Search Documents

By Sebastiaan Peelman

NdFeB permanent magnets are the best available magnets used in many technology applications. However, at their end-of-life (EoL) most of magnets and the contained REEs are lost during the recycling of the bulk metals. The REEs are classified as the most critical raw materials in the European Union, and recycling of REEs from EoL products will reduce their criticality and contribute to the sustainability of REE. Various technological routes have been reported, but most of the methods are effective for highly concentrated magnets or magnet scrap, which is greatly dependent on expensive pre-dismantling processes. This paper presents various innovative metallurgical solutions to the effective REE recovery from current industrial practice for WEEE recycling, including the ferrous scrap from WEEE shredder products and shredder residues from computer hard disk drives. Both hydrometallurgical and combined hydro- and pyrometallurgical REE recovery routes are developed after demagnetization and physical upgrading.

Recovery of Tantalum Capacitors from Waste Printed Circuit Boards Using a Pneumatic Separator

Sep 13, 2010

By Wenming Wang

Recycling of retired cadmium telluride (CdTe) photovoltaic (PV) modules has attracted attention due to new European environmental regulations. Recycling tellurium from CdTe PV modules is becoming more important because of the low availability of this metal. We investigated several treatment paths for reclaiming tellurium from solutions obtained from leaching fragments of CdTe PV modules. Our experiments showed that conventional soda ash neutralization/hydrolysis methods recovered only 50~60% of tellurium. However, by appropriately combining neutralization and sulfide precipitation, almost all the tellurium present in the leaching solution was precipitated and recovered; the concentration of tellurium in the processed solution was reduced from 900-1000 mg/L to less than 1 mg/L, yielding a tellurium recovery greater than 99%. This method can be incorporated in the scheme of recycling spent CdTe PV modules and manufacturing wastes. It may be also an alternative to the current operations for removing tellurium from copper anode slime leaching solutions.

Jan 1, 2006

By N Rivera, A Music, C Cisternas

In an underground mine operated with panel caving and subjected to high stresses, geotechnical events such as collapses or rock bursts are fairly recurrent. Both situations can involve risks for people, considerable production losses and increasing operational costs.This paper discusses an operational methodology for the recovery of the undercutting front carried out at El Teniente mine, which uses panel cave mining with post-undercutting, after the occurrence of severe damage due to a seismic cluster. The main objective of the recovery of the undercutting front is to prevent the spread of the collapse to the production level, risking the operational continuity. The methodology is the result of repairs that were carried out in the year 2014 at the North Reserves sector from El Teniente mine. Its characteristics are an undercutting front of almost 1000 m long, with the presence of relevant structures and faults, high stresses and high seismic activity.The practical implementation of the proposed methodology was successful since it prevented the spread of the damage, completely recovered the undercutting front and avoided production losses during the execution of the repairs. Also, considering the origin of the damage and the operations associated to the subsequent recovery of the undercutting front, in this paper we discuss the main control variables to be measured. These variables should allow any operator and short-term planner to take action in mines operated with conventional panel caving in a complex geotechnical environment.CITATION:Rivera, N, Music, A and Cisternas, C, 2016. Recovery of the undercutting front in a mine with conventional panel caving – case study at North Reserves sector, El Teniente Mine, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 713–722 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By L. C. Bird, N. T. L. Landgren, M. W. Mikhail

"Through funds made available in 1972 by the Nova Scotia Department of Mines and Energy (DME) and the federal Department of Regional Economic Expansion, a program was initiated to recover saleable coal from mine waste dumps adjacent to the existing Acadia wash plant in Stellarton, Nova Scotia.Following evaluation of these dumps in 1972, the Acadia wash plant was modified to treat high-ash material. The first production was recorded in late 1974. By the end of 1979, a total of 738,202 t of dump material had been processed, yielding a total of 205,212 t of thermal-quality coal.The successful Stellarton operation led to considering the possibility of recovering thermal coal from other dumps. Evaluation of the Westville dumps indicated total recoverable reserves of 1,346,617 t averaging 53.8OJo ash.Parameters for plant design were defined from the washability characteristics of the dump material and the results of a bulk test. Two options were proposed; one was to use the existing plant with some modifications, the other was to build a modular mobile plant that could be used at future dump sites in the province after Westville. At the 25% ash level, the potential recovery of coal from the dump was estimated at 41% yield (by weight) or 549,679 t."

