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By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

By A. T. Iannacchione

Underground mining of stone in the US is increasing, as is the depth of overburden above the mines. Data gathered from mine visits, maps, discussion with operators and numerical simulation have been used to investigate pillar design and recommend safe practice. Many pillars have slender shapes with relatively large adjacent mine openings: width-to-height ratios range from 0.54 to 3.13 and extraction ratios from 0.56 to 0.91. The pillar material is often very strong and average overburden only 80 m, but occasional failure due to excessive local stress has occurred where pillar size had been unintentionally reduced, overburdens were greater than 200 m, width-to-height ratios were less than 1.25 or extraction ratios were greater than 0.83. Pillars with width-to-height ratios of less than 1.5 appear more likely to fail under excessive stress. When width-to-height ratios fall below 1.0, defects such as through-running discontinuities can have a significant influence on stability. Dip, orientation and material properties are also important

Jun 21, 1905

By R. Sweennen, A. Vervoort, J. Caers

A case study is presented of the mechanical behaviour of fractures in the Westphalian A and B siliciclastic succession of mud-, silt- and sandstones with intercalating coal layers in the Campine basin of northeast Belgium. Mining ceased in the area in 1992 and a pilot well was drilled to assess the feasibility of methane extraction by hydraulic fracturing. Work was carried out to study the influence of types of cement fill in fractures on the shear behaviour of the rocks by comparison with that of the coal seams. X-ray computerised tomography was used for visual appraisal and selection of jointed rocks before destructive shear testing was carried out. Two major type of veins were found to be present, one cemented with carbonate and the other with kaolinite or kaolinite/carbonate. Uniaxial compressive strength and shear tests showed that differentiation of the two types of veins was vital in evaluating the strength of the sandstones, as cementing of the fractures by rigid carbonate minerals can reinstate the strength of the rock masses to that of the intact material. Kaolinite was more susceptible to plastic deformation than carbonates

Jun 19, 1905

By P. A. Davies

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 11pp., 15 refs. Hazards such as vibration, dust emission and fragment projection can result in an area called the Danger Zone being set around a blasting site. Traditionally Danger Zones have been set solely on the basis of consequences (e.g. based on the maximum distance of rock projection or expected ground vibration plus a defined safety margin). Advances in risk assessment and its growing acceptance as a safety management tool have led to the setting of Danger Zones based on both consequences and frequency of occurrence. This allows distances to be optimised on the basis of acceptable risk levels rather than the potential consequences of infrequent events. The setting of a flyrock Danger Zone is used to demonstrate a risk-based approach compared with a traditional consequence approach

Aug 1, 1995

By T. J. Serenko

The epithermal deposit is hosted by Tertiary volcanic rocks that lie between mid-Miocene normal faults of the Northern Nevada Rift. Petrographic, laser-ablation and metallurgical observations suggested that the gold occurs in two principal forms: native (and electrum) and disseminated in arsenopyrite. It was proposed that gold is distributed between two parageneses with distinct mineralogical associations. Detailed downhole geochemical study supported the observations. Concentrations of Au, Ag, As, Sb and Se were determined from drill core and reverse-circulation cutting composites and contoured on cross-sections. Gold was indeed shown to have a bimodal distribution with the two parts separated spatially and perhaps temporally, implying that two separate genetic processes acted to concentrate gold at Mule Canyon

Aug 1, 1995

Paper presented at the UK minerals industry conference and published in: Minerals extraction towards the millennium. UK minerals industry conference, 3-5 April 1995, University of Leeds. London: Institution of Mining and Metallurgy, 1995. The various types of risks that arise in minerals industry projects are usually financial, technical, or environmental, and the key to valid risk analysis is complete integration of all risks, both within and between categories. Geographical information systems (GIS) and geostatistical simulation methods can provide a means of integrating data and conducting realistic risk analyses. Risk can be quantified but there are limitations to numerical approaches to risk assessment. Realistic quantification requires adequate models of the processes that give rise to risk. Risk perception must also be taken into account when conducting risk assessment and reporting the results, especially in public forums. The modelling and visualisation capabilities of a combined GIS/simulation system can provide the means of dealing with perception in risk analysis

Jun 19, 1905

By D. M. A. Flight, P. M. Green, J. A. Plant, P. R. Simpson

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The British Geological Survey's regional geochemical database is used to identify the patterns associated with the various mineral deposit types and to examine the extent to which their distribution reflects the presence of long-lived metallogenic provinces in the crust. Image analysis provides new insights into the setting of the mineralisation, geochemical constraints on tectonic models of Caledonide evolution and evidence for terrane amalgamation and large-scale processes. There is evidence that much of the mineralisation reflects the presence of long-lived provinces with a distinctive geochemistry reflecting their origins as zones of crustal extension. In the case of the Middle-Upper Dalradiam sedex deposits, the relationship between geochemistry and tectonic setting is direct. In other cases, rocks deposited in extensional zones appear to have acted as reservoirs of ore-forming elements which were further concentrated during later events

