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By G. Hamel

The LCL&L process (Low Caustic Leaching & Liming) is a patented hydrometallurgical route developed by Rio Tinto Alcan (RTA) to economically process spent pot lining (SPL) generated by aluminum cells. The three resulting end-products (carbonaceous, fluorinated and caustic liquor) are inert and have valorization possibilities. An industrial size pilot plant located in Saguenay (Quebec) was inaugurated in mid-2008 to demonstrate and optimize the technology. This paper describes characteristics of the LCL&L process and the experience acquired by RTA since the plant's start-up, including ramp-up capacity and technology challenges that were overcome. Possible end-products valorization methods are also presented. The carbonaceous end-product can be separated into carbon and brick rich fractions and used as either alternative fuel, reducing agents, or as raw material for third party processes. The development of a conversion process for the fluorinated end-product would allow its reuse as a substitute to fluorspar mineral for aluminum fluoride production. Finally concentrated caustic liquor is already valorized at the nearby RTA Vaudreuil alumina refinery.

Jan 1, 2011

By Z. F. Lodhi, J. H. W. De Wit, H. A. Terry

Zinc and its alloys have been extensively used as replacements for Cadmium coatings in aeronautical and automobile industries. Zn alloys with low Co or Fe have been highly investigated but coatings with higher amount of Co are very difficult to achieve due to anomalism associated with these coatings. Anomalous Zn-Co-Fe alloy is a relatively recent addition to the family of Zn alloys. It is found that the addition of Fe in the electrolyte assist in overcoming the anomalism. In this research Zn-Co-Fe alloys especially with higher amount of Co (>15%) and Fe (~1%) are investigated, after overcoming the anomalism associated with its deposition, and the corrosion resistance is compared with pure Zn and Cd. It is found that an increase in Co to higher than 25 % accounts for a shift in the OCP to a level near Cd yet keeps it electronegative to steel. The coating shows superior corrosion resistance, in terms of its sacrificial and barrier properties in 3.5% NaC1 as compared to Zn and Cd.

Jan 1, 2006

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

By V. A. Chanturiya, T. N. Matveeva, N. K. Gromova, T. A. Ivanova

"The research is aimed at solving the problem of increasing the extraction of gold from refractory ores, which are the main source of growth in gold production in the next decades. The purpose of the research is the development and scientific substantiation of the reagent modes for flotation extracting of gold from refractory ores using eco-friendly low-cost herbal modifiers (HM), providing increase in gold recovery and quality of gold concentrates. In the course of research laboratory techniques for the preparation of experimental samples of HM were developed, which included the sequence of operations of grinding Heraclium leaves and stems grinding, 2-stages extraction at a temperature of 50-60 °C, short-term ultrasonic treatment, filtration and subsequent unification of extracts. According to the developed method, the experimental samples of HM and conducted research were tested to analyze their sorption and flotation activity related to the extraction of gold from refractory gold ores.New data on adsorption and flotation properties of Heraclium stems and leaves extracts (HSE) in selective flotation of Au-sulfide minerals were obtained using UV-spectroscopy, scanning electronic and laser microscopy and atomic force microscopy. The dimensions and shapes of adsorbed hydrophilic films of herbal reagents were identified and mechanism of formation of stable insoluble compounds on the surface of minerals in flotation was explained.Research flotation tests carried out on samples of refractory gold ore of one of Russia deposits showed the possibility of effective use of herbal modifiers to improve qualitative and quantitative indicators of enrichment compared with the standard reagent regime. New reagent modes, using herbal modifiers in an amount of 5 to 10 ml of the extract (300 - 600 g / t, respectively) improves the quality of the concentrate: gold content attains 14.7 g / t, 1.34 times higher than in the baseline experiment and provides a gain of 3.13% extraction.The developed reagent regime with herbal modifiers is the author's original design, patented (patent of the Russian Federation) and have no analogues in the world of mineral processing. (Application number 2015116125 from 04.28.2015, ""The method of flotation separation of sulfide minerals using herbal modifier"", Russia). Actual application of new plant extracts as modifiers in flotation of sulfide minerals is the possibility of replacing of highly toxic chemical compounds by environmentally safe substances of plant origin. Implementation of the developed methods of extracting gold from refractory minerals with herbal modifiers will help to improve gold recovery at 3-5% and the quality concentrate of not less than 1.2 times, leading to higher productivity and a reduction of the negative man-made effects on the environment ."

