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By A. J. Rigby

The wear mechanisms of the tuyere lines of Peirce-Smith and Hoboken converters are a subject of endless debate and speculation. However, there has been an indication that one of the primary factors in the deterioration of tuyere lines is due to the batch operation of the converting process. The cooling of the brick in the tuyere line during out-of-stack times leads to shrinkage of the brick and resultant opening of the joints. Subsequently, on re-entry of the tuyere line into the bath, the joints become penetrated with matte and re- expansion of the brick is prevented. It is thought that this regular cycle of exiting the batch for slag skimming and replenishment of matte and re-entering for further blowing leads to a gradual “ratcheting” of the tuyere brick lining. If no expansion allowance is furnished between the endplate and the endwall of the lining, then the generation of damaging compressive stress is unavoidable. INTRODUCTION It is generally accepted industry-wide that the integrity of a refractory lined vessel is determined by an inextricable combination of refractory brick quality, the caliber of the lining design and installation, and the severity of the process inflicted upon the high wear areas of the vessel lining. Rigby has summarized the concentrated attempt, over the past several years, to optimize the microstructural, chemical, and fracture properties of the refractories used in non-ferrous pyrometallurgical vessels. Furthermore, lining design concepts involving larger and longer brick and the extent and positioning of expansion allowance in the joints have been extensively trialed. All these efforts have provided some, but not startling, improvements. The simple fact is that a vessel lining composed of bricks with an optimized microstructure and chemical inertness must installed with a well-conceived design to decompress the lining stresses that are generated by the batch operation of copper converters. REFRACTORY QUALITY Converting is conducted by injecting air into the molten matte and white metal for the very purpose of generating iron and copper oxide slags. These slags must be contained by a refractory which, by its mineralogical formulation, is optimized for chemical inertness.

Jan 1, 2019

By S. Konetschnik, Lux Degel, R. Degel, T. Haslinger

UrbanGold and its partners from Mettop and SMS group have developed a novel technology for the recovery of valuables from all non-ferrous metals’ fractions of WEEE (Waste Electrical and Electronic Equipment), with a special focus on low qualities which are commonly landfilled or incinerated. The technology is marketed under the brand name “UrbanGold Flex” to illustrate the high flexibility in respect of plant design and raw material portfolio, allowing also the processing of low grade material and materials with high caloric values. The process of the technology’s centrepiece, a modified and enhanced bath smelting furnace called “HENRI”, was investigated in numerous pyrometallurgical trials as basis for a scale-up towards a capacity of up to 100,000 tons of WEEE-concentrates per year. All relevant facility components have been evaluated in respect of references, fall-back options, as well as exit strategies (alternatives) to minimize risks when establishing a novel technology. A spin-off within the development is the “UrbanGold Compact” technology which can be seen as optimization of state-of-the-art smelters by using an optimized TBRC as primary processing unit. As an UrbanGold Compact plant will be the first industrial scale reference of UrbanGold’s technologies, it is also explained in the publication. As precious metals recovery is of major (economical) importance when recycling WEEE, major attention has been given to minimize the losses of these valuables. These measures, as well as a sophisticated way of utilizing waste heat as far as possible, result in interesting business cases with gross profits of up to 20% or even more. INTRODUCTION Over the past years, the demand of electrical and electronic equipment has increased dramatically with technological progress. Innovations on the technology of electronic devices led to a shorter usage and lifespan and thus boosted the generation of Waste Electrical and Electronic Equipment (WEEE). WEEE is one of the fastest growing waste streams, growing at 3 to 4% per year worldwide and is expected to reach more than 52 million tons per year by 2021. Currently, about 45 Mt of these wastes are estimated to arise worldwide, and the trend is rising (Baldé et al., 2017).

