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By John Malcolm Gray

Interest in X-80 linepipe steels emerged in the early 1980’s and it was first used in 1985 by Ruhr Gas [1]. The early steels were extensions of conventional Nb-V or Nb-Mo microalloyed X-70 steels but other alloying concepts emerged based on Nb-Mo-B alloying (NKSTAF [2] and ULCB [3]). The latter had acicular ferrite/bainitic microstructures and carbon contents below 0.05 percent. In parallel renewed interest developed in ultra low carbon (0.02 percent) higher niobium steels which had first been studied in 1962 [4]. Such steels exhibited excellent notch toughness when processed with high finish rolling temperatures (>950°C) which made them suitable for processing on weak, older rolling mills. With time such steels, designated “High Temperature Processed”, or HTP steels, were further optimized and produced in modern, very strong rolling mills due to their superior economy compared with traditional vanadium and molybdenum containing steels. The chronology of the HTP development is presented in the present paper. Full scale demonstration heats of a 0.06 percent carbon 0.10 percent niobium steel were produced by Bofors Steel Plant in 1972 and were converted from slabs to plates by nine different steel mills [5-7]. Commercial application in API Grade X-70 first occurred in Canada in 1974 [8,9] but the concept was only used sporadically after that until 1998 when it was applied for the API Grade X-70 Sour Service Cantarell Project [10] in Mexico. Soon thereafter, the El Paso Cheyenne Plains Project used a 0.05%C 0.095%Nb 0.27%Cr variant of the HTP steel [10-12]. Nowadays the HTP concept is being utilized for construction of approximately 6000 km of 48” OD x 18.4 mm X-80 per year in China. The metallurgical principles and history of the development are presented in details in this paper.

Aug 7, 2018

By Rodrigo Fina Ferreira, Jacek Kolacz, Luciana Gois, Neymayer Pereira Lima

The recent developments on the sensor detectors together with the higher capacity of the machines, due the high-speed computing recent advances, have made possible extending the application in the mining industry. The use of x-ray fluorescence, x-ray transmission and radiometric sensor based sorting can selectively remove gangue minerals in different size fractions for different minerals. This paper summarizes the potential application of SBS for an iron ore in three size fractions aiming to increase the %Fe after the removal of particles with main gangue minerals associated. Pilot plant tests were carried out with samples of iron ore in different size fractions and different content of hematite and gangues. The use of x-ray transmission sensor showed the possibility to increase the %Fe from about 63% to above 68% for particles below 80mm and 45mm, after the removal of low density particles. The presence of fines on the feed affected the performance of the SBS X-rays transmission machine, especially for the fine fraction feed. The mineralogical determination, carried out to know the association between hematite and gangue minerals, and the density of the particles on the feed, can be used to preview the quality of products of the x-transmission sorting process.

Oct 3, 2019

By Johan Richaud

Achieving high surface quality steel in the continuous casting process requires optimal mould level control. The design of the casting channel from the tundish to the mould is crucial to prevent formation of undesired instabilities or biased flows that can cause level fluctuation. With the aid of CFD and with physical water models, the geometry of the stopper nose and the nozzle seat have been studied and optimized to improve the overall mould flow stability. A special stopper nose; Ripple Stopper (RST), has been developed that reduces the formation of large and unwanted eddies in the liquid steel that destabilize the port exiting jets. Instead, the RST produces a fast release of turbulence in the form of a large number of small eddies. The large sudden fluctuations in the mould level are reduced, which in turn reduces the occurrence of surface defects. An additional benefit is derived from the local pressure around the stopper nose region being greater which reduces the refractory erosion. For a tundish gate type flow regulation, a new design encompasses an offset in the Tundish Well Nozzle (TWN) that realigns the flow and reduces the bias flow that is common to tundish gate regulation. The steel recirculation regions below the throttling gate are decreased reducing the risk of oxide depositions. The RST and the Offset bore casting channel have been applied successfully leading to a superior flow control performance between the tundish and the mould.

