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By Douglas A. Karvonen

"Competition in the world potash market has increased significantly since the late 1970s. The failure of consumption to grow at expected levels has led to industry over-capacity, a situation which is likely to persist at least until 1990. Individual Saskatchewan producers and their offshore marketing company, Canpotex, have responded to this challenge by increasing mining efficiency, developing more cost-effective and reliable transportation systems and establishing innovative financing and market development programs tailored to customers' special needs. Investment in warehouse facilities to serve U.S. customers and exploration of opportunities for intermodal distribution through the Great Lakes and the Mississippi River system have maintained individual producers' position in the highly competitive domestic market.Export sales through Canpotex have been bolstered by utilization of CIDA funds, Exp ort Development Corporation financing guarantees and other innovative payment plans which enable heavily indebted developing countries to maintain the import levels which are necessary for their agricultural development.IntroductionPotash is the general term applied to various potassium salts both natural occurring and commercially derived. The most common of the commercial product s are potassium chloride, potassium sulphate and potassium magnesium sulphate. The potassium content of potash is measured in units of K20 equivalent. The common grades of potassium chloride produced for agriculture average at least 60 0/0 K20 compared with approximately 50% Kp for potassium sulphate and 22% for potassium magnesium sulphate."

Jan 1, 1985

By Marcio Luis S. Godoy

The Salobo Project will be the first Vale operation to use an HPGR mill to process copper-gold ore. The mine is located in Para state, southeast of the Amazon region in Brazil. The circuit was designed to treat 12 million metric tons per year of finely disseminated sulphide ore with high hardness. The comminution circuit comprises a gyratory primary crusher, secondary crushing utilizing two cone crushers, two 2 x 1.5 m HPGR operating in closed configuration with 6 mm screens, followed by two 26 x 40 ft ball mills. The concentration circuit consists of two rougher flotation stages using mechanical cells, regrinding with vertical mills, three cleaner stages with columns and one cleaner scavenger stage in mechanical cells. The concentrate is dewatered, filtered and transported by trucks and train to the port, to be exported. The circuit was designed on the basis of data obtained from a comprehensive laboratory and pilot plant campaign. The ore variability was assessed through simulation using data from a drilling core characterization program. The start-up of the industrial plant is planned for 2011. This paper describes the main aspects of circuit design, as well as information related to the beginning of the project construction.

May 1, 2010

By Peter A. Hacquebard

Recent drilling programs have shown that the in-situ coal resources of Nova Scotia are very substantial. The grand totals of the measured, indicated and inferred categories amount to 232 m, 646m and 993 m tons, respectively. This vast quantity of coal occurs essentially in five main fields: Sydney, Mabou, Port Hood, Pictou and Springhill. The largest resources (84% of the total) occur in the submarine area of the Sydney coalfield. With a 65% recovery rate, there are at present 150m tons of proven, recoverable coal in Nova Scotia. At a predicted maximum annual production of 5 m tons, this amount equals a lifespan of 30 years. However, additional drilling, particularly in the Sydney offshore area, holds promise of increasing the recoverable reserve tonnage to at least 350 m tons. This figure may be compared with the 484 m tons production obtained during 191 years of mining (from 1785-1976). The geological appraisal of the remaining coal resources in the five fields mentioned is presented in three-dimensional diagrams, per individual seam and corresponding reserve area. In addition, the submarine extensions of the Sydney and Mabou coalfields are discussed in light of results obtained from off shore oil exploration wells. The terminology and standards of coal resource calculations are pointed out, and the phenomenon of seam splitting and its prediction from geological data is illustrated. The availability in Nova Scotia of either thermal or metallurgical coal is considered in relation to rank and sulphur content. This paper was presented in June 1977 at the 90th Annual Meeting of the Mining Society of Nova Scotia. The coal resource estimates, however, have been updated to include the results obtained with the offshore drilling in the Sydney Coalfield to November 1977.

