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By Raj K. Rajamani, Ilesh M. Shah

Maintaining pH, a routine requirement in many industrial processes, is by no means trivial. The control is troublesome because of the inherent nonlinearity and frequently changing process dynamics. Many researchers in the past have investigated advanced on-line estimation and/or adaptive control techniques to overcome these difficulties. Most methods require the development of a complex mathematical model. The present work deals with the use of a simple and elegant method for pH control, based on the use of fuzzy logic. First, a standard fuzzy-logic controller is discussed, followed by a self-organizing controller. The latter algorithm generates a set of rules based on observation of the process. Thus it is a learning algorithm. The development and application of the algorithms to a laboratory acid-base neutralization experiment are presented. This elegant technique is powerful and deserves attention in mineral pro- cessing.

Jan 1, 1990

By Julian Malnic

The emerging marine minerals exploration and mining industry is currently focused mainly on the technical elements for its success such as developing exploration and mining technologies. However, in one sense, the technical challenges are quite soluble whereas those arising in the fields of the environment and public opinion could present this new generation of miners with problems that are far more difficult to overcome. One need only look at the issues currently faced by mining projects on land to see how powerful the new forces of so-called ?civil society? are in stopping mineral developments in many countries. From the geographic viewpoint, there are many countries but there is just one ocean, so the impacts experienced by any one operation are likely to have pervasive repercussions throughout the industry. A well-oiled NGO development protest lobby will see leverage in resisting this new industry and will seize on the single-ocean angle. The Australian Minerals Industry has established a voluntary Code for Environmental Management that provides an active and valuable model for satisfying the ?court of public opinion? and in delivering economic results to industry that are in current jargon, sustainable. An explanation of the Code for Environmental Management, and the reasons behind 44 companies representing more than 300 operations and 85% of Australia?s sizeable mineral production being signatory to it will be given. Participants see it as a means to future shareholder wealth.

Jan 1, 2000

A semi-automatic device has been constructed that can be used to check the solution strength of cyanide solutions. It consists of a wheel on which a gold-foil-bearing glass slide is mounted. The wheel moves the gold foil through the solution under test and intercepts a light beam. As the gold foil is attacked by the cyanide solution its light absorption diminishes. The successive in-crease in transmitted light intensity is recorded and gives a measure of the gold dissolution rate. Curves have been obtained to show the effect of cyanide concentration and oxygen content on dissolution rates. Details are presented of the construction of the unit, and some practical operating procedures are outlined. 0 NE of the important, although often neglected, factors in the extraction of gold by cyanidation is the actual dissolving strength of the cyanide solution. This depends in a

Jan 1, 1964

By R. M. Goktan

Point-attack picks are one of the most widely used tools for the mechanical excavation of rock and coal. In the literature, some practical formulas have been developed to estimate their performances under varying cutting conditions such as the pick geometry, cutting depth and cutting geometry. In this study, it is shown that Evans?s theoretical model, the most cited in the literature, has serious limitations concerning the changes in the cutting geometry. Analysis of the two independent full-scale linear rock cutting experimental data reveals that both his theory and its recent modification can not fully explain the mechanism of rock breakage under asymmetrical attack. The cutting force predictions made by employing such models are shown to be too significantly weak to be of any service in practice. In this study, a semi-empirical approach was followed by means of which cutting forces under varying cutting geometries could be made. By analysing the full-scale rock cutting test data, prediction equations of the peak cutting force and mean cutting force have been developed. Comparisons of laboratory determined and predicted force values indicate that the suggested prediction equations are applicable to quite different rock materialsm which have uniaxial compressive strength in the range of about 30?170MPa, and valid for different cutting geometries. It is also shown by regression analysis that the established prediction equations are statistically significant.