Jan 1, 1981

A modified liquation technique was developed for recovering tin from tinhouse scruff metal or hardhead containing about 10 per cent iron and 15 per cent occluded flux, palm oil, and moisture. This was effectedby heating the scruff metal to 950°C followed by rapid cooling to suppress the formation of FeSn2 and FeSn, and then subjecting it to the ordinary liquation and drossing processes of refining. By this method it was possible to recover about 83 per cent of the original tin content and, with subsequent smelting of the irony drosses, an overall recovery of 92 per cent was obtained.

Jan 1, 1969

By Fathi Habashi

"A process is proposed for the treatment of phosphate rock for the recovery of uranium and the lanthanides. The process assures the production of phosphatic fertilizers without polluting the environment with radioactive material.IntroductionWhile many processes for uranium recovery from phosphoric acid produced by the H2S04 route are known and utilised commercially, little is known about uranium recovery from phosphoric acid produced by the HN03 route1. Advantages of the latter route are both the elimination of the gypsum disposal problem, and the possibility of radium disposal in a controlled way2. Further, the lanthanides originally present in the rock can be recovered if the nitric acid route is used; they will be mostly lost in the gypsum produced by the sulphuric acid route3. In the present work a scheme for the recovery of uranium and the lanthanides from phosphate rock without interfering with the normal route for fertiliser production is proposed using HN03 as a leaching agent. Attention was also given to uranium decay products and their separation so that they might not contaminate the fertiliser4. Further, an attempt was made to defluorinate the leach solution in order to upgrade the fertiliser and at the same time recover the fluorine5. Rapid analytical methods for the determination of uranium, radium, and lanthanides in phosphate rock were developed6,7."

Jan 1, 1997

Recovery of Vanadium from Stone Coal Through an Environmentally Friendly Acid Leaching Technology

Sep 13, 2010

By Henry Howe

THIS paper is a discussion of the extremely valuable one of Mathewson and Phillips, The Recrystallization of Cold-Worked Alpha Brass on Annealing,1 which not only gives us a wealth of important data reached with great intelligence, but also shows both uncommon powers of imagination and a perfectly fair spirit. Let me try to analyze some of their results, and to enunciate some of the laws to which these results point. For brevity I refer to them as "The Authors." The page numbers in parentheses refer to their paper. 1. The Visible Aspects of Recrystallization.-Plastic deformation in a single direction, as in cold-rolling, draws the grains out in that direction, that is, inequiaxes them, without destroying their apparent individuality. Each grain seems to endure the drawing out without changing either its volume or its orientation materially, for the etching tint of each grain seems to be as uniform after as before the drawing out, save for the "etch bands,"2 shown in Figs. A to D of the Authors' Plate I. As the drawn-out metal is heated progressively, on reaching a certain "disintegration temperature" these old grains seem to break up, probably into submicroscopic fragments, and this apparent disintegration is followed by a coalescence of these fragments, so that their number decreases and their size increases, till they may become very much coarser than before the drawing out. Ruder3 coarsened the grains of silicon steel in this way till single grains reached an area of 50 cm. (7.75 sq. in.). The deformation itself probably breaks each grain up into many very small fragments, but the fact that each grain continues to have a uniform etching tint different from that of its neighbors indicates that these fragments retain the initial common orientation of the grain. The apparent disintegration which we observe, then, is rather an abandonment of community of orientation for individuality of orientation, by the fragments formed earlier during the deformation. Hence we

Jan 10, 1916

By Ian Gordon Hall

El presente texto describe el proceso de recuperación de las partículas ultrafinas de casiterita en los relaves de la mina San Rafael a través de diversas pruebas metalúrgicas, donde se usaron dos tipos de concentradores centrífugos, los cuales indicaron la posibilidad de una recuperación de 50%, produciendo concentrados de 50% Sn. Asímismo, se instala una planta piloto donde se verifica el proceso de las distintas configuraciones y combinación de equipos, como el efecto de las cargas circulantes. Paralelo a ello, se realizan pruebas para aumentar la ley de los concentrados primarios y así obtener concentrados finales a través de concentración gravimétrica.

