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By J. P. Coughlin

Gypsum plaster is calcium sulfate hemihydrate (CaS04-1/2H2O). There are two varieties, commonly designated as a and ß. The hydration setting) of this plaster involves the chemical reaction: CaS04?1/2H20(c) + 3/2H20(l) = CaSO4?2H20(c); that is, the hemihydrate combines with water to form the dihydrate. Many substances, when present as impurities, either in the hemihydrate or the water have influenced the rate of the hydration reaction. The objective of the Bureau of Mines work described in this report was to investigate the accelerating or retarding effects of small amounts of dissolved substances and to attempt to classify these effects upon a chemical basis. To eliminate competing effects, the work was conducted separately on the two varieties of hemihydrate; both were in highly pure form. (Commercial plasters usually are a mixture of the hemihydrates, with other substances present as impurities.) As the hydration reaction of each variety of hemihydrate evolves heat in amounts known from previous work, 5,6/ the authors decided to use calorimetric methods to follow the extent of the hydration reaction as a function of time. Two calorimetric methods were employed. One was designed to study the hydration reaction with a large water to plaster ratio and the other with a small water to plaster ratio (to simulate commercial practice in utilizing plaster).

Jan 1, 1959

By T. T. Campbell

Studies were conducted by the Bureau of Mines to develop a process for preparing thorium-magnesium master alloys or pure thorium metal by magnesium reduction of thorium tetrachloride in a semicontinuous reactor. Thorium tetrachloride was prepared in a fluidized-bed reactor by chlorination of thorium oxide or thorium oxalate. Conditions were established for producing a suitable thorium oxide feed for a fluidized-bed reactor. Thorium tetra-chloride was purified by vacuum sublimation and subsequently reduced by magnesium in a semicontinuous reactor to form thorium-magnesium alloys. Relatively pure thorium was produced by removing magnesium from the alloys by vacuum sublimation. Close to 100 percent of the thorium fed into the reactor was recovered either as metal (~93 percent) or as thorium oxide (~7 percent). The oxide can be recycled directly into the process.

Jan 1, 1971

By Frank E. Cash

"INTRODUCTION The producing iron-ore ranges in the Lake Superior district are the Marquette and Menominee in Michigan, the Gogebic in Michigan and Wisconsin, and the Cuyuna, Mesabi, and Vermilion in Minnesota. These ranges produce about 85 percent of the iron ore mined in the United States. The accident experience in connection with this production is better than that of the regions producing the remaining 15 percent. Production and shipments vary slightly from year to year owing to stockpiling underground ore during the winter, or nonshipping, season but closely approximate each other over a period of years. This information circular supplements, combines, and continues the data contained in Information Circulars 7321 3/ and 7410 4/, including statistics for 1946 and 1947.Whereas the title ""Accident Experience"" is used for uniformity and logical indexing throughout this report, ""injury"" will be used as a general term to apply to disabilities of all degrees.During the 8-year period 1940 to 1947, inclusive, 619,054,023 long tons of iron ore was shipped from the Lake Superior district. 5/ Michigan and Wisconsin shipped 117,828,939 tons, or 19.03 percent of the total, and employed approximately 9,260 men. Minnesota shipped 501,225,084 tons, or 80.97 percent of the total, and employed an approximate annual average of 12,260 men. The tons produced and shipped per man employed in Minnesota is much greater than in Michigan and Wisconsin, owing to the large open-cut production in Minnesota."

Jun 1, 1949

By Stephen C. Tadolini, Thomas M. Barczak

Roof support systems, longwall shields in particular, have persistently grown in size and capacity for the past 25 years. Why is this? Is it a good thing or is it unnecessary? What are the consequences of this “bigger-the-better” design philosophy? Rarely do we see a “one size fits all” approach to roof support except when it comes to longwall shields, where the historical trend for new procurements is to simply purchase the highest capacity support you can buy. Does high capacity ensure failures will not occur? The answer is no! The highest capacity tailgate supports are typically the ones that fail the most often. What does this tell us? It tells us that there are fundamental aspects of support design and ground control that we still do not understand or recognize when designing a support system. This paper provides an interesting evaluation of these issues and proposes a different approach to support design that attempts to match the support performance characteristics to the ground behavior. Along the way, some of the old premises of support design will be discarded, and new “controversial” ideas developed. Thinking outside the box never hurt any industry. Mining has made it a common practice.

