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By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016

By A. de Ville d’Avray, G. Guezennec, P. Wavrer, E. Braak

The aim of the European CEReS project was to develop an innovative copper recycling route based on the coprocessing of coal production waste by bioleaching and printed circuit boards (PCBs) from Wastes of Electrical and Electronic Equipment (WEEE). Coal waste is processed by bioleaching in stirred tank reactors, and the resulting bio-lixiviant solution is used to extract copper from PCBs pre-treated by catalytic cracking. Copper is then extracted using solvent extraction, stripping and electrowinning. The whole process flowsheet combines thermal, biotechnological, physical and hydrometallurgical operations. Once the process concept has been validated at laboratory scale, a simulator of the whole process has been built in the USIM PAC software platform. The tool enables to improve the analysis of the results of the lab-scale experiments and to design industrial-scale scenarios by simulation. The results of such simulations allow to estimate the economical interest and to perform environmental impact assessment. After presentation of the CEReS project objectives and main results, the paper describes the methodology used to build the simulator and define the scenarios corresponding to feasible process routes. The main results of the simulations are then presented with technical, economic and environmental point of views. INTRODUCTION Because of rapid technological innovations in the electronics industry, electronic waste represents the fastest growing waste stream in the world, especially in developing countries (Işildar et al., 2018). Meanwhile, the global copper demand is expected to go on rising in the future. As significant amounts of copper are present in end-of-life printed circuit boards (PCBs), it becomes a necessity to develop efficient copper recycling routes. Metal refining from e-waste is traditionally performed by pyrometallurgical processes. However, the hydrometallurgical processing of PCBs, which has been shown to be technically feasible at laboratory scale with a wide range of leaching reagents, could be a less energy intensive and more flexible alternative (Tuncuk et al., 2012). However, a large amount of leaching reagent is required to leach the metals from PCBs.

Jan 1, 2019

By Feng Tianran, Lu Shijie, Shen Zhengchang, Han Zhibin, Tan Ming

"As a kind of non-metallic material, high-purify quartz sand has been widely used in many fields. Flotation is a popular way to process quartz sand. But it is in difficult position for flotation to get high-purify quartz product due to large amount of coarse particles contained in the feed. In this paper, a design principle of special flotation cell for high-purify quartz sand has been put forward base on ore property analysis and laboratory test, and the pilot scale special flotation cell has been developed to meet the requirement of the quartz sand flotation process. The special flotation cell for high-purify quartz sand is featured by middle positioned impeller, false bottom and draft tube, which could decrease the rising distance of mineralized bubble and strengthen the circulation capacity of the lower part of the flotation cell. Hydrodynamic study indicates that high air dispersion degree and strong lower slurry circulation could be produced by pilot scale special flotation cell, which is helpful to create a suitable hydrodynamic environment for quartz sand processing.INTRODUCTIONNatural quartz is a non-metallic mineral, which is widely used as raw material in multiple industry process (Shifu, 2006). High purity quartz, especially containing more than 99.9% silicon dioxide, is characterized by high temperature resistance, small thermal expansion coefficient, highly insulating and so on. The demand of high purity quartz has been rising along with social and economic development, now high purity quartz is widely used in the field of photovoltaic industry, electronic information, communications and aerospace industry.Quartz is a kind of main rocking-forming minerals in the nature. There are seven genetic types, such as natural crystal, quartz sandstone, quartzite, vein quartz, konilite, natural siliceous sand, granite quartz (Baolei, Shuilin, & Dianchao, 2012). The natural crystal is primarily used as raw material to refine high purity quartz, but it is not available for two reasons. On the one hand, the natural crystal is extremely expensive and poor in resources reserves, which can not satisfy the need of large-scale industrial production. On the other hand, the chemical component of natural crystal is instability, it may lead to low stable product performance in large industrial applications, and it is also difficult to achieve raw materials standardization. Therefore, there are a lot of studies to search for other technological methods to obtain high purity quartz from other genetic quartz types."

