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By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By Han Xing, Cui Jianzhong, Qin Ke, Shao Bo, Zhang Haitao

In this paper, a new approach that uses hot-top DC casting process to producing multi-alloy ingots is present. The different type and size of composite and coated ingots (4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm and 4045/3003 coasted ingot with F140mm/F110mm in diameter) are cast by this approach. The macro-morphologies and microstructures of the composite ingots, the temperature distribution and the element distribution in the interface zone were investigated, also and the interface bonding strength was measured. Results show that the solid supporting layer formed on the cooling plates plays a key role in the casting process of composite ingots. The solid supporting layer can prevent the blending of two melts by resisting the impact of alloy melt, which ensures the stable casting process and casting high quality composite ingots, because the contact height is increased using hot-top DC casting. In addition, fabrication and properties of 4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm are reported in detail.

Jan 1, 2015

By A. S. Knight

THE breaking and handling of ore is obviously the most important consideration when the layout of a new mine is contemplated. The problem must be attacked with due regard to the claim area of the property, the dip of the orebody, the anticipated percentage of payability, the width of the reef, and the amount of dislocation anticipated by dykes, faults, or sills. Among these, as far as East Geduld is concerned, the three most important items are: Area. 2,640.5 claims. Average dip 12° (from flat to 35°) Average channel width 36 inches. We are fortunate on the Witwatersrand in 'chat there is usually sufficient information available from surrounding properties to determine, within narrow limits, the factors mentioned above. With this information avail-able, the choice of layout is not limited, and it will be found that on the Witwatersrand each group has developed its own technique to suit its individual requirements. On East Geduld, the layout of the property for handling ore is known as the endless-rope haulage system. Following is a brief description of the general principles followed.

Jan 1, 1942

By J. E. Dutrizac, J. M. Zinck

Ferrihydrite is often the initial precipitate resulting from the rapid neutralization of Fe(III) sulphate solutions, and it seems to be a major constituent of zinc plant neutral leach residues. The most important parameters affecting ferrihydrite precipitaton are temperature, solution pH and the neutralization rate. Low temperatures and rapid neutralization rates yield poorly filterable ferrihydrite, whereas higher temperatures and slower neutralization rates produce readily filterable precipitates; in all instances, however, the precipitates are two-line ferrihydrite. Significant amounts of Zn are incorporated in the ferrihydrite precipitates, and the Zn contents increase with increasing Zn concentration, pH or temperature. Generally, the sulphate contents of the precipitates decrease as the Zn contents increase, and this may indicate that the Zn is adsorbed on the ferrihydrite. Discrete Zn phases were not detected. Neither Cd nor Tl is precipitated with ferrihydrite, although thallium jarosite co-precipitates with ferrihydrite at high Tl concentrations and elevated temperatures. Virtually all of the Sn added to the solution precipitates with the ferrihydrite, but the tin is believed to be present as intimately admixed amorphous SnO2.nH2O. Although selenite extensively precipitates with the ferrihydrite, selenate remains mostly in solution, likely because of the close similarity of the SeO4 2- ion to the SO4 2- ion which is present in high concentrations and saturates the available sites for anion adsorption.

Jan 1, 1998

By D. J. Scarpato

"Slope construction in shale can present some interesting challenges for geotechnical design engineers and contractors alike. There are challenges that can be expected and designed-for; however, all too frequently, such challenges manifest themselves as “surprises” in the field. Common constructability challenges can include those such as drill hole deviation during drilling for controlled blasting; and, excavation slope instability arising from inconsistent perimeter control drilling. Drill hole deviation results from the cumulative effects from both drilling mechanics and rock mass conditions. Once a hole has initiated the deviation trajectory, it is difficult to rectify drill steel position. Although such challenges are not necessarily unique to shale, they are often exacerbated by weak, weathered and transversely isotropic nature of bedrock conditions. All too often, the working assumption is that shale is “soft” and easily excavatable; however, this blanket assumption can prove to be costly. This paper is intended to provide design professionals and contractors with the practical considerations needed to avoid the “surprises” associated with drill hole deviation, and minimize the potential for costly claims.INTRODUCTIONFor all the slopes that have been excavated worldwide, and for such advancements in excavation technology and field characterization, one might be tempted to believe that the industry almost has slope development down to a science. This is frequently not the case, especially for weak/weathered and anisotropic bedrock. Excavation contractors are still pushed to the limits of what their technology can achieve, and engineers are all too often called to the field during construction, to make potentially risky onthe- fly decisions relative to excavatability, short and long-term slope stability, and project safety. Although there have been a host of other research papers and journal articles that have been written on the subject of deviation over the past 30 years (Brown, Geen, Sinha, 1981), the problems associated with drill hole deviation are still all too frequent. This fact is especially true for civil engineering surface excavations in bedrock."

