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By S. Orzecki

The KGHM Copper Refinery Plant, Glogów 1, has operated for 35 years and -increased its capacity almost ten times.Cathode quality, expressed in terms of the total impurity content, has undergone a five-fold improvement. The present refining capacity is equivalent to 240,000 metric tonnes of copper cathode, with a total impurity content of 20 ppm, inclusive of 10 ppm Ag. These accomplishments result from combined implementation of current technological progress in electrolytic refining and KGHM's own solutions applied to the Glogów Refinery. The quality improvement measures feature both lowering actual current density, despite an increase in nominal current density, and diminishing the role of non-ion mechanisms which transfer impurities to cathodes. The paper contains a detailed discussion of these issues and outlines possible measures aimed at further production and quality improvements.

Jan 1, 2007

By G. B. Harris

A process for the recovery of copper from the waste oxide copper of a mined-out sulphide orebody is described. Hydrometallurgical recovery of copper from this and similar wastes has been tried several times previously without success. Leaching is carried out by sulphuric acid in columns under conditions that minimise the iron content of the pregnant leach liquor, and copper is then recovered by ion exchange rather than the more conventional solvent extraction. The resin is stripped by spent electrolyte and copper is electrowon. Results are presented for testwork originally carried out in 1993, and repeated in 2006, and the novel aspects of the process, leaching and ion exchange, are discussed. Finally, preliminary order of magnitude capital and operating costs are given, demonstrating that the process is cost effective.

Jan 1, 2007

By Marta Polgari, Eva Surova, Bohumil Molak

Abstract -The Ûrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organic­ geochemical methods. Both depositionallocalities were affected by the Lower Jurassic Toarcian anoxic event. Ûrkút shales are rich in organic matter (av. 2.94 wt% total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (?0.2 wt% TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decom­ position of organic matter that also involved Mn reduction.

Jan 1, 1992

By G. Plascencia, A. Warczok, M. Zamalloa, T. Utigard, N. Behnood

The objective of this investigation was to investigate interactions between high-grade copper mattes and Rexal 60DB direct bonded basic bricks. The infiltration and attack of Rexal 60DB bricks by copper matte and continuous converter matte was investigated in laboratory tests at temperatures up to 1300 °C. The brick dissolution and infiltration tests did not show any significant difference between the 70% Cu and the 81% Cu mattes. More metallic copper was visible in the pores in the case of 81% Cu matte. An important mechanism for direct-bonded magnesia-chrome brick destruction is that oxysulphides start to infiltrate the brick, followed by slow oxidation of the matte producing metallic copper and cuprous oxide, which then react with MgO and Cr2O3, primarily attacking the direct bonds of the brick.

Jan 1, 2004

By R. A. L. Drew, C. A. Rodríguez González, Caleym W. F.

This work addresses the need of new refractories for copper converters. Technological improvements and environmental regulations for chromium containing refractories have generated this need. Chemical interactions, mechanism of penetration and the effect of oxygen potential and temperature in the system Cu2S-FeS-SiO2-O2 are presented for two refractories: a burned magnesite chrome brick (typically used by the copper industry) and a chrome-free spinel direct bonded brick. The main difference determined in the refractory performance was the blister copper penetration resistance; burned magnesite chrome brick is penetrated while direct bonded brick is not. These results are very promising since blister copper penetration has been reported as the major cause of refractory wear. The results are explained in terms of refractory porosity and wetting characteristics.

Jan 1, 2004

What Discounted Cash Flow Analysis can do for you: ?Provide an accurate financial analysis of a project for the first 25 to 30 years of operations ?Identify cash flow requirements ?Identify relative sensitivity of the project to the various input parameters ?Place a value on the resource in place after 30 years of operations ?Correct for errors in input parameters

