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By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

By M. J. Scoble, H. L. Francis, D. F. Salter, G. R. Baiden

Intelligent ore delineation refers to the ability reliably to characterize the geological setting of a mineralized body and its grade distribution. This necessitates using all available geological information in a timely and efficient manner, such that effective geological control is achieved. The importance of geological control is paramount to improving the efficiency and competitiveness of underground mines. As a result, the development of new geosensing tools designed to provide more reliable and timely information should be a priority. However, as the sensing tools advance then so, too, must the decision support system in order to allow the full benefits of these tools to be achieved. One potential system considered able to provide this architecture is ’true 3D-GIS’ (Geographical Information System). GIS promises to provide a seamless data flow and to connect information currently unavailable to the underground mine operations by bringing together previously disparate and spatial data sets in a visually effective and timely way. This paper considers the potential revolution GIS offers over the flow and use of data in mining by focusing on the integration of geosensing data and GIS to facilitate intelligent ore delineation.

Jan 1, 2000

By I. A. Kovalevska

Considered problems: elaboration and implementation of resource-saving technologies, low-cost support systems improvement, openings security and support, based on wallrock condition control with supreme implication into the rock pressure occurrence counteraction work. Results of analytic and underground investigations using computer simulation of the finite elements in order to calculate stressstrain state of the multivariable geomechanical systems are presented. Solutions of concrete objectives are found using spatial geomechanical model of solid motion around openings, considering real geomechanical parameters formation of support forms with proper conditions of their contact and real mechanical characteristics. Ultimate solutions of resource-saving technologies implementation based on the analysis of multivariate vertical, horizontal, and reduced stresses components calculation and also near-contour rock, support bearing components and security constructions movements are found. Results of experimental investigations of combined supports and security constructions, which increase openings' stability in difficult conditions of flat coal seams are presented.

Aug 1, 2013

By Y. Champoux, N. Atalla, R. Oddo, C. Lesage

"Percussion drills are the source of the most serious noise problems in mining activities, due to their extremely high noise levels(114-122 dB(A)) and widespread use(Bartholomae and Stein, 1988). Percussion drills will continue to be widely used to drill small diameter holes in hard rock because no other method seems to be economically avail-able to replace them (Boillat et al., 1993).Many studies (Danière, 1991; Hawkes etal., 1977a; Jensen and Visnapuu, 1972;Leblond et al., 1976; Milette, 1989) were con-ducted to determine the major noise sources of percussion drills. The exhaust air of pneumatic drills, the hammer, the bit in contact with the rock and the drill rod have been identified as the major noise sources. A muffer can be used to reduce the exhaust noise and the hammer can be enclosed. The bit noise is considered to be of concern only at the beginning of holes. When all the available methods are used to reduce the noise of a percussion drill, the drill rod vibrations become the dominant noise source (Hawkes and Burks, 1979). However, the noise levels generated by this source remain high and future efforts should concentrate on reducing its radiation.Works by Hawkes and Burks (1979) and Hawkes et al. (1977b) for the U.S. Bureau of Mines provide the most complete description on the noise and vibration of percussion drill rods.The longitudinal and bending waves are the two most important types of elastic waves generated in drill rods. Among these, only the longitudinal waves contribute to the drilling rate. The bending waves are caused by non-centralized impacts, drill rod curvature and non-uniform bit/rock interface. Drill rod noise is generated by Poisson’s ratio expansions and contractions of the rod as the longitudinal waves travel up and down it and by transverse rod motions induced by bending waves. The radiation efficiency is much higher for bending waves than for longitudinal waves. Most of the impact energy is transformed into longitudinal waves, as expected for axial impacts. The evaluation of the relative contribution of longitudinal and bending waves to noise generation poses a very difficult problem for experimental, analytical and numerical approaches. It is, however, an important issue because the relative contribution of these two waves will guide future noise reduction efforts. It seems that very little can be done to reduce the noise radiation of the axial waves without affecting the drilling rate. The main difficulty that analytical and numerical approach-es face, in the evaluation of the relative contribution of the two waves, is that there is no adequate theory for predicting the bending vibrations from the factors that cause them. The experimental approach has, thus, been limited to test fixtures that do not adequately represent the boundary conditions, as well as by measurements obtained under real operating conditions from which it is difficult to establish the relative contribution of the two types of waves. For example, Hawkes and Burks (1979) and Hawkes et al. (1977b) used a test fixture with free-free boundary conditions and made no clear link with measurement under real operating conditions. Rather, they have based their discussion on a simple model. Many authors assume that fexural waves are the main noise source on drill rods. However, measurements have been somewhat contradictory and researchers are still unable to state with certainty that this is indeed the case (Lednik et al., 1988)."