Sep 12, 2005

By Georgios Kafantaris, Carsten Bonde, Nataša Katic

Within the investigation works for the Copenhagen Cityring metro, Geo/CMT have carried out 90 geotechnical boreholes. Together with the previously available investigation, this resulted in more than 15 km of vertical drillings and several thousands of laboratory tests. The design is made for 17 stations, four shafts and two parallel 16 km long tunnels. The geotechnical investigation and design have been carried out in several stages comprising appropriate refinement of structural design and design of excavation operations, including TBM break-in and launching operations at each station shaft. Acceptance of the solution and / or refinement of the investigation and design schedule in the next stage were based on the geological conditions, area availability at surface level, planning and cost-control criteria. The applied recursive design refinement is presented herein with an example of the Østersøgade shaft location.

Jan 1, 2016

By John L. Sundstrom

Complete systems were designed -and are in operation to recycle the effluent streams and to remove impurities from tankhouse. electrolyte, Heavy em¬phasis was placed on making usable products from as many streams as poss¬ible at minimum capital and operating costs. Almost complete recycling: and reuse of water and sulfuric acid were paramount. Techniques used in-clude solvent extraction - electrowinning, evaporation - crystallization and filtration.

Jan 1, 1992

Seventy-three of the 90 naturally occurring elements that are found in the earth's crust are metals or metalloids. The quantities of metals used annually in the United States range from about 100 million metric tons (steel) to a few kilograms (osmium). The recovery of metals from discarded products or industrial process wastes, especially those metals that are used in large quantity, are very expensive, or are unusually toxic, is important to the national economy and to the natural environment. From its inception in 1910, the U.S. Bureau of Mines (USBM) has been the Government's prime source of information on metals recycling, as well as a major innovator in recycling technology. Statistical data on scrap generation and processing have been summarized annually for many years in the USBM's Minerals Yearbook. Most of the data for individual metals discussed in this report were extracted from that publication.

Jan 1, 1993

By Charles R. Marek

There is an ever-increasing need for quality construction materials to provide the necessary housing and transportation facilities required for the protection and movement of people and goods. By the year 2000, requirements for housing in the United States will have doubled due to population growth. Requirements for transportation facilities in this same period will also have increased substantially. Further, all existing facilities for both housing and transportation will require substantial maintenance of one form or another. Aggregate is the basic material of the construction industry. There is some occurrence of aggregate source material in virtually every state of the United States, and in every country in the world. United States reserves of commercially useable aggregate have never been systematically estimated and are probably so vast as to be incalculable.1 However, in many areas its existence is largely negated by inaccessibility. Often it is lodged deeply or intricately in the earth or it is too distant from markets to offer a desirable "return on investment" under the present economic structure. Other factors that prevent its utility are the occurrence of small scattered deposits that individually are too small to justify the necessary capital investment for exploitation and collectively are too widely disseminated; also, the aggregate nay be deficient in certain desired chemical or physical qualitites.1

Jan 1, 1974

Recycling and Recovering Fine Particles from Auto Shredding Residue (ASR/SR) to Conserve Raw Materials and Protect Environment

Sep 13, 2010

By Thomas J. Neil, O&apos

Mine land reclamation is a comparatively new science-Although some mining companies point with pride to reclamation efforts of 20 to 30 years ago these were the exception rather than the rule. In the last ten years the skyrocket of environmental awareness has been awesome to behold. Future shock gripped mine operators everywhere as they struggled to cope with rapidly changing and escalating demands. The initial result was that two divergent points of view became dominant. Environmentalists said, "Put it back the way it was," and the miners responded, "Let's grow some weeds and hide it." These views are not surprising as they represent rather obvious alternative responses, albeit at opposite ends of the decision spectrum. The former case has prevailed more often than the latter, as most state and federal legislation -- both proposed and passed -- has required drastic alteration of the post-mining landscape so that evidence of prior mining is largely obliterated. An exception to this has been in porphyry copper country where the infrequent abandonment of mines has given emphasis to the second philosophy -establishing vegetative cover on mine waste materials. Now, it should come as no revelation to most mining people that both of these approaches to mine reclamation suffer from serious drawbacks when applied to open pit copper mines. First, whereas waste dumps and tailings dams can be vegetated with some aesthetic benefit, the massive presence of copper mining operations remains very prominent. It is difficult to conceal an open pit copper mine. Second, returning open pit copper mines lands to their original topography and productivity is simply not a reasonable alternative.

