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By A. Ansari

Standard depressants used in the selective separation of copper and molybdenum sulfides by flotation pose environmental and health hazards. In this investigation, the floatability of chalcopyrite and molybdenite in the presence of six well-characterized lignosulfonates was studied through Hallimond tube flotation and adsorption tests. The results define the physicochemical conditions (lignosulfonate type and dosage, pH, presence of ions) for possible selective separation of molybdenite from chalcopyrite. Dissolved polyvalent cations, especially calcium, appear to serve as "activators" for lignosulfonate adsorption on both minerals. From this point of view, the use of lime as a pH modifier is not always appropriate for optimum selectivity since high dosages of lime to produce high pH tend to indiscriminately depress both sulfides.

Jan 1, 2006

By R J. Worland, D Bowyer, J L. Mauk

The TerraSpec is a compact field portable mineral analyser that uses non-destructive reflectance spectroscopy for mineral identification. The instrument uses and measures infrared and visible light that is absorbed by certain covalent and molecular bonds (AlOH, FeOH, MgOH, CO32-, OH, H2O and NH4) within the lattice of a mineral at specific wavelengths producing an absorption spectral profile. A variety of minerals can be detected including clays, micas, carbonates, and hydroxides as well as some sulfates and silicates. However, not all minerals are detectable, such as quartz and feldspar. Alteration minerals replacing volcanic rocks have been studied for several epithermal prospects in the lower Waitekauri Valley (Sovereign, Jubilee, Scotia and Jasper Creek) and a geothermal field in the Taupo Volcanic Zone. At the Sovereign, Jubilee, Scotia and Jasper Creek prospects previous XRD investigations determined well developed clay mineral zonation with illite in the west (Sovereign and Jubilee) grading into interstratified illite-smectite (Scotia) and smectite (Jasper Creek) to the east. Although the percent of illite within interstratified illite-smectite could not be determined and some illite-rich illite-smectite (>90 per cent illite) and some smectite-rich illite-smectite (>90 per cent smectite) could be misidentified as illite or smectite respectively, the TerraSpec survey determined the same zonation of illite to illite-smectite and smectite. Common chlorite, rare calcite and local kaolinite were also detected. At the geothermal field, the TerraSpec was primarily used to determine the occurrence of kaolinite, dickite and alunite, which form in acid conditions. Widely spaced (every 50 to 100 m) XRD results are in excellent agreement with closely spaced (every 5 to 10 m) TerraSpec results that further determined the occurrence of these minerals in previously unrecognised intervals. It also determined the occurrence of zoned smectite, illite-smectite, illite, and chlorite alteration. Overall, the TerraSpec is a rapid mineral identification technique that is very useful in delineating the occurrence and distribution of certain minerals in both epithermal deposits and geothermal fields. Although the TerraSpec cannot detect as many minerals as XRD, the TerraSpec allows data collection at a sampling scale and speed (real time) that is not practical by XRD.

Jan 1, 2006

By Dennis R. Dolinar

Screen material in the form of welded wire mesh and geogrids are used in underground coal mines to prevent the fall of small pieces of rock from the roof between roof bolts. Further, if the screen is installed during the production cycle, roof fall injuries can be reduced significantly. Therefore, the National Institute for Occupational Safety and Health (NIOSH), because of the safety implications, conducted an evaluation of screen materials commonly used in U.S. coal mines to determine their support characteristics and identify the parameters that could affect their performance with respect to controlling the fall of rock from the roof surface. To evaluate the load and stiffness characteristics of the screen, a test frame was designed and installed in the Mine Roof Simulator (MRS) at the NIOSH Pittsburgh Research Laboratory (PRL). With this test set up, the screen is bolted at four corners of the frame and a center load is applied. The test set up allows for up to 20 in of screen deflection while the load and screen defection are continuously recorded. A series of tests were conducted to evaluate the effects of various parameters such as bolt tension, the type of load bearing surface and the size of bearing plates on welded screen performance. The most common screen material used in U. S. coal mines is an 8-gauge wire welded in a 4-by-4-in spacing or aperture. The peak screen load was normally limited by wire breakage. The conditions at the bearing plate influence the nature of the wire breakage. However, the screen stiffness was controlled by slippage at the bearing plates, and by weld and wire failure. The size of the bearing plate had a significant effect on the performance of the welded screen. Therefore, the design capacity of the 8-gauge screen is evaluated based on plate size. For a 6-by-6-in bearing plate the average peak load is 2,900 lb with a stiffness of 250 lb/in. For an 8-by-8-in bearing plate, the average peak load is 4,500 lb with a stiffness of 430 lb/in. These test results are based on a 4-by-4-ft bolt spacing. A geogrid mesh was also tested.

