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By M. Samuels

"Block and panel cave mining methods are being increasingly proposed as they allow massive, deeply situated ore-bodies to be mined economically at a time when discovery rates of significant near surface deposits are declining. Cave-to-Mill, a mine-to-mill approach for block cave mines, defines ore block models with respect to both mine and mill performance. A cave-to-mill study for the New Afton block caving operation focused on identifying value opportunities related to fragmentation and sorting for a future lift as development progresses deeper. The lack of selectivity and potential for dilution associated with the block cave mining method results in many caving operations having to mine and either dispose of or process material that is below cut-off grade at certain stages of production. As an outcome of the study, the variation in cave fragmentation size and the sensitivity of mill throughput to feed size was examined. To evaluate the amenability of bulk and particle sorting, Prompt Gamma Neutron Activation Analysis and X-Ray Fluorescence sensors were tested. A conceptual bulk and particle sorting flowsheet is presented. Grade data from regular underground sampling was used to predict the performance of a bulk sorter. A heterogeneity analysis of material reporting to drawpoints helped to identify areas of the extraction level that experience high variations in grade and thereby stand to benefit from dedicated ore and waste material handling systems should underground bulk sorting be implemented.INTRODUCTION Block and panel caving are low-cost underground mass mining methods that are suitable for excavating weak, massive and steeply-dipping orebodies. Accordingly, cave mining methods have predominantly been used to mine copper porphyry and diamond bearing deposits. Due to the increasing depletion of near-surface orebodies, it is expected that block and panel caving methods will be increasingly used in the copper-gold industry. Their implementation holds significant potential to extend the life of existing open-pit operations by providing an economic means to access ore located at depths that are beyond the practical limits of open-pit mining. Examples of cave mines proposed for British Columbia include the Kwanika Mine, Red Chris underground, Kemess Underground project, and the Iron Cap and Mitchell cave mines of the Kerr-Sulphurets and Mitchell (KSM) project (Moose Mountain Technical Services, 2017; Imperial Metals, 2017; Golder Associates, 2017; Tetra Tech, 2016)."

Jan 1, 2018

By M. Dadvand, G. Kipuros, A. Dadvand

"The ability to codeposit fillers within a nickel matrix has led to the production of a new generation of cermet coatings with properties useful for various applications. Hexagonal boron nitride (hBN) is a ceramic-type particulate matter with thermal conductivity, thermal stability, inertness, and lubricity properties that allow it to be codeposited. In this paper, a method was developed for modifying hBN surfaces to allow them to be uniformly dispersed in water-based solutions such as an electroless nickel plating bath. hBN surface modification improved wear performance of the electroless plated cermet due to enhanced interaction between the particulate and nickel matrix. RÉSUMÉ La capacité à effectuer un dépôt simultané de charges dans une matrice nickel a abouti à la production d’une nouvelle génération de revêtements cermet (une combinaison de céramique et de métal) dotés de propriétés très utiles pour diverses applications. Le nitrure de bore hexagonal (h-BN) est une matière particulaire de type céramique utilisée pour ses excellentes conductivité et stabilité thermiques, son inertie ainsi que son caractère lubrifiant, qui permettent son dépôt simultané. Cet article explore une méthode mise au point pour modifier les surfaces du h-BN de manière à ce qu’elles se répandent uniformément dans des solutions aqueuses telles qu’un bain de dépôt autocatalytique de nickel. La modification des surfaces du h-BN a amélioré la résistance à l’usure du placage autocatalytique du cermet en raison d’une interaction accrue entre la matière particulaire et la matrice nickel.INTRODUCTION Electroless nickel alloy coatings can be used for many applications; however, the need for improved tribological properties such as higher wear resistance and better lubricity has increased interest in incorporating particulates (fillers) into the nickel matrix by codepositing the particulates with nickel during the plating process. The selection of the particulate type depends on the desired properties (Sahoo & Das, 2011; Sudagar, Lian, & Sha, 2013). In terms of tribological applications, electroless nickel-based composites are categorized mainly into lubricating and wear-resistant composite coatings depending on the type of particles incorporated. The electroless nickel-phosphorus (Ni-P) composite coatings are composed of codeposited solid lubricants such as polytetrafluoroethylene (PTFE), graphite, WS2, MoS2, and hexagonal boron nitride (hBN) and, compared to nanocomposite electroless Ni-P coatings, they demonstrate a lower coefficient of friction. On the other hand, the nickel-phosphorus wear-resistant composite coatings are composed of hard particles such as silicon carbide (SiC), aluminum oxide (Al2O3), boron carbide (B4C), silicon nitride (Si3N4), diamond, tungsten carbide (WC), and zirconium oxide (ZrO2) and, compared to nanocomposite electroless Ni-P coatings, they have higher hardness and better wear resistance (Sahoo & Das, 2011; Sudagar et al., 2013; Parucker, Klein, Binder, Ristow, & Binder, 2014; Chakarova, Georgieva, Petrova, Dobreva, & Stoychev, 2016)."

