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By D. Shen, J. Cheung

Variable reactance arc control by the SPLC (Smart Predictive Line Controller) has been installed at many different mining sites and steel processing plants around the world. Since its first installation 18 years ago, many advances have been made to both the technology, and to its integration with furnace processes and plant operations. The SPLC has helped to improve electric arc furnace stability by reducing electrode movement while maintaining flat line arc power. Stable furnace operation at higher average power increases productivity. This paper summarizes the progression of electro-technology at Hatch since the 1970s, including fixed and variable reactance, digital electrode regulation, and fast variable speed hydraulics for Soderberg electrode, as demonstrated and benchmarked through projects and lessons learned over the years.

Jan 1, 2015

By J. G. Pearson, F. H. MacDougall, A. G. Galley

The difference in age, host rock lithology, alteration and style of mineralization indicates a fundamental difference in the format ion of gold deposits in the Flin Flon and Amisk Lake areas. The Flin Flon area contains early quartz-sulfide-gold veins fo rmed within intermittently active fractures and later plutonic hosted deposits thought to be generated in a porphyry system. In the Amisk Lake area two types of gold occurrences are recognized: I) gold-quartzcarbonate- sulfide veins within or flanking fault zones and 2) structurally and stratigraphical ly controlled zones of dissem inated and vein type sulfide-gold mineralization within extrusive and intrusive rhyolite and dacite porphyries. Both types of deposits are set within supracrustal rocks. are accompanied by intense alteration haloes and were formed prior to the major deformation event suggesting an early, epigenetic hydrothermal origin.

Jan 1, 1986

By Samuel Frimpong

Green house gases have become a major concern within the international community over the last two decades due to their potential link to global warming. Carbon dioxide (CO2) is the principal greenhouse gas. In the Kyoto Agreement, Canada has committed to reduce emissions by 6 % below 1990 levels by 2012. This presents a serious economic challenge to Canada and Alberta. Over the next decade, oil sands production expansion, population and industry growth and energy demand will increase CO2 emissions. Current and future CO2 emissions and their economic implications in Alberta will be critical in formulating a comprehensive and balanced policy for dealing with concerns in this area. Disposal of carbon dioxide (CO2) in land aquifers is a potentially viable option for Alberta in dealing with long-term CO2 emissions. Studies have confirmed the existence of appropriate aquifers in the Alberta Basin for CO2 storage over a long geological period. Carbon dioxide is an ideal candidate for aquifer disposal because of its high density and solubility in water at relatively high pressures. In this study, the authors develop a computer simulation model of a scaled aquifer disposal system. The scaled model consists of an injector well, aquifer environment with dominant Ca++ and Mg++ cations. Liquefied CO2 is injected at an appropriate pressure and concentration through an injector well model. The injected CO2 migrates from the point of contact between the injector well and the aquifer domain to the main regime of the latter. The rate of migration is a function of porosity, permeability, cations, aquifer fluid flow regime and CO2 injected pressure. These models are validated using flue gas data from the 546 MW Wabamum Power Plant in Alberta. The total energy requirements for aquifer CO2 disposal system are distributed between a minimum of 105 MW and a maximum of 172 MW, with a mean of 132 MW and a coefficient of variation of 10%. The results show that there is significant variability in all the energy requirements for the CO2 disposal system. The total energy requirements for the disposal system as a fraction of the total power generated by the Wabamum plant of 546 MW could be between 0.19 and 0.32. This is a very significant energy requirement and thorough analysis must be carried out to reduce this variability and energy requirements.

