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By R B. Stewart

Where pasture production is the intended land use of the areas to be reclaimed, the creation of a suitable growing +medium is a major objective. To achieve this land reclaimers require a sound understanding of the proposed mining plan and a knowledge of the physical, biological and chemical properties of materials intended for resurfacing disturbed areas. Where the original soil is not being replaced in its natural state, research is usually required to determine an alternative growing medium. Results from field research conducted on waste material from the Waihi Gold mine are reported with emphasis on the significance of soil depth in relation to pasture production in this environment.  Problems in extrapolating field research to large scale operations are also considered.   Essentially the requirements for successful pasture production, on surrogate growing medium, are akin to conventional approaches used in New Zealand in the development of unimproved agricultural land. High inputs of fertiliser are initially needed, especially where volcanic soil is used, and careful management of pastures and soils is required to minimise soil erosion and create a sustainable system. In the first three to five years of pasture production, grazing use of the land requires to be dictated by pasture availability and soil conditions and not by animal feed requirements. The use of light stock (young dairy or sheep) is recommended.   Successful land restoration requires a team approach by a range of cooperative specialists including engineers, soil scientists, farm managers, agricultural contractors, landscape architects and environmental officers.

Jan 1, 1991

By J. A. King, D. A. Knight

"The Porgera orebody is located in mountainous terrain in Enga Province, Papua New Guinea. An underground mine has been developed which produces up to 2000 t/d of ore grading over 2 ozs Au/t. Some 79% of the gold in the ore is free, with the balance in a highly refractory form as sub-microscopic gold evenly disseminated within a pyrite matrix.This paper describes the metallurgical plant that uses flotation and cyanidation circuits to effectively recover the free gold in the ore feed, allowing for wide variation in the gold head grade. The refractory gold component in the ore is stored as leached pyrite flotation concentrate and this concentrate will be later treated by autoclaving techniques to recover the contained gold.The ProiectThe property is located in the Porgera Valley 600 Km North West of Port Moresby. The remote location is 2500 m above sea level. The mine area has 3600 mm of annual rainfall and a temperate climate with temperatures ranging from 10° c to 22° c throughout the year.Alluvial gold was reported in the Porgera area in 1938 and has been an important source of revenue for the area for many years. Intermittent exploration was carried out until the 1960 1 s when Placer (PNG) Pty. Ltd. with Mt. Isa Mines commenced an extensive exploration program. The property was brought to production in 1990 by the Porgera Joint Venture group consisting of Mount Isa Mines Ltd, Rennison Goldfield Consolidated Ltd. and Placer Dome Inc, each with a 30% ownership and the Government of Papua New Guinea with a 10% share. Placer Dome Inc. is the manager of the property with construction under the direction of the Placer Dome Technical Services group."

Jan 1, 1992

By X. Zhou

In this study, the cyclonic static microbubble flotation column (FCSMC) was investigated for fluorite beneficiation. The structure and principle of the specially designed column are described. Fluorite samples from the tungsten separation tailings of the Shizhuyuan Mine, Chenzhou, Hunan Province, P.R. China, were tested using a small-scale continuous flotation test unit, and concentrates with a fluorite grade higher than 98% were obtained. One rougher and three cleaner stages in the FCSMC achieved the same separation performance as one rougher and eight cleaners in conventional flotation cells. This greatly simplified the flotation circuit and reduced operating costs.

Jan 1, 2007

By J. F. Lupo

Leaching operations combine both metallurgical and hydraulic processes to extract metals from the ore heap. In the design of leaching operations, metallurgical tests and simple hydraulic tests are often conducted to define operational parameters such as leach cycle time, application rate, lift height, and effective leach area. While metallurgical constraints are often the primary focus on leach facility design, the hydraulic factors are also critical to the overall success of the operation. Some of the hydraulic factors that are known to impact solution flow through heaps include: • Ore physical and hydraulic properties, • Variation in ore properties under heap loading, • Ore mineralogy and its susceptibility to chemical and/or mechanical degradation, and • Heterogeneities within the heap. This paper presents a discussion on hydraulic factors that may impact the effectiveness of leaching operations. In addition, methods are presented which may be used to assess flow conditions within active and inactive heaps.