By K. K. Kelley

This work is a continuation of a program of study of the measurement and correlation of fundamental thermodynamic data inaugurated several years ago by the United States Bureau of Mines. Previous bulletins in this series were concerned with (1) The Entropies of Inorganic Substances (66),3 (2) High-Temperature Specific-Heat Equations for Inorganic Substances (67), (3) The Free Energies of Vaporization and Vapor Pressures of Inorganic Substances (68), (4) Metal Carbonates-Correlations and Applications of Thermodynamic Properties (71), (5) Heats of Fusion of Inorganic Substances (69), and (6) A Revision of the Entropies of Inorganic Substances-1935 (70). The present bulletin has as its primary purpose the correlation of the thermodynamic properties of elementary sulphur and its inorganic compounds and the presentation, after careful consideration of all available information, of a self-consistent system of thermodynamic relationships for these substances. It is believed that such a set of relationships, concerning substances of such great metallurgical importance as sulphur, sulphur oxides, hydrogen sulphide, metal sulphides, and metal sulphates, is of considerable value in indicating directions of possibly profitable experimental work and in clarifying subjects of technical interest upon which direct experimental information is difficult and expensive to obtain. It cannot be doubted that many problems of technical importance that at the outset appear almost hopelessly complex or obscure either may be solved, if enough information is available, or the specific lacking information clearly indicated by the adoption of the thermodynamic viewpoint. This has been demonstrated many times in the work of the Metallurgical Division, Pacific Experiment Station, Berkeley, Calif. Even when only crude basic information is available, a semiquantitative picture often may be developed by thermodynamic means in which general trends and approximate limits of a proposed process or modification of practice may be clearly portrayed and thus used as guides in further considerations and experimentation.

Jan 1, 1937

By E. Chin

The countries of Asia and the Pacific, with their large mineral resource base, are significant suppliers of a wide variety of minerals to both regional and world markets. Australia, China, and India dominate the commercial mineral exploitation in the region. Australia has known reserves of major minerals, which are adequate for both domestic demand, and for exports, and is a significant producer of bauxite; copper; diamond; gold; iron ore; lead; manganese; mineral sands (titaniferrous minerals, monazite, and zircon); nickel; salt; silver; tin; uranium; and zinc. China is the world leader in proven reserves of antimony, barite, ilmenite (titanium), magnesite (magnesium), molybdenum, rare earths, and tungsten. China also has large resources of low-grade iron ore and significant resources of other mineral commodities, such as coal, based on its production and export capabilities. India has significant resources of bauxite, barite, graphite, iron ore, and mineral sands.

Jan 1, 1995

By J. P. McGee

A 1,000-hour test with a gas turbine at 1,200° F showed a working fluid of 1 gr of ash per 100 scf of power gas (79 percent of the ash 7 to 35 microns in diameter) to be excessive for acceptable blade wear for commercial practicability. Blades in the turbine consisted of about 20 percent each of chromium, cobalt, and nickel; 3 percent molybdenum; 2-1/2 percent tungsten; and smaller amounts of manganese, columbium, and tantalum. Erosion of both the fronts and backs of the turbine nozzles was particularly heavy, the trailing edges being worn to a featheredge. Erosion of the buckets was less marked, although the leading edges were somewhat pitted. A refractory-lined combustor performed efficiently and with little abrasion of the lining by the ash-laden gas.

Jan 1, 1969

By Anatol Wojtowicz

This research program was conducted to determine if respirable coal dust emanating from a continuous mining machine can be suppressed more effectively by a high expansion foam than by the water sprays conventionally used. A high expansion foam system was developed and tested on a continuous mining machine under actual operating conditions. The utility of the system was demonstrated. Test results tend to show that foam application is more effective than water sprays in suppressing respirable coal dust. However, because of the extreme variability of the test conditions, scatter in the sampling data, and other factors, not enough data was obtained to form a firm conclusion that foam is more efficient than a water spray in suppressing respirable coal dust. Sufficient statistical data was obtained, however, to indicate that foam is more efficient than water in suppressing total float coal dust.

Jan 1, 1974

By H. Reginald Hardy

This report is Volume III of a three volume final report dealing in general with the microseismic monitoring of a longwall coal mine. The research presented in Volume III was undertaken as part of the overall microseismic project in an effort to relate, if possible, observed micro seismic activity with surface subsidence. A discussion in regard to the correlation of these factors is presented in Volume I of the final report. Field measurements of subsidence carried out at a Central Pennsylvania Coal Mine are described. Comparative analysis of actual field results with data obtained using empirical and finite element techniques Has undertaken. Comparison of field results with published National Coal Board data revealed marked differences. The influence of stronger rock beds overlying the coal seam in the current study was assumed to I be the main cause. Use of the general Gaussian profile resulted in a satisfactory fit to the field data provided the value of the maximum field subsidence was used in the analysis. In general, when low tensile strengths were assumed for the associated rocks, finite element techniques gave results which compared well with the observed field data. The study also indicated that at shallow depths there is a marked difference in subsidence over dip and rise sides of the coal-face, maximum subsidence being shifted more towards the dip side. Finally, time-dependent deformations were shown to be insignificant shortly after mining operations ceased.

