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By G. W. Norval, V. G. Papangelakis, G. A. Moldoveanu

Smelting has been the primary method of treatment for refractory copper sulfide concentrates such as enargite (Cu3AsS4), but the pyrometallurgical processing generates elevated levels of volatile arsenic. The present research investigates a novel hydrometallurgical process of oxidative dissolution of enargite at ambient conditions in the presence of chlorine dioxide (ClO2), a very powerful oxidant generated in solution by the reaction between a strong acid (HCl or H2SO4) and sodium chlorite (NaClO2). The effects of initial oxidant concentration, particle size, agitation speed and temperature on dissolution kinetics and copper extraction were investigated. It was found that a stoichiometric ratio of ClO2:Cu3AsS4 = 9:1 were needed to completely and congruently dissolve the mineral with fast kinetics (<15 minutes) under ambient temperature. The dissolution extent (metal extraction) increases with increasing ClO2 concentration and decreasing particle size of solids, but is not influenced by temperature or agitation speed.

Jan 1, 2014

By John J. Barakso

A summary of geochemical dispersion processes is presented. Secondary and tertiary dispersion of uranium was examined at several uranium prospects in British Columbia. The vertical migration of uranium from bedrock (primary dispersion) through overburden into the various soil horizons, and into snow and plants, was studied, and relationships were sought to explain the dispersion patterns in the secondary and tertiary environments. Soil developments were examined to obtain information on factors affecting the dispersion of uranium in soil profiles and tertiary substances; samples were analyzed for a number of elements. Biogeochemical data indicate that plant geochemistry is a possible exploration aid in areas of heavy overburden owing to the high selectivity of certain plants for specific elements. Some new data on the geochemistry of snow are discussed as a matter of research interest in the tertiary dispersion of uranium. Analytical techniques and problems are discussed, particularly extraction techniques, which must be carefully chosen to give reliable information on uranium dispersion.

Jan 1, 1979

By Pascal Turcotte

_ Introduction _ LaRonde _ Controlling Instability in Haulage Drifts _ Failure mechanism in drifts walls _ Failure mechanism in drifts back _ Field Behaviour of Support Elements _ The ?Hybrid Bolt? _ Conclusions

Feb 1, 2008

By M. A. Perras, M. S. Diederichs

"The Niagara Tunnel Project (NTP) is a 10.1 km long water-diversion tunnel in Niagara Falls, Ontario, which was excavated by a 14.4 m diameter tunnel boring machine. The excavated rock types included limestone, sandstone, siltstone, shale and mudstone. Based on observations and measurements the overbreak was divided into four zones. Approximately half the tunnel length was excavated through the Queenston Formation, which locally is a shale to mudstone. Three of the four overbreak zones were within the Queenston. Zone 1 includes the formations above the Queenston Formation, Zones 2 and 4 are border regimes with little or no influence from St. Davids Buried Gorge and Zone 3 is the area influenced by the gorge. Zones 2 through 4 can be generally summarized as having overbreak as the result of stress induced spalling. Zone 2 marks the transition from slabbing at the Whirlpool contact in the stress shadow to spalling towards Zone 3. The behaviour of Zone 3 is interrupted from the typical high stress behaviour due to the presence of St. Davids Buried Gorge. As the tunnel passed from the gorge the high regional stresses induce spalling, which creates the typical notch shaped overbreak geometry of Zone 4.Three modelling approaches were used to back analyze the brittle failure process at the NTP: damage initiation and spalling limit, laminated anisotropy modelling, and ubiquitous joint approaches. Analyses were conducted for three tunnel chainages: 3+000, 3+250, and 3+500 m because the overbreak depth increased from 2 to 4 m. All approaches produced similar overbreak geometries to those measured. The laminated anisotropy modelling approach was able to produce overbreak depths and chord closures closest to those measured, using a joint normal to shear stiffness ratio between 1 and 2. The back analysis results were able to produce sets of stress and strength inputs for different sections of the tunnel at the transition from overbreak Zone 3 to 4. The back analysis procedure demonstrates the importance of including the anisotropic stiffness in the numerical modelling approach to correctly capture the overbreak geometry and deformations around underground excavations."