Jan 1, 2006

By P. A. Olubambi

The leaching of zinc and copper from Nigerian bulk sulphide ore with sulphuric acid in the presence of hydrogen peroxide was studied. The aim of the study was to investigate the effectiveness of hydrogen peroxide as an oxidant for the sulphuric acid leaching of zinc and copper from a complex sulphide ore. Distribution of elementals within the various particle sizes was initially determined by ICP-OES and XRF to provide a basis for explaining the dissolution process. The effects of concentration of hydrogen peroxide, particle size, stirring speed, and leaching time at a constant temperature of 298K were studied. There were variations in elemental and mineralogical composition within the different sizes. The concentrations of zinc and copper reduced as particle size decreased while silica, sulphur, iron and lead contents increased. Dissolution results showed that the leaching rate of copper was lower than that of zinc. The highest recoveries of zinc and copper were obtained at a leaching time of 180 minutes, stirring speed of 160 rpm, particle size of 75 µm and a concentration of 1M H2SO4/1MH2O2. It was observed that the leaching rate of zinc and copper increased with increasing hydrogen peroxide concentration. Increased stirring speed had a negative leaching effect as it promotes hydrogen peroxide decomposition. Keywords: Nigerian sulphide ore, zinc, copper, hydrometallurgy, sulphuric acid, hydrogen peroxide.

Jan 1, 2006

By Rolf Schillinger

Blasting activities on the surface or underground necessarily involve the most sensitive aspect of environment remediation, human response or annoyance. Such effects are unavoidably characteristic of those activities. For this reason, blasting activities are governed by law and official regulations under surveillance of authorities, where companies and explosives engineers have to proceed within proper limits. Subject of the paper is a practical way of handling some necessary vibration standards being focused on blasting activities. The paper is based on the German Standard DIN 4150, Part 1 - 3, “Vibration in buildings”, Part 1: “Prediction of vibration parameters”, June 2001, Part 2: “Effects on persons in buildings”, June 1999 and Part 3: “Effects on structures”, February 1999.

Jan 1, 2006

By Leigh Freeman

This article provides an overview for a series of leadership development workshops offered through the SME Young Leaders Program. The first of these workshops, “Accelerated Development Plan,” will be held at the upcoming SME Annual Meeting in St. Louis, MO on Sunday, March 26. How does a foundation of technical competencies relate to the development of social competencies necessary for management and leadership roles in the resource sectors? Technical competencies provide the foundation for a successful career. Social competencies provide the framework on that foundation. Successful leaders will be those who develop competencies in all areas.

Jan 1, 2006

By W. Bullen

A hypothetical economic model has been developed for diamond projects in the Canadian Arctic using data from recent exploration and mining projects. The model reflects economic conditions applicable to the diamond mining industry in the Canadian Arctic at the present time. The economic model captures pre-production expenditures, production data, and post-production costs. Before- and after-tax cash flows are derived from the data along with the relevant economic criteria. From the corporate perspective, the model provides guidance concerning the minimum size and/or in situ value per tonne requirements of targets being sought in order to ensure economic success and predict exploration and development expenditures. From the government perspective, the model provides an indication of income and mining tax revenues that can be expected from a particular diamond project. The model shows, on average, diamond projects in the Canadian Arctic are expensive to explore for and develop, but are economically robust under the present conditions. They generate great economic return for mining companies and significant amounts of tax revenue for governments. The fact that diamonds can be transported directly from the minesite by air makes them particularly attractive targets for mining companies that operate in the Canadian Arctic.