Jan 1, 2019

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami

Blasting is the main method of production in many non-coal underground mining operations and produces multiple toxic gases as a result. The Mine Safety and Health Administration (MSHA) requires mine operators to measure the level of toxic gases in mines as frequently as necessary to ensure they are below regulatory safety limits. The current practice uses portable gas monitors to check the concentrations of toxic gases after a fixed post-blast time. This paper studies the application of a gas monitoring system in the return entry of a limestone mine to determine a safe re-entry time. The National Institute for Occupational Safety and Health (NIOSH) conducted such a monitoring program in a limestone mine from September 2016 through May 2018. NIOSH/PMRD (Pittsburgh Mining Research Division) is endeavoring to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions. This study showed that the use of gas monitoring in the return air can be a useful tool at the mine operator’s disposal to detect and reduce the risk of hazardous conditions and also to reliably estimate the re-entry time. INTRODUCTION Underground miners are at risk of overexposure to toxic gases from various sources. Production blasting operations using explosives in underground mines are a source of multiple toxic gases that could be harmful and even fatal to humans if prolonged exposure occurs beyond the safe limits. According to Code of Federal Regulations, Title 30, Part 57.5002 [1], metal and nonmetal mine operators must conduct gas, mist, and fume measurements as frequently as necessary to determine the adequacy of control measures to protect miners from overexposure to harmful gases. MSHA will inspect mine operators’ activities to verify the evidence of such measurements [2,3]. Continuous gas monitoring in the return air is an effective way to make sure that toxic gas concentrations at the working areas are kept below the regulatory limits before the return of miners. Toxic gases can enter the mine atmosphere from different operations, such as welding, combustion, and blasting. The main gases produced from blasting are carbon monoxide (CO), carbon dioxide (CO2), nitric oxide (NO), and nitrogen dioxide (NO2). Other gases are produced in small amounts and, therefore, were not considered for this study. Related regulatory and recommended exposure limits of CO, NO, and NO2 gases are summarized in Table 1 [4].

Jan 1, 2019

By Barry Hope, Javier Rico

"Goldcorp’s Hoyle Pond mine has recently completed several projects which have impacted the overall ventilation system. The project includes extending the Fresh Air Raise (FAR) to depth, development of a new Return Air Raise (RAR), and the installation of new sensors and ventilation controls throughout the mine. Two years after the completion of #2 Winze, the mine is ramping up its ore production to 1,300 tpd (up from 1,100). To ensure safe and profitable production, a reliance upon technology has been needed to provide the required ventilation to the work areas according to the mine plan. To systematically assess the mine’s ventilation in real-time, a significant increase in remote monitoring was required. This included installing additional flow, pressure, temperature and gas sensors. The first step in upgrading the existing monitoring was to purchase airflow and differential pressure monitors and install them in key areas of the mine. This paper presents the process of expanding the monitoring capability at Hoyle Pond mine, the selected equipment and the results of the implementation. The intended goal was to improve safety while minimizing capital and operation costs. The monitors were installed in strategic locations to provide immediate feedback on the impact of changes to the primary ventilation airflows. Comparing the available sensor technologies, installing them and systematically monitoring the ventilation served as a first step towards developing a mine wide Ventilation Control System. In addition, the initial state of the monitoring and control system, with final results and the chosen solution for the mine site, are presented. INTRODUCTION The Hoyle Pond mine is located in the City of Timmins, within the Porcupine mining district, Ontario, which has produced more than 70 million ounces of gold since 1910. Currently, approximately 60% of Porcupine Gold Mines gold production comes from the Hoyle Pond underground mine. Mechanized cut and fill and long-hole mining methods are used to extract the ore. The remainder of the ore comes from the Hollinger Open Pit mine. The Dome Underground mine ceased operations in 2017. Hoyle Pond is currently mining at 1820 meters below the surface and plans to go deeper. The average dry-bulb as wet-bulb temperature underground varies according to the depth and surface conditions which has extremes of –40°C in winter to +30°C in summer. The total airflow volume pushed down from surface is 240 m3/s to accommodate the diesel-powered equipment needed for normal operations. In order to improve the quality of air underground a program has been implemented to use diesel particulate filters, starting with the truck fleet and 6-yard scoops, followed by the intention to implement the rest of the functional diesel-powered equipment and eventually move to electric equipment."

