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By Seshadri Seetharaman, Nurni N. Viswanathan, Haijuan Wang

The present work aims at some process modifications in specified metallurgical processes, wherein CO2 can be used successfully as an oxidant for decarburization in steelmaking and applied in some non-ferrous metals production processes. During the decarburization of Cr-containing high alloyed steels, the present researchers investigated the possible use of CO2 instead of Ar-O2 mixture and could successfully decarburize the steel melt without significant loss of alloyed Cr to the slag phase. A mathematical model was developed based on the bubble formation accompanying the chemical reaction: C(molten steel)+ CO2(gas)= 2 CO(gas). The model predictions were tested by laboratory scale (1 kg) experiments carried out in an induction furnace and very good agreement between the model predictions and experimental results were observed. A national project has been sanctioned in China for the implementation of CO2 in decarburization of ferroalloys as well enable the addition of pig iron in the electric arc furnace process when the scrap supply is limited. New processes have been developed for the utilization of CO2 in the case of non-ferrous processes. A novel method of treatment of Al dross by leaching with water and capturing the evolved NH3(formed by the hydrolysis of AlN) has shown very promising results.

Jan 1, 2015

By E. Howard Lambert

"Operating costs of mining plants are increasing due to the increased cost of labour, materials and fuels. Labour and materials costs are factors not readily controlled. However, the use of energy from fuels may be controlled by plant operations. This paper describes the fossil fuels, their expected rate of depletion and their costs. The paper considers methods which may be used to provide an efficient use of energy from fuels. It includes an outline of obtaining energy, as heat, from mine milling operations (air compression) and obtaining the maximum use of energy from fuels used to generate electricity."

Jan 1, 1973

By K. U. Kainer

Magnesium and its alloys as the lightest available construction metal offer a wide range of opportunities for the usage in transportation industries, especially Magnesium wrought alloys with their improved mechanical properties show a high potential for structural applications, While magnesium cast components have found their application the interest is now spreading to wrought alloys due to the possibility to get even more homogeneous and better properties compared to cast parts, Therefore alloy and process development especially for extruded and sheet material is a main concern to enhance the application of Magnesium wrought alloys, Castings are still form the majority of applications of magnesium alloys, although efforts to develop adequate wrought alloys have increased, In the presentation, the alloy requirements for processing of cast and wrought alloys will be discussed, The various processing routes and alloy compositions result in specific microstructures and properties which determine the potential use of these alloys, Today, the spectrum of available alloys covers standard alloys as well as alloys for use at elevated temperatures, The trend will be to further diversify the alloy compositions and to improve the alloy properties, Areas of concern still remain the wrought processing and the high temperature (creep) and corrosion properties of magnesium alloys, Examples of recent developments in these sectors will be given, The presentation will also provide an overview of the historical and current use of magnesium and an outlook on future applications.

Jan 1, 2006

By Roger V. Pierce

IN the last few years, much study has been devoted to increasing stoping efficiency. The reasons for this are shortage of manpower, shorter working hours, operating regulations, and shortages of essential materials. More efficiency in mining methods is needed to offset these adverse factors. In the past, attention has been centred upon haulage, hoisting equipment, mill flow-sheets, etc., but recently the spotlight has been focused on the cost of stoping and the cost of handling materials. Scrapers and scraper hoists have thus assumed greater importance. In order to make it possible for certain orebodies to be mined at a profit, it has been necessary to apply assembly-line practices to the streamlining of mining methods. All cycles of the mining operation must balance, and the sooner broken ore is removed from the working face, the sooner another round can be started. Since the introduction of scraper hoists in metal mines more than thirty years ago, much progress has been made in their design and application. Alert operators are now constantly watching for methods in which to apply scrapers. The saving of manpower in development work and the changing of mining methods that once employed manual handling of materials are increasing vital wartime tonnages. Essential ores from newly discovered orebodies are moving rapidly from stopes to reduction plants-because it is now possible to develop an orebody and place it in production with a minimum of manpower and development work. Today, speed is one of the prime essentials o mining. Everywhere, there is a concentrated effort to use experienced miners in breaking rock, in timbering, and in carrying out the various phases of mining that require many months of training. Much effort is being made to mechanize the working places because experienced men naturally prefer to work where the majority of materials are handled mechanically. In line with this policy, many new men are being taught the details of scraper work, because even green men can quickly become acquainted with scrapers and thereby release older heads to perform the more skilled phases of mining.