Jun 19, 1905

By T. B. Colman

Paper presented at the MEP '89 conference held in Madrid, 13-15 November 1989. Britain has sustained an important metalliferous mining industry over many centuries. Recently, new geological concepts and exploration techniques have indicated that there is considerable potential for the discovery of a variety of deposit styles, often in previously neglected areas. The recent discoveries at Aberfeldy (Ba-Zn-Pb), Gairloch (Cu-Zn) and Cononish (Au-Ag)in Scotland and Curraghinalt (Au-Ag) and Lack (Au-Ag-Pb) in Northern Ireland are illustrations of this potential. Some of the prospective areas for future exploration are described and an indication is given of the legislative framework within which mineral exploration and development are carried out

Jan 1, 1991

By R. A. D. Pattrick, R. A. F. Ixer

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. At Calliachar Burn, 14 steeply dipping quartz-sulphide veins, with and without gold, infill master joints that crosscut gently dipping metasediments and metabasics of the Pitlochry Schist Formation. The wallrock is extremely bleached and enriched in sericite, chlorite and carbonate. Gold grades vary from high with quartz-galena-pyrite to low with galena-chalcopyrite; the gold forms electrum inclusions smaller than 20 micrometres in pyrite or, rarely, arsenopyrite. At Urlar Burn, gold is present in small amounts in 4 quartz-galena-chalcopyrite veins. Although much of the mineralogy is similar to that at Calliachar, there are significant differences in Sb-, Te-, Bi- and Hg-bearing phases. Fluid inclusion data suggest mineralisation occurred over the range 320-140 degrees C, from fluids with significant CO2 and 2-13 wt% equiv. NaCl. Mantle-derived fluids appear to have been generated during the late Caledonian and focused by the Urlar Burn fault

Jun 19, 1905

By T. G. Carter, R. I. Miller

First, the influence of variation in the

Apr 1, 1995

By A. Dean, J. Roberts, I. Stone, J. R. Merefield

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 11 refs. No completely reliable method for characterising and quantifying airborne dust risk exists. A new monitoring technology has been developed whereby dust collected from four-way directional and high volume samplers is analysed for mineral content and particle size for integrated dust mapping. A dust database was set up for the area surrounding the Ffos Las open cast coal site in South Wales. It included XRD directional traces from 17 gauges over 20 months, XRD traces from window ledges in the nearby communities, the major soil types in the area, dust data from haulage roads and public roads and reference-type mineral samples. The database can be accessed relationally to compare and analyse the data using mineral, direction, time, weather and geographical relationships. The data has been used to assess areas of low, intermediate and high levels of risk from dust fall-out

Apr 1, 1995

By A. D. Fowler, M. T. Anderson

A phenomenological model is presented that relates Pb-Zn mineralisation to proximal geopressure zones. Typically, geopressure zones (GPZ) consist of masses of undercompacted sediment encapsulated within impermeable shales and are characterised by high formation fluid pressures. Heat flow is perturbed in some GPZ on account of their insulating properties. Geothermal gradients as high as 150 degrees C/km have been observed over short distances in the sediments of the US coast of the Gulf of Mexico. Some modern geopressure zones are known to reach temperatures of 120-150 degrees C at depths of 2.5-3.5 km. It is demonstrated that the zones may act as proximal sources of hydrothermal fluids, thus explaining the high temperatures of mineralisation observed in the deposits, which are hosted in basins characterised by thick, rapidly deposited, shale-rich clastic sequences

Jan 1, 1991

By C. S. Spirakis, A. V. Heyl

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The modified basinal brines, containing partly oxidised sulphur species, scavenged metals from basement rocks and sediments and transported them through the host rock, which contained local concentrations of organic matter. Reacting in various ways with the mineralising solution as temperatures at the sites of mineralisation changed, organic matter caused the precipitation and dissolution of a variety of minerals in the ore zones; it was organic matter that caused all of these reactions to occur at the same sites. Thus all components of the mineralising fluid - salt, water, heat, sulphur and metals - were obtained within the ore district. The siting of the mineral districts was related to the locations of faults through U- and Th-enriched granites beneath sediments containing basinal brines, and the locations of ore deposits within the districts were controlled by local concentrations of organic matter

Apr 1, 1995

By P. Grainger, P. G. Kalaugher

Paper presented at conference and first published in preprint volume of: Risk assessment in the extractive industries, held in University of Exeter, 23-24 March 1994. London: IMM, 1994. Large, unpredicted ground movements resulting from open cast or underground mining present risks to the safety and economy of extractive industries. As large, sudden failures are usually preceded by small displacements at a much slower rate, the detection and monitoring of these minor changes to the ground surface provides a means of assessing the risks. It is recommended that a visual approach is often preferable to surveying or fixed instrumental measurements. An optical system has been devised, incorporating a 35 mm camera, which allows an immediate comparison on site between a colour transparency taken on a previous inspection and the scene it represents. The observer fuses the transparency stereoscopically with the directly viewed scene. The impression is close to that of normal vision except that differences in detail which have occurred since the transparency was taken are immediately obvious, enabling a qualitative assessment of changes to be made on site. If repeat photography is required it can be taken with exactly the same alignment and coverage. The two images are then available for office analysis using simple micro-photogrammetry

