Search Documents

By H. Paudyal, K. Ohto, H. Kawakita, S. Alam, B. Pangeni

The orange waste after lime water modification was converted into promising adsorbents for fluoride by metal loading reaction. The effectiveness and mechanism of fluoride adsorption on metal loaded orange waste gel from synthetic and real plating solution were investigated. Amount of zirconium(IV), aluminium(III), cerium(III), lanthanum(III), titanium(IV), vanadium(IV) and tin(IV) loaded on orange waste from aquearegia dissolution were evaluated to be 1.62, 1.16, 0.93, 0.95, 1.20, 1.12, 0.97 mmol/g respectively. The maximum adsorption capacity (qmax) of zirconium(IV), cerium(III), lanthanum(III), iron(III) and aluminium(III) loaded orange waste for fluoride ions were evaluated to be 1.74, 0.91, 1.07, 0.98 and 1.01 mmol/g from aqueous solution. The mechanism of fluoride adsorption by metal loaded orange waste was inferred to be ligand exchange reaction. Application of zirconium(IV) loaded saponified orange juice residue(SOJR) for real plating solution showed effective removal of trace concentration of fluoride down to the accepted standard. The negligible interference of co existing anions like nitrate, carbonate, sulphate and chloride makes zirconium(IV) loaded SOJR a promising sorbent for waste water treatment. The adsorbed fluoride from fluoride loaded zirconium(IV)-SOJR was effectively desorbed by using alkali solution for its regeneration. This work shed light on the potential application of metal loaded SOJR to remediate fluoride contaminated water for environmental relevance.

Jan 1, 2012

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from both primary and secondary sources having various compositions. Vanadium pentoxide and vanadium trioxide are the most available and known sources of vanadium oxides. In this paper, an overview of leaching both oxides has been reported. The problem of vanadium pentoxide leaching under acid conditions is the low solubility of the dissolved vanadium. This was investigated and then supplemented with further studies of leaching at mildly basic pH’s as well as under acid reductive leaching conditions (to form vanadium (IV)). Atmospheric oxidative leaching of vanadium trioxide was investigated using oxygen and ferric ion as the oxidant. It was shown that the leaching of vanadium trioxide using oxygen is very slow; however, ferric ion can dramatically increase the kinetics and leach efficiency.

Jan 1, 2014

By \/eena Sahajwalla, Alexander Blagus

This paper reports the effect of using High Density Poly-Ethylene (HDPE)/coke blends on the reduction behaviour of Mn3O4 to MnO at 1000°C. The results suggest that CH4 release increases with increasing HDPE addition. The results show that the rapid release of methane, over only the initial five minutes, limited the interaction of Mn3O4/MnO with CH4. With the devolatilisation of HDPE there was increased porosity in samples containing HDPE, assumed to be the major factor in differences of reduction rates.

Jan 1, 2011

By Afshin Sadri, Wai Lai Ying, Brycklin Wilson, Zoe Coull

"Although there have been great steps forward to integrate corrosion engineering into operations, there is still an underlying tendency for maintenance tasks to be performed in a reactive manner. This is especially true when strategies focus on lagging indicators such as visual inspections, RCA (root-cause analysis), and FMECA (failure mode, effects and criticality analysis). This trend to “reactive maintenance” can be avoided by utilizing more inspection and monitoring methods to identify leading indicators of failures. Prevention is generally less costly than repairs; moreover, when paired with appropriate monitoring techniques, intervention of corrosion protection can be more effectively timed and based on more accurate data. Hatch asset reliability studies show nearly 80% of defects are introduced through operations and maintenance. Therefore, proactive corrosion management can provide the necessary feedback to optimize operations and maintenance strategies preventing costly corrosion losses. Understanding corrosion risks gives a clear picture of the benefits of a proactive approach to asset performance. Monitoring techniques (Non-Destructive Testing, field testing, sampling, etc.) by nature are a more effective means of improving maintenance efforts and preventing corrosion losses than other methods (RCA, FMECA). This paper will outline the importance of proactive corrosion management and demonstrate its benefits through industry examples.INTRODUCTION Over the past few decades, with the growth of technology and awareness of sustainable development many studies have shown the benefits of a proactive approach to maintenance strategies. However, in practice there is still an underlying tendency for maintenance tasks to be performed in a “reactive manner”. This is especially true when strategies focus on lagging indicators such as visual inspections, RCA (root-cause analysis), and FMECA (failure mode, effects and criticality analysis). This trend to “reactive maintenance” can be avoided by utilizing more inspection and monitoring methods to identify defects and leading indicators to failures."