Jul 30, 2018

By Priscilla Pessin Coppo

The prevention of dental enamel wear has particular relevance for preventive and restorative purposes in dentistry. The wear damage can increase due to salivary disorders and/or parafunction (bruxism); antagonists incisal surfaces become flat and coincident. This study aims to investigate the wear behavior and the related mechanisms in sliding pairs of conformal incisal enamel, with similar values of hardness and fracture toughness, with different applied normal loads and lubricated conditions. Bovine incisors, under pin on flat configuration, were tested in two lubrication condition (dry or with natural saliva) and two applied normal loads (8 and 16 N). The worn surfaces were investigated by 3D profilometry and SEM. The analysis of worn surfaces indicated mechanisms of brittle fracture, but with different severities. Under a normal load of 16 N and dry condition, wear is controlled by a brittle process: microcracking with flake-like wear particles, which results in high friction coefficient (> 0.85), wear rate and wear volume. On the other hand, under a normal load of 8 N and natural saliva, wear took place in the interprismatic region, with consequent exposure of prisms and fracture in localized regions. In this case, the friction coefficient was 16% lower and the wear volume was one order of magnitude lower. Under 8 N and natural saliva, the wear was greater than in the dry condition, probably due to tribochemical reactions.

Jul 31, 2018

By Carlos Alexandre Gonçalves de Moura

O trabalho se baseia na redução do retorno parcial de aço por temperatura na Aciaria LD com foco em análise estatísticas do processo, melhorias no projeto alinhado ao plano de manutenção dos componentes mecânicos e elétricos do sistema de aquecimento de panelas. Para análise do problema foi elaborado um estudo utilizando Lean Six Sigma através do DMAIC, analisando as condições de processo, procedimento operacional e plano de manutenção dos equipamentos. Como resultado do trabalho obteve-se uma redução em 58% no retorno parcial em panelas de aquecedor.

Jul 30, 2018

By Danilo Gonçalves de Oliveira

A linha de Decapagem e Laminação a Frio da ArcelorMIttal Vega vem recebendo constantes investimentos para aumento da sua capacidade produtiva sendo o mais recente a instalação do quarto tanque de decapagem química realizada em março de 2015. Para que esse investimento trouxesse o resultado esperado, eram esperadas melhorias de desempenho no processo de Laminação a Frio. O presente trabalho expõe a metodologia empregada para identificar os projetos necessários e os expressivos resultados obtidos com a sua condução ao longo do ano de 2014.

Aug 16, 2017

By Cláudio S. S. Pinto

Em face do agravamento da situação da energia elétrica no Brasil, com disponibilidade cada vez mais restrita e custo cada vez maior, torna-se urgente reduzir o seu consumo onde possível. Ventiladores centrífugos de processo de médio e grande porte são grandes consumidores de energia elétrica e podem ter um elevado potencial para a redução do seu consumo. Este texto mostra como identificar a possibilidade de economizar o uso da energia elétrica em um determinado ventilador e que modificações ele necessita para cumprir este objetivo.

Sep 25, 2017

By Benito Barbabela Silva, Michel Garant, Mathieu Dubé

Pellets market challenging scenario has stimulated pelletizing experts to pursue innovative alternatives to process development in order to increase pellets competitiveness vis-à-vis sinter. When it comes to indurating process, pelletizing productivity is still limited and its OPEX inflated by the lower input of carbon into mixes due to quality impairment caused by magnetite formation in pellets core. This obstacle led to the rethinking of carbon distribution strategy within the green balls. To achieve such purposes, COREM through its precompetitive research program dedicated to its members, has proposed the layered pellets®, a two-stage balling technology. Balling in disc and pot-grate tests in COREM’s pilot plant were carried out to proof the concept, support the arising technology and evaluate its potential. According to first results, while CCS strongly improved, tumble and abrasion indexes as well dynamic LTD must be further investigated. Tests on four classes of equivalent carbon content pellets to evaluate layering strategy gave very good perspectives concerning the increase of productivity, and the reduction of fuel consumption and GHG emissions.