Jan 1, 2006

By Paul J. Axtell

Two new railroad bridges in Kansas City, Missouri are founded on drilled shafts embedded into the soil and underlying shale. The uncertainty arising from the non-homogeneous, anisotropic nature of most shales, and the variability of shales across the U.S., makes it a difficult material to assign appropriate design properties. As was the case on this project, the uncertainty of foundation performance in shale can lead to overly conservative designs, particularly with drilled shaft foundations. An extensive Statnamic axial testing program was performed to verify that the load-settlement behavior of the drilled shafts would be acceptable for the intended railroad traffic. Axial Statnamic testing was applied in three increasing cycles of 927 kips, 1007 kips, and 3177 kips, respectively. The maximum movements recorded at the shaft head during each of the loadings were 0.052 inches, 0.062 inches, and 0.257 inches, respectively. The loads applied in each of the respective Statnamic tests were not sufficient to reach the capacity of the shaft; so direct comparison of measured and calculated capacities is not possible. However, evaluation of the estimated design capacity can be accomplished based on results from the Statnamic testing program by utilizing normalized load transfer relations presented by O?Neill and Reese (1999). Such comparisons necessarily require extrapolation of the data measured in the Statnamic tests following typical load-displacement response. Results indicate the Kulhawy and Phoon (1993) method for estimating side resistance in Pleasanton shale rock sockets, assuming a smooth socket, appears to agree well with observed behavior during Statnamic testing. Accordingly, the O?Neill and Reese (1999) method for estimating the toe resistance in intermediate geomaterials, assuming cohesive rock with Rock Quality Designation (RQD) between 70 and 100, appears to agree well with observed behavior during Statnamic testing. Finally, based on Statnamic testing at varying load magnitudes and normalized curves developed by O?Neill and Reese (1999), the contribution of side resistance to the capacity of a deep foundation can be determined assuming no load is transferred to the base of the foundation during lower magnitude testing. Furthermore, higher magnitude testing can provide a means to evaluate the accuracy of design end bearing calculations.

Jan 1, 2006

By Jose L. Garcia

The following document aims to cover all issues concerning the three main methods employed for the in-situ survey of concrete pile integrity. Within it are described both sonic coring and low-strain tests and the frequency and time domain analysis of their results, which are the most advanced techniques currently in use in Spain. The survey techniques described were developed and began worldwide deployment in the 1960s, but it was not until the 1980s that they saw large scale implementation in Spain, largely thanks to the miniaturisation of electronics and computer equipment that made them easier to use on-site. Sonic coring, echo and frequency-response testing or mechanical impedance tests are spreading further every day. However, there appears to be a need for standardisation of the testing methods, as well as their implementation, interpretation and the presentation of results. The goal of these Spanish recommendations is to serve as a guideline for test standards and to provide examples for a correct and commonly agreed interpretation of test results, as well as settling any differences in the evaluation of defects detected in foundation works.

Jan 1, 2006

By J. G. Wiese

Reagents are added to the flotation process of Merensky Reef ores to achieve specific functions that enable the separation of valuable minerals from gangue minerals on the basis of the difference in their surface properties. However, due to the complexity of the process, the various interactions that occur as well as the incomplete liberation of the ore and range of minerals present, it is difficult to quantify the behaviour of each of the reagents. More specifically, changes made to achieve a particular outcome may have secondary effects that can override the desired effect. If all the effects and interactions can be accounted for, it is possible to manipulate reagent suites and obtain better overall metallurgical performance. This paper discusses the effect of the addition of copper sulphate at different operating points of the recovery of the sulphide minerals. Batch flotation tests indicated that the recovery of chalcopyrite was not affected when operating conditions were varied, whereas pentlandite recovery was strongly affected by the point of reagent addition, and pyrrhotite recovery was enhanced by copper sulphate addition, irrespective of the point of addition, with the extent being dependent on the ore source. Floatable gangue was activated by copper sulphate in the presence of the dithiophosphate collector. Froth stability was also affected by copper sulphate addition.