Jan 1, 2019

By G. R. C. Pacheco, D. M. Fonseca, R. Neuböck, G. E. Gonçalves, W. Moulin-Silva

Degradation by sulfur gases is an important lining wear mechanism in the copper industry. SO2/SO3 gases infiltrate into the pores of the basic refractory bricks, combine with their raw materials through expansive reactions and significantly modify the bricks’ structure. This study presents a comparison of the corrosion resistance against sulfur attack of different magnesia-based refractories using a simple, low-cost and quantitative method. Recipes containing sintered MgO grains showed lower resistance to corrosion by sulfur oxides compared to basic grades containing fused grains. Chromium corundum grades were used as a reference and showed very good resistance to this corrosion mechanism under the test conditions. The novel test provided relevant results that agree with what is commonly observed during operation and in previous post-mortem studies. This tool could be very useful in selecting refractory grades for the copper industry and predicting their performance. INTRODUCTION Oxidation of matte sulfides during copper production leads to the formation of sulfur oxides, which infiltrate into the pores of the refractory lining and react with the basic oxides below 1000°C to form magnesium and calcium sulfates. This reaction is accompanied by an expressive volume increase, consequent densification of the refractory microstructure and weakening of the brick bond (Malfliet et al., 2013). Thus, corrosion by SO2/SO3 is an important wear mechanism in the non-ferrous industry and the resistance to this compound should be considered when defining refractories for this application. Previous studies on this matter include expensive and complex testing methods involving pressurized SO2 gas cylinders in order to investigate the corrosion resistance of MgO-containing materials by sulfur oxides (Gerle & Podwórny et al., 2016; Fotoyi & Eric, 2011; Fotoyi, 2009; Podwórny & Piotrowski et al., 2008). The current study was based on a test developed by Pacheco & Fonseca (2018) to assess alkali infiltration and aims to provide an evaluation method of the corrosion resistance of refractories by SO2/SO3 in a simple and quantitative manner. This novel test is useful to compare the corrosion resistance of different refractory recipes and properly select the grades that should be employed in the non-ferrous industry. A case study is provided to illustrate the damage caused by sulfur oxides in refractory linings.

Jan 1, 2019

By Chris Dougherty

"This presentation will provide a demonstration of the methodology used in designing a modern shaft and hoisting plant utilizing a review of the challenges faced and solutions delivered for the Elk Creek Superalloy Materials Project (Niobium/Scandium). The development of the design required the review of complex hydrogeological conditions, mine production requirements, demanding capital expenditure (CAPEX) limitations and tight schedules. Through an extensive review of various alternatives to satisfy these constraints, the Nordmin Group (including Nordmin Engineering Ltd.) (Nordmin) was able to define a concept and design that addressed risks to the project, met production requirements, cost and schedule constraints and improved constructability. INTRODUCTION The Elk Creek Project, owned by NioCorp Developments Ltd. (NioCorp) presently, will become Nebraska’s first underground metals mine, built to access the Elk Creek Niobium/Scandium deposit. The development of the design for this facility required the review of challenging hydrogeological conditions, mine production requirements, demanding CAPEX limitations and tight schedules. Through an extensive review of various alternatives to satisfy these constraints, the Nordmin Group was able to define a concept and design that addressed risks to the project, met production requirements, cost and schedule constraints and improved constructability. This paper will review the challenges faced, and solutions arrived at in a demonstration of a methodology used in designing a modern shaft and hoisting plant. THE CHALLENGES Nordmin became involved in the project in 2015, invited by the Feasibility Study Consultant to provide input on estimating and layouts for the new operation. Many of the fundamental decisions regarding mining methodology, water handling and production strategy had been made, and the scope of Nordmin’s involvement was very limited in this first engagement. Following submission of that study in late 2017/early 2018, Nordmin had opportunity to discuss the overall effort, and its many assumptions and challenges, with NioCorp’s project team. The dialogue quickly identified several significant opportunities to improve the project construction schedule and costs along with the mine production profile and operational approach while reducing project risk."

