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By M. N. Shetty

LARGE copper whiskers (-100 p) of 11111 orientation were tested in a floor-model Instron testing machine, at liquid nitrogen temperature. (Testing methods will appear elsewhere.) Whiskers deformed by twinning after some initial deformation. A load-elongation curve at the onset of twinning is reproduced in Fig. 1. Twinning was confirmed by taking a back-reflection Laue picture, using a slit colli-mator, which showed distinct splitting of reflections. The tensile stress reached just before twinning is about 1.4 x 107 g per sq cm (-7.0 x106 g per sq cm—resolved shear stress) which drops to 1.2 x107 g per sq cm (-6 x 106 g per sq cm—resolved). This twinning stress is about five to ten times larger than the value for bulk single crystals of copper deformed at 77°K (-106 g per sq cm—resolved). Twinning models based on Cottrell-Bilby's pole mechanism are discussed in detail by Venables.' In the present work a mechanism based on the idea of failure of a Lomer-Cottrell barrier by recombination will be proposed. An L-C barrier may fail either by recombination or by dissociation.3 Fig. 2 provides the necessary information. It shows that the stress necessary to break such a barrier is about 1.8 x 107 g per sq cm by recombination and 4 x 107 g per sq cm by dissociation at 77°K. The twinning stress reached by whiskers is comparable to the stress level required for failure of an L-C barrier by recombination. (Stroh himself points out that his calculations should not be taken too literally.) We consider a segment of the L-C dislocation which has recombined (AB in Fig. 3) over a length to form the total dislocation which then glides in the

Jan 1, 1965

By V. M. Troughton

Large diameter bored piles with grouted bases have been adopted for the foundations of the majority of the buildings at Canary Wharf in London's Docklands, including a deep basement car park. The piles are founded in the Thanet Sand which forms part of London's aquifer where water levels are reported to be slowly rising. A special pile test has been carried out to determine the effects of both the basement excavation and a possible long term rise in the groundwater level on the performance of base grouted piles. These effects were simulated by injecting water around the pile toe and thus reducing the vertical effective stress. In this paper the test layout and procedures are described and the results are presented. The test results showed that the reduction in pile base resistance under increased water pressures was less than predicted by conventional design methods based on vertical effective stress. The end bearing resistance was found to be proportional to the mean effective stress.

Jan 1, 1989

By P. G. Flood

A simplified conceptual model shows how the arc flank to arc fringe areas adjacent to ignimbritic centres form a prospective zone for natural zeolites. Large alkaline lakes that serve as the repository of voluminous ash-fall tuffaceous material provide the ideal chemical setting for pervasive alteration of silicic glass to zeolites. The unusually old age of the Escott deposit demonstrates that any silicic volcanic province that contains low-temperature, unmetamorphosed sequences is a potential zeolite exploration target and that age should not be used as a criterion to exclude potential areas. It has also been demonstrated that heulandite and mordenite, formed by diagenetic alteration of silicic glass, do not always change to analcite and albite through the ageing process

Jan 1, 1991

By N. Sutcliffe

Refractories and slags play a vital role in the production of stainless steel. They are in intimate contact with the steel at temperature, and chemical reactions between the three can and do occur. These interactions can be beneficial, in the case of active tundish and ladle slags, and negative in the case of refractory erosion and slag entrapment. This paper presents the results of both plant trials and laboratory investigations of steel/refractory and slag/refractory interactions. The interaction mechanisms observed are described leading to selection criteria for new refractory products. Keywords: slags, steels, refractories, reaction mechanisms.