Jan 1, 2005

By R. Simon, P. Pagé, L. Li, P. Yang

The Mathews-Potvin stability method is widely used in the Canadian mining industry as a starting point to determine the maximum dimensions of mine stopes. However, it cannot be applied to inclined (more frequently encountered) mine stopes without conducting numerical modelling to obtain the stress factor A, defined as a function of the ratio of unconfined compressive strength of intact rock to the induced principal stress on the exposed stope walls. The need to conduct numerical modelling significantly limits the application of the Mathews-Potvin method. In addition, given its empirical nature and main application for preliminary design, it is deemed undesirable to conduct numerical modelling, especially elaborate modelling. Alternatively, theoretical methods can provide a much simpler and quicker way to estimate stresses around stopes and the corresponding stress factors. Over the years, a large number of studies have been conducted to estimate stresses around openings excavated with various crosssections. However, theoretical or graphical solutions remain unavailable for mine stopes that typically consist of horizontal floor and roof, and two parallel inclined walls (hangingwall and footwall). To remedy this situation, a series of numerical simulations is first performed for openings with vertical and inclined walls, including typical stopes commonly encountered in underground mines. A group of empirical solutions is then formulated to estimate the induced principal stresses at the roof centre and mid-height of the stope walls. The validity and predictability of the proposed solution have been verified using additional numerical simulations. The proposed solution can thus be used to calculate stresses and the resultant stress factors A around typical mine stopes with any inclination angle and height to width ratio, under any in-situ stress state, without conducting numerical modelling.

Aug 1, 2021

A field method combining solvent extraction and paper partition chromatography permits a simple and rapid semiquantitative estimation of gold in siliceous, argillaceous and sulphide ores. The method will facilitate the eyaluation of prospect samples in which the gold is too fine for separation by panning.Ethyl alcohol-hydrobromic acid mixtures are suitable for chromatographic development of the gold complex, and give clear reproducible definition of the gold zone. Substitution of commercial "methylated spirits" for the ethyl alcohol gives equally good definition, improving the potential of the method for field use.A batch of six samples in the range of 0·5 to 5·0 dwt/ton can be completed in two hours. The range may be extended by simple modification to higher or lower values.INTRODUCTIONIn a chromatographic method described previously (Lever 1958, Nevill and Lever 1959), gold from a standard volume of ore clamped between -plate glass was extracted by aqua regia on to the paper. After cautious drying the chromatogram was developed by an ethyl acetate-nitric acid-water mixture and gold was identified by spraying with stannous chloride solution. Sensitivity of the method in the low range was poor. The brown line obtained in the 1-3 dw/j ton range, caused by movement of gold in the reduced form, was not considered to be a satisfactory confirmation of the presence of gold. It was felt that the method would be improved by using a more elegant extraction and applying developing conditions which would produce a well defined purple line at all gold values. Iron was a limiting factor, and a method of eliminating its interference was needed.The method now developed overcomes these shortcomings, and gives a reliable result with a purple line for assay values of 0·5 dwtjton and over. Gold is dissolved from an...

Jan 1, 1964

By Clarence O. Babcock

A simple robust rock bolt load gage was tested in the laboratory to define its characteristic behavior and to obtain a measure of its performance. The gage uses three vibrating wire sensors crimped 120 degrees apart into the outer surface of a hollow cylindrical steel tube. The resonant frequencies of the wires change as the gage is loaded. This change is read with a Creare meter developed for the Bureau on a previous contract to read borehole stress gage results. A statistical analysis of data obtained defines the variables influencing results. A U. S. patent (3,914,992) assigned by the author to the Department of the Interior was granted October 28, 1975.