Jan 1, 2015

By K. Chattopadhyay

Fluid flows in metallurgical reactors play a vital role on liquid metal cleanliness for both ferrous and non-ferrous metallurgy. Thus, it is absolutely critical to understand different fluid flow mechanisms, and the use of computational methods to model the complex non-isothermal, turbulent, single- and multiphase-flows, has to be appreciated. The present case study emphasizes on controlling the flow of liquid steel in a tundish and enhancing liquid metal cleanliness. CFD modeling was used to build a robust mathematical model, and effects of flow control furniture and non-isothermal conditions were analyzed. The mathematical model was validated against water model experiments. Parameters that were conducive for inclusion removal were identified and implemented in the plant. Some flow control devices could increase inclusion removal to a great extent compared to the existing configurations. In cases, where a hot ladle was poured into a relatively cooler tundish, inclusion removal was better, whereas results were catastrophic in cases where colder liquid was poured from ladle to the tundish. Similar techniques can be applied for other liquid metals including light metals and non-ferrous metals.

Jan 1, 2015

By J. Basi, J. A. Finch

ABSTRACT Testing the effects of bubble size (Db) in a Mo cleaning ?otation column at Highland Valley Copper mine indicated that increasing the proportion of small (< 1 mm) bubbles signi?cantly improved column metallurgical response, compared to typical operation. The results were a three- to four-fold Mo recovery increase and a 1 to 2% Mo (absolute) concentrate grade increase. The improvedcolumn operation produced a 4% Mo plant recovery increase. This study also showed that modelling the ?otation rate constant (k) as an inverse square function of Db was more accurate than considering k to be inversely proportional to Db.

Jan 1, 2010

By C. Riveros, H. Henein

Bulk Metallic Glasses have a high potential as advanced engineering materials due to their various properties including strength and corrosion resistance, to name a few. This paper investigates amorphous phase formation and rapid solidification characteristics of impulse atomized Co-based alloys in order to understand and control the application properties of the final products. Amorphous fraction and kinetic crystallization properties of the atomized Co-based alloy powders were quantified by means of Differential Scanning Calorimetry. In addition, different but complementary characterization tools were used to analyze microstructures of the powders. These include optical microscopy, X-ray diffraction and micro-hardness tests. While the amorphous fraction within the powders is promoted by high cooling rate and smaller powder size as expected, hardness is found to decrease with the fraction of amorphous phase.

Jan 1, 2015

By L H. Warren

The types of equipment available for generating a plasma have been reviewed. The efficiency and potential of the plasma generating equipment used in performing extractive metallurgical reactions have been determined. A general classification of the reactions that might be per-formed in a plasma has been proposed. Experimental work done on extractive metallurgical plasma reactions, heat transfer between the plasma and solids, and the quench of the products of plasma reaction has been summarized. From the preliminary results it appears that the high-intensity are or the transpiration-cooled anode plasma torch offer the most promising areas for further research. C ONSIDERABLE world-wide research effort is currently being devoted to the development of processing technologies which employ the new high-temperature generating devices that have appeared over the past few years. The plasma flames produced by these devices offer the potential for subjecting materials to any single gas or mixture of gases at temperatures up to 20,000°K. With these conditions available, many reactions in extractive metallurgy,

