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By Haskiel R. Shell

While the original purpose of the Bureau of Mines work on fluorine micas was to synthesize large single crystals or film suitable to replace natural muscovite or phlogopite, the objective was broadened to include development of the many possible fluorine micas as a class of new, unique materials. Several methods were developed for the synthesis of the fluorine micas at atmospheric pressure: Solid state reaction, melting in crucibles, internal resistance electric melting, and arc resistance electric melting. The latter two methods are now med commercially. A variety of fluoromicas were synthesized by isomorphic substitution including disilicic, trisilicic, and tetrasilicic. Fluorophlogopite, KMg3AlSi3O10F2, is the fluoromica most widely used. While most of the fluoromicas are completely stable to water, many water-swelling fluoromicas and fluoromontmorrilonoids were synthesized. Single crystals or film of the fluorine micas were grown to 2 inches or more by a number of methods, but none has as yet proved economical. In the report, detailed data and descriptions are given on compositions, syntheses, products, and uses, and on the properties including physical, dielectric, chemical, X-ray, optical, and structural.

Jan 1, 1969

By L. D. Tracy

The first study of this subject hits been made in Illinois, but as opportunity affords, similar studies will be made in other States. It is hoped that the data obtained will assist the coal-mining industry to standardize the forms of leases, and so avoid some of the abstruse and ambiguous clauses which slay be found in many of them and the consequent liability of costly litigation. In some of the publications of the Illinois Mining; Investigations prepared under a cooperative agreement with the U. S. Bureau of Mines, the Illinois State Geological Survey and the Engineering Experiment Station of the University of Illinois, the coal areas of the 'State have been divided into eight geological districts, each district being treated separately. This report covers District No. VI of that classification, and it is hopped that studies of the other districts will be completed in the near future and similar results published.

Jan 1, 1926

By Jeffrey Y. Foley

In 1980, the Bureau of Mines investigated the northern Darby Mountains on the Seward Peninsula, AK, for radioactive mineral deposits. Uranium is concentrated in silicified shear zones in biotite quartz monzonite of the Darby pluton. The shear zones are best exposed in steep, narrow, avalanche gullies; they are characterized by radiometric anomalies and by uranium and thorium geochemical anomalies. Radiometric and geochemical anomalies are also found over altered biotite quartz monzonite where there are no visible shear zones. The radiometric and uranium anomalies are often spatially, but apparently not genetically, associated with alkaline mafic and felsic dikes. Similar geochemical and radiometric anomalies over discolored altered zones and geochemical anomalies in sediments downstream from the altered zones indicate that additional areas may also be favorable targets for uranium deposits. Analyses of panned, heavy mineral concentrates show no significant concentrations of uranium or thorium in resistant heavy minerals. This indicates that radioactive elements in the Darby pluton are concentrated in soluble, nonresistant minerals that may constitute a recoverable uranium resource.

Jan 1, 1986

By Peter G. Chamberlain

The surge in gold and silver prices during the 1970's attracted many new mining operators and has rekindled interest among experienced ones. With its low capital investment requirements and fast payout, leaching has attracted many operators--particularly those with small or low- grade deposits. Although in certain situations leaching offers many advantages over conventional mining methods, many operators are uncertain how these relatively new techniques should be implemented. Consequently the Bureau of Mines has prepared this circular to disseminate information on gold and silver leaching practices, techniques, and problem. Engineering data gathered from 26 operations indicate that most ores are leached in heaps following crushing and distribution on pads. Metal values are recovered from cyanide leach solutions using either zinc precipitation or charcoal adsorption. Potential problems that my hamper on block development of a leaching operation are poor percolation characteristics of the ore, calcium salt buildup, low temperatures, and solution losses. An extensive bibliography on gold and silver leaching is appended.