Jan 1, 2016

By J. Karonen, M. Tiihonen, J. Guentner, L. Haavanlammi, Outotec GmbH, E. Kolehmainen

"Rare earth elements have obtained significant attention during the last few years due to predicted increase in their demand. Several projects worldwide are at pre-feasibility or feasibility stage aiming to commence production. Deposits of rare earth elements are typically complex and multi-metallic of nature. This means that production processes are often also complex and therefore, various metallurgical unit processes are needed. Outotec’s equipment and technology portfolio is very comprehensive and includes hydrometallurgical and pyrometallurgical apparatus and processes applicable to the efficient exploitation of rare earth deposits. Outotec has gained useful experience relevant to the processing of rare earths through several assignments including those for Alkane Resources Ltd. (Dubbo Zirconia Project), Greenland Minerals and Energy Ltd (Kvanefjeld Project), Frontier Rare Earths Limited (Zandkopsdrift project), Tantalus Rare Earths AG (Madagascar), Quest Rare Metals (Strange Lake project) and Orbite Aluminae Inc. (HPA project). The hydrometallurgical test work of two process flowsheets is presented in the paper. A roasting or acid baking step is common to several proposed rare earth projects. In the past, rotary kilns have been used, but Outotec has developed a new process concept to handle the rare earth material in fluid bed reactors. The basis for this development is long experience in fluid bed technology of Outotec in Germany. One advantage of fluid bed roasting is the higher throughput per unit. In combination with the roasting and baking, Outotec offers the gas cleaning and acid plant and provides a complete and closed concept.INTRODUCTIONRecovery of rare earth elements (REE) has obtained significant attention during recent years. It has been estimated that their demand will be boosted because of their need in many technology areas. REE can be utilized in magnets, batteries, displays, catalysts, optical devices etc. (Jordens, Cheng, & Waters, 2013; Zhang & Edwards, 2013). The production of REE is focused in China, which means that production outside of China is very scarce. However, there are multiple active development projects worldwide working towards production of REE containing products outside of China (Chen, 2011)."

Jan 1, 2016

By R. Esteban, D. Runnels, S. Girgin, J. Torrealba-Vargas

"Each mineral processing project requires early testwork to evaluate the economic potential of a deposit. The testwork needs to be efficient and it should provide enough information to obtain key parameters, first for a high level flowsheet selection at the conceptual and PEA stages and then, for later stages, to confirm the flowsheet selection and optimize the metallurgical efficiency of the plant. The testwork should consider all rock types or lithologies present, and carry out testwork for the purpose of sizing the major processing equipment.A successful project requires that the project stakeholders develop an efficient sample collection program to produce enough material for a scoping and pre-feasibility level program. This involves the participation of a team of geologists, mining and metallurgical engineers in the project, as early as possible, to define the deposit characteristics that need to be validated.The project schedule requires a close control of the testwork scope, procedures, and timing, but also the efficient analysis of results to provide indications of red flags that could impact circuit design as early as possible.In some cases, projects are put on hold due to fluctuations of the world economy until the return of more favorable conditions. In that scenario, prior data analysis of former testwork results could reduce significantly the amount of testwork required to restart a project. The paper will also present examples where the analysis of former testwork data was used to reduce the amount of new testwork in addition to presenting examples of latest projects where the above-mentioned test program approach was followed."

