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By H. R. Manouchehri

Sustainable development requires the optimal use of natural resources and recycling of the wastes. In fact recycling is the final productive use of obsoletes. ELVs, obsolete appliances and industrial wastes have become important resources for production of iron and steels, non-ferrous metals, and composites. Within shredding plants, these obsoletes are firstly shredded to the pieces and then processed to recycle different materials, especially ferrous and non-ferrous metals for metallurgy. Traditional and new developed mineral processing technologies are nowadays used for recycling different materials from waste effluents. Shredding and separating plants are currently recycle the wastes by make use of different technologies to mainly produce raw material for metallurgical application. However, other non-ferrous components are also treated for energy conservation and protecting environment. Currently, recovery in shredding and recycling plants maximises to 75% and about 25% of the feed is land-filled. However, recycling rate must be increased in due to the economical, environ-mental and social concerns. A comprehensive study for recycling, with especial focus on ferrous metal recovery, was sup-ported by Swedish Environmental Agency (MISTRA) to look at possibilities to increase the recycling rate and to reduce the amount of disposal. Part of this study was dedicated to study the shred-ding plant facilities and to look for possibilities to improve the quality and quantity of the shredding product streams. The aims were to improve the quality of ferrous scrap (apparent density > 0.9 and Cu<0.25%) for iron and steel production as well as having better quality for non-ferrous metals through the recycling schema, and finally to treat the shredder residue (SR) to recover metals and plastics to reduce the disposals. This paper summarises the results of sampling and conducting separation tests for improving the recovery of the ferrous and non-ferrous metals. The results indicated to be possible to obtain high quality ferrous scrap at recovery of 88%. However, the total recovery for metal scrap has reached 93%. Furthermore, test results on fine, P< 8mm, shredding residue (SR) showed promising prospect in recovery of metals and protecting environment by physical separation, i.e. electrical separation technique.

Jan 1, 2014

By Markus A. Reuter, Jacques J. Eksteen

The modelling of bath type furnaces tends to be either fundamental in nature or total empirical "black box models". While models of the first kind are robust, they tend to lack accuracy, in cases where they are to be used for process control, and may take an overly long in development time. On the other hand, black box models tend to lack robustness of prediction for all circumstances and tend to be limited to interpolate based on historical data. While this may very often provide short-term accuracy, the models may have problems with stability in the long term. Moreover, the model structure may not reflect any of the fundamental properties of the system and remains opaque to fundamental analysis. The aim of the model development is in obtaining a model that have robustness, high accuracy, a short development time and which is adaptive to a changing environment. The models are specifically developed for on-line decision support or control of furnaces. The modelling approach is evaluated for a chromite bath smelting furnace. The role of systems analysis, mass balance smoothing, thermodynamic analysis are integrated into one generic algorithm for bath type furnaces. Therefore, this paper argues that to understand complex metallurgical furnaces a hybrid approach is the only method to fully grasp the intricacies of metallurgy, to improve operations, economics as well as environmental performance.

Jan 1, 2003

The status quo of ecological rehabilitation in metal mine in China and progress in the technology for ecological rehabilitation are presented, including soil reconstruction, soil improvement, plant selection. The present and future research fields are suggested: basic theory of ecological rehabilitation, operative technology of ecological rehabilitation, new technology application research and ecological rehabilitation plan, management and policy.