May 1, 2001

By N. Geoffroy, E. Benguerel, G. P. Demopoulos

In the late 1990s, a chemical process to remove mercury and selenium from weak sulphuric acid solutions was patented and implemented in the CEZinc refinery in Valleyfield, Quebec. The CEZinc process comprises two stages. In the first one, sodium sulphide is added to the weak acid solution in order to precipitate the soluble mercury. The solution is then treated with sodium dithionite in order to reduce the selenium to elemental form. Because of recent changes in the composition of the industrial solution, a project to study the background chemical reactions was started. In this paper, a review of the background chemistry is presented on the basis of several eh-pH diagrams on one hand, while on the other experimental results are reported dealing with the reaction of selenium (IV) species with either dithionite, sulphide or a combination of the two. According to this work, elemental selenium enjoys a wide pH-eh range stability with selenium sulphide being metastable. Selenium (IV) in single metal synthetic solutions was found to be reduced - to elemental state - at ambient temperature down to ppb range with dithionite as long as the stoichiometric ratio (dithionite/selenium) was in excess of two and the pH < 1.7. Under these conditions the reaction was very fast reaching completion within one minute. Sodium sulphide proved equally effective in reducing selenium (this time as selenium sulphide) to ppb range from single metal solutions. However, in mixed Se-Hg solutions deviations from this "ideal" behaviour was observed resulting in higher levels of residual soluble selenium left in solution.

Jan 1, 2008

By H. B. Sahu, N. M. Mishra, D. C. Panigrahi

The paper presents the development of a spontaneous heating liability index (SHLI) of coal based on a mathematical approach. The parameters for the calculation of this index have been determined by differential scanning calorimetric studies. Thirty-one coal samples representing both fiery and non-fiery coal seams of different ranks have been collected from different Indian coalfields and their SHLI values have been determined. In addition, the susceptibility of these samples to spontaneous combustion has been ascertained by standard crossing-point temperature measurement. The moisture percentage of all the samples has been obtained by proximate analysis. A comparative study between SHLI and crossing-point temperature, along with moisture percentage, indicates that SHLI predicts the proneness of coal to spontaneous heating more accurately.

Jan 1, 2008

By Linlin Tong, Xiangling Song, Guobao Chen, Zhenan Jin, Hongying Yang

Biooxidation of a high arsenic-bearing refractory gold ore was investigated to determine the arsenic removal efficiency by the cultured bacteria and to examine the effect of biological pretreatment on subsequent gold cyanidation. The biooxidation pretreatment process utilizes the ability of adapted acidophilic bacteria to oxidize pyrite and arsenopyrite and release the encapsulated gold. The released gold can be efficiently extracted by the subsequent cyanidation process. The biooxidation experiments were conducted with cultured bacteria using various sizes of agitation tanks. Leaching results showed that over 96.26 % arsenic extraction could be obtained from this ore after 6 days of bioleaching with continuous stirred tank reactor (CSTR). Gold extraction during the cyanidation process was increased from 29.35% to 96.71% after biological pretreatment. The content of arsenic in the biooxidation residue was reduced to below 0.3%. The transformation process of As was considered as [AsS]2- ? As (?) ? As (?) during the biological pretreatment.

Jan 1, 2014

By Y. Wang

In this study, homogeneous (unseeded) precipitation of nesquehonite (MgCO3.3H20) by the reaction of MgC12 with (NH4)2CO3 in supersaturated solutions at 30 °C was investigated. Factors which influence the precipitation of MgCO3.3H20, such as initial concentration, temperature, stirring speed, titration speed, equilibration time, have been studied. SEM images show that the initial concentration and titration speed have significant effect on nesquehonite&apos;s crystal morphology and particle size. In addition, stirring speed and equilibration time also have some influence on its properties. With the optimization of operating conditions, the crystals can grow up to a length of about 40µm and a width of 5µm, indicating good filtration properties. High purity nesquehonite obtained in this study was calcined to produce highly pure MgO at 800 °C as shown by XRD results. The novel process may be used to separate Mg and Li from high Mg/Li ratio brines in Qinghai, China.

Jan 1, 2007

By N. Schreithofer

The deposition of octadecylamine (ODA) at the KCI crystal/NaCI-KCI brine interface was investigated using atomic force microscopy (AFM). The AFM images of freshly cleaved KCI specimens immersed in KCI-NaCI saturated brine at room temperature reveal disappearance with time of the atomic steps and formation of cubic NaC1 crystals. These crystals were found to form when the specimen was withdrawn from the saturated solution. Depending on the way of contacting the specimens with the octadecylamine dispersion, the AFM images show huge differences in the deposition patterns of ODA on KCI crystals. Adequate dispersion was found to help the formation of quite even ODA coverage. The coverage was several monolayers thicker when air/brine/solid contact took place, suggesting that in the potash flotation the collector is likely to be carried to the solid surfaces by air bubbles. The presence of methyl-isobutyl carbinol (M IBC) enhanced the dispersion of ODA in brine, thus helping the spreading of the surfactant on the KCI crystal surface.

