Search Documents

By G. R. Fritterer

INVESTIGATORS in the field of temperature measurement have long sought a thermoelectric couple fulfilling the following requirements: 1. It should be useful up to and including high industrial tempera-tures; i. e., 1000° to 1800° C. 2. Its thermoelectric variation with temperature should be linear and be maintained after heating to high temperatures for long periods of time. 3. It should be reproducible; i. e., different couples of the same elements should have similar calibration curves. 4. Its thermoelectric power should be large so as to allow the industrial use of rugged recording instruments. 5. Chemical reactions with, and physical changes within the elements of the couple should not alter its calibration. No thermocouple proposed to date exhibits simultaneously all of these characteristics, whereas the couple about to be described fulfills all requirements to a satisfactory degree.

Jan 1, 1933

By M Szwec, P Corbett, P Sheffield

Centennial Coal operates the Springvale and Angus Place longwall mining operations that extract coal beneath the Newnes Plateau in the Western Coalfields of New South Wales. Springvale and Angus Place mines have a history of difficult geotechnical conditions, where mining operations are conducted with a thick coal roof interbedded with numerous claystone units and relatively high levels of vertical and horizontal stress. The combination of a relatively high stress regime and weak laminated roof has led to numerous roof failures throughout the mine’s life.Following underground roadway development, the mine roadways can experience high levels of roof movement that can lead to roof falls. Two-point wire extensometers (known as ‘telltales’) are extensively used for roadway condition monitoring. Along with extensive other geological and geotechnical data, monitoring data is used to prepare geotechnical hazard plans that are then used in all areas of mine planning to allow for safe and efficient operation of the mine.This paper presents a case study of the use of a new software tool that allows time-scaled visualisation of monitoring data in the context of longwall and development face positions and installed strata support. It can be used in the identification of geotechnical risk factors and their interaction with the mining process to allow a more robust geotechnical hazard process. It interfaces directly with the widely used ExtoChart database software and can be presented with scale drawings of geological/geotechnical data to allow correlation of monitoring data with risk factors.CITATION:Corbett, P, Sheffield, P and Szwec, M, 2014. A new tool for extensometer data analysis and improved understanding of geotechnical risk factors, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 217–232 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By Y Li, Z Fu, D J. Williams, E Topal

Mine waste rock is unavoidable in the recovery of ore by open pit mining methods. Effective management of waste rock movement covers the removal and placement of the waste rock, generally in a surface dump in the most cost-effective way while satisfying the long-term environmental expectations. Since the 1960s, there has been significant research carried out into planning of ore movement from open pit mines such that the overall net present value (NPV) of the project can be maximised. Currently, several software packages are available to achieve this task as a common practice within the mining industry. However, planning of mine waste rock movement is still achieved manually, as the available software does not consider optimal waste rock movement and dump design. This paper describes a tool to optimise waste rock placement, which minimises the haulage cost while creating environmentally friendly waste rock dumps through selective placement and encapsulation of the reactive waste rock in the dump. The embedded methodology in this tool has been developed based on the mixed integer programming (MIP) modelling technique to optimise the waste rock movement. The methodology provides an easily-manipulated and fully-automatic tool for professionals to complete waste rock dump scheduling in four main steps: data input, model construction, model computation and solution retrieval. The application of the new tool into a real case project in this paper shows that it can determine economically and environmentally optimised waste rock dump schedules in an acceptable time frame.CITATION:Fu, Z, Li, Y, Topal, E and Williams, D J, 2015. A new tool for optimisation of mine waste management in potential acid forming conditions, in Proceedings Tailings and Mine Waste Management for the 21st Century, pp 333–342 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By Glenn Kosick, John Starkey, Glenn Dobby

