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By Nobuaki Sato

For the recovery of uranium from spent nuclear fuel, sulfide reprocessing process, which consists of voloxidation, selective sulfurization, and magnetic separation or selective dissolution steps, are proposed. In this paper selective sulfurization of rare-earth oxides in the presence of uranium oxides was studied by thermogravimetry and X-ray diffractometry. In case of the mixture with UO2, the rare earth oxides R2O3 (R=Nd, Eu, etc.) were preferentially sulfurized by CS2 formingoxysulfides and sulfides, while UO2 remained at temperatures lower than 500 °C. When R2O3was mixed with U3O8, first, the reduction of U3O8 to UO2 occurred at low temperatures followed by the sulfurization of R2O3. The separation of rare earth elements from UO2 in suspensionsolution by the use of permanent magnet was examined. The advantage of the proposed process was also discussed by compared with current process.

Jan 1, 2006

By M L. van Kampen

The recent (2005) amendments to the Resource Management Act 1991 have made it clear that there is no obligation on an applicant to consult. However the importance and value in consulting with the community, particularly before commencing a major project, cannot be understated.   This paper looks at the provisions of the Resource Management Act as they relate to consultation and public participation in the process, and will discuss the benefits of consultation both before an application is filed and following the filing of the application. Engaging with the local community can help shape a project to better fit the community, engender support and address opposition. In short, taking the extra step to what is legally required, can help smooth what is potentially a bumpy road. Examples in practice of the value of consultation are given.

Jan 1, 2006

By Olga Frank-Kamenetskaya

The experimental results of study of atmospheric corrosion processes on Saint-Petersburg bronze monuments surface, received in situ and by means of simulating experiments, have been discussed. Influence of the time factor on corrosion film (patina) mineral composition has been analyzed. Direct dependence between patina mineral composition and environmental conditions has been proved. The sequence of patina phases crystallization has been established. Effect of the chemical composition and heterogeneity of artistic bronze and also monument surface structure on the rate of corrosion process has been regarded. The time variations of mass of the crystallized in the hydrochloric acid vapor phases have been investigated. The kinetic laws of their development at the initial stage of formation, indicating simple (non chain) reactions, have been revealed.

Jan 1, 2006

By Gábor Csicsovszki

We have developed a novel method - at the laboratory scale - comprising an ion-exchange separation and a membrane-electrolysis step for the purpose of zero-waste regeneration of spent HCl pickling liquors originating from hot-dip galvanizing of common steels. It is aimed at the parallel regeneration of HCl and iron. Experiments revealed that iron can be electrodeposited at high current efficiencies by maintaining the following conditions: 0.04-0.08 M HCl, 500-1000 A/m2, 20°C and stationary electrolyte in a conventional cell. Zinc in the solution did not disturb the deposition of iron, however it contaminated the product and it poisons the anion-exchange membrane required to tackle acidity during electrolysis. For a preliminary separation, anion-exchange tests were carried out to produce pure iron solutions. Beyond the equilibrium studies, column experiments were carried out showing that low flow rates of the loading solution and the ~1.5 M HCl eluent are essential for separation.

Jan 1, 2006

Electrochemical measurements are presented on electro-deoxidation of silica in molten calcium chloride at 900°C, with porous silica pellets as starting material. Measurements during pre-electrolysis (to remove water from the melt) showed electrochemical noise, which is consistent with the evolution of hydrogen. Throughout, the dominant anodic reaction appears to be CO2formation, based on the observed potential at the anode, and measured anode wear. Because of the presence of dissolved CaO in the melt, some of the CO2 candissolve in the melt; the resulting calcium carbonate formation was confirmed by electrolyte analysis after reduction runs. Reduction of dissolved CO2 at the cathode is likely to contribute to the background current during the reduction process. For the electrode and cell configuration used here, most of the over potential arises from polarization of the anode, and ohmic potential drop in the electrolyte.

Jan 1, 2006

By Paul D. Tomlingson

World class performance is the ultimate objective of many maintenance organizations. It marks the organization as a leader in its industry and sets it apart as the ultimate achiever. But what is a “world class” standard and how can it be achieved? Is there a yardstick by which an industrial organization can measure the relative performance of its maintenance activity and compare it with performance levels that universally identify “world class” status? Are there financial formulas, achievements, evaluation techniques or indices that provide this yardstick?

Jan 1, 2006

By Ishwinder Grewal, Michael Fullam

Many factors affect the overall performance of a gravity circuit beyond that of the primary gravity recovery device. It is critical to examine the gravity circuit in its entirety in order to determine the dominant operating variables that affect overall performance. Knelson has developed a mathematical model which has been used to assist in the design of gravity circuits, and in particular, in making accurate predictions of plant scale gravity recovery. More recently, inclusion of recovery by particle size class and additional data from various mine sites and research studies has made the model more robust. The model is now able to predict GRG (gravity-recoverable-gold) recoveries using various devices such as centrifugal concentrators, shaking tables, jigs and flash-flotation within the grinding circuit. The benefits derived by these recent advancements in modeling capability are two-fold; the first is as a tool to assist in circuit design and correct equipment selection and the second is as an analytical tool to help to evaluate and enhance the performance of existing gravity circuits.