Jan 1, 1965

By T. Crivits

"Freeze lining technologies are used industrially to protect the integrity of furnace walls in pyrometallurgical reactors. This is achieved by solidifying a protective layer of slag on the inner furnace wall. In the current study, laboratory experiments have been undertaken to produce freeze linings in ‘Cu2232 O’-‘FeO’-MgO-SiO slags under controlled conditions using an air-cooled probe technique. Whilst most thermal models of freeze linings have assumed the freeze lining-bath interface to be at the liquidus temperature of the bulk bath and to be planar in geometry, the current research has demonstrated that this is not the case. Experiments undertaken using this high-temperature slag system have shown the interface at steady state conditions to be at subliquidus temperatures. The solid phases present at the interface do not include the primary phase and the interface is non-planar. The study indicates the need for improved understanding of the fundamentals of freeze lining formation, and of the influence of system properties and process parameters"

Jan 1, 2015

By Jaeheon Lee, Junmo Ahn, Doyun Shin

"Many alternative leaching systems including bacterial leaching have been introduced to avoid passivation on the surface of chalcopyrite and to increase the leaching efficiency of copper from chalcopyrite. Recently, glycine, one of the simplest amino acids, has been emerging as an efficient and environmental-friendly lixiviant to recover copper. In the present study, an alkaline glycine–peroxide lixiviant system was used to leach copper from chalcopyrite concentrate and the leaching mechanisms were also investigated by a suite of kinetic studies under different conditions. The chalcopyrite concentrate contains 28.8% copper with 30.8% sulfide sulfur. The effect of concentration of glycine and hydrogen peroxide of the leaching solution was investigated. Glycine concentration was varied from 0.5 to 1.0 M and the hydrogen peroxide concentration was changed between 3 to 5%. Leaching time and pulp density were also varied. Hydrogen peroxide is an oxidant of the system and the leaching efficiency with periodic additions of the peroxide was also studied. A mineralogical study was performed using XRD and SEM. To investigate the surface of the residue materials, XPS was used to see if any passivating layer was formed during the leaching. Detailed results from mineralogical, chemical, and metallurgical studies will be presented and discussed.INTRODUCTION The greatest global resource of copper is low-grade chalcopyrite and heap bioleaching may be the only economic option for its processing. However, formation of a passivating layer on the surface of chalcopyrite slows down the oxidation reaction and reduces the efficiency of the process."

Jan 1, 2017

By Peter N. Blakey, Jean-Paul Paquette, Barton A. Thomson

"FROM THE BEGINNING OF THE PIT, it was known that the surface mining method had a projected life of about ten years, and that the ore extended to depths recoverable only by underground mining. When serious consideration was given to underground mining in 1968, it was realized that tremendous advantages could be gained by starting the underground mine as early as• poss1ble. These included: 1. The availability of underground ore for grade control, which would become more difficult as the pit deepened. 2. The need to develop new systems, equipment and skills to take full advantage of the technological revolution in underground mining. 3. Early knowledge of rock behaviour through trial mining on a small scale prior to finalizing plans for major blocks. In addition, the pit would be available to guarantee the mill supply if problems were encountered. 4. With sufficient time and early mining experience a much better job could be done on all mine planning. Because ample reserves of economic underground ore were virtually assured, the desired underground mining capability became a function of two restraints: first, the time required to excavate and construct the permanent headframe, shaft and ore-handling facilities necessary to handle large volumes of stope ore; second, the time for lateral and stope development on at least one level which would normally follow shaft sinking. The decision made was to move immediately on the permanent hoisting installations and at the same time embark on the planned ramp from surface, which would allow much stope preparation to be completed prior to .bringing the shaft on stream. Both projects were placed on an urgent basis early in 196S' and the following decisions made shortly thereafter."

Jan 1, 1974

By J. Grignon, C. Fleming

It is possible to reproduce the performance of an operating CIP or CIL plant in the laboratory, in small scale batch kinetic tests, coupled with mathematical models that translate kinetic data into predicted steady state gold profiles across multi-stage adsorption circuits. Once the performance of the commercial plant has been mimicked by the model, the plant operating parameters can be varied systematically in the model, and the likely response of the plant to the step wise change can be determined. In this way it is possible to inexpensively optimize the operating conditions of an existing plant, with no disruption to plant operations and no economic risk to the mining company. This approach had been adopted by IAMGOLD to optimize the performance of their Rosebel CIL plant following several major expansions in mill capacity since 2004.