May 1, 2010

By Maurizio Violo, Arjan Beqiraj, Umberto Masi

"Abstract - Four main podiform occurrences of chromite have been distinguished in the ultramafic Bulqiza massif, Albania; they are associated from the bottom to the top with: i) basal harzburgites (lower tectonite sequence), ii) dunitic lens-bearing harzbugites (middle-upper tectonite sequence), iii) layered chromitite-bearing dunites of transitional zone, and, iiii) the stratigraphically lowermost part of the magmatic section. However, only the occurrences hosted by rocks ii) and iii) are economically important.Chromite compositions similar to those of other podiform chromites are bimodal. Thus, chromites from occurrences ii) and iii) are richer in Cr than chromites from the other two occurrences. Accessory chromite disseminated throughout the massif is richer in Fe than orebody chromite, displaying similar range of the Cr/Cr+Al ratios, with accessory residue chromite matching the characteristic (Cr/Cr+Al >0.6) range of type-III Alpine peridotites. Both orebody and accessory chromites show compositional ranges correlating with host-rock compositions, i.e., the Cr-rich chromites are hosted by the most refractory ultramafic rocks. Therefore, the Cr/Cr+Al and Mg/Fetot (Cr/Fetot) ratios of chromite are useful for exploration of high-grade, metallurgical chromite ore at Bulqiza and in other massifs of similar geodynamic setting."

Jan 1, 2000

During industrial copper electrowinning, a fraction of the electrolyte becomes entrained with the oxygen gas bubbles that are evolved at the anodes. The fraction of entrained bubbles increases from the bottom of the anode to the top, resulting in a bubble distribution that appears as an inverted wedge between the cathode and anode. Since the bubbles act as insulating spheres, electrolyte resistance increases from the bottom of the electrodes to the top resulting in correspondingly higher local current densities and uneven copper growth along the cathode. To counter-act the inherent tendency toward excessive copper growth near the bottom of the cathodes, the use of tapered anodes was examined. The potential improvement in cathode current distribution was evaluated by comparing the primary current distributions for 2-D computer models of a copper electrowinning cell with plate shaped anodes against one with tapered anodes.

Jan 1, 2007

By S. K. Sadrnezhaad, B. Hashemi, Z. A. Nemati, Z. Moghimi

Based on the kinetics relationships of a solid - gas model, a software was developed for the prediction of oxidation. Preliminary prediction of oxidation by the software and experimental results of MgO-C refractories were studied and compared. By using the obtained data from this approach, the effective diffusion coefficient, intermolecular diffusion coefficient and diffusion activation energy in the MgO-C refractories, containing various amount of graphite were obtained at different temperatures. First of all, the prediction by the software was very compatible with experimental results, for different oxidation mechanisms in the MgO-C refractories. The results showed that pore diffusion is the predominant oxidation mechanism in this system. The results indicated that when graphite content was above 10wt%, the intermolecular diffusion coefficient was independent from graphite content, and it was closed to a constant value at each temperature.

Jan 1, 2004

By Fengxiang He, T. Meadowcroft, Yanjun Zhang

Slag from the zinc fuming furnaces contains about 3 percent zinc and 0.1 percent lead. The paper outlines several experimental techniques for recovering these components from liquid fumer slag. The simplest method, remelting followed by a hold period, indicated that a substantial fraction of the metal values was recoverable as a result of fuming into the gas phase, presumable by reduction of the metal ions by divalent iron ions. Following on from this, slag samples were equilibrated with copper, chosen because the activity coefficients of zinc and lead in copper are very low. This improved metal recovery, with substantial amounts of lead and zinc reporting to the liquid copper as well as to the fume. Application of an electrical emf across the slag-metal interface, using a graphite anode and a liquid copper cathode, resulted in further gains in metal recovery.

Jan 1, 2004

By T. Cutard, E. Cailleux, F. Nazaret, G. Bernhart

This paper deals with the study of the mechanical behavior in the 20°C-900°C temperature range of refractory concretes reinforced with metallic fibers. Fibers are introduced to improve the damage resistance and to minimize the quasi-brittle behavior of refractory concretes. In some cases, a plastic or ductile like behavior can be obtained. Two approaches are considered in these studies. The first one is based on the micromechanical scale. Main objectives are to understand, quantify and predict the thermomechanical behavior of monofiber microcomposites. Such considerations are helpful to optimize the composite formulation for a better behavior. The second one is based on the macromechanical scale. Main objectives are to characterize and to model the macroscopic thermomechanical behavior of randomly reinforced refractory concretes. A particular attention is firstly paid to the relationships between the microstructural changes and the mechanical properties and secondly to the structural size effects.

