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By Mark Aylmore, Guy Deschenes

"Increasing pressure are motivating the gold mining industry to develop a substitute to cyanide for leaching gold. This effort in mainly based on the high toxicity of cyanide and on the lack of efficiency of cyanide in the treatment of mildly refractory gold ores (sulfides and pre-robbing). Consequently, in only a few years, consortia have been created to elucidate and implement a new technology. The most promising lixiviant that has been selected to replace cyanide is thiosulfate. This paper will present a critical analysis on the latest developments in thiosulfate leaching and illustrate the potential and limitations of the technology with experimental data. Finally an assessment of the cost and performance of thiosulfate leaching relative cyanidation will be evaluated.INTRODUCTIONConcerns regarding the toxicity of cyanide and inability of cyanide solution to effectively leach some carbonaceous gold ore or mild refractory gold ores have made the gold mining industry evaluate alternative lixiviants to leach gold. This concern has been heightened recently by the cyanide spill at a mine in Romania, which devastated a 250-mile stretch of the Danube River and its tributaries, and the environmental damage at Ok Tedi mine in Papua New Guinea. Some countries and locations have prohibited the application of cyanidation to recover gold, such as, California and Colorado States, Japan and Turkey etc.There are several potential non-cyanide lixiviants (Sparrow and Woodcock, 1995) for gold extraction, such as thiosulfate, thiourea and halogen. A pilot feasibility test (Marchant and Broughton, 1987) had suggested that thioureation might result in acutely toxic byproducts even after treatment. Scientists of Swedish Academic of Sciences reported that thiourea is a carcinogen. Halogen is also a pollutant to the environment. Thiosulfate leaching appears to have very good potential as an effective and less hazardous procedure for gold and silver extraction from auriferous ores. In addition to being much less toxic and relatively cheap, it forms a stable anionic complex with gold but is less reactive to other metals, for instances, copper and carbonaceous materials, in comparison with cyanide."

Jan 1, 2001

By N. L. Hayward, V. H. Ness

In the past decade Australia has seen the development, construction and commissioning of three complex processing plants for the treatment of lateritic nickel ores. These have all been based on high pressure acid leaching (HPAL) for extraction of nickel and cobalt into solution, followed by solid liquid separation in a CCD circuit. However, flowsheets for separation and purification of the nickel and cobalt diverge markedly. The existing plants have been commissioned with varying degrees of success, with a variety of problems ranging from materials of construction to inadequate design. While the process problems are not insurmountable, there is much room for improvement. Currently there are several new HPAL plants at the feasibility or financing stage. All of these have adopted one of the existing flowsheets. Most of the enhancements have focused on increasing autoclave size. It is now time to assess the success and failures of the three existing plants and incorporate this experience in a design for productivity, efficiency and reliability. Towards this end, this paper discusses aspects of flowsheet optimization, materials of construction and engineering design.

Jan 1, 2001

By Yindong Yang

Despite the importance and usefulness of basicity in metallurgical slags, the optimum quantitative expression of it has remained elusive, partly due to the fact that the precise concept of basicity has not been properly clarified. The two basic approaches to the concept of basicity are the Lux-Flood, which perceives basicity in terms of the activity of the free oxide ion, a O2- , and the Lewis, which perceives basicity in terms of the ability to donate negative charge. The former has been almost universally adopted in the area of metallurgical slags, while the latter has been increasingly accepted in the field of glass chemistry. In this paper, some difficulties of the Lux-Flood approach are pointed out, including the need for indirect measures of a O2- , which have proliferated in recent years. Accordingly, it is suggested that the Lewis approach has a good deal to commend it, and that the quantification of it in terms of optical basicity is the best measure of basicity available, which should therefore be more widely applied in metallurgical slags than it currently is. The fact that there are intrinsic problems in evaluating the optical basicities for the transition metal oxides is acknowledged, and a new scale is recommended. The patterns of iso-optical basicity lines in ternary systems are shown to agree well with the pattern of iso-activity and iso-capacity lines under appropriate conditions. * Originally published in the Proceedings of MINPREX 2000, published by The AusIMM.