Jan 1, 2000

By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By Archie Richardson

The trona mines in the Green River Basin, commonly known as the "trona patch," present an interesting set of rock mechanics issues stemming from mining in a unique underground environment. Like other minerals occurring in tabular deposits, trona is mined using high-productivity room-and-pillar and longwall methods. However, trona does not behave quite like other evaporites and behaves far differently than coal. In this paper, the following key issues in trona patch rock mechanics are discussed: material properties, in situ stress field, water and gas pressure effects, creep characteristics, pillar behavior, roof span stability, floor stability, underground tailings storage, longwall mining, two-seam mining. and solution mining. Many of the existing trona producers are entering potentially more difficult mining conditions, and much consideration is being given to "new" technologies such as longwall mining and solution mining. In analyzing 20 years of experience with trona patch rock mechanics issues the authors have identified key comparisons and contrasts with conventional tabular deposit rock mechanics that will help illuminate what has been learned as the trona patch enters the 21" century.

Jan 1, 1999

By James W. Reil

A test series of small, precisely-controlled and thoroughly-monitored production blasts was conducted at two quarries. In each series, all variables except delay were kept constant, as much as practically possible. The first aim of the study was to determine the effect of local geology on ground vibration. The second aim was to test several hypotheses relating the effect of millisecond delay intervals to fragmentation and ground vibration. A resonant frequency of ground vibration was shown to be related to the thickness of the overburden, in accord with a model proposed by Gupta (1961). Since the overburden geology creating this resonant vibration cannot usually be changed, two methods were tested to choose delays such that blast vibrations would destructively interfere. These were shown to be effective in modifying both the peak particle velocity and response spectra of ground vibration. The delay interval chosen also affects fragmentation, primarily in massive rock, with an optimum relief between holes of 2 ms/ft. Strain gage records indicate a possible mechanism consistent with this information.

Jan 1, 1985

By David Preece

The Thirlmere aqueduct was constructed over 110 years ago to provide water from the Lake District (in the north-west of England) to the city of Manchester some 60 miles (100 km) away. The aqueduct remains, to this day, a key piece of infrastructure in the distribution of raw water in the north-west of England. A short section of the aqueduct was identified as being in poor condition during routine inspections by the owner. Subsequent investigations attributed the conduit damage to the movement of unstable ground over the conduit. Bachy Soletanche Ltd was subsequently appointed to carry out the design and construction of the slope stabilisation works and to undertake repairs inside the damaged conduit. The works were undertaken on an existing slope which, in places stands at a gradient of up to 40º to the horizontal. Strict limitations on plant and equipment were imposed by the client (United Utilities) to ensure that slope and conduit loading and associated vibrations were kept to an absolute minimum during construction. An intensive instrumentation system was installed to monitor surface movements, ground movements at depth, conduit movement and strains across existing planes of weaknesses within the conduit. The solution comprised the installation of spaced piles up-slope and down-slope of the conduit. Restrictions were imposed on the minimum stand-off distance between the outside face of the conduit and the piling works so targeted permeation grouting was undertaken to improve the ?connection? between the conduit and the down-slope piles. The presence of existing sub conduit groundwater flows was suspected and the permeation grouting was focused in areas to minimize disruption to the groundwater regime. The paper presents the basis of the design and highlights the combined construction and instrumentation methods adopted to minimise damage to this valuable asset.