Jan 1, 2014

By Alireza Javadi Nooshabadi, Kota Hanumantha Rao

Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by sulphide minerals during grinding was examined. It was found that pyrite (FeS2), chalcopyrite (CuFeS2), sphalerite ((Zn, Fe) S), and galena (PbS) generated H2O2 in pulp liquid during wet grinding and also when the freshly ground solids are placed in water immediately after dry grinding. Pyrite produced more H2O2 than other minerals and the order of H2O2 production by the minerals was found to be pyrite > chalcopyrite > sphalerite > galena. The pH of the water influenced the extent of hydrogen peroxide formation with greater amounts of H2O2 produced at highly acidic pH. Furthermore, the effect of mixed sulphide minerals, i.e., pyrite-chalcopyrite, pyrite-galena, chalcopyrite-galena and sphalerite-pyrite, sphalerite-chalcopyrite and sphalerite-galena on the formation of H2O2 showed increasing H2O2 formation with increasing pyrite fraction. There is clear correlation of the amount of H2O2 production with the rest potential of the sulphide minerals; the greater the rest potential of a mineral the greater the formation of H2O2. This study highlights the necessity of revisiting the electrochemical and/or galvanic interactions between sulphide minerals, and interaction mechanisms between pyrite and other sulphide minerals in terms of their flotation behavior in the context of inevitable H2O2 existence in the pulp liquid.

Jan 1, 2014

By M. Kalicinski, M. Lyssyy

"Access to information is a key component for making improvements to any process. This is particularly true for all aspects of the iron mining and steelmaking process. The ability to make rapid control decisions can significantly influence process outcomes, including ensuring product specification, mining quality, transportation limits, upgrade factors, waste bypass and direct shipping, among many others. While traditional laboratory methods provide feedback for such processes, having access to analysis results in real-time can lead to positive reactive and predictive control decisions to be made rapidly, leading to significant improvements throughout the process. Scantech has been designing, manufacturing and supplying technological products to the minerals industry since 2002 to enable the availability of such real-time information to a mine or plant, with the benefits being enjoyed by a wide range of operators. This paper provides a summary of the available technologies used in the iron ore and steel industries, as well as providing case studies of their use in African and Australian iron ore and European steel, as well as a description of the potential benefits of a range of analysis equipment.INTRODUCTION Access to information is critical for any process, and is a fundamental component for making process control decisions. In order to yield effective processing outcomes, it is important for that information to be readily available, preferably as quickly as possible, and to be as accurate as possible. While speed and accuracy are often traded off against each other, there are numerous technologies available in a processing environment that allow for both rapid flow of information and a high level of accuracy. The use of on-belt analysis equipment has a long trusted history of use in a number of mining and processing environments and industries, providing information such as elemental composition and grade of conveyed materials, moisture content, waste proportion and energy information. Australian company Scantech has been a provider of such equipment since 1981, and has become an industry leader in both the supply and development of on-belt analysers across a range of industries."

Jan 1, 2018

By P. Ying

An auxiliary system connected with SEM-EDX for rapid identification of mineral and rock sample has been developed. With the aid of a synthetic spectrum library created, using the compare and match techniques provided by INCA software in EDX the mineral or rock sample names for refer-ence can be given at the same time analyzed.

Jan 1, 2014

By Ajay K. Jha1

Drilling and Blasting are two important unit operations in the production cycle of a mine and a strong link exists between these two and other unit operations/subsystems like loading, transportation, and crushing. Under the present concept of ? Mine to Mill?, it is important to optimize the drilling and blasting operations by applying scientific approach to drilling and blasting using sophisticated instruments and new technologies, which depends heavily on Information technology (IT) to meet this imperative. Development of innovative models and software has lead to blast optimization process. Till date, the blast results are evaluated in terms of available empirical approaches like powder factor, which are too simple to exclude some key parameters or lack in providing reliability because of non-availability of user friendly IT enabled techniques. Although with the help of developed approaches, formulation of user-friendly software to assist the site engineers in effective post blast assessment has started but there is a dearth of holistic approach to design an optimum blast considering the techno-economic feasibility of the subsystems and the geo-mining conditions to achieve blast optimization. The science of IT enablement in drilling and blasting is capable to build innovative models for achieving blast performances which will be doped with productivity, economy and safety with due regard to environment. The present paper discusses the use of existing IT enablement in various mines of India citing the Indian scenario and the future requirements for achieving the techno-economics in overall mining operations.