Jan 1, 2015

By H. Soto, P. Lacombe, R. del Villar

"During the summer of1989, Les Mines Selbaie, with the cooperation of Université Laval initiated a research project to evaluate the column flotation technology for its concentrator near Joutel, Quebec. The experimental work involved both a 5 cm by 11 m laboratory column and a 45 cm by 10 m home-made pilot unit Amenability tests were conducted using both units on various streams of the plant. Results showed that columns are not suitable for the copper cleaning circuit because the loss of precious metals, associated with the rejected pyrite, overcome the improved copper metallurgy. On the other hand, column testing at the zinc circuit showed improved zinc selectivity.Scale-up testing was&apos;, therefore, conducted on the first zinc cleaner concentrate using the laboratory-size column. The influence of variables such as porous parger grain size, wash water flow rate, airflow rate and froth depth values on column performance was&apos; first assessed. Scale-up parameters were then determined using the optimal operating conditions from the previous tests. Simulation facilitated the determination of the most convenient plant-scale column arrangement.A number of conclusions concerning the experimental determination of scale-up parameters are also presented."

Jan 1, 1993

By R. K. Jonas

Many leading copper and other mineral processors have rapidly adopted advanced controls in last 5-10 years. Almost 600 multivariable predictive controls have been installed in mineral processing, and almost 50% of those are in copper concentrator plants. In most cases, mineral processors rely on 3rd party support to implement these advanced technologies. One challenge facing advanced control user is the selection providers and services for these technologies. The trend has been towards the use of multivariable predictive control and use of technology provider’s services. This paper will discuss status of advanced control, and the merging trends in the mining industry. A review will be presented of how advanced control is being applied in the mining industry over the last decade, and how user challenges are being overcome. Next the emerging uses of multivariable predictive control (such as multi/inter-unit optimization), focusing on the latest trends in concentrator plants. Finally, a review will be made of emerging technology advances in the that can be advantageous to mineral processors. INTRODUCTION Review of advanced control in mineral processing Advanced controls are serving an increasing role to improve processing plant operations and profitability. As advanced control is being installed into more mining processing plants such as copper concentrators, many of these plants are concerned about the selection technologies and vendors to support the installation and maintenance of these controls. In a study by Jonas and Craw (2011), they found that most new users have not had prior experience with advanced controls. It is the author’s experience of almost 30 years in advanced controls that most mineral processers considering advanced controls can benefit from better understanding of the technologies and their support requirements.

Jan 1, 2019

By B. K. Gorain

"As mining has evolved over a century, so are the challenges associated with mining. Mining of complex ore bodies at greater depths is a major challenge requiring high capital and operating costs due to remote locations, high energy costs, water quality and complex environmental issues. In addition, the stakeholder expectations are growing along with challenges associated with highly complex mine permitting processes and changing demographics of mining jurisdictions. The dynamic metals market adds to these challenges impacting the long term development and sustainability of mining projects.These challenges are compelling mining companies to look at various innovations with an integrated approach focusing on meeting the needs of various stakeholders. Mining companies are slowly tapping into some successful concepts that have transformed other industries such as manufacturing, chemical, pharmaceuticals along with oil and gas.This paper provides an overview of various innovations and technology developments in mineral processing that have shaped the current mining industry. A glimpse of the present and future challenges in mining is also presented. An integrated approach to problem solving involving various stakeholders is gaining momentum and this has been reflected in this paper. Various developments that are being pursed in mineral processing focusing on a change in the existing mining paradigm are also presented in this paper.INTRODUCTIONAs mining is evolving, so are the challenges associated with mining. Some of the key challenges are complex ore bodies at greater depths, high capital and operating costs, water scarcity and quality issues, high energy costs, complex environmental issues including tailings management, worldwide constraints on resource availability, more and more elaborated regulations in emerging economies impacting the permitting processes, increasing stakeholder expectations, changing demographics of mining operations with ever-changing cultural or community expectations and the urgent need for a better assessment of project viability, this in very dynamic metals markets impacting the dynamics of mining projects development and sustainability."