Jan 1, 2018

"Batch flotation testwork demonstrated that a low-grade chromite ore from Bird River, Manitoba, was best floated at pH 2 using Armac C (coco amine acetate) collector and sulphuric acid as pH modifier. A grind of 100% minus 150 um was necessary for liberation, and flotation selectivity was greatly enhanced by prior desliming. A concentrate analyzing 24.2% Cr203 with a recovery of 90.2% was obtained, after three cleaning stages, from ore grading 6.05% Cr203. Total rougher collector concentration was 500 g/t and cleaner collector concentration 380 g/t. Similar grade and recovery were obtained during the pitot-plant evalualion, when a concentrate analy zing 22.3% Cr203 with a recovery of 93% (based on deslimed feed) was obtained for a total collector addition of 630 g/t.Selective flotation in a region of positive surf ace charge implies anionic activation, and a possible flotation mechanism is suggested.IntroductionIn an earlier study(1) of the beneficiation of chromite ore from Bird River, Manitoba, several methods of beneficiation were explored. These included ore sorting, heavy-media separation, and gravity concentration with flotation using Armac C (coco amine acetate) collector at pH 2, and sulphuric acid as pH modifier. Because flotation was not fully evaluated, a laboratory study was undertaken to determine the optimum parameters of chromite flotation. Optimization of parameters was established first on a laboratory scale followed by confirmation a t the pilot -plant level. Flotation of chromite using Armac C and sulphuric acid as a pH modifier has been reported as being selective for low-grade chromite ores(2)."

Jan 1, 1990

By J. C. Ingram

IT SEEMS particularly appropriate that, in celebrating its Diamond Anniversary, the Canadian Institute of Mining and Metalturgy chose our Province of British Columbia as its locale in this, our own Centennial year. I am sure your organization is justifiably proud of its achievements and growth over the period of its sixty years, and we, for our part, are justifiably proud of our growth over our first one hundred years. With your kind indulgence I pro-pose to talk to you today about our industrial growth, or, to put it an-other way, to highlight, historically, our progress in industrial development over the past one hundred years, and to take the liberty of speculating on what we may reasonably look forward to over the next few years. I am sure, Mr. Chairman, that some may have questioned the appropriateness of a talk on the industrial development of British Columbia to the Canadian Institute of Mining and Metallurgy. However, strangely enough, we in British Columbia owe our origin, constitution-ally and industrially, to the mining industry.

Jan 1, 1958

Operationalizing the Ruggie Framework in a Mining Context Ruggie?s 3 Pillars: The State?s duty to Protect Policies, regulation, adjudication The Corporation?s responsibility to respect Acting with due diligence to avoid infringing Addressing adverse impacts when involved in abuses Access to Remedy ??even the most concerted efforts cannot prevent all abuse.?

May 1, 2013

By R. Matusewicz, A. Kaye

Ausmelt Top Submerged Lancing (TSL) Technology has gained widespread commercial acceptance in non-ferrous applications, including the processing of lead and zinc primary concentrates and secondary (post-consumer) materials. TSL is highly flexible and efficient, and is one of the few technologies which can process primary and secondary feeds, and use varying fuels, to deliver high recoveries and excellent environmental performance. With the recent high value of both lead and zinc, and an escalating awareness of the sustainable use of resources, focus on the processing of secondary feed material sources has surged. Ausmelt Technology has proven to be well suited to the economic recovery of values, with twenty-two (22) Ausmelt furnaces processing lead and zinc bearing feed sources now in operation, under design or construction. This paper describes Ausmelt's progress in the fields of lead and zinc processing, and developments in new processing areas such as EAF dust processing and linking to innovative hydrometallurgical technology. Ausmelt has recently committed to the Whyalla Zinc project as the owner/operator of a facility for the treatment of zinc bearing secondary feeds. This project is due for start up in the first quarter of 2008.