Jan 1, 1943

By D. E. Parson, W. A. Morgan

This paper offers a brief review of current literature pertaining to vacuum degassing or vacuum casting of steel as practiced in the U.S.A., Germany and the U.S.S.R. The advantages of vacuum degassing of large forging ingots, heavy section casting, for the conversion of rimming bessemer steels to killed steel and for the production of transformer steels are discussed. Operating pressures, reduction in gas contents and improvements in hydrogen segregation, steel cleanliness and mechanical properties, obtained with the various techniques, are described. The paper includes a description of an experimental vacuum stream-droplet degassing unit and some preliminary results obtained at the Physical Metallurgy Division Research Laboratories Department of Mines and Technical Surveys, Ottawa on laboratory steel melts. Experimental 500 lb direct arc, basic melts have been spray cast into either ingot moulds or dry sand moulds, held inside a vacuum tank. Also 500 lb melts have been

Jan 1, 1961

By J. Paturaud, A. G. Villemiane, J. Y. Buffiere, D. Fabregue, M. Perrier

In this work, a detailed characterization of the cyclic damage mechanisms on duty in car heat exchangers has been carried out in order to improve their reliability. The material which consists in very thin (<0.3 mm thick) sheets formed of 3 co-rolled aluminum alloys (4045 /3916/ 4045) has been brazed in order to obtain metallurgical and surface conditions representative of those of the real components. Fatigue tests at constant stress amplitude have been performed at room temperature and 120°C in order i) to characterize the cyclic resistance of the studied materials and ii) to study the effect of temperature on the fatigue damage mechanism. The mechanisms leading to failure have been identified from post mortem fractographic analysis. The Wohler curves obtained show that, contrary to common structural Al alloys, this type of thin sheet brazed multi material can be cycled for several hundred thousand cycles at very high stress level (> ~ 80 % of the tensile strength). This behaviour is analysed with respect to the microstructure resulting from the brazing process and the low number of grains present in the sample thickness (around 5 grains).

Jan 1, 2015

By K. Barbetti

"The carbon-in-pulp (CIP) process has been the dominant gold recovery process since the early 1980s. CIP has proven to be very adaptable for a wide range of ores and circuit configurations. The key performance indicator for CIP circuits is the minimisation of soluble gold losses to tailings, however, it is also important to operate the circuit efficiently (maximising gold loadings on carbon and minimising carbon inventory). Over the last 30 years the Curtin Gold Technology Group has studied CIP circuits as part of an on-going collaborative industry funded project (the AMIRA Gold Processing Technology Project). In the early years the project undertook basic research into understanding activated carbon, and its management in the circuit. More recently the development of process models and instrumentation has provided additional tools to assist operators. The results show that while most CIP circuits operate well, there are still significant opportunities for further cost savings, or additional revenue. This paper reviews the observations arising from this work, including key requirements for good carbon management, the results of benchmarking and industry surveys of carbon circuit over 20 years, the value of process modelling of CIP circuits to establish operating parameters, and the use of automated instrumentation to better optimise carbon control in the circuit.INTRODUCTION The introduction of activated carbon to recover gold from cyanide leach solutions in the last quarter of the 20th century was the most significant development in gold ore processing since the advent of cyanidation seventy years before. Replacing the Merrill–Crowe zinc cementation step with carbon-in-pulp (CIP) or carbon-in-leach (CIL) circuits provided a process that allowed the treatment of lower grade and problematic ores (e.g. high-clay ores), at lower capital and operating costs, and higher metal recoveries. The CIP circuit was first developed in the 1950s at the Carlton Mill, Cripple Creek, Colorado. All the components of the modern CIP process came to fruition at the Homestake Mine in South Dakota in 1973 (Fast, 1988). From the late 1970s onward a variation of CIP, carbon-in-leach (CIL) which combined the leach and adsorption stages, became the preferred circuit design in most parts of the word."

