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By Robert B. Parsons

"New Brunswick Finance Minister John Baxter pulled something out of a hat for the mining industry in April, but there is a general concensus in the industry that he should put II back where it came from.The industry has never been in the mood f or progressive rate structures, but that is exactly what New Brunswick 's 1984 budget offers to this depressed sector of the economy.IntroductionThe Province of New Brunswick stunned the Canadian mining community in April with the announcement that the province' s 16% mining tax rate would be replaced with a progressive rate structure effective January 1, 1984 (Table I). The proposed change, contained in the bud get papers tabled by Finance Minister John Baxter on April 17, caught the industry totally by surprise. The move to a progressive rate structure was completely unexpected for a variety of reasons:• Generally speaking, relations between the province and the industry have been relatively good, yet the industry was apparently not consulted with respect to the proposed measure and had no indication that a change of th is nature was coming. This is in stark contrast to the mood which prevailed during the major revamping of the province' s mining tax regime in 1977: at that time, the industry was invited to contribute in advance to the province's plan for a new tax structure.• The new structure would appear to make th e province less competitive in terms of mining tax rates with Ontario , Quebec, and other provinces, despite indications in the past that New Brunswick is very cognizant of this competitive factor in formulating mineral policy.• A joint report in November 1978 by federal and provincial officials to federal and provincial finance and resource ministers, which was careful not to directly criticize Ontario and Quebec's progressive mining tax rate structures, recommended that provincial "" tax regimes be examined to ensure the inclusion of appropriate mechanisms to avoid the excessive taxation of cyclical type profit "" , and that ""the federal and provincial governments consider the concern over progressive tax regimes expressed by the industry and examine mining and royalty tax regimes and the income tax regime with a view to alleviating the effect of such regime on the aggregate marginal tax rate"". In this context, any move to a progressive rate structure would be viewed by many observers as retrograde."

Jan 1, 1984

By Rene A. Morin, John K. Kebe

"As explosives become more widely used in urban and other congested areas, governmental regulations pertaining to their use are becoming more pervasive and stringent. This is forcing the blasting industry to review its entire spectrum of operations. Greater attention is now being paid not only to the design and layout of blasts, but also to the monitoring and recording of their after-effects for both legal and business reasons.Current PracticesThe major users of explosives in urban areas are quarry operators and construction companies. A characteristic of both of these industries, at least in recent years, is a relatively low margin of profit. This, coupled with the fact that their use of explosives is relatively intermittent, prevents them from having the kind of professional consulting services that blasting operations really warrant in today's regulatory environment. When such services are obtained, they tend to be directed more at the design and execution of the blast than at the recordkeeping function. The records that are kept tend to be more in the form of a summary of the consultant's design data as opposed to the kind of after-effect detail that is necessary.The more experienced consultants and operators now realize that at least as much attention must be paid to the record-keeping as to the design work. Regulatory bodies at all levels of government are insisting on the availability of such records.Unfortunately, the instrumentation in use today for taking such measurements does not lend itself to the practice of intermittent consulting. Current monitoring and recording instruments are based on so-called analog technology of the type that has traditionally been applied to the monitoring of earthquakes. They require set-up and calibration procedures which must be repeated each time the instrument is moved, or the blasting parameters are changed, as well as complex total analysis of the recorded data. This can lend to confusion and a dilution of responsibility for anything other than the design work and possibly some summary reporting."

Jan 1, 1985

By Yuki Soma, Tsutomu Ogawa, Jae Hyung Hong, Toshihiro Nagato

The Saganoseki flash furnace was built in 1973. The steel frames of the flash furnace were designed to absorb the expansion of refractories and contain expansion-absorbing materials between their frames and the skin plate. Expansion and deformation resulted in the furnace settler because of the repeated increase and decrease in temperature from more than 30 maintenance shutdowns. Preliminary investigations were conducted to confirm the condition of the settler, and it was found that partial cracks accompanied the expansion in the lower layer of the refractories. As a result, the risk of molten-matte leakage increased. Based on the above investigation, it was decided that the entire settler should be replaced by introducing a spring-displacement structure that was capable of maintaining the furnace integrity over an extended period. The difficult redesign and rebuilding of the Saganoseki flash furnace was accomplished successfully and safely in 76 days from September to December 2017, as planned. Because of various redesigns, the furnace was changed to a flash-smelting furnace that can withstand higher thermal loads based on recent trends of copper concentrate with increased sulfur and reduced copper. The new furnace is operating smoothly at present. INTRODUCTION The flash-smelting furnace of Pan Pacific Copper Co., Ltd. Saganoseki Smelting & Refinary commenced operation in 1973, with an original designed feeding rate of 71 t/h. As a result of facility remodeling and operational improvements, shown in Figure 1, the feeding rate was increased to 215 t/h in recent years. After more than 40 years of operation, the original settler in the melt holding section of the flash furnace underwent significant expansion and deformation.