Jan 1, 1976

By Kosta Fytas, Nour-Eddine Chaouai

"Selection of the appropriate kriging plan during indicator kriging estimations is of a paramount importance to the precision of ore reserve estimation. However, very little is known on the sensitivy of indicator kriging results when changing the kriging plan parameters (mainly search distance and number of samples). This paper evaluates the effect of the search distance and number of samples on indicator kriging results using a gold deposit as a case study.IntroductionBlock estimation using kriging is based on the autocorrelation function (variogram) on one hand and on the kriging plan on the other. As far as the variogram is concerned it is more or less subjectively adjusted and this is reflected on its parameters (range, sill, nugget effect and anisotropy). The effect of a poor estimation of these parameters on the kriging variance of ordinary kriging has been proven very important (Brooker, 1986). Choosing a kriging plan is generally a difficult matter depending on the estimation type (global or local). Generally there is not a unique kriging plan be cause there is not a unique structural analysis (variogram). There are no rules or dogmas in choosing a kriging plan but it is rather a function of the sampling pattern (David, 1982).Structural analysis requires the hypothesis of quasistationarity but very often either the data available within the zone of quasi-stationarity are too many so that the search distance is reduced during kriging or the data are too few to satisfy a stationary kriging system (Journel and Huijbregts 1978). As a rule, the larger the neighbourhood, the more precise the estimates should be , but for large neighbourhoods the hypothesis of stationarity does not always hold (Rivoirard 1987; Armstrong and Champigny 1989)."

Jan 1, 1991

By H. Copur

Experimental studies for quantification of force and brittleness indices relevant to rock cutting performance are presented. A simple interpretation method is developed, which quantifies the force-penetration response obtained from indentation tests. Basic parameters of the quantification are force increment and decrementrates, force increment and decrement periods, and number of increment and decrement data points. Blocks of eleven different rock samples were collected from different operating mines in Turkey and subjected to indentation tests to calculate the indices. The samples included harzburgite, serpentinite, trona, limestone, claystone, two different sandstone samples, siltstone and three different chromite ore samples. The concept was validated by a set of full-scale linear cutting tests using a conical cutter for measuring the cutting performance in relieved and unrelieved conditions, i.e. cutter forces, specific energy, size distribution of rock cuttings. The rock cuttings were sieved to determine coarseness index, indicates coarse chip generation characteristics, and size distribution. The force index is moderately correlated with the cutting performance and mechanical properties of the rocks, and poorly correlated with the coarseness index and size distribution of cuttings. A general and moderate trend is observed between the brittleness index and the coarseness index, cutting performance for unrelieved cutting conditions and mechanical properties of the rocks. However, additional data is required to fill the data gaps and to potentially establish relationship between the brittleness index and all other parameters.

Jan 1, 2003

By Nicholas Macrae Steven

Abstract - The Shaba-type Luamata Cu-Co(-Ni) deposit (11°50_S, 24°28_E) is located in a tectonic slice of Katangan Roan Supergroup (Mines Group) sedimentary rocks, surrounded by younger Kundelungu Supergroup lithologies in the external fold and thrust belt of the Lufilian Arc. Luamata is a classic central African copper clearing in dense woodland, visible as a tonal botanical anomaly on Landsat imagery. Supergene Cu-Co mineralization (especially malachite and subordinate chalcocite, digenite, covellite, and copper and cobalt oxides) and, probably hypogene, bornite, and chalcopyrite are hosted by altered, but essentially unmetamorphosed, moderately dipping, dolostones and dolomitic shales. Alteration products include talcose dolomite, sericite rocks and intense silicification and brecciation. Friable yellow shale is best mineralized with cobalt (up to 0.43 wt%), whereas, highest copper grades occur in brecciated, silicified shale (up to 13.5 wt% CuO). Soil copper and cobalt contents are up to 2.2 and 0.6 wt%, respectively. A newly identified nickel zone (where soil contents exceed 0.1 wt% Ni) fringes the Cu-Co deposit. Polymictic, matrix-supported breccias with a calcareous matrix that underlie the Cu-Co deposit are interpreted to be fluidization breccias related to thrust tectonics and the emplacement of the Mines Group slice. Although small compared to the Kolwezi district Shaba deposits in the Democratic Republic of the Congo, Luamata exhibits all the classic features of an ore deposit type (with low calcite contents), whose high metal concentrations could potentially be very profitably exploited by low-cost opencast mining and hydrometallurgical recovery methods.