Jan 1, 2011

By G. Capobianco

"The coal industry is an important part of Canada's economy - as an energy source, employer, and generator of export earnings. Coal comprises 71% of our fossil energy and with rapidly advancing handling and burning technology will clearly play a major role in our national energy mix, eventually as synthetic gases and liquids.International coal markets are very competitive and Canada is disadvantaged by long rail hauls to port, and a heavy tax burden. However, high mine productivity has allowed us to increase our markets.Currently, domestic markets are dominated by coal use for electrical generation, a market with significant growth opportunities.Strong growth is expected in export thermal markets, while metallurgical coal demand is projected to show little or no growth in the medium term. IntroductionThe coal industry is a vital part of the Canadian energy scene .• Coal supplies 17% of Canada's energy.• On a per capita basis, Albertans use more energy in the form of coal than they do oil and gas.• The value of Canada's exports of coal last year was equal in value to all the cars we imported from Japan.• Coal is our largest single export to our seco nd largest trading partner, Japan.• The value of coal produced in Canada exceeds the value of any other single mineral produced in thi s country.• In Alberta, the safety record for coal mines is on a par with that of department store clerks.• The coal industry employs about 25% of the total number of people employed in all metal mines in Canada, directly and indirectly accounting for about 50 000 jobs.Coal comprises 71% of Canada' s hydrocarbon energy resources on a crude oil equivalent basis . This is more than double our oil sands resource and dwarfs our conventional crude oil and gas resources (Fig. I). In the short term, coal as a solid fuel plays a significant part in the Canadian energy scene. In the longer term, coal, in the form of electricity and eventually liquids and gases, has a tremendous role to play. In 1986, Canada produced 57.8 million tonnes, slightly down from the record high of 60.8 million tonnes in 1985. Our exports in 1986 were 26.0 million tonnes, a growth of 53% in three years."

Jan 1, 1988

By Pedro Tumialán

Los yacimientos mineralizados metálicos de la cordillera de Huayhuash se hallan en rocas estratificadas del cretácico medio, discordantes y algunas veces concordantes con la estratificación en rocas ígneas del terciario. En ese sentido, el presente texto describe el estudio de esta asociación mineralógica a través de la división de tres áreas: zona de Pacllón (sur), zona de Huallanca (central este y norte), zona de Tucu Chira (central oeste); en una extensión total de 60 por 45 Km. Asimismo, los minerales económicos se hallan con otros no económicos, deduciendo una serie de guias mineralógicas para la exploración minera.

Sep 1, 1976

By Zhuofei Yang, Jidong Kang, David S. Wilkinson

The fatigue behavior of AM60 high pressure die casting magnesium alloys was studied in a straincontrolled manner. The fatigue test was interrupted every 2,000 cycles for X-ray tomography scanning. The specimen was removed to be scanned on a desktop micro-CT system. The value of using X-ray tomography in a fatigue properties study was assessed with respect to porosity, cracks and fracture surfaces. The 3D analysis and model results showed porosity could be well measured and modelled in 3D. Defects bands are made of pores under 50 µm in volume-equivalent sphere diameter. Larger pores are randomly distributed in the region between two defect bands. Observation of cracks by X-ray tomography occurs in three ways such that the 3D model gives the best illustration of crack-porosity interaction while the other two methods have better detectability on crack initiation and crack tip observation. X-ray tomography is also of value in failure analysis on fracture surfaces. By summarizing X-ray tomography data during fatigue testing and observing fracture surfaces on a 3D model, a better understanding on the crack initiation, crack-porosity interaction and the morphology of fracture surface is achieved.

Jan 1, 2014

By J. -F. Lessard

Most underground mines rely on ore pass systems to ensure the transport of ore and waste. The design and operation of ore pass systems often rely on past experience, which is often anecdotal and at times contradictory in nature. This paper summarizes the current practice in Quebec underground metaliferous mines. The information was collected during a series of site visits in ten underground mines. The database includes information on ore pass configuration, support, materials transited, and overall ore pass performance.

Jan 1, 2006

By Don Rose

INTRODUCTION A number of tunnels supported and permanently lined by steel-fiber-reinforced shotcrete (SFRS) have been built in North America in the 1980s. The material is more economical than, and technically equal or superior to, conventional shotcrete using wire mesh. The design and construction of SFRS-lined tunnels is straightforward, and only a few new design principles, laboratory tests or construction equipment modifications appear necessary in order to use this material. Modern tunnel Contractors may use cyclic drill-and-blast methods on some tunnels, with intermittent shotcreting as part of an orderly cycle. The Dry Mix method is most suitable for cyclic, intermittent, relatively small-scale shotcreting. However, modern Contractors excavating tunnels continuously using large long Tunnel Boring Machines (TBMs) or Roadheaders may prefer Wet Mix shotcreting on a mass production basis. In either case, the use of steel-fiber-rein¬forced shotcrete (SFRS) promotes the rapid and economical excavation of tunnels. The addition of microsilica will improve SFRS properties and reduce rebound, and is expected to become standard practice with SFRS in North America, as it now is in Scandinavia. HISTORICAL REVIEW Steel-fiber-reinforced shotcrete (SFRS) at the present time (1985) is essentially conventional shotcrete with straight or deformed steel fibers added, and in general SFRS for tunnel linings encounters the same problems that conventional shotcrete does. Shotcrete history is well known. The use of sprayed plaster on wire frames for mounting animal skins by Carl Akeley of the Smithsonian