Jan 1, 2016

By Kathy S. Kalenchuk

Damages have been observed in shafts, backfill infrastructure and the slick line at the Leeville Mine. Shaft damage (shearing and spalling of the concrete liner) is attributed to mine-induced rock mass deformations concentrated where regional faults intersect the shafts. Aggregate bin, mixer station and conveyor drive damage (shotcrete shearing, heave of concrete floor slabs and bending of a vertical steel beams) is attributed to rock mass squeezing induced by elevated magnitudes of the vertically orientated major principal stresses. Separation of the slick line has occurred do to extension of the stressshadowed rock mass immediately above the mined out areas. Three-dimensional numerical models have been developed and calibrated to simulated rock mass deformations with magnitudes similar to those believed to have produced the observed damages. By stepping through the mine sequence, models reproduce deformations at the same mining stage as when damage has occurred. Calibrated models have been used to forward project further damage over the remaining mine life.

Jun 1, 2012

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By Michel Lefebvre, André Piché

Every organization performing R&D is faced with the challenge of introducing new technologies to its operations. Difficulties must be overcome if companies are to realize the benefits anticipated from such developments. This paper outlines the difficulties encountered in transferring to operations various technologies developed at the Mining and Exploration Division of the Noranda Technology Centre. The approach used in the selection of a privileged partner for the technology transfer, the criteria motivating the choice and the process followed to establish the partnership are presented.

Jan 1, 1997

By Henry F. Hebley

THE solid fuel industry, especially that branch represented by bituminous coal, is gradually becoming aware of its ? paramount importance in a world where there is an ever increasing demand for the products of a mechanical age. In practically every process of manufacture, the necessity for energy in some form is being multiplied. Some of that prime energy is derived from water power-hydro-electric schemes, flood control schemes, etc. - but often the electrical energy thus developed is generated at great distances from the load centres, requiring long transmission lines with consequent transformer and transmission losses. A few plants have harnessed the tidal power of the seas and one has harnessed the energy of the wind in a modern manner. All of these schemes are dependent on certain natural geographical, hydrographical, and physical advantages of terrain, as well as an adequate area of consumption of the energy developed. If flood control is the primary object, then power generation is a by-product; and the economics of large capital expenditure on power generating equipment must be considered in that light.

Jan 1, 1945

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from both primary and secondary sources having various compositions. Vanadium pentoxide and vanadium trioxide are the most available and known sources of vanadium oxides. In this paper, an overview of leaching both oxides has been reported. The problem of vanadium pentoxide leaching under acid conditions is the low solubility of the dissolved vanadium. This was investigated and then supplemented with further studies of leaching at mildly basic pH’s as well as under acid reductive leaching conditions (to form vanadium (IV)). Atmospheric oxidative leaching of vanadium trioxide was investigated using oxygen and ferric ion as the oxidant. It was shown that the leaching of vanadium trioxide using oxygen is very slow; however, ferric ion can dramatically increase the kinetics and leach efficiency.

Jan 1, 2014

By A. D. Hunt

THIS PAPER will review Canada's fossil fuel situation as we understand it today and indicate some of the options available to meet our energy requirements during the next 15 years. It would therefore be helpful to examine Canada's total energy requirements and discuss the un certainties of the data base on which we must base future energy investment decisions. On the world scene, Canada is at the top of the energy-consuming nations, using about 49 bbls of oil equivalent per caput/ year. This appears to be slightly ahead of the U.S. and of course much higher than that of many countries. It is generally accepted that there is a more or less direct relationship between energy consumption and material standard of living. However , as we know, Canada, when compared with other industrialized countries on a GNP, an individual-income or some other standard basis, is lower in the list. This situation may be explained by our more severe climate and a relatively small population distributed over a land mass second only to that of the Soviet Union.