Sep 1, 2012

By Jie-Liang Wang, Yongdan Cao, Zhao Cao

"The effect of ethylenediamine tetraacetic acid (EDTA) on flotation separation of fluorite from bastnaesite and its selectively depression mechanism on fluorite were studied by single mineral flotation, artificial mixed minerals flotation, solution chemistry analyses, Zeta potential and XPS measurements.The results show that fluorite can be deeply depressed by EDTA while the flotation of bastnaesite is almost unaffected when octanohydroxamic acid (OHA) is used as a collector. The separation index (SI) between bastnaesite and fluorite increases with the dosage of EDTA, SI can be raised from 1.18 to 12.66 when EDTA dosage increases from 0 to 2×10-3mol/L.Solution chemistry analyses show that EDTA is able to convert the Ca(OHA)2 hydrophobic precipitation on fluorite surface to a soluble Ca-EDTA complex but cannot complexly dissolve the Ce(OHA)3 precipitation on bastnaesite surface. Therefore, the Zeta potential of OHA conditioned fluorite can be reduced significantly by EDTA while the reduction degree to Zeta potential of bastnaesite is relatively low. XPS measurement shows that EDTA removes the chemically adsorbed OHA from fluorite surface but has little effect on the adsorbed OHA on bastnaesite surface. As a result, fluorite can be selectively depressed by EDTA in bastnaesite flotation, which behaves an important industrial application prospect in rare earth ore flotation.INTRODUCTIONNowadays, Rare earth elements (shortened as RE) and compounds are of significant importance for a range of rapidly expanding industrial applications including catalysis, metallurgy, renewable energy, and special materials due to their unique electrical, magnetic, optical and chemical properties [1]. The seventeen RE elements, including the lanthanide-group fifteen elements, yttrium and scandium, could be divided into three groups, i.e., light, medium and heavy RE elements based on the different solubility of RE sulfates [2]. Bastnaesite ((Ce,La)CO3), containing approximately 75% REO, is one of the most important light RE minerals [3]. Flotation is the common method to recover basetnaesite [4-6]. Nonetheless, basetnaesite is often associated with calcium-bearing gangue minerals such as fluorite, and the separation of basetnaesite and fluorite by flotation is usually difficult due to their similar surface properties and therefore floatability [7-9]. Therefore, research on high selective flotation reagents of bastnaesite over gangue minerals has attracted a lot of attention [10]."

Jan 1, 2018

By Dmitriy Kim, Natalya Ibragimova, Galina Sedelnikova

Gold and copper are lost in flotation tailings in mineral processing of copper-zinc-pyrite ores. Large resources of precious and base metals have accumulated in tailing ponds of Russian plants. Object of the study is the sample obtained from Ural Mining and Metallurgical Company in Russia. The main constituents in flotation tailings are Au, Ag, Cu and Zn with content 1.4 g/t, 12 g/t, 0.66 and 0.5% respectively. The flotation tailings are a refractory material. Gold, as main metal, is fine encapsulated in sulfides, mainly in pyrite. Gold extraction from tailings is 34.0 and 42.7% at P42 and P90 of 0.074mm particle size respectively. In this work heap bioleaching of tailings was studied for oxidation sulfides (pyrite and chalcopyrite) with using mesofilic and moderately termofilic bacteria in acidic solutions. The tailings had low filtration property (< 0.3 m/day) and pelletization was used before bioleaching. Copper containing converter slags flotation tailings and calcium oxide were used as binding material for increasing filtration property of tailings. Copper was extracted in sulfate solution and was precipitated by cementation after cleaning of bacterial solution from iron. Copper recovery was 56.8% at content 61.4% in precipitate. The biooxidation of pyrite was 80%. Cyanidation, leaching with thiourea and heap leaching by cyanide were tested too. Gold extraction from solid bioresidues was 82, 75.3 and 77% respectively. The results of this investigation were recommended for pilot test.