Jan 1, 1979

By G. Lucas

"Material substitution occurs continuously in response to competitive and economic pressures. Technical development can accelerate or slow substitution by improving the performance of the invading or defending material. The choices are seldom simple and have to be made in the context of continuous commercial change.The development and commercialization of a new aluminum material is examined. The material has been introduced into· several different markets, so it is possible to compare and contrast the degree of success obtained in each.IntroductionAluminum-based materials have been in use for over one hundred years and , therefore, the development of a new family of alloys is rare. In the early 1970s, Dr. L.R. Morris and his coworkers at Alcan' s Kingston Research Centre started work on what was, at the time, something of a scientific curiosity-a family of alloys strengthened by an unusual mechanism.This paper deals with the development and commercialization of what became known as the Alcan 255 alloys"". These alloys have found uses in several markets, usually as improved substitutes for existing materials. Forecasting the usefulness of a substitute material in an existing marketplace is difficult, in part, because even material users are seldom able to specify precisely their requirements. This uncertainty can cause the failure of some substitutions but can also lead to opportunities which were not initially obvious.Technical BackgroundPure aluminum is a soft, weak material. It can be strengthened by the addition of various alloying elements and by work hardening. Alloying elements usually act by forming solid solutions which are stronger than the pure metal or by precipitating during heat treating or aging and so preventing the easy movement of dislocations during deformation. Elements which can perform either role had been investigated for decades and were thought to offer little chance of technical breakthrough in 1970. An outgrowth of the then new and exciting research on directional solidification seemed, however, to offer such promise.Some aluminum-iran-manganese alloys will solidify under certain conditions as 'coupled growth' eutectics (Figs. I and 2). The microstructure shows one phase growing as long rods through the other. This is an uncommon structure and it was investigated to see if it had equally unusual properties. On deformation by rolling the rods were broken up into small equiaxed , evenly-spaced particles (Fig. 3). Materials with this structure were found to be stronger than other alloys with similar amounts of alloying addition, and to resist thermal softening remarkably well. This combination of properties was thought initially to be due directly to the particles by a dispersion strengthening mechanism, but later this was found not to be strictly true."

Jan 1, 1987

By Ian R. Morrison

"Abstract - The Izok Zn-Cu-Pb-Ag volcanogenic massive sulfide deposit is located 265 km south of Kugluktuk (Coppermine), Nunavut Territory, Canada, in the west-central Slave structural province. The Izok deposit is owned 100% by Inmet Mining Corporation and represents one of the largest undeveloped zinc-copper resources in North America. The Izok deposit is hosted within and near the top of a thick sequence of predominantly felsic pyroclastic rocks of late Archean age. The hanging-wall stratigraphy includes additional felsic volcaniclastic rocks, andesitic and basaltic flows, thin sulfide-rich iron formations, and turbiditic sedimentary rocks. The felsic volcanic rocks are intruded by intermediate dikes and sills, followed by gabbroic dikes and sills. Both intrusive suites are interpreted to be volcanic feeders to the overlying flows. All lithologies are subsequently cut by younger, irregular, granitic pegmatite and diabase dikes. The volcanic and sedimentary rocks are regionally metamorphosed to pyroxene hornfels grade. The massive sulfides occur within a large (kilometer-scale) Na-depleted sericitic alteration zone. The immediate footwall and hanging-wall rocks to the deposit are characterized by zones of muscovite- biotite-sillimanite, lesser chlorite-biotite-cordierite, and locally intense silicification and sodium metasomatism. All lithologies have been affected by younger Ca-metasomatism. As currently defined, the Izok deposit comprises a cluster of five complexly zoned composite lenses: the Northwest, North, Central West, Central East, and Inukshuk lenses. The first four lenses are amenable to open-pit mining, whereas the Inukshuk lens will require underground development. The total indicated mineral resource presently stands at 16.5 million tonnes with a grade of 2.2% Cu, 11.4% Zn, 1.1% Pb, and 60 g/t Ag. Inmet Mining Corporation is presently reviewing the economic feasibility of developing the property."

