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By S Kakara, A Kamaraj, S S. Varanasi, B V. R Mandalika, M B. Shaik

The properties of top slags play a very important role in secondary steelmaking. Fluxes should be chosen based on the ladle furnace (LF) slag requirements like viscosity, melting temperature, sulfide capacity, etc. CaF2 and CaO-Al2O3-based synthetic slags are the most used fluxes in secondary steelmaking to improve slag fluidity and interfacial chemical reactions. CaF2 is obsolete due to fluorine pollution and CaO-Al2O3 based slags have 40–50 wt per cent Al2O3 and 30–40 per cent CaO which is not beneficial for desulfurisation. Yet another drawback is that LF slag disintegrates into fine powder during cooling due to phase transformation C2S (2CaO.SiO2). Hence, there is a need for the development of low melting fluxes with high CaO content and the capability to prevent slag disintegration. The current work studied the effect of 0–9 wt per cent B2O3 on physico-chemical properties and characterisation of LF slags. X-ray diffraction (XRD) analyses were carried out to identify mineralogical phases present in slag and Fourier-transform infrared spectroscopy (FT-IR) analysis was done to understand the changes in bonds of B2O3 added LF slag. The characteristic temperature of slag was determined by a hemispherical method using high-temperature microscopy. Empirical models were used to calculate viscosity, break temperature, and sulfide capacity. FactSage™, ver 8.2 (by GTT-Technologies) simulations were carried out to find the equilibrium phase fractions and percentage of liquid slag at different temperatures. New phases such as Ca11B2Si4O22 and Ca2B3O5 were formed in LF slag with B2O3 addition. Based on the results, 0.5–1.0 wt per cent B2O3 was found to be sufficient to prevent C2S-driven disintegration of LF slag. Also, the melting temperature and viscosity of LF slag were reduced by adding 3–8 wt per cent B2O3 due to the formation of BO3 planar triangular structure and low melting eutectics in slag. Liquid slag started forming at a temperature as low as 800°C when B2O3 is >6 wt per cent. It was found that the sulfide capacity, viscosity, and break temperature of the slag decreased with increasing wt per cent B2O3. Based on the analysis carried out, B2O3 can be a promising fluxing material in secondary steelmaking, for improving the desulfurisation kinetics and valourisation potential of LF slag.

Aug 21, 2024

By Muller GP, van Deventer JSJ

A mineralogical analysis has shown that in the Hartebeesfontein ore studied, uranium is associated mainly with uraninite, sulphides such as pyrite and to a lesser degree carbonaceous material such as thucolite. Little could be learned from the literature regarding the mechanism of flotation of these uranium-bearing minerals. A wide variety of reagents were used so that conditions enhancing the flotation of either the sulphides, carbonaceous material, oxides like uraninite, or combinations thereof, were created. As could be expected, the xanthate based floats gave-better selective recovery of sulphides than oleic acid. A substantial fraction of the uranium is associated with pyrite, so that addition of oleic acid to a xanthate float did not enhance the recovery or grade of uranium. After a pre-leach with sulphuric acid in which the pH and Eh were controlled so as to destroy the uraninite, higher uranium recoveries were obtained for the combined float (xanthate, DTP and oleic) and the DTP float. This was most evident when iron was added before flotation. Roasting, which destroyed the sulphides and thucolite, caused a significant decrease in uranium recoveries. The uranium liberated in this way was obviously not flotable in the same way as the uranium liberated from uraninite. A small amount of iron (2 kg/t) added before milling resulted in slightly higher grades and recoveries of sulphur for xanthate based floats. Higher iron additions had a detrimental effect on sulphur recoveries. Even in the case of oleic acid the addition of small amounts of iron had a positive effect on the recovery of sulphur and uranium.

Jan 1, 1993

Deposition of uranium in the South Alligator river area has been influenced structurally by reverse faulting; and lithologically by carbonaceous shales and sandstones. Mineral assemblages suggest a mesothermal-epithermal epigenetic mode of origin. The ultimate source of the uranium and associated metals is probably in deep seated magmatism which is expressed at surface in the widespread penecontemporaneous vulcanity.

Jan 1, 1968

Although a formal EES was not prepared for the WIM project due it winding down, CRA Ltd has been through the EES and planning scheme amendment process for its demonstration plant. Community consultation was involved with all aspects of this process. The paper outlines the WIM EES consultation program and provides lessons for future community consultation for major projects in regional locations with significant potential to alter the environment.