Jan 1, 1997

By L. Li

To accommodate the large payloads and harsh operating conditions associated with heavy vehicles in the mining industry, off-the-road (OTR) tires are typically used with heavy mining vehicles. These tires have increased abrasion and wear resistance due to their thicker tread, sidewall and bead thicknesses. Given these features, OTR tires are much stiffer than conventional passenger vehicle tires and cannot be mounted to a single-piece rim without damaging the structural integrity of the tire during the mounting process. Therefore, multi-piece wheels are used with OTR tires to facilitate mounting. While these assemblies are necessary, several instances of their failure have been reported to result in injuries or fatalities within the mining workplace. Many of these failures were specifically reported to be caused by the disengagement of the wheel lock ring - a component used to securely engage the assembly during operation. In this study, a threaded-connection locking mechanism has been proposed in place of the traditional lock ring design. The performance of this threaded-connection was numerically evaluated in a pull-out test against a conventional five-piece wheel assembly. The pull-out test was devised as a means of quantifying the engagement ability of each wheel?s locking mechanism. A high degree of modelling accuracy was maintained throughout the analysis by validating the vertical and horizontal static loaddeflection behaviour of the rim model of the five-piece wheel assembly against experimental data. Through validation, the model data were found to be within 10.5 and 4.80 %, for vertical and lateral loaddeflection behaviour, respectively. Results from the pull-out analysis found that the threaded-connection demonstrated a 113 % increase in the force required for disengagement to occur relative to the conventional five-piece design - a force of 9,550 kN in total.

Aug 1, 2013

By S. Steinlechner, G. Schneeberger, J. Antrekowitsch

Due to always getting stricter environmental legislations as well as increasing land filling fees the efforts for treating residues from metallurgy are continuously increasing. In case of filter dusts from metallurgical industry, the high zinc bearing electric arc furnace (EAF) dusts or also dusts from secondary copper industry are important sources for the recovery of secondary zinc oxide. Because of low capacities for secondary zinc concentrates (like Waelz oxide) in primary zinc metallurgy, the upgrade of such concentrates to a quality that meets the requirements of high quality (technical) zinc oxide becomes more and more important. This would open the opportunity to break into new markets and use it for example directly in electrolytic galvanizing. Therefore this paper will summarize possibilities for an elimination of halogens from secondary zinc oxides. Furthermore selective volatilization trials, with a synthetic mixture according to the analysis of Waelz oxide, were carried out to remove impurities to achieve an upgraded product quality.

Jan 1, 2011

By H. H. Gardner

Introduction The Greenhill mine of West Canadian Collieries, Limited, is on the Alberta side of the Crowsnest pass, twelve miles from the Alberta British Columbia boundary-line. Here, five coal seams of Lower Cretaceous age are found in the Kootenay formation. They outcrop on the north and south slopes of the valley, with strike approximately N.30°W., paralleling the main range of the Rocky mountains, and dip about 40 deg. westward. Of the five seams, only two, designated No. 1 and No. 2, have been worked to date. On the West Canadian Collieries property, No. 1 seam ranges in thickness from thirty feet to nil. Generally, it has a hard, strong conglomerate roof. No. 2 seam is separated from No. 1 by forty-five feet of shales and sandstones. It has a thickness of eight to thirty feet.

