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By R. A. Ixer, R. A. Lord, H. M. Prichard, A. J. Boyce, P. McConville, C. T. Pillinger, I. P. Wright, J. Maynard

Analysis of 62 samples show that the sulphides throughout the igneous stratigraphy have a magmatic signature, with the exception of the uppermost gabbros and the lowermost basal thrust talc-carbonate lithologies. Mean delta-34S values for whole-rock samples from harzburgites, dunite pods in harzburgite, crustal dunites and wehrlites, the main and high-level pyroxenites and gabbros suggest that the primary sulphides derived their sulphur from a magmatic source enriched in 34S. This finding is compatible with the proposed origin of the ophiolite above a subduction zone. Values for pyrite mineralisation in the uppermost part of the gabbros are thought to result from precipitation from a seawater-derived fluid, while isotopically light sulphur in the basal thrust could have been introduced from underlying metasediments. The replacement of pentlandite by heazlewoodite has not led to sulphur fractionation

Jun 19, 1905

By M. E. D. Raymont

"During the history of the sulphur industry there have been three distinct phases of production. Factors controlling supplies during these periods have shifted from demand for sulphur to demand for energy and a cleaner environment. The pattern of brimstone production is t raced through these phases and includes estimates of future supply; these indicate an involuntary excess production of some 20 million plus tons per year by 1980 unless some large-scale new uses are found. Traditional uses for sulphur, including fertilizer, chemicals, fibers, etc., are generally expanding slowly; how• ever, supply in ""by-product"" form alone will soon outstrip demand. The predicted oversupply situation can be corrected by the development of novel potential markets. Promising areas include construction materials, insulation and plastics, among others."

Jan 1, 1972

By K. Loutet, A. Guenkel, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985. Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. The sulphur dioxide (SO2) for this process can be supplied either as liquid SO2, SO2 gas or as a sulphite-based salt. The majority of SO2/air operations have used sulphite-based salts as the ‘SO2’ equivalent probably due to low capital cost. Liquid SO2 has also been used frequently, but due to concerns with safety and availability, this option is often not preferred. The solid salt sodium meta-bisulphite (SMBS) is commonly employed, but its cost is an order of magnitude higher than that of sulphur. Due to the high cost of SMBS, the increased capital cost for a sulphur-burning SO2 gas plant (green field or retrofit) usually has a pay-back of less than three years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas volume. Therefore, a SO2 gas plant will not trigger the Canadian Environmental Protection Act (CEPA) E2 Regulations or the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and El Boleo).This paper focuses on the production of sulphur dioxide gas generated on site and on demand for the use in hydrometallurgical processes. The capital and operational costs of a SO2 gas plant is compared to conventional process alternatives using sulphite-based salts or liquid SO2."

Jan 1, 2016

By L. B. Gittinger

Mr, Chairman, members- and guests of the AIMS, I greatly appreciate this opportunity to speak before you. I hope this is just the beginning of a long and mutually beneficial relationship. This winter I decided to join the other 36 Freeporters who belong to the AIME; and, I applied for membership in the Society of Mining Engineers. To queries as to my interests in the Society, I had this answer: our principal challenge -- more so today, than at any time in my nearly 25 years in the industry -- is discovery and development of new sources of raw materials. I want to join you in meeting this challenge.

Jan 1, 1966

By P. A. Olubambi

The leaching of zinc and copper from Nigerian bulk sulphide ore with sulphuric acid in the presence of hydrogen peroxide was studied. The aim of the study was to investigate the effectiveness of hydrogen peroxide as an oxidant for the sulphuric acid leaching of zinc and copper from a complex sulphide ore. Distribution of elementals within the various particle sizes was initially determined by ICP-OES and XRF to provide a basis for explaining the dissolution process. The effects of concentration of hydrogen peroxide, particle size, stirring speed, and leaching time at a constant temperature of 298K were studied. There were variations in elemental and mineralogical composition within the different sizes. The concentrations of zinc and copper reduced as particle size decreased while silica, sulphur, iron and lead contents increased. Dissolution results showed that the leaching rate of copper was lower than that of zinc. The highest recoveries of zinc and copper were obtained at a leaching time of 180 minutes, stirring speed of160 rpm, particle size of 75 µm and a concentration of 1M H2SO4/1MH2O2. It was observed that the leaching rate of zinc and copper increased with increasing hydrogen peroxide concentration. Increased stirring speed had a negative leaching effect as it promotes hydrogen peroxide decomposition. Keywords: Nigerian sulphide ore, zinc, copper, hydrometallurgy, sulphuric acid, hydrogen peroxide.