Jan 1, 2017

By J. W. Spyker, D. H. Filson, W. H. W. Husband

"Large deposits of sodium sulphate exist in southern Saskatchewan in the brines or muddy crystal beds of alkali Jakes. Currently, more than 300,000 tons per year of sodium sulphate are produced from these lakes and sold as salt cake to the paper industry. Most of the production is obtained from the brines of a limited number of Jakes.The Saskatchewan Research Council was requested to develop a process for recovering sodium sulphate from the muddy crystal beds so that this type of deposit could be exploited in the future. A flowsheet was developed with the aid of phase diagram data and the process was studied on a pilot-plant scale using raw material from three different lakes. Satisfactory yields and product purities were obtained in all cases, and an economic analysis indicated that a 100,000-ton-per-year sodium sulphate plant could produce salt cake at a cost of $12.26 per ton for a rate of return upon investment of 16 per cent at current market prices."

Jan 1, 1966

By H. C. Gunning

SOME small vanadium-bearing deposits on the west coast of British Columbia about 100 miles north of Vancouver are of interest for several reasons. They are of a type that is, so far as we know, unique. They are difficult to identify as being vanadiferous so that, unless they are described, other similar deposits could easily pass unrecognized. Furthermore, although none of them has as yet been proven to be of commercial proportions, no good reason is apparent why larger, and therefore valuable, deposits should not occur under similar geological conditions. The original discovery on Quadra island was made in 1932 and has been recorded by H. V. Ellsworth and H. C. Gunning (l). Since 1932, prospecting in the area has revealed other similar deposits, one about a mile south of the original and another some ten miles to the east, near Menzies bay on Vancouver island. The Quadra Island showings are a mile and a half north of the head of Gowland harbour, a small inlet that is easily reached by gas boat from Campbell river, about four miles to the southeast on Vancouver island. The deposits were examined by the writers in the spring of 1943 in connection with field work sponsored by the Department of Geology, University of British Columbia. We are indebted to Mr. G. A. Dirom and Mr. Lothrop, of Vancouver, for helpful data on the Menzies Bay deposits, and to Dr. V. Dolmage for making a brief trip to Gowland harbour and discussing the deposits.

Jan 1, 1944

By F. H. Edmunds

I N presenting this paper, the writer wishes to point out some of the difficulties and problems of geological work in that part of Saskatchewan in which outcrops are few. These problems are well known to all geologists who have made investigations in this region, but may not be so well known to those outside. A table of the strata as known in certain areas of Saskatchewan and the adjacent provinces is given, with a brief discussion of some of the formations and beds about which there is little knowledge due to their being deeply buried and not exposed in the region. Comment with regard to possible oil and gas structures is made and some features of the structures in the Battleford and Simpson districts are described. The writer wishes to make acknowledgment to members of the Geological Survey of Canada to whose work in Saskatchewan and the adjacent provinces reference is made, and to others who have made, or are making, valuable contributions to the stratigraphy of Saskatchewan. Mr. G. C. Webb has kindly furnished information regarding and materials taken from a well bored recently in the Paynton district. Special thanks are due to the Simpson Oil and Gas Company for permission to use much valuable information with regard to their wells and for the generous way in which the officials and staff co-operated with the writer. The opportunities the writer has had to visit many parts of the Province have been in connection with investigations for the Provincial Department of Natural Resources and through facilities provided by the Department of Soils of the University of Saskatchewan. To these Departments the writer accords his thanks. For the purposes of this discussion, Central Saskatchewan may be considered as that portion of the Province extending from Township 16, with Regina, Moose Jaw, and Swift Current situated on or near the southern boundary, to Township 48, with Prince Albert and Lloydminster on the northern boundary. This region includes territory underlain by Cretaceous sediments and excludes the southern portion of the Province, where Tertiary beds underlie the surface and are exposed to an extent sufficient to permit a measure of systematic mapping.

Jan 1, 1937

By D. K. Storer, W. Lee, S. Tkach

"A microcomputer-controlled multi-probe K-40 monitoring system was developed internally for the Phase II mill at the Lanigan potash mine. The K-40 probes were mounted in a variety of positions in several process streams, ranging from dry ore on a conveyor belt to brines and slurries. A description will be presented of the objectives, the equipment and the difficulties encountered in correlating results.IntroductionThe successful control and optimization of most metallurgical processes involves monitoring not only physical parameters such as flow rate and temperature, but also the chemical compositions of critical streams. Composition has proven difficult to measure on -line in industrial scale processes. However, in potash processing there is a convenient chemical parameter that has long been utilized to measure in situ the concentration of potassium chloride (KCl). Potassium has a long-lived isotope which is slightly radioactive. K40 decays by beta elimination to Ca40, ultimately radiating a characteristic gamma-ray photon. This gamma emission when detected by scintillation counter can be used to estimate the concentration of potassium in a process stream."