Apr 1, 1996

By D. K. Bose, R. H. Rakhasia, V. D. Shah, J. C. Sehra

A series of experiments was conducted to determine the effects of roasting temperature, soaking period and quantity of soda ash added. At a laboratory scale, under optimum conditions of roasting at 873 K for 2 700 s with soda ash 10 wt% in excess of stoichiometric, molybdenum recovery was 99%. The investigations indicate the technical feasibility of producing high-purity MoO3 by combining the roasting process with carbon adsorption/desorption. The process uses low-cost chemicals, can be scaled up readily and is free of the SO2 pollution generated by conventional roasting, as the sulphur content of the concentrate is converted to sodium sulphate

Jun 18, 1905

By R. K. Dunham, D. J. Reddish, X. L. Yao

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 10 refs. The integrated approach combines a powerful ground movement prediction program with a knowledge-based expert system. ESDAS (Expert Structural Damage Assessment System) was developed to evaluate mining subsidence damage in the form of risk and in terms of the three vital contributing components (mining factors, site factors and structural factors). Using a certainty factor risk assessment technique, the system can be used to predict the likely damage to a particular structure subjected to mining subsidence. A previously developed powerful ground movement prediction program, SWIFT (Subsidence With Influence Function Techniques), has been combined with the expert system to allow the mining factor to be more accurately determined in a broader range of mining layout. Since SWIFT can be calibrated to any particular coal field using local subsidence data, it is believed that the integrated system could be used in any coal field worldwide for the assessment and control of mining subsidence damage risks

Dec 1, 1995

By R. D. Stewart

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 18pp., 5 refs. A seismic risk assessment method has been developed for application to rockburst prone deep-level mining sites which have sufficient seismic coverage. The technique utilises several seismic hazard parameters simultaneously and assesses the seismic risk on a daily basis according to the individual levels of these parameters. Critical levels are determined from investigation of the long-term behaviour of the parameters in relation to recorded potentially damaging seismic events. The method has been applied to a data set comprising 15 months' worth of seismic data, with encouraging results

Aug 1, 1995

By B. J. Breen, C. S. Mogg

Considerable borehole investigation work has been completed at a proposed site at Sellafield in Cumbria, supplemented by seismic surveys, other geophysical sensing and geological mapping. The focussing of investigation on the rock mass itself will be achieved by means of the planned underground rock characterisation facility, giving access to depths of about 800 m in the strong, low-permeability basement rocks of the Borrowdale Volcanic Group. Characterisation work undertaken during the sinking phase and interaction with continuing surface-based exploration and monitoring should permit a firmer assessment of the long-term safety of a repository. Key considerations in the choice of a design for the repository include the waste handling method, underground inlet cell, underground vaults, vault environment and environmental effects

Aug 1, 1994

By D. W. Taylor, I. W. Farmer, N. Mojtabai

Rittinger's and Bond's descriptions of rock crushing relate the energy input required to fracture rock and the surface energy required to form new fractures to the change in specific surface area of feed and product during comminution. The potential applicability of this approach to blasting is illustrated, using the results of data from bench blasting tests on Pinal schists and production blasting of Carboniferous limestones. The approach contributes to understanding of the mechanisms involved in blasting and to the design of test blasts. A modified form is presented of the relationship between blasting energy, specific surface area of the muckpile and a rock energy constant related to the discontinuity structure of the rock. The modified equation fits observed data and offers a simple basis for further experiments

Jun 19, 1905

By S. L. R. Lenharo, H. Kahn, H. Born

Different ore types result from the irregular spatial distribution of the associated alkaline/carbonatite rocks and the zoned alteration profile within which apatite may have undergone reprecipitation. Different flotation responses are caused by their mineralogy, iron oxide impregnation and grain-size characteristics. Samples from seven deposits were crushed, screened and separated before being studied by chemical analysis, optical microscopy, X-ray diffraction, FTIR spectroscopy, cathodoluminescence and scanning electron microscopy. Two main apatite varieties with peculiar crystal morphology were identified: hydroxy-fluorapatite as the primary phase and carbonate-fluorapatite as the reprecipitated phase. The former occurs as prismatic or ovoid grains and the latter as polycrystalline aggregates or crusts on the primary grains; both are associated with iron oxide coatings (primary) or intergrowths (secondary). Microflotation tests showed variations in flotability for particular apatite associations as well as intensity of iron oxide coatings. The differences in flotation behaviour can be related to morphological properties and chemical substitution in the apatite structure

Aug 1, 1996