Jan 1, 2006

By P. A. Olubambi

The leaching of zinc and copper from Nigerian bulk sulphide ore with sulphuric acid in the presence of hydrogen peroxide was studied. The aim of the study was to investigate the effectiveness of hydrogen peroxide as an oxidant for the sulphuric acid leaching of zinc and copper from a complex sulphide ore. Distribution of elementals within the various particle sizes was initially determined by ICP-OES and XRF to provide a basis for explaining the dissolution process. The effects of concentration of hydrogen peroxide, particle size, stirring speed, and leaching time at a constant temperature of 298K were studied. There were variations in elemental and mineralogical composition within the different sizes. The concentrations of zinc and copper reduced as particle size decreased while silica, sulphur, iron and lead contents increased. Dissolution results showed that the leaching rate of copper was lower than that of zinc. The highest recoveries of zinc and copper were obtained at a leaching time of 180 minutes, stirring speed of 160 rpm, particle size of 75 µm and a concentration of 1M H2SO4/1MH2O2. It was observed that the leaching rate of zinc and copper increased with increasing hydrogen peroxide concentration. Increased stirring speed had a negative leaching effect as it promotes hydrogen peroxide decomposition. Keywords: Nigerian sulphide ore, zinc, copper, hydrometallurgy, sulphuric acid, hydrogen peroxide.

Jan 1, 2006

By R. J. Forzatti

The production of sulphuric acid from sulphur generates heat. The majority of this heat is recovered as steam and is often used to generate electricity. Heat not recovered as steam is rejected to cooling water systems. The design of the turbine, condenser, and cooling water systems impacts the overall water, energy, and environmental footprint of the plant. This review considers a conceptual 2000 t/d sulphuric acid plant with several alternative cooling water systems. The review utilizes Hatch?s 4 Quadrant sustainable design tool to compare the alternatives on both an economic and a weighted sustainability scale.

Jan 1, 2014

The production of sulphuric acid at Port Pirie by the contact process began in March 1924 with the commissioning of the Electrolytic Zinc Co.'s roasting and acid plant. This plant, operated by B.H.A.S. Pty. Ltd. on behalf of the E.Z. Co., continued to produce sulphuric acid from the gases evolved when roasting Broken Hill zinc concentrate in mechanically rabbled furnaces until September 1954, when the plant was closed down.In this peri9d of approximately 30 years some 600,000 mono tons of 98·5 per cent sulphuric acid was produced, most of which was used for fertilizer production at Wallaroo and Port Adelaide. During World War II 14,400 mono tons of the above was produced in the form of 20 per cent Oleum and railed to the Salisbury Munitions Factory for use in the production of nitro-glycerine, gun-cotton and T.N.T.In the early post-war period various ways of converting at least some of the sulphur in the gases' discharged to atmosphere from the lead sintering plant were considered until, in 1949, it was decided to erect a modern contact acid plant. Much work remained to be done on the roasting plant to produce a gas of suitable grade for the contact process and also on the design of a purification section suitable for the treatment of D.L. gases.The acid section itself, however, was largely of conventional design and it was therefore decided that this would be erected first. To it was then attached a sulphur-burning section to allow it to operate as a "hot gas" brimstone acid plant until the roasting and gas purification plants had been designed and erected. In this way the urgent need for sulphuric acid in the fertilizer industry would be relieved, to some extent at least, as soon as, possible.