Jan 1, 2019

By Michael L. Free, Zongliang Zhang, Joshua M. Werner

In the copper electrowinning process, short-circuiting between the anodes and the cathodes is a critical problem that changes the current allocation among local electrodes and reduces the current efficiency significantly. Possible reasons for the short-circuiting include the improper alignment of the electrode, bent electrode, and nodules on the cathode surface. In typical tankhouses, there is often a time between shorting and harvesting as well as between shorting and clearing. Therefore, it is inevitable to have short-circuiting affect the operation performance in practical electrowinning operations. However, one key piece of missing data is the actual measurements of the current efficiency as short-circuiting is approached and allowed to continue. Consequently, short-circuiting tests that allow tracking of electrowinning parameters before and after short-circuiting were performed in a laboratory scale Cu electrowinning cell. In the tests, the electrode spacing change, the mass of electrodeposited Cu, the deposition morphology, and the current allocation as well as the current efficiency before and after short-circuiting were studied. Results show that the short- circuiting affects the current allocation and the current efficiency significantly. Moreover, it changes the Cu deposition on the short-circuited cathode and therefore causes problems for Cu electrowinning. INTRODUCTION Electrowinning (EW) is commonly used for copper production around the world, with a rated production from 120,000 to 200,000 tons per year per operation (Wiechmann, Aqueveque, Henríquez, Muñoz, & Morales, 2014). In Cu electrowinning, Cu ions in the electrolyte are reduced on the cathode surface as metallic copper with a DC current, while on the anode, a counter anodic reaction occurs with oxygen gas generation (Werner, Zeng, Free, Zhang, & Cho, 2018; Zhang, Werner, & Free, 2018; Zhang, Werner, & Free, 2018). In copper electrowinning, an average current density of 200 to 400 A/m2 is applied to the electrowinning cell (Wiechmann et al., 2014). As the Cu deposits on the cathode, the distance between anode and cathode reduces and most of the time, short-circuiting forms between some anodes and cathodes in a large tankhouse containing thousands of electrodes, reducing the current efficiency and increasing the energy consumption significantly. The current efficiency in well-run copper EW operations is typically above 90 %. Most of the unused current is wasted through short circuits, stray currents, and by-byproduct formation (Davenport, King, Schlesinger, & Biswas, 2002; Wiechmann, Vidal, Pagliero, & Gonzalez, 2002; Wiechmann, Morales, & Aqueveque, 2010). Usually, in the tankhouse, the short-circuiting increases the current in the involved cathode by up to 1500 A (Wiechmann et al., 2010). Multiple reasons can cause the short-circuiting in the cell, and the most common reasons include the uneven current distribution among cathodes, tilted electrodes, bent electrodes, and nodules formed due to the large deposition roughness. Recognition of this challenge in the Cu electrowinning process has led researchers to perform many investigations on approaches to avoid and reduce the short-circuiting in the cell. A series of research investigations have been conducted to develop and improve a new type of intercell bar for Cu electrowinning (Wiechmann et al., 2002; Wiechmann, Morales, Aqueveque, & Burgos, 2007; Wiechmann, Morales, & Aqueveque, 2009; Wiechmann et al., 2010; Wiechmann et al., 2014). The associated test results show that this new design limits the occurrence and magnitude of short circuits and allows operation at higher current densities. Sandoval, Clayton, Dominguez, Unger, and Robinson (2010) stated several keys to control short circuits, such as maintaining the straightness of the cathode, removing “edge hair” from the cathode starter, and maintaining electrode alignment in the cell. Prengaman and Siegmund (1999) from RSR technologies developed a new Pb-Ca-Sn anode to prevent the anode deformation, thereby reducing the short-circuiting in the Cu electrowinning cell. Although the negative effects of short-circuiting on the Cu electrowinning have been recognized, and various investigations have been conducted to address this issue, the actual measurements of the electrowinning behavior and performance as short-circuiting is approached and allowed to continue are seldom reported. However, in typical tankhouses, there is a time between when shorting occurs and harvesting/clearing are performed. One key factor in determining the harvest time is the frequency of shorting. Consequently, we have performed short-circuiting tests that allow us to track electrowinning parameters before and after short-circuiting.

Jan 1, 2019

By E. Cauda, K. Phillips

"Diesel particulate matter (DPM) exposures are a serious occupational health hazard in underground mines. While the complex nature of DPM makes direct analysis difficult, its primary component, elemental carbon (EC), can be used as surrogate. The near real-time FLIR Airtec monitor measures EC mass based on laser extinction. It was developed for use in underground metal/non-metal mines, and calibrated to the NIOSH Method 5040. Its effectiveness has not been demonstrated in coal mines, however, where coal-sourced EC could produce analytical interference. To gain preliminary insights regarding the Airtec’s performance in the presence of coal dust, experiments were conducted in a controlled laboratory chamber. The Airtec EC results consistently underestimated Method 5040 EC for both respirable-sized and submicron coal dusts. While underestimation of coal-sourced EC bodes well for limiting coal interference for DPM measurement, one key reason for the observed trend was non-uniform coal particle deposition on the Airtec filter. This may be problematic in coal mines where DPM and coal dust occur together in the instance that DPM deposition is also non-uniform. INTRODUCTION Diesel particulate matter (DPM) is an occupational health hazard, and underground miners have the potential for relatively high exposures due to their work in confined environments with large diesel equipment (NIOSH, 2011). DPM is heterogenous and complex in terms of its chemical composition (Birch & Cary, 1996; Noll et al., 2006), but elemental (EC) and total carbon (TC) are often used as analytical surrogates (Birch & Noll, 2004; Noll et al, 2015). EC is the solid “soot” component of DPM, whereas TC also includes particulate organic carbon (OC) (Noll et al., 2007). EC and OC can be measured in filter samples using the standard NIOSH Method 5040 (NIOSH, 2003), and summed to obtain TC. In US mines, TC has been adopted as the analytical surrogate for DPM in regulatory activities. In metal/non-metal mines, personal exposures are limited under 30 CFR Part 57. In coal mines, limitations are made on emissions from each piece of equipment (30 CFR Part 72) rather than for personal exposures. This is because coal dust has the potential to interfere with TC measurements in personal samples. In some other countries, and for non-regulatory purposes in the US, EC is also commonly used as a surrogate for DPM in mine monitoring applications [e.g., see AIOSH, 2013). EC generally exhibits a linear correlation with TC (Birch & Cary, 1996; Noll et al., 2006 and 2007) but unlike TC measurements, which are analytically intensive, EC can be determined more simply using a laser absorption/extinction principle on filter samples (Noll et al., 2013)."