Jan 1, 2001

By Michael R. Walsh, John H. Wright, Eivind B. Jensen

A tunnel boring machine (TBM) was designed and built at the Cold Regions Research and Engineering Laboratory in 1992 for use in Antarctica. The TBM system was tested at the South Pole where a 120-m long tunnel was bored to prove the concept. Modifications were made to the system resulting from this work. In 1999,boring of a 600-mutilidor began as part of the new South Pole Station. Tunneler hydraulics reliability problems prevented the completion of the tunnel before the end of the short construction season. This paper discusses the design and operation of the TBM, proposed solutions to the problems encountered, and current operations of the system.

Jan 1, 2001

By C. G. Anderson

Today, with a stringent economic and environmental climate prevailing in the copper business, there is increased interest in evaluating new processing alternatives for production. Hydrometallurgical pressure oxidation of copper concentrates is one of the more viable approaches and several technological candidates have emerged. Of these, an overlooked but, ironically the first industrially proven methodology, utilized nitrogen species catalyzation in the oxidizing pressure leach system to produce copper via SX/EW. Given its many inherent process advantages, this may prove to be a feasible process alternative for the future. In this paper, the history of the system and its application to copper concentrates and ores will be outlined. In particular, a novel methodology for effective recovery of precious metals from chalcopyrite concentrates will be discussed. Finally, the perceived economics of chalcopyrite concentrate treatment with this unique industrially proven process will be delineated.

Jan 1, 2001

"The Key Lake mill was commissioned in 1983 to process the two Key Lake ore deposits. With the depletion of these ore bodies in 1999, the plant was converted to mill the exceptionally rich McArthur River deposit located seventy eight kilometers northeast of the Key Lake mine site. This paper describes in detail the Key Lake milling process. The mill consists of a grinding circuit, a leachkounter current decantation circuit, a solvent extraction circuit, a yellowcake precipitatiodcalciner circuit, an ammonium sulphate crystallization circuit, and a waste treatment circuit. The paper also describes process changes to handle McArthur River ore, including the ore receiving stationLOCATIONThe Key Lake mill is located 78 kilometres south of the McArthur River mine. It is located at latitude 57' N in northern Saskatchewan, within the southern boundary of the Athabasca formation. The nearest town is Pine House, located 240 kilometres to the south. Access to the mine is by an all weather road and by a private airstrip.HISTORYAND DESCRIPTION OF OPERATIONThe Key Lake mill was commissioned in October 1983 to process ore from the Gaertner and Deilmann ore bodies. The mill was designed to produce twelve million pounds of uranium oxide (U308) a year from a feed grade of 2.4% U3O8.Following grinding, the uranium is leached in a two stage leach circuit using oxygen and sulphuric acid. An eight-thickener counter current decantation (CCD) circuit is used to separate the uranium bearing solution from the solid waste residue. The uranium is further purified in a solvent extraction circuit and then precipitated using ammonia. It is then calcined at 840' Celsius, and packaged into drums for shipping to refineries. There is a crystallization circuit to recover ammonium sulphate produced in the process and a waste treatment circuit."

Jan 1, 2001

By K. Burke, K. L. Myers, R. Espell

Barrick Goldstrike’s (Goldstrike) AA Heap Leach Pad is an HDPE lined facility used for gold recovery from low grade ores using conventional cyanide heap leach technology, operated from 1987 through 1999. Goldstrike prepared a unique reclamation plan for the AA Leach Pad Facility to provide for a cost-effective, environmentally sound facility closure and to fulfill the State of Nevada’s closure requirements. Traditional Nevada leach pad closure has involved rinsing to reduce cyanide concentration to an acceptable level, followed by reclamation. However, certain metals and compounds are not typically reduced by rinsing and some constituents may increase in concentration with rinsing. A closure scenario to effect limited infiltration through installation of a capillary cover for the leach pad was developed. The capillary cover was constructed by placing a fine-grained layer above the coarse-grained spent leach material to create a capillary break. In an arid climate such as Nevada, the fine-grained layer will rarely reach full saturation and the cover will be able to store water during precipitation and allow removal of water through evaporation and transpiration (ET) during the growing season. A 1.22 m (4 ft) cover thickness was selected as the optimum design cover thickness. The drainage network on the surface of the re-contoured AA Heap Leach Pad was specifically designed to enhance the revegetation, reclamation, and sediment yield control aspects of the AA Heap Leach Pad closure, while resulting in a natural looking surface, compatible with the surrounding topography. Adjacent natural topographic features were used to establish target design parameters for re-contouring and erosion control design.