Jan 1, 1992

By Millen M. J, Rainey S, Sowerby B. D

The control of size reduction in grinding machines and circuits may be enhanced by a continuous and accurate measurement of the particle size of solids in appropriate process streams. This paper presents a brief review of commercial particle s

Jan 1, 1997

The mathematical modelling of rock fragmentation by blasting is one of the most difficult and challenging problems of applied mathematics. Not only is complex mathematics required but there is incomplete understanding of the basic physics and chemistry involved. The possibility of getting the physical basis of a model correct by simple mathematical and experimental procedures is demonstrated for the novel process of fragmenting rock by high-pressure arc discharges. While the importance of obtaining the correct physical basis for a model is emphasised, high-pressure arc induced fragmentation of rock is shown to be a powerful laboratory tool for the study of blasting.

Jan 1, 1990

Underground mine ventilation is now com monly simulated on a digital computer. Such a programme, incorporating natural ventilation has been modified by others to account for methane emission and elevated local tempera- tures. At Wollongong University, the pro- gramme was further developed and extensive interactive graphics incorporated such that any view of the three dimensional mine could be viewed, and superimposed upon that view are areas where a nominated parameter has exceeded a particular value - generally at a nominated time after a particular event and usually a fire/explosion of one type or another. A further programme was developed such that up to 20 'times' could be examined at a particu- lar location after say, a fuel rich fire at some other place in the mine. The output from this programme includes a plot of methane 1, smoke 1, temperature, pressure and air flow versus time - a most useful graphic to observe the limits of safe attendance in a particular Airway.

Jan 1, 1983

By Renwick MT

Two innovative ground reinforcement products have been developed for use in the mining industry. One of these products is a high strength polyethylene (HOPE) bar for use as a rib bolt in underground coal mining and as a corrosion proof tendon in open pit mines. The other product is a cable bolt (Ultrastrand) which demonstrates enhanced load transfer and is available in continuous lengths. Ultrastrand's exceptional in- situ performance and versatility makes it ideal for mechanised installation in both underground and surface mining operations. Details of these products are presented and results from labortaory and field trials are discussed.

Jan 1, 1992

By Williams JK, Bolitho BC

Laverton Gold NL (Laverton) is the first junior Australian mining company to establish a viable mining operation in Indonesia. It successfully commissioned the Rawas plant in Sumatra this year with an average anticipated production of 85 000 ounces of gold equivalent (as gold and silver) per year, a feat of which Laverton is justifiably proud.Working in Indonesia and South-East Asia generally is very stressful for juniors and stretches human and financial resources to the limit - more so than in medium to large companies which can absorb the workload in-house more effectively.

Jan 1, 1997

By S J. Kim, S W. Kim, L Tomas da Rocha, S Jung

Al2O3 has been regarded as a harmful gangue component in iron ore, especially causing reduction degradation in industrial sintering of iron ore. The current study aimed to utilise low-grade iron ore containing high Al2O3 content in sintering process. In order to counteract the adverse effect of Al2O3 on reduction behaviour of iron ore sinter, mill-scale and calcined dolomite were chosen as FeO- and MgO-bearing materials. Firstly, mill-scale was added to high Al2O3 sinter and addition was optimised as 10 wt per cent, then calcined dolomite was added further. Magnetite and magnesio-ferrite were identified as the major phases in iron ore sinter when adding mill-scale and calcined dolomite. As the dosage of calcined dolomite increased beyond 4 wt per cent of in sinter mix, unreacted MgO particles were observed, which is ascribed to the limitation of MgO dissolution into magnetite matrix. Both mill-scale and calcined dolomite were effective in improving compressive load and Reduction Disintegration Index (RDI) of iron ore sinter although its reduction degree was highly decreased. The addition of both FeO and MgO-bearing materials to high Al2O3 sinter has a potential to improve the sinter quality, also contribute to the recycling of industrial by-product. However, the amount should be optimised in views of phase development and deterioration of reducibility.

Jun 19, 2024

By Hall K

The Osborne copper gold mine, 100 per cent owned by Placer Pacific Limited, is situated 195 kilometres south east of Mount Isa. The orebody is broadly categorised into three main ore zones; oxide, transitional and sulphide copper. Copper oxide

Jan 1, 1997

By Flloyd J. M

A continuous oxygen probe,incorporating a SIRO2 solid electrolyte oxygen sensor which measured the oxygen potential of a small volume of gas enclosed above the melt's surface,was constructed and tested. The oxygen potential of iron-silicate slags in equilibrium with solid iron in the temperature range 1250 to 1300¦C were measured continuously for tests of up to 40 hours duration. Results were in agreement with those of previous workers using gas equilibration techniques. Tests on non- iron buffered slags proved unsuccessful due to corrosion of the probe's component in contact with the slag and an alternative material is Required.

Jan 1, 1987

Grey River Gold Mining Ltd commenced dredging alluvial flats in the Grey River Valley in 1989.Previous drilling indicated over 100 million cubic metres of gravels with some 90% of the gold in the bottom 7 metres.The dredge built by Rahco, Spokane, was innovative in a number of aspects but particularly in the fact that a separate ladder with a cutter and pump was used to strip the overburden and a bucketline to mine the gold bearing wash below.Metallurgical studies and exploration were initiated when the project commenced; Leasing and environmental considerations were investigated and action taken.While progress is being made, the operation at this stage is not meeting required production and performance. Main problems have been with the stripping system and wear.