Jan 1, 2004

By James D. Nickerson

Thee Brightwater water treatment facilities, currently scheduled to be completed in 2010 and begin operating in 2011, will serve the northern part of King County, WA. The facility includes a new treatment plant and extensive conveyance system consisting of more than 21 km (13 miles) of influent and effluent conveyance tunnels and five portals. The majority of the conveyance system tunnels are mined by tunnel boring machines (TBM) and microtunnel boring machines (MTBM). Tunnel and portal construction is divided into three main contracts. The Ballinger Way receiving portal, constructed under the central tunnel contract, is the terminus for the BT-3 leg of the central contract and the BT-4 terminus of the west contract. The shaft has a 7.3-m (24-ft) finished inside diameter (ID) to accommodate removal of the central project TBM and the west contract TBM and extends to a depth of 66 m (216 ft) below grade through a complex and challenging soil profile characterized by multiple ground water tables. Vinci Grand Projects/Parsons/Frontier-Kemper Constructors (VCFK) was the joint venture team for the Ballinger Way portal. Frontier-Kemper was responsible for the shaft sinking. VCFK evaluated either slurry wall techniques or ground freezing for earth support during excavation of the portal and liner installation. The selection process took into account the vertical depth, cost, past practice, geology, water tables and a 9-m- (30-ft-) thick zone of contaminated soil at the top of the shaft. Ground freezing, which would also act as a hydraulic barrier, was deemed the better option for this project. The contract was awarded to New Jersey-based geotechnical contractor Moretrench. Typically, frozen walls, by design, key into an underlying cutoff. At the Ballinger Way portal, however, the [ ] freeze bottomed out in a substantially thick stratum consisting of predominantly clay, but with some inclusions of permeable soil that indicated significant ground water pressures. To ensure stable conditions at the bottom of the shaft, Moretrench, which also specializes in dewatering, designed and installed a perimeter array of deep wells to temporarily depressurize the permeable soils. The movement of ground water generated by pressure

Jan 1, 2009

By J. Danoczi

Specially designed X-ray machines are used extensively on diamond mines for the recovery of diamonds from ores. These machines are extremely expensive and, at present, there are no reliable methods of determining if the equipment is performing efficiently. The objective of this work was to manufacture translucent X-ray diamond simulants, which would emit varying but known luminescence signals when exposed to X-rays. These X-ray diamond simulants could then be used to determine the efficiency of diamond recovery operations.

Jan 1, 2008

By W. W. Weller

Heat capacities of ferrous molybdate (FeMoO4) and ferrous tungstate (FeWO4) were measured over the temperature range 51° to 298.15° K. Ferrous tungstate has a lambda type heat capacity anomaly at 74° K. The 298.15° K entropies are FeMoO4) 30.9 cal/deg mole and FeW04) 31.5 cal/deg mole.

Jan 1, 1966

By Matthew I. G

A new process for leaching zinc sulphide concentrates with gaseous mixtures of SO2 and O2 in aqueous solution is described.The reaction of SO2/O2 with Rosebery, Mt. Isa, Broken Hill and Elura zinc concentrates yields zinc and iron sulphates, elemental sulphur and some sulphuric acid. Rates of zinc extraction are controlled by a surface chemical reaction without apparent interference from the elemental sulphur layer for SO2 concentrations up to 9 per cent in the gas phase. Pyrite in concentrate exerts an activating effect, possibly through galvanic interaction with the sphalerite. Metal extractions are dependent on SO2 and O2 tenors of the gas, particle size, and the acidity and zinc content of the solution, but are independent of the ferric ion level. Extractions also reach maxima at about 85°C.Generation of acid may be prevented by conducting the reaction in the presence of ferrous iron and at acidities of 40 g/l or greater. Zinc and iron levels in Elura lead concentrate may be reduced by leaching with SO2/O2.

Jan 1, 1981

By Cyril Stanley Smith

IsolatEd alloys of copper and silicon were prepared and examined by chemical methods more than one hundred years ago, but it was not until the work of Rudolfi l that the equilibrium relations were studied. The early history of the alloys was well described by Baradue-Muller 2 and need not be further discussed here. The diagram of Rudolfi, based entirely on thermal observations, showed sillcon to be soluble in copper up to 4.5 per cent. at 849" C., at which temperature there was a peritectic horizontal resulting from the formation of a ß phase with about 7.4 per cent. silicon from a and liquid with 7.85 per cent. silicon. The ß phase was believed to form a eutectic with Cu3Si at 820" C. and 9.8 per