Jan 1, 2019

By Rodrigo Madariaga, Tracy T. Morris

The practice of stripping copper starter sheets from titanium blanks to be used in a conventional electrolytic tankhouse has been around since the advent of Electrometallurgy. Historically it has been done manually, utilizing many people to produce in some cases thousands of starter sheets per day. Some other conventional tankhouses have successfully converted to using mechanical means to strip starter sheets or have made the switch to permanent cathodes and although robotics have been around for quite some time they have not been used to strip starter sheets until recently. The Amarillo Copper Refinery began using robotics to strip several years ago and the details to how this came about and how the robots work will be described. INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting and Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co- products (Marcosson, 1949). Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills and two solvent extraction-electrowinning (SX-EW) plants all in Arizona plus a copper smelter in Arizona and a copper refinery in Texas. Figure 1 illustrates how the copper metal comes out of the ground at the mine and ends up as a refined product at the refinery The copper refinery in Texas is known as the Amarillo Copper Refinery (ACR) and is located in Amarillo, Texas. It was built in 1975 to replace 3 other aging refineries and was designed to produce 550,000 tons (500,000 MT) of refined copper per year using conventional starter sheet technology. At the time it was commissioned it was the largest tankhouse in the world at just under 1/2 miles long under one roof.

Jan 1, 2019

By E. Yan, M. Mankosa, E. B. Wasmund

Mechanical cells are the dominant unit operation in base metal rougher flotation applications worldwide. As economic demand for metals increase, and as the feasible ore grades decrease, the installed capacity of mechanical flotation units worldwide has greatly increased, adding significant capital and operating cost. One opportunity to improve this situation is to use fundamental knowledge to make the industrial flotation process more efficient. A key insight is that the flotation process can be optimized by dividing the processing of the pulp into two distinct fluidic environments; a collection cell where air and pulp mix in a highly energetic compartment, and a low energy gravity separation cell. This is the basis of the “2-stage flotation device” that has been patented by Eriez and marketed under the tradename StackCell™. Two industrial case studies will be presented to highlight the potential metallurgical and commercial advantages of the StackCell. In the first, a train consisting of three pilot scale StackCells (each 0.6 metre diameter) was run in parallel with a train of conventional mechanical cells in a major copper concentrator and benchmarked against a batch Denver test. In the second, the performance of a 3 metre diameter StackCell in a nickel sulfide cleaning application was benchmarked against a batch Denver test. The flotation kinetics observed in the StackCells were 2.4 to 2.9 times faster when compared with the lab Denver test. In the first case study, the kinetics of the StackCell was about six times faster than conventional mechanical cells. It is hypothesized that the efficiency improvement in kinetics is because of reduced “drop-back” during the froth recovery phase, which is reduced because of the reduction in the shear that is present in a conventional mechanical tank cell. This result suggests that a 2-stage flotation system can be used to reduce the working volume of flotation units by five to six times. This would allow operators to significantly reduce the size of their flotation lines for a comparable flotation objective. Some discussion will follow about the scale-up criteria, maintenance and operability issues, comparisons of layout, and possible cost savings. INTRODUCTION The solution that most equipment suppliers have offered to reduce the cost of mechanical flotation equipment over the last 30 years has been to increase the size of the flotation unit cell (Mankosa, 2017). For example, three 100 m3 machines with three smaller motors, mechanisms and control valves could be replaced with a geometrically similar 300 m3 with a larger version of each ancillary component. While there are some efficiencies and cost improvements to be gained by this approach, it does not take advantage of fundamental insights into the flotation process, and it does not represent a step-change in terms of process design or economic benefit for the customer. The advantage of the “bigger is better” approach is that there is past experience of incremental improvements by making cells larger and there is a well-established scale-up method, which allows practitioners to estimate equipment capital costs based on very simple laboratory test- work. A different paradigm, which is gaining interest rapidly is to use a unit operation in which it is easier to optimize the flotation process, which will be described in this paper. This approach is often referred to “2- stage flotation”. Because this approach is new, it is important to benchmark it against existing conventional technology and to demonstrate a robust methodology for sizing equipment and flowsheets. This paper aims to address these issues with two case studies.

