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By Jerry M. Whiting, Neil J. Duncan

"Does Canada need a mining industry? Isn't it a chronically depressed collection of businesses that pollute the air and water and tear up the countryside? Wouldn't it be better if Canada's investors devoted their attention to high-technology endeavours, tourism, and other relatively pleasant tasks?Probably the answer to whether Canada needs a mining industry in the 21st century is to look at the real mining industry that is in operation today. The facts indicate that mining is a very important contributor to Canada. It has certainly encountered some challenging times during periods of recession, and it face s severe and continuing problems of cost and competition in world markets. However, uneconomic mines have been closed, others suspended, and productivity has risen dramatically with employment at 77 000, down from 101 000 in 1981. The country's metal and non-metal mines, metallurgical plants and semi-fabricated metals industries employed an estimated 378000 workers in 1986, and paid wages than any other sector of the Canadian economy. This effort resulted in the production of 60 different metals, non-metals and structural minerals valued at $13.5 billion.The trade aspects of the mining industry are of paramount importance. If there is a reason for this situation to change during the next century. it eludes the authors. Canada has the well-developed expertise to discover, evaluate, develop, operate and profit from existing and new businesses based in an enormous area endowed with a nearly unbelievable variety of mineral resources. Many countries throughout the world must rely on producers like Canada, if they are to maintain and/or improve their standard of living."

Jan 1, 1988

By Morgan Schauerte, Laura Raimondi, Mariel Palomeque

Executives in the mining industry are facing dramatically changing market expectations on reporting and transparency regarding the environmental and social impacts of projects, supply chains and products. Companies increasingly need to disclose the governance procedures they have in place to ensure communities, investors, employees, and Indigenous partners are effectively managing social and environmental risks. These disclosure requirements begin during exploration and carry through to all stages along the project life cycle. This type of environmental, social and governance (ESG) disclosure is referred to as ESG performance by the investment community. ESG is not a new concept, and it builds on and is intertwined with many concepts such as corporate sustainability, corporate social responsibility, eco-efficiency, triple bottom line thinking, life cycle management and many others. This paper will explore how mining companies can develop a credible ESG governance approach and strategy that will reduce risk, open opportunities, and create value. This paper will summarise ESG trends and drivers, discuss the economics and investors’ perspective towards ESG, and outline leading ESG standards and guidelines of interest to investors, regulators, communities and other stakeholders. Linkage of ESG to global sustainability efforts such the United Nations Sustainable Development Goals and Global Compact will also be addressed.

Jan 1, 2023

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By C. Bourgoin

"The factors constraining productivity in the mining of narrow vein ore deposits are numerous and often interdependent. This paper concerns mining techniques capable of reducing some of these constraints in the case of vein deposits whose dip is less than 45 degrees. Modifications of conventional mining methods as well as suggested new developments are presented, as are matters pertaining to the mechanization of operations as a mean of increasing both productivity and work safety. IntroductionThe mining of vein deposits, whose width (thickness) is generally less than 2 metres and whose dip is often variable, calls for the use of varying stoping procedures as well as appropriate infrastructure and equipment. In the case of intermediate dips (15 degrees to 45 degrees), it is generally conceded that the degree of mechanization is limited and that ore removal via gravity is impossible. This paper proposes certain innovations in matters of equipment use and stoping methods, together with certain technical data pertaining to the application of these new procedures Stoping MethodsTo mine vein deposits, one must choose a method that can adapt to irregular ore limits and allow, as well, for good ore recovery with as little dilution as possible. In addition, it is important to minimize development work in waste rock. In principle, one selects a method that is both safe and profitable; this method will be defined mainly by the nature of the vein deposit and its dip, by the competency of the rock formations and by certain technical considerations. Moreover, the stoping procedure in a given deposit may well change with time as a function of new layouts or new equipment."