Jan 1, 2006

By Natalya. N. Ankusheva

The problems of ore-bearing palaevolcanic structures in folded belts are actual because of their high productivity in nonferrous, ferrous and noble metals ores. Now relationships of location and conditions of formation for sulfide-massive and gold-bearing deposits are investigated very well in Urals. But carboniferous sulfide-barite mineralization, for example the barite veins in Arcaimsky palaevolcano are?nt studied enough now [3-5]. The purpose of this research is the studying of mineralogy and thermobarogeochemistry of barite from the hydrothermal veins. It will allow to determine the conditions of its formation and to compare it to the similar mineralization of others ore types.

Jan 1, 2006

By M. J. King, A. Weissenberger, W. G. Davenport

Keywords: Pyrometallurgy, sulphuric acid, sulphur dioxide The raw material for sulphuric acid manufacture is clean SO2 gas. It comes from (i) burning molten by-product sulphur; (ii) roasting or smelting metal sulphide concentrates, and (iii) decomposing contaminated organic chemical process sulphuric acid catalyst. Efficient gas cleaning is required for metallurgical and contaminated acid decomposition gases, especially the former. Sulphuric acid is made from SO2 gas by (i) oxidizing the SO2(g) to SO3(g) in contact with supported liquid-phase catalyst then (ii) reacting the resulting SO3(g) with the water component of 98.5 mass% H2SO4, 1.5 mass% H2O acid. This paper discusses the reasons for these process steps and indicates how acidmaking can be controlled and optimized. Special emphasis is placed on SO2(g) oxidation efficiency and how it is influenced by feed gas composition, feed gas temperature, catalyst composition, catalyst bed pressure, number of catalyst beds, and double versus single contact acidmaking. In addition, a review of various other treatment methods for SO2-bearing gases is provided. A brief description of each process is included along with commentary on their technical and economic applicability for use at metallurgical facilities.

Jan 1, 2006

By T. J. Snell

Bolnore Village in Haywards Heath, Sussex, England, is a large development covering 8 to 10 hectares and expected to provide 1500 homes in five phases to assist in the continuing demand for new homes in the London area. Part of the development required housing on a relatively shallow slope found to have deep seated failure planes which are fairly prevalent in this part of Sussex. Locally the slope angle was around 20 degrees but more typically the gradient was 6 to 7 degrees. There were significant concerns about slope stability and bearing capacity due to pre-existing shear surfaces and the complex geotechnical profile. There was some evidence of instability in the form of residual shear surfaces and tension cracks. The development required terracing the site with retaining structures up to 5 meters in height, formation of access roads and foundations of new houses. The developer Crest Nicholson adopted a collaborative approach with consulting engineers Powell Tolner and specialist geotechnical contractor Keller Ground Engineering. The solution consisted of a novel combination of contiguous bored piling, ground anchors, and both block work and timbacrib retaining walls to ensure the geotechnical issues were adequately addressed within the time and cost constraints set by the team. The paper describes the geotechnics of the problem together with the design, practical implementation, and site progress achieved

Jan 1, 2006

Keywords: Pyrometallurgy, Pretoria University Substantial research in pyrometallurgy at the University of Pretoria started in 1980 with the appointment of Rian Dippenaar to the Iscor Chair, a position that he held until 1996, when Chris Pistorius became the leader of this pyrometallurgy group. This paper reviews the main research themes over the quarter-century from 1980 to 2005, as well as some of the industrial developments that have shaped the research approach. The main topics have been the use of electrochemical sensors for equilibrium measurements, ilmenite smelting, steel processing, and reduction.