Jan 1, 1929

By Cyril Stanley Smith

IsolatEd alloys of copper and silicon were prepared and examined by chemical methods more than one hundred years ago, but it was not until the work of Rudolfi l that the equilibrium relations were studied. The early history of the alloys was well described by Baradue-Muller 2 and need not be further discussed here. The diagram of Rudolfi, based entirely on thermal observations, showed sillcon to be soluble in copper up to 4.5 per cent. at 849" C., at which temperature there was a peritectic horizontal resulting from the formation of a ß phase with about 7.4 per cent. silicon from a and liquid with 7.85 per cent. silicon. The ß phase was believed to form a eutectic with Cu3Si at 820" C. and 9.8 per

Jan 1, 1929

By F. Bruey, T. Bruce, D. R. Nagaraj, W. Thomas, P. Riccio, E. Guitard

"AEROPHINE® 3418A Promoter is a flotation collector that has been an industry standard in the Canadian mineral processing industry since its first commercial use at the Kidd Creek concentrator in 1980. Its wide range of applications in sulphide mineral flotation has made it successful, specifically in the processing of complex sulphide ores which contain copper, lead, zinc, and silver or any combination of these elements for selective separation.AEROPHINE® 3418A Promoter is a unique, phosphine-based collector originally developed for the flotation of copper sulphide minerals and activated zinc minerals. It is now recognized for its selectivity for complex, polymetallic sulphide ores and porphyry copper ores. In addition, AEROPHINE® 3418A Promoter is highly selective for copper, lead, activated zinc, nickel and precious metals. AEROPHINE® 3418A Promoter exhibits strength yet, selectivity against iron sulphides (pyrite, pyrrhotite, marcasite, and arsenopyrite), non-activated sphalerite, and many minerals which contain penalty elements.This paper outlines a brief history of the product’s development, its historical use in Canada and several potential innovative mineral processing applications with the use of the chemistry. Three Canadian case studies will be presented on various ore types including: a Cu-Au ore, a Cu-Zn ore, and Cu-Pb-Zn ore. A plant production update will also be given on the future supply of AEROPHINE® 3418A Promoter.INTRODUCTIONCytec Industries Inc. operates a phosphine derivatives plant in Niagara Falls, Ontario, that manufactures various products for their speciality chemicals division. The products from this site are based on phosphine (PH3) chemistry and are used in a variety of markets including electronics, agriculture, LED lighting, water treatment, metal extraction, and mineral processing. One of the major products is the phosphine-based sulphide mineral collector, AEROPHINE® 3418A Promoter.AEROPHINE® 3418A Promoter (Figure 1) was originally developed for the flotation of copper and activated zinc minerals (Thomas, 2010).."

Jan 1, 2015

By T Hughes

The Gekko InLine Pressure Jig (IPJ) was unleashed on the World gravity separation market in 1996 and has since sold over 150 units in applications including tin, diamonds, silver, coal, garnet and gold. During the past twelve years the knowledgebase of the best applications and capabilities of the IPJ has greatly increased. Improvements to the original IPJ design have included engineered ceramic ragging in specific gravities from 1.6 to 5.0, full automation and improved designs of feed presentation and tailings and concentrate handling systems. The IPJ has been found to be able to handle a wide feed size range and recover mineral at liberation size without significant addition of water to the mass balance. Test work carried out during full-scale operation of the IPJ has shown the IPJ can recover diamonds down to 0.5 mm, sulfides down to 0.3 mm and gold down to 0.1 mm which greatly expands its application in the mineral processing industry. A significant volume of data now supports the symbiotic benefits of an IPJ and flotation circuit combination to pre-concentrate an ore and minimise downstream processing requirements.

Jan 1, 2008

By Y. H. Zhan

A new P(MAAA) latex was developed and used in separation of ultrafine apatite from calcite and silica by means of selective flocculation. The latex was found to flocculate selectively apatite from apatite/calcite and apatite/silica mixtures in the presence of sodium tripolyphosphate and sodium silicate over a pH range from 9.1 to 9.4. The separation of apatite from calcite was more selective with sodium tripolyphosphate, while the results of the separation of apatite from silica were better when sodium silicate was used. In the apatite/calcite system, 90% apatite recoveries into a concentrate containing 34% P2O5 were possible in the presence of 4 mg/l of sodium tripolyphosphate at a latex dosage of 2.2 kg/t. In the apatite/silica system, 80% of apatite could be recovered into a concentrate containing 33% P2O5 in the presence of 20 mg/l of sodium silicate at a latex dosage of 1.1 kg/t. Deposition tests were used to study the interaction between the latex and the mineral surfaces. The results revealed that deposition density of the latex on apatite was higher than on calcite; the differences between the deposition onto these two minerals were higher at pH 9.2 than at 7.2. The results point to the stronger interaction between the latex and apatite surface when compared with the latex-calcite interactions.