Jan 1, 2004

By T. Hartmann

The presence of crud represents a permanent challenge for solvent extraction in the hydro-metal industry. The crud is a stable emulsion which slowly spreads along the phase boundary between the aqueous and organic phase. The crud can significantly impair the efficiency of hydro-metal extraction because the phase boundary between the aqueous and organic phases assumes substantial proportions, and the settlers cannot react flexibly. In a chain reaction, all settlers connected in series become infected with crud. The transfer of organic phase to the electrowining (EW) cell can cause 'cathode burn'. Continuous treatment of the crud is extremely effective and reliable with a 3-phase separating solid bowl centrifuge. All three phases are separated distinctly from one another. All associated process steps exhibit a steady uniform efficiency. First and foremost, they ensure a reliable, continuous extraction process and, second, they recover valuable re-usable organics from the crud.

Jan 1, 2007

By M. Rigaud, N. Zhou, K. Sankaranarayanane, X. Zhou

The effect of amount and type of dispersants on the rheological behaviour of bauxite-based low-cement castables has been studied in detail. The rheological properties: flow resistance and torque viscosity, as measured by a rheometer, are found to be strongly influenced by the amount and type of dispersants. In the present investigation, a mix containing sodium hexametaphosphate, at an optimal level, is observed to be theologically superior at the given experimental conditions.

Jan 1, 2004

By Y. C. Kim

This paper discusses Air Liquide's patented SPALTM (Surface Protection Air Liquide) technology and process for the inerting of coreless induction furnaces using cryogenic liquid gas. Air Liquide Canada Inc., in collaboration with Riverside Brass and Aluminum Foundry Limited (Riverside Brass), conducted plant trials to demonstrate the applicability of the SPALTM technology for copper-based alloys. Results showed that with SPALTM, Riverside Brass benefited from a significant increase in metal yield as the level of dross formation was drastically reduced. Together with the many other benefits of this technology, SPALTM demonstrated to be a non-negligible cost-effective solution to reduce metal production costs. In an effort to optimize the argon flow, different flow rates were used and the oxygen level above the metal bath was measured to pinpoint optimal flow. The results of metal yield, charge mix, dross formation, and melt temperature are compared with and without argon. The metal yield improvements are dramatic and calculated net savings are presented hereunder.

Jan 1, 2007

By G. Kordosky

Leaching aids that result in an increase in leaching rates and overall copper recovery have the potential to be beneficial to copper leach/solvent extraction/electrowinning operations. It is generally accepted that effective leaching aids facilitate the penetration of leach solution into ore by lowering the surface tension of the leach solution. Surfactants are designed to do this, and a leaching aid containing the widely used surfactant class, alkyl phenol ethoxylates, has been suggested. Alkyl phenol ethoxylates were tested to determine how they may affect phase separation, entrainment and degradation in a copper solvent extraction plant. The test results suggest the use of leaching aids at a regular rate, or even for a short time period, may have a long term impact on copper solvent extraction. Several scenarios are evaluated regarding existing operations and future solvent extraction projects and cautionary suggestions related to the use of surfactants as leaching aids are given.

Jan 1, 2007

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

In addition to the harsh environment, materials for high-temperature applications are often subjected to a significant mechanical loading. Several researchers have noted that the rate of oxidation can be affected by stress in a range of materials. We have recently studied this effect in y-TiAl, based on the preliminary work of Magnan and Weatherly which showed that nitridation rates on the tensile side of a flexural creep specimen could be 10 times higher than on the compressive side. We have since developed a four-point bending creep setup capable of controlled atmosphere testing. We present quantitative data on the effect of creep on scale growth under a range of atmospheric conditions. Finite element analysis will also be used to show how modest applied stresses can have a large effect on scale growth rates through the generation of large stresses due to the mismatch of creep rate between the metallic substrate and the scale.

Jan 1, 2004

By Jamie W. Pardy

The objective of the Canadian International Development Agency program is to facilitate the efforts of the people of developing countries to achieve self-sustainable economic and social development in accordance with their needs and environment. The British Columbia Ministry of Energy and Mines (BCMEM) is the executing agency for the four-year Peru Minerals and Metals Public Sector Assistance Project which began in December 1998. The primary beneficiary is the Ministerio de Energía y Minas del Peru (PMEM). The project is designed to address mine health & safety, environmental management and mineral resource information. Project activities currently underway include joint development of: an inspection system, a mine rescue system, an enhanced and e-Commerce capable mineral information website, environmental guidelines for industry and standardized ministry evaluation criteria for environmental impact assessments and closure plans. In addition, reports on management options for mineral concentrate transportation, storage and handling, and on mine reclamation security policy have been delivered at workshops.