Jan 1, 2001

By Robert Harris, Peter Pheeney

"The Murray Brook gold mine operated from September 1989 to March 1991. Approximately 1.2 million tonnes of gossan were mined from an open pit and treated at a rate of 900 tonnes per day. The facility applied an agglomeration vat-leaching cyanidation plant for gold and silver recovery. The leached ore or tailings were rinsed of residual gold and cyanide and placed on an adjacent clay lined pad for storage and containment. A 50,000 tonne heap-leach demonstration project was constructed at Murray Brook in 1992 to recover copper and zinc from ore located in a sulfide-rich zone occurring beneath the gossan. The operation proved unsuccessful because of poor recoveries and low metal prices. The project terminated in the same year.A corporate decision was made in September 1999 to undertake complete and final reclamation of the Murray Brook site. Jacques Whitford and Associates Limited were contracted to develop the final reclamation plan and to assist the company in presenting the plan to the New Brunswick government for approval. The government approved the plan in January 2000. Two important reclamation issues were the mobility of mercury from the gossan tailings and the potential of acid mine drainage from exposed sulfides. The mine site is situated upstream of a productive river system, and the issue or impact of chemistry changes to the environment over the long term became an overriding factor in the development of the reclamation plan.A resource assessment of the gossan tailings in 1999 indicated an average concentration of mercury of 40 ppm. The mercury occurred naturally as the mineral cinnabar, but the exposure to residual cyanide (less than 10 ppm) over several years in the pile has likely caused much of the cinnabar to decompose into more soluble mercury forms. The reclamation plan specified the replacement of all sulfides to the pit followed by approximately 600,000 tonnes of gossan. To ensure “fixing” of the mercury, the gossan was replaced in compacted lifts and both the remaining pile and that replaced to the pit covered with available till and compacted. The reclamation work was successfully completed in September 2000 and the chemistry of the receiving environment will be monitored over a three-year period, after which the company expects to achieve walk away conditions."

Jan 1, 2001

By David Weidner

Public relations, regulatory compliance, determination and implementation of pre-blast inspections, and accurate blast monitoring data are all essential components when conducting blasting operations for a large scale, high profile, urban site development. By working closely with the contractor, an independent vibration consulting firm can provide the commitment of time, energy and resources to tie all of these elements together. When this comprehensive approach is properly implemented, problems often associated with projects of this magnitude can be almost completely eliminated.

Jan 1, 2001

By Robin B. Dill, Mark Pelletier, Daniel J. Dobbels, Subodh Bhaumik, Daniel J. VanRoosendaal

Although primarily cut-and-cover excavations are required for replacement of the existing elevated I-93 interstate highway through the heart of Boston for the Central Artery/Tunnel (CA/T) project, some mined tunnel construction was also undertaken. The mined tunneling conducted was the 22-m-wide northbound roadway structure which passed below a 20-m-deep operating underground subway station that was built in 1913. The innovative underpinning scheme used to support the subway station during construction resulted in the successful mining beneath the subway station with negligible vertical settlement. Two grouting galleries were carefully mined below the subway structure, and pre-grouting of the granulary, pervious glacial soils and weathered bedrock was carried out from these galleries. The reinforced concrete walls of the underpinning structure were constructed within three stacked drifts that were sequentially mined below each grouting gallery. After 11 cross adits were mined between the grouting galleries, cast-in-place post-tensioned girders that spanned between the stacked-drift walls were constructed to support the subway station. The stacked-drift walls also provided lateral support for the 22-m wide by 29-m long by13-m high opening beneath the girders.