Jan 1, 2014

By C. L. Xiao

With reference to the test report carried out by Guangzhou Nonferrous Metal Research Institute in 1983, the mineral process flow sheet of Yichun Tantalum-niobium mine is determined based on the characters of ores and successful experiences in light of the problems in the existing flowsheet: The ore is desilted before crushing; the primary slime is separately treated; the staged grinding process used while the fine slime is collectedly treated with tantalum and niobium as the main recoveries and lepidolite and feldspar powder as the secondary. The flowsheet is featured by comprehensive recovery, low investment and low energy cost.

Jan 1, 2014

Deposit of Jinbaoshan platinum group metals (PGMs) ore ranks the second in Yunnan province, China. Study on process mineralogy shows that the grade of copper and nickel in the ore is just 0.16% and 0.20% respectively. Moreover, the impurities magnesium and iron and silicon are rich in the ore. The copper and nickel sulfides in the ore, especially the minerals of PGMs, are finely disseminated with the gangues like serpentine. Fine grinding is necessary, and high content of MgO in the concentrate is inevitable through traditional flotation technology on the basis of process mineralogy studies. Achievements on process mineralogy studies are applied to guide the flotation tests successfully. Progress on flotation has been made through comprehensive studies. Suitable grinding by two stages is required for the finely disseminated PGM sulphide ore to achieve the liberation of valuable minerals. Stage grinding and stage separation shall be conducted for a better recovery of valuable minerals. The oxidation state of mineral surface of sulphides has a profound effect on flotation of the ultra-fine sulphides, especially the pentlandite. The combined use of collectors enhances the selective collecting on the ultra-fine and low-grade valuable minerals, is of critical importance.

Jan 1, 2014

By E. Scheepers

The process under investigation is the large-scale production of phosphorus. Gravity delivers the feed, consisting of pelletised apatite, coke and silica (in the form of gravel), to a submerged arc furnace through ten, evenly distributed feed chutes ensuring constant packed bed volume. Within this packed bed, solid-gas reactions are dominant in generating the gaseous product. These reactions, as well as the packed bed itself, were the main focus in the development of a fully three-dimensional CFD model in which fluid flow and energy distribution are represented as functions of chemical reactions, heating and melting of material and heat losses. The associated complex process interactions necessitated the creation of two process-specific, user-developed models that integrates accurate, thermodynamical data with computational fluid dynamics calculations, as well as reaction kinetics. The boundary conditions are provided by industrial measurements, and the key model parameters of reaction kinetics were obtained by laboratory experiments for different feed mixtures. Thirteen temperature probes installed inside the refractory lining of the furnace especially for this project allowed parameter fitting and validation to be guided within the constraints of real measurements. Simulation results reveal a thin, dome-shaped, reductive zone where conditions are optimum for maximum phosphorus recovery, as well as evidence of a thermal reserve zone similar to an ironmaking blast furnace located above this reduction zone. When compared to actual operating data, the CFD model can successfully predict the specific power consumption, the phosphorus in the slag and gaseous product flowrate under given operating conditions. This CFD model forms part of a larger project that aims to create a Dynamic-CFD hybrid control model.

Jan 1, 2014

By X. J. Lu

Purified Na-montmorillonite samples were used as the starting materials to prepare organically modified montmorillonites (OM), and a series of OM samples were prepared by intercalation of al-kyl quaternary ammoniums with different alkyl chain length. The interlayer spacing (d001) of the OM was determined by small angle X-ray diffraction and its gelating performance was characterized by measuring the viscosity of OM/dimethylbenzene mixture. The effects of alkyl chain length, dosage of alkyl ammonium, intercalation duration and layer charge of the starting material on the OM structure and gelating properties were investigated. According to the results, the adsorption quantity of the alkyl ammonium is dependent on the hydrocarbon chain length, the dosage of the alkyl ammonium and the retention time. The adsorption quantity of the alkyl ammonium increases with the chain length and the dosage, and extra adsorption more than the CEC of the montmorillonite sample was observed under the dosages of more than 1.3 CEC. The interlayer spacing (d001) of the OM shows a dynamic variation with the dosage and the retention time, and super interlayer spacings greater than the length of the alkyl ammonium were observed under larger dosages and shorter retention times. However, the gelating performance of OM does not follow the variations of the adsorption quantity of alkyl ammonium, an optimum viscosity value of OM/ dimethylbenzene gel was observed with the moderate adsorption of the alkyl ammoniums. Furthermore, the layer charge plays an important role on the gelating performance of OM. The OM synthesized by the starting material with lower layer charge shows better gelating performance in the dimethylbenzene solution.