Jan 1, 2006

By Hanlong Liu

The construction process and load-bearing behaviors of Cast-in-place Concrete Thin-wall Pipe Piles are analyzed based on its application on Yan-Tong Expressway project. The low strain test, static load test and field excavation are also carried out. It can be concluded that the new type of pile is convenient to construction with high bearing capacity and reliable quality, which has great potential in practical engineering.

Jan 1, 2006

By William R. Yernberg

The 2006 North American Tunneling (NAT) Conference was held June 10-15, 2006, in Chicago, IL. The biennial conference was the first NAT conference by the newly formed Underground Construction Association of SME (UCA of SME). The UCA of SME was formed earlier this year at the request of members of the American Underground Association (AUA) (ME, April 2006, page 75). The conference included a keynote session, technical programs, workshops, a trade show and social activities. The conference exceeded expectations with 570 attendees. They included engineers, equipment manufacturers, representatives from government agencies and other interested individuals in the underground construction industry. The trade show was also a success with more than 86 booth spaces sold. Vendors included the biggest names in the underground construction and tunneling industry and included equipment manufactures, construction contractors and engineering companies. The trade exhibition provided a forum for interested parties in the tunneling industry to meet and discuss services, equipment and techniques.

Jan 1, 2006

By M. Hagfors

Underwater explosions have been used several decades for the determination energy content of explosives. It’s the only test method by which shock and gas heave energy values can be determined separately. The total energy is a sum of these two partial energies. This test method enables us to develop explosives for different purposes; the military high explosives should contain more shock energy whereas the gas heave energy is a very important feature for the blasting explosives. The method also enables us to observe the changes and to adjust the energy content of an explosive as a function of increments of one or more energetic component.

Jan 1, 2006

By J. A. Rusnak, M. M. Gadde, S. S. Peng

In situ stresses are one of the key inputs to a successful underground excavation design. Because of the complex mechanisms involved in arriving at the current state of stress at a point in the Earth’s crust, often the only reliable way of estimating in situ stresses is by actual measurement. In the United States coal mines, overcoring relief method is by far the most popular technique used for estimating the virgin stress field. Typically, for stress measurement with overcoring, a vertical borehole is drilled into the roof or floor of an underground coal mine opening to a certain distance and change in borehole diameter is monitored at multiple points along the length of the hole when this borehole is overcored. For the measured stresses to represent the pre-mining stress field, the measurement points should be located beyond the influence zone of the mine opening. Actual data from several US coal mines have been collected to check if the measured stresses by overcoring represent true in situ stresses. The data indicate that most of the stress measurements were within the excavation influence zone. A three-dimensional numerical modeling methodology was applied to one of the collected cases to correct the measured stresses for the excavation influence. The modeling approach demonstrated the usefulness of integrating numerical modeling into a stress measurement program to estimate ‘true’ in situ stresses.

Jan 1, 2006

By William F. Anderson

A series of pile load tests (maintained load tests, constant rate of penetration tests at different rates, and statnamic tests) was carried out on an instrumented model pile installed in clay beds prepared by consolidation of a slurry in a calibration chamber. The total load, shaft resistance and end bearing during the pile load tests were investigated. Following this, alternative methods of deriving the static load-settlement curve from a Statnamic test in clay taking into account damping effects have been proposed. These methods have then been used to interpret a statnamic test on a full size instrumented pile installed in a stiff glacial till.

Jan 1, 2006

By C. Braun, C. Kennedy, P. Katsabanis

A series of small scale tests, simulating multi-hole blasts have been performed to establish the effect of delays on blast fragmentation. The blasts were performed in high quality granodiorite blocks, which were cut from stone prepared by dimensional stone quarry operations. The pattern used was equilateral triangular, with a distance of 10.2cm between boreholes, which had a diameter of 11mm, were loaded with detonating cord and the coupling medium was water. The delays used were achieved using different lengths of detonating cord for the cases of delays between 0 and 100 microseconds between holes and a sequential blasting machine firing seismic detonators for larger delays up to 4ms. All fragments were collected and screened. The experiments showed that the coarsest fragmentation was achieved with simultaneous initiation of all charges. Fragmentation became finer with delay time between holes up to 1ms between holes. The results show that in moderate to competent rock, similar to the granodiorite of the experiments, fragmentation optimization requires delays of few milliseconds per meter of burden. In view of the findings, which agree with previous published work, the current trend of selecting fast firing times for fragmentation optimization is questioned.