Jan 1, 1994

By P. A. Studemeister

"A trondhjemite stock intrudes a volcanic sequence that has massive sulphide lenses and that is metamorphosed to the greenschist facies at Gutcher Lake, 25 km north of Wawa, Ontario. The stock is 4 km2 in plan and is partly enveloped by an aureole of chlorite-epidote-amphibolehornfels up to 1 km wide. Within this contact aureole, biotite is partly pseudomorphosed by chlorite;epidote and hornblende are mottled by chlorite, calcite, plus quartz; albite has 0% An to 8% An; and hornblende porphyroblasts have actinolite rims. The stock has chlorite pseudomorphous after biotite; and feldspar is mottled by white mica plus calcite and has a clear rim of albite. Fractures filled with quartz, calcite, ankerite, chlorite, white mica, pyrite, and native gold cross-cut the stock and its hornfels aureole. These gold-bearing veins are enveloped by foliated rocks with quartz, calcite, white mica, and chlorite that grade outward from the veins into trondhjemite or hornfels.The stock, emplaced into a submarine volcanic series, emanated heat that caused seawater to convect and formed a contact aureole of hornblende hornfels. The stock eventually intruded its aureole and this culminated with regional metamorphism to the greenschist facies. Regional metamorphism hydrated the stock and its hornfels aureole. Native gold precipitated with quartz along fractures from metamorphic flu ids in response to cooling and wallrock hydration. exploration for this type of gold deposits should focus around felsic intrusions that have albite and that have contact aureoles retrograded by regional metamorphism."

Jan 1, 1985

By Tom Shumka

Introduction ?This technique detects 100% of all gear tooth surface indications, providing comprehensive data, and has the ability to size indications accurately. ?The remarkable advantages of ECA technology, is improved inspection capabilities and significant time-savings. ?The advantage of using EMCD is its ability to size indications accurately. ?This technique does not require the gear teeth to be wiped down by hand after cleaning as in MT, LT or UT inspections. (Figure 1) ?This technique will inspect one gear tooth in 30 seconds. ?All of the data can be archived for future comparisons in an electronic report. Methodology ?This technique utilizes Eddy Current Array (ECA) as the principle inspection technique. ?What has been added are specialty scanner probes with multiple coils, a multiplexer and a software package. ?With 2 and 3D dimensional isometric displays, the defect can be seen electronically as it is on the gear tooth surface, thus, reducing the reliance on human interpretation.

May 1, 2011

By Frank Mucciardi, Louca Gourtsoyannis

"Low and inconsistent recoveries of aluminum in the production of aluminum-killed steels triggered an extensive research program on the aluminum dissolution kinetics at McGill University. This research program led to the understanding of the melting kinetics and the hydrodynamics of making additions to liquid steel. It showed the necessity of gradually releasing liquid aluminum at the bottom of the ladle to increase aluminum recoveries.This knowledge was verified in practice at Sidbec-Dosco, where a prototype aluminum wire injector was developed and installed for the first time in Canada. The industrial application showed the validity of the theoretical and experimental results and provided further data for the mathematical modelling of the process.The development of the theoretical understanding, the industrial results, and the interaction between university and industry are presented.IntroductionAluminum is an extremely effective deoxidizer of molten steel; nevertheless, an efficient method of adding it to steel has eluded steelmakers for many years. It is well known that the recovery of aluminum used in the production of aluminum killed steel is both low and eratic, especially when the aluminum is added in the form of bars or lumps from chutes into filling ladles, a practice still common in many of today's steelmaking operations.As the density of aluminum is only about 40010 that of molten steel, it is conceivable that loose bars of aluminum simply ""thrown"" into a filling ladle will resurface before any appreciable dissolution of the aluminum has occurred, particularly if the depth of penetration of the additions is small. Before one can conclude that this is indeed the case, it is necessary to know the melting kinetics of an aluminum addition. Back in 1972, this information was not available; hence an extensive research program which focused on melting kinetics was initiated at McGill University."