Jan 1, 2001

By M. C. Fuerstenau

Collophane, cryptocrystalline fluor-apatite, is examined as a substrate for plant water and wastewater remediation. The attenuation of Fe3+, Fe2+, Hg2+, Pb2+, and Cd2+ is presented as a function of metal ion concentration, amount of collophane, initial pH and conditioning time. TCLP results for Pb2+contaminated collophane are presented. Mechanisms of adsorption for divalent and trivalent species are suggested.

Jan 1, 2001

By G. Budge

In the extractive industry the term ‘continuous improvement’ (CI) usually means procurement of the latest state of the art equipment. This is generally perceived as the only way to add further value to the supply chain, with the driving philosophy of increased tonnage to dilute operational costs. However, not all market places can facilitate this approach. RJB lives in a fiercely competitive market and has targeted the standard efficiency drivers of rationalisation and stock management with a vengeance; and also operate CMMS (Computer Maintenance Management System), RCM (Routine Condition Monitoring)and CBM (Condition Based Maintenance) methodologies. Ultimately though, these systems are only as good as the people who operate and manage them and to add further value without procurement, people must be re-introduced back into the operation. Through TPM (Total Productive Mining), that is what RJB have set out to do.

Jan 1, 2001

By Jan L. Reichelderfer, Thomas L. Richardson

Completion of the H-3 Highway Tunnel Project was a critical element in opening this award winning project. The exploratory tunnel was completed as a maintenance tunnel and included difficult shafts extending into the main tunnel cross passages. The project also involved a major addition to the traffic operations center including a deep excavation in close proximity to the tunnel portal structures. The projects also included various completions and improvements to the main tunnels, such as paving, drainage, maintenance, and a variety of critical life-safety issues, such as radio systems, telephones, etc. The highway opened in December 1997.

Jan 1, 2001

By J. Nesset, F. Rosenblum, P. Spira

"Sulphide concentrates may exhibit self-heating to various degrees during storage or shipping, the worst cases presenting a serious hazard from fire and SO2 emission. Based on measurements of heating rates on a wide variety of concentrate samples in a special apparatus, combined with field experience, a methodology has been developed which allows concentrates to be rated for their heating potential. This has proven to be very useful in practice, for example, in deciding on the need to take preventive measures. Oxidation under ambient conditions in the presence of moisture initiates heating locally within a stockpile. In the case of highly active materials, such as those that contain abundant pyrrhotite, heating may progress through three stages to temperatures well above 5000C. However, most concentrates show little or no propensity to selfheat. Heating rates were used to estimate values of the heat output, or self-heating capacity (in joules per gram), which sustains the process at each stage. Thermal data from differential scanning calorimetry are also reported. Variables which affect self-heating are discussed and an actual case of heating control on a stockpile by covering is described. A simple apparatus which can be used to simulate stockpiling conditions has been tested successfully and is proposed as a convenient test system.INTRODUCTIONPrevious publications from this laboratory on the evaluation of self-heating in sulphides dealt with tailings backfill (Rosenblum et al. 1982) and waste rock (Rosenblum and Spira 1995). Sulphide concentrates may likewise exhibit self-heating in storage or during shipping. In a comprehensive but dated review, Kirshenbaum (1 968) pointed out the conflicting nature of information on means of controlling the problem, particularly with regard to the application of water and ventilation. Modelling by Simpson (1 97 1) of autogenous heating in stockpiled zinclead concentrate and associated field measurements by Wright et al. (1972) showed that the supply of oxygen by wind and the shape of the piles were the major factors in the development of hot spots. Simpson did not attempt to explain the complex mechanism of self-heating, simply ascribing its onset to oxidation. Pearse (1 980) investigated a potential method of testing for selfheating which consisted of (i) reaction with hydrogen peroxide and (ii) differential thermal anal sis, to characterize the response of concentrates at both ambient and temperatures above 100 C. He found the method sensitive enough to identify the need for careful handling but not to predict ignition. He recommended compacting concentrates and covering stockpiles with plastic sheeting to prevent ingress of air. All these workers recognized the key role played by oxygen and moisture in triggering self-heating."