Jan 1, 2016

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015

By Q. B. Li, B. Gonçalves da Silva, J. T. Germaine, H. H. Einstein, Z. Moradian

"Shale gas and oil production has grown rapidly in recent years, and consequently there are increasing demands to understand the mechanical and microseismic properties of shale. Acoustic emission (AE) monitoring provides useful information on the fracture mechanisms of shale rocks, and provides a basis for interpreting field seismic observations. While there have been attempts for microseismic monitoring of conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted to understand the characteristics of the AE waveforms propagated through Opalinus shale rock in the time and frequency domains. Frequency range, arrival time, first arrival amplitude and other parameters such as counts, duration and energy of the waves generated from artificial and natural sources in the shale specimens were detected and compared with AE characteristics of granite, a brittle rock that has been extensively investigated. The experimental tests showed that there are some important factors that influence the analyses and interpretations of seismic surveys and microseismic monitoring of shale compared to granite. One of these factors is the anisotropic behavior of shale that causes the wave to propagate with different velocities in different directions. Also bedding planes and micro-discontinuities in the shale cause attenuation of the waves. Thus the AE waveforms that arrive at the sensor are a distorted and attenuated versions of the source waveform.INTRODUCTIONMonitoring microseismic activity from hydraulic fracturing of shale provides vital information for mapping injection paths and fluid migration in order to check the effectiveness of the hydraulic fracture stimulation. Analysis of microseismic source locations can be used to identify fracture networks induced or mobilized during the hydraulic fracturing operation (Rotherd and Shapiro, 2003). On the other hand, by monitoring and assessing detected signals from hydraulic fracturing one can evaluate the induced seismic impact of the stimulation operation.While there have been attempts to monitor microseismic events in conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted on Opalinus shale to understand its acoustic emission (AE) characteristics in the time and frequency domains."

Jan 1, 2015

By Jan Rosenkranz, Anders Sand, Lisa Malm, Nils-Johan Bolin

Within flotation technology the general trend is towards very large cells. Scale-up is usually done by postulating geometrical similarity, which implies keeping the aspect ratio constant when increasing cell volume. Consequently, the design of flotation circuits typically involves several cells of identical geometry within a bank. Using a few standard sizes in a flotation plant simplifies design, manufacturing and maintenance of the cells, but does not necessarily guarantee optimal performance and selectivity of the flotation process. Geometry parameters for a given cell volume that influence flotation cell performance include cell height, which causes changes in the hydrostatic pressure and suspension hydrodynamics, and also influences the travel distance of particle-bubble agglomerates as well as the homogeneity of the mixing. Also the thickness of the froth layer depends on the aspect ratio of the cell. The objective of this work is to gain a better understanding of material distribution and properties within a flotation cell and, based on this information, elucidate how alterations of the cell geometry can influence separation efficiency. For this purpose systematic measurements and analyses of the spatial distribution of the different phases within a 160 m3 flotation cell have been carried out with a particular focus on an industrial, low-grade copper ore beneficiation process. The concepts for sampling at different vertical and lateral positions of the flotation cell are introduced. The results from the experimental work give an understanding of internal material distribution within flotation cells. Based on the measured phase distribution and concentrations as well as particle properties at various positions within the cell, the implications for an optimized scaling and design of individual flotation cells within a flotation circuit are discussed.

Jan 1, 2016

By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By Liangtian Liu, Tie Ou, Guangqiang Li, Chenghuan Yu

For stabilizing the production of containing nitrogen steels, a study on nitrogen absorption behavior of killed molten steel has been carried out by means of the RH vacuum device in which nitrogen was used as a driving gas. The results showed that there was an increase of nitrogen content in molten steel under vacuum processing but the rate of nitrogen absorption was slowed down by the surface active elements. Therefore, a kinetic equation for nitrogen absorption of molten steel with apparent first order reaction was derived by constructing a modified model in which the adsorption of closed surface site was taken into account. The experimental results confiimed that the calculated values agreed with the observed ones. This model is suitable for the prediction of nitrogen adsorption operation for containing nitrogen steels.