Jan 1, 1977

The overall objective of this study is to gather operational data from selected surface coal mining systems in the United States, and to assess the potential production and economic capacity of the systems. The study includes: four mines, each using a different mining technique and different equipment. One mine was selected from each of the major coal fields: Midwestern, eastern,, northwestern, and southwestern. The Midwestern Mine is located in the Central Plains and produced 1.45 million tons of raw coal during the study year The Midwestern Mine uses the area mining or box-cut technique. A large in-pit shovel and a bucket wheel excavator are used to remove the overburden. Coal is removed by a loading shovel and transported to the dumping point by large off--highway trucks.

Jan 1, 1975

By Kenneth M. Maas

The Bureau of Mines inventoried the land in southwestern Alaska to classify ownership and availability and compared this land with known mineral terranes and mineral deposits. This report discusses and quantifies the potential for favorable location of mining claims for metalliferous (locatable) mineral deposits. Of the nearly 24 million acres that constitute the study area, approximately 3.6 million acres or 17% are available for mineral location, 3.4 million acres or 14% are available with restrictions, and 17 million acres or 71% are unavailable. Mineral terranes are known to underlie about 7.8 million acres or 33% of the study area; 3 million acres or 38% occur on land available for mineral location, 1.3 million acres or 17% occur on land available with restrictions, and 3.5 million acres or 45% occur on unavailable land. The State of Alaska has opened over 91 % of its land in the study area to mineral location; in comparison, the Federal Government allows mineral location on 0.07% of the land under its jurisdiction. There are 117 known mineral deposits or occurrences within the study area, including 77 lode deposits and 40 placer deposits. Of the 41 lode deposits occurring within a mineral terrane, 2 occur on available land.

Jan 1, 1988

Develop geophysical techniques suitable for enhancing miner safety. Specifically, to use geophysical methods to detect hazardous conditions in a rock mass in deep underground mines as well as to assess the mechanical integrity and monitor changes of the rock.

Jan 1, 1997

By Peter F. Steidl

Seven degasification wells have been completed in the Pittsburgh coalbed at the new Emerald mine near Waynesburg, Pa. Funding was provided by the Bureau of Mines to perform stimulation treatments on five of the wells, to show that this is a feasible and economical means of degasifying part of a coalbed. The seven wells ranged in depth from 590 to 910 feet. Stimulation treatments used 25,260 to 42,660 gallons of foam and 7,400 to 12,800 pounds of 20/40-mesh prop sand. Pumping rates were 10.8 to 11.6 bbl/min and treating pressures were from 1,050 to 1,600 psig. On the day following stimulation, gas production ranged from a few hundred cubic feet per day to more than 100,000 cu ft/day.

Jan 1, 1978

By Peter F. Steidl

Seven degasification wells have been completed in the Pittsburgh coalbed at the new Emerald mine near Waynesburg, Pa. Funding was provided by the Bureau of Mines to perform stimulation treatments on five of the wells, to show that this is a feasible and economical means of degasifying part of a coalbed. The seven wells ranged in depth from 590 to 910 feet. Stimulation treatments used 25,260 to 42,660 gallons of foam and 7,400 to 12,800 pounds of 20/40-mesh prop sand. Pumping rates were 10.8 to 11.6 bbl/min and treating pressures were from 1,050 to 1,600 psig. On the day following stimulation, gas production ranged from a few hundred cubic feet per day to more than 100,000 cu ft/day.

Jan 1, 1978

By William C. Miller

This report describes investigations by the Bureau of Mines designed to establish the noise level and spectrum of various types of pneumatic rock drills and to furnish information that would be useful in conducting sound measurements in mining environments and in reducing the noise generated in pneumatic drilling. These investigations show that (1) the noise generated by the drills in the frequencies below 100 cps is caused by the impact of the piston and drill steel, in the frequency range between 100 and 2,000 cps by the exhausting of air from the ports, and in the frequencies above 2,000 cps by the resonant frequencies of steel drill parts and of drill steel; (2) satisfactory instruments and instrumentation systems are available for field and laboratory measurements; (3) reliable sound measurements can be made in mining environments; and (4) devices can be developed that will abate the noise.

Jan 1, 1963

By C. I. Pierce

The Bureau of Mines conducted laboratory tests to determine if ultrasonic energy could reduce either the residual water or oil content of petroleum reservoir-rock samples from Appalachian area oilfields. Brine-saturated core samples were flooded with oil to residual brine saturation and subjected to 20 kilocycles per second ultrasonic energy. Then they were flooded with brine to residual oil saturation and again subjected to ultrasonic energy. Additional water displaced as a result of the application of ultrasonic energy to the flow system ranged from 0 to 4.3 percent of the original brine and averaged 1.9 percent. The increase in oil recovery as a result of the ultrasonic energy ranged from 0 to 9.0 percent of the original oil and averaged 3.1 percent. On the basis of the tests, it appears that 20-kcps acoustic waves would not have field application for oil recovery.