Jan 1, 1982

By J. G. Schofield, C. G. Tan, R. J. Ord

"Most electric furnaces in the nickel and copper smelting industries are still fitted with conventional electrode holders which consist of water-cooled electrical contact clamps and a pressure ring. The water cooling exerts a significant cooling effect on the electrode column. The importance of controlling the temperature of the Soderberg electrode paste at the contact clamp area is examined, using in-plant experience and computer simulation of the paste melting and baking process. In addition to the effect of water-cooling, the effect of other variables, including the mantle air temperature, the electrode current, the furnace freeboard temperature and the electrode slipping rate are discussed. Ways in which the variable heating conditions in the paste melting zone can be controlled are outlined.IntroductionIn most non-ferrous electric smelting operations, the breakage of Soderberg electrodes is an infrequent, isolated occurrence. Occasionally, however, a rash of breakages may be experienced on a particular furnace for what appears to be no obvious reasons. The extent of the breaks may not exhibit a uniform pattern; sometimes the break may be less than half a metre above the electrode tip; at other times it may be at or just below the roof level. The latter type of break is, of course, the most dangerous since it is closest to the non-baked, weak portion of the electrode paste column. No matter where the breaks occur, they result in abnormal furnace power, charging and tapping conditions and loss of production while the new electrode section is slipped and baked. On a six-electrode furnace, breakage on one electrode has the immediate effect of reducing the total furnace power by one-third. On a three-electrode furnace, the effect is more drastic, one half of the power being lost."

Jan 1, 1995

By D. E. Salman, R. R. Maclachlan, R. J. Barclay

"There is a considerable resource of data for spherical charge cratering, both as single charges and in row-of-charge geometr(1). The data are. however, based on cratering performance to a single free planar surface.In practice. the more common circumstance involves an angular surf ace geometry. such as occurs at the toe of a bench or the wall of a stope. It is for the purpose of investigating this circumstance that the described test work was conducted.The test objectives were: (1) to observe the change in single-charge cratering performance between planesurface and angle geometry; (2) to identify the optimum performance of single charges cratering to a plane surface. cratering from a bench sub-grade position and cratering from a condition of zero sub-grade or stope wall geometry; and (3) to observe the performance of row-of-charges cratering to an angular surface at various row burials and spacing. The row charge burial and spacing dimensions were to be expressed in simple numerical multiples of single-charge depth-of-burial data."

Jan 1, 1981

By Paul Toor

The operation of SAG mills is variable over time due to their continually changing liner shape, mass and subsequent load motion. However, this tends to be poorly accommodated in liner design and mill control, with only limited compensation made for this influence, usually in the first few weeks after a new liner is installed. With ever-increasing ore competency, increasing energy costs and decreasing ore grades, simplified design and operational approaches that compromise the achievable mill efficiency are no longer adequate. This paper presents a methodology that has been developed to measure and account for the changes in mill performance as the liner wears. This involves monitoring all liner profiles ? in other words the three-dimensional liner shape - over the life of the liner, then conducting controlled surveys at different stages of the liner wear life, and correlating the mill performance to the liner profiles. The measured liner mass is modelled to provide an ongoing meaningful load mass measure that excludes the liner mass.

Jan 1, 2012

By R. M. Clowes

"As part of LITHOPROBE's multidisciplinary earth science research program to understand the evolution of the North American continent, studies have been undertaken in a number of key areas in Canada. In the Trans-Hudson Orogen of Manitoba and Saskatchewan, LITHOPROBE results require re-evaluation of tectonic models related to its origin. In the Abitibi greenstone belt of Quebec and Ontario, results indicate a more complex evolution for the southern Superior province, one that links with the development of gold and massive sulphide deposits. As part of the program, the seismic reflection profiling method is being adapted for the mining industry. Three examples demonstrate the subsurface information that can be obtained. In Noranda, the base of the volcanic Blake River group is imaged and reflectivity is tied to geology through well logs; in Matagami, the zone of mineralization is shown to be downdropped along a majorfault; in Sudbury, a new structural model is developed, one that shows marked asymmetry at depth and indicates that some ore-bearing units on the margins of the igneous complex may be repeated at depth. IntroductionLITHOPROBE is Canada's national, collaborative earth science research project, established to develop a comprehensive understanding of how the North American continent has evolved. Ten transects, or study areas, were chosen to investigate pivotal geological features to their deep lithospheric roots. They span the country from the Pacific to the Atlantic Oceans and from the U.S. border to the Yukon and Northwest Territories, and geological time from four billion years ago to the present. A multidisciplinary approach, which is spearheaded by seismic reflection techniques, is essential to developing complete interpretations and outstanding scientific results. LITHOPROBE also has pioneered the use and demonstrated the value of using reflection technology to determine subsurface geology in mining camps.This paper provides an overview of the transects and their significance for the tectonic evolution of North America. Two specific examples demonstrate how we detennine present three-dimensional lithospheric structure and past geotectonic processes which formed it. The application of the reflection method to imaging complex structures in ""shallow"" crystalline rocks has been developed with funding and other support from the mining industry and provincial geological surveys. Sustaining funds, however, are derived from the Natural Sciences and Engineering Research Council and Geological Survey of Canada. Emphasis has been placed on developing deeper penetrating tools for exploration of deeply buried, but economically retrievable, mineral resources near existing mines, where an expensive infrastructure already is in place. Three examples, Rouyn-Noranda in western Quebec, Matagami in northwestern Quebec and Sudbury in northeastern Ontario, illustrate these developments."