Jan 1, 2004

By M. Sengupta

International trade in minerals plays a very important role in the economic growth of many nations. Several less developed countries a1•e heavily dependent on their mineral exports for earning foreign exchange, which is needed for industrialization. Mineral exporting nations experience many problems in international mineral markets; the most important are tariff barriers, deteriorating terms of trade, instability in metal prices, etc. The formation of international mineral cartels to raise prices can be successful only to a limited extent and only for a short period of time.

Jan 1, 1976

By M. P. Filion, K. Ferguson, L. L. Sirois

Acidic drainage is the largest single environmental problem facing the Canadian mining industry today. Technologies to prevent acidic drainage from occurring in wasterock piles and tailings sites, and on the walls of open pits and underground mines, need to be developed and demonstrated. There are two groups in Canada which have accepted this challenge: the national Mine Environment Neutral Drainage (MEND) program and the British Columbia Acid Mine Drainage (BCAMD) Task Force. This paper summarizes the activities of these two organizations.

Jan 1, 1990

By J. Peck, M. J. Scobie, M. D. Pollitt

"IntroductionOne aspect of current research in the Canadian Centre for Automation and Robotics in Mining (CCARM) involves the automatic identification of different rock types based on particular drill performance parameter responses. In this paper, the four drill performance parameters of torque, pulldown pressure, rotary speed and penetration rate, were measured from an instrumented rotary blasthole drill during field investigations undertaken at the Fording River Mine, Elkford, British Columbia. The variations in these parameters were subsequently correlated with the corresponding rock types using the results from gamma, neutron and core logs in the same or adjacent boreholes. Work to date has sought to understand the relationships between drilling performance parameter variation and rock properties. Using the results of these studies, the present research is aimed at developing techniques whereby classical statistical pattern recognition methods are applied to drill data to permit the discrimination of different rock units. A monitoring system incorporating such a capability would greatly enhance the quality and amount of geological information on a per borehole basis while drilling. This data in tum could be used economically and directly towards explosive loading, geological exploration and reserve estimation. Background and PhilosophyThis work is an extension of equipment monitoring studies at the Fording River Mine. At this site over a two-year period, 5180 m of data was acquired on an instrumented Bucyrus-Erie 60R drill during routine production blasthole drilling. Throughout these studies, a 311mm diameter S8M Security tungsten-carbide tricone bit was used. The mine, located in southeast British Columbia, is a large-scale, open pit coal operation. The means of excavation revolves around a drill-blast-muck cycle and employs a standard shovel-truck system of transport. Four main rock types are present: sandstone, siltstone, mudstone and coal, with average compressive strengths ranging from 10 MPa to 150MPa respectively (peck 1989). However, based on the field studies, very few differences in terms of strength and compositional properties were seen between the sandstones and siltstones at the site. Therefore, they are referred to as sandstone/siltstone in all further discussions."

Jan 1, 1991

By D. H. Rousell

"Rocks of the Whitewater Group (Aphebian age) oc ithin the Sudbury Basin and consist of three formations rre, from oldest to youngest: Onaping, heterolithic breccias lus an igneous-textured component; Onwatin, argillite and siltstone; and Chelmsford, greywacke with minor argillite with siltstone. Mineralization in these rocks is as follows:1) Sulphides are disseminated throughout the Onaping Formation. Pyrrhotite, the major sulphide mineral, occurs mainly as fragments; other sulphides are chalcopyrite, sphalerite, galena, pyrite and marcasite.2) Zn, Pb, Cu, Ag and A u mineralization in the Vermilion member, a carbonate-chert unit near the base of the Onwatin Formation (Vermilion and Errington mines).3) Pyrite and minor base metals in the Onwatin Formation .4) Mineralized quartz veins, located at or near the base of the Onaping Formation, include such deposits as Moore Lake (Pb, Zn and Ag), Foisey (Zn, Pb), Papineau (Cu, Au and Co) and Proulx (Pb, Zn, and Cu). Quartz-carbonate veins in a meta-gabbro sill contain Cu, Zn, As and Au. Material from quartz veins from two former ""gold mines"" (Gordon Lake and Creighton) yielded no Au values.5) Anthraxolite veins in the Onwatin Formation .The mineral occurrences can be explained in term of either the volcanic theory or meteorite-impact theory of basin formation. According to the latter theory, the sulphide fragments in the Onaping Formation may have been formed by the brecciation of sulphide-rich pods located in the upper mantle and at the base of the transient crater; some of the sulphides may have been derived from target rocks of the Huronian Supergroup. The Vermillion-Errington deposits may represent sedimentary exhalative deposits of the Remac type; mineral-rich brines, trapped at the base of the transient crater, rose upward and precipitated the mineralized carbonate-chert under reducing conditions. These conditions continued throughout the deposition of the upper Onwatin Formation but pyrite was the only sulphide that formed.The quartz veins were emplaced during the time of basin deformation. Metamorphism remobilized and concentrated carbonaceous material in the Onwatin Formation 10 form the anthraxolite veins."