Jan 1, 2014

By Linghu Changjin

Based on the characteristics of typical marine sedimentary phosphate rock in Guizhou, Southwest China, together with the research findings made on the surface electric properties of pure collophanites taken from different areas in pure water and under the action of collectors, a pure minerals flotation test of collophanite was conducted in this research. The differences of collophanite flotation behavior and the effects of the different pH values, varieties, and dosage of collector on flotation separation of collophanite were studied. It is suggested that that in pure water, collophanite had a negative charge within a wide pH range. The electro negativity values of collophanite increased with the addition of collectors GJBW and WF-01. When GJBW and WF-01 were used as collectors, the collophanite was depressed in acid medium, but had a good flotability in basic medium.

Sep 1, 2012

By E. Yigit

In the flotation process the physical factors such as agitation intensity air flow rate and pulp solid concentration are very important parameters affecting grades and recoveries of the products. The flotation tests were performed on the samples of Bigadic colemanite ore to investigate these factors at different agitation intensities ranging from 1000 rpm to 1400 rpm and air flow rates from 1000 cm3 ? min-1 to 2000 cm3 ? min-1 with 2 L and 4 L cells using Denver laboratory flotation machine. The tested collectors were Cytec Aero 825, Aero 848N and their mixtures. Agitation intensity and air flow rises resulted in more floated material although sometimes being not selective. These effects can be attributed to powerful collisions between air bubbles and mineral particles. The first observation was the effect of pulp solid concentration on the floatability of minerals, while the flotation in 2 L cell (0.125 g.L-1 solid concentration) at 1000 rpm (0.176 wattcm-3), and with 1000 cm3.min-1 air flow rate was possible, the flotation in 4 L cell (0.0625 g.L-1 solid concentration at 1000 rpm. (0.176 wattcm-3) and with 1000 cm3 ? min-1 air flow rate was not possible. However at 4 L cell after increasing agitation intensity to 1200 rpm (0.201 wattcm-3) keeping 1000 cm3 ? min-1 air flow rate, flotation was possible again. This shows that these factors such as agitation intensity have some critical role on flotation. Another interesting observation was on the selective effect of pulp solid concentration. In the flotation with 1 L cell at different agitation intensities, collector Aero 848N was selective against calcite, while in the flotation with 2 L cell at different agitation intensities the same collector Aero 848N was selective against colemanite.

Jan 1, 2014

The present study is devoted to improvement of the leaching efficiency during phosphorous removal from high phosphorous gravity-magnetic concentrate. Before leaching the concentrate has been subjected to roasting with the addition of either Ca(OH)2 or CaO. The oolitic iron ore is roasted at 900°C for one hour. This reflects in reaction between alkaline earth additive and quartz, aluminosilicates, phosphorus, and some other minor components of the gangue minerals. The application of leaching, physical separation, and wash out of salts has resulted in the decrease of phosphorus from 0.7 to 0.15 % and it is established that the major influencing factor is the concentration of acid and to a less extent duration of the leaching process. About two third of the phosphorus can be removed by roasting with 3 % CaO to hematite, coarse grinding to d50 0.3 mm, dry high intensity magnetic separation and leaching of the magnetic fraction with hydro-chloric or nitric acid.