"A practical new test has been developed for SAG hardness determination. Using two kilogram samples of minus one inch diamond drill core or crushed muck samples, the Starkey SAG Test has been shown to give accurate predictive information which directly relates to on-stream SAG mill performance. Typical results and test criteria are discussed in the paperAchievements to date include:• Identification of hardness profiles and the location of hard and soft zones in a large ore body.• Accurate prediction of the hardness of a bulk sample by using an adjacent diamond drill hole.• Derivation of a plotted curve relating pilot plant power to laboratory relative hardness.• Demonstration that for every test done to date, the Starkey SAG Test produced a product size distribution identical to that produced in a pilot plant or full scale plant SAG operation.This test can now be used for blast hardness monitoring and short term control of mine production in existing plants and for identifying the proper locations for bulk samples in new projects. In addition, new SAG mill design can now be rationalized in a low cost way to eliminate unforeseen production shortfalls.IntroductionThis paper is presented to introduce the Starkey SAG Test, a practical new laboratory tool for measuring the relative hardness of small ore samples in a semi-autogenous grinding (SAG) environment. The test was first designed for use on diamond drill core samples during the prefeasibility stage of new mining projects, to provide new information about the ore body at reasonable cost. It is a new tool and does not replace existing pilot plant test requirements.The test will also be useful for throughput prediction in existing SAG plants by assisting in short and long term mine planning, where forecasting of metal grades and milled tonnage is used to control mine profitability. Because in-plant hardness testing has previously been unavailable on small samples, this test offers exciting possibilities for SAG mill operations where hardness variation is or could be a problem.The Starkey SAG Test provides the following benefits to the mining industry"

Jan 1, 1994

By Jean-Luc Collins

"This new tool can be used as a quick guide f or the assessment of the potential economic wealth of any risky capital project. It does provide an unambiguous recommendation of the type ""go or no go"" to the decision-maker simply by comparing two different ratios profit/investment. One ratio determines the minimum value required to at least break even while the other measures a probable value based on the asymptotic theory of statistical extremes.Its application is briefly illustrated by means of an underground gold mine extension project, an oil sands mine project and a polymetallic open pit project.Once a favourable recommendation has been obtained then a detailed ""cash flow after taxes"" analysis can be carried out for the project.IntroductionMany tools are used in financial decision-making such as the payback period, the discounted cash flow, the internal rate of return and the wealth growth rate (Berry , 1971).These tools are useful and meaningful in evaluating normal projects closely related to regular business where the number of assumptions made is usually very small and where the cost of capita! is usually selected as a discount rate or a hurdle value. In situations where a significant number of assumptions have to be made,two problems can emerge, namely:I. the risk involved is underestimated leading to a potential financial disaster; or2. a good opportunity is lost because the approach used in evaluating the project is too conservative.Each assumption has its own degree of uncertainty and it is well known that combining uncertainties together can lead to a total uncertainty of critical proportion. The easiest way to account for risk is to increase the discount rate or the hurdle value, but this approach alone is quite subjective and can easily lead to the problems described above."

Jan 1, 1993

By R. K. Singhal

This new tool can be used for the proper assessment of the potential economic wealth of any risky capital project. It does provide an unambiguous recommendation of the type "go or no go" to the decision-maker simply by comparing two different ratios profit/investment. One ratio determines the minimum value required to at least break-even while the other measures a probable value based on the asymptotic theory of statistical extremes (weakest link concept). Its application is briefly illustrated by means of an underground gold mine project, an oil sands mine project and a poly-metallic open pit project.

Jan 1, 1993

By E R. Ramanaidou, M A. Wells

Asian steel mills are demanding iron ore with specific chemical, mineralogical, metallurgical and environmental properties to warrant that the ore is of the greatest quality. As a result, a toolkit of analytical techniques becomes important. Hyperspectral analyses of iron ore cores and chips using a HyLogging™ system are now routinely undertaken by BHP Billiton Iron Ore in Western Australia for banded iron formation-hosted iron ores and channel iron deposits to better characterise their iron ores. Objective information can now be expanded by adding new sensors. The current HyLogging™ system provides point analysis reflectance spectra and a red–green–blue high-resolution image, while recent developments, such as hyperspectral imaging using the Corescan system, now provide full spectral image and surface topography. The addition of Raman spectroscopy provides the ability to detect and quantify quartz and magnetite (or maghemite) and cross validate hyperspectral information on hematite and goethite and aluminium substitution in the iron oxides. Micro-X-ray fluorescence mapping also adds chemical information appropriate for cross validation with the aforementioned methods. This paper demonstrates the value of combining these techniques for an optimum characterisation of iron ore.CITATION:Ramanaidou, E R and Wells, M A, 2015. A new toolkit for iron ore characterisation, in Proceedings Iron Ore 2015, pp 587–590 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Mingchun Lu, Yunjin Yan