Jan 1, 1984

By Joanna LaForte

"IntroductionIn respect to The Human Dimension by M. Phyllis Bray, this author's impression is that research on long distance commuting (LDC) is long overdue. This type of mining is not new to many workers, especially those from areas such as the Maritimes, who have had to look for work away from their families for at least a decade. Perhaps to the industry the over-all set-up is new, but to workers who have faced mine shut-downs in their areas finding a job was the main objective and if the security of long-term employment was evident, then the families might join them later. This was the situation with which the writer' s family was faced.LDC LifestyleBeing the wife of an underground miner, the author has personally experienced this lifestyle for almost 10 years, and has never experienced accommodation in a company town. The first five years of marriage were spent in a small rural municipality within 50 miles of the worksite, but the town had industry separate from mining and was not affected by the mine shut-down.Since her LDC lifestyle began her family has been pretty much city-based, out-of-province commuters with two children and a third to arrive some years later. She therefore lived a fairly normal married life with a husband home daily. The author has experienced life with a husband who worked away for five-day stretches and then drove long distances to be home weekends or the portion of time left over from driving and fatigue. She has done the 3D-days in/l4-days out routine, and for approximately the past four years has been existing on a two-weeks in/two-weeks out ritual .The author does not agree that the ""bottom line is that mining families go where the jobs are"" . The miners go where the jobs are and the families fend for themselves with the assistance of the pay cheque making it home each pay period.Perhaps because there are many personal frustrations with this type of lifestyle, perceptions may be inaccurate. Having only dealt with underground operations, there may be gross differences between the pressures and demands of other forms of mining."

Jan 1, 1991

By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By Eric Pirard

"A mineralogical and trace element analysis was performed on the Küre historical slags in order to evaluate the possible recovery of copper and cobalt. Reflected light microscopy, electron microprobe and image analysis were combined to determine the Cu and Co distribution in the slag.The results indicate that 81% of the total cobalt is chemically combined in the fayalite whereas only 3.4% is in the mechanically entrapped sulphides. The remainder being in hercynite and wiistite. On the other hand, 95% of the total copper is in the sulphide phase.This kind of applied mineralogical investigation gives invaluable information when it is performed preliminary to metallurgical experiments.IntroductionThe recycling of metallurgical slags is a growing business. The operation is directed toward recovering base metals (Cu, Pb, Zn), and by-products (Floyd and Mackey, 1981).Two reasons are invoked to explain metallic losses in slags: (1) mechanical entrapment of matte globules in the silicate melt; and (2) chemically combined metals in the slag-forming phases. Obviously, a chemical analysis of the slag cannot distinguish between those two modes. Grinding and flotation of the liberated sulphides have often been used to evaluate the importance of mechanical entrapment (Mechev, 1970; Imris , 1982).Recent studies in applied mineralogy of pyrometallurgical products (Bérubé et al., 1987; Pignolet et al., 1986) have demonstrated the benefits of quantitative mineralogical analyses of slags. Optical microscopy together with electron microprobe and image analysis offers a powerful and easy way of quantifying the relative importance of mechanical and chemical losses."