Jan 1, 1956

Plant for the production of sulphuric acid from pyrites flotation concentrates was commissioned at Cockle Creek during 1956, to meet increasing demands for commercial acid and superphosphate. Pyrite was chosen as raw material because of the uncertain supplyposition of imported brimstone and the desirability of utilising domestic sulphur.Desulphurisation of the pyrite is performed by two 40-ton per day roasters of the Turbulent Layer type operated under licence from the Badische Analin and Soda Fabrik (B.A.S.F.) organisation. These units are the first of their kind commissioned in the southernhemisphere. Pyrite is fed to the roasters in the as-received un-dried condition. Waste heat steam production is coupled with electricity generation within the plant. Sulphur dioxide is produced at comparatively high strengths and cleaned by conventional cyclone and hot electro-filter equipment.The acid unit has a capacity of 100 mono tons of sulphuric acid per day and includes cooling and wash towers, mist precipitators, a single stage drying tower, 4-pass oxidation section and absorption system.INTRODUCTIONSulphuric acid has been manufactured at Cockle Creek Works since 1913, when the first chamber nitration plant was commissioned. The raw material was brimstone roasted in Herreschoff furnaces. Since that time three additional chamber units have been constructed and have produced acid from brimstone, zinc concentrates, pyrites and -spent oxide, according to changing economic and supply factors.Three chamber units are still in operation. Contact processes have become increasingly important since the first Schroder-Grillo unit was commissioned in 1923. Six of these 5-ton per day units were operating in the mid-thirties, but have since been demolished. Two 15 ton Chemico hot gas contact units commenced operation in 1937 and 1938, and although modified, are still in service.The increasing demand over recent years for sulphuric...

Jan 1, 1957

By W. Vorster

Bateman Engineering Project's acid-plant track record goes back to 1977. Bateman Engineering can design sulphuric plants based on gas from sulphur burners, metallurgical off gas as well as pyrite roasting systems. Bateman Engineering has a technology marketing agreement with NORAM Engineering Ltd of Canada to provide state-of-the-art, well-proven acid plant technology, and also has access to roaster technology from several sources, including Chinese technology. Utilising the Noram technology agreement, Bateman was awarded the Engineering and Procurement (EP) contract for the Ambatovy Nickel Project, Sulphuric Acid Facilities in 2007. This is the first Greenfield sulphuric acid plant Bateman has designed for many years, producing a combined 5,500tpd, and is one of the largest sulphur burning acid plants in the world. This paper gives an overview of the sulphuric acid plant for the Ambatovy Nickel Project, advantages of Noram?s unique technology on offer, an overview of work conducted on a recent study of an pyrite roasting acid plants as well as a new technology currently being developed by Bateman for the direct combustion of solid sulphur to form sulphur dioxide.

Jan 1, 2009

By W. Vorster

Bateman Engineering Project's acid-plant track record goes back to 1977. Bateman Engineering can design sulphuric plants based on gas from sulphur burners, metallurgical off gas as well as pyrite roasting systems. Bateman Engineering has a technology marketing agreement with NORAM Engineering Ltd of Canada to provide state-of-the-art, well-proven acid plant technology, and also has access to roaster technology from several sources, including Chinese technology. Utilising the Noram technology agreement, Bateman was awarded the Engineering and Procurement (EP) contract for the Ambatovy Nickel Project, Sulphuric Acid Facilities in 2007. This is the first Greenfield sulphuric acid plant Bateman has designed for many years, producing a combined 5,500tpd, and is one of the largest sulphur burning acid plants in the world. This paper gives an overview of the sulphuric acid plant for the Ambatovy Nickel Project, advantages of Noram?s unique technology on offer, an overview of work conducted on a recent study of an pyrite roasting acid plants as well as a new technology currently being developed by Bateman for the direct combustion of solid sulphur to form sulphur dioxide.

Jan 1, 2009

THOUGH the literature on the chamber process is considerable, it mostly refers to European conditions. Owing to the demand for acid for flotation and leaching at the mine, it may be necessary to work the process under other conditions. Consequently, some results obtained during the chlorination days at Mount Morgan, within the Tropic of Capricorn, may be useful for reference when working in a similar climate. Though the chambers must be protected against tropical storms, thorough ventilation should be provided, with plenty of space between the chambers, which are almost invariably crowded together. Not only does the space assist in the cooling of the chambers, but it is very desirable during repairs, when lead andtimber have to be hoisted up. The connecting flues between the chambers, which are fairly efficient mixers and condensers, should be round, supported from above, and with the least possible timber about them. Their position and arrangement deserve careful attention. Lattice work will be sufficient protection for the sides of the chambers, and the roof should be high and well ventilated. The Mount Morgan plant, crowded and not well situated, consisted of seven chambers (four over 50 ft. in length), one Glover tower 7 ft. 2 in sq. x 20 ft. high, one Gay Lussac 9 ft. sq. x 30 ft. higb, also one 5 ft. diam. x 25 ft. high. There was one pipe column 4: ft. sq. x 14 ft. 6 in. high. The chambers were run as one unit, and were much lower than those usually constructed in Europe-less than 15 ft. high. Provided that suitable timber can be obtained, 20 ft. is quite low enough. It should be quite satisfactory to use round poles for the studs, and so admit more air space between studs andlead.