"This paper describes a new type of bell-less top installed on two relined blast furnaces at Tianjin Iron Works and another new-built at Echeng Steel Works in China. A compact installation was presented for existing furnace top innovation with the least reformation of existing top structure. A water cooling and sealing gearbox used for driving the chute discards completely the traditional idea about necessity of continuous supply of cooling gas for the gearbox. A multiring spreader and its dozens of selectable charging patterns enables an operator to achieve optimal burden distribution easily under the condition of a minimum investment of control equipment. Some useful conclusions have been made through a small-size model and a full-scale model tests. The excellent characteristics and the superiority of the new top have been fully proved at both works.IntroductionIt is known that there are some advantages with the bell-less top of a blast furnace: suitable for furnace to operate at high top pressure, capable of realizing optimal burden distribution, less investment and maintenance costs, etc. But why do most of blast furnaces in the world still remain using conventional bell top. One of the concerns is that current bell-less tops still have some shortcomings:1) The height of a current bell-less top might be lower than three or four-bell top or two-bell plus valve seal top, but still much higher than an ordinary two-bell top.2) The gearbox for driving the rotating chute is positioned onto the lip of the furnace. It is subject to attack by crude hot bf gas. Continuously pumping cooling gas (pressurized nitrogen or clean bf gas) into the gearbox is indispensable to withstand such a harsh working environment. Therefore, a plant furnished with blower8 and its ancillaries has to be built, It involves a large sum of investment and much expense in its annual running costs.3) Although the current bell-less charging device as a means of controlling burden distribution possesses a wide range of freedom, it is difficult to realize optimal burden distribution. There are some large blast furnaces realized better burden distribution, but sophisticated control means is indispensable so that the investment of control means is much higher."

Jan 1, 2000

By Y. M. Zhao

The dry coal preparation technology based on air dense medium fluidized bed is an innovative dry highly efficient technology of coal by introducing fluidization technology into beneficiation.. A modularized 40-60 tones/hr system (KZX-40) with an air dense medium fluidized bed separator was established. The construction cost of the modularized system is only 1/3 of the traditional wet heavy-medium coal preparation plant construction cost with the same capacity, and the consumption of dense medium can be reduced by 50%-60%. The footprint and volume of the system are decreased by 75% and by 89.81%, respectively. These facts show the improved intensity, efficiency and economy of modularized coal preparation technique. The modularized KZX-40 system can be used to separated 50-6 mm coal over a separation density range of 1.3-2.2g/cm3 depending on the variation of <1mm fine coal content. The separation efficiency of the system was investigated at low and high separation densities by float-sink experiments. The partition curve of the products at low separation density shows that the separation density (d) is 1.33g/cm3, and the probable error (E) value is 0.05g/cm3. Using 50-6mm coal with an ash content of 55.35% as feedstock, at a high separation density of 1.61g/cm3, the clean coal with an ash content of 14.67% and the tailing with an ash content of 71.26% are produced with an E value of 0.06g/cm3. It is clear that the modularized KZX-40 system is suitable for separating 50-6mm coal effectively. During the dry coal preparation process, the dust is removed by the bag collector and recycled back into the separator. So the system has the advantages to work without environmental pollution and water. The modularized system greatly reduces the construction and operating costs and decreases the area and volume required, compared with wet dense medium system. The system is applicable to the coals located in arid regions and also to the coals that tend to slime during wet separation. Keywords: modularized, KZX-40, fluidized bed, beneficiation

Sep 1, 2012

By Florian Kongoli

New operating conditions and process parameters are often necessary in today&apos;s industrial practice of non-ferrous smelting and converting in order to accommodate various new chemical compositions of mineral charges and environmental requirements or to conceive new and more efficient industrial technologies. An important parameter in non-ferrous smelting and converting is the liquidus surface of multicomponent slags. This surface is affected by multiple factors such as temperature, gaseous potentials, the content of each component in the slag, etc., and cannot be quantified by the existing ternary liquidus diagrams. In this work a new type of representation of the liquidus surface of multi component systems has been presented by means of a thermodynamic model. This representation waives the need of the multidimensional representation of multi component systems and yields practical two-dimensional diagrams, which can be easily used in the industrial practice.