Jan 1, 1994

By R. W. Thompkins

"PREFACEPart 1 of this paper, published in the September issue, covered the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.This Part 2, which follows, deals with radiation theory applied to uranium ores, other radon migration factors, factors affecting the radon gas release rate, the measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade and estimating radioactivity from grade analysis.The series will conclude with Part 3, in the November issue, which will discuss the techniques for controlling radiation and provide some example calculations.10.0. Radiation Theory Applied to Uranium Ores10.0.1. The processes of diffusion transport of radon gas, through rock from the fundamental physics is a function o f the radon gas concentration in the interstitial pore spaces and the distance from the surface. Expressed by Fick's first law of diffusion, it is expressed: [ ]10.0.2. The maximum concentration is a function of the emanating power (ß), thus the above equation may be expressed: [ ]10.1. The Effect of Porosity10.1.1. If a constant emanating power is assumed (ß), a family of curves can be obtained for concentrations at varying distances and rock porosities. The curves as originally plotted assumed a constant emanating power of 5 x 10-4 pico curies/litre/sec and show the maximum expected concentrations in the pores in pico curies per litre. Because these concentrations are proportioned to the emanating power, this set of curves can be structured to show the fraction of maximum concentrations possible at various porosities of the rock.10.1.2. Notice that at 10, 20 and 30% porosities a 5-cm sample (hand-sized and drill-sized pieces) has no practical increase in pore concentration. Thus, by measuring the emanating power of hand-sized pieces of ore, the actual radon gas production into any pile of broken ore could be estimated readily."

Jan 1, 1982

By Yuki Tsunazawa, Shuji Owada, Sho Fukui, Chiharu Tokoro

"Since the amount of e-waste has been rapidly increasing all over the world, there is a desire to develop the effective recycling process. E-waste has various kinds of electronic components with valuable and/or hazardous materials. Recycling of them is an important subject from the viewpoint of both the recovery of valuable materials and waste treatment. In common with all mineral processing, the comminution of e-waste is a key process because the liberation states after comminution determine the overall efficiency of metal recovery. Since some of useful critical metals are concentrated in a specific component, a special and selective grinding is expected to be effective. However, the knowledge about the mechanism and the effectiveness of the selective grinding is still limited and unclear.To better comprehend the mechanism, in this study, the investigation of comminution process using the particle-based simulation was conducted. Especially, this study focused on the comminution performance of printed circuit boards (PCBs), which are major components of e-waste. The behavior of PCBs and airflow in a drum typed agitation mill having flexible chains was simulated by the discrete element method (DEM) coupled with computational fluid dynamics (CFD). To model the shape of PCBs, the particle based rigid body model was introduced into the DEM. Since this model could not directly simulate the breakage phenomena, collision energy was calculated to qualitatively evaluate the comminution performance. In addition, the simulation results were compared with the experimental comminution tests using simulant PCBs where some capacitors were solder-mounted. These results indicated that comminution performance was affected by the rotation speed of the agitator. It was also demonstrated that the comminution performance was qualitatively evaluated using the particle-based simulation and this particle-based simulation made it possible to investigate the mechanism of e-waste comminution."