Jan 1, 2008

By G. H. Agnew

When water floods are initiated after gas-oil ratios have increased, the transition period from the start of injection until" the gas-oil ratios are returned to the solution gas-oil ratio may be important for either economic or technical reasons. The transition period is longest, and consequently most critical in water floods where injection is equal to withdrawals. This paper describes a theoretical basis for predicting the behavior of such a system and outlines a procedure for making the necessary calculations. The calculation procedure is illustrated for two actual cases: a line drive water flood and a five spot water flood. In each case there is a reasonable similarity between the actual and calculated performance.

Jan 1, 1960

By Jochen Petersen

This paper gives an overview of the various strands of postgraduate and undergraduate training offered in the Department of Chemical Engineering at UCT. Since 2003 the Department is offering a formal postgraduate MSc programme in hydrometallurgical engineering aimed especially at graduate work-based engineers, with 5 weeks of intensive course work plus a research dissertation on a work-related project. This programme has now run 5 times over the years and produced some 20 degrees. The paper reflects on the experiences with running the course, especially the difficulties experienced with supervising industry-based external students. Furthermore, through the Department a graduate training program is offered for all junior metallurgists at a major South African minerals company. This 2-year program, which is currently on its 12th cohort, offers 1 or 2 week intensive blocks of course work alternating with longer stints where the candidates are based at various operations. Although primarily focussed on minerals processing, it has a significant element of hydrometallurgy in it and in recent years an advanced hydrometallurgy stream has been introduced. The paper reflects on the development of the program over the years, the benefits it has provided to the company as well as some of the challenges that remain. Finally the paper gives an overview of hydrometallurgy related undergraduate and research-only postgraduate MSc and PhD projects at the university. Some emphasis is placed on the recently launched South African Minerals and Metals Research Initiative (SAMMRI), a joint government-industry programme to support university-based research in the area of applied metallurgy.

Jan 1, 2014

By J. A. Allan

The utilization of natural deposits of salt is one of the oldest industries in Alberta. In 1820, Sir James Richardson visited Salt river, and in the same year D. W. Harmon states chat "clown Slave river, there are several places, where almost any quantity of excellent dean white salt may be taken, with as much ease as sand along the seashore. From these places the greater part of the northwest is supplied with this valuable article". This reference is to the salt chat occurs around springs on Salt river at the northern boundary of the Province. This and other occurrences will be described later in this paper. It is not on account of the development of salt and gypsum in Alberta chat this paper has been prepared, but rather to draw attention to the widespread distribution of salt-bearing and gypsum-bearing rocks, and to the stratigraphic importance of these rocks . The origin of the deposits of salt, gypsum, anhydrite, and dolomite is discussed, and the economic significance of these minerals is considered. There is no salt production reported from Alberta in 1928.

Jan 1, 1929

By D. F. Coates

Slope problems arise on mining properties from cuts for roads and railroads and from open pits. When it is 'realized that 1,000,000 extra tons of waste may have to be mined as a result of an average slope being reduced by 1 ° it is easy to appreciate that the slope problems connected with open pits are of far greater importance than the others. The type of slope failure that can occur can be classified in different ways. The most useful classification would be one that separates the causes in such a way as to provide a basis for studies to deal with problems of prevention and control. Using this criterion the types of slope failures are classified into four groups. Having classified the problems in this way an understanding can be gained of the various mechanisms involved in failure ..

Jan 1, 1961

By P. Tarassoff

Extractive metallurgy is concerned with the winning of metals from their ores and concentrates. It is therefore not unexpected that extractive metallurgy in Canada has always been closely linked with mining. The discovery and exploitation of new orebodies has provided the impetus for the building of many of our smelters and refineries - past and present - and for the development of new metal extraction processes. The purpose of this paper is to provide a brief overview of those early metallurgical developments, and to highlight the continuing expansion and diversification of the Canadian metallurgical industry.