Jan 1, 1990

By R. A. May, P. J. Brooks, W. M. Smith

"Neill and Gunter Limited (NGL) has prepared a preliminary design and a cost estimate for a ferric chloride leach plant to recover copper, lead, zinc, and silver from a typical complex sulphide ore. This plant design is specifically intended to treat unconcentrated ground ore (flotation feed), but can be readily adapted to treat bulk concentrates. Samples of ground ore and bulk concentrate were obtained from Heath Steele Mines, Miramichi, New Brunswick, laboratory testing, and preliminary process flow sheet preparation was carried out by the Research and Productivity Council in Fredericton, New Brunswick. Approximately thirty drawings have been produced, including process and equipment flowsheets, process piping and instrumentation drawings, and preliminary general arrangements. Preliminary capital and operating cost estimates were prepared for a plant that would treat 1000 t/d of crushed and ground ore to produce about 30 000 tpy of zinc. Capital and operating cost estimates were also projected for plants up to 4000 t/d of processed ore. Recoveries of 99% for zinc, 98% for lead, and 96% for copper were achieved in laboratory tests on unconcentrated ore. These recoveries were higher than the overall recoveries obtained from bulk concentrate, yielding approximately 10% more revenue.A 1000 tonne per day plant was determined to have a low return on investment, however, depending on the size and type of mining operations employed and the FCL plant throughput. DCF-ROI projections of 20% to over 30% were calculated for 100% equity financed “green field” mine, mill and FCL plant operations of 2000 t/d and higher"

Jan 1, 1997

By L. Heber Cole

The search for potash in western Canada during the years of the great war led to the staking of claims on many of the "alkali lakes" and sloughs which occur in numerous localities in the morainic areas of the prairies, as well as in British Columbia, in the hope that potash salts would be found in commercial quantities. While the search for potash, up to the present time, has been disappointing, the prospecting of these areas has demonstrated that Canada possesses large reserves of sodium and magnesium compounds, principally in the form of sulphates, carbonates and chlorides. he writer first became interested in these deposits in 1911 while investigating the sodium chloride springs of northern Manitoba. In the fall of that year a number of the sulphate ? deposits in Saskatchewan and Alberta were visited, but owing to the excessive rains at that period, all the deposits were under water and only a few brine samples were obtained. Owing to pressure of other work investigations of the alkali deposits in western Canada, by the Mines Branch of the Department of Mines, could not be undertaken until the field season of 1921, but since that time the work has been continuous. During the summer of 1918 a reported discovery of a large deposit of potash bearing salts was featured in western papers and in a short time practically all the lakes and sloughs of the prairie provinces, which showed the least indication of being saline, were staked for potash. This reported discovery was not substantiated on investigation and many of those who had staked claims allowed them t~ lapse without the slightest effort to determine the character of the material in the deposits which they? had leased.

Jan 1, 1924

By J. Sadaki, G. Dodbiba, S. Murakami, T. Fujita, S. Matsuo, H. Ono, K. Okaya

Printed circuit boards (PCBs) from discarded personal computer (PC) and household appliances were crushed by mechanical crushing or water explosion to remove mounted parts. More parts were stripped from PCB for PC composed of epoxy resin than from PCB for household appliance composed of phenol resin. In an attempt to raise the copper grade of PCB by removing other components, a carbonization treatment was investigated. The crushed PCB without surface-mounted parts was carbonized under a nitrogen atmosphere at 1073K. After screening, the char was classified by size into oversized pieces, undersized pieces and powder. The copper foil and glass fiber pieces were liberated and collected in undersized fraction. The copper foil was liberated easily from glass fiber by stamping treatment. On the other hand, tantalum capacitors were collected from mounted parts. The tantalum-sintered bodies were separated from molded resins by heat treatment at 723 to 773K in air atmosphere and screening of 0.5mm. Silica was removed and 70% of tantalum grade was obtained after more than 823K heating and separation.