Jan 1, 2016

By Nirmal Weerasekara, Lian X. Liu, The University of Queensland, Weiguo Xie, Benjamin Bonfils, Ping Yu

A mill model structure based on the population mass balance framework incorporating breakage characteristics, slurry and solids transport, product classification and discharge and energy consumption was reported in XXVII IMPC and named the Generic Tumbling Mill Model Structure Version I (GTMMS I). In this work, a new 4D (four dimensional) appearance function sub-model based on the experimental results of the JK Rotary Breakage Tester (JK RBT) was developed to describe the breakage characteristics and was applied to this new model structure. The newly developed 4D appearance function model has fewer fitting parameters and is more generic in nature. Most importantly, it is applicable to both high and low energy impact breakage. It is therefore much more versatile in comparison to the existing JKMRC t10- tn appearance function and the size-dependent JK M-p-q t10-tn appearance function. In addition, the Discrete Element Method (DEM) energy distribution model was integrated into the new model structure. With DEM results providing energy distribution information inside the mill directly, the selection function and the back-calculation method used in the existing JKSimMet modelling method are not needed in this model structure. With the above two revolutionary innovations, the previous model structure was upgraded to the Generic Tumbling Mill Model Structure Version II (GTMMS II). Furthermore, the new model structure is dynamic in nature with time-stepping technique for non-steady-state simulation. A case of the dynamic grinding of a SAG mill was studied to validate the GTMMS II. The model simulation results agreed well with the plant data. With the newly developed 4D appearance function model, the incorporation of DEM energy distribution and transport function, the GTMMS II is an important step forward towards mechanistic modelling of tumbling mills.

Jan 1, 2016

By Andrew Bamber

The mining and beneficiation of minerals is the second largest end-use of electrical power on the planet, and comminution is by far the largest single contributor to this. Several jurisdictions, including British Columbia, have, in response to concerns about greenhouse gas emissions and climate change, adopted energy conservation legislation, including carbon taxes, carbon trading and conservation incentive schemes. Key to achieving conservation objectives is firstly an understanding of usage metrics across the various unit operations in the sector, and secondly an understanding of the conservation potential represented by available technologies and approaches in reducing end-use. This paper presents the results of a recent utility-funded study on energy use metrics and conservation potential at large open pit mines which are typical of the sector in BC.

Aug 1, 2013

By C. S. Ha, H. S. Choi, D. Y. Shin

POSCO installed a new 100 ton oxygen bottom-blown converter in 2013 for the development of new steelmaking process named as PS-BOP which is reading POSCO-Saarstahl Basic Oxygen Process. This process was developed by the collaboration research between POSCO and Saarstahl AG in Germany that is based on substantial increase of CO post combustion in a converter by blowing hot air from the top of converter. The collaboration research has been finished successfully in November 2013 with 17% decrease in hot metal ratio (HMR) when hot air was blown from the top of the oxygen bottom-blown converter. After the collaboration research the converter has been tried to be operated as oxygen top and bottom-blown converter to reduce bottom wear and to decrease production cost with increased use of low cost Fe source by the help of increased CO post combustion. The presentation includes experience on the start up of oxygen bottom-blown converter, HMR reduction trials with hot air top blowing and transition from oxygen bottom-blown to top and bottom-blown converter operation.

Jan 1, 2015

"The Australasian Joint Ore Reserves Committee (JORC), which is sponsored by the Australian mining industry and its professional organisations, developed the JORC Code to provide minimum standards for public reporting. JORC was first published in 1989 and later incorporated into the Listing Rules of the Australian and New Zealand Stock Exchanges making compliance mandatory for listing public companies in Australia and New Zealand."

Jan 1, 2003

By F. T. Manns, G. Harper

"The Swayze gold mine is an Archean vein deposit in northern Ontario. The veins are superimposed on a conjugate joint system and are contained within an anastomosing alteration envelope in a metadiorite body. Reserves were estimated on the basis of fire assays of channel samples and car load samples from underground mine openings, surface and underground diamond drilling and surface trenching. A semi-variogram constructed from channel samples along one of the drifts yielded a horizontal, regionalized influence of approximately 9.0 m. Common industry practice has been to use 6.1 m for similar deposits in Ontario. Proven ore was defined from underground openings. The maximum extrapolation distance for proven ore along strike and dip from a data point is taken to be 6.1 m. Probable ore is extrapolated 7.6 m from a data point in a mine opening or from a drill intersection. Possible mineralization is based on geological continuity one-half the distance to a neighbouring data point.The mineral inventory estimate of 1.45 million tonnes at a grade of4.8 g Au/tonne gives an excellent outline of the geology of the deposit. The deposit contains 313 000 tonnes of ore reservesat a fully diluted grade of6.9 g Au/tonne. These figures include dilution for several reasons: (I) a 2.1 m mining width is used rather than the more typical 1.5 m width to allow for over break because of the shallow dip of some vein zones; (2) over break is allowed for adjacent to major unmineralized dykes; and (3) grams of gold are deleted from estimates to allow for the mining of unavoidable minor dykes.A personal computer with off-the-shelf software was used to compile 712 geologically defined ore blocks and sort them into a number of revealing categories. The computer was used to perform grade sensitivity tests, as well as to evaluate depth potential. Hopefully, the reiterative aspect of the method has randomized the errors and helped to cancel their effects."