Jan 1, 1999

By Imane Benhamed, Jaouher Diouani, Laurent Cassayre, Florent Bourgeois, Carine Julcour-Lebigue, Université de Carthage

The attrition-leaching process aims at improving leaching performance when formation of passivation layers at the surface of leached particles is a severe limiting factor, as discussed recently by Julcour and coworkers (Julcour et al., 2015). This paper proposes a geochemistry-based modelling scheme for deriving the window of possible operating conditions for the attrition-leaching process to match the properties of the processed ore. The rationale is that the attrition-leaching process maintains the surface of reacting particles in an unpassivated state by continuous mechanical removal of surface leach layers, so that the process reactions can be modelled from thermodynamic equilibria throughout the duration of the process. The strength of the proposed modelling approach is that it bridges the gap between the properties of the ore and the process operating conditions. The present paper exemplifies the proposed process modelling route for derivation of the attrition-leaching process operating conditions in the context of the leaching of silicate ores, matching model predictions against controlled laboratory experiments. It is shown how thermodynamic modelling, when used in conjunction with a solid knowledge of the phases present in the system, can assist with deciding upon suitable process operating conditions. As an example, this firstprinciple modelling approach predicted that steel grinding medium would be converted into siderite (FeCO3) under a wide range of operating conditions, which led to questioning this initial choice of grinding medium for the attrition-leaching process under mineral carbonation conditions. It is emphasised that the same approach could be applied to ores of greater economic significance.

Jan 1, 2016

By C. Y. Lim, H. W. Kim, M. S. Kim, J. H. Cho, Y. S. Lee

Al - 5.5 wt% Mg - 0.3 wt% Cu alloy strip was successfully fabricated by horizontal-type twinroll casting (TRC). For producing sound strips with no surface defect, the casting was conducted at various roll rotation speed, and the sound strip could be obtained at relatively low casting speed (3 rpm). The cast strip was homogenized at 450 °C for 10 hours, and then cold rolled with a reduction rate of 78%, followed by a final annealing at 450 °C for 1 hour. The annealed sheets showed good mechanical properties with approximately 330 MPa in tensile strength and 27 % in elongation, but exhibited strong anisotropy depending on the tensile directions. For the homogenized sheets, warm rolling was also conducted at 200, 300, and 400 °C. The tensile test results of the warm-rolled sheets showed that the rolling at medium temperature (300 °C) was proper to fabricate the sheets with relatively good mechanical properties and low anisotropy.

Jan 1, 2014

By Jehan Rondot

Les trois intrusions alcalines de Suzorite en haute Mauricie, bien que non datees, son! sans doute d ,attacher aU)( nombreuses autres intrusions alcalines dispersees sur les blocks Grenvillia et Laurentia et datees de I 050 Ma =t= 10%, done reliees d l'orogene grenvilien. L 'utilisations de la Suzorite est liee d sa forte proportion de phlogopite (>50%). Le rapport Mg/Fey varie de 3 d 7. Sa mineralogie et sa composition particulieres (forte proportion de Mg, Ket H20) en font son attrait.

Jan 1, 1984

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019

By A. Desbiens, R. del Villar

"This two-part paper summarizes the design and implementation of a distributed PIbased control strategy installed at the B grinding circuit, at the Kidd Creek Division of Falconbridge Ltd. Part I details the design of the control strategy using a grinding circuit dynamic simulator (DYNAFRAG). The first step consisted of sampling campaigns and data processing to calibrate DYNAFRAG. Then, several control alternatives were designed and tested with the simulator. The main feature of these strategies is their ability to regulate or keep within an upper and lower limit five output variables (circulating load, rod mill density, cyclone feed and overflow densities and pump box level) with only three manipulated variables (rod mill water, pump box water and rod mill tonnage). By simulation on DYNAFRAG, it was possible to discriminate among several control structures. The preferred control strategy uses a saturation algorithm, which allows the adequate regulation of two measured variables with only one actuator. Controllers located in interacting loops are appropriately tuned, taking into account the existing process coupling. Part II will present the implementation of the selected control strategy.IntroductionSteady state simulators are used to predict the stationary state of a given process under specific operating conditions. Tradi - tionally, steady state simulation has been applied for process flowsheet design, for evaluating process modification benefits or for determining key operating parameters in process operation optimization. Dynamic simulators add a new dimension to process simulation since they allow the prediction of the process transient behaviour, resulting from the application of a different set of operating conditions and/or from natural disturbances or equipment failure. Dynamic simulators can also be used for the training of new operators or for the design of control strategies."