Jan 1, 1947

By S. Steinlechner

"Today the common recycling technologies of automotive catalysts are either energy intensive pyrometallurgical processes generating huge amounts of residues or hydrometallurgical ones which have to cope with effluent problems. Next to that, other valuable metals beside PGMs such as rare earths from the wash coat are not recovered.Therefore, the present paper introduces a hydrometallurgical concept developed in cooperation with the company Railly & Hill for the recovery of the PGMs as well as cerium from the wash coat of the catalysts in a closed loop. Next to the process concept, the required parameters for the different steps are discussed, including the chemical reactions, leaching efficiencies and mass flows, which form the basis for an economic estimation of the concept.Contrary to the pyrometallurgical recycling where the monolith is completely melted down to slag which is typically dumped, in this process the remaining monolith forms an utilizable product for the ceramics/refractory industry. As a result of the closed loop of the leaching media an environmentally friendly process was developed from which nearly no new residues or effluents are generated, with a sustainable usage of chemicals."

Jan 1, 2014

By R. R. Potter

"IntroductionAlthough iron formations were recognized in western New Brunswick about 1820, commercial production was not achieved until 1848. The Jacksonville deposits near Wood stock were developed first, and ore was treated at a blast furnace constructed 5 km to the southeast on the Saint John River. Several charcoal burners were also constructed. Pig iron was produced sporadically until 1884, when operations were finally suspended. There was little further interest in the area until 1953, when Stratmat Ltd. initiated an ambitious exploration program. At the same time, the company carried out research on an electric-reduction process to produce metallic iron and ferromanganese. The technical feasibility of this process (Udy process) was confirmed, however the high energy costs were prohibitive and work ceased in 1957. Some metallurgical research was carried out by Mandate Refining Ltd. about 1970 and more recently by the New Brunswick Research and Productivity Council.The Years Prior to 1848New Brunswick became a separate province in 1784, shortly after the influx of a large number of Loyalists from the United States. Man y of these people sett led along the Saint John River, including the area of excellent farmland near the present town of Woodstock.There were indication s that some of these earl y settlers recognized iron formations in the vicinity of Woodstock about 1820, however the nature of the deposits was not known until 836 when Dr. C.T. Jackson, a geologist commissioned by the Stat e of Maine, investigated the mineral potential of the area. Jackson (1836) described the ""ore"" as compact red hematite yielding 44 per cent pure metallic iron, and suggested that sizable tonnages may be present. It was about this time that an extensive limonite deposit was found in north-central Maine, near Mt. Katahdin. Other iron deposits were found in the Nictaux area of Nova Scotia, and a few years later at Londonderry."

Jan 1, 1983

By G. E. Wood

Steep Rock Resources Inc. owns a calcite quarry property at Tatlock, Ontario, and a calcite processing plant at Perth, Ontario. The Tatlock marble deposit forms part of an extensive series of carbonate rocks of the Grenville Geological Province in the Precambrian Shield of southeastern Ontario. The deposit is very unusual, if not unique, in the Grenville area in its combination of characteristics of large size, whiteness, high calcium content, low magnesium and silica contents, and scarcity of accessory minerals. A major expansion of the fine grind products capacity of the plant was undertaken in 1982 and came on stream in 1983. The expansion provides important operating benefits at the plant: greater flexibility as to the product mix and reduced dependence on the single grinding mill previously in place. The expanded facility consists of prima,y and secondary crushers, a rotary drye,~ a screenhouse producing a range of screen separator grade products, an airswept Raymond Mill, and a pebble mill with integrated air classifiers, product storage bins, bulk, semi-bulk, and bagged product shipping capabilities, road and rail access, and a substantial product warehouse. The expansion was designed to be compatible with a move into ultrafine calcite production, and is capable of supplying the anticipated sales growth within its market area during the next 5 years. Products are exceptionally white, with good chemistry, low abrasion, and consistent quality. Markets range, according to product particle size, from pre-cast concrete aggregate to fillers for coatings, plastic pipe, and compounds.