Jan 1, 2000

By L. G. Marshall

WHILE surveying in a small Western mine, the following problem was encountered: Two traverses had to be connected by running a traverse line down the main hoisting shaft, which was the only connection between the two levels. The shaft was inclined at about 80 deg. from the horizontal and measured 8 by 10 ft. The distance between levels was about 110 ft., measured on one side of the shaft. The surveying equipment consisted of a transit, tripod, level rod, 100-ft. chain, and plumb bobs. There were no side or top the- scope attachments with which to take large, vertical angles. Therefore, we were confronted with the problem of taking readings between two points, one of which could not be seen through the instrument when set up under the other point, owing to the obstruction of the horizontal plate, and of measuring the distance between these points with a chain that was too short. The method of a line of plumb bobs down the shaft was impractical because a setup would be needed part way down the shaft, which would call a halt to all hoisting operations for some time. After considerable experimentation the following method was used.

Jan 1, 1936

By G. E. Viens

The electric arc furnace has characteristics which make it attractive for a number of metallurgical applications. Some of these characteristics are: high thermal efficiency, the possibility of attaining very high temperatures, low off-gas volume compared to fuel-fired furnaces, no impurities are introduced by the heat source, and impurities in only minor amounts are introduced by the electrodes. It also has disadvantages, the chief ones being the relatively high cost of electrical energy compared to fossil-fuel energy and the fact that, when oxide ores are smelted using carbon as reductant, the off-gases emitted are rich in carbon monoxide. As in many other pyrometallurgical processes, fumes and dust are emitted from melting or smelting operations. In many installations, some or all of the off-gases are flared, thereby wasting their energy and contributing to atmospheric pollution. During the last eight years, a shaft-electric furnace has been under development at the Mines Branch, Department of Energy, Mines and Resources, Ottawa, Canada. This project was initiated to try to overcome, or at least minimize, the disadvantages of the electric furnace. Experience on other projects, prior to the beginning of this program, had indicated that preparation of the charge materials, for example by sizing raw ore, sintering concentrates and crushing and sizing the sinter, or agglomerating concentrates into uniform-sized pellets, could make a substantial contribution towards achieving success in arc-furnace smelting projects; This entire

Jan 1, 1971

By Pawan Bharadwaj, Wim Mulder, Thomas Tscharner, Guy Drijkoningen, Rob Jenneskens

"The Earth’s properties, composition and structure ahead of a tunnel boring machine (TBM) should be mapped for hazard assessment during excavation. We study the use of seismic-exploration techniques for this purpose. We focus on a seismic system for soft soils, where shear waves are better and easier to interpret than compressional waves, as has been shown over the last decade. The system is intended to be deployed on the machine’s cutter head, with a few seismic sources and sufficiently many seismic sensors to tackle spatial variability and noise characteristics. An important property of the newly developed system is its ability to process data with very little human interaction. Images need to be available in near real time, without human interactions slowing down the imaging process. This can be achieved by employing Full Waveform Inversion, which minimizes the difference between modeled and observed data. Because this method may suffer from local minima in the cost function if the data lack low-frequency information, we employ a dedicated seismic source that can generate sufficiently low frequencies for the relevant length scales. With data acquired in a number of field settings that mimic realistic TBM configurations, we show that the designed seismic system can successfully look ahead of the TBM and offers a valuable capability to support decision-making during tunnel excavation. INTRODUCTION While excavating a tunnel with a Tunnel Boring Machine (TBM), the geology and the ground conditions along the planned tunnel trajectory need to be investigated in order to safely and efficiently carry out the underground operations. This entails detecting the occurrence of boulders, foundations, pipes and faults, necessary to prevent hazards and time-consuming delays in the tunnel boring operations. In order to facilitate ground prediction ahead of a TBM, techniques as used in seismic exploration can be deployed. Two components common to seismic-exploration techniques are data acquisition and processing, the latter including inversion. We will discuss each of these for the application to tunnel excavation with TBM, in particular for soft soils."