Jan 1, 1987

By Vincent Doyon

For several years, the GDD SSW EM Probe is being used in nickel?s mines in Canada and Brazil to define ore limits, reduce dilution and predict nickel grades. It is used with success to test most if not all percussion blast holes at all Falconbridge Mines in Sudbury and Raglan and all Inco?s Thompson mines. However, after testing the SSW Probe in other metal mines, we realized that EM conductivity does not define ore limits by testing blast holes for copper, zinc or gold. For non-conductive ores, no instrumentation is yet available on the market to reduce dilution, by outlining quickly and inexpensively the real shape of an orebody. To that effect, Instrumentation GDD Inc has developed a new revolutionary photonic probe that will make the reduction of dilution possible by probing blast holes. Once surveyed with the probe, a computer draws graphs of the ore grade as a function of depth for each blast hole. A contribution by Canada Economic Development made possible the development of this new technology. Canmet and Soredem also cautioned this technology developed by Instrumentation GDD Inc. This new photonic probe will allow: 1) to better understand the shape of the orebody 2) to raise the grade of the ore fed to the mill 3) a more complete extraction of the ore 4) to raise the competitiveness of mines

Oct 1, 2004

By Ali M. Ghazi, Ronald J. Goble, Lowell S. Whiteside

"Geerite (Cu1.6S) is a rhombohedral copper sulphide which occurs naturally in epitactic replacement of sphalerite; cell dimensions closely approximate those of the host sphalerite.Geerite-type structures can be produced by leaching digenite (Cu1.8S) in ferric sulphate solutions. X -ray diffract ion and electron microprobe studies indicate that eight metastable geeritetype structures can be produced, depending upon the concentration of f erric sulphate solution used and the duration of the each. Although compositions cluster on or near values observed for natural phases, optical properties indicate that we are dealing with polymorphs of these phases. Leaching of chalcocite (CU2Sj in dilute f erric sulphate solutions produces similar results. In contrast, leaching of chalcocite in more concentrated solutions seems to produce true analogues of natural minerals.During froth flotation, sphalerite is activated with a monolayer of floatable copper sulphide with the composition, CuS, of the mineral covellite. However, covellite is not significantly more floatable than sphalerite, and has an incompatible structure because of the presence of covalently-bonded atoms of sulphur. Leaching ofdigenite was used to produce a polymorph of covellite with a geerite-type structure, compatible with that of sphalerite. This polymorph has a flotational behaviour similar to copper-activated sphalerite, suggesting that the monolayer has a geerite-type CuS structure. IntroductionIn an ideal close-packed sulphide structure the distance between sulphur layers, D, is equal to 2R 2/3, where R is the radius of the sulphur atoms. In sulphides with covalently-bonded sulphur layers, such as covellite (Fig. I), D will be an average of the number of covalentl y-bonded and close-packed sulphur layers, weighted as to the relative number of each type of layer. Both D and R are spacings which are readily identifiable structurally and on X-ray diffraction patterns. Goblel has shown that for copper-iron sulphides with metal-to-sulphur ratios between 0 and 2 and copper-to-total metal ratio s between 113 and I there are strong correlations between composition and measured D and R distances (Fig. 2). D can be represented by a single empirical equation relating interlayer spacing to composition; R must be represented by three equations relating the radius of sulphur atoms to composition. One of these equations (R, in Fig. 2) represents ideal close-packed behaviour, the other two represent sulphur radii greater than (R1) or less than (Rh) the ideal."

Jan 1, 1988