Jan 1, 2004

By V. G. Minenko, A. L. Samusev

For efficient leaching of gold from sulfide ores and the oxidation of sulfides into sulfates, it is necessary to introduce a substantial amount of oxidant - atomic oxygen, hydrogen peroxide, ozone, potassium or sodium hypochlorite. In this paper, hypochlorite electrochemical treatment is proposed as an effective method of intensification of refractory ore leaching. The objective of the study is to increase the gold recovery from refractory ores with the application of chlorinated solutions that are modified by chemical or electrochemical treatment. The advantages of the use of the modified chlorinated solutions instead of cyanide for gold-sulfide leaching are considered to be the following: a high concentration of the oxidizing agent (hypochlorite ions) in solution helps to achieve a high speed of gold dissolution in the form of chloride complexes; the possibility to produce hydrochloric acid solutions that may be used for the recovering gold by electrolysis; the possibility of the processing of carbonaceous, arsenic-bearing and others kinds of refractory gold ores. The mechanism of the interaction of the modified chlorine solutions with gold-bearing sulfides (pyrite and arsenopyrite) was investigated. The efficiency of the application of chemical and electrochemical leaching method was proved. The main factor that limits the rate of gold dissolution is a high concentration of sulfate ions (SO4 2-) formed in the solution by the oxidation of sulfide minerals. The optimal parameters of chemical and electrochemical leaching method and effective ways to remove sulfate ions were determined. The method helps to increase the level of the gold recovery up to 87% from refractory ores. The intensification of leaching by chemical and electrochemical treatment opens up opportunities for the creation of modern efficient and environmentally-friendly technologies that may be applied for gold extraction from refractory gold ores.

Jan 1, 2016

By A. J. Williams

"Whenever a decision is made to bring a mineral deposit into production, the Owner in actual fact has decided to convert substantial sums of capital into productive capacity with the intenti6n of making a profit from such conversion.Escalating costs of construction, frustrating and costly delays in comp1etion, the increasing tempo of technological change and the increasing size and complexity of mineral processing projects have convinced Owners that the best way of implementing their capital must be sought and utilized. This requirement has stimulated a search for ways and means of applying modern management techniques to the design and construction of mineral processing plants.This search by consulting firms has resulted in the evolution of the concept of project management and the development of planning and con trolling techniques with the result that Owners can seek and obtain better assurance that their project objectives will be fulfilled.This paper will attempt to outline how a mineral processing plant can be brought into production through the implementation of project management techniques.Definition And Objectives Of Project ManagementThe design and construction of mineral processing plants is subject to the restraints of three inter-related parameters -Quality, Cost and Time each of which influences and is influenced by the other two.Project management is a technique where the Owner delegates complete responsibility to a single organization for all phases of a project (design, procurement, construction and commissioning) for the above parameters but retains freedom for major decision making. Normally, the consultant under-takes full responsibility for all phases, but partial project management services can be provided when the Owner so desires.The objective of project management is first to devise and define and then to implement a program in which the relationship between the three parameters of Quality, Cost and Time is optimized, i.e., the desired functional and other requirements are attained (but not exceeded) at the lowest practicable overall cost in the shortest practicable time. The measure of success of a project lies in the degree to which this objective is achieved."