May 1, 2001

By M. Olper

Commercial copper plants utilising current best technology are tending towards ever increasing scale, the concentrate requirements of which cannot be serviced by a single mine. In such cases, raw materials are often sourced from different mines, which are often far away from the production plant and usually with very different ore compositions. These plants tend to use the traditional thermal processing steps of smelting, converting to blister, anode refining and casting to produce copper anodes that are then refined in a sulphate electrorefining operation. These thermal steps are in some cases troublesome and require the recycling of considerable quantities of material. A new process was developed taking advantage of the latest developments of the first thermal step of the classic loop, the smelting of copper concentrate to high grade matte or white metal using the well known AUSMELT Top Submerged Lancing Technology. The white metal and/or high grade matte product is converted directly to copper cathode and elemental sulphur using the ECUPREX technology. This approach provides an alternative to the traditional thermal steps of conversion to blister, thermal refining and anode casting, which, especially at small scale, can be expensive and problematic in terms of technical and environmental concerns. At first evaluation, this new process can be operated at low capacities, thereby, changing the traditional approach to copper production. Instead of taking the concentrate to the copper production plant, the copper production plant is taken close to the mine with some significant economic and technical advantages.

Jan 1, 2007

By J. F. Henderson, N. H. . C. Fraser

"Camlaren Mines, Limited, owns a group of claims near Gordon lake, in the Northwest Territories about 45 miles northeast of Yellowknife. The Hump vein on the property was explored continuously from the summer of 1937 to December, 1938, when all work was stopped. The two-compartment vertical shaft sunk near the vein is 380 feet deep and drifts and cross-cuts on the 200- and 350-foot levels total 2,241 feet . This exploration indicated 13,177 tons of ore with a gold content of between ½ and 1 ounce a ton1GEOLOGY AND STRUCTUREThe property is underlain by remarkably fresh greywacke and slate of the Early Precambrian Yellowknife group. The thickness of the b ~ds averages 1 to 2 feet, although that of the coarser greywacke may be 10 feet or more. Most of the greywacke beds show a gradation in grain from sandy at the base to slaty at the top. They are composed of chlorite, sericite; carbonate, and detrital quartz and feldspar grains.The structure of the greywacke and slate underlying a part of the property of Camlaren Mines, Limited, is shown in Fig. 1. The beds are isoclinally folded so that they dip at steep to vertical angles and at many places are overturned. The axes of the folds are 50 to several hundred feet apart, and generally plunge at angles of 45° or steeper. The beds along the axes of the folds generally meet to form a sharp V, and at the point of the V, or axial part of the fold, the beds are commonly ruptured . Minor faulting movements along the broken crests of the folds in many cases result in well-defined shear zones. Discontinuous quartz veins and irregular lens-like masses of quartz lying more or less parallel with the bedding are plentiful throughout the sediments, but tend to be concentrated along the ruptured and sheared, anticlinal and synclinal fold axes ( Fig. 1)."

Jan 1, 1954

By E. Tulcanaza

Mining companies normally establish exploration and research programs originated with actions in embryonic stage. At their early stages of development, these exploration and technological activities are subject to uncertainties that need, first, to be resolved, deciphered or, at least, mitigated for information reporting; and later, for valuation reporting. Under these circumstances, these exploration activities follow a sequence of development phases that range from exploration work to the profile, conceptual, and finally to basic engineering phases and construction. For information reporting, the International Template for Reporting of Exploration Results, Mineral Resources and Mineral Reserves integrates the minimum standards being adopted by the relevant professional bodies in Australia, Canada, South Africa, Chile, USA, UK, Ireland, and other European countries which set up the Committee for Mineral Reserves International Reporting Standards (CRIRSCO, www.crirsco.com). These standards are based on the progressive collection of relevant information to reduce present and future uncertainties over time under a context of transparency, materiality, and technical competence. For valuation reporting several procedures have been disclosed and applied. However, in the last decades financial instruments such as real options, decision analysis, and games theory have developed into a niche of great potential for mine valuation applications. The objective of this paper is to provide a summary of the information reporting standards prepared by the Chilean National Commission for the Qualification of Competent Persons in Mineral Resources and Mineral Reserves and show a procedure and an application of real options to the valuation of the sequential development phases of a mine asset from the exploration stage through up to full development.

Jan 1, 2007