Oct 1, 2019

By Mayworm Luiz, Mantovanelli Mauro, Merisio Everaldo, Oliveira Edgar Adrian, Vieira Estéfano Aparecido, Kaneda Kazuyuki

Os filtros da estação de tratamento de água do circuito spray da planta de lingotamento contínuo apresentam problemas de desempenho quanto a vazão, gerando perda de produtividade do processo de produção de placas da ArcelorMittal Tubarão. Na etapa de filtração da água de recirculação utilizada no circuito de spray, ocorre redução da vazão com o tempo de operação não atendo a necessidade do processo. Existe uma divergência de especificação de projeto uma vez que o projeto original visa tratamento de água potável e não água do sistema direto de lingotamento, uma água com alta concentração de sólidos em suspenção e óleos&graxas. Para recuperar a vazão da água filtrada, é necessário aumentar a frequência de contra lavagem, melhorando a passagem da água e limpando os leitos, porém a alta frequência de contra lavagem torna-se uma complicação para operação da ETA, não garantindo a estabilidade da operação. O objetivo deste trabalho foi identificar e propor soluções para os problemas de vazão dos filtros de forma a garantir a especificação nominal de projeto (1380 m³/h / 5 filtros) e consequente estabilidade operacional do sistema. Foram feitas avaliações em laboratório para identificar a composição ideal do leito filtrante assim como sua distribuição granulométrica, além de modificações internas do filtro e das crepinas utilizadas no sistema de contra lavagem. Após as modificações, o filtro está operando por quase um ano conforme especificação, garantindo a vazão de filtração e prolongando o tempo de contra lavagem de 6/6 horas para 15/15 horas.

Oct 1, 2019

By Marcos Paulo Kohler Caldas

O desenvolvendo da indústria de eletroeletrônicos associada ao barateamento dos produtos tem reduzido a vida útil de equipamentos levando a uma geração elevada de resíduos de equipamentos eletroeletrônicos (REEE). Um componente desse resíduo são as placas de circuito impresso, que possuem em sua composição altos teores de metais, que podem ser recuperados através de processos de reciclagem. O presente trabalho busca caracterizar placas mãe de computador, determinando sua quantidade de material orgânico, cerâmico e metálico. As placas foram direcionadas para cominuição, que foi realizada em moinho de facas com grelha de 9mm, seguida por um moinho de martelos, atingindo uma granulometria menor que 2mm. A amostra foi então quarteada, para uma maior homogeneização e passou por ensaio de digestão em água régia. O licor resultante foi diluído para determinação do teor dos metais Ag, Al, Au, Ba, Ca, Cu, Fe, Ni, Pb, Sn, e Zn utilizando espectrometria de emissão óptica por indução de plasma (ICP-OES). O sólido filtrado, também resultante da digestão em água régia, passou por um ensaio de perda ao fogo a 800°C por uma hora, para determinar o teor de material orgânico. Os resultados indicaram que o Cu é o metal de maior concentração com 22,5% na placa de circuito impresso e que a mesma possui 43,7% de metais, 31,9% de polímeros e 24,4% de cerâmicas. A prata representa 0,04% dos metais e sua obtenção será realizada na forma de nanopartículas a partir de rotas hidrometalúrgicas.

Aug 8, 2018

By Johanna Alegría-Ortega

Cr/CrN bilayer coating was deposited on AISI 440C by Cathodic Arc. The composition and structure of the Cr/CrN coating were investigated by scanning Electron Microscope, X-Ray Diffraction and X-ray Photoelectron Spectroscopy. The results show that crystal structure obtained was CrN phase with preferred [220] orientation. The hardness and adhesion of coating also were studied. The evaluation of erosion-corrosion (EC) on 440C bare and coated with Cr/CrN was performed by carrying out wear tests using a slurry jet with impingement angle 90° at 4 and 8 m/s. Corrosion, erosion and synergism wear rate were evaluated following the procedure described in ASTM G-119-09. This study presents that the synergism wear rate exceeds 40% of the total mass loss for coating and 60% of mass loss for the 440C, being the most aggressive wear component. The increase in impact velocity generated a rise in mass loss for both 440C bare and coated. The Cr/CrN coating offers better corrosion and erosion–corrosion resistance under all the tested conditions.