Jan 1, 2011

By Francis W. Gray

Introduction Extensive undersea coal-mining has developed on both the east and west coasts of Canada, and at this time some four million tons, or 25 per cent of the total output of Canadian coal, representing a pit-mouth value of $14,000,000 per annum, is coming from coal seams lying under the sea. Of the coal now being mined in Nova Scotia, 55 per cent comes from under the sea, and this proportion is likely to increase. The Province of Nova Scotia is at this date receiving in royalties paid upon coal ?removed from undersea areas a sum exceeding $400,000 per annum. The subject is, therefore, one of special interest to the Mining Society of Nova Scotia and the Canadian Institute of Mining & Metallurgy, and while this paper will deal chiefly with undersea coal-mining in Nova Scotia, an attempt has been made to summarize the development of mining practice in the winning of undersea coal in other parts of the world, with the hope that such a recital may assist in the assessment of local problems. The connection between the mining of coal under the sea and an insular or maritime geography is obvious in regard to Great Britain, Japan, Vancouver Island, Australia, and Cape Breton Island, and also in regard to the curious conformation of Chile; the tendency towards growth of a mercantile marine and naval eminence is equally obvious where coal is mined at tidewater. But, there is the further and less favourable significance that the mining of coal under the sea is associated with poverty rather than with abundance of coal reserves.

Jan 1, 1927

By A. D. Fisher

This paper describes the future position of metallurgical coal, particularly as applied to Canadian reserves. Quality coking coal is declining in availability, but preheating practices may alleviate this situation to some extent. Two new processes are discussed in the paper - formed coke and direct reduction - and their coal specifications are outlined.

Jan 1, 1972

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By Y. Nishida, Y. Nara, T. Ishida

Understanding time-dependent deformation and fracturing in rock is essential, because the information of the long-term stability of rock is required for many sub-surface structures excavated in a rock mass. Time-dependent fracture propagation has been invoked as a potential key mechanism responsible for the increase in seismicity preceding earthquake ruptures. In engineering projects and in preventing natural hazards, the study of time-dependent fracturing is necessary. Subcritical crack growth is one of the main causes of time-dependent fracturing in rock. For silicate rocks, subcritical crack growth has been investigated by various researchers. It has been clarified that surrounding environmental conditions (temperature, humidity, and existence of water) have strong influence on subcritical crack growth in silicate rocks. Therefore, the information of subcritical crack growth in silicate rocks has already been enough. On the other hand, information of subcritical crack growth in carbonate rocks is not enough. Especially, the influence of surrounding environment on subcritical crack growth in carbonate rock has not been clarified yet. In this study, we investigate subcritical crack growth in carbonate rock experimentally using a fracture mechanics testing method. Marble obtained in Skopje in Macedonia is used as a carbonate rock sample. The Double Torsion method is used to measure the crack velocity and stress intensity factor. Especially, influence of water on subcritical crack growth in Macedonian marble is investigated. It was shown that the crack velocity in water is much higher than that in air at the same temperature. Based on the results of subcritical crack growth measurements, the long-term strength is evaluated for marble. It was clarified that the long-term strength in water is lower than that in air in marble. It is concluded that water has a remarkable influence on subcritical crack growth in marble. It is also considered that the long-term stability of carbonate rock masses should be ensured in a dry environment.