Jan 1, 1985

By Sara Jane Boles

In recent years the demand for products of greater refractoriness has placed an ever-increasing emphasis on ceramic materials, including the metallic oxides. Magnesia (MgO) is one of the most important of these oxides, exhibiting, as it does, high electrical resistivity, high slag resistance, and a melting point of 2,800° C. However, magnesia has a tendency to hydrate in the presence of water and to volatilize above 1,500° C. in certain kiln atmospheres and has a comparatively low resistance to thermal shock. Because of these disadvantages, the previously listed advantages inherent in this material have been largely overlooked, and research on magnesia has lagged behind that on oxides such as alumina and zirconia. This bibliography has been prepared in an effort to present to Government and industry a comprehensive picture of the prospects for greater utilization of magnesia as a refractory material in future research. To provide as selective and accurate a collection as possible, the references included cover magnesia in a pure state, not as an additive or in combination with other materials. However, several references discuss the effect of minor impurities (less than 5 percent of the total) on the properties of magnesia, as these papers are considered to be of special importance. A few references to articles on forming techniques are also included, as they are valuable additions to the overall treatment of the subject. The processes used in obtaining and refining the raw materials are adequately covered in earlier publications and are excluded. A number of references are omitted as being of questionable value in enhancing the cumulative study of pure magnesia as an ultra-high-temperature refractory material.

Jan 1, 1962

By João Carlos Jânio Gigolotti

Foram estudadas experimentalmente as relações de fases do sistema Nb-Ti-Si na seção isotérmica a 1200 °C. Ligas fundidas em forno a arco em atmosfera de argônio a partir de Nb, Ti e Si de alta pureza (? 99,9 %), foram tratadas termicamente a 1200 °C durante 264 h em forno tubular, em atmosfera de argônio, encapsuladas em tubos de quartzo. As ligas tiveram sua microestrutura caracterizada por difração de raios-X, microscopia eletrônica no modo elétrons retroespalhados e por microsonda. Ficaram determinados os campos ternários Nb5Si3 + (Nb, Ti)3Si + (Nb, Ti, Si), Nb5Si3 + (Nb, Ti)3Si + Ti5Si3, Ti5Si3 + (Nb, Ti)3Si + (Nb, Ti, Si), Nb5Si3 + Ti5Si4 + Ti5Si3, Nb5Si3 + Ti5Si4 + NbSi2, NbSi2 + Ti5Si4 + TiSi, NbSi2 + TiSi2 + TiSi e NbSi2 + TiSi2 + SiSS. Existe boa concordância dos resultados com as propostas calculadas e experimentais existentes na literatura para essa seção isotérmica do sistema Nb-Ti-Si. Pequenas alterações composicionais são sugeridas para a locação dos campos ternários observados.

Aug 16, 2017

By Luiz Augusto Ferreira de Campos Viana

O processamento de aços ARBL (Alta Resistência Baixa Liga) para fabricação de bens de capital de dimensões avantajadas pode sobrecarregar máquinas operatrizes de indústrias do setor metal-mecânico. Uma rota alternativa para processamento deste material é a conformação do mesmo a temperaturas elevadas (processamento "a morno"), para redução de seu limite de escoamento e consequente diminuição do esforço nos equipamentos. Entretanto as propriedades mecânicas destes materiais devem ser mantidas após seu retorno à temperatura ambiente. Neste trabalho um aço ARBL temperado e revenido foi submetido a 1, 3, 5, 7 e 9 ciclos térmicos, com a soma do tempo de todos os ciclos térmicos igual a 10 horas e temperatura de 580°C. Em seguida ensaios mecânicos de tração, impacto em corpos de prova Charpy-V e dureza Vickers foram executados. A caracterização microestrutural e análises fratográficas dos corpos de prova de tração e impacto foram realizadas por meio de microscópio eletrônico de varredura (MEV). A análise microestrutural revelou o coalescimento de partículas de cementita em todas as amostras. A resistência mecânica dos corpos de prova submetidos a 1, 3, 7 e 9 ciclos caiu. A energia absorvida no ensaio de impacto aumentou para estas amostras. O corpo de prova submetido a 5 ciclos térmicos apresentou endurecimento secundário. A fratografia de todos os corpos de prova ensaiados a tração revelaram fratura dúctil. O mesmo ocorreu para os corpos de prova submetidos ao ensaio de impacto, exceto para os corpos de prova submetidos a 5 ciclos térmicos. Em nenhum dos casos ocorreu descaracterização do material com quedas nos limites de resistência a valores inferiores aos especificados pelo fabricante.