Jan 1, 1984

By S. V. Burr

"IntroductionOne of the more puzzling geological enigmas, in the writer's opinion, is how rock can move sideways with respect to other rock. In the writer's study of regional northwest-southeast folding in North America (Burr, 1980), he may have found the answer to horizontal offset.Horizontal OffsetSideways movement or horizontal offset does not mean that the movement was, or is, horizontal. As indicated below, the actual movement may be at a high angle from the horizontal. However, it is the horizontal VECTOR, or offset, which is measured on surface by geologists. Vertical movements (thrust, normal, reverse) can be understood, as they involve blocks of rock , generally separated on four to six sides, which have been pushed up or subsided. Vertical faulting across dipping strata can produce APPARENT horizontal offsets. However, this thesis deals only with ACTUAL offsets.The ProblemFigure 1 is a plan view of a simple hypothetical horizontal offset. Three vertical dykes are intersected by a fault lineament. Two dykes exhibit no movement; the middle dyke has been offset a distance (a). Vertical faulting would have produced no horizontal offset. How can a horizontal distance (a) disappear or appear? Rock expands or contracts in infinitesimal amounts.SolutionThe map (Burr, 1980) shows the writer's interpretation of regional northwest-trending folds in Ontario. The writer made two observations about horizontal offsets during his thirty year study of these folds:1) All major horizontal fault lineaments strike at a high angle to the northwest fold axes. Many of the northwest-trending lineaments are fault s, but their movement is essentially vertical.2) Close to many of the known horizontal offsets (and several lineaments), there are areas where plunge reversals are so frequent and close together it is impossible to draw in all the fold axes at a scale of 1 inch = 4 miles, and, in the highly faulted Espanola area southwest of Sudbury, Ontario, all the indicated folds cannot be easily separated at a scale of 1 inch = 1 mile. The writer has observed folds less than 30 feet apart next to the strong Puskitamica-Chibougamau fault in northern Quebec."

Jan 1, 1982

"In developing a backfill system handling tailings feed to and from the storage silo, it is necessary to establish a slurry laboratory to develop the technology and silo design criteria. This paper presents the principles involved in such development and the importance of testing principles for optimizing the slurry system. Evaluation procedure based on experiments is applicable to a wide range of materials and allows silo design by scaling up the data gained from model tests. Silo simulation has been successful to design and operation, so becomes an effective approach to backfill applications. IntroductionThe silo is a device comprising specialized equipment and operating with related procedures for storing and handling the mill rejects as backfill slurry. It provides a steady supply of the solids slurry, prepared at desired pulp density under the continuous feed conditions. Because the silo system is designed to accomplish specific objectives when dealing with a particular mill tailings slurry, it is necessary to characterize certain slurry properties, behaviour of the solids slurry and understand the silo performance to establish design criteria. Bench-scale, pilot-scale and dewafull- scale experiments were employed in developing the load-storage-discharge system, and routine procedures are now available for pre-design testing. Silo model experiments and full-scale tests were conducted to define the design parameters and evaluate the silo performance. A silo can be designed by scaling up the silo model geometry and data obtained during tests.Since the early 1960s, silo backfill systems have been widely established. The shape and size of the silo and the operation procedure, as practised, all appear to be relevant to successful operation. Understanding the basic material properties and behaviour of solids slurry retained in the silo will help perfect the silo design, operation procedure and, consequently, improve the silo performance."