Jan 1, 2016

The concept and practices of co-extraction of coal and methane have emerged in recent years to improve coal mining safety and productivity, utilise methane resources, and reduce fugitive emissions in environments that involve multiple coal seams with low gas permeability. The system of co-extraction integrates two previously separate operations of coal extraction and methane drainage. The coal mining operation reduces the coal seam gas pressure and creates strata fractures that enhance gas migration and capture from mine workings and surrounding coal seams. An effective methane drainage operation produces a consistent and quality clean energy product and, at the same time, reduces the methane concentration in underground workings and the methane content and pressure in the adjacent coal seams. This is a significant benefit in preventing gas explosions and outbursts, and promotes a safer and more productive coal mining environment. In addition, the co-extraction with enhanced utilisation of coal mine methane directly leads to a reduction in greenhouse gas emissions. Presented in this paper are key results and outcomes of a major Asia Pacific Partnership project carried out from 2008?2012 by the Commonwealth Scientific and Industrial Research Organisation in collaboration with Huainan Mining Industry (Group) Co. Ltd., to develop and demonstrate advanced technologies at Pansan mine, Huainan, that promote the concept and practices of co-extraction of coal and methane. A comprehensive approach was adopted to assess fundamental strata and coal seam methane conditions during mining, and optimise mining sequences and coal mine methane capture systems. The project has not only demonstrated a practical approach and procedures of advanced co-extraction of coal and methane systems but also delivered significant benefits and outcomes in improved mining safety and efficiency, increased methane capture and utilisation, and reduced fugitive methane emissions at the Pansan mine. The total mine gas drained increased from 25.36 Mm3 in 2007 to 47.0 Mm3 in 2011, and the mine gas utilisation increased from 4.94 Mm3 in 2007 to 21.15 Mm3 in 2011. The improved methane capture resulted in reduced coal and gas outburst risks and methane concentration levels at the mine workings, provided a safe working environment for coal production, boosted the mining efficiency, and eliminated methane related incidents over the last few years at Pansan mine.

Aug 1, 2013

By D. C. Sharpstone

THE Polaris-Taku mine is a new gold property, situated in the far north-west corner of British Columbia. Production was started in November, 1937, at the rate of 150 tons a day, and recently has been increased to 200 tons. The property, which promises to become one of British Columbia&apos;s important gold mines, was developed and brought into production in twenty-nine months after work was started on it as a virtual prospect in June, 1935, by Edward C. Congdon and associates. Inaccessibility, extraordinarily complicated geological problems, and difficult metallurgy retarded development of the property before acquisition by the present interests, an::l, in fact, discouraged two companies that had spent substantial sums upon it from continuing development. This paper is concerned with reviewing the development of the property and describing the principal features of the geology, the mining and metallurgical practices, and the equipment employed. Acknowledgments The writer is indebted to Mr. Edward C. Congdon, President of the Polaris-Taku Mining Company, and to various members of the mine staff for their assistance in assembling the data for this paper. Special thanks are due to Mr. George G. Griswold, Jr., of Butte, Montana, who generously and painstakingly prepared the section dealing with milling and power. Microscopic studies of ores were made by Professors Frank Grout an::l G. M. Schwartz, of the University of Minnesota, and by Mr. Griswold.

Jan 1, 1938

By Bernard Tougas, Franco Chiesa, David Levasseur, Bernard Duchesne

"In the present paper, the optimization of a tilt poured permanent mold will be carried out using filling and solidification modeling. This exercise resulted in 3 modifications of the initial mold design which was based on the foundry experience. The optimization provided a 20% improvement in the yield while increasing the output from 10 to 15 castings per hour.In a subsequent study, the value of the critical fraction solid of AlSi7Mg (A356) alloy was verified by radiographic analysis of the castings produced in the first 5 cycles of a run, which are necessary to bring the mold to a dynamic thermal equilibrium."