Jan 1, 2017

By Getu F. Biftu

There is general agreement among scientists that global surface temperatures have been increasing during the past decades. The increase in temperature is postulated to be the result of either an increase in greenhouse gases emission or climate variability (i.e., due to variations in sun or volcanic activity or El Nino and La Nina events) during past decades and may continue to increase. The effects of a predicted rise in the Earth?s surface temperature include an increase in average global evaporation and increase or decrease in precipitation (Bloomfield, 1992; Mann et al., 1991; Vinnikov et al., 1990; Gan 1995; Zhang et al., 2000a). The general circulation models (GCMs) project a global warming due to greenhouse effects of 1.5-4.5°C by the mid 2050s, with the most pronounced changes taking place in northern latitudes (Nicholls et al., 1996). However, similar predictions at a watershed scale or even a regional scale using GCMs are mot possible yet (Arnell et. al., 1996; Georgievskii et. al., 1996; Zhang et al., 2000a). Detection of historic trends, changes and variability in climatic variables is another indirect means of understanding potential future changes or variability at regional and local scales. The main objective of this paper is to review studies related to climatic change or variability and associated hydrologic changes at a regional scale and local scale, particularly those studies applicable to the Oil Sands Region (OSR) of Alberta. This paper identifies gaps in our current understanding of the hydrologic processes that may be affected by climate change; it discusses potential implications to developments in the OSR; and it explores mitigation opportunities including several that have already been implemented.

May 1, 2004

By G. W. Poling

"Construction, equipping and planned operation of a new laboratory for engineering-teaching and research in coal and mineral processing is described. This facility will provide approximately 1860 m2 (20,000 ft. 2 ) of laboratory space with nearly half devoted to a new venture in coal preparation. Two high-bay, overhead crane-accessed areas will accommodate major unit operations for each of the ""coal"" and ""mineral"" laboratories. COAL PREPARATION FACILITIES:The coal facility provides three main functional areas:(1) Sample preparation (drying, blending, crushing, screening) and sink-float washability testing.(2) Unit operations U1igh-bay, serviced by crane).(3) Analytical laboratories.(l) Sample Preparation and Sink-Float TestingBreaking or comminution of coal will be accomplished using a rolls crusher, a hammer mill, a jaw crusher, or a pulverizer. Capacity to prepare coal at rates of up to approximately 4 tph will be provided by some of these units. Large diameter (~0.5m) baths of heavy organic liquids will be available for sink-float washability tests on coal samples of several kg. Particle sizes of up to 25 mm can be tested in these baths. Smaller scale washability tests on finer samples will be accelerated by centrifuges."

Jan 1, 1980

By C. Jewell, G. H. Rupay

"67 - 2:15-3:00Regeneration of Hydrochloric Acid from Waste Pickle Liquor Using a Fluidized Bed Reactor System. G. H. RUPAY and C. JEWELL, Dominion Foundries and Steel Ltd., Hamilton, Ont.The disposal of acidic waste liquors from pickling processes has always been a problem for the steel industry. With increased awareness toward environmental control and the problems acidic wastes create, processes utilizing recovery and regeneration of the waste acids are becoming more popular. This paper describes the Keramchemie/Lurgi process for regenerating hydrochloric acid from waste pickle liquor using a fluidized bed reactor system. The process parameters are outlined, together with a brief description of the equipment. This is followed by a discussion of the operating problems and concludes with economic data."

Jan 1, 2000

"Pilot plants for pressure hydrometallurgy represent special design and project execution challenges. Over the past twenty years, Zeton has designed and fabricated a variety of world-class pressure hydrometallurgical pilot-plant facilities for the nickel industry, and this paper discusses design considerations and strategies related to such projects. Project execution methods are also discussed, and guidance is given for the selection of materials of construction and for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical pilot equipment. The paper concludes with a discussion of the need for process similarity with future commercial operations and the realities of pilot-scale equipment.INTRODUCTION The process technology developer or owner and the designer/fabricator of a new pilot-plant facility are faced with some difficult technical choices even after the decision to build a dedicated plant has been taken. A pilot-plant project is usually on the critical path of a large commercial project involving investments many multiples greater than the capital cost of the pilot plant. Schedule savings in the design, manufacture, and commissioning of the pilot plant or in a rapid completion of the experimental program can be disproportionately beneficial to the overall development project. However, inappropriate shortcuts resulting in major oversights can be disproportionately problematic. A number of considerations and suggestions for both the project execution approach and the process engineering design of pressure hydrometallurgical pilot-plant facilities are presented as a guide for potential owners and operators of new pilot-plant equipment and facilities. These suggestions are particularly applicable to the nickel industry, where the majority of our firm’s prior hydrometallurgical experience was obtained. This paper is an update to an earlier publication (Martin, 2004), offering an opportunity for a new generation of metallurgists and engineers to learn the specialist requirements of pilot- and demonstration-scale plant design, which are key functions in the development and commercialization of new processes."