Jan 1, 1991

By R. E. G. Caines, P. Alport

"Operating heavy equipment in Labrador, where the winters are 8 months long and the temperature frequently drops below -40°F (-40°C) for days and sometimes weeks presents unique problems in both the operation and maintenance junctions. Winterization programs must be well designed and implemented at the proper time. These programs must include the proper selection of fuel oil, engine oil, hydraulic oils, greases, cooling system fluids, etc. More often than not, modifications have to be made to the original equipment in order that it can be operated safely and economically in the Canadian North. Manufacturers usually design equipment for a less harsh environment and the user makes adaptations by trial and error.Operators have to be trained for the proper operation on ice- and snow-covered roads in an open-pit mine. Special emphasis must be put on haulage road conditions. In this paper, the authors will cover some specific maintenance procedures, equipment modifications and operator training problems experienced by the Iron Ore Company of Canada in its open-pit operation in Labrador.IntroductionT he Iron Ore Company of Canada is engaged in open-pit mining , concentrating and pelletizing of iron ore. The company operates in two provinces, Quebec and Newfoundland (Fig . 1) . The Knob Lake operation "", based in Schefferville, Quebec, has mine sites located both in Labrador and Quebec . The Caro l Lake Project is situated in Labrador, 25 kilometres east o f the Quebec border at Labrador City. The Carol operation mines, concentrates and pelletizes it s o re before rail transportation to the seaport o f Sept-lies via the Quebec North Shore and Labrador Railway."

Jan 1, 1984

By D. Doyle, T. Cienski

"This paper presents and discusses the results of a detailed study conducted on the subject of energy consumption in the comminution of industrial minerals. The study was based on pilot circuit testing, plant operating data collection, detailed equipment data and literature research. The areas covered by investigations include: high efficiency classification; air classifiers for cement grinding circuits; grinding aids in dry grinding; and dry grinding circuit control based on particle size measurement. Results obtained indicate a large potential for the reduction of energy consumption, in particular in the cement clinker grinding circuits. Better classification techniques and correct application of grinding additives can significantly reduce power used per tonne of product and also substantially increase grinding circuit output."

Jan 1, 1992

By Jian Deng, Haitian Sun, Zengqian Hou, Shuhe Song

"Abstract - Volcanogenic massive sulfide (VMS) deposits, an important base-metal deposit type in China, occur widely in submarine volcanic districts of variable magmatic affinities. These VMS deposits range in age from Archean to Mesozoic, but most are in Proterozoic and Paleozoic sequences. More than 60% of VMS deposits formed in the Paleozoic, the most important metallogenic eon. Three important Paleozoic VMS-metallogenic provinces include Northern Qilian, Sanjiang and Altai provinces. The Proterozoic constitutes the next important era, but with no VMS deposits in the middle Proterozoic. VMS deposits associated with the Proterozoic volcanic rocks occur around the Yangtze Platform and in the western Kunlun-Qinling. The Triassic is third in importance, with VMS deposits concentrated in the Sanjiang Tethys. The Archean has only one VMS deposit, on the northern margin of the Sino-Korea Platform.Five distinct compositional classes of Chinese VMS deposits have been distinguished: Cu, Cu- Zn (or Zn-Cu), Cu-Fe, Zn-Pb-Cu, and Pb-Zn (-Cu). The Cu, Cu-Co, and Cu-Zn types of deposits occur sporadically from the Archean to Paleozoic, and are closely associated with mafic and ultramafic volcanic sequences. The Zn-Pb-Cu and some Cu-Zn type deposits are restricted to the Paleozoic and Triassic, and are hosted by calc-alkaline felsic rocks in bimodal basalt-rhyolite sequences, whereas Cu-Fe and Pb-Zn type (except for the Laochang deposit) deposits are restricted to the Proterozoic and occur in calc-alkaline volcanic sequences. As large quantities of marine mafic volcanic rocks were deposited in western China, Cu and Cu-Zn deposits are major types of Chinese VMS deposits.Chinese VMS deposits formed in a wide range of paleo-tectonic settings and depositional environments, such as island-arcs, rifts, aulacogens, and ocean ridge hot spots. Among these, the rift and back-arc environments are the most important, containing about 60% of Chinese VMS deposits. Aulacogens are a subordinate environment where most of the Proterozoic VMS deposits formed. The oceanic ridge and hot-spot systems are common in the tectono-magmatic domains in China, but contain only a few small Cu and Cu-Zn type VMS deposits.The Chinese VMS deposits have usually been influenced by both deformation and metamorphism to various degrees, resulting in changes in the shape and metal distribution. Seven representative deposit styles have been recognized: sheets, sheet plus strata-bound stringer, cyclically zoned deposits, mounds, mound-like deposits, strata-bound stringer-disseminated, and stockwork-disseminated deposits. The formation of these various styles of deposits is controlled by several key factors, such as lithology and permeability of the host rocks, focused or unfocused discharge, temperature and chemical composition (e.g., salinity) of hydrothermal fluids, as well as depth of seawater."

