons of silica much as mollusks secrete lime and form their Shalls. When the diatoms die they settle to the bottom together with anything else which may be present, such as sand, clay or volcanic ash. The organic matter gradually disappears leaving the silicious skeletons of the diatoms which, with impurities, make up the deposits of diatomaceous earth. These deposits which are still being foamed at the present time and which were produced throughout very different epochs, were more prolifically formed in the Tertiary, so that the thickest beds so far discovered are of that Age."

Nov 1, 1925

By O. C. Garst

"The lightness and relatively high strength per unit weight of certain magnesium alloys have interested designing engineers for many years. Ever since the noted investigator Bunsen3/ first produced the element by electrolysis of the fused chloride in 1852, utilization of this light metal has been considered. Magnesium is widely distributed over the earth's surface in high-grade as well as low-grade deposits; it occupies eighth place in the list of elements arranged in order of their decreasing abundance, as there is 2.24 percent magnesium in the earth's lithosphere. Even though the element is distributed widely in the form of relatively insoluble: minerals and also as soluble salts in sea water and spring water, as well as being an indispensable constituent of plants and animals, the technology of magnesium was slow development. This slowness of development was first caused by confusion or the part of the early investigators who thought that magnesia, magnesite, magnetite, and the pyrolusite-type manganese ores were compounds of the same metal. At one time the metal that we now know as manganese was called magnesium, and magnesium was called either magnium or talcium. In addition to this coon, the chemical activity of the metal, especially at high temperatures, created problems that are still difficult to solve.With the advance of science in all branches, .methods for -he production of magnesium were developed. The methods first used for producing the element were: (1) reduction of magnesium salts with alkali metals,4/ (2) electrolysis of aqueous solutions of magnesium salts, and (3) electrolysis of fused magnesiun salts.The first attempts to produce magnesium by the carbothermal reduction of magnesia were failures as sufficient thermodynamic knowledge concerning the reversibility of the reaction between magnesia and carbon was not at hand. As the igneous electrolytic Method for making the element was more easily controlled than the others and. yielded more metal per unit of energy, considerable work was expended on the improvement of this process. The work in this field paralled that on the electroreduction of aluminum and the alkali metals. For several years the entire magnesium industry was dependent on this igneous electrolysis process for its supply of the metal, but as demand for the metal increased and more scientific knowledge was available, other processes were developed. Today magnesium is produced by the electrolysis of molton magnesium chloride electrolytes, the carbothermal reduction of magnesia, in arc furnaces followed by shock cooling of the furnace gases by a coin inert atmosphere, and the silicothermal reduction of calcined dolomite in stainless steel retorts."

Mar 1, 1946

By J. N. Geyer

During the early stages of the mining industry of the United States an apparently inexhaustible supply of high-quality, easily accessible coal made the product cheap and the attendant mining methods wasteful of recoverable coal. Because coal from advance places could be mined with less effort and a large outwit obtained as the entries advanced, much of the coal left in pillars to support the roof was lost. Squeezes often developed in these mined-over areas, or, if pillars were of sufficient size to-prevent squeeze, the roof would be so weakened by long exposure that any pillar recovery was extremely hazardous. As the value of unmined coal increased, a high recovery of the available coal became necessary. Numerous plans were tried during the period that followed, some of the methods proving successful while others were complete failures or only partly successful. As a better knowledge was pained of the roof strata and its behavior, however, pillar mining became more successful and methods suited to special roof conditions were developed.

Jan 1, 1933

By Nelson Rivera

El presente texto analiza la crisis económica y su relación con el Banco Minero. Para ello, se revisa las dos últimas recesiones económicas que tuvo el Banco entre 1975 y 1982, donde la crisis se agudizó por una caída en los precios de los metales y una inflación de costos que no pudo ser transmitida al precio de venta. Como consecuencia de ello, las empresas mineras que tuvieron préstamos, acusaron pérdidas en sus ejercicios e incumplieron en el pago de sus obligaciones. Como medida anti-crisis, el Banco Minero estableció comisiones de alto nivel para evaluar las situaciones y recomendar la dación de dispositivos legales que permitieron asistir a los Pequeños y Medianos mineros en la restitución de liquidez mediante préstamos sobre liquidaciones a precios deprimidos, Asimismo, generó la consolidación, refinanciación y moratoria de los clientes que estaban en suspensión de pagos de las obligaciones contraídas con el Banco Minero y la creación de líneas de crédito especiales para la Pequeña Minería.