Jan 1, 2000

By I. L. Follington

This paper describes the research and development programme to develop a prototype underground auger mining system aimed at developing and demonstrating an underground auger mining system able to provide economic access to thinner (<1.8 m) coal reserves of South Africa. Data concerning the performance of modern coal augers under South African coal mining conditions were gained from a proven surface auger which operated across a range of coal types. These data were analysed and considered in conjunction with historical information regarding previous attempts at building underground augers dating back to the 1950s. Drawing on these data a prototype underground auger mining system, the BryDet BUA 600 underground coal recovery auger, was designed and manufactured by the BryDet Development Corporation in collaboration with Eskom and Cutting Edge Technology Pty Ltd with support from Anglo Coal and the Ingwe Coal Corporation Ltd. The prototype BryDet BUA 600 underground coal recovery auger commenced trials in March 2000 at the Matla Mine near Witbank in South Africa. The initial trials were undertaken in an open cut to facilitate the commissioning and training associated with a prototype mining machine. A total of 30 holes was augered in the box cut before the machine moved underground. The prototype BUA 600 first achieved the target penetration depth of 80 m in its third hole. The prototype BUA 600 is a new underground mining system which has passed early testing with ?flying colours? and could provide access to extensive underground coal reserves unmineable by conventional mining techniques both in South Africa and elsewhere around the world.

Jan 1, 2001

By Joseph Renk, David Akers, Glenn Shirey

Each year, US coal cleaning plants landfill or impound millions of tons of high-quality, fine-sized coal. This coal is not only difficult and expensive to capture during cleaning, but, if captured, can pose serious materials handling problems. The GranuFlow. Technology was developed and patented by the U.S. Department of Energy (DOE) to address these problems. GranuFlow involves the addition of a coal binding agent such as an asphalt or heavy oil emulsion to coal to reduce moisture, dusting, and freezing and to improve the flow properties of the coal in bins and chutes (1, 2, and 3). When the emulsion is added before mechanical dewatering, the binding agent causes the formation of fine-sized coal agglomerates that dewater better than untreated coal. In addition, the binding agent increases the capture of ultra-fine coal in screen-bowl centrifuges. Previous work by DOE has also demonstrated that such treatment results in a significant reduction in dustiness and a reduced potential to freeze. To address concerns about the handling and combustion characteristics of GranuFlow treated coal, DOE performed a pilot-scale pulverization and combustion test (4). No problems were encountered during pulverization or combustion, and use of this fuel in a p.c. boiler was found to be feasible from a technical perspective. CQ Inc. has an exclusive license from DOE to market this technology and is currently performing a series of commercial demonstrations to determine if GranuFlow is both technically and economically viable.

Jan 1, 2005

By Lon Santis, Michael Swisdak, John Tatom

The Institute of Makers of Explosives (IME) and A-P-T Research, Inc. (APT) have developed a quantitative risk assessment tool called IMESAFR (IME Safety Analysis for Risk) for managing risk from various activities undertaken in the commercial explosives industry. The first version was completed in 2006 and Version 2.0 of the software was completed in 2012, incorporating several major new features. The platform is now based on a Geographic Information System (GIS), providing a bird’s-eye-view to help visualize facility layouts and risk. Spatial data on potential explosion sites and exposed sites can now be automatically transferred from the images to ease users’ data input. Use of GIS data provides the ability to check facility compliance with quantity-distance (QD) standards such as the American Table of Distances (used by the Bureau of Alcohol, Tobacco, Firearms and Explosives, ATF), the NATO standard (used by Natural Resources Canada and other nations), or a user-defined table. Research conducted and knowledge gained over the last 10 years enabled changes in the algorithms and models that provide greater fidelity and reduce conservatism. Expert users can change global settings to more accurately match actual site conditions and the program runs using either Imperial (English) or SI (metric) units of measure. These changes and other new features are discussed and demonstrated.

Jan 1, 2013

By Neel Gupta, Dustin M. Crandall, Brijes Mishra

X-ray computed tomography (CT) images of rock specimens often contain artifacts which must be corrected before scientific analyses are performed. This paper presents a new workflow of automated image processing to utilize poor-quality X-ray CT scan images. The workflow runs on the open-source image analysis software and efficiently separates desired features from low-contrast scanned images. The new workflow is a two-step technique using contrast enhancement and automated feature segmentation to generate noise-free binary images. The results of binary images using the proposed workflow and using a conventional thresholding technique are analyzed to show the quality of the proposed method. The paper also presents a workflow of estimating the structural geometries of features in two and three dimensions. The results of the structural feature analyses and computational time were compared between the open-source (ImageJ) and commercial image analysis software (Bruker Computed Tomography Analyzer). The commercial software was more computationally efficient, but the task-specific macros in open-source software enabled the user-desired automation in image processing and data extraction of desired structural features of comparable quality.