Jan 1, 2019

By J. C. Kurnia

Methane is recognized as one of the prime causes of underground mine disasters around the globe. A cost-effective mine ventilation system and methane control is required to ensure a safe and productive environment in an underground mine whilst keeping energy usage and operating cost at minimum. Typically methane enters a mine environment or tunnel from localized distributed sources at high initial concentration. Hence, an understanding of its dispersion from discrete sources is important to design a methane management system via effective ventilation. This study employs computational fluid dynamics to model methane dispersion in an underground tunnel which has a number of discrete sources of methane and effective ways to dilute and or disperse it. Air flow distribution within the tunnel as well as methane dispersion is simulated by solving the governing transport equations subject to appropriate boundary conditions. First, the effectiveness of ventilation duct placement is examined. Several possibilities are explored and investigated. It is found that the common configuration utilized in underground mine performs best as compared to other configurations in maintaining the concentration of methane below permissible levels. Next, a novel intermittent airflow ventilation system is proposed and evaluated via simulation with the goal of reducing the energy cost whilst maintaining methane level in the mining face below the allowable level. Parametric studies are conducted to investigate effects of various factors influencing the effectiveness and performance of this novel intermittent ventilation system. This study will provide some new ideas for designing an efficient and effective underground mine ventilation system by lowering the net average amount of air that needs to be circulated in the tunnel for a safe operation. KEYWORDS

Aug 1, 2013

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Arsenic in mineral processing solutions and effluents is commonly removed and immobilized via iron(III)-arsenatecoprecipitation. The effect of re-crystallization of 2-line ferrihydrite on the long-term stability of iron(III)-arsenate coprecipitate is still not fully understood. This work investigated the redistribution of arsenic and iron during 2-line ferrihydrite transformation at different pHs and temperatures over time. X-ray diffraction (XRD), transmission electron microscopy (TEM) and chemical extraction were employed to characterize the crystallinity of the iron oxyhydroxides. Results showed that the amount of arsenic released into solution during aging increased significantly with increasing media pH.

Jan 1, 2014

By A. Khan, C. Ciriello, W. Oliveira

"The purpose of this paper is to demonstrate the value of Operational Readiness (OR) in the successful delivery of capital projects. OR can be captured using several technical and practical definitions:• To ensure that the capital project being delivered is capable of an effective start up, ramp-up as planned and a sustainable productive operation.• To function as intended when started, with the appropriate people able to run it.• To increase the value in delivering the product/service through established systems, processes and procedures, while simultaneously minimize risk to both the project and the business.Historically, mining and metallurgical capital projects concentrate efforts on cost and scheduling during the implementation and design phases. The completion and subsequent handover of the operational unit is the main objective.When reviewing the mining and metallurgical industry’s capital projects, it seems many poor results and errors in terms of project design and ramp-up are self-inflicted, with the project neglecting to account for key aspects of the future operational plant. Interestingly, if the problems for the future plant occur during project implementation, they can be prevented during the project phase. It is required to connect the operational knowledge with the project in order to ensure an effective start up and operation.The benefits of OR will be shown to be applicable not only to mining capital projects but also to sustaining and business transformation projects. The paper also includes industrial examples showing both proper and improper use of OR techniques.The paper will cover 3 main areas of Operational Readiness: the OR model, OR related risk elements (i.e., risks associated specifically with the improper execution of OR) and conclude with OR specific case studies."

Jan 1, 2016

By D. H. Wilson

"This paper examines the increasing need for mechanical-electrical people within the industry and some of the reasons why such a shortfall exists. It is suggested that, in part, it is image related. The present industry-education relationship in addressing the situation is examined and some thoughts are expressed on how these may be built on, in order to help solve the problem of attracting people to this critical area.IntroductionAs a long-time proponent of plant engineering and maintenance as a management function, I would like to review the progress made by the industry/ educational approaches in satisfying the needs in that area. In doing so, I would like to make the following points:1) that there has been an accelerating shortfall of mechanical-electrical people relative to the needs of the industry;2) that the condition will probably get worse before it gets better; ,3) that the past industry I educational approaches to alleviate the problem have met with limited success; and finally4) I would like to review some of the things being done and consider how these efforts might be extended."