Jan 1, 1977

By G. T. Lapidus, R. M. Luna-Sánchez

In the present study, a series of cyanidation experiments were performed on a bulk sulfide concentrate which contained silver in four distinct phases, to determine its extraction rate, varying the oxygen concentration. The results showed that three of the four phases were refractory, aguilarite (Ag,iSeS) being the only leachable phase, and that the effect of the oxidant concentration is minimal. Mathematical simulations were performed, adjusting only the Damkohler number to adequately fit the experimental data. This model, and the mechanism implied, was compared with that found for acanthite (Ag2S) in a previous study, and the differences between the two discussed.

Jan 1, 2005

By Seungwoo Park, Whuisu Shim, Roe-Hoan Yoon, Kaiwu Huang

"A comprehensive froth model has been derived from first principles. It is based on predicting the kinetics of film thinning in the presence of particles of varying sizes and surface hydrophobicity. According to the Reynolds lubrication theory, the thinning of a horizontal film is driven by the excess film pressure (p), which is determined by the capillary pressure (pc) and the disjoining pressure (II). In the presence of particles, macroscopic capillary pressure (pc) is affected by the local capillary pressure (pc,local) in the vicinity of a particle and the number of particles in the film (N1,film), which in turn vary with the hydrophobicity and size of the particles. The Reynolds equation corrected for pc,local and N1,film is then used to predict the time (or froth height) at which a film is thinned to a critical rupture thickness (hcr), which in turn can be predicted using the Vrij’s capillary wave model (1966) after a modification to incorporate the contributions from hydrophobic disjoining pressure (IIhp). The model can predict bubble coarsening represented by the bubble size ratio between the top (d2,t) and bottom (d2,b) of a froth as functions of particle size and hydrophobicity, ? -potentials, frother dosages, froth height, gas flow rate, salt concentration, etc. The model predictions have been verified in experiments.INTRODUCTIONFroth flotation is regarded the best available technology today for upgrading minerals and coal fines. In the pulp phase of a flotation cell, air bubbles collect hydrophobic particles dispersed in it and rise to enter the froth phase on the top. Once in a froth phase, the bubbles coalesce with each other and become larger, resulting in a decreased bubble surface area. Under conditions of limited surface area, less hydrophobic particles drop off the bubble surface and return to the pulp phase. Thus, bubble coarsening provides a useful mechanism of increasing product grades. On the other hand, uncontrolled coarsening results in a decrease in bubble carrying capacity and hence throughput."

Jan 1, 2016

By Charles Tkaczuk

Key issues ? Process control is a corporate function implemented locally. ? Security and documentation is mandatory requiring standard practices. ? Publish and communicate activities (do not re-invent the wheel). ? Payback metric system for all projects. ? Partnering with vendors based on experience, expertise and joint R&D. ? Focus on phased process control projects and distribution of costs. ? Integration of services and functions. ? Application of global standards. ? Big picture application thinking.

Apr 1, 2005

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By W. S. Dyer

The Minto coal basin lies in the central part of the province of New Brunswick, near the head of Grand Lake. The village of Minto which is the centre of mining activity of the district, lies about 35 miles east of Fredericton and somewhat greater distances to the north and west of the cities of St. John and Moncton respectively. Although coal has been mined in the basin for a number of years, it was not until recently that the production became sufficient to warrant a thorough geological investigation. The summer of 1922 was spent, in accordance with in structions from the Director of the Geological Survey, in making a detailed study of the geology and coal resources of the Minto coal basin, which is covered by the Minto and Chipman map sheets, each embracing an area of 200 square miles. The present paper is a short outline of the principal results obtained in the field. The writer wishes to acknowledge the assistance cheerfully given him by the managers and officials of the various companies operating in Minto. He wishes especially to thank Mr. W. B. Evans, Manager of the Rothwell Coal Company, for assistance in the collection of fossils and for the generous supply of information relative to the early history of the coal field.