Sep 8, 2022

This paper presents the latest developments in the flotation model being developed collaboratively between the Julius Kruttschnitt Mineral Research Centre in Brisbane, Australia, and the Mineral Processing Research Unit of the University of Cape Town in South Africa as part of the Australian Minerals Industries Research Association (AMIRA) P9 Project. It includes: - characterisation of flotation cells using the bubble surface area flux, Sb; - relationship of Sb to the overall flotation rate constant; - determination of the froth recovery factor; - evaluation of ore floatability; - modelling of entrainment - development of the Floatability Characterisation Test Rig (FCTR); - use of the model in design and optimization of flotation plants; and - current and future work.

Jan 1, 1999

By N. T. Cowper

Slurry viscosity ultimately affects the majority of mineral extraction processes. However, to date its role has been disguised because mineral processing equipment has been conservatively designed to operate at minimal slurry viscosity. With most ores this still meant acceptable solids concentration was achieved. However, with the advent of treatment of weathered ores the resulting higher slurry viscosity (rheology) has meant solids concentration has had to be reduced, often to unacceptable levels. To permit operation at higher solids concentration chemical dispersants are employed. These dispersants are expensive and their addition should be controlled. Slurry Systems Pty Limited (SSPL) has developed an On-Line Viscometer to monitor and control slurry viscosity, whether by controlling water addition or by controlling dispersant addition. Using this instrument the slurry rheology can be controlled at the optimum level, maximizing solids throughput, and minimizing water, reagent, and dispersant addition. This paper discusses rheology of typical mineral slurries, the relationship between slurry rheology and percent solids in a slurry, and the need for rheological control in mineral processing. The effects of rheology on various process steps, and the use of dispersants are reviewed. The paper concludes with summarizing actual case histories and cost impact of Theological control.

Jan 1, 1992

By Janet A. Flinn, David G. Fileccia

Machine guidance and control systems have become more pervasive in the mining industry in recent years but not always from mining-experienced providers. Dozers, motor graders, scrapers, excavators, shovels, draglines, drills and haul trucks are just a few examples of the types of heavy machinery now equipped with global positioning system (GPS)-aided guidance systems. While equipment manufacturers are offering their own software, many only supply solutions for the machines they produce. The proliferation of GPS equipment manufacturers entering the machine guidance and control arena has resulted in a multitude of makes and models of GPS receivers. Some of these companies also produce their own guidance software. But they usually just specialize in a narrow range of heavy machinery. So customers are forced to use multiple systems and face new challenges in implementation, training, reporting and inter-system communication.