Jan 1, 1997

By W. W. Cummings

Canada's only current tungsten producer started up in 1962 with a small open-pit mine on the Flat River , 180 air miles north of Watson Lake, Yukon Territory. The orebody was in a contact-metamorphic skarn zone and contained about 1.5 million tons of ore grading an estimated 2.47% W03 and 0.5% copper. Near the end of the open pit , a new zone was discovered on the lower limb of the same structure, and the decision to go underground was made in 1972. The new "E Zone" contains over 4 million tons of ore grading an estimated 1.6% W03 and 0.28% Cu , and has been supplying the concentrator at about 175,0 00 tons/ year since late 1974. A continuing program of change and up-grading is necessary in the conversion from a seasonal open-pit mine with limited life to an underground operation with twenty years of reserves. Changes are necessary in plant and services as well as the mine. Also, environmental protection requirements have changed from rudimentary to rigorous over the life of the operation. This paper sums up the changes in the operation since 1971 and outlines the changes yet to come.

Jan 1, 1977

By Ian Orford, Ken L. Boyd

"Can the ever-increasing tonnages of ore and waste being mined today be accommodated simply by using bigger and better crushers? This paper updates the principal author’s earlier publication, “Crushing Plant Design and Layout Considerations” (SME Mineral Processing Plant Design, Practise, and Control, 2002). It reviews the latest primary crushing and large cone crusher designs. Its goal is to help consultants and operators select the optimal equipment and custom-designed items in the material handling flowsheet from the mine to the mill, maximizing operating hours per year.INTRODUCTIONAre larger crushers the answer to meeting the demands of existing or new mining projects for increased tonnage? The principal author’s previous paper in the year 2002 on ""Crushing Plant Design and Layout Considerations"" provided a detailed design and layout review for the design of primary and fine crushing (Secondary, Tertiary, Quaternary) mineral processing facilities. Some of the conclusions in this previous paper had predicted that larger crushers for primary and fine crushing would be beneficial and contribute to the further development of mineral processing. Larger crushers for primary and fine crushing applications are now available.The rock size reduction process, from the mine to the selected milling process facility has not changed since man first broke a rock to get at the interesting mineralization within. The rock size reduction process circuit from the mine to the mill can be summarized into four (4) stages:• Stage 1: Mining ( Rock Breakage and Fragmentation)• Stage 2: Pre-Screening (Scalping)• Stage 3: Primary Crushing• Stage 4: Fine Crushing (Secondary, Tertiary and Quaternary; the crushers used in this stage are identified by the titles which usage has conferred on them)Plant throughput and ore delivery schedule will form the basis for flowsheet design and equipment selection. Once a project's design criteria and the mine plan has been established, the actual circuit's utilization percentage (percentage of hours when the circuit is being utilized) can be optimized for each of the four stages. The mining and process departments are the key stake holders in the selection of the final comminution circuit and both departments should be familiar with and contribute to the design of the circuit."

Jan 1, 2016

By E. Yan, M. Mankosa, E. Wasmund

"Rougher flotation in sulfide ore applications is typically performed using conventional flotation machines. The trend over the last 100 years has been for these cells to become larger in volume with cells reaching sizes of 600 m3 and in some cases even larger. The associated foundation loadings, transport and installation requirements along with building size have also increased. In an economic environment where projects must be executed with dwindling capital supply, bigger is not always better. More recently, industry is being challenged to identify new technology that allows for improved flowsheets and financial returns through efficiency gains. To meet this challenge, a novel high-intensity two-stage flotation system known as the StackCell™ was tested to potentially achieve installation volume and required retention time gains when compared to conventional flotation circuits. The results from on-site pilot scale work conducted on typical copper concentrator rougher flotation feed showed retention time gains on the order of 6 to 9 times when compared with conventional flotation equipment. This finding has the potential of reducing capital demands for rougher flotation circuit designs when incorporating the StackCell. The results from test work will be discussed in this paper showing comparative test data generated with a Denver bench batch test, pilot StackCell and large conventional cells, all receiving the same feed.INTRODUCTION Over the last few years, a number of flotation devices have been described as two-stage or multi-stage flotation units. The idea behind multi-stage flotation devices is that flotation performance can be improved by utilizing cells with multiple specialized units in series, but not all units of the same type, as is practiced in trains of multiple tank cells or columns. Instead, each unit is specially designed to provide the optimized fluid environment for each stage of the sequential flotation process. This idea has been proposed based on a study of the fundamentals of the flotation process, and the realization that the process consists of discrete sequential processes, that are each optimized with dissimilar process conditions (Finch et al, 1995), (Zhou, 1996). Instead of executing each step simultaneously in a homogeneous fluid environment, where the conditions would be a compromise between particle collection and froth recovery, the multi-stage flotation unit operates in a set of segregated process environments, each with a set of conditions optimized for that step."

Jan 1, 2018

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001