Mar 1, 1985

By A. Eltringham

Operations downstream of mining and beneficiation are still being subjected to increasing scrutiny as highly capitalized projects have been either slow to achieve their targets or have actually failed to do so. Leaching and smelting projects have fundamentally high calls on capital and technology as reaction rates are increased and the capture and disposal of unwanted products are subjected to greater restrictions. Separating value from waste inherently becomes riskier as the purification of the desired product imposes greater demands on the process to produce benign wastes. When we superimpose on the chemistry of the project severe predictions of throughput rates, that bring in facets of manufacturing, we are introducing complexities that the records show are not handled well. This paper discusses some of the more common challenges that operators face and what methods are available and are likely to be successful in preventing the loss of value as projects are brought on-stream. This thinking needs to start much earlier and at greater intensity than our industry has normally chosen to employ.

Jan 1, 2011

By A. Demirag, F. Burat

"The most important metals in the jewelry sector are undoubtedly gold and silver. As a result of workmanship work done in the jewelry industry, the tiny metal and jewel fragments and metallic powders are scattered. Given the prices of gold and silver on the market, the dust that emanates from these workshops is of great importance. Gold recycling has become as important as raw material production within the mass market and gold production industry. In 2016, 29% of the world gold supply has been obtained through recycled gold production. Waste derived from jewelry activity is included in this category, and represents an essential component of this percentage. In the scope of this study, the recovery possibilities of Au and Ag from jewelry sweeps floor sample was investigated using flotation method. In the experiments, optimum pH value, particle size, the effect of dispersant, type and amount of reagent were investigated. As a result of these studies, it was determined that the optimum pH value was 6.5 and the particle size was -212 microns. It was observed that the most suitable reactive combination was Aero 242 and Aerophine 3418A and Na2SiO3 has no positive effect on recovery of Au and Ag as a dispersant agent. As a result of tests, a final concentrate containing 268 ppm Au and 2122 ppm Ag was obtained with 81.4% and 74.5% recovery respectively. INTRODUCTION Because of the softness of pure gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. On the other hand, gold has some special chemical properties which in normal conditions, don’t react with water, dry or humid air, oxygen, ozone, nitrogen, hydrogen, fluorine, iodine, sulfur and hydrogen. In these days, gold is used in different sectors like jewelry, electronics, finances and investing, dentistry, medicine, aerospace, awards & status symbols. According to Deutsche Bank Research, the primary usage of gold is jewelry. It has been used to make ornament and jewelry for thousands of years. In this sector craftsmen learned that alloying gold with other metals like copper, platinum and silver to increase gold’s durability. Alloying gold with other metals changes the color of the products. Another significant sector of gold is electronics. Modern electronics want the use of noble metals, like gold, especially in the areas of information processing, telecommunications, and military and space electronics (Habashi, 1997). Electronic devices use very low voltages and currents which are easily interrupted by corrosion or tarnish at the contact points. Gold is the highly efficient conductor that can carry these tiny currents and remain free of corrosion. Electronic components made with gold are highly reliable. Gold is used in connectors, switch and relay contacts, soldered joints and connecting wires. Every sophisticated electronic device have a considerable amount of gold. This includes cell phones, calculators, personal digital assistants, GPS units, and other small electronic devices. Most large electronic appliances such as television sets also contain gold. Humankind has known silver since prehistoric times like gold because silver occurs in native form. The metal is found in the Earth's crust in the pure, free elemental form native, as an alloy with gold and other metals, and in mineral such as argentite. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining. Silver is very soft metal like gold also, it is the highest electrical conductivity, thermal conductivity, and the lowest electrical contact resistance of all metals (Habashi, 1997). Silver is used in different sectors like industry, jewelry, electronics, photography silver good, and coins. The main usage of silver is supplied by electronics. Silver's unsurpassed thermal and electrical conductivity among metals means it cannot easily be replaced by cheaper materials. In addition to silver is using in ener"