Jan 1, 1924

By C. Moctezuma

Since the start up of the IMMSA electrolytic zinc refinery in 1982, the dissolved iron coming from the acid attack of the ferrites has been precipitated by the jarosite process. At the beginning of operations, sodium jarosite was produced; however, the plant was converted to ammonium jarosite in 1990. The final storage of the residue is on the company&apos;s property adjacent to the plant, over the natural surface of the land. Before the construction of the refinery, several studies were done in order to evaluate the characteristics of the ground, such as, permeability, underground water localization, etc. The results showed that the site was adequate for the storage of this kind of material. For several years, the jarosite residue was filtered on rotary drum filters and was sent as a pulp to the storage area for settling. The water from the storage pond was recycled to the re-pulp tank for the jarosite residue. These filters were replaced in 1999 by an automated filter press. Since then, the jarosite residue has had a lower water content, and the zinc recovery improved. At present, a second filter press for the jarosite circuit is in the acquisition process to diminish the soluble zinc content in the residue from the present value of 2% to < 1% Zn.

Jan 1, 2006

By M. K. Gangal, M. A. Stoakes, A. E. Hall

"The major features of the CANMET thermodynamic mine ventilation network program, developed by the Mining and Mineral Process Engineering Department of the University of British Columbia for the Canada Centre for Mineral and Energy Technology (CANMET), are described.The program is designed for use by deep Canadian mines in planning ventilation flows where the effects of auto-compression of air, moisture lift work and natural ventilation are significant. Routines to simulate stalled fans and give an optional cost printout have been included in the program.A supplementary plotting program used to simplify data interpretation is also described.The program is described with a test data example of a deep mine. It is a valuable analytical tool which can assist ventilation engineers to simulate many alternative ventilation strategies at a low cost in a very short time.IntroductionCanadian underground mines are becoming deeper and more extensive. The use of more and larger diesel-powered equipment increases the amount of air required to be circulated in these complex systems. These effects, coupled with the increasing unit cost of the energy required for mine ventilation, require that the air is used with maximum efficiency.Optimum airflow distribution can be obtained by using network computer programs enabling engineers to plan future ventilation systems based on quantitative assessments. The programs used for deep mines must make allowance for the change of air density with depth, as the assumption of incompressible flow leads to serious errors. Natural ventilation effects may vary with depth and from part to part of the mine; this must be catered for by the program. The air moisture content changes throughout the circuit and a significant portion of the fan work may be used in removing moisture from the mine; as this work varies directly with the flow, a suitable relationship must be utilized in the program."

Jan 1, 1982

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By T. T. Wang, T. H. Huang, Y. C. Chiu

Quantitatively analyzing deformation of a tunnel with lining anomalies for structural safety evaluation is essential for sustainable tunnel engineering. However, a complete theory and associated methodology accounted for displacement of a built tunnel is absent. This manuscript introduces a novel characteristic matrix method proposed by the authors which is an integrated procedure that analyzes displacement of rock tunnels in operation. First, establish a numerical model expressing a specific state of the tunnel in interest. Derive the characteristic displacement modes by a unit disturbances and check their independency. Once the characteristic displacement modes are proved to be orthogonal (independent), they are ready for use. Given a tunnel displacement, modal decomposition returns the magnitude of each characteristic displacement modes that together consist the given displacement. By realizing the definite value of horizontal and vertical translation, rotation, uniform compression/expansion, elliptic deformation, triangular deformation…etc. for a tunnel displacement, one can distinguish tunnel displacement and deformation types from their modal composition. A circular tunnel with elastic structure and surrounded by elastic rock mass is chosen to demonstrate the outcome of characteristic modes and how they work. The influences of tunnel shape, elastic modulus ratio between rock mass and tunnel structure, and numbers of monitoring points on a tunnel profile were also discussed. Identifying possible tunnel deformation causes is attainable if further connections between mode combination and force increments were built.

Jan 1, 2015