Jan 1, 1999

By A. P. E. Dirige

In order to maximize the recovery of ore and to save on costs in undercut mining, backfill of low cement content is used to fill the mined out excavations. This backfill mass is supported by a sillmat structure cast from cemented backfill of very high strength. The stability design of sillmats must be carefully studied to provide very effective, safe and economic mining operations. This paper presents a methodology and procedures for sillmat design based on three engineering modeling approaches: analytical, numerical and centrifuge modeling. Application of the design approach is demonstrated from a design study conducted for an underground gold mine, aimed at minimizing backfill binder content and at producing cost efficient paste fill recipes for sillmat construction. Application of the engineering design recommendations was projected to result in substantial annual cost savings to the mine operation.

May 1, 2007

By George J. Simandl, Suzanne Paradis, Kirk D. Hancock, Jana Simandl

Traditional prospecting and boulder tracing are the two most important field techniques used in exploration for magnesite deposits hosted by sedimentary rocks. Consequently, success depends largely on the prospector&apos;s ability to identify magnesite. A density agent called sodium polytungstate (3Na2W04·9WOj&apos;HPJ was successfully used to determine the presence of magnesite in sedimentary carbonate rocks of southeastern British Columbia. A rapid field method was developed and tested. This method permits discrimination between limy dolomites, dolomites, magnesite-bearing dolomites and magnesite-rich rocks.

Jan 1, 1993

By C. P. Verschuren, P. W. Kingston, W. F. Caley

"In recent years, there has been rapid growth in the use of natural stone building and construct ion products. The largest growing markets are for pre-fabricated natural stone panels for interior and exterior wall facing and flooring. This increased demand is attributed to advanced quarrying and processing technologies, renewed appreciation for the aesthetic appeal of natural stone, and to the superior durability of natural stone when compared to glass, steel, and concrete. Geologically, plutonic rocks, and to a lesser extent marble and limestone/dolostone, are used extensively for these applications. This paper details the economic structure of the dimension stone industry, describes the necessary characteristics of a stone quarry, and outlines the geological criteria which favour an economic quarry.INTRODUCTIONThe world building stone industry has remained relatively stable over the last 5 to 6 years. In contrast, the North American stone industry has experienced substantial growth during that period. The increased use of commercial granite is primarily responsible for this growth, where use as exterior wall veneer for commercial, industrial, and institutional buildings represents the largest and fastest growing market.This increased usage in the construction industry has been sparked by the application of new technologies in quarrying, processing and installation , ma king natural stone more competitive with man-made materials which are energy intensive to produce, and have risen dramatically in price. The development of safer, time-saving stone installation techniques has also appealed to the liability-conscience construction industry. Finally, there is a trend by designers and architects toward utilizing long-la sting weather-resistant building materials, and a renewed appreciation of the aesthetic appeal of natural stone. The other large user of granite is the monument industry of North America which, although it has decreased slightly in recent years, still consumes approximately 40% of all commercial granite produced. The local use of commercial marble has remained relatively stable, and North America still relies heavily on European sources and suppliers. There has been some concern over the use of marble for exterior applications in areas subject to acid rain, and in colder climates where the marble ma y be vulnerable to freeze thaw cycles. Despite these concerns, the greatest problem is not with the structural breakdown of marble but the inability of some marbles to retain their polished finishes in the se environments. As a result, there has been an increase in the use of granite at the expense of marble for exterior applications. Finally, commercial marble is used extensively for interior flooring, wall s, counter tops, furniture, sculptures, and stairway components"