Jan 1, 1990

By Thomas R. J

Following asmallnumberofpollutionincidents involving the death of cattle from ingestion of cyanide that had escaped from gold processing plants, the Queensland Government undertook to develop competent guidelines addressing this problem. These guidelines, "Queensland Government Guidelines on Prevention of Water Pollution from Cyanide Use in Gold Ore Processing", issued by the Department of Environment and Heritage, Department of Resource Industries and Water Resources Commission, cover hydrology and general house-keeping intended to reduce the likelihood of significant impact from a spill or unintentional dis- charge of contaminated material. There are three major advances for Queensland embodied in this Guideline: ò the use of a design approach that gives site specific standards rather than trying to give a multitude of standards broad enough to cover all situations, ò the use of hazard assessment and a "critical period" hydrologi- cal design technique, and ò new monitoring and reporting requirements. The guideline is presented here in a summary form:

Jan 1, 1991

Queensland hosts vast deposits of brown and black coal, significant accumulations ranging in age from Permian to early Tertiary. The great diversity of coal resources in the State to some extent reflects the proximity of Queensland to plate-marginal tectonic processes through much of the Phanerozoic eon. Coal is contained within sedimentary basin fills of four fundamental types; 1. extensional, 2. foreland, 3. strike-slip, and 4. intracratonic. Thick (10 m+) though laterally restricted coal bodies are characteristic of extensional and strike-slip basins, whereas coals of more modest thickness but much greater lateral extent are typical of foreland and intracratonic basins.

Jan 1, 1991

Experience in evaluating grade control at operating mines has shown that a number of similar errors re-occur in diverse settings. These can be broadly classed as technical errors, and procedural or grade contra management errors. Examples of typical errors are presented a; generalised case studies. A brief explanation of why the recommender solution worked is also presented for each case.

Jan 1, 1993

By Phillips D. N, Herbert H. K, Fletcher A. C, Lewis R. K

Quartzite is a common feedstock used for the production of silicon by reduction at high temperatures in a submerged electric arc furnace. Silica fume, formed as a by-product in this process, contains crystalline silica in the respirable fraction. The crystalline silica in the fume represents entrained quartz derived from unreacted quartzite raw material within the furnace. A knowledge of the fragmentation of quartzite feedstock, in response to thermal disaggregation in the furnace, is important in feedstock selection to help minimise (a) the amount of crystalline silica in fume, critical from an occupational health and safety perspective, and (b) impurity levels necessary to achieve the highest possible purity of product silicon. In this study, a series of quartzites has been assessed in terms of the above requirements and correlations drawn between mineralogical and chemical characteristics. Alkaline solubility correlates with grain-size and level of stored strain in the quartz matrix. Grain-size affects the surface area available for attack while stored strain enhances the chemical reactivity of the strained matrix as well as profoundly influencing the disaggregation and microfracturing characteristics of strained grains and, hence, available surface area for chemical reaction.

Jan 1, 1995

By Gostylla W

The economic feasibility of controlled district cross-cut recirculation is examined in this paper with particular reference to the most important mine ventilation network parameters. An algorithm is developed to express the annual cost of recirculation which is then compared to the annual cost of conventional ventilation using the University of Queensland Experimental Mine as a case study. The concepts of resistance ratio and volumetric efficiency ratio are introduced and used to analyse the economic feasibility of controlled recirculation within a mine ventilation network.

Jan 1, 1988

By Fry P. R

Dragline operations have played a major and successful role in coal mining around the world for more than 30 years. Because of this long history, many of the operating draglines are reaching an age where maintenance and downtime costs are prohibitive, and decisions need to be made to either replace or refurbish them.In the current economic climate, refurbishment is a popular choice and this usually involves major structural repairs above and below the roller circle, together with replacement of the roller circle components. Often, the dragline tub is also replaced by a completely new one.

Jan 1, 1992

By Whiten WJ, Narayanan S

Data from ball mills of a wide range of sizes are analysed using detailed mathematical models and non-linear least squares fitting techniques. This analysis reveals that the relative power inefficiency of large ball mills is due to inefficient grinding of coarse (plus 4 mm) particles in these mills. A qualitative physical hypothesis is proposed to explain this behaviour. The results of the analysis can be used to scale up ball mill behaviour, using the mathematical models and techniques developed. A simpler ball mill scale-up procedure is also proposed, and its limitations stated. Laboratory experiments are being conducted to determine the average size distributions of single particles of different ores after breaKage. These experiments can distinguish between the different ores, and it is hoped to use their results to model and predict the grinding of different ores in ball Mills.

Jan 1, 1978