Jan 1, 1981

By J. Álvarez, J. Mesías, C. O. Gómez

"Operations routinely run flotation tests in laboratory mechanical cells to determine adjustments to plant operation based on feed flotation response or the effect of new reagents and dosages. The metallurgical results of these tests are certainly affected by changes in bubble size, which simultaneously impact the recoveries of the collection and froth zones. It is known that bubble size depends on the characteristics and operation of the machine in use, particularly on the gas flow rate delivered to the unit and the selected frother type and dosage. Although flotation rate constants have been related to bubble size, bubble surface area flux seems to be a more fitting variable to correlate flotation kinetics and cell performance, as it integrates bubble size and superficial gas velocity effects. However, although some evidence has been provided, a categorical relationship between cell recovery and bubble surface area flux has not been established. Our interest is to demonstrate this relationship to use it as a basis for developing soft sensors to track on-line collection zone recovery in cells. Flotation tests were designed to produce Cu concentrates for a range of bubble surface area flux values, obtained through changes in frother concentration at a constant gas flow rate, and by increasing gas flow rate at the same frother concentration. The tests were run on samples prepared from an ore batch supplied by a local operation, following strict grinding and flotation procedures, with a shallow froth to approximate cell recovery to that in the collection zone. Bubble sizes were determined using the sampling-for-imaging technique developed at McGill. The results unequivocally showed a consistent positive correlation between cell recovery and bubble surface area flux, and significant variations in performance when frother addition and gas flow rate were changed.INTRODUCTIONMineral flotation is a separation process to produce concentrates of valuable minerals by selective attachment of particles to the surface of bubbles. The process is carried out in machines where air is injected through a mineral pulp to form bubbles, and operated to create two zones: a bottom one (collection zone) where bubbles are continuously generated under conditions adequate to form bubble-particle aggregates by collision of the rising bubbles with suspended particles; and a top one (froth zone) where bubbles and bubble-particle aggregates continue to rise while concentrating and forming a froth layer for water and entrained particles to drain back to the collection zone, before overflowing as a concentrate stream. The phenomena occurring in these zones are complex and, in many cases, interactive, as they simultaneously affect stages of the particle separation sequence occurring in both zones. Although there have been significant advances in instrumentation to characterize particle and bubble populations, these have not resulted in knowledge to explain or models to describe phenomena from fundamental principles. Measurements continue to be limited to the development of empirical models for predicting the effect of operating variables on performance."

Jan 1, 2016

By Zhongxue Li

This paper reviews an analytical model that defines the relationship of weight-weighted or volume-weighted average haulage distance with bench height and other related parameters, presents the optimum bench heights under various conditions in terms of minimizing the weighted average haulage distance of ore/waste during the full lifetime of an open pit mine, and discusses the truck haulage economics of mining open pits by high bench, specifically by 15 m, 18 m and 20 m benches through marginal analyses. The observations from these analyses disapprove the previous conflicting assertions that the over-all weighted average haulage distance either increases or decreases directly with bench height. It is concluded that: (1) an increase of bench height to 15 m from 12 m is likely to be viable under the general conditions of large-scale deep open pit mines; (2) the reduction of haulage cost is much limited with the case of increasing bench height to 18 m from 15 m; and (3) the feasibility of mining open pits by 20 m benches is generally questionable. These conclusions may serve as a useful guide for those who advocate open pit mining by high bench.

Jan 1, 1995

By George P. Demopoulos

In this paper the author will provide an overview of over 20 years of research & developments in the area of hydrometallurgical arsenic immobilization that culminated recently in the industrial implementation of the atmospheric scorodite process. The paper will consider various aspects of arsenic fixation in the non-ferrous metal industry from the iron-arsenic co-precipitation process employed to arsenic-bearing effluent solutions; to autoclave processing of arsenical copper and gold feedstocks and the fate of the in-situ formed iron sulphato-arsenate precipitate phases; the precipitation and stability of scorodite; the possible stabilizing role of mineral phases like yukonite, and the development of "scoroditeplus" processes employing novel encapsulation strategies. Emphasis is placed on the characterization and long-term stability of the various forms of arsenic-immobilized phases under either oxic or anoxic conditions over a wide pH range and the establishment of critical links between process parameters and hazardous material stability, contributing thus to advancement of new generation safe and sustainable waste management technologies.

Jan 1, 2014

By Vern Evans

Saskatchewan has historically been recognized for farming, but in 1943 while drilling for oil, potash was discovered. The initial attempt to gain access to the potash beds was unsuccessful, however, subsequent attempts were successful and today there are ten operating potash mines in Saskatchewan. In this paper we will provide a brief overview of the historical and current Potash industry in Saskatchewan.