Jan 1, 2011

By S P. Giambra

The 50,000-ton-per-day Concentrator and Crushing Plant, complete with its related water supply, tailings disposal and concentrate handling systems, was started up in a five-month period, with the entire plant obtaining its design capacity six months after the first mill became operational. Individual mill lines, with their spiral circuits, achieved design capacities within a week after the first treatment of ore through each mill. Construction and start-up proceeded together in many areas of the plant, and considerable organization and cooperation between the Owner, the Engineer and the Contractors permitted a smooth transition from construction to operation. PLANT DESCRIPTION THE Carol Lake Plant of the Iron Ore Company of Canada l1as been well described in various technical magazines. The purpose of this paper is to present a brief outline of the start-up of the con-centration complex. This start-up was accomplished in a period of five months, with the plant producing one million tons of concentrate and achieving its design-rated tonnage less than six months after the first ore was treated.

Jan 1, 1963

By N. Ahern, L. Manoukian

"Cyanide is a leaching agent for precious metals commonly used in gold ore processing. Cyanide exists in various forms (including free, complexed as weak or strong complexes, and as ions such as cyanate and thiocyanate), so its detection, speciation and analysis in processing or environmental samples can be complex. This paper will review best practices for cyanide sampling and preservation in the field, interferences and pretreatment methods required prior to sample analysis and analytical methods that are used for cyanide species. Titrimetric, flow injection ligand exchange, spectrophotometric, colorimetric, potentiometric, amperometric, and chromatography techniques will be discussed and their chemistries, detection limits, advantages and limitations will be described.INTRODUCTION Cyanide is well known to be an extremely toxic species. Accurate cyanide measurement in effluent from mines is critical from an environmental perspective. Its measurement is also an important control parameter in the recovery of gold using cyanidation. Cyanide chemistry is diverse and complex, and cyanide analysis can be challenging as a result of and because of limitations in understanding of analytical methods. Various chemical mechanisms can form or destroy cyanide, and the sample matrix or preservation chemicals can also affect analytical results. These interferences make the collection of reliable cyanide measurements challenging and can start as soon as the sample is collected, during laboratory pre-treatment and during analysis. This paper reviews different methods of cyanide measurement. The basic chemistry of cyanide, best practices for sampling and preservation, as well as various methods of analysis will be discussed.CHEMISTRY The complexity of cyanide chemistry is well known (Beck, 1987; Delgado, Botz, Bucknam, Milasovljevic, & Staley, 2008; Botz, Milosavljevic, & Ward, 2013) and is attributed to the ability of cyanide to undergo: •,Volatilization •,Precipitation •,Adsorption •,Complexation with metals •,Oxidation to cyanate, ammonia, or cyanogen chloride •,Reaction with sulfur or sulfide minerals to form thiocyanate •,Redox reactions leading to the formation of cyanogen and cyanate •,Redox reactions (of some cyano complexes) •,Photochemical reactions (of some cyano complexes)"

Jan 1, 2017

Infrared spectroscopic data collected using HyloggerTM technology is being used to assess the mineral composition of Archean iron ore bedrock and Cenozoic detrital units in Western Australia’s Pilbara region. Analysis of infrared spectra enables quantification of: (1) composite iron mineralogy, (2) composite clay mineralogy, (3) hydrous silicates and (4) carbonate mineral abundances. Stratigraphic and rock mass unit logging of core has identified several detrital and bedrock units recognisable across the Pilbara. However, due to alteration related to mineralisation, weathering and later stage precipitate overprinting, it can often be difficult to assess the detrital-bedrock boundary and the occurrences of specific geotechnical units in the detritals and bedrock, particularly when using non-core drilling techniques and traditional geochemical assays. Infrared spectroscopic data collected concurrently on core from several sites has shown distinct correlation against existing unit subdivisions and associated geochemical parameters. Where infrared spectroscopic data have also been collected on rock chips recovered from reverse circulation infill drilling, these correlations allow robust geological and geotechnical models to be developed based on the typical mineralogical-geochemical signatures. The geotechnical sub-units identified in core can be readily distinguished using the various iron and clay minerals captured by the HyloggerTM technology as opposed to total iron, potassium, and alumina captured by geochemical assays. Further, some of the minerals targeted by infrared spectroscopic analysis (eg gibbsite, white mica, vitreous goethite) and their ubiquitous presence as the products of weathering, assist in recognition of various ancient weathering surfaces and help to define the origin of the material, whether bedrock or detrital. Overall, HyLogging of core and chips allows important mineralogy focussed data to be captured at minimal additional financial outlay. Correlations against geochemical unit identifiers are robust both within deposits and between deposits. Significant improvements in the confidence of geological and geotechnical models are attained.