Jan 1, 2014

By A. Abadías Llamas, N. Bartie, M. Stelter

Evaluating the economic viability as well as the sustainability of the Circular Economy (CE) system requires a deep understanding of the distribution of all elements, compounds, alloys, materials etc. in flows. In this paper, the circularity of the copper value chain, including primary and secondary processing, is rigorously evaluated. The studied system comprises the metallic copper production from primary sources (from mineral to metal), copper-containing commodity production (copper is mixed with other metals) and copper recycling through secondary smelting to close the loop. This is linked to photovoltaic (PV) panels and battery storage. A simulation model of this system is created using HSC Sim, considering more than 30 elements (and its various compounds), 180 unit operations and 800 flows. From the mass and energy balances obtained through the simulation, an exergy analysis is conducted to evaluate the resource consumption from a second law (entropy) perspective. Additionally, these results are complemented through a Life Cycle Assessment (LCA), the recovery of technology elements and by-products is discussed, while quantifying the losses through the value chain. Through the digitalization of the complete system, a better CAPEX and OPEX understanding of the metal recovery and losses can be obtained, as well as the associated resource consumption and environmental impacts. New flowsheets and technologies can be evaluated. Several scenarios show how the resource consumption and the environmental impacts are affected by the recovery of different materials to produce different products. INTRODUCTION A key challenge of the circular economy (CE) is the linkage and optimization of both resource and energy efficiency of the (renewable) energy infrastructure and the resource cycle depicted by Figure 1 simultaneously. In addition, the CE requires the linkage of all stakeholders as shown by Figure 1. This has been discussed in some detail by Reuter and Bartie (2019) and Reuter et al. (2019). Copper and all its associated technology elements is one of the key enabling metals that is an economical copper colored thread through CE society (Reuter & Kojo, 2014). The Metal Wheel (Figure 2) shows the linkage of and recovery of various elements associated with copper and other carrier metals. This reveals that copper acts as an important carrier metal because of its properties i.e. the wealth of technology elements it carries from geological ores, but also its capacity to act as solvent of valuable elements and thence a key closer of various complexly connected element and material cycles when these technology elements are released during copper refining. The same applies to all other carrier metals of modern CE society as shown for example recently in a lead policy brief (Blanpain, Reuter & Malfliet, 2019).

Jan 1, 2019

By Stefan Boshkov

THE ADVENT of mining at great depth has brought to the fore the question of stresses around mine openings. The many-pronged attack on this problem is certified by the accelerated appearance, in the mining literature, of articles on various topics related to this subject (1). Whereas it may be agreed that we, of the mining profession, have fallen woefully behind in research and the development of an understanding of this important facet of the general problem of mining, it must also be accepted that the analysis of the stresses in a mine structure is usually more complex than is the case in the majority of structures encountered and dealt with in civil engineering. Whereas homogeneity and isotropy are readily acceptable for most metals, such properties are but crudely approximated in rocks. Whereas the external loads on a structure in civil engineering may be readily determined, those on a mining structure are subject to ?conjecture. Whereas the limits of the structure may readily be defined in civil engineering, the boundaries of the mining structure are, in most cases, indeterminate, and subject to intelligent guesswork, at best.

Jan 1, 1956

By J. S. Redpath

Eighty feet of overburden, thirty feet consisting of fine, water-bearing sands, was encountered during the construction of a shaft collar for Chimo Gold Mines Limited at its Louvicourt, Quebec, property. This paper describes the excavation and construction methods used on the project. Open-cut methods, a sheet pile cofferdam, chemical grouting and special blasting methods were used during excavation. Concrete placement was hampered in the lower portion by a heavy water flow, and aided in the upper portion by an unusual method of form bracing. Plant and • pum11ing facilities are also described.

Jan 1, 1966

By T. Takahashi, K. Oyamada, Y. Miyata, T. Isoo

The carbonation reaction of steelmaking slag has been known for many years. However, the size of blocks manufactured from this by-product material has been limited due to the difficulty of achieving a uniform reaction throughout the block. Using newly developed conditions, large porous slag blocks (1.0 x 1.0 x 0.5 m) were produced by car¬bonation of steelmaking slag with the optimum amount of water and supplying CO2 deep into slag powder compacted in molds. The development of these blocks has great poten-tial to solve the problem of slag utilization, for example, by recycling slag in large car¬bonated blocks for artificial fish reefs and seaweed cultivation beds. This paper de¬scribes the carbonation reaction, the new process for producing large slag blocks, and the utilization of blocks in past and recent years.