Jan 1, 2016

By S. Beitler

The availability of renewable energy does not meet the demands of consumption. Hence, fossil fuels will continue to be an important energy source, and coal promises to cover the requirements for the coming decades. Because of its high energy content, deep lying bituminous coal and anthracite are important for energy generation. One trend in the future of coal mining is thin seam mining, because thick seams more and more have been exploited. A well-known and approved longwall mining method for thin seams is plowing which has big advantages compared to a shearer because of its compact design. The extraction of those thinner coal seams will become more and more important in coal industry and therefore the plow will receive more attention in future. Most approaches in longwall automation are focused on the shearer and need a more or less intelligent exploitation machine. Therefore those approaches cannot be used for the plow technology. The authors introduce a shield-data-based horizon control (SDHC). The developed approach integrates the shield data provided by the roof support and process monitoring into the horizon control process to keep the plow in seam even if the seam trend changes. This control concept can be used for the shearer as well as for the plow. The basic idea of SDHC for plow application will be introduced in this paper and first simulation results will be shown.

Aug 1, 2013

By Sneddon J

This Is not a highly technical paper, but rather an attempt to give a general outline of coal mining for the benefit of those present who may have little or no experience in the industry, and is intended to give some general knowledge which may help to a better understanding of the problems of the industry. A knowledge of the disposition of workable material is necessary to give a comparison with other mining practices. Coal Is usually found in comparatively fiat seams of varying thickness, whereas other minerals are generally found in highly inclined lodes of variable width. However, even in comparatively flat seams unaffected by faulting, grades can, and do, vary greatly over short distances.This variation causes many local problems in working the small area affected. Even very steep seams, and some are much steeper than 1 in 1, vary considerably not only in grade, but also in direction of grade and level course. This is probably caused by folding during alteration of the shape and form of the basins after deposition.These swellies are common to most coal seams and vary only in extent. This type of variation in grade and direction of grade, while common to most ore bodies, is a matter of great importance in coal mining when it is considered that roadways are driven in the seam itself and have to be graded and made suitable for haulage purposes.The area of ground involved in an individual coal mining operation is often very large; many times larger than most metal mining propositions, and often comprises many thousands of acres.When it is considered that the specific gravity of coal may be only one-fifth of that of some ores mined, and the coal seam may be five or six feet in thickness, the vastness of the area necessary for continuous mining operations over many years will be realised.To achieve comparable outputs, with about five times the bulk of material to handle, much more ground and working places must...

Jan 1, 1947

By Fathi Habashi

"Crushing and grinding of ores and their beneficiation by washing away gangue minerals has been practiced since ancient times. Primitive crushing was done by hand pounding the ore with a hard stone then by using metallic hammers. The mortar and pestle was mechanized using a lever and when the size of operations increased in the middle ages, the stamp mill was introduced. The grindstone played an important role in grinding of ores. Panning for gold and hand sorting of minerals were two old methods of separation, now gave way to modern techniques. Flotation started in the middle of the nineteenth century by using oils to collect the mineral particles and float them on the surface of the aqueous slurry. It was only in the 1920s when it was discovered that organic compounds were affective floating agents. Textbooks written by distinguished engineers such as Rittinger, Rickard, Pryor, Taggart, Richards, Gaudin, and others contributed to the recognition of this field as a new discipline to be taught in Universities. INTRODUCTIONThe ancient Egyptians knew already that it would be easier to melt an earth rich in gold particles than another which is poor. As a result all efforts were made to enrich the gold by washing away the light gangue minerals (Figure 1). Another ancient method for enriching gold particles from a river stream was by means of fleece, hence the Greek myth of the “golden fleece”. The present day Georgia was known in ancient times as Colchis and was a center for gold working. It was known to the ancient Greek as the land of Golden Fleece. The use of special cloth to catch gold particles was also described by Agricola in his 1555 book De Re Metallica (Figure 2)."