Jan 1, 1974

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By J. Suarez

The innovation initiatives for world-class mines today and in the future focus on automation and robotics in equipment and machinery. These innovations have benefited from the development of advanced tools in global positioning, the Internet, the capabilities of data storage, transmission and handling, and intelligent systems. Forward-thinking companies have been investing in automated trains and trucks, selfdrilling rigs, intelligent flotation systems, etc. Considering that the emphasis has been mostly laid on improving the performance and reliability of the equipment and machinery, it is not surprising that the visibility was geared toward mechanical, electrical, process, and metallurgical engineering. One of the critical disciplines, mining engineering, has had less shine from the spotlight of automation and robotics. Mining engineering is concerned with the design, the operation, the management, and the reclamation of mines and mining facilities. In essence, it does benefit from the advantages of automation and robotics in equipment and machinery. However, being ?left out? in the innovation process may impede the core capabilities of this engineering discipline, which would create a two-tier knowledge and technology system in mines. For example, shovels in an open pit may be equipped with technology that can send real-time data of actual payload, number of buckets, mechanical status, etc. But, are mining engineers aware of the possibility to incorporate the data into their planning tools in order to have updated forecasts and accurate information? And if they are, are they equipped with the tools to reap the rewards of those technologies? And if so, is the personnel trained to use the tools efficiently? This paper is a contribution to the discussion on the technological advances in mining engineering. For the authors, the roadmap to the future requires a smart integration of technological advances in hardware and software so that mining engineers are not only aware of the possibilities, but also trained and capable of using the available tools. Essentially, this paper believes that automation and robotics in equipment alone will be undervalued and underutilized if the owners and drivers of the mining systems (i.e. the mining engineers) do not possess the tools and training to integrate the technological advances into the functions of mining engineering. The intent of the paper is to analyze the available technologies for the core mining engineering functions of design, planning, scheduling and optimization. The analysis will lead to discussions and suggested solutions on integrative technology solutions that would create optimum value for the mining processes and equipment technologies.

Aug 1, 2013

By H. Ikeman

"The highly specialized communication systems used in the mining industry place exacting demands on equipment and transmission media. Safely and reliability of services are perhaps the two most important factors. Fibre optics is ideally suited 10 meet these stringent requirements. Aside from being an intrinsically safe, non-sparking and EMI/RFI immune medium , fibre optics offers greater reliability , higher quality of services and superior flexibility over conventional copper or radio-based communication systems.This paper wilt show how fibre optics can be applied in mining industry applications. Emerging trends and concepts will be presented to show how fibre-optic-based integrated service communication networks and local distribution systems can be implemented.IntroductionCommunication requirements in today's mine s are varied and extensive. The communication system must be rugged , safe and reliable, yet provide an ever increasing amount of high quality services. Presently, these systems are implemented using conventional copper cable. As mining method s and technology advance and the demand for better and more communication services increases, traditional systems quickly reach their limitations. It is under these circumstances that we turn to fibre optic communication systems.Fibre optics is a mature technology which is finding its way into more and more applications worldwide. A fibre optic communication system can provide a level of performance unattainable by conventional cable systems yet ca n be cost competitive. As is well known, fibre optics provides a noise-free, noise-immune, high -capacity communications channel. Glass fibre, being dielectric and non-sparking, is an intrinsically safe communications medium. Clearly, it is ideally suited to the harsh environment present in a mine.From a communication systems point-of-view, the topology of a deep mine is unique. The objective of the systems engineer is to implement a total communications capability throughout this wide spread area. Ideally all classes of services should be accessible throughout the network-an integrated network concept. Recent advances in communications technology combined with fibre optics make this realizable."

Jan 1, 1984

By Klau Meyer

"At Teck-Corona Operating Corporation's David Bell Mine, a successful water quality management strategy has been established. This resulted from the development and application of process technology, allowing year round discharge of an effluent exceeding the chemical and biological standards set by the Ministry of Environment. This strategy aims at minimizing contaminant levels of effluents through optimization of reagent selection and reduction of effluent volumes through maximizing reclaim water usage. Concentrator and effluent treatment plant operating practices, process chemistry and the results of the water quality management strategy are reviewed.IntroductionThe David Bell Mine is located in the Hemlo gold camp 42 km east of Marathon, Ontario. The concentrator has a design throughput of 1000 tonnes per day. The processing of the run of mine ore ( - 15cm) involves the following unit operations: grinding in a semi-autogenous mill followed by a ball mill, thickening, pre-oxidation , cyanidation, and carbon-in-pulp gold recovery followed by electrowinning and refining.The David Bell Mine water quality management strategy is composed of the following items (Goodfellow and Meyer, 1991):• natural destruction of cyanide contained in the tailing water in a large shallow tailing pond ;• preliminary treatment of reclaim water in the grinding circuit for cyanide and heavy metal removal;• pre-oxidation of sulphide minerals in pipe reactors to reduce cyanide consumption using pure oxygen;• pH control in the grinding, pre-aeration and leach circuits to minimize the dissolution of stibnite while maximizing gold recovery; • close control of cyanide addition rates to the leach circuit to maintain the lowest possible levels;• a carbon column for gold recovery;• an effluent treatment plant for antimony and heavy metal removal; and• the use of final treated effluent for industrial water underground to minimize fresh water consumption."