Jan 1, 1920

By D. G. Minnes

Many non-metallic minerals and structural materials are produced in Ontario to serve the needs of domestic manufacturers and export markets. In 1982 production was estimated to have a value of $765 million. Approximately 81 per cent of this was represented by structural materials, nearly 12.8 per cent by salt, and the remainder was other industrial minerals. Total mineral production in Ontario in 1982 was estimated at $3 .16 billion, down nearly $1.5 billion from 1980's high of $4.58 billion.

Jan 1, 1984

By D. R. Babich, E. R. Bauer

Noise-induced hearing loss (NIHL) in mine workers, especially underground coal miners, continues to be a problem in the mining industry. The recently enacted MSHA noise standard, Part 62 – Occupational Noise Exposure (Federal Register, 1999), is aimed at reducing NIHL in the mining industry. The U.S. National Institute for Occupational Safety and Health (NIOSH) is conducting a cross-sectional survey of noise sources and worker noise exposures to address NIHL in various aspects of coal mining including surface mining, coal preparation plants and underground mining. In underground bituminous coal mining, noise surveys, consisting of full-shift worker noise exposure, time-motion studies and equipment noise profiling, have been completed on longwall and continuous miner sections in six underground coal mines. The studies revealed widely varying shift-to-shift worker exposures, with workers in certain occupations routinely exposed to potentially hazardous levels of noise. A summary of these studies is reported, including worker dose, source/dose relationships and equipment noise profiles.

The West Coast region of the South Island is situated astride the Pacific û Australian plate boundary zone. The most significant component of this zone is the Alpine Fault. A variety of reconstructions of the pre-Alpine Fault plate tectonic configuration of the New Zealand continental area have been attempted over the past 25 years or so. Most of these have not been closely constrained by a regional compilation of field data related to the age and horizontal displacement history of the Alpine Fault. A model in which the Alpine Fault was initiated no earlier than the interval 18 - 16.5 Ma (B.P.) is proposed, a significantly younger age of inception than has been widely accepted as the onset of dextral displacement along the plate boundary through the South Island. A subsequent history of displacement is presented consistent with the West Coast basin stratigraphy. The alluvial gold content of some parts of the Miocene to Pleistocene conglomerate sequences is also discussed.

Jan 1, 1996

By Francis D. Leathers

Four friction pile load test programs, including 23 tension tests and 9 compression tests, have been performed as part of the Central Artery/Tunnel Project in Boston, Massachusetts. The tests, performed on both precast, prestressed concrete (PPC) piles and steel piles, yielded the following adhesion values: [Soil Type Clay Clay Glacial Till Interbedded Sand and Clay Interbedded Sand and Clay Pile Type PPC Steel Steel Steel PPC Adhesion (psf) 610 to 1,200 230 to 900 220 to 550 680 1,280 ] The adhesion appears to be affected by differences in pile material type, with PPC piles having higher adhesion than steel piles. However, part of the apparent difference for the clay may be due to differences in time between driving and testing. The significant range of test data means that the need for site specific testing to determine or verify design values of adhesion should be considered during design. Creep rates at loads near failure ranged from about 0.02 to 0.18 inches per log cycle of time, with most values in the range of about 0.04 to 0.08 inches per log cycle of time.

Jan 1, 1994

Many of the difficulties faced by the U.S. mineral industry in 1982 and 1983 emanated from the worldwide recession, from the high value of the U.S. exchange rate, and, in part, from actions taken by foreign governments to protect selected industries. While some problems will be minimized with continued worldwide economic recovery, others remain and may require special attention by U.S. policymakers. These problems include declining U.S. production capacity in selected mining and mineral processing industries, the impact of the high value of the U.S. exchange rate, and protectionist trade practices by competitor nations. Illustrative of the last is the International Trade Commission (ITC) determination in June 1984 that both the domestic steel and copper industries have been substantially injured by foreign imports. In its July 1984 recommendations to the President, the ITC suggested higher tariffs and quotas for 5 years on 70 percent of steel imports but conditioned the aid on cost-cutting and modernization steps by the domestic industry. In the copper decision, two commissioners recommended increased duties, two recommended that quotas be imposed, and one recommended that no relief be provided. The President decided in September to seek voluntary restraint agreements with nations that export steel to the United States and rejected both quotas and higher tariffs on copper imports. General Economic Setting This decade opened with the U.S. mineral industries struggling to deal with double-digit inflation, record high peacetime interest rates, and almost 7 years of oil-cartel-induced energy price increases that seriously affected the profitability of energy-intensive industries such as mineral production and processing.