Jan 1, 2017

By K. Kudo

Magnesium rods of 99.95% purity and approximately 6 mm in diameter were continuously cast at rates of between 15 and 25 mm/min by a heated mould process and their mechanical properties evaluated. It was found that rods cast at 15 and 20 mm/min consisted of a single crystal, while rods cast at a speed of 25 mm/min were multi-crystalline and showed a unidirectional structure. Although room temperature tensile ductility to fracture varied widely, it was found that with an appropriate crystal orientation, cast rods can exhibit elongation by as much as 215%.

Jan 1, 2006

By J. Ander

About fifteen years age some mines in western Canada commenced using Diesel engines, partly for development work but also for operations on quite a large scale. In the Eastern mining field, the Diesel engine made its appearance some eight years ago and has since, at quite a number of mining plants, proved to be a reliable and economical prime mover. As a result, it is today used more extensively than could have been foreseen only a few years ago, and it is reasonably safe to predict that the next few years will see the Diesel engine utilized to a still greater extent in the Canadian mining industry. It is not much more than thirty years since the first Diesel engine was put in operation. During the early years of this century, the Diesel engine took, so to say, its first faltering steps in public service. Since then it has reached a high state of perfection, and its importance has grown in a most remarkable way, until today it is used in practically every field where power is required. It is slowly but surely superceding steam for a great many purposes, as, for instance, for ship propulsion. While in 1921 only about 8 per cent of all tonnage launched was motor-driven, the proportion had grown to 38 per cent in 1927, and for 1929 it was slightly over 45 per cent. Some of the finest passenger liners afloat are Diesel-driven. In the early days, Diesel engines were built only in comparatively small units. Today engines with a capacity per unit of up to 10,000 horsepower, or even more, are being built for marine and stationary purposes.

Jan 1, 1930

By J. Aiello

"Introduction Byron Creek Collieries Limited Corbin mine is located in southeastern British Columbia approximately 180 air kilometres southwest of Calgary (Fig. I), twenty four kilometres south of Highway No. 3 via a newly constructed provincial road (Fig. 2). The development of the area began July 30, 1905, when D.C. Corbin, a prominent businessman from the northwestern U.S., and his associate E.J. Roberts first visited the site of Coal Mountain on horseback. Coal was in great demand by railways and other industrial users, so the Corbin Coal and Coke Co., after acquiring 6,000 hectares of land in the area, began to develop a mine. Mr. Roberts was responsible for the construction of the 22-kilometre rail spur, the Eastern British Columbia Railway, which joined the mine to the CPR main line at the McGillivray Loop. Rail access to the mine and its developing community, Corbin, B.C., was completed in September 1908, the same year that the first underground mine began production. The Corbin Coal and Coke Co. operated six mines on Coal Mountain (Fig. 3) and production from 1908 to 1930 inclusive totalled 2,120,800 tonnes. This production was allocated to the mines as follows:"

Jan 1, 1985

By M. L. Jeremic

The design of the long-hole sublevel mining method was originally based on the traditional assumption that the principal load was due to the weight of the overlying rock, and that the horizontal stresses are equal to one-third of the vertical stress. However, as mining progressed, the virgin lateral stress was found to be equal to or greater than the vertical stress. The virgin stress in the rock mass is not uniform throughout the folded orebody and adjacent strata. From detailed investigations, three basic patterns of virgin stress in ore panels have been inferred: uniform, bent and twisted. Stresses induced by stoping are up to three times greater than original stresses in the rock mass; they cause heavy ground conditions and make extraction of ore difficult. In the last ten years, the original mining system has been modified several times in order to destress the ground and improve the extraction of ore.

Jan 1, 1978

By Gordon W. Parsons, Ross E. Sampson

"THIS PAPER will trace the work done in bringing the Munro underground ""A"" •Orebody into production to replace the open pit, which was scheduled to be completed early in 1959. Included will be an outline of the exploration work and early planning, and of the final decisions on mining methods. Some of the more detailed work will be described and reasons will be given for the decisions made regarding development work, mine ventilation, ground support, and equipment. Brief mention will be made of open pit operations, as these have had some influence on underground development. Also, some of the main geological features of the ore occurrence will be de-scri0bed, as these had to be taken into consideration when making decisions on ore development and mining methods.LOCATION AND HISTORYhe Munro mine of Canadian Johns-Manville is in Ontario, approximately 50 miles east of Timmins and 40 miles west of the Que-bec-Ontari-0 boundary. The producing orebody is in the southwestern part of Munro township. Property controlled by the Company extends nortl1westerly about 2¥2 miles into Beatty township, on which two other interesting asbestos-bearing zones have been partially expl-0red. Active exploration work on the property was started in March, 194.9, and continued until the summer of 1950."