Jan 1, 2006

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016

By S. Esfahani, M. Barati

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, slags with different basicities were studied during non-isothermal cooling. Their continuous cooling transformation (CCT) diagram were plotted and compared with each other. Then, a mathematical model was developed that predicts the amount of crystallization during cooling. The results were validated by experiments performed by Single Hot Thermocouple Technique and image analysis. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow optimizing the slag/air ratio for both heat recovery and slag glass content.

Jan 1, 2015

By J. J. Mather

NEPHELINE SYENITE is a feldspathic rock resembling granite in texture and hardness but it is white in colour and contains appreciable quantities of the mineral nepheline, the result of a silica deficiency. It is relatively common, with known occurrences in Russia, Scandinavia, India, Canada, United States, and other parts of the world. However, the particular deposit being mined at Nephton, Ontario, by American Nepheline Limited is unique in its remarkable uniformity and low content of iron bearing minerals, both qualities essential in a ceramic raw material. The orebody is a pear-shaped mass over five miles in length, up to a mile in width, rising in three prominent ridges as much as 300 feet above the surrounding lakestudded terrain. American Nepheline holdings, consisting of 2,200 acres, comprise some 85 per cent of the total mass.

Jan 1, 1957

By N. Dobrin, R. Sheinman, Y. V. Kokotov, L. N. Braginsky

Increasing the production of a Mixer-Settler unit requires either increasing flow rates or increasing extractant concentration. The mixers still have to ensure complete emulsification and to maintain high values of specific interface surface area in order to provide a high rate of mass transfer. Theoretically, an increase in mixing intensity can support increased flow rates without reducing extraction efficiency. Unfortunately, conventional pump mixers and mixing systems create small droplets that do not separate easily. As pumping action and mixing intensities are increased, the quantity of small droplets increases. We describe the development and industrial application of a novel mixing system for efficient mass transfer without forming significant quantities of small droplets, targeting both high mass transfer rate and low entrainment values.

Jan 1, 2014

By A. Jordens, Y. Zhiyong

"IMBSRE, one of the largest rare earth element (REE) producers in China, produces a rare earth oxide (REO) concentrate as a by-product by floating the middlings stream from a low intensity magnetic separation step in the main iron ore processing stage. As the mine depth has increased, flowsheet changes in the main iron ore circuit have reduced the REO grade and increased the magnetite to REO ratio in the middling product used as flotation feed for the REO circuit. Extensive laboratory work was carried out and identified a new modified hydroxamic acid product, Florrea 8920, that could provide better metallurgical results over the standard hydroxamic acid used as the main collector. This paper briefly reviews the use of hydroxamates in the flotation of oxide minerals, provides detailed information on the different hydroxamates available from Florrea and then provides a case study of the successful implementation of the Florrea 8920 product in a commercial Chinese REE flotation plant. The case study consists of a one year program of pilot plant testing and industrial trials to confirm the results of laboratory tests. The implementation of the new collector resulted in an improvement in grade and recovery to 61% and 64% respectively. The new collector also provided significant economic and environmental benefits.INTRODUCTIONThe flotation of rare earth element (REE) bearing minerals is a topic which has been dominated in the English language literature by the work conducted on the Mountain Pass bastnäsite deposit (Pradip, 1981; Fuerstenau, Pradip, Khan, & Raghavan, 1982; Pradip & Fuerstenau, 1983, 1985, 2013; Fuerstenau & Pradip, 1991; Fuerstenau, Pradip, & Herrera-Urbina, 1992; Herrera-Urbina, Pradip, & Fuerstenau, 2013). By far the most important collector type used for the flotation of rare earth minerals (REM) is hydroxamates. These reagents were initially extensively described as REM collectors in the English literature by Pradip (1981) however they have been successfully applied to numerous other minerals such as: cassiterite (Sreenivas & Padmanabhan, 2002); pyrochlore (Gibson, Kelebek, Aghamirian, & Yu, 2015); hematite, chrysocolla, rhodonite, hubnerite and pyrolusite (Fuerstenau, 2005); and malachite (Lenormand, Salman, & Yoon, 1979) amongst others."