Jan 1, 1976

By Craig T. Jones, Zachary Q. Maassen

"Jet grouting is a method of ground improvement that relies on the erosive capacity of high-speed jets to cut and mix the ground in place with a cementitious grout. A continuous return flow of cuttings, called jet grout backflow or spoils, is expelled to the surface during the grouting process. Data from projects completed in Toronto and Ottawa is presented where BOS Solutions’ services provided significant savings compared to the traditional spoils treatment utilizing vacuum trucks for spoils disposal. These traditional treatment methods are cumbersome and expensive by nature. BOS Solutions provided an alternative solution that is environmentally friendly and capable of handling full flow to process these jet grout spoils utilizing a tank system paired with centrifuges and flocculation additives to remove the ground soils and grout product from the spoils slurry. BOS’ process produced a clean water for reuse in the project while reducing the overall waste volume by producing a dry, stackable solid that could be hauled to a landfill. Benefits observed by using the BOS process were disposal waste volumes decreased over 30% and at least a 19% reduction on disposal costs.SCOPE OF WORKJet grouting is a method of ground improvement that relies on the erosive capacity of high-speed jets to cut and mix the ground in place with a cementitious grout. A continuous return flow of cuttings, called jet grout backflow or spoils, is expelled to the surface during the grouting process. The backflow, or spoils, is a mixture of grout, water and soils. Traditionally, the spoil would be collected in in-ground pits and allowed to solidify for a few days prior to hauling to a final disposal site. For the projects completed in Toronto and Ottawa, the jet grouting work was performed at street level, in high traffic congested areas, presenting the challenge of insufficient space for the contractors to process the jet grout spoils in the traditional way. At first, attempts were made of using vacuum trucks to collect and haul the wet spoils to an off-site location where the spoils would be allowed to solidify. However, this method proved cumbersome and expensive due to the high volumes of spoils generated daily and the high number of vacuum trucks required to support the jet grouting operations, respectively."

Jan 1, 2017

By V. Kamavaram

Keywords: Recycling, Aluminum Metal Matrix Composite, Ionic Liquids, BMIC Recycling of aluminum metal matrix composites (MMC) via electrolysis in ionic liquids at near room temperature was investigated. The electrolytic melt comprised of 1-butyl-3-methylimidazolium chloride (BMIC) and anhydrous AlCl3. Impure aluminum composite (Duralcan MMC Al-380, 20 vol % SiC) was electrochemically dissolved at the anode and pure aluminum (>98%) was deposited on a copper cathode. The deposits were characterized by scanning electron microscope, X-ray diffractrometer, and mass spectrometer. The influence of various process parameters such as concentration of electrolyte, and applied cell voltage on the recycling process was studied. The recycling process yielded current densities in the range of 200-500 A/m2, and cathode current efficiency of about 85%. The results indicated that impurities such as Cu, Si, Ni, Fe, Mg, Mn, and SiC particles were removed as anode residue. Energy consumption of about 3.7-6.3 kWh/kg-Al was obtained at a cell voltage of 1.0-2.0 V and cell temperature of 100 ± 5°C. Low energy consumption and no emission of pollutants are the two main advantages of this process compared to present recycling processes.

Jan 1, 2005

By A Cox

It has been demonstrated that all the cadmium from spent batteries, typically 4 g per battery, can be recovered by burning polyvinyl chloride waste to yield hydrogen chloride; this reacts to produce volatile calcium chloride, which can then be condensed and collected in a separate reactor. Alternatively, chlorine may be used to chlorinate the cadmium with equal efficiency. There is also a prospect of using very low concentrations of these gases, less than 1%, to effect the separation. The Cd was recovered more quickly when exposed to sustained, controlled flow rates of chlorinating gases, whereas when PVC was burnt most of the gas was produced in a very short time, not allowing complete reaction. This problem can be overcome by recirculation of the gas into the reactor. The technology is efficient and clean and the equipment used is simple, enhancing the prospects for a pilot-scale version of the process

Jun 21, 1905

Recycling of Process Water in Sulfides Processing and Flotation Selectivity

Sep 13, 2010