Jan 1, 2015

By François Robert

"The Eastern Abitibi Sub province (Quebec segment), contains two main types of gold deposits: the common quartz-vein type and the rare pyritic type. Both occur in areas dominated by volcanic rocks and are spatially associated with major fault zones.Quartz-vein gold deposits consist of simple to complex networks of quartz-carbonate-pyrite veins in reverse shear zones and extensional fractures. They occur in areas dominated by mafic volcanic rocks and are commonly associated with small syn- to late-tectonic porphyritic felsic intrusions. Associated alteration, which postdates peak metamorphism, is dominated by carbonatization, sericitization and pyritization of the wallrocks. These deposits formed late in the geologicalevolution of the Abitibi.Pyritic gold deposits range from deformed massive sulphide lenses to zones of syntectonic pyrite-rich veinlets and associated pyrite disseminations. These deposits occur in environments dominated by felsic volcanic rocks that are typically converted to sericite schists near the deposits. The associated pre-metamorphic aluminous alteration is now characterized by metamorphic sericite, andalusite, kyanite and chloritoid, overprinted by a late retrogression of alumino- silicates. These deposits probably represent deformed volcanogenic massive sulphide deposits, but the timing of gold introduction in these is not fully understood.The differences in geological attributes reflect significant differences in the genesis these deposits: the pyritic deposits probably have a multistage genesis, including a pre-tectonic stage, in contrast to a single stage late-tectonic genesis for the quartz-vein deposits.RESUMELa partie Est de la Sous-Province de l’Abitibi( segment québécois) renferme deux types de gites d' or: ceux de type ""veine de quartz"" et ceux, plus rares, de type ""pyriteux"". Ces deux types se trouvent dans des secteurs particulièrement riches en roches volcaniques et mantrent une association spatiale avec des zones de failles majeures.Les gites de type ""veine de quartz"" correspondent à des réseaux de complexité variable de veines de quartz-carbonate-pyrite se développant dans des zones de cisaillement inverse et des fractures de tension. Ils se concentrent dans les régions dominées par des roches volcaniques mafiques et s’associent fréquemment à de petites intrusions porphyriques felsiques syn- a tardi-tectoniques. L’altération associée ace type de glte est postérieure à la phase majeure du métamorphisme et consiste en une carbonatisation, une sericitisation et une pyritisation des épontes. La mise en place de ces gites est tardive par rapport à l'évolution géologique de l'Abitibi.Les gites d' or de type pyriteux consistent en des lentilles de sulfures massifs déformes, des zones d' abondantes veinules pyrite uses syntectoniques, et des zones de pyrite disséminée. Ces gites se retrouvent dans des empilements contenant surtout des roches volcaniques felsiques qui sont transformées en schiste à séricine pres des gisements. L’altération a l’umineuse pre-metamorphique associée a ce type de glte a donné naissance, lors du metamorphisme regional, a la sericite, a 'andal ousite, a Ia lcyanite et au chloritoi""de; par la suite, les alumino-silicates ont été affectes par une alteration retrograde tardive. Ces gites representent probablement des depOts de sulfures massifs volcan gènes déformes, mais la chronologie de la mise en place de l'or dans ceux-ci est encore mal comprise.Les caractéristiques géologiques propres à chacun de ces types de gites reflètent des conditions de formation différentes: le type ""pyriteux"" montre une histoire génétique polyphasée, incluant une étape pre-tectonique alors que le type ""veine de quartz"" s’est développe au cours d’une seule phase tardi-tectonique."

Jan 1, 1990

By J. D. T. Steyl

Anglo American Corporation and the University of British Columbia have developed a medium-temperature oxygen pressure leaching process for the extraction of copper from chalcopyrite concentrates in an acid-sulphate system (AAC/UBC process). Leaching is performed at 150°C and surfactants are added to disperse molten elemental sulphur from the unreacted sulphide surface to prevent liquid sulphur occlusion. Copper extractions of over 95% and elemental sulphur yields of around 60% were observed over a 2-hour average residence time in a continuous pilot autoclave. Sporadic blockages occurring under continuous conditions were found to be caused by the accumulation of molten elemental sulphur mixed with unreacted sulphide mineral. A batch programme of experimentation was undertaken to establish the reason for this phenomenon. Batch experiments were conducted at low pulp densities on concentrate samples with narrow size distributions and at similar solution compositions to those experienced in the pilot autoclave. The overall rate of chalcopyrite oxidation was shown, under approximately constant solution composition, to be a strong function of the total available mineral surface area. Initial copper extraction rates followed the shrinking particle kinetic model under intrinsic surface control. Deviation from shrinking particle kinetics was however observed after a certain oxidation time. Secondary electron images identified small (typically less than 20 µm) sulphur conglomerates at the point of deviation, which &apos;collected&apos; unreacted chalcopyrite mineral particles and lowered the total mineral surface area available for oxidation. These sulphur clusters are thought to be the precursor for blockages experienced in the continuous pilot autoclave. These results emphasised the importance of fine grinding (P80 5-20 µm) and suggest that shorter residence times may minimise the formation of sulphur conglomerates in a continuous autoclave operating at medium temperature.

Jan 1, 2004