Jan 1, 2006

By Jim F. Lemons

INTRODUCTION A nickel doesn&apos;t buy much anymore. That&apos;s even true in the cost of recovering nickel -- the commodity. A 5[C] per pound (11 [c] per kilogram) increase in the nickel price won&apos;t cover a 10-percent increase in fuel costs for processing laterite ores, nor will it cover a 10- percent increase in wages for recovering nickel from a sulphide ore. It won&apos;t even cover a 5- percent increase in the capital cost necessary to mine and process ocean nodules. The basis for this statement and a quantitative analysis of the variations in costs to recover nickel from different types of nickel ores will be discussed in this paper. During the early part of the 1970&apos;s, the interest in nickel and its potential development was shifting from Canada to the Pacific Basin area. Canadian growth rate was slowing and each additional increase in nickel capacity was very expensive (Argall, G.O., 1970). Laterite ores were attractive to developers since they were easy to mine at a low labor cost, and technologies were being developed that would allow the recovery of nickel in marketable forms (Mohide, T.P., Warden, C.L., Mason, J.D., 1977). During the last decade, new laterite production was achieved in the Philippines and Botswana, and a significant increase in production from Indonesia and New Caledonia occurred. However, recent reports on nickel identify numerous problems plaguing the industry, i.e., high energy costs that are forcing shutdowns (INCO, 1980), (Mohide, T.P., Warden, C.L., Mason, J.D., 1977), high Canadian sulphide mining labor costs (Anon., 1976), and rapid inflation of nickel capital costs (Anon., 1981b). No definitive study has been made to determine how sensitive the total cost of production is to rising energy, labor, or capital costs, or to identify to what extent increased byproduct revenues could be used to offset these production costs. The purpose of this paper is to quantify the effects of increases in energy, labor, capital costs, and by-product credits on the future cost of production from nickel reserves and/or resources. METHODOLOGY OF ANALYSIS In order to evaluate the sensitivity of nickel production costs to changes in energy, labor, and capital costs, and in byproduct revenues, an analysis was made of existing and proposed nickel operations, their costs, and their sensitivity to change. The data for these analyses were obtained from numerous sources including international govern¬ment and university publications, professional journals, company reports, private communications, U.S. Bureau of Mines contracts, and estimates by Bureau of Mines personnel. These data were collected, in part, as an ongoing effort of the U.S. Bureau of Mines Minerals Availability System (MAS) to systematically measure and classify identified mineral resources according to their respective extraction technologies, economics, and commercial availability. The MAS Program is currently evaluating the present and potential availability of nickel to the United States in relation to mining, beneficiation, smelting, refining, leaching, transportation, infrastructure, environment, land use, labor, productivity, technology efficiencies, operating capacities, deposit life, and political factors. As a summary of this data, the following briefly describes nickel ore types as each relates to energy, labor, capital, and byproducts. Sulphide Operations Nickel is currently available from sulphide deposits. Roughly 55 percent of the current world nickel production in market economy countries is from sulphide ores, although only about 20 percent of the known land-based nickel reserves and/or resources are sulphides (INCO, 1981). In 1979, the Western World sulphide reserves were estimated at about 9.2 million metric tons of nickel (Little, A.D., 1979). Sulphide ores are typically mined underground, thus resulting in high mining costs; however, these ores can often be upgraded by flotation prior to final nickel recovery and require about one-third of the energy required to recover nickel from laterites (Anon., 1981c). In addition, nickel in sulphide ores may be associated with economically recoverable byproducts, which include copper, cobalt, gold, silver, and other precious metals. Laterite Operations Forty-five percent of current nickel production is from laterite deposits. Laterite deposits account for 80 percent of the known land-based nickel reserves and/or resources (INCO, 1981). In 1979, the Western World laterite reserves were estimated at over 35 million metric tons of nickel (Little, A.D., 1979). Nickeliferrous laterites are residual soils formed by weathering, typically under tropical or near tropical conditions. They can be easily mined by open-cut methods, but generally cannot be beneficiated; thus, recovery of nickel must entail processing of the total mined ore. Usually, these ores have high moisture content (20 to 30 percent by weight) that result in additional fuel costs to dry the ore. Nickel silicates, garnierites, are, processed by pyrometallurgical methods; limonite nickel oxides are normally leached. Byproduct cobalt is not recovered from most ferronickel operations, and is only recovered to a limited extent from many leach operations.

Jan 1, 1982

By G. Bjorling

After complete dissolution of chalcopyrite concentrate in sulphuric acid in presence of nitric acid the excess of the latter is expelled by a surplus of concentrate and the last traces of nitrate removed in the mother liquor after crystallization of the copper and iron sulphates. Zinc accumulates in the mother liquor from which it can be removed by solvent extraction of zinc sulphate as a pair of ions. After dissolution of the sulphate crystals in water the neutral solution is oxidized in an autoclave at 140°C where iron sulphate is thermally hydrolyzed; the iron-free solution is taken to copper electrowinning and the cell acid after partial evaporation recirculated with the mother liquor to the leaching circuit. Total recovery of copper is about 96%; other metals like zinc and iron are concentrated in industrially usable products. At a copper price of about 70 c/lb, the method appears to be profitable also in a small unit.

Jan 1, 1976

By Praterm J. D.

The process parameters for effective utilization of nitric acid as an oxidant for copper-iron sulfides have been developed. Leaching variables found to be important were acid concentration, temperature, time, atmosphere, pressure, mineral type, particle size, and percent solids. Particular attention was devoted to analysis and control of fumes evolved during the oxidation. Responses recorded were metal extraction, elemental sulfur formation and oxidation, product gas composition and evolution rate, reagent consumption, and residue flotation response. The paper concludes by laboratory testing a flow sheet based on the above observations. Ninety-eight percent of the copper contained in a chalcopyrite-bornite concentrate was recovered, requiring 1. 6 pounds of nitric acid to be regenerated externally per pound of copper extracted. Iron remained in the leach residue as hydrogen jarosite and was ultimately rejected from the system by froth flotation. Sixty percent of the sulfur contained, in the heading concentrate reported in the elemental form; the remainder was oxidized to sulfate and eliminated with the hydrogen jarosite in the flotation tails or by neutralization of the solvent extraction raffinate with lime. Nitrogen was evolved primarily as NO and NO2; up to 3 percent N2O was also present. Gases containing sulfur were absent except when pyrrhotite was solubilized in the absence of soluble copper. In this case, H2S was evolved.

Jan 1, 1972