Jan 1, 2016

By R. St. C., G. E. Morris, M. Zbik, Smart

Effective flocculation and dewatering of slurry streams containing clays (particularly kaolin and smectites which are often <200nm in lateral dimension) is becoming increasingly urgent. Release of water (often >75 wt%), for recycle and reduced make-up water consumption, from slurries in tailings streams and dam beds is usually slow and incomplete. Changes in settling rates and solids density of tailings containing clays can be achieved in practice by changes in pH, dissolved cations and flocculant additions. To achieve fast separation of clays from water and minimization of retained water, individual particles need to be bound in the initial stages of thickening into large, high-density aggregates, which may sediment more rapidly with lower intra-aggregate water content. Quantitative STIMAN (STructural IMage ANalysis) cryo-SEM imaging, shows that the structure of aggregates formed before flocculant addition has a determinative effect on these outcomes. Without flocculant addition, 4 stages occur in the mechanism of primary dewatering of kaolinite: initially separate particles and aggregates are dispersed (<0.3GP, where GP is the gel point); a partially-gelled chain network then forms linking particles edge-edge (EE) still well below the OP but remains largely suspended; after an induction time, this network structure rearranges from EE to face-face (FF) contacts densifying, compacting and dewatering the aggregates with settling rates well above Stoke&apos;s Law estimates for >20µm particles or aggregates; the GP is rapidly reached during settling producing a network spanning the vessel with compressive strength. This sponge-like structure with EE oriented particles limits slurry dewatering because the steric effect in the resulting partially-gelled structure is much more dominant than the electrostatic effects predicted by DLVO theory. Van der Waal&apos;s forces at very close distances, as particles slide across each other, may be responsible for the EE to FF change in structure. In this way, the previously extended network contracts, and when the solid volume fraction is low, the continuous network breaks apart forming aggregates and aggregate associations as flocs which arc able to freely settle. These densified aggregates settle at increased rate, give lower bed density and retain less water after drainage. With flocculant addition, the internal structure and networking of the pre-aggregates is largely preserved but they are rapidly and effectively bound together by the bridging action of the flocculant(s). The STIMAN analysis shows that there is a inverse correlation of intra-aggregate porosity (and void permeability) with Darcian permeability (and extent of dewatering) whereas there is a strong positive correlation of Darcian inter-aggregate permeability with settling and primary dewatering rate.

Jan 1, 2004

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By J. G. Ross

IN the paper entitled Block Caving at the King Mine (1), which was presented at the Annual General Meeting held in April, 1934, at Quebec, it was pointed out that, owing to certain conditions and financial restrictions, it was advisable to provide a temporary shaft. This was raised from the )00-ft. level to the bottom of the pit, and a 45-degree incline track was constructed up the face of the pit to surface. The temporary shaft and incline were within the ore-body, but were to be used only until such time as the new shaft-the subject of this paper-could be sunk and made ready for operation. After a careful study had been made of all available information pertaining to the ore-body, including examination of diamond-drill core records and geological data, a shaft location was selected well outside the ore-body. Further, since the crusher and dryer buildings are located over part of the ore-body, it was necessary to plan the removal of these buildings and to construct a new crushing and drying plant. This, and the new shaft, must operate in conjunction with the present mill and rock storage bin, which would continue robe used as formerly. No part of this programme, with the exception of drifting toward the shaft site, was started prior to 1937. More than usual detail on technical features is given in this paper in the hope that some parts of it may be of assistance to other members of the Institute who have to undertake somewhat similar work. The engineering and operating staff designed and supervised the work, while at the same time carrying on regular production in four mines at the rate of 12,000 tons of rock mined per day, the output at the King mine being at the rate of 140 tons per hour. No additional engineers were required.