Aug 8, 2018

By Stefan Wahlund, Tom Adams, Mats Söder, Zhi Zhang

By applying high-end rolls with utmost performance and superior surface quality, hot strip mills can be further optimized. Operations in the mill have been also waiting for improved roll solutions that can minimize required roll changes which impact production efficiency. Limitations are usually due to the low performance and surface degradation of the rolls in the late finishing stands (F5 – F7). VICTURATM is the most recent developed grade for rolls utilized in the late finishing stand at Union Electric Åkers (UEÅ). These rolls have been tested and applied in mills all over the world. A significant improvement over the enhanced ICDP rolls has been observed. Hot strip mills are realizing improved operating efficiency and Total Cost of Ownership (TCO) through the transition of their entire roll inventories to these break-through products.

Oct 1, 2019

By Sander Mul, Michael Brandner, Armin Paar

Graphitic HSS roll grades such as ESW’s brand VANIMO can be considered as the latest developments for the last finishing stands in hot strip mills. These roll grades are developed on the basis of the alloying concept of (Carbide Enhanced) Indefinite Chill work roll materials. During the development of VANIMO, the amounts and types of carbide forming elements were increased and adjusted into the direction of cast HSS roll grades. The microstructure of graphitic HSS roll grades therefore consists of tempered martensite, cementite and several different carbide types as well as a well-defined amount of free graphite. The main purpose of graphitic HSS roll grades is to combine the high surface quality of Indefinite Chill alloys as well as the high wear resistance of HSS roll grades. Several systematic steps were taken to increase the wear performance from Carbide-Enhanced Indefinite Chill grades to the more advanced VANIC grade and further on to the highest alloyed roll grade VANIMO. In every development step, the surface quality of the roll grades was carefully monitored. The decision to invest in new testing equipment at ESW’s plant was driven by the wish to see microstructural effects of different alloys in a macroscopic dimension. Usually samples are taken from cast rolls and investigation is done in comparably small areas compared to the total surface of a roll. Rolling of strip is done with the entire barrel, so effects of alloy and microstructure can appear anywhere on the barrel surface. To ensure better understanding and deeper knowledge about influences of alloying trials we decided to install the last version of LRI (Lismar Roll Inspection). LRI includes the latest technology of Eddy Current with an enormous resolution. Depending on the formation of carbide precipitations, carbide network as well as matrix and free graphite, the EC test can detect smallest differences. The possibility to analyze the different results of EC and UT surface wave inspection will be discussed. A few examples of surface effects in the mill application will be discussed and improvement strategies explained.

Oct 1, 2019

By Hui-bin Wu, Rui Yuan, Yang Gu, Peng-cheng Zhang, Zheng-zhi Zhao

The corrosion behavior of three kinds of medium-Cr rolled steel pipeline steels in carbon dioxide collecting and transporting environment at different temperatures was studied. The results shew that the 5Cr sample was most affected by temperature. When the temperature rised from 30 °C to 90 °C, the corrosion rate increased from 0.12 mm/a to 1.87 mm/a, which was increased 15.6 times. The corrosion rate of 7Cr steel at 30 °C was similar to that of 5Cr steel. However, as the temperature increased, the corrosion rate rised slowly, increasing by 2.4 times at 90 °C. The corrosion rate of 9Cr steel was not obvious with temperature, and it was always below 0.06 mm/a. The thickness of the corrosion product film of the three samples gradually increased below 70 °C, and suddenly increased above 70 °C. This was related to the negative temperature coefficient of the solubility of FeCO3, and the thickening of the product film also affected the ion exchange of the cathodic reaction. An increase in the Cr content contributed to grain refinement and increased the proportion of the small-angle grain boundaries. More fine grains mean an increase in the total length of the grain boundaries, which could provide a diffusion channel for the free Cr element; on the other hand, the low-angle grain boundary structure was more orderly, with a lower free volume and lower interface energy. Under the combined effect of both, 9Cr steel and 7Cr steel had high volta potential and better corrosion

Oct 1, 2019

By Nelson SOUTO, Nicolas LEGRAND, Christian COUNHAYE, Don EARLEY

The work is motivated