Jan 1, 2004

By K. P. Plucknett, Z. Memarrashidi

WC-Co ‘hard metals’ are widely used in a variety of industrial applications due to their resistance to abrasive wear, in addition to their high hardness and toughness. However, in contrast to their mechanical properties, the corrosion response of these materials is relatively poor. In the current work the corrosion mechanisms of two WC-Co cermets are analysed, with 10 and 30 vol. % of the Co metal binder, in a 3.5 wt.% NaCl aqueous solution. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential, potentiodynamic polarisation and cyclic polarisation, together with systematic analysis of the post-corrosion solution chemistries using inductively coupled plasma optical emission spectroscopy. The corrosion potential and current density were determined, following Tafel extrapolation, allowing the calculation of the corrosion rates. It is demonstrated that continuous dissolution of the cobalt phase occurs during corrosion, which is a result of poor cermet passivation behaviour, and this response increases with the amount of binder in the cermet.

Jan 1, 2015

By Fathi Habashi

The year 1987 marked the centennial of the beginning of modern hydrometallurgy. On October 19, 1887 British Patent No. 14174 entitled Process of Obtaining Gold and Silver from Ores was issued*. The discovery was made by John Steward MacArthur (Fig. 1), a chemist-metallurgist, supported and assisted by Robert and William Forrest, two brothers practicing medicine in Glasgow. The discovery was made in the basement of their clinic. The process, which became known as the cyanidation process in reference to the alkali cyanide reagent used, immediately received industrial success in New Zealand in 1889 and in South Africa in 1890t. It displaced the chlorination method which had been in use. In 1903 MacArthur was awarded the first Medal of the Institution of Mining and Metallurgy in London1131 - The cyanidation process was responsible for the doubling of gold production in the world in the two decades which followed its first application (Fig. 2). To the modern metallurgist, it may be surprising to think of MacArthur coming across an obscure reagent such as an alkali cyanide as a leaching agent for gold ores. It is the purpose of this paper to discuss the background and the factors that led to this invention, the development of the understanding of the process, and the application of modern technology.

Jan 1, 1999

By Grant Arnold

Le Camp Minier de Matagami est situé dans la ceinture volcano-sédimentaire Harricana- Turgeon appartenant à la Province du Supérieur, sous-province de l?Abitibi, au Québec. Les gisements de métaux de base polymétalliques sont retrouvés exclusivement dans les deux domaines lithotectoniques comprenant l?association basalte-rhyolite (Matagami-Brouillan et Joutel-Raymond). Tous ces dépôts, à l?exception de ceux de Selbaie, sont de type exhalatif et représentent des dépôts volcanogènes à Zn-Cu, typiques de l?Archéen. Le complexe volcanique de Matagami est constitué principalement de deux phases de volcanisme tholéïtique. Les dacites et les rhyolites du Groupe de Watson, représentent la phase la plus précoce et celles-cis sont recouvertes par la seconde phase qui est constituée majoritairement de roches intermédiares à mafiques intercalées d?horizons felsiques, formant le Groupe de Wabassee. Un sédiment chimique sulfuré, la Tuffite Clef, marque le contact et l?hiatus entre ces deux groupes. Cette tuffite est reconnue à la grandeur du flanc sud du camp minier et représente l?horizon favorable à explorer puisque sa déposition a correwspond à une période d?intense activité hydrothermale. Le complexe volcanique de Matagami est limité au nord et au sud par des bandes sédimentaires orientées est-ouest, connues respectivement sous les noms de Groupe de Matagami et Groupe de Taïbi. Le Complexe intrusif de la Rivière Bell, qui occupe la base du Groupe de Watson, est un complexe lité consistant en une séquence stratifiée gabbroïque avec localement des niveaux stratiformes à concentrations d?oxydes magmatiques, la bordure de ce complexe est marquée par la présence d?un horizon granophyrique. Cette intrusion synvolcanique prétectonique, représente probablement la source de chaleur étant à l?origine de l?activité hydrothermale observée dans les roches volcaniques sus-jacentes. Suite à un levé aéroporté, le camp minier de Matagami a vu le jour en 1956 lors de la découverte du dépôt de Mattagami Lake, un gisement volcanogène de 25.6 millions de tonnes. Depuis ce temps, un total de neuf gisements ont été exploités et un dixième, Bell Allard, est présentement en production. En date du 31 décembre 1999, la production historique du camp s?élevait à plus de 41 millions de tonnes. Cette présentation mettra l?accent sur la géologie des récentes découvertes dans le prolifique camp minier de Matagami. Les ressources publiées pour le dépôt Persévérance sont de 947,000 tonnes titrant 19.12% Zn, 1.37% Cu, 32 g/t Ag et 0.40 g/t Au. Deux autres découvertes, Équinoxe et Persévérance Ouest contibueront à la ressource globale. Les trois dépôts sont situés au niveau de la Tuffite Clef même si les roches sus-jacentes ne sont pas celles typiquement observées dans les autres dépôts du flanc sud. Ces découvertes sont le résultat d?un programme d?exploration ciblé et soutenu, démontrant ainsi la possibilité de découvrir de nouvelles ressources même dans les camps miniers comme Matagami qui ont été explorés intensivement depuis plus d?un demi-siècle.