Jan 1, 2015

By C. Pichler, C. Benigni, J. Antrekowitsch

"The recycling of steel mill dust results in zinc oxides which are sold to the primary industry in or-der to recover zinc in its metallic form. Due to the contained impurities - chlorine and fluorine - these sec-ondary oxides are usually charged into the roaster together with primary concentrates. Appearing problems in this furnace limit the application of secondary materials. Based on the zinc amount, a direct leaching, assumed that a low halide concentration is present, would be possible. To use the zinc solution directly in the electrowinning stage, the concentration of impurities, first of all iron, is limited. Iron can be found in secondary zinc oxides due to carry over during the recycling process. In order to reduce the iron content in the solution, the leaching has to be pH-controlled. This leads to a limited number of simple purification steps before the solution enters the electrolysis. Various trials were performed to evaluate the influence of temperature, time and sulphuric acid concentration on the iron dissolution. This paper deals with the results and also focuses on other impurities such as halides. Additionally, the soda washing process, usually done with secondary zinc oxides to remove most of the halides, and the challenges within this step are discussed.INTRODUCTION Recycling of steel mill dust, which is the main zinc containing residue, in the Waelz process dis-plays the common method worldwide. The product of the process is a secondary zinc oxide which is con-taminated with different elements like lead, iron and halides due to mechanical carry over or evaporation. Depending on the feeding material the concentration of each element in the dust is varying. The zinc con-tent of the product, also called Waelz oxide, lies around 65–68%. Based on these values it presents an al-ternative to the primary concentrate for the production of metallic zinc. The contained halides limit the direct utilization in the leaching stage and therefore have to be reduced. State of the art is a soda washing process but also solvent extraction gives a possibility to remove chlorine and fluorine but the desired con-centration for the electrolysis is hardly reachable (Antrekowitsch et al., 2016) Iron is present as an undesirable component of such secondary zinc oxides due to carry over. During the hot acidic leaching of the secondary concentrate, iron is dissolved too. Based on the higher electrical potential iron has to be removed before the zinc solution enters the electrowinning stage. It is usually removed by precipitation as goethite, hematite or jarosite, which is the common precipitation residue (Ismael et al., 2003)."

Jan 1, 2017

By Brian G. Pewsey

Located in the northern part of the Province of British Columbia, the Cassiar Mine started development of its asbestos orebody in 1952, and is currently producing 105.000 tons of asbestos fibre annually. The townsite is nestled in a beautiful valley and supplies more than average facilities. The fibre is shipped to more than 40 countries and is used in many industrial products.

Jan 1, 1978

By D. G. Minnes

Many non-metallic minerals and structural materials are produced in Ontario to serve the needs of domestic manufacturers and export markets. In 1982 production was estimated to have a value of $765 million. Approximately 81 per cent of this was represented by structural materials, nearly 12.8 per cent by salt, and the remainder was other industrial minerals. Total mineral production in Ontario in 1982 was estimated at $3 .16 billion, down nearly $1.5 billion from 1980's high of $4.58 billion.

Jan 1, 1984

By G. J. McTeer, D. L. Verhelst, D. J. Rioux

Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. Since 1997, KIVCETTM flash smelting technology has been utilized for the treatment of zinc plant residues and lead concentrates. Trail Operations’ furnace uses four water-cooled jackets for bullion tapping. This paper provides an overview of KIVCET bullion tapping for the past 16 years, and discusses successes and challenges encountered with respect to operations, training and monitoring.

Jan 1, 2015