Jan 1, 2001

By R. L. Guerguerian

Critical fasteners are described as they apply to the specification, manufacture, and assembly on large grinding mill bolted joints. The importance of adequate design methods, related joint diagrams and pivot analyses, and special emphasis on the quality of manufacturing and the tightening procedures in the field, are discussed; all in an effort to ensure high availability plant operation.

Jan 1, 2001

By A. S. Murphy, E. V. Manlapig, C. Green, J. W. Parkinson

Historically in Australia and the United States many coal mines deposited raw wash plant fines into large slurry impoundments. At the time the technology and market economics did not exist to make it viable to recover coal from these tailings. Today better technology exist to dredge and clean the tailings and there are circumstances where government regulations and market forces have come together to make coal recovery from these old tailings impoundments economically viable. This paper discusses the processes and equipment being used in tailings impoundment reclamation operations in Australia and the United States, and discusses the economic forces driving these operations.

Jan 1, 2001

By B. Comley, M. C. Harris

There is as yet no accepted method of predicting flotation frother performance in plant processes based on laboratory scale characterisation techniques. This paper investigates the use of dynamic surface tension, using the maximum bubble pressure method, as a means of evaluating frothers and frother mixtures. An adsorption model is presented, which has been used to quantify the role of frother type and concentration during frother bubble interaction, based on the correlation of model parameters to physical frother characteristics. This approach was found to provide useful insight with respect to blending and selection of flotation frothers to meet specified flotation performance criteria.

Jan 1, 2001

By J. C. Willett, J. R. Sanfilipo, P. D. Warwick

The U.S. Geological Survey has conducted an assessment of the Nation’s coal deposits that potentially could be mined during the next 30 or more years. For the Gulf Coastal Plain region, the assessment includes reviews of the stratigraphy, coal quality and resources, and coalbed methane potential of the Cretaceous, Paleocene, and Eocene coal deposits in the region. The results of these efforts are a series of digital maps, text, and tables published in CD-ROM format. Although abundant coal resources are available in the Gulf Coast region, coal quality issues may limit large-scale development in the future. Additional data are required to better evaluate the coalbed methane resource potential for the Gulf Coast region.

Jan 1, 2001

By H. R. Bullis

"Abstract- This paper discusses what appears to be a flaw in the current belief, widely held within the gold mining industry and investment community, that the creation of ever-larger gold mining companies is desirable for mining companies and investors alike. The basis of the flaw is in the underlying assumption that very large gold producers can discover or acquire new gold deposits of the size necessary to replace extracted reserves on a year-on-year basis over the intermediate to long term (i.e., five to ten years and longer). As it will be noted in this paper, deposits of the size required to replace annual production of very large gold producers (VLGPs) are relatively few in number. Although discoveries of new gold deposits continue to be made, they are predominantly in the 0.5 to 2.0 million ounce range. Data represented here suggest that, although gold production from individual VLGPs continues to increase, the change is due to merging or acquiring other companies or projects with similar reserve life profiles. Therefore, the reserve life profiles of VLGPs have remained flat or have decreased.The paper will note recent changes in the industry and the remarkable increase in gold production reported by individual mining companies over the past several years. It will provide an overview of the geographical and geological distribution of known gold deposits and the range of deposit sizes. Finally, the paper will discuss the challenges that face large gold producers in replenishing their reserves that are being depleted at an ever-increasing rate. Unless otherwise stated, all production and reserve data have been taken from company documents in the public domain or publicly available information."

Jan 1, 2001

By M. C. Roberts

As nations advance through various stages of economic development, the patterns of demand for minerals change. For example, as a nation develops from a subsistence economy through industrialization and into a service based economy, the use of minerals is at first low, then grows rapidly, and finally stabilizes. The past trends in the use of agricultural minerals by the currently advanced nations provide a pattern that the world as a whole may follow as it progresses through the stages of economic development. Future needs for agricultural minerals are estimated using this approach.

Jan 1, 2001