Jan 1, 1998

By Paul Swatkowski

A Note About Copyrighted Material ??Permission to Use? has been granted ?Teachthe7habits ?Think win/win (4thHabit) ?Don?t stop here ?i.e., buy the book

Jan 1, 2009

By Rajni Patel, John McDonald, Steve Dubnewych, Michael McKenna

The Upper Reach segment of the Northeast Interceptor Sewer (NEIS) is a3.2-km-long tunnel excavated in interbedded marine sedimentary deposits with approximately 40 m of cover. The tunnel was initially classified by Cal/OSHA as “potentially gassy.” During excavation, high levels of hydrogen sulfide and methane were encountered, prompting Cal/OSHA to reclassify the tunnel as “gassy.” In addition, the tunnel excavation encountered an abandoned, 100-year-old water tunnel known as the “Narrows Gallery.” This existing tunnel was completely full of water and under 30 m of hydrostatic head. This paper will discuss the unanticipated difficulties and design solutions implemented to construct a gassy tunnel exposed to high volumes of water.

Jan 1, 2005

By K. E. Wood, K. J. DiRocco, L. A. Becker

The Russia Wharf segment of the Silver Line Phase II Project for the MBTA incorporated ground freezing and underpinning during New Austrian Tunneling Method(NATM) tunneling through timber pile foundations, urban fill, and abandoned wharf structures beneath two historic 7-story buildings with steel frames and masonry facades. During construction, the project team implemented an extensive program to monitor, evaluate, and mitigate the ground and building movements caused by the various construction activities. Mitigation included freeze cycling and building raising/lowering to compensate for ground movements and safely maintain the serviceability and occupancy of the buildings. In this paper, we present the history of the freeze, tunnel construction, and thaw-related movements that occurred and the building response that we observed.

Jan 1, 2005

By Sam Yao, Ali Naeem, Sara Barrett

Brooklyn Basin Project is a multi-billion-dollar development of the former Port of Oakland 9th Avenue Terminal located along the Oakland Estuary of California. A centerpiece of the development is the 10-acre shoreline park which will be built on a 1,200 ft long by 225 ft wide historic wharf. The wharf was built in the 1930’s on concrete and timber piles with a flat concrete slab. Prior to constructing the wharf, a rock dike was placed to protect the shoreline. The presence of the rock dike increased the hazards from lateral spreading of the underlying bay mud and non-ductile shear failure of piles driven through the dike. To open the park to the public, the wharf required a seismic retrofit in compliance with the California Building Code. The paper presents the results and conclusions of the following topics: • Structural condition assessment and repair strategies for the existing wharf deck, piles and jackets • Application of the California Building Code (CBC Ch31F) for the performance-based seismic evaluation of existing piers and wharves • Nonlinear pushover analysis of the wharf including the combination of inertial and kinematic effects • Impact of rock dike on lateral spreading and kinematic effects and the significance of existing piles in stabilizing the lateral spreading of the rock dike • Retrofit strategies for the wharf to meet the required seismic performance requirements per the California Building Code and reduce the demands on existing piles which were driven through the rock dike INTRODUCTION The 65-acre Brooklyn Basin Development project is located in Oakland, California. The project consists of 3,100 housing units, 200,000 sq. ft of retail and commercial space, along with various parks and public access improvements along the Oakland Estuary. A centerpiece of the development is the 10-acre Shoreline Park which will be built on a 1,200 ft long by 225 ft wide historic wharf. The wharf was built in the 1930’s on concrete and timber piles with a flat concrete slab. As shown in Figure 1, the wharf deck and piles support the 9th Avenue Terminal Building.