Jan 1, 1984

By Sumner M. Anderson

THE importance of the mineral industries of the Latin American area in 1964 may be evaluated in respect to a number of points of reference, a few of which are measurable and appropriate for examination. With regard to the region's contribution to total world production, it accounted for total 1964 world output of natural nitrates (from Chile), and about 97 percent of the optical and electrical grades of quartz crystal (from Brazil). The region supplied over 20 percent of world output of 7 other mineral commodities and accounted for 4 percent or more of world output of 19 other mineral products. Among major commodities, the area, occupying 15 percent of the earth's land surface, supplied within 3 percent of that proportion of the world's output of copper, lead, tin, zinc, barite, and crude petroleum. Incomplete compilation of production data, particularly that of nonmetallic minerals, precludes production estimates on some items for the area ass whole, and therefore the importance of Latin America as a world producer of some additional commodities may not be clearly assessed. For example, most of the countries of the area collect only incomplete data or no data at all on the production of clays and other ceramic materials, sand and gravel, dimension and crushed stone, lime, ornamental and precious stones, perlite, vermiculite, carbon black, coal tar products, and petrochemicals. In the case of many countries of the area, the value of production of one or more of these commodities greatly exceeded that of other mineral industry products that are carefully reported.

Jan 1, 1966

By Douglas A. Donato

This Information Circular presents the MULSIM/PC system of numerical modeling computer programs developed by the U.S. Bureau of Mines. This system consists of four programs: PREMUL, the preprocessor or mesh generator; MULSIM/PC, the actual numerical modeling program (number cruncher); MUL3D, a three-dimensional postprocessor; and MUL2D, a two-dimensional postprocessor. These programs were specifically designed to operate on IBM-compatible (MS-DOS-based) personal computers for easy transfer of this technology to the mining industry and academia. MULSIM/PC uses a subvariation of the boundary-element method, namely, the displacement-discontinuity technique, for linear-elastic geomechanical analysis of mine plans in one or two parallel underground tabular deposits. Results calculated by this technique include stresses and displacements as they relate to changing mine geometries and materials. In addition to describing the MULSIM/PC program and its features, and providing a detailed example model, this report also documents the associated preprocessing and postprocessing programs that are part of the MULSIM/PC system. User's guides for all the programs are contained in the appendixes following the main report.

Jan 1, 1992

By R. V. Lundquist

The compound 2Na2O?3CaO?5Al2O3 occurs as a minor phase in lime-soda sinters prepared for extracting aluminum from siliceous aluminum-bearing materials. About 99 percent extraction of sodium and aluminum from synthesized 2Na2O.3CaO.5Al2O3 was obtained in solutions of NaOH-Na2CO3 at leaching temperatures of 50° C and above. Extractions in water were low because insufficient NaOH was generated by hydrolysis. Extractions in NaOH solutions were limited to about 80 percent owing to the precipitation of hydrated calcium aluminates. Rapid extractions of 100 percent were obtainable in NaaC03 solutions, but the subsequent rapid precipitation of alumina trihydrate caused losses in alumina recovery.

Jan 1, 1965

By W. H. Lewis

This Bureau of Mines report and its companion report (Information Circular 9073) have been prepared as a complete reference on underground coal mine lighting. This report discusses system design criteria and procedures, data and specifications to aid in selection of suitable mine lighting hardware, and guidelines for system installation and maintenance. Topics include light measuring techniques and instruments, illumination regulations for underground coal mine environments and equipment, lamps and ballasts, available mine lighting hardware, design and evaluation of coal mine illumination systems, and installation and maintenance of a mine lighting system.

Jan 1, 1986

By Carlton E. Brown

Brown and Yant6/ recently described a microprojection method for determining the particle-size distribution and number concentration of samples of dust collected from the air by such samplers as the Owens jet dust counter7/ and the thermal precipitator8/. This method was developed to obviate or reduce the eyestrain consequent to the regular filar-micrometer method9/ and to save time and work. The article stated that work was in progress on a microprojection method for courting impinger dust samples; this article describes the method developed. ACKNOWLEDGMENTS The assistance of the personnel of the Ventilation Department of the Anaconda Copper Mining Co., Butte, Mont., in developing this method and particularly in suggesting a suitable material to use for the microprojector screen is sincerely appreciated. Much of the work was done in the laboratory of the Anaconda Copper Mining Co. on samples collected in Butte mines during a cooperative study with this Bureau.

Jan 1, 1938

By Jay D. Dixon

The Bureau of Mines has developed structural design data for unreinforced concrete tunnel linings for drifts used in block caving stopes. Design data are given that consist of moment, thrust, and deformation coefficients from which bending, axial, boundary stresses, and structural deformations can be determined at any point on the lining. Data is given for circular, horseshoe, and rectangular linings, each with two different thicknesses and subjected to eight different loading conditions for drifts excavated in hard and soft rocks. The structural analyses performed are based on procedures that account for both the structural behavior of the lining and that of the drift and take into consideration deformational interaction that occurs between them.