Jan 1, 1997

By F. N. Smith

The carbon steel casings of Heat Recovery Steam Generators (HRSGs) in a co¬generation plant were found to have developed cracks that originated on the inside surfaces. The HRSGs receive hot exhaust gases from the primary Gas Turbines (GTs), which are fuelled with pipeline natural gas. The GTs was initially operating without any suppression of nitrogen oxides (NOx). After being in service for about two years, some of the cracks were found to have penetrated right through the 1/4 in. thick casings. The casings are fitted with insulation on the inside (hot gas side). Examination of steel samples cut from the casing walls revealed (i) fine cracks propagating through the steel from the inside surfaces, and (ii) the presence of relatively large amounts of nitrate ion on the inside surfaces. It was concluded that the nitrate ions originated from nitric acid that was condensing on the relatively cool walls of the casings behind the insulation. Nitric acid was formed in the GT exhaust gases by the combination of water vapour (formed from combustion of the hydrocarbon fuel and from moisture in the combustion air) and nitrogen oxides (formed from nitrogen and oxygen in the combustion air).

Jan 1, 2005

"In 2008, the Committee for Mineral Reserves and International Reporting Standards (CRIRSCO) and the Russian State Commission on Mineral Reserves (GKZ) entered into an agreement leading towards harmonization of Russian and international minerals reporting systems. The purpose of the protocol is to define an agreed method by which mineral resources and reserves, reported by companies in Russia according to the current Russian classification system, can be expressed in terms that are comparable to the CRIRSCO reporting codes in Russia and elsewhere."

Jan 1, 2003

By John Battista

Uranium mining in Australia has a chequered history. This paper reviews the development of the Australian uranium mining industry from the 1930?s to the present day. It outlines the geology of the various deposits and the mining and metallurgical techniques used to extract the uranium. The industry is profoundly affected by government policies and the paper considers the roles of the Federal, State and local governments. The influence of public opinion on nuclear issues and the effects current and historical policies of various governments have had on uranium mining are outlined. Despite heavy restrictions placed on it, Australia?s uranium mining industry has maintained its place as one of the world?s largest producers. This paper also provides an outline of where the industry in Australia may be headed in future.

Aug 1, 2010

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, P. Ghobadi

Design and selection of equipment for a grinding circuit strongly depends on the mill function, ore properties and requirements of the down-stream circuit. Primary mills usually work in open circuit and size distribution of product would be controlled in the final steps using a classifier like cyclone. Although HPGRs are mostly utilized as pre-grinding mills, it is preferred to utilize them in a closed circuit due to their specific mechanism of comminution. Unique mechanical design of HPGR and its completely different crushing process than tumbling mills needs precise consideration on its circuit design. In this paper, we investigate the impact of different parameters on design of pre-grinding HPGR circuit and selection of the proper classifier. Our study focuses on iron ore properties (e.g. moisture, particle size distribution of feed and product, compatibility and de-agglomerability). We also investigated various options of HPGR circuit according the classifier efficiency and influences on down-stream processes. The optimum operating parameters of HPGR (working pressure, speed and level of hopper) for the selected circuit were also determined based on pilot and industrial data. Our pilot and industrial tests and observations revealed that HPGR should be arranged in closed circuit because of the edge effect, as a negative factor of non-uniform distribution of pressure force along the roller width and presence of non-crushed particles in the mill product. Wet vibratory screen could be the optimum option for screening of its discharge. Fine part of the wet screen discharge could be delivered to the concentration stage without over-grinding in ball mill using a hydrocyclone working in a reverse closed circuit mode. Moreover, our pilot and industrial tests during design and operation of ten HPGRs in various iron ore processing plants proved that higher pressure and lower roller speed in a fixed level of material inside the hopper could give the desired product size distribution.