Jan 1, 1989

By G. Tairova, M. Murchie, B. Esford, E. Lam

"The objective of this project is to investigate methods to lower the sulphate concentrations in the mill effluent. Currently, the concentration of sulphate in mill effluent is approximately 2 g/L. The high concentration of sulphate ion in the effluent has the potential to become a regulatory issue. The target sulphate concentration in mill effluent for this work was less than 500 mg/L. The pilot studies, using sulphate precipitation, were carried out at the mill. The results of the sulphate precipitation pilot study, using calcium hydroxide and sodium aluminate, indicated that:• The sulphate concentrations in effluent could be reduced to less than 500 mg/L.• The concentrations of most other elements of concern, such as selenium, arsenic, cobalt, nickel and vanadium, were also reduced.INTRODUCTIONHistorically, the concentration of sulphate, SO4 2-, in water has not generally been subject to regulation. However, with the increasing global consumption of water, stricter regulations on sulphate quantity may be imposed. Sulphate is a concern in process waters as it forms scale on process equipment and leads to operational problems. High sulphate concentrations may result in adverse health effects. The taste theshhold for the most sulphate salts in drinking water ranges from 250 to 500 mg/L.A literature search and review to identify methods to reduce sulphate concentration in the mill effluent was carried out. A number of methods were selected and tested in the lab. The experimental results indicated that the precipitation methods, using calcium hydroxide and aluminum compounds, barium compounds, as well as the ion exchange and the membrane methods, were effective for the removal of sulphate to below the required limits. Some other elements, such as vanadium, nickel, cobalt, selenium and molybdenum, were also removed.The process, using calcium hydroxide and aluminum compound for sulphate precipitation, similar to the Cost Effective Sulphate Removal (CESR), also known as “Walhalla” process, described in the Montana Tech report (“Demonstration Of Sulfate Removal” 1999), was selected for further consideration [1]. In the CESR process, the water is treated with lime for precipitation of gypsum, followed by the reaction with a proprietary aluminum compound for removal of a residual sulphate. The final pH adjustment is carried out using carbon dioxide. Results of a preliminary cost estimate indicated that the removal of sulphate using calcium hydroxide and aluminum compound was the preferred method of treatment, considering its low cost, availability of chemicals and minimal changes to the existing plant circuit."

Jan 1, 2012

By J. Boulton

"Nuclear energy is an established and proven energy source. Today, CANDU-PHW nuclear-electric generating stations produce over one third of Ontario&apos;s total electrical supply: safely and economically. In many parts of Canada, where economic hydro resources do not exist or are fully developed, coal and nuclear energy are the only alternatives for future large-scale electrical generating capacity.Recent analyses have suggested that, in the f ace of increasing energy demands and decreasing reserves of hydrocarbon fuels, Canada must depend on electricity to provide an expanded fraction of its energy budget. Nuclear energy is likely to play an increasing role in the generation of electricity; there are also potential applications as a supplier of process heat in industry and in the in-situ recovery of bitumen fro m tar sands.The future supply of nuclear fuel, reactor safety and radioactive waste management are briefly discussed. In each case, the benefits to be gained from a controlled expansion in the use of nuclear energy outweigh any uncertainties which may exist."

Jan 1, 1981