Jan 1, 2009

By A. Dienenthal

"The casthouse floor has always been one of the most dangerous working places on a blast furnace or a ferro-alloy/nonferrous furnace. Apart from working in an atmosphere including toxic gases, fumes, and dust, the workers have to perform hard and heavy manual work close to runners and ladles filled with hot liquid metal and slag.Before the invention and installation of tapping equipment the tap-holes were opened and closed manually. Opening was done by means of steel bars and sledgehammers, whereas the tap-hole was closed by repeatedly ramming small amounts of clay or refractory material into the tap-hole, again with the help of long, heavy bars. In addition, on blast furnaces the blast had to be stopped, since it was impossible to close the tap-hole properly against the blast furnace pressure. This stoppage of the blast resulted in regular losses of production. Around 1900 a major change in technology occurred. Samuel W. Vaughen, superintendent of the blast furnace department of the Cambria Iron company at Johnstown, Pennsylvania (USA), invented the first clay gun in 1895 (Wiley, 1896) (Figure 1)."

Jan 1, 2014

By S. Tuylu, D. Adiguzel, A. Bascetin

"Optimization techniques are successfully used in many different fields such as engineering, physics, economy, and politics in order to enhance the performance of the systems. In concrete technology, Aggregates are prepared by mixing the water and cement in proportional quantities. In order to obtain desired quality control parameters, the determination of the ingredients ratios is one of the important problems for the optimization. Additionally, in the quarries where the aggregate quality constantly changes, blending optimization must be made to obtain a sustainable aggregate quality. This study showed that linear programming, which is easy and which includes many aggregate properties, cannot be used in terms of some aggregate properties. Therefore techniques such as nonlinear programming or genetic algorithm must be used. INTRODUCTION Concrete is a used construction material and made by mixing the aggregate, cement, and water. The concrete properties are directly related to the properties of these materials in blending. The quantity of aggregates in concrete is approximately 70 percent of the concrete’s volume. Therefore, the most important material is aggregates. The extraction of aggregate materials in quarries is more problematic because of variable bedrock properties. Therefore, the quality of the materials changes and the characteristics of the concrete are also influenced directly. In terms of sustainable use of natural resources, produced aggregate materials which have different qualities should be used optimally (Adiguzel et al., 2014). Nowadays, in the solution of the blending optimization, various optimization techniques are being used such as linear programming, nonlinear programming, and genetic algorithm. In this study, blending optimization techniques especially used for concrete aggregates blending have been summarized, and the advantages and disadvantages of these techniques have been introduced. BLENDING PROBLEMS Blending is a frequently encountered problem in process-type manufacturing such as mining, refinery, food industry, chemical industry and metal industry (Sakalli 2010). Blending is a commonly used method in lots of practical solutions (Sarker and Newton 2008). Several optimization techniques are available for blending problems (Furman and Pardalos 2009). The most important issue is to blend with minimum cost. The blending problem is a special linear model which was developed to solve this problem. In blending optimization research, linear programming is a widely used method (Adiguzel et al. 2011; Bascetin and Adiguzel 2011)."