Aug 16, 2017

The Ross Goldfield is a unique gold resource. From its discovery in 1865 there was a growing understanding of the geology of the deposit as mining moved from the surface at Jones Flat in the south to underground extraction at Ross Flat further north. Multiple layers of gold-bearing gravels were penetrated in deep shafts and six rich gold-bearing bottoms were worked. The ultimate bottom on the Old Man Group gravel surface has never been reached either at Jones Flat or at Ross Flat. Mining at Ross Flat was ultimately halted by uncontrollable flooding, by escalating costs and by a shortage of labour during the First World War. Mining at Jones Flat recommenced in the late 1980s and attention has once again been drawn to the potential magnitude of the resource at Ross Flat. Research of historic literature shows that there is potential for a bulk gold grade of 400 mg/m3 in a volume of 82 million cubic metres of gravels which lie in a basin between Jones Flat and north Ross.

Jan 1, 1993

By R. P. Harvey, J. E. Walstrom, A. A. Brown

In view of the large number of wells directionally drilled from offshore platforms and urban drillsites, greater interest is being focused on the directional survey and on the uncertainty inherent in calculating the position of the bottom of the hole, or other benchmarks in the wellbore. Of the two methods presented here for evaluating this uncertainty, the first is analytical and uses the principles of probability and statistics. The second method uses Monte Carlo simulation to generate a pattern of the scatter of possible bottom-hole locations. Both methods are based on a model for which the usual assumption is made that the curvilinear axis of the wellbore is adequately represented by a large number, M, of linear segments joined end to end from the top to the bottom of the hole and closely following the course of the hole. The errors due to this approximation are assumed to be negligible and are not studied here. One form of the model is to consider that for a given hole there exists a perfect set of data describing it, of the above form. Each linear segment has an angle of inclination with the vertical 7, in radians, an azimuthal angle from true north xi in radians, and a length Si, in feet. The subscript variable, i, extends from 1 to M. Each of the M linear segments representing the axis of the wellbore has three components in the X, Y, and Z directions. These components are calculated from the equations: The bottom-hole coordinates as determined from the reference set of data for the wellbore are given by the following for i = 1 to M: X=SX, Y = Sy, Z=SZ; . (2) A directional survey instrument, lowered into the wellbore to the M segments, or stations, measures the values of the 7; and the 3,. In general, because of errors from various sources, the resulting angular measurements will not be precisely equal to the 7" and xi. Random variables l, and Ai are therefore considered with associated probability density functions fi(li) and gi(Ai), respectively, which represent the distributions of potential survey measurements for this hole. Since it is assumed that the values Si are accurately measured they are treated deterministically. The random variables corresponding to the surveyed bottom-hole coordinates are given, for i = 1 to M, by:

Jan 1, 1970

By L D. Queen

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Tifalmin porphyry copper district is located in the Star Mountains roughly 35 km north-east of the Ok Tedi mine. The district is a cluster of temporally and geochemically related porphyry copper deposits and their associated skarns. It covers an area of roughly 10 × 6 km and comprises at least three intrusions (Olgal, Futik and Kum Kom) where drilling has demonstrated the presence of porphyry copper mineralisation, and another three intrusions (Rattatat, Unfin and Pad 48) where porphyry copper mineralisation is strongly suggested by surface investigations and geochemical or geophysical signatures.Copper and gold mineralisation was first discovered in the area in the 1960s as part of the regional exploration program by Kennecott that located Ok Tedi. The mineralisation is associated with poly-phase porphyritic diorites, quartz diorites and tonalites that intrude the Upper Eocene to Middle Miocene Darai limestone and underlying Cretaceous to Eocene Feing Group. Radiometric K-Ar and U-Pb zircon ages cluster between 4 and 2 Ma for both the mineralised and post-mineral intrusions. In addition to porphyry-type mineralisation, variable amounts of calc-silicate and/or magnetite skarn occur near the contact of most of the intrusions. Mineralisation in the Olgal and Futik porphyries occurs as chalcopyrite replacement of mafic minerals and in a stockwork of micro-veinlets. Mineralisation mostly occurs in the intrusions but is also observed in hornfelsed siltstones and sandstones of the Feing Group on the southern margin of the Olgal intrusive body. Quartz veining is uncommon. Secondary magnetite is commonly associated with the highest copper and gold grades. Sericitic alteration is most prominent in the mineralised hornfels. Structurally, the area is dominated by syn- to post-mineralisation thrusting from the north. At least one of the deposits (Olgal) appears to be truncated at depth by a thrust fault.CITATION:Queen, L D, 2015. The Tifalmin porphyry copper gold district, Star Mountains, Western Papua New Guinea , in Proceedings PACRIM 2015 Congress, pp 357–360 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By C. Feng, C. Elbaum

Knoop hardness measurements were carried out on large grains of iodide titanium containing different amounts of oxygen. For each oxygen content the hardness is recorded ainingas a function of the crystal orientation and of the angle 4 between the indenter diagonal and the projection of the C (hexad) axis in the surface. The results can be expressed by the following relation; hardness = n-k cos 2ø, where n and k are constants for a given oxygen content and crystal surface orientation. A NISOTROPY of hardness is a well-known phe-nomenon and has been reported for many metals.1-3 At the present time, however, such information is not available in the literature for titanium. Consequently, a systematic study of the simultaneous effects of oxygen content and crystallographic orientation on the hardness of titanium was undertaken in this laboratory. Evaluations of oxygen content in titanium are frequently carried out through hardness tests. Although such procedures may be justified in small grain specimens, the results of the present investigation indicate that the anisotropy of hardness should be taken into account in the case of coarsegrained specimens as well as in the case of pronounced preferred orientation. Materials and Experimental Procedures Iodide titanium, 99.99 pet pure and containing of the order of 0.002 wt pet O, was used throughout this investigation. The metal was arc melted in an argon atmosphere and cold rolled into strips 1/16 in. thick. These strips were subsequently recrystal-lized and strain annealed in vacuum (10" mm Hg or better) at 850°C in order to produce crystals varying in diameter from 10 to 25 mm. Oxygen was introduced into selected large crystals by heating at 700°C in an atmosphere of pure oxygen under an observed pressure of approximately 50 mm Hg. Each sample was subsequently annealed in vacuum at 850°C for 100 hr, in order to homogenize the oxygen content throughout the specimen. It was found that longer annealing was not necessary, for no change of surface hardness in a given direction was detected after prolonged annealing. The oxygen content was determined by the difference in weight of the specimens before and after the oxidation-annealing cycle. The accuracy of oxygen determination is within ±0.1 mg in samples weighing 0.5 to 1 g. A vacuum fusion analysis of oxygen was performed on several samples and gave results in good agreement with the ones obtained by the weight change. It should be emphasized that expected weight losses through evaporation of the metal in vacuum at 850°C' are many orders of magnitude lower than the precision of these measurements. Following the annealing treatment, both oxidized and unoxidized crystals were carefully polished. All detectable traces of surface cold working were removed by repeated polishing and etching. Laue back reflection X-ray patterns were taken for each crystal for the purpose of determining the orientation and ascertaining the absence of substructures detectable by this method. Hardness measurements, using a 1 kg load, were subsequently carried out on a Tukon hardness tester equipped with a Knoop indenter. The Knoop indenter was used throughout this work because indentations obtained by means of a Vickers indenter are considerably distorted due to the anisotropy of the elastic constants in titanium. Such distortions are much less pronounced in the case of Knoop indentations, although for some orientations a cer-

Jan 1, 1959