Jan 1, 2006

The results of a series of physical model studies of the stability of jointed rock slopes carried out some years ago are described. These models were tested under centrifugal loading. Four ?geological? structures were tested; all had the same joint orientations and strengths, but the relative spacing of the joints was different. The results showed that the mechanisms of failure of the slopes varied for the different models, and the gravitational loads at which failure developed also varied. The following conclusions are drawn from the results of the physical model tests: ?the mechanism of slope failure is by progressive deformations throughout the slope ?the ratio of the spacings between the different sets of discontinuities exerts considerable influence on the slope failure ?in the models tested, the intact material strength had no noticeable influence on the stability of the jointed rock slopes(note that for hard rock, similitude conditions indicate a prototype slope height of 300 to 400 m, and therefore intact rock failure might not be expected under simple gravity conditions, i.e. no tectonic stresses) ?rock slope failures are three-dimensional and in general are not amenable to two-dimensional simplification ?knowledge of the orientations of discontinuities in the slopes does not allow prediction of a unique failure surface, nor of a volume of failure. The volume of failure is determined to a large extent by the plan configuration of the slope.

Jan 1, 2006

By Michael I. Brittan, Craig M. Sams

"Economies of scale and the variable characteristics of many large ore deposits have resulted in grinding installations using very large SAG mills fitted with variable speed drives. Low-aspectratio single-stage SAG mills were introduced in South Africa to process the consistent gold bearing Witwatersrand quartzites. Elsewhere, circuits were patterned after the more conventional North American circuits with high-aspect-ratio SAG mills followed by ball mills. This paper provides information on two recent Gold Fields group installations covering both types of SAG mill in large, single-stage applications. While these operations process similar tonnages, the mills represent opposite ends of the aspect-ratio spectrum. The Tarkwa mine in Ghana employs a low-aspect 27’ x 42’ 14MW SAG mill. The St Ives mine in Australia operates a conventional 36’ x 18’ 13.4MW SAG mill.INTRODUCTIONGold Fields is one of the world’s largest gold producers with annual production of approximately 4.2 million ounces. The Gold Fields group has operations in South Africa, Ghana and Australia, along with numerous exploration sites and advanced projects in several other countries. This paper discusses new milling operations in Ghana and Australia.TarkwaThe Tarkwa Gold Mine is located in Ghana, West Africa, approximately 350 kilometers west of the capital city of Accra (Figures 1 and 2). The site conditions are tropical with an average annual rainfall of 1,930 mm and a maximum temperature of around 35°C."