Jan 1, 2016

By L. M. Nolan

Chemical Mechanical polishing, or CMP, has four components in the polishing interface; namely the polishing pad, the polishing fluid, the abrasives in the fluid, and the surface being polished. Understanding the way that load is transferred between these components is key to understanding and predicting wafer polishing. Numerous models of CMP and the different load sharing arrangements which occur between these four components have been proposed. These include models by Luo and Dornfield (1) and Fu, Chandra and colleagues (2). Other models focus on just one or two loading arrangements, such as `hydroplaning' when all load is transmitted by the liquid in the case of Runnels and Eyman (3). In this work, we consider four possible combinations of load transfer from pad to wafer in CMP. These combinations are listed below in Table 1 and are illustrated schematically in Figure 1. It is important to note the role of scale in this process; the illustrations in Figure 1 are drawn to scale from actual profilometer scans obtained over a length of 5 with particles of 150 nm in diameter. Table 1 - Load Transfer Combinations Load Regime Illustration Wafer - Fluid - Pad Figure la Wafer - Particles/Fluid - Pad Figure lb Wafer - Particles - Pad Figure lc Wafer-Pad Figure ld The interest in load-sharing between the system components is because some configurations are anticipated to achieve higher polishing rates than others. For instance, in hydroplaning, or hydrodynamic lubrication, the lateral force exerted on the polished surface by the particles can be no higher than the fluid shear force developed in the gap between the pad and wafer. This is not expected to generate high rates of material removal from the surface (4). For contact that is largely between the pad and the wafer, such as the regime depicted in Figure ld, the lateral load is transmitted to the wafer by the pad and is hence limited by the pad's low rigidity. This regime is not expected to generate high material removal rates either. The highest levels of material removal are expected from regimes where the mechanical load exerted on the system is transmitted by the particles, in combination with either the fluid or the pad. Under what circumstances does the polishing regime change from one to another? What must occur in order to initiate or terminate contact between the system components? This is an ongoing question in the field of tribology, and has traditionally been viewed in terms of the pressure and velocity applied to the system, the thickness of the fluid film between the two surfaces, and the roughness of those surfaces (4). In this paper, we propose a new mechanism ? that the load on the particles may be sufficient to totally embed them in the polishing pad, at which point they are no longer able to transmit load and polish the wafer surface. This is illustrated schematically in Figure 1(d).

Jan 1, 2010

By N. R. Thornton

This paper discusses the rapid growth in the application of instrumentation for metallurgical process control. It covers such methods as ultrasonics, pulp density measurements, on-stream X-ray analysis and reagent control, as well as the expanding use of computer control and data acquisition.

Jan 1, 1971

By G. Barrasso

REACH was proposed by the EU Commission in October 2003 and stands for the Registration Evaluation, Authorisation and Restriction of Chemicals. It requires that all substances identified as persistent, bio-accumulative and toxic, whether the risk of those chemicals being released is real or perceived, require registration prior to them being allowed to be imported into the European Union. An internal investigation by the metals industry indicates that almost all primary raw materials streams would be classified as hazardous due to the potential health or environmental hazard properties of one or more of their ingredients. REACH uses a wide definition for chemicals and metals and as such its implications greatly impact the entire supply chain of the metals industry. The process of registration would require the producer/ importer to produce a dossier. Initiatives along the same lines as the EU REACH are also coming up in other parts of the world. REACH requires registration of at least four substances manufactured by the aluminium industry: aluminium metal, including powder, aluminium oxide, and aluminium hydroxide. The proposed legislation permits the affected companies to band together to form a consortium to develop certain aspects of the registration application. The aluminium industry has established a consortium and testing is currently underway.

Jan 1, 2006

By S. Shrestha

Magnesium-based alloys are of growing interest for many industrial applications due to their favourable strength-to-weight ratio and excellent castability. Mass reduction has advantages in many industrial sectors for example, in automotive, a reduction in mass improves fuel economy and can lead to more efficient mechanical systems by reducing the weight of moving parts like wheels, gears, pistons. However, the relatively poor corrosion and wear resistance limits the use of magnesium and its alloys in many potential applications. The patented Keronite® plasma electrolytic oxidation (PEO) process enables manufacturers to overcome such problems and, in its latest generation equipment has been developed to industrial realisation for high volume production. This paper presents microstructural characteristics and corrosion performance of two most widely used high pressure die-cast magnesium alloys AZ91D and AM6OB with a duplex corrosion protection coating system that comprised a thin Keronite pre-treatment followed by a subsequent automotive grade final powder coat.

Jan 1, 2006