Jan 1, 2019

By Gobbs C., J. Lam

"The Eagle East project, accessed from the existing and operating Eagle Mine in the Upper Peninsula of Michigan, is an underground base metal project currently in execution by Lundin. This paper will provide an update on several aspects of ventilation including use of a twin-decline access, innovative airflow crossover arrangement and construction ventilation methodology. Integration into existing mine ventilation systems including construction methodology will also be covered. Performance benchmarks and lessons learned are discussed across these topics.INTRODUCTIONLundin has owned and operated the Eagle Mine since 2013. This hard rock underground mine is located in the upper peninsula of Michigan, USA. High-grade nickel ore is mined using sublevel open stoping mining methods and trucked to surface via haul ramp. The mine, having been in production for four years, is nearing the completion of the initial orebody. A satellite orebody 2,000 meters East of the current workings and approximately 900 meters below surface, was identified that could extend operations until 2023. In 2016, Lundin approved the Eagle East project and construction began in 2017 (Lundin Mining Corporation, 2017).Due to proximity to the existing mine, Eagle East will be both accessed and serviced from the existing Eagle Mine. Ventilation at the Eagle Mine uses two fresh air intakes with direct fired combustion heaters; one at the mine portal feeding fresh air into the ramp and one at a fresh air raise located near the Eagle deposit. The primary ventilation circuit is powered on the exhaust air side, with two 700 hp exhaust fans located at a single return air raise. Underground, fresh air is distributed through the main access decline and fresh air raise (FAR) to the production levels and controlled with mechanical regulators on the exhaust side. The exhaust air is collected through return air raises with a collector/transfer drift on 250 Level and then to the surface through a return air raise (RAR)."

Jan 1, 2019

By S. Litke

Elemental sulfur was stockpiled at the Mount Polley Mine for use as a source of sulfuric acid as part of research into leaching copper from oxide ores, but the project did not proceed beyond an initial pilot- scale evaluation. Since placement, the sulfur has oxidized and some sulfuric acid leached into the underlying rock. The reaction of the acid with these underlying materials has been studied as part of an evaluation of the effects of leachate from the pile. The rock underneath the sulfur pile is composed dominantly of primary and secondary alumino-silicates with less than 1% carbonate (calcite) and iron sulfide (pyrite). In its unaltered condition, the rock is classified as non-acid generating. Conceptually, it was expected the sulfuric acid would be neutralized by the rock to varying degrees resulting in a series of pH-controlled weathering fronts progressing from leached near the contact with the sulfur pile (pH <3), to active neutralization by silicates (pH 4–5), to active neutralization by carbonates (pH >7). The rocks underneath the pile were sampled to determine the extent to which the rocks had reacted and their long-term stability after removal of the acid source. INTRODUCTION When rock is blasted and excavated to facilitate mining ore, it is typically placed and stored on the surface in piles. The resulting drainage may have a neutral to basic pH (i.e., non-acidic drainage) or a low pH (i.e., acid rock drainage, ARD) depending on the mineralogy of the rock being stored in the piles. Acid- base accounting (ABA) can be used to characterise the two types of rock: potentially acidic drainage generating (PAG) and not potentially acidic drainage generating (NAG) (Price, 2009). According to Price (2009), NAG is defined as having an excess of neutralization potential (NP) in the rock in the form of calcium carbonate-like minerals when compared to acid potential (AP), i.e., a Neutralization Potential Ratio (NP/AP = NPR) greater than 2.0, whereas PAG is classified as having an excess of AP (i.e., an NPR less than 1.0). This is a conservative estimate and may be slightly modified depending on the mineralogy at specific mine sites. Rock with an NPR of 1–2 is also capable of generating acid (Price, 2009) and, depending on the mineralogy, may also be classified as PAG. Drainage from PAG material can generate acid immediately, or many years after it has been exposed to surface conditions. Disposal techniques depend on the category (i.e., NAG or PAG) and reactivity of the rock stored in the piles.