Jan 1, 1985

By Arnold J. Farstad

The Location Group conversed in the Petroleum Room of the Green Center with the purpose of addressing the following list of topics in light of the Bureau of Mines' requirements for detecting and locating trapped miners by electromagnetic methods. These topics include: Noise, Sources, Antennas (transmit and receive), the Propagation Medium, Signal Processing, Optimum Frequency, Receivers, Pulse vs. CW Techniques, Passive Location Techniques, and Obstacles. Practical constraints such as equipment size, weight and power requirements, cost and intrinsic safety were kept in mind during these discussions. It was emphasized that in-mine equipment must be inexpensive, rugged, simple and lightweight. Otherwise, the mine operators probably would not buy it nor would the miners be able to effectively use it. Present techniques for experimentally detecting and locating trapped miners were discussed, along with techniques to improve their location accuracy. Analytical, numerical, and scale modelling methods were considered as a means of giving further insight into measurement, anomalies caused by terrain variations, conductivity contrasts, and obstacles. After discussion of these topics, conclusions were drawn and existing problem areas were identified. These problem areas were addressed in developing guidelines for future efforts. Following the discussion period, the Chairman gave a summary of the Location Group report and comments were solicited from the entire group. 2.0 GROUP DISCUSSION HIGHLIGHTS 2.1 Noise W. Bensema asked the group whether the noise data provided by NBS was adequate. It was determined that for location systems analysis, the most important form of noise data was the frequency spectra of vertical and horizontal magnetic fields on the surface, and the answer to his question was affirmative. Drs. Wait and Frischknecht pointed out the difficulty in accurately measuring the true vertical magnetic field since these measurements are heavily influenced by the loop setting and the local geology. Nevertheless, these measurements are important since the same perturbations would also affect a receiving loop oriented to receive the vertical magnetic field. Dr. Rankin pointed

Jan 1, 1973

By Douglas Banks

Construction for the new 2.5 MGPD raw water intake project commenced December 2002. The project, initially designed as a 12' Ø concrete lined intake shaft,145' deep, with two offset 24" lake taps, 520' and 470' long was subsequently “value engineered” running the two lake taps through a single conduit. The offset for summer and winter pools was accomplished via a second shaft located at the lakes edge. Construction involved the use of blind drilling techniques for the shaft development and drill and blast techniques for the tunneling. All works were completed through extremely hard crystallized sandstone. The project came online August 12, 2004.

Jan 1, 2005

By G T. Kukla

A Seam deposit User oriented Mine Planning System (SUMPS) was developed by The Broken Hill Proprietary Company Limited (BHP) at its head office in Melbourne. It is one of the computer mine planning systems developed by the Corporate Data Processing (CDP) section of BHP. To date it has been employed in the feasibility study of four coal prospects for the BHP Group, including Gregory in central Queensland û Ham and Van Hoorn (1978). It was also used in detailed short term mine planning for Gregory. A recent application was in the feasibility study of Saxonvale, a multi seam coal deposit in New South Wales with seams up to 20 m thick. The other two applications of SUMPS were also on thick multi seam coal deposits. Development of programs for the underground subsection of SUMPS is continuing. SUMPS was developed and implemented on mini computers with graphics and plotting peripherals. The company's philosophy towards computing is one of centralized development and project planning, with transfer of hardware and software to site once the mine becomes operational. Support of the site's system continues from head office which is continually involved in development of SUMPS and issuing revision updates to sites. The users, as well as programmers, were mostly geologists and mining engineers. This helped to ensure rapid, successful implementation. The broad approach of this system was to use interactively the specialist skills and interpretative abilities of the user mining engineers and geologists with the data manipulation abilities of the computer. It is an integrated system which covers geological exploration, deposit modelling, mine planning and production scheduling. An important feature of the system is that the user has full interactive control over each function through a graphics terminal where applicable.

Jan 1, 1980