Jan 1, 1992

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By James Ransford Dankwah

High sulphur carbonaceous materials like petroleum coke and rubber tyre are unsuitable as reductants in ironmaking because part of the sulphur is transferred to the reduced metal. Globally, while large amounts of petroleum coke are produced annually from the industrial processing of crude oil, billions of end-of-life rubber tyres are held in landfills and stockpiles. This work therefore investigates the potential feasibility of utilising these high sulphur carbonaceous materials as reductants in ironmaking without transferring the sulphur into the reduced metal. Composite pellets of iron oxide containing end-of-life rubber tyre (RT), petroleum coke and blends of RT/petroleum coke and petroleum coke/high density polyethylene (HDPE) were heated under argon atmosphere in a horizontal tube furnace. Reduced pellets were analysed after 10 minutes of reduction for their sulphur content. The results showed that sulphur-free metallic iron can be successfully synthesized using RT and petroleum coke as reductants. The level of desulphurisation depends on the nature of blending of the carbonaceous materials.

Jan 1, 2014

By Marty Hudyma

Mining-induced seismicity and rockbursting is one of the primary risks in deep mines. Seismic data management software has been created to facilitate analysis of mining-induced seismicity. The Mine Seismicity Risk Analysis Program (MS-RAP) is a purpose built database with mine seismicity analysis tools. One of the primary features of MS-RAP is the creation of seismic hazard maps in quasi-real time. The seismic hazard maps identify areas that are more prone to large seismic events and rockbursts, allowing risk management measures to be focused on the areas of greatest risk. These maps allow mining engineers to be more proactive about identifying and managing seismic related geomechanics risks in mines.

Oct 1, 2009

By B. McFadzean, J. Taguta

In order to recover minerals by flotation, the sub-processes of collector adsorption onto the valuable minerals followed by bubble-particle attachment should occur efficiently. This paper investigates both of these sub-processes for various thiol collectors and their mixtures onto base metal sulfide minerals. The aim of the work was to investigate whether there is a correlation between the strength of the collector interaction with the mineral and the subsequent bubble-particle attachment. The collector-mineral affinity was measured experimentally using an isothermal titration calorimeter in order to determine the molar enthalpy of adsorption for each collector-mineral system. The bubble-particle attachment was measured using a microflotation device which essentially determines the hydrophobicity of the mineral. Sodium ethyl xanthate (SEX) and sodium diethyl dithiocarbamate (DTC) and mixtures thereof were used as collectors with either single minerals or binary mixtures of pyrite and chalcopyrite, respectively. The adsorption enthalpies of the collectors were interpreted with reference to the chemical structure of the collector molecule and showed that the greater the positive inductive effect of the collector, which may be qualitatively related to their pKa, the greater their affinity for the mineral surface. In the microflotation studies, recoveries were strongly related to the alkyl chain length but there was no correlation between the enthalpies of adsorption and the flotation recoveries. When mixtures of collectors were used there was clear evidence of synergistic effects and in the case of DTC/xanthate mixtures it is possible that this synergism is related to a DTC promoted oxidation of xanthate to dixanthogen. When mixtures of pyrite and chalcopyrite were used the flotation recovery and enthalpy of adsorption of SEX onto the individual pyrite particles in the mixture increased substantially compared to the case of pyrite alone. Mechanisms are proposed to interpret these important observations.

Jan 1, 2016