May 1, 2011

By Jianhong Xu, Hailong Hou, Yu Jing, Yundong Wang

Microcapsules containing extractants have been applied to the extraction of metal ions, organic acid, pesticide, and herbicide. The difficulties of conventional liquid-liquid extraction in phase mixing and phase separation (e.g. high energy consumption, emulsification phenomenon, and large equipment requiring housing) could be overcome in a liquid-solid system by using microcapsules. Even some extractants with high viscosity and poison can be encapsulated conveniently into microcapsules. In the work described in this paper, polysulfone microcapsules containing 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (P507) were successfully prepared. Then, the extraction rate of lanthanum, samarium, and erbium in dilute solution into the microcapsules containing P507 was studied. An extraction kinetic model is proposed based on the interfacial reaction model accompanied by intraparticle diffusion expressed by Fick’s law. The extraction efficiency was obtained by using the kinetic model with the separately determined complex formation rate constant and the intraparticle diffusion coefficient. From the results, it was confirmed that the kinetic model could predict the experiment in a microcapsule system over a wide concentration range of lanthanide solution. In the future, the model could provide good guidance for the design and application in extraction of lanthanides.

Jan 1, 2014

By E. R. Rivenbark

"The coal handling plant represents an investment of about $100 million in coal handling and storage equipment. The coal receiving is done by a continuous ship unloader that can handle ships in the 60 000 T range at Q rate of 1750 /ph. A unique feature in the system is a stacker/reclaimer unit which will work inside a dome storage structure. The coal for the unit will include any low sulphur coal that can be delivered by sea at an economical price blended with New Brunswick high sulphur coal.ThE flue gas scrubber is a wet limestone system capable of 95% SO2 removal. The scrubber will utilize about 150 000 tonnes of limestone per year and will produce commercial grade gypsum by the forced oxidization method.IntroductionWith the need for new generating capacity being required, New Brunswick Power reviewed, in 1985, its options for the next unit. The study indicated that the most attractive option for New Brunswick Power would be a coal-fired unit capable of receiving imported coal at a sea port. The site selection process resulted in three site options being considered.The existing Coleson Cove and Dalhousie sites, and the Belledune site were considered. To meet load distribution needs, it was then decided that the unit had to be located in the northern section of the province, thus eliminating the Coleson Cove site. The Belledune site was selected because it had the capacity to have additional units added where as the Dalhousie site would have only been able to accommodate one unit"

Jan 1, 1994

By Masaharu Moteki

At present, the Unmanned Construction System (UCS) is adapted on initial operation against the disaster. For instance, it has been used in Unzen. When the scale of the disaster is big, or the danger to a person is big, the UCS is expected as a quick and safe construction technology. The Remote Controlled UCS is introduced into construction site to repair earth-fill embankment or to remove rock, as urgent measures after the disaster outbreak. For improvement of the operability, shortening of the skill time, reduction of the fatigue, examination of the most suitable system (placement of a monitor and the joy stick) of the remote system is a main theme in the Public Works Research Institute (PWRI). In the report of this year, when the operator controls construction machine directly or he controls it using remote system (he can check the situation of site only via monitor), the degree of achievement, construction efficiency and construction precision were inspected. The remote system which is based on the system used at Unzen was developed at PWRI.

Aug 1, 2013

By H. Somekawa

The fracture toughness and deformation structures an AZ31 magnesium alloy processed by equal-channel-angular extrusion (ECAE) were investigated. The average grain sizes of as-ECAE and annealed-ECAE alloys were 4.0 and 16.3 µm, respectively. The plane-strain fracture toughness, Kip, in as-ECAE and annealed-ECAE were estimated to be 27.3 and 23.5 MPam1/2, respectively, by stretched zone analysis. The fracture toughness indicated higher value with grain refinement. From optical microstructural observations in samples after fracture toughness tests, although deformation twins were observed in annealed-ECAE, no deformation twins were observed in as-ECAE. From TEM observations, the dislocations on basal and non-basal planes were activated in as-ECAE. With grain refinement, the activations of dislocations on both basal and non-basal planes were possibly related to the reduction in formation of deformation twins in as-ECAE. In addition, in comparison with direct extruded process, ECAE process was more effective method to improve the fracture toughness in magnesium alloys.