Sep 1, 2012

By P. Matias

The study involved two projects that will produce copper concentrate and may have their operations integrated. Transport by trucks, conveyor belt, and the equipment called RopeCon were evaluated as options for the ore transport between the sites. A rainforest stretch, that Vale S.A. demands to preserve, is situated between the projects. It was suggested to further review RopeCon because it presents minimal interactions with the environment. To design the preliminary system layout, a research was done on the rainforest cover height data, but the information found was scarce and imprecise. For preserving the local forest, the use of this data would conduct to the oversizing of RopeCon towers and, consequently, overestimation of its costs. For the acquisition of reliable information, a method was developed using local data acquired through airborne laser survey. The volume between the digital surface and terrain models was calculated to generate a surface representing the forest cover height. It was revealed, by plotting the points obtained from this surface, that 85% of the vegetation is below 25 m. This height is suggested to review the preliminary project with a more accurate design of the equipment towers, thus reducing its costs estimates. The method permits the precise location of the large trees, making easier to find a pathway, for linear-shaped facilities, that would minimize the creation of vegetation-free zones as a measure to protect equipments against falling trees and forest fires. Keywords: forest cover, mining projects facilities, digital models, airborne laser survey

Sep 1, 2012

By R. Singh

The present paper deals with the development of flotation based process for enrichment of a lead-zinc sulphide ore from Ganesh-Himal region of Nepal. Detailed characterisation and flotation studies were carried out under varying process conditions. The sample assayed 2.47% Pb with 13.6% Zn. The ore was predominantly made up of spahlerite and pyrite in association with subordinate amounts of galena, minor amounts of pyrrhotite and chalcopyrite. Dolomite was the main gangue. The modal analysis showed the probability of fair liberation of sulphides from gangues around 210 microns but the locking of galena with sphalerite and other sulphides continued to finer sizes. Under the optimum process conditions the rougher lead and zinc recoveries were 96.3% and 90% respectively. Multistage cleanings of rougher products proved helpful in improving the concentrate grade, meeting the required specification. Based on the studies undertake a process flow-sheet for the concentration of the ore to individual lead and zinc concentrates was developed.

Jan 1, 2014

By H. B. Zhou

The process of bioleaching marmatite using moderately thermophilic bacteria has been studied in this research by comparing marmatite leaching performance of mesophilic bacteria and moderately thermophilic bacteria and valuating the effect of venting capacity on marmatite leaching performance of moderately thermophilic bacteria and the effect of pulp densities on marmatite leaching performance of moderately thermophilic bacteria. The results show that moderately thermophilic bacteria have more advantages over mesophilic bacteria in bioleaching marmatite. Aeration agitation can improve the transfer of O2 and CO2 in solution and promote the growth of bacteria and therefore, enhance the leaching efficiency. With the increase of pulp density, the total leaching amount of valuable metals increased, however, the extraction efficiency decreased due to many rea-sons, like increasing shear force that results in poorly growth condition for bacteria, etc.

Jan 1, 2014

By Andrei Yevdokimov, Ivan Sidorov, Olga Lanchakova, Olga Khmelnitskaya, Tatiana Chikina

"The paper focuses on the results of the research on development of hydrometallurgical process of gold recovery from refractory sulfide flotation concentrates based on fine and ultrafine grinding. Refractory concentrates (the degree of refractoriness is 16.9%-82.6%) were chosen for testing. The efficiency of the process based on fine and ultrafine grinding to treat flotation concentrates with gold intergrown with sulfides and rock-forming minerals was shown. Based on the test work conducted, the process option was chosen. In included grinding of flotation concentrate to the size of 98% minus 20µm in a bead mill, lime treatment with air blow, CIL, filtration and detoxification of liquid phase of the slurry. This process (compared to the basic option) provides the recovery of gold from 82.6%, up to 94.0% and decreases the residual grade in the tailings from 3.3g/t to 1.1g/t at the consumption of 12.6NaCNkg/t. Based on the results of the test work and pilot plant testing, project design criteria of flotation circuit at a Russian plant was developed."

Jan 1, 2014