Jan 1, 1939

By AN. Kumar

Two fabrication stages in the manufacture of pipelines are identified as causing significant deterioration of the steel plates, namely cold bending and welding. The objectives of this work include quantitative assessment of the degradation of the quality of the steel plate by the loss of fracture toughness, and an estimation of the safe working pressure. The study was conducted on three API grade steels: X42, X46 and X60. After cold bending by the UO technique, various welding technique were employed for joining of the bend plates along the pipe length. A crack-tip opening displacement parameter (CTOD) was used at the onset of initiation and at the first load maxima as the criterion for assessing the toughness degradation under various fabrication stages and regime (such as WZ, HAZ and parent body). In addition, strength, hardness and impact energy values were determined to check the degree of degradation. Microstructural and microfractographic investigation of the fractured samples were also carried out in the scanning electron microscope (SEM). X60 grade steel plate suffers from CTOD toughness loss by around 38 and 55% after welding and cold bending, respectively, for the conditions studied. A combined effect of the two stages results in a loss in toughness by around 70% for the same steel. In X42 grade, the loss in impact energy ranges from 78 to 35 J due to electrical-resistance welding study (ERW). Crack resistance curves are also obtained for the steels to study the crack growth resistance behaviour and to supplement the information on crack initiation behaviour. The orientation of the pearlite banding, as observed on the fracture plane with respect to notch front and applied loading direction appears to have a strong influence on the microvoid-coalescence mechanism of fracture as well as the toughness values. An integrated analysis of the performance of pipelines, considering all these key factors, is discussed.

Jan 1, 2005

By H. Aminian

Gold powders have many important industrial applications. In this paper the available processes for the preparation of gold nano and micron sized powders are described. The attention has been given to hydrometallurgy route and the recent works and achievements in controlling the powder morphology are highlighted.

Jan 1, 2011

By Suman Giri

Non-Intrusive Load Monitoring (NILM) is a method of extracting appliance-level power consumption information from aggregate circuit-level data with the goal of giving users feedback regarding their energy consumption so they can take control of their consumption habits. In this paper, we present a novel algorithm for classification of on and off states of appliances. We compare the performance of our algorithm in on state detection with a pervious paper that evaluated the same dataset and show that it performs up to 13% better. We also present the results of a case study where we collected data for different modes of a cooktop, microwave and dishwasher and used our algorithms to perform power estimation. The error on ten different setups in the test bed ranges from 1% to 32%. We discuss our results and lay out ideas for future work.

Aug 1, 2013

By P. G. Claridge, G. P. Holmes, M. A. Redfearn

"IntroductionThe purpose of this chapter is to describe current practices in operation and maintenance of flotation circuits in Canadian mineral processing plants. The chapter consists of five sections covering description of equipment, typical flow diagrams, operating practice, instrumentation and maintenance. The approach to this subject matter is intended to be practical in nature, hence no deeply technical treatment of flotation theory will be included.Flotation is an extremely common method of beneficiation of ores. Reasons are the relatively low cost of flotation compared to many other processes, the wide range of minerals to which flotation may be applied and the high efficiency of separation which can usually be achieved. The flotation process as we know it today has been developed within this century and it has had a major impact on the mining industry. While flotation is commonly considered to be important because it provides a relatively simple method of separating minerals in complex ores, the availability of flotation has also made a multitude of mineral deposits in Canada into economically viable mining operations because it allowed production of a concentrate of valuable minerals from the ore. These concentrates could then be transported from geographically remote locations to centraHzed plants for further processing, although the existence of the remote and perhaps small ore body alone would not have justified installation of metallurgical processing plants on site and the grade of ore would not have justified direct shipment of ore.Some of the more common minerals concentrated by flotation are sulphides of copper, nickel, cobalt, iron, zinc, molybdenum, lead and arsenic, as well as non-sulphides such as sodium chloride, potassium chloride, phosphates, silicates, chromite, fluorite, limestone and coal. Precious metals are also recovered by flotation, generally in association with another sulphide mineral."

Jan 1, 1989