Jan 1, 2019

By Huilan Yang, Feng He

This paper intends to introduce the development of copper smelting and converting technologies in China in recent years, with a particular emphasis on the introduction of various continuous converting technologies, and moreover, it analyzes the advantages and disadvantages of those technologies, including their impact on the downstream anode refining from different points of view. INTRODUCTION At present, many converting technologies are used in copper pyro-metallurgical plants in China, including Peirce-Smith (PS) converter, flash converting furnace, multi-lance based top blowing, bottom blowing and so on. These technologies have spanned a wide range of time. PS converter technology has been applied in copper smelters for many years and most of the blister copper have been produced by this technology; flash converting technology has been developed since 1990s and been maturely applied in several plants up until now; top blowing and bottom blowing technologies have been revived in China in the past decade and boast good environmental protection performance, energy efficiency, throughput capacity and short process flow. All of the said technologies have reference operations in treating high-grade matte. As more and more attention is paid to environmental protection globally and copper smelters continuously seek for cost reduction, it is necessary to share those converting technologies, especially those new converting technologies derived in China, with copper smelting practitioners in the world. This paper aims to analyze the advantages and disadvantages of various technologies from a macroscopic view and discuss their actual application effects, current developments and future improvements. BRIEF INTRODUCTION OF VARIOUS CONVERTING TECHNOLOGIES IN CHINA China has seen a rapid development in copper smelting industry in the past 30 years and has become the largest gathering place of copper smelters in the world, most of which are operating with PS converting furnace technology, however, with the increasingly strict environmental requirements of the Chinese government in recent years, the low-level pollution issue and the disadvantage of large gas exhaust amount per unit of copper of converting furnaces are particularly prominent.

Jan 1, 2019

By R. Bryce, T. J. Doughty, K. Stoll

Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Ca6Al2(SO4)3(OH)12•26H2O Ettringite readily precipitates in high pH water and by doing so, removes sulfate from impacted waters. The SAVMIN process, piloted in South Africa, is one method to produce ettringite. In this process, aluminum hydroxide is the aluminum source. The Cost Effective Sulfate Removal (CESR) process is similar to SAVMIN, but uses a proprietary aluminum source instead of aluminum hydroxide. Outotec and Veolia also have their own versions of the process using their specialized process equipment. TWC patented a version of ettringite precipitation using metallic aluminum as the aluminum source for ettringite formation. The benefit of using aluminum metal is that no additional ions are added to the process. At high pH, the raw aluminum corrodes in water causing hydrogen gas generation as the water is chemically reduced. This reaction is shown below:

Jan 1, 2019

By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By Remi Proulx, Ruilin Yang

The effectiveness of presplit in soft or fractured ground is hard to visualize or quantify. There have been many attempts by the blasting community to measure and quantify the effectiveness of presplit blasts. Various methods have been adapted by different researchers, and the results are debatable.

Jan 1, 2019

By Alejandro Rosario, Ricardo González

The restrictions imposed by the Brazilian environmental legislation regarding natural caves lead to a block of substantial amount of mineral reserves. Mining activities can released caves, as long as the company ensures that the activities will not cause any damage to them, requiring profound and time-consuming studies. Since the use of explosives in the mine are potential sources of some damage to any structures, it leads to a deep need for controlling the rock blasting activities. In this context, the maximum charge per delay used in operations close to cave regions must follow some internal blasting assumptions that have been developed during specific tests and mining activities. By the seed wave technique, it is possible to determine the behavior of a seismic wave, which travels through a rock mass and it is generated by blasting a known explosive charge. This technique has proved to be an effective tool because it is able to accurately include the physical characteristics of the rock and different lithologies. This paper discusses about modelling blasting induced vibrations in order to improve caves protection, which surround the mining operations.

Jan 1, 2019

By D. Runnels, A. Allaire, J. Torrealba-Vargas

Data mining and modelling of operational data involves the discovery of patterns in large datasets for future use in benchmarking and plant optimization. The modern pattern of discovery in large data sets involves statistical techniques, machine learning and new visualization tools. Former examples of data mining are revisited and presented in this document. INTRODUCTION A network of enthusiastic and active professionals is currently developing and maintaining several open source statistical software tools (packages) for data analysis (example Rstudio, Orange, Spyder, etc.). The advantages of the open source software philosophy are the fast development and testing of the solutions presented to the community. Books and support are available for each software application. Since each modern work activity generates massive amounts of data, it is attractive to learn and test those available tools considering that we are at the door of the new work revolution coined as “Mine 4.0”. Data mining involves collecting large datasets, the preparation and cleaning of a dataset (term named data wrangling), the uploading of the data to a database program capable of handling big datasets, the development of prediction models and the presentation of the results. Machine learning techniques help to develop mathematical models and algorithms that could be used to improve the performance on a specific task. Mine operations are producing an incredible amount of data each day and the need to analyze those results seems to be impossible due to the lack of time, as well as the lack of skills to investigate the data collected. If we add to this the traditional habit of working in silos, an additional challenge is to consolidate databases from different departments in search of trends that could help to optimize production.