Jan 1, 1968

By F. Cherpereel, R. Gabillard, J. P. Dubus

We present an electromagnetic method taken from the well known radiogoniometer that allows us to locate at the surface of the ground the vertical axis of a magnetic antenna transmitter buried at a depth h in the earth. The method and the equipment achieved are called R. E. P. E. (Relevé Electromagnétique de Points Enterrés). They are daily used to accurately survey old quarries by using triangulation instruments at the surface of the earth rather than in galeries where the setting difficulties considerably reduce their accuracy and increase the work length. The results of several surveys allow us to give the optimum working conditions of the instruments and show that, when the transmitter is at a 20 meters depth, its position is known at the surface with an error lower than 1 centimeter. The power transmitter is of about 8 watts and we can find its location with an error smaller than 1 meter when buried at a depth of about 100 meters. This equipment may be successfully used for location of subsurface miners. The space surrounding the transmitter must then be free from ferromagnetic bodies.

Jan 1, 1973

By David E. Siskind

The Bureau of Mines has studied the fracturing produced in the vicinity of large-diameter blastholes in Lithonia granite. Cores were taken from the vicinity of AN-FO production blasts and examined using a total of seven laboratory and field measurement techniques to delineate zones of damage and evaluate the effectiveness of the seven diagnostic tests for fracture-state determination. Laboratory measurements of acoustic pulse velocity, porosity, permeability, compressive strength, and Young's modulus indicated the extent of fracturing with the acoustic techniques providing the best means of distinguishing between fractured and unfractured core. A severely fractured zone was found to extend approximately 25 inches (64 cm) from the center of the 6-l/2-inch blastholes, equivalent to 8 blast-hole radii. A second zone, characterized by a lesser degree of fracturing extended from 25 to 45 inches (64 to 114 cm) or 8-to l4-blasthole radii. Beyond 45 inches (114 cm) the rock was undamaged.

Jan 1, 1974

By K. K. Kershner

Sulfide ore concentrates containing cobalt, nickel, copper, lead, and iron were salt roasted and leached on a laboratory scale. More than 95 percent of the cobalt, nickel, and copper was recovered. Heating patterns for salt roasting different concentrates were established. More cobalt, nickel, and copper were recovered from a bulk concentrate composed of a mixture of copper concentrate and iron concentrate. This mixture corresponded roughly with the mixture of these materials in stockpiles in southeastern Missouri. A temperature range of 375° to 400° C. was best for salt roasting. Metal chlorides were leached at a pH of 1 from chloridized charges of concentrates, Although the amounts of cobalt, nickel, and copper extracted were high, the amount of iron dissolved simultaneously interfered with subsequent separation and recovery of these metals. The amount of dissolved iron was reduced substantially by steam treating chloridized charges of bulk concentrate at 300° C. In this way, the ratios of cobalt, nickel, and copper to iron in leach liquors permitted satisfactory separation and recovery of these metals. INTRODUCTION The Federal Bureau of Mines is experimenting with chloridizing reactions.4 5 6 7/ Salt roasting of sulfide ores and concentrates, or their calcines, to form metal chlorides has certain advantages. Chlorides of

Jan 1, 1961

By Thomas E. Marshall, Timothy Batchler, Anthony T. Iannacchione

As the amount of new fractured surfaces or "damaged rock layers" within roof rock increases, the stability of the rock mass decreases. While direct measurements of this phenomenon are not easily made, there is good circumstantial evidence to support this hypothesis. For example, it is common to observe increased cracks or fractures in the immediate mine roof rock before a roof fall. Likewise, roof drill holes placed in areas that later fail often reveal increased numbers and/or separations of fractures within the rock column through time. And finally, the frequency of microseismic activity, representative of rock fracturing, increases before a roof fall. For this study, more than 700 microseismic emissions were collected from two underground limestone mine roof fall areas in southwestern Pennsylvania. Microseismic events were located and magnitudes determined using the moment magnitude technique. Moment magnitude is based on the event seismic moment, which is a measure of the seismic deformation. The amount of new fracture surface length was calculated based on the stored strain energy within the rock prior to fracture. In the two case studies presented, a significant amount of microseismic activity was observed as much as two days before the first signs of failure in the roof fall areas. Additionally, results from this analysis reveal much about the behavior of strata prone to failure and allows for the construction of hazard maps based on microseismic emissions. The potential use of this technique as a means of anticipating roof falls is analyzed and discussed.