May 1, 2001

By L. R. Hougen

The Falconbridge Matte Leach Process yields high-purity nickel chloride by selectively dissolving nickel from copper-nickel converter matte with hydrochloric acid , purifying the solution by solvent extraction and crystallizing NiCl2 4H2O by further acidifying the purified leach liquor. In the Kristiansand Matte Leach Plant, a granular oxide is produced by high-temperature hydrolysis of the nickel chloride for subsequent reduction to a high-purity granular metal product, designated NICKEL 98. This paper describes the investigation of on alternate route to processing nickel chloride in which high-quality cathode nickel is produced by electrowinning from all- chloride electrolyte. The investigation was made in a pilot circuit containing two production-size electrowinning tanks operated in conjunction with the commercial-scale leach plant.

Jan 1, 1977

By M. H. Pelley

To increase drill fleet capacity and meet increased ore demands at its Carol Lake Project, the Iron Ore Company of Canada initiated a program in 1975 to convert the Gardner-Denver 120 and Bucyrus-Erie 60-R rotary drill fleet from 12 1/4-inch-diameter multi-pass drilling to 15-inch-diameter single-pass drilling. This paper will examine briefly the conversion program , including some tests and results, and examine how the utilization of the 15-inch-diameter blast-holes, coordinated by a comprehensive drilling and blasting program, has improved the drilling, blasting and drilling-plus-blasting aspects of the mine operations, from both economic and operational viewpoints.

Jan 1, 1978

By H. Sipilä, H. Vartiainen, H. Paarma

"The carbonatite massif of Sokli includes several low-grade Nb showings composed of ores and wastes as identified by routine analyses. More detailed lithologic proportions were determined in two orebodies in the Kaulusrova Nb-mineralized area by a careful geological study and by thorium radiation measurement on 10 cm-long drill core cuttings with a total length of 460 metres. The distribution of Nb in eight X-ray spectrometrically analyzed drill core sample intervals (totalling 35.8 m) was determined by analyzing the intervals semi-continuously by an X -MET analyzer. The geological studies suggest that Nb-mineralized bodies are feasible fo r the sorting of are and waste. This was confirmed by the semi-continuous determination of Nb on the X-MET analyzer.IntroductionThe Sokli carbonatite complex is located in eastern Finnish Lapland. The main ore of the carbonatite massif is a regolithic phosphorus ore in the weathered crust. Large-scale geophysical measurements and diamond drillings have also established several niobium showings within the magmatic carbonatites. Owing to the complicated geology of the massif, the niobium showings occur as irregular zones o r areas displaying complicated structure, texture, mineralogy and geochemistry (Vartiainen and Paarma , 1979; Vartiainen , 1980). The tonnages in areas such as this are large but the grades in-situ are low . The most intensely studied niobium showing is the Kaulusrova area.The exploitation of these showings depends on the feasibility of applying a sorting technique to upgrade the feed and to minimize the amount of material to be treated in the concentration plant. These possibilities o n the Kaulusrova area have been viewed by a detailed geological and X-MET an analyzing study."

Jan 1, 1985