Jan 1, 2006

By A. J. Neale, B. C. Flintoff

"A review of the dynamic rod mill-ball mill grinding circuit simulator developed at the University of Alberta, highlighting the modular structure and open-ended design, demonstrates the ease with which classical feedback control strategies can be designed and implemented. Various open loop simulations are presented to demonstrate the highly interactive nature of the grinding circuit and to indicate where potential control problems may be encountered. Closed loop simulations are examined, beginning with the basic SISO classical feedback control of circuit product size. Further improvement in the grinding circuit performance in the presence of various disturbances is realized through the application of a classical MIMO feedback controller. As an example of advanced (multivariable) control, static decoupling is implemented and shown to provide additional improvement in overall circuit performance.INTRODUCTIONIt has long been recognized in the processing industries that a dynamic process simulator is an indispensable tool in the design and evaluation of automatic control schemes. In mineral processing the lack of these simulators is felt to have been a major hindrance to the widespread implementation of effective process control systems. In particular dynamic simulation is a necessary precursor to any study of modern (as opposed to classical) process control methods. This paper discusses the development of a dynamic simulator that can be used to study various feedback control strategies. The simulation software provides a powerful educational tool for those individuals interested in grinding circuit control."

Jan 1, 1988

By R. De Ruiter

"In times when mines are emphasizing cost reductions, a properly rebuilt shall conveyance can be more cost-effective than building a new unit. Awareness of the safety aspects of conveyance design along with proper maintenance playa large part in reducing operating costs. A knowledgeable operator can maintain a high level of safety and significantly lengthen the service life of a conveyance. Such an operator is also in a better position to determine when a major overhaul is necessary.After the decision has been made to rebuild, operators must decide who will do the overhaul. Whether the work is to be done in-house or contracted out, the goal is to achieve a conveyance recertified to ""as new"" condition. By dealing with conveyance rebuilds as an engineered product, operators can be certain they are getting a top quality product for their money.This paper deals with the engineering aspects of conveyance rebuilds. Actual examples of typical problems are discussed and corrective action outlined. Design considerations such as proper material selection, component fatigue due to cyclic loading, effects of stress concentrations and corrosion are all part of the initial design considerations that must carryover into the rebuild process. All too often equipment overhauls are done by people who are not experienced in conveyance design.As a manufacturer of mining equipment, Wabi has gained expertise over the past 70 years. By sharing this knowledge the company hopes to create a safer work environment and help to reduce operating costs."

Jan 1, 1994

By D. E. Gill, A. Piche, S. Dufresne

"SOMMAIREUne méthodologie de prévision des coûuts de forage en galeries est proposée. Cette méthodologie a été élaborée pour les perforatrices pneumatiques manuelles. Elle est composée de quatre modèles: (1) un modèle de pénétration conduisant à la prévision du temps de forage; (2) un modèle d'estimation de la durée de vie des fournitures; (3) un modèle d'estimation de fa quantité d'énergie consommée; et (4) un modèle de calcul de couts. Elle fait intervenir la résistance en compression uniaxiale de la roche du massif foré, le diamètre des trous, Ie type de perforatrice utilise, fa pression d'air d'opération, la longueur des fleurets, les temps morts associes au forage ainsi que le rendement des compresseurs, des perforatrices et du réseau de distribution de l’air comprime. L 'application de la méthodologie est illustrée à l’'aide d'un exemple, suivi d'une courte analyse de sensibilité et d'une brève discussion. ABSTRACTA drilling cost estimation methodology for underground headings is described. This methodology has been developed for percussive hand-held drills. It comprises four models: (1) a drillability model used for the prediction of the drilling period; (2) a model for the prediction of bit and rod lives; (3) an energy model; and (4) a cost model. It makes use of the uniaxial compressive strength ofthe rock drilled, hole diameter, drill type used, operating air pressure, drilling rod length, dead times that may occur during the drilling operation as well as compressor, air distribution network and drilling machine efficiencies. The application of the methodology is illustrated with an example, followed by a short sensitivity analysis and brief discussion."

Jan 1, 1994

By W. Blum

Progress made in improving the creep resistance of Mg alloys is reviewed with the emphasis on microstructural interpretation. Experimental results on the increase of creep strain with time at constant stress a measured for limited times and strains are displayed in a transparent form as creep rate-strain diagrams from which the minimum creep rate stress is safely derived. In addition, data on the thermal stress component a derived from high-precision a-reduction tests are reported. Within a simple statistical dislocation model these data allow one to quantify the relation between dislocation velocity v and a . In combination with structure evolution laws this relation serves as a basis for modeling the creep rate. New alloys have distinctly higher creep resistance than AZ91 where precipitation hardening plays a minor role. This is due to hardening by intermetallic phases which may form a continuous skeleton along the grain boundaries (e.g. Ca-alloyed AZ91) and/or submicron-sized precipitates within the grains (MRI230D, Mg-Zn-Ca alloys).

Jan 1, 2006

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016