Jan 1, 2018

By Cordner G. D

Titanium is not yet being produced on a commercial scale despite the facts that it has some impressive properties, and that it occurs very abundantly in easily-mined, highgrade oxide ores. One important reason for this is that the excellent mechanical properties of the metal were not widely recognised and appreciated until about twenty years ago.Another factor which has tended to retard progress in titanium metallurgy has been the realization that the oxide minerals of titanium are very stable; in other words, considerable energy has to be expended to reduce the oxide to metal. Table 1 presents the minimum energies which would have to be expended to produce one ton of each of the metals, aluminium, magnesium, titanium and iron from their respective oxides under theoretically ideal conditions at normal temperature and pressure. At higher temperatures, the minimum energy requirements are different, but the values for the various metals still fall in the same order as indicated in Table 1.In actual fact, the energy consumption in the case of any particular metal is higher than the ideal value by an amount which can be determined only by' the results of plant practice. The only general conclusion that can be drawn from the data in Table 1 is that it might eventually prove...

Jan 1, 1950

[Page Minutes 5 Present Status of Petroleum Industry 9 F. M. Van Tuyl. Developments Along the Line of Low Heat, Carbonization 13 A. C. Watts. Uses for Fine and Pulverized Coal 14 C. A. Allen. Have Mining Engineers Accepted All That Developments in Machinery Apply? 16 R. Dawson Hall. Coal Mine , Accidents and State Mining Law 23 D. Harrington. Harmony and Co-Operation 26 H. F. Nash. Personal Dangers 28 John Bevan. Methods of Improving Safety and Health Conditions 29 C. A. Allen and A. L. Murray. The Economic Relation of Accidents and Preventable Diseases to the Coal Mining Industry 39 Recent Developments in the Use of Electricity in Mines 43 Graham Bright. Discussion of Graham Bright's Paper 48 Mine Safety Work at Dawson, N. M 49 W. F. Murray. Mine Safety Work 54 Eli Follett. Wire Rope in Mining Operations 56 James F. Howe. Discussion of F. E. Shepard's Address 69]

Jan 1, 1922

By A. G. Mayton

Vehicle vibration exposure has been linked to chronic back pain and low back symptoms among agricultural tractor drivers. The objectives of this study by the National Institute for Occupational Safety and Health (NIOSH) were to assess driver whole body vibration (WBV) exposures and recommend interventions to reduce the risk of back related injuries, particularly relative to vehicle jarring/jolting (the transient mechanical shock components of WBV). The methodology included collecting, from two independent samples, ?eld data and health and work history data of farm equipment operators. Data were collected during mowing, raking, baling, chiseling, tilling, and road travel for different model tractors. Spraying using a sprayer and shrub removal with a skid steer loader were also included. Based on ISO 2631 (1985), the American Conference of Governmental Industrial Hygienists, threshold limit values, presents 0.5 m/s2 as the action level recommended by the Commission of European Communities for overall weighted total RMS acceleration (vector sum for axes x, y, and z) [ACGIH, 2006. Threshold limit values and biological exposure indices. Cincinnati, OH]. WBV measured at the operator/seat interface exceeded this action level. The roughest rides and highest vector sum accelerations occurred with small utility tractor mowers (3.3 and 2.8 m/s2) and a skid steer loader (1.7 m/s2). Major ?ndings from health and work history data showed 96% of participants reported having to bend or twist their necks, although 24% reported neck symptoms. Sixty four percent of participating operators reported experiencing back symptoms (e.g., pain, aching, stiffness, etc.). Recommendations included: specifying a seat that ??better?? isolates operators from jars/jolts with new tractor purchases; maintaining the seat/seat suspension and replacing worn or damaged cushions with NIOSH tested viscoelastic foam padding; using larger diameter tires with radial ply instead of bias ply construction, particularly on small utility tractor mowers, to aid in attenuating ride ??roughness??; using a swivel seat to reduce the stress on the neck from bending or twisting; and improving efforts to educate owner/operators of the adverse effects of WBV exposures. Since the data presented in this paper were collected from two independent samples, the authors were unable to draw any correlations or etiological inferences from the study. However, results were compared and contrasted with other studies which included similar vibration measurements in agriculture.

Jan 1, 2008