Jan 1, 2006

By Holger Cordes

X-ray diffraction has long been used for qualitative and quantitative mineral analysis but Rietveld data analysis is still an under utilized method for mineral exploration and processing applications. In this full-profile approach the structural parameters of each mineral phase, together with experimental parameters, are refined by least-squares methods to minimize the difference between observed and calculated diffraction patterns. The result is a standard-less, quantitative analysis of the mineral abundance in the sample that is more accurate and considerably faster compared to traditional methods. The TOPAS software package combines a user-friendly interface with a unique approach to resolve overlapping peaks. Automated analysis options are also available and significantly reduce analysis time for routine samples. Several examples on a wide range of naturally occurring rock types are shown that illustrate the capabilities and limitations of the method. The examples include several options for the quantification of amorphous constituents like volcanic glasses.

Jan 1, 2006

By David B. George

Kennecott Utah Copper adopted Outokumpu Flash Smelting and Kennecott-Outokumpu Flash Converting in 1995, a process based on granulating high grade copper matte. While nickel mattes and very small quantities of copper matte had been commercially granulated for years, no large scale copper matte granulation system had been built. This paper summarizes the history and benefits of copper matte granulation, the Kennecott design basis, the successful operation for over 10 years and potential problems inherent in some matte granulation approaches.

Jan 1, 2006

By Javier Rodriguez

Adaptive re-use of existing structures in urban environments has become very common due to lack of available space in our cities and requirements for increased structural capacity. Often, it involves retrofitting existing foundations to support increased loading. In such cases, Engineers face the need to review existing deep or shallow foundations for their true load carrying capacities in order to determine the required magnitude of retrofit work, if any. To accomplish this, the engineer must track down and cull through the existing construction documentation to determine what was actually constructed, complete an investigation to confirm these conclusions, possibly sample the foundation elements for strength properties, and on occasions complete non destructive or full scale load testing of indicator elements. This paper describes the typical procedure followed by the authors for design of retrofit schemes for existing buildings in the Washington DC metropolitan area. Three case histories are presented that illustrate various issues encountered during design.

Jan 1, 2006

By Peter Moser, G. Reihholf

Holcim, one of the world's leading suppliers of cement, aggregates and concrete, has set up a few years ago a working group “Quarry” in order to optimize the performance of its central European quarry operations in terms of work safety, environmental standards and economic performance. One of the activities of this working group "Quarry" addresses the subject of blast fragmentation in the quarries. A benchmark study of the blast work in all quarries has shown substantial differences for the various operations in terms of drill& blast costs. Especially big differences were found with respect to the drilling patterns as a function of the borehole diameters and with respect to the utilization of the borehole volume for charging the explosives.

Jan 1, 2006

By R. Hardy

LaModel is a boundary-element program capable of calculating the displacements and stresses in thin bedded deposits such as coal, salt, or potash. Throughout its history, it has continually been upgraded in order to expand analysis detail and stay current with the latest advances in computer technology. The most recent enhancements include: an increased grid size capability, a significant increase in the speed of the automatic grid generation using an AutoCAD visual interface, implementation of subsidence-based horizontal strain calculations for multiple-seam situations, and pillar safety factor calculations. To demonstrate these new features, a multiple-seam case study of a longwall panel undermining an active set of main entries is presented.

Jan 1, 2006

By Rebecca Hardy

The escalating demand for coal, in addition to the steady depletion of reserves, has produced increasingly difficult mining conditions for coal mining companies within the United States, resulting in mining above or below previously mined areas. The safe and productive extraction of coal in a multiple seam environment requires specific design technology for effective mine planning. Presently, one of the most useful design approaches for multiple-seam feasibility analysis is using numerical modeling techniques. Therefore, numerical modeling programs LaModel 2.1 and Lam2D were used to determine the feasibility of mining the Herrin (No. 6) coal seam over an existing room-and-pillar mine in the Springfield (No. 5) coal seam in the Illinois Basin.

Jan 1, 2006

By Khaled Morsy

In the past two decades, high horizontal stress has been attributed to many ground control failures. Most believe that entries parallel to the high horizontal stress is most stable and least stable when perpendicular to it. Entry stability decreases when the angle between entry and horizontal stress increases. The concept of 2-D stress shadow has been proposed for selection of proper panel orientation, often with mixed results. In this paper 3-D finite element modeling was used to analyze the stress distribution at the headgate of a longwall panel subject to high horizontal stress at various angles. It was found that the directions of induced principal stresses at the longwall face and headgate are independent of the panel orientation. The induced principal stresses concentrate or relief at headgate based on the panel orientation with respect to the directions of the induced principal stresses. Accordingly, only 3-D modeling can fully account for the effects of high horizontal stress on panel orientation. The paper illustrates in details the changes in orientation and magnitude of all three principal stresses around the longwall face and T-junction area as panel orientation changes.

Jan 1, 2006