Jan 1, 2018

El presente trabajo explica el panorama historiográfico del proyectoToquepala, -en tanto proyecto industrial de la historia minera del cobre-, así como su influencia en el desarrollo económico y manufacturero del Perú. El depósito mineral de Toquepala está situado en el departamente de Tacna, zona sur del país. El reconocimiento como zona cuprífera es partir de Velarde en La Minería enel Perú (1908) y Basadre en Estado actual y porvenir de la industria minera en los departamentos del sur del Perú (1918). Posteriormente en 1937, Juan Oviedo de Villegas denunció los depósitos en Toquepala y fue el geólogo Schmedeman de la cerro de Pasco Corporation, quien reconoció la mina como un depósito de pórfido de cobre. Es a partir de 1938 que se inicia la explotación y en 1948, la Northern Peru Mining and Smelting Company se hace propietario de la zona minera. La exploración del depósito de Toquepala se realizó por medio de taladros verticales, perforados con máquinas de diamantina y de percusión. Durante el periodo de perforación, se realiza un sondaje de percusión previo que determina la extensión hacia otros hoyos para muestrear los valores y así medir la capa y espesor del mineral, mientras que el sondaje diamantino informa sobre la interpretación geológica del subsuelo de esa sección. Para la comprobación de los resultados de la perforacíón se buscó comparar los resultados de perforaciones de diámetro pequeños y grandes, con aquellos del minado del mineral en volúmenes de muestras relativamente grandes. Los métodos de muestreo empleados fueron acorde a las prácticas más estrictas actualmente recomendadas en este tipo de trabajos y supervisados bajo el control de un personal técnico. Luego del trabajo de comprobación del depósito de Toquepala, a mediados del año 1955, se unieron cuatro compañías para formar la Southern Peru Copper Corporation y en ese mismo año el gobierno peruano aprueba el desarrollo del programa y operación de este proyecto . Los planes de minado fueron terminados en 1955 minero. El avance de los trabajos de preparación de este proyecto se realiza a través de dos partes: la construcción de los servicios necesarios para la operación y los trabajos de preparación preliminares a la explotación minera. El ajuste de constucción y minado del programa se culminó en cuatro años (1952 - 1954), dando inicio a la operación en 1955. Finalmente, hablar la inflluencia del proyecto de Toquepala en el desarrollo económico industrial en el sur del Perú, es señalar su apoyo en el manejo de las vías de comunicación, favoreciendo el intercambio comercial entre las zonas ganaderas de la sierra de Tacna, Moquegua y el resto del país, así como del progreso de pequeñas industrias. El acceso a la educación y la erradicación de bajas condiciones sanitarias son elementos que también ayudan al avance social de la población, otorgándole a este proyecto sureño, un lugar importante en el panorama industrial y minero del país.

Jul 20, 1957

By José María Lezcano, Diego Urquiaga, Pedro Delvasto, Marcos Garayar

La extracción de minerales ricos en sulfuros metálicos tiene el inconveniente de generar drenajes ácidos (AMD), los cuales causan severos impactos en los ecosistemas acuáticos, el suelo y el recurso hídrico. Como posibilidad de remediación (alcalinización) de estos pasivos, en el presente trabajo se propone el uso de coproductos férricos oxidados (CFO). Luego de presentar las características de un tipo de CFO específico, se muestran los resultados —a escala de laboratorio—sobre la respuesta alcalina del mismo, y se discuten las implicancias de estos hallazgos para el tratamiento de los AMD.

Nov 30, 2020

Geophysical Abstracts 1 - 86 wore issued in mimeographed form by the Bureau of Mines; Abstracts 87 - 111 were published in bulletins of the Geological Survey; Abstracts 112 - 119 were issued in mimeographed form by the Bureau of Mines as Information it ion Circulars 7256, 7257, 7267, 7273, 7285, 7292, 7303, and 7310. 1. GRAVITATIONAL METHODS 7786. Barton, D. C.3/ Case Histories and Quantitative Calculations in Gravimotric Prospecting. Am. Inst. Min. and Meat. Eng., New York, Tech. Pub. 1760, 1944, 49 pp.

Jan 1, 1945

By William W. Odell

In Europe and in certain other foreign countries studies have been made, extending over a period of years, relating to the winning of oil from oil shale. More work has been done in these countries than in the United States, for the reason that a supply of natural petroleum has not been so generally available there as here. Information has been obtained relating to present practices in these foreign lands in the development of a shale-oil industry. It is realized that in the past there has been very little inducement to invest capital in shale-oil enterprise in the United State's because the supply of petroleum has been plentiful; however, the time possibly is not far distant when the utilization of oil shale may be cons¬idered a desirable and financially sound venture, as it may be necessary before long to augment our supply of oil with that recovered by processing shale. The data presented herein portrays at least some of the thoughts of those engaged in obtaining oil from oil, shale in Europe, and they depict some of the results thus far obtained as well as certain plans for further efforts to win oil from shale; it is hoped that those who undertake the development of a shale-treating industry in this country will find useful information in this report.

Jan 1, 1946

By I. M. Wolf, S. A. Usmar, L. A. Cornish

The limiting criterion in the use of stainless steel for certain forming operations such as coining is its hardness, which determines parameters such as required striking pressure, wear on dies, and integrity of pattern detail. Attention is given here to the development of ultra-soft ferritic stainless steels for coinage. In the first instance, the influence of carbon content on the striking properties of a series of commercial and experimental 17%Cr alloys was evaluated. It was found that a lower carbon content permitted the striking of relatively highly profiled and intricate patterns, provided that the hardness did not exceed 125 HV. Hardnesses as low as 115 HV were achieved in the fully annealed condition, but these alloys required high striking pressures. In a further study, three grades of experimental 14%Cr ferritic stainless steels were produced with a view to optimizing the ductility. When the residual impurities were minimized, hardness values of about 100 HV and lower were achieved. Micro-alloying additions allowed the heat-treatment response and grain size to be controlled. Excellent tensile properties, with elongations of up to 42 per cent, were achieved in the fuly annealed condition, and highly profiled patterns were produced in coining trials.

Jan 1, 1993