Jan 1, 1973

By Almon F. Robertson

"INTRODUCTION At various times, North Carolina has supplied small quantities of brown-iron ore to the furnace o the South. Between 1917 and 1920, the quantity reported to the Federal Geological Survey was 126,000 tons. Most of this came from Cherokee County. 3/In furtherance of the program initiated by the Bureau of Mines to develop additional reserve of iron ore during the emergency, the Cherokee County deposits were examined by an engineer 4/ of the Bureau of Mines, and work was recommended on,12 properties.The project was begun in April 1944 and continued intermittently until April 1945, when work was stopped. During this period, eight properties were explored, and an additional property was mapped.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch; Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director."

Nov 1, 1946

By August J. Kwitowski

This report presents the results of a joint Bureau of Mines-U.S. Department of Energy project that evaluated a newly developed low-coal mining system: the 4M miniminer system. The evaluation took place from April through October 1981 and determined potential health, safety, and productivity factors for the mining system using the surface test facilities at Bruceton, PA. The planning, testing, results of testing, and a summary evaluation of the 4M miniminer system are included in the report. The miniminer system was found to be a very good concept with future potential for safe, healthful, and economic production in thin-seam mining. The mining system was also judged to have considerable potential for use in some coal seams that are presently considered unminable by other existing mining equipment. The preproduction, prototype version of the miniminer system that was tested suffered from several safety and production problems. These problems are also described, along with suggested remedies.

Jan 1, 1989

By Michael S. Miller

In 1987, 1988 and 1989, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the Sperry Creek Wilderness Study Area (OR-003-035; 5,600 acres) and the Gold Creek Wilderness Study Area (OR-003-033; 13,600 acres), plus an additional area (OR-003-033; 2,180 acres) adjacent to the Gold Creek Wilderness Study Area. The wilderness study areas and the addition are south of the Malheur River and are about 20 miles east of Juntura, Oregon. The wilderness study areas and the addition are underlain by volcanic rocks, predominantly basalt and rhyolite flows, breccias, and welded ash-flow tuffs. Lacustrine deposits containing diatomites occur mainly at the east side of the Gold Creek Wilderness Study Area and addition. Alluvium lies along the Malheur River, in terraces and fans south of the Malheur River, and along the floors of some creeks. Shear zones and faults have offset the rocks and provided channels for eruption of volcanic rocks and epithermal mineralization by hot springs.

Jan 1, 1989

By Oliver Bowles

"General.The term mica is probably derived from the Latin ""micare"", meaning to shine or glitter, for the brilliant reflection from mica flakes in rocks has directed more than ordinary attention to this group of minerals. Mica includes a group of several minerals all characterized by a perfect basal cleavage, by virtue of which they may be split into exceedingly thin plates. The minerals are of very common occurrence in all countries, constituting about 4 per cent of the igneous rocks of the world The term ""isinglass"" is sometimes applied to glazing mica, but this is incorrect, for true isinglass is a soluble combustible material made from the air bladders of certain fish. As a constituent of granites and schists, mica is present as flakes too small for commercial use. Mica occurs also as small scales in many sandstones. When granites decompose, the quartz and the white mica are the most resistant to weathering, and so remain when the other constituents have been decomposed and carried away. A secondary white mica known as sericite is formed by the metamorphosis of clay-bearing rocks, and thus, in extremely fine-grained form it constitutes an important constituent of slates and related rocks. Some schists contain a high percentage of mica, but the presence of large amounts of quartz and other minerals has up to the present time rendered them useless as commercial sources of mica for grinding. It is possible, however, that certain mica or seri-cite schists which are composed almost wholly of mica with very little quartz may be utilized for ground mica if found in large enough entity. Considerable micais sometimes found mixed with the residual kaolin that results from decomposition of pegmatites, and in one locality at least it has been recovered as a by-product in a clay purification plant."