Jan 1, 2019

By P. C. Holloway, M. J. Collins, K. R. Buban

Historically, there has been little incentive to process copper-arsenic concentrates by leaching, rather than via established smelting operations. However, with ever tightening environmental emission standards and more arseniferous concentrates being produced, increasingly sophisticated and upgraded off- gas handling facilities are required in smelting operations, generating greater quantities of challenging metallurgical dust. In this context, oxidative pressure leaching offers distinct advantages. The current state of pressure leach technology delivers high extractions from copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. However, as was shown in an earlier study, copper extractions and environmental leach residue stability are impacted negatively by arsenic levels above 2.5 to 3.0 wt%. In further studies on pressure leaching of copper concentrates, Sherritt has developed process conditions that allow even highly arseniferous (> 7 wt% As) feed materials to be converted into environmentally stable residues, with excellent copper extractions. At the same time, pressure leach residues can be generated that are amenable to silver recovery via direct cyanidation, without pre-treatment by lime boiling or hot curing. The results of pilot plant test work are discussed. INTRODUCTION As the production of copper has expanded over the years, resource exploitation has extended beyond relatively clean, high grade and easily accessible ores, and copper sulphide concentrates increasingly come with higher levels of contaminants, such as As, Hg, Sb and Bi, and lower copper and sulphide sulphur concentrations. However, as concerns on the impact of the emission of such contaminants into the natural environment have mounted, import/export restrictions have made the trading of copper concentrate more difficult, and, in particular, the export of concentrates with greater than 0.5 wt% As; under ever tightening environmental emission standards, these lower quality concentrates can be a significant strain on the off-gas handling facilities in smelting operations. The processing of arsenic bearing copper concentrates is, therefore, an increasing challenge as copper producers seek to exploit more complex mineralization and to extend the life of their operations. In this environment, processing arsenical copper concentrates with high temperature pressure leaching (>200°C) must be considered as an alternative to pyrometallurgical processing. Leaching kinetics for copper minerals at these temperatures are rapid and acid is generated for potential use in heap leach operations. Pressure leaching of copper concentrates eliminates gaseous emissions of arsenic and sulphur, while generating environmentally stable residues, as measured by the Toxicity Characteristic Leach Procedure (TCLP) (Kalanchey et al., 2007). Both medium and high temperature pressure leaching of copper concentrates have also proven themselves technically on an industrial scale (Marsden et al., 2004) with high copper recoveries.

Jan 1, 2019

By David Hanson, Sean Warren, Chaparral Berry

"Coal bumps, also referred to as dynamic failure events or coal bursts (Lawson, Weakley, and Miller, 2016), continue to be a hazard in underground coal mines. While current design methods have significantly reduced the occurrence of coal bumps, they have not been completely eliminated. This paper investigates a correlation between coal compositional components, coal molecular structure, and probability of coal bumps in an effort to deepen understanding of coal behavior in an effort to reduce hazards in underground coal mines.Samples from the Penn State Office of Coal (PSOC) Department of Energy Coal Samples (DECS) were obtained for Fourier Transform Infrared Spectroscopy (FTIR) analysis using the KBr pellet method. Peaks indicative of the coal molecular structures were obtained using spectral integration software. These data, combined with published elemental data, were compared to historic bump occurrence in order to establish a possible correlation. Finally, results based on multivariate analysis of the elemental and FTIR data with bump status as the dependent variable suggest that elemental sulfur and molecular structure can be used as an indicator of bump susceptibility within the sample set considered.INTRODUCTIONThe study of coal requires consideration of multiple variables: percentages of organic and inorganic components, organic component origins, coal age, pore structure, cleat density, elemental composition, etc. Examining coal in situ increases the number of variables, such as coal depth, seam thickness, surrounding stratigraphy, and so forth. This collection of variables influences the subsequent behavior of coal simultaneously, and weighing their relative impact is a challenge for researchers. “A problem never exists in isolation; it is surrounded by other problems in space and time” (Ackoff, 1956). Having a substance such as coal that we know so much about, and yet so little, we have to ask what can be learned.An experimental study using Fourier Transform Infrared Spectroscopy (FTIR) was undertaken to determine if the chemical structure of coal contains information which may lead to a better understanding of triggers or attributes which may, in turn, lead to an increased probability of a dynamic failure event. While a full analysis of the factors driving dynamic failure are beyond the scope of this study, it is possible that a better understanding of the chemical structure of coal will lead to an increased knowledge of its inherent behavior, including its propensity to burst."

Jan 1, 2019