Jan 1, 2006

By Christopher Mark

The first International Conference on Ground Control in Mining opened with the topic of pillar design. Two classic papers were presented, one by Bieniwski and the other by Wilson. Unfortunately, the two methods were so radically different from each other that it was nearly impossible to reconcile them. Adding to the confusion were the many other pillar strength formulas (such as the Salamon-Munro, the Holland-Gaddy, and the Obert-Duvall, just to name a few) that were also available. Little wonder that discussions of pillar design in those days often ended with anguished cries of ?but which formula is the right one?? The past 25 years have seen substantial progress in the science of coal pillar design. Indeed, one testament to the improvement is the relative scarcity of papers on the topic at recent Conferences. Two factors have been largely responsible for the progress that has been made. The first has been the collection of large data bases of actual case histories of pillar performance in a variety of settings, from shallow room-and-pillar mines through deep cover longwalls. These have made possible the development of empirical design procedures that are closely linked to real world experience. The second important factor is the development of sophisticated computer models that can accurately simulate pillar behavior and roof/pillar/floor interactions. Together, these two lines of research have led to a new understanding of pillar mechanics that identifies three modes of pillar failure: ? Sudden, massive collapse, accompanied by airblast, for slender pillars (width/height<4) ? Squeezing, or slow, non-violent failure, for most room and pillar applications (4<w/h<10) ? Entry failure or bumps for deep cover and longwall applications (w/h>10) It is particularly satisfying that the insights gained from numerical models broadly support those obtained from the empirical studies. While far less controversial than in the past, pillar design problems continue to arise. One recent example is pillar design for highwall mining. NIOSH has just released a software package, called ARMPS-HWM, which employs a number of modern pillar design concepts. Since highwall mining web pillars are long and slender, the greatest danger is that of a sudden collapse. ARMPS-HWM suggests two possible prevention strategies, one which concentrates on the SF of the webs, and the other which creates a ?pressure arch? using properly sized barrier pillars. The paper will close with a discussion of some current needs in coal pillar design, including: ? Updating older empirical methods, such as ALPS, where changes in technology (new types of roof support, more demanding ventilation requirements, faster retreat rates) may have made some of the original case histories obsolete. ? Methods for determining site-specific coal strengths, focusing on bedding plane strength and other factors that may effect confinement, as input for both empirical and numerical design. ? Improved methods for evaluating coal pillar performance for environmental issues, such as surface subsidence and hydrologic impacts, which consider such factors as depth, w/h ratio, water immersion/drainage, and time dependent seam strength.

Jan 1, 2006

By L. Mabiza

Keywords: Pyrometallurgy, circular furnace, PGM, platinum, Peirce-Smith converter, Zimbabwe The Zimplats Smelter, located on the northern part of the Great Dyke, at the Selous Metallurgical Complex, is the only PGM smelter in Zimbabwe. Zimplats? operations currently consist of the Ngezi Platinum Mine, which is a 1.5 Mt/a open-cast and 0.7 Mt/a underground mine, and a Concentrator and Smelter to which ore is transported 80 km by road. The final converter matte product is transported to Impala Refining Services in South Africa for refining and marketing. The Zimplats Smelter operations consist of a concentrate filtration plant, a Drytech flash dryer, a modified Elkem / Hatch 13.5 MVA circular furnace, two 10? x 15? Peirce-Smith converters, and a matte granulation plant. The Zimplats smelter uses a three-field electrostatic precipitator, supplied by ELB-Brandt, for removal of particulates in the gas streams from both the converter and furnace. Construction of the smelter commenced in 1995, under the BHP / Delta Gold of Australia joint venture. The furnace was lined mid-1996, and smelting operations commenced in 1997. Due to design challenges, the Elkem furnace was modified by Hatch in 1998, and the smelter had not reached full capacity when operations were suspended in 1999. Re-commissioning took place in January 2002.

Jan 1, 2006

By Xiaowen Liu

The thermal decomposition of diaspore was investigated by thermogravimetry (TG),differential scanning calorimetry (DSC), X-ray power diffraction(XRD),infrared (IR)spectrain this paper. The thermal decomposition mechanism of diaspore was discussed according to Coat-Redfer equation. It was found that the decomposition of diaspore was carried out at 500?,and the peak temperature was 530?. The electrovalent balance of diaspore was destroyed. The previous crystal structure was changed. a- Al2O3 was obtained after thermal decomposition. The activation energy is 287KJ/mol.

Jan 1, 2006

By Qing Bo

In this study, the cobalt oxide precursor was prepared in open-style reactor in the condition of high reactant concentration, and then the precursor was decomposed to obtain the cobalt oxides (Co3O4). The effects of some factors on the cobalt precipitation, the particle size and size distribution, and the micro-morphology were addressed. The factors studied include cobalt concentration, initial pH of solution, temperature and time for the reaction, the charge amount of urea, and the temperature for decomposition. It is determined that the precursor particle is in the chemical composition of Co2(OH)3Cl with fine crystalline. By calcinations under proper conditions, the mono-dispersed cobalt oxide particles were prepared with fine crystalline, about 2 µ m in particle size and regular shape in morphology.

Jan 1, 2006