May 1, 1922

By Donald I. Kurth

This Bureau of Mines report describes the development and application of a computer model of aquifer hydrology associated with in situ leaching of uranium. The model provides uranium resource developers with a simulation of leachant flow characteristics in a preproduction or pilot five-spot leaching operation. Various types of aquifers are modeled using closed form solutions of the partial differential equations describing the change in fluid head (pressure) as the leaching operation is carried out. User-supplied descriptive input consists of aquifer, well, and leachant flow characteristics. Numeric and graphic outputs such as isopressure, iso-velocity, and isotime contours are available. A typical application is shown.

Jan 1, 1978

By P. G. Barnard

The Nation's steel industry is largely dependent on shipments of manganese from foreign sources for steel production. An adequate substitute for the manganese requirements of our present steel technology would improve our national self-sufficiency and also contribute substantially to the conservation of our manganese resources. As each of these objectives is a major interest of the Bureau of Mines, possible substitutes for manganese in steel were investigated. Titanium was selected as the most promising substitute because the published results of several investigations indicate that titanium would perform the most obvious function of the manganese in steel: The elimination of iron sulfide and its deleterious effects. The investigation involved extending the published data on titanium additions in steel to provide enough information for an accurate evaluation of the practical value of the substitute. Therefore, quantitative data were obtained on the partition of sulfur and carbon between iron and relatively small titanium additions.

Jan 1, 1962

By D. Montagna

The Kroll-Betterton process for debismuthizing lead is based on adding calcium and magnesium to impure molten bullion to form solid Ca-Mg-Bi inter-metallic compounds that float on the surface as drosses. Present practice in industry is to hand-skim off these drosses, often followed by hydraulic pressing to squeeze out some of the entrapped liquid lead. In an effort to develop an improved technique, the use of an argon-shrouded dipping centrifuge to perform the required phase separation was investigated. Centrifugation experiments demonstrated that the bismuth content of an impure bullion could be lowered from an initial 0.5 percent down to 0.03 percent with a lead recovery of 90 percent, which is comparable to lead recovery after hand skimming of drosses in commercial lead-debismuthizing operations. Centrifugation provides better control in removing drosses, faster operation with less oxidation and relatively little fuming, and recovery of a lead bullion that approaches commercial specifications.

Jan 1, 1972

By C. E. Jordan

Domestic cobalt resources are relatively large, but low grade. The full potential for cobalt production from domestic sources is at least 19.4 million lb of cobalt per year exclusive of offshore resources. A summary of the cobalt processing technologies for the major domestic resources is presented in this Bureau of Mines report. The processing technologies for the Blackbird, Madison Nine, Duluth Gabbro, iron ore pyrite, laterites, and manganese sea nodules are nearly complete, but the economics are not favorable. Research on these resources should be limited to approaches that promise to cut the total processing costs by at least 50 pct. The most promising sources of cobalt are the spent copper leach solutions and siegenite from the Missouri lead ores. Research on cobalt processing from these two sources needs to be completed.

Jan 1, 1988

Great strides have been made in recent years to reduce the disaster potential of underground mine fires. However, mines can still be caught unprepared for a fire emergency. Fires can grow too large before they are detected, warning systems can be too slow and uncertain to reliably signal the danger, and suppression systems can be inadequate to extinguish the flames. New mining systems and equipment may create unanticipated fire hazards, and new materials may generate highly toxic combustion products. This report contains papers that summarize recent significant developments from the Bureau of Mines mine fire protection research program relating to these problems. Certain of these findings are also applicable to surface mining operations. The papers fall into the general categories of fire detection and instrumentation, fire warning, fire suppression, diesel equipment, spontaneous combustion, and toxicity analysis of combustion products.

Jan 1, 1988

By K. K. Kelley

Synthetic fluorphlogopite mica (KMg3AlSi3010F2) is a relatively new product developed at the Norris (Tenn.) Station of the Bureau of Mines, Thermodynamic data have applications both in the production and use of this product, and the work described in this paper was undertaken to fill the need for such data. Measurements were made of the heat of formation at 298° K., the heat capacity between 50° and 298° K., the entropy at 298° K., and the heat-content and entropy increments between 298° K. and a maximum of 1,804° K. These basic data are combined to obtain heats and free energies of formation of the mica from the elements and from molecular constituents at temperatures ranging from 298° to 1,800° K. Minimum heat requirements to form melted mica from commonly used ingredients were calculated.

Jan 1, 1959