Jan 1, 2016

By D. K. Sarkar, J. Perron, J. D. Brassard

"Nearly perfect spherical shaped water drops rolling-off from the surface of lotus leaf is one of the beauties of nature. This kind of surface is called superhydrophobic, since the water does not like it. Physically, a superhydrophobic surface provides a contact angle (CA) of water over 150°. The combinations of both mico-nanostructure topography as well as low surface energy are essential to have such high CA on a surface. Nano-micro structured superhydrophobic surfaces have been developed in different methods. (i) Monodispersed fluorinated silica nanoparticles have been synthetized via Stöber Sol-Gel process and deposited on various surfaces, such as aluminium or glass, to obtain transparent superhydrophobic thin films. (ii) Similarly, zinc stearate nanocomposite coating has been fabricated by spray process on the same substrates. These thin films are found mechanically robust with drag reduction of coefficient 16% lower than as-received surfaces. (iii) By electrodepositing pure zinc on steel surfaces and further coating it with diluted room-temperature vulcanized silicone rubber, the surface become superhydrophobic. This superhydrophobic surface protects the steel against corrosion by increasing the polarization resistance from 1.5 k? on steel to 44.4 k?. This coating also reduced the ice adhesion on the steel surface 6.3 times as compared to bare steel substrates. Globally, these superhydrophobic surfaces have tremendous applications against corrosion reductions, drag reductions and ice adhesion reductions.INTRODUCTIONSuperhydrophobic coatings are increasingly attractive to the industry and academia due to their unique self-cleaning properties as a result of their water repelling characteristics. Fabrication of superhydrophobic coating is an inspiration from nature as water is seen to repel on many natural surfaces such as those of the lotus leaves, butterfly wings, water striders’ legs, and so on (Gao & Jiang, 2004; J. Huang, Wang & Wang, 2006; Neinhuis & Barthlott, 1997; Zheng, Gao & Jiang, 2007). This non-wetting phenomenon is well understood on lotus leaves, shown on the Figure 1 (a), and it is considered as the basis of the studies of superhydrophobicity. The existence of this binary structure on the surface of the lotus leaves allows a large amount of air entrapment and consequently reduces the contact area of water on it and the presence of low surface energy waxy components with reduced affinity to water together leads to the superhydrophobic properties. The phenomenon is shown on Figure 1 (b). Cassie and Baxter (Cassie & Baxter, 1944) as well as Wenzel (Wenzel, 1936) proposed two mathematical models to explain the wetting phenomena on rough surfaces that leads to superhydrophobic properties. By definition, superhydrophobic surfaces are characterized by a water contact angle value = 150° with the rolling off of water drops from the surfaces (Sarkar & Saleema, 2010). Superhydrophobic surfaces find tremendous importance in the technological world where it can applied in domains such as anti-corrosion, anti-biofouling, electrowetting, icephobic and even in drag reductions (Bushnell & Moore, 1991; Cao, Jones, Sikka, Wu & Gao, 2009; Carlborg & van der Wijngaart, 2010; Carré & Mittal, 2009; Y. Huang, Sarkar & Chen, 2010a; R. Karmouch, Coude, Abel & Ross, 2009). However, the most important challenge faced by industries is their feasibility large scale in an effective an economical manner."

Jan 1, 2016

By M I. Pownceby, M A. Rhamdhani, D M. Fellicia, S Palanisamy, R Z. Mukhlis

The trend of global copper production has prospectively increased over time. Based on typical mined ore grades, 1 t of copper ore generates approximately 6–10 kg of copper, which requires much energy, usually in the form of metallurgical coke. Copper production using carbon as a fuel and reductant contributes up to 0.3 per cent to global greenhouse gas (GHG) emissions. As a result, research into decarbonisation processes applicable to reducing low-grade copper sulfide ores, copper oxides, electronic wastes and other alternative complex Cu-rich materials has increased. Alternative fuels for reducing carbon-rich emissions in pyrometallurgical copper processing include methane, ammonia, biomass, solar and wind power, but in recent times increased focus has been on hydrogen as a potential fuel and reducing agent for materials such as oxidised copper scrap, Cu2O/CuO and Cu-rich slags/e-wastes. From a thermodynamic perspective, hydrogen exhibits a significantly more negative standard Gibbs free energy (ΔG°) than copper oxide making it a suitable reductant and the exothermic thermal effect from reaction between hydrogen and Cu2O/CuO may be used to control process parameters. These characteristics renders hydrogen an ideal gas for reducing copper oxides and copper-containing slags/e-wastes. This review article assesses previous research on utilising hydrogen for producing and refining copper from primary and secondary feed materials.

Jun 19, 2024