Jan 1, 1960

By Hämäläinen M., O. Hyvärinen, E. Jääskeläinen

HydroCopperTM is a new hydrometallurgical process for the treatment of copper sulphide concentrates, which has been developed by Outokumpu. The process includes chloride leaching of copper concentrate, solution purification and precipitation of copper(I) oxide, an intermediate product, which is reduced and cast into copper products. The reduction can be carried out by pyrometallurgical methods or hydrometallurgically in an autoclave. This paper discusses the thermodynamic and kinetic aspects of the hydrogen reduction of copper(I) oxide in an autoclave. The results of the laboratory tests are presented and discussed. Finally, the autoclave method is compared with other options.

Jan 1, 2004

AT the Annual General Meeting held in Winnipeg last March, the whole of one of the technical sessions was devoted to a special Symposium on Geological Investigations in Canada, introduced by a paper entitled The Geological Survey (lî which had been specially prepared by Dr. G. A. Young, Chief Geologist of the Survey, and had been published in the February BULLETIN, prior to the meeting. Geologists from each of the provinces contributed to the Symposium, including directing officials of the geological divisions of provincial Departments of Mines, representative geologists from the Universities, and company and consulting geologists. Space, unfortunately, does not permit publication of a complete record of the proceedings,_ or even inclusion of all contributions to the discussion. The following summary, however, gives what is believed to be a fair cross-section of the opinions expressed by representatives from each Province. The Symposium resolved itself largely into a discussion as to how the Geological Survey and the several provincial bureaus or divisions of geology could co-operate most effectively in the important task of carrying out geo-logical investigations, with avoidance of duplication of work and waste of effort, and, so far as broad principles are concerned, there was remarkably close agreement among those participating in the Symposium as to how the various types of investigation should be allocated as between the Federal and Provincial organizations. Briefly, the concensus was that the Geological Survey can render the most effective assistance by conducting reconnaissance investigations, with mapping at 4 miles to one inch, leaving to the provincial organizations the more detailed, and hence more local, studies and mapping at larger scales. There was general agreement that the preparation of base maps, essential to systematic geological investigation, is a service devolving upon the Federal Government.

Jan 1, 1940

By G. A. McGuffin

"IntroductionWITH the increase in quantity of sour gas reserves in the Province of Alberta, and the wider market for sulphur brought about by mounting world demand and restrictions placed on the principal supply, it was inevitable that this important source of sulphur would be .developed. In the light of these facts, it seems timely that a general paper on sulphur recovery from petroleum gases be presented. This, then, is the purpose of the following text. A short discussion of each of the following subjects is presented:(1) Properties and uses of sulphur(2) Existing sources(3) Market research(4) The recovery process in Turner Valley(5) Hazards of sulphur productionNo pretext of originality of material is made since innumerable reports have been prepared on this and related topics and information contained in these has been used quite liberally.Properties and uses of SulphurSulphur is a non-metallic element having an atomic weight of 32.06. The stable crystalline form at atmospheric temperature is referred to as 'rhombic' sulphur. It is bright yellow and has a specific gravity of 2.05, equivalent to 129.2 lb./cu. Ft. Above 204°F. sulphur has another stable crystalline form, referred to as 'monoclinic'. This is reddish-brown and is slightly less dense than the rhombic variety (122.4 lb./cu. Ft.). Sulphur in bulk form weighs 84 to 90 lb. per cu. Ft. Sulphur melts at approximately 240°F. to a straw coloured liquid which is quite viscous."

Jan 1, 1952

By David Ulrich Furrer

Materials and manufacturing processing technologies have played an important role in the development and capabilities of nearly all manmade products. Market drivers for fuel efficient, low cost, environmentally friendly, more capable transportation has given rise to significant materials challenges and subsequent developments. The rate of improvement and implementation of new commercial products can be limited by the rate of new materials and process technology development and qualification. As many materials are being designed for unique requirements and even location-specific unique properties, the implementation of tools and methods to enable rapid characterization and validation of material definitions and design systems must also be accelerated. A review of new integrated material, manufacturing process and component designs, engineering processes and emerging tools and methods will be discussed. The linkage of computational materials science and engineering into component design will also be discussed along with the challenges and opportunities for further growth and application of integrated computational materials engineering (ICME).

