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By J. S. Coats, G. E. Patts, N. Hughes

Conventional sampling methods are known to suffer from the variable loss of fine gold by elutriation. Freeze sampling yields representative and quantitative data that, when combined with information on the sedimentology of gravel-bed rivers, may facilitate the development of improved dispersion models for source detection. It is suggested that freeze sampling may have particular application to the orientation stage of a large gold exploration survey

Jan 1, 1991

By Xuejing Xie, Tianxiang Ren

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Standardised stream-sediment sampling procedures have been used in mountainous and hilly terrains. Special sampling procedures were developed for application in remote environments, such as high mountains, desert, semi-desert, karst and loess-covered regions. The diversified analytical methods used in more than 20 analytical laboratories participating in the project have been unified into two multi-element, multi-method analytical systems. A unified data monitoring procedure was developed based on primary and secondary standard samples. To date the project has covered about 4 000 000 km2 and the aim is to complete the coverage within the present decade

May 1, 1991

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

By L. Villa, O. Suarez, D. Arias, L. G. Corretge

The deposit comprises two vertical, lenticular bodies emplaced in the allochthonous block of a Variscan thrust. Epigenetic mineralisation occurs as replacement of carbonated volcaniclastic rocks of Cambro-Ordovician age. The dominant sulphide minerals are sphalerite and galena with minor chalcopyrite; the main non-metallic mineral is quartz and there is hydrothermal silicification, chloritisation and sericitisation. Sulphur isotope values for sphalerite and galena are heavy and reflect the fundamental relationship between delta-34S in ZnS and in PbS, suggesting isotopic equilibrium. Four sphalerite-galena pairs yield temperatures between 163 and 218 degrees C, in good agreement with the 187-207 degrees C estimated by the Ga/Ge-sphalerite geothermometer. The ore sulphide was leached by the hydrothermal solution from diagenetic pyrite in the host rocks and disseminated sphalerite and galena in Cambrian carbonates

Jun 19, 1905

Carbon anode cells were studied by two-dimensional computer simulation to evaluate their suitability for alumina electrolysis at high superficial current densities. The most efficient anode arrangement was needed to overcome the electrochemical disadvantages of alumina's low solubility in chlorides. Cells with packed-bed anodes might provide practical superficial current densities greater than 0.67 A/cm2 when the granule size was less than 1 cm, but in the process of electrolysis the granules within the active zone would be consumed and become smaller, affecting alumina concentration transport. For zones of very small granules a concentration-dependent model should be considered; for more complete consideration a time-dependent model can be introduced to describe the variation of granule size and its influence on mass transfer and polarisation

Jun 19, 1905

By A. T. Iannacchione

Underground mining of stone in the US is increasing, as is the depth of overburden above the mines. Data gathered from mine visits, maps, discussion with operators and numerical simulation have been used to investigate pillar design and recommend safe practice. Many pillars have slender shapes with relatively large adjacent mine openings: width-to-height ratios range from 0.54 to 3.13 and extraction ratios from 0.56 to 0.91. The pillar material is often very strong and average overburden only 80 m, but occasional failure due to excessive local stress has occurred where pillar size had been unintentionally reduced, overburdens were greater than 200 m, width-to-height ratios were less than 1.25 or extraction ratios were greater than 0.83. Pillars with width-to-height ratios of less than 1.5 appear more likely to fail under excessive stress. When width-to-height ratios fall below 1.0, defects such as through-running discontinuities can have a significant influence on stability. Dip, orientation and material properties are also important

Jun 21, 1905

By M. K. G. Whateley, W. Hatton

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 20pp., 31 refs. Estimates of coal tonnage on UK open cast mining sites often vary from the recoverable tonnage. This is because the estimates depend on the geological variability of the coal measures. Geological parameters, such as thickness, quality and disturbance of the seam, have a direct control upon this variance. Risk analysis techniques have been applied using commercially available software to combine each parameter's variability into a cumulative variance, resulting in a tonnage distribution. Sensitivity modelling has also been used to identify the geological parameters which have the largest influence on the variance of the simulated tonnage distribution. An understanding of the relationship between the tonnage and geological variability has helped to focus exploration more efficiently. A cost to risk relationship can now be monitored, helping management to avoid negative consequences on site

Aug 1, 1995

By P. P. Jenkins, T. G. Ball

Paper presented at the Drillex '90 conference held in London, 5 April 1990. Two drilling techniques are employed - guided longhole drilling and reverse circulation coring - for underground longhole exploration of the coal reserves and the fault structures that affect them. These are complementary to, or replacements for, surface boreholes, underground development drivages and seismic techniques. The developments of the drilling techniques and some case histories are presented in detail.

Jan 1, 1991

By R. A. D. Pattrick, R. A. F. Ixer

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. At Calliachar Burn, 14 steeply dipping quartz-sulphide veins, with and without gold, infill master joints that crosscut gently dipping metasediments and metabasics of the Pitlochry Schist Formation. The wallrock is extremely bleached and enriched in sericite, chlorite and carbonate. Gold grades vary from high with quartz-galena-pyrite to low with galena-chalcopyrite; the gold forms electrum inclusions smaller than 20 micrometres in pyrite or, rarely, arsenopyrite. At Urlar Burn, gold is present in small amounts in 4 quartz-galena-chalcopyrite veins. Although much of the mineralogy is similar to that at Calliachar, there are significant differences in Sb-, Te-, Bi- and Hg-bearing phases. Fluid inclusion data suggest mineralisation occurred over the range 320-140 degrees C, from fluids with significant CO2 and 2-13 wt% equiv. NaCl. Mantle-derived fluids appear to have been generated during the late Caledonian and focused by the Urlar Burn fault

Jun 19, 1905

By T. Yalcin

In the Box-Wilson method, the correlation between dependent and independent variables is represented by a polynomial response function, whose constant and coefficients are determined by applying regression analysis to the experimental data collected. The five levels used for each variable consist of a minimum, a maximum and three intermediate values. A study was carried out using Ni-Cu ore from Sudbury, Ontario, in which 15 experiments designed according to the Box-Wilson method were carried out in random order and in duplicate. The two sets of replicate data showed close similarity, with an overall variance of 0.311 for the five parameters studied. The response functions were used to optimise frother dosage, collector concentration and air flow rate and an experiment was then carried out under the optimised conditions; the results agreed closely with those predicted by the response functions

Jun 21, 1905

By M. J. Scoble, L. M. Daneshmend, C. Hendricks

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. An attempt is made to relate emerging technologies to education and training requirements by examining the nature of the Canadian mining industry's human resources. Particular attention is given to the trends evident in mine automation and their likely impact on instructional needs. The characteristics of "computer-aided instruction" systems are reviewed and related to the implementation and support of mine-wide monitoring and communication networks, which are seen as fundamental to the eventual automation of underground hardrock mines

Apr 1, 1994

By F. Tailoka

Bi was electrorefined from alloys containing 10-90 wt% Pb, together with Cu and Ag as minor impurities, in a basic cell and in a recessed-channel cell with 27.5:72.5 NaCl-PbCl electrolyte at 450-470 degrees C and 10 000-20 000 A/m2. The voltage in the basic cell was as high as 9 V, with some carryover of Bi to the cathode observed, whereas in the recessed-channel cell it was as low as 285-635 mV. Flow patterns observed in a room-temperature model indicated that the recesses provide both static liquid hold-up and good mixing of the alloy, enhancing cell performance in combination with the reduced anode-cathode distance of 0.90 mm. The purity of the resulting anode product is as high as 99.9%

Aug 1, 1995

By D. M. A. Flight, P. M. Green, J. A. Plant, P. R. Simpson

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The British Geological Survey's regional geochemical database is used to identify the patterns associated with the various mineral deposit types and to examine the extent to which their distribution reflects the presence of long-lived metallogenic provinces in the crust. Image analysis provides new insights into the setting of the mineralisation, geochemical constraints on tectonic models of Caledonide evolution and evidence for terrane amalgamation and large-scale processes. There is evidence that much of the mineralisation reflects the presence of long-lived provinces with a distinctive geochemistry reflecting their origins as zones of crustal extension. In the case of the Middle-Upper Dalradiam sedex deposits, the relationship between geochemistry and tectonic setting is direct. In other cases, rocks deposited in extensional zones appear to have acted as reservoirs of ore-forming elements which were further concentrated during later events

Jun 19, 1905

By S. L. R. Lenharo, H. Kahn, H. Born

Different ore types result from the irregular spatial distribution of the associated alkaline/carbonatite rocks and the zoned alteration profile within which apatite may have undergone reprecipitation. Different flotation responses are caused by their mineralogy, iron oxide impregnation and grain-size characteristics. Samples from seven deposits were crushed, screened and separated before being studied by chemical analysis, optical microscopy, X-ray diffraction, FTIR spectroscopy, cathodoluminescence and scanning electron microscopy. Two main apatite varieties with peculiar crystal morphology were identified: hydroxy-fluorapatite as the primary phase and carbonate-fluorapatite as the reprecipitated phase. The former occurs as prismatic or ovoid grains and the latter as polycrystalline aggregates or crusts on the primary grains; both are associated with iron oxide coatings (primary) or intergrowths (secondary). Microflotation tests showed variations in flotability for particular apatite associations as well as intensity of iron oxide coatings. The differences in flotation behaviour can be related to morphological properties and chemical substitution in the apatite structure

Aug 1, 1996

By L Besra, A. R. Prasad, B. P. Singh

The role of surface-chemical phenomena and the physical processes that participate in the dewatering of a suspension of alumina trihydrate were subjected to a systematic investigation, which has increased understanding of the influence of surface tension, contact angle and adsorption in the process. The residual moisture content of the cake can be reduced significantly through the use of surface-active agents in slurry pretreatment or as wash-water additives. The effectiveness of a particular surfactant is hard to predict from any single parameter, but is dependent on its ability to reduce surface tension and possibly to modify the solid-liquid contact angle. If scaled up to industrial operation of the dewatering step of the Bayer process in India, the use of these chemical additives could substantially improve its process economics, reducing the fuel costs for thermal drying by a much as Rs 50/t

Jun 21, 1905

During the construction of storage caverns, and during their lifetime if the use to which they are put so requires, it is necessary to provide adequate ventilation to ensure the safety and comfort of the underground workforce. An analysis of likely contaminants during construction has indicated that where a large facility is situated in a rock mass of even moderate temperature climatic conditions are likely to be the limiting factor during most of the mining operation and atmospheric pollution when blasting is undertaken. Possible options for improvement are increased air flow, cooling of intake air and reduction of the heat source by altering the number and type of haulage units employed in the cavern. Local solutions are an alternative approach where heat problems are confined to a few specific locations

Aug 1, 1994

By H. K. Taylor, B. Denby, L. D. Smith

Contributions by H.K. Taylor and G.A. Davis discuss the three papers published in Transactions IMM A, vols. 103 and 104, with responses by Smith and Dowd

Dec 1, 1995

By T. B. Colman

Paper presented at the MEP '89 conference held in Madrid, 13-15 November 1989. Britain has sustained an important metalliferous mining industry over many centuries. Recently, new geological concepts and exploration techniques have indicated that there is considerable potential for the discovery of a variety of deposit styles, often in previously neglected areas. The recent discoveries at Aberfeldy (Ba-Zn-Pb), Gairloch (Cu-Zn) and Cononish (Au-Ag)in Scotland and Curraghinalt (Au-Ag) and Lack (Au-Ag-Pb) in Northern Ireland are illustrations of this potential. Some of the prospective areas for future exploration are described and an indication is given of the legislative framework within which mineral exploration and development are carried out

Jan 1, 1991

By B. M. England, L. C. Mackey

Magnesia minerals are included in most iron ore sinter mixes to provide the MgO requirements of blast furnace slag. The properties of these minerals have an influence on the eventual sintering properties of the mixes. A detailed study was undertaken of serpentine and dolomite and the use of limestone, olivine and magnesite was also investigated. A consideration of particle properties indicated that as these materials calcine a reduction in size can occur together with cracking and changes in surface properties. These changes could affect the permeability of the sintering bed and sintering performance. Studies of sintering reactions showed that magnesium and calcium, formed from the calcination of dolomite, are extremely mobile before the formation of melt. Evidence suggests that the movement of these oxides into surrounding areas is via a solid-state diffusion process. The diffusion of Ca into the surrounding hematite particles is faster than that of Mg, resulting in the formation of dicalcium ferrite and magnetite or magnesioferrite, the last two subsequently being converted to dicalcium ferrite in the presence of Ca with removal of Mg from the structure as ferroan periclase. Studies of pilot-plant sinters indicated that reaction mechanisms formulated from the bench-scale studies were occurring in actual sintering processes. The differences in sintering reactions between dolomite and serpentine were considered to be the major cause of differences in the availability of lime for bonding phase formation. Pilot-scale studies indicated that the sintering properties of a mix containing dolomite could be improved by increasing the basicity of the sinter mix while keeping the MgO level constant

Jun 18, 1905

By G. G. Barbante

Anode slimes produced during copper electrorefining are a valuable source of silver, gold, selenium and tellurium. The conventional pyrometallurgical process for treating slimes involves preliminary leaching in sulphuric acid followed by smelting in a reverberatory furnace with fluxes, but it is slow and has many recycle streams. The chemistry of the phases and the reactions that occur in slimes smelting are poorly understood and and this prevents major improvements to the process. Laboratory-scale experiments were conducted using unleached slimes, with and without the addition of fluxes and under neutral, oxidising and reducing conditions. Results show that selenium is readily removed as gaseous selenium dioxide and that molten Cu-Ag-Se-O phases form when fluxes are added. Oxidation-refining of these phases by air injection and flux addition can result in the formation of silver suitable for further electrorefining

Aug 1, 1995