Jan 1, 2015

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

Forward-Looking Statements Information set forth in this presentation may involve forward-looking statements under applicable securities laws. Forward looking statements are statements that relate to future, not past, events. In this context, forward-looking statements often address expected future business and financial performance, and often contain words such as "anticipate", "believe", "plan", "estimate", "expect", and "intend", statements that an action or event "may", "might", "could", "should", or "will" be taken or occur, or other similar expressions. Forward-looking statements or information relate to, among other things expected iron ore demand, timing for a production decision, expected share price drivers, potential railway options, timing, grade and quantity of potential resource estimates, employment and economic benefits, taxation estimates and timing of key project milestones. By their nature, forward-looking statements involve known and unknown risks, uncertainties and other factors which may cause our actual results, performance or achievements, or other future events, to be materially different from any future results, performance or achievements expressed or implied by such forward-looking statements. Such factors include, among others, the following risks: the risks associated with the need for additional financing; operational risks associated with exploration; fluctuations in commodity prices; title matters; environmental liability claims and insurance; reliance on key personnel and other risks and uncertainties discussed in the management discussion and analysis section of our interim and most recent annual financial statement or other reports and filings with the TSX Venture Exchange and applicable Canadian securities regulations. Forward-looking statements are made based on management's beliefs, estimates and opinions on the date that statements are made and the Company undertakes no obligation to update forward-looking statements if these beliefs, estimates and opinions or other circumstances should change, except as required by law. Investors are cautioned against attributing undue certainty to forward-looking statements. NI 43-101 Qualified Person Alderon?s exploration work on the Kami Project is supervised by Edward Lyons, P.Geo., the Chief Geologist for Alderon and a Qualified Person as defined byNational Instrument 43-101. Mr. Lyons has reviewed and is responsible for the technical information contained in this presentation. Mr. Lyons is a member in good standing of the Association of Professional Engineers and Geoscientists of British Columbia (APEGBC) and the Professional Engineers & Geoscientists Newfoundland & Labrador (PEGNL) as a registered Professional Geoscientist (P.Geo.).

May 1, 2011

By Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

At the present time of depletion of reserves of high grade rare earth deposits, it has become necessary to involve low grade raw materials in the production. Among the rare-earth deposits in Kazakhstan, the most advanced one is Kundybai. The mineralogical composition of ore is represented by the minerals: a-quartz SiO2, kaolinite Al2(Si2O5)(OH)4, muscovite KAl2(AlSi3)O10(OH, F)2, albite Na(AlSi3O8), rutile TiO2, and hematite Fe2O3. It contains: 59.1–68.5% SiO2, 19.1–28.4% Al2O3, 7.2–10.3% Fe2O3, 0.51–0.84% TiO2, 0.10–2.32% CaO, 0.39–2.10% MgO, and some other elements. Rare earths are located in the clay part (kaolinite, goethite) in the ion-adsorbing form, and they are represented by the main ore mineral churchite - YPO4·2H2O. In the ore the amount of rare-earth elements (total REEs) varies from 210 to 600 ppm. Elements of the cerium group predominate (La, Nd, Ce, Sm, Pr) and the yttrium group is represented by Y, Gd and Dy. Extremely thin intergrowth and accumulation of REEs in clay minerals cause difficulties in their recovery using flotation and gravitation beneficiating methods. The purpose of this work is the development of an extraction method for the main mineral components of ore with transfer of the total REEs into the solution with high extractive efficiency. Results of the experimental work into high-temperature processing (hereinafter referred to as sulphatization) of ore by sulphuric acid with subsequent dual-mode water leaching of the sulphate product (sinter) are presented in this manuscript. The influence on the ore sulphatization process of some physical and chemical parameters: liquid-to-solid (L/S) ratio (0.36–0.86 cm3/g), temperature (100 – 500°?), concentration of sulphuric acid (3.0–18.62 mol/L) and duration (0.5–2.5 h) was studied. Optimal technological parameters of the process were determined to be: L/S ratio 0.36–0.46 cm3/g; temperature 500°?; concentration of H2SO4 9.0 mol/L; soaking time 1.5 h. Under these conditions it is possible to obtain extractions of ~ 85% REE, as well as 58% aluminium and 10% iron. XRD and IR-spectroscopy analyses were used to determine the material constitution of sulphated cakes obtained under optimal conditions. It was found that the primary minerals are quartz and muscovite; however different sodium aluminium silicates and albite minerals are present as well. In the future, it is proposed that the leach residue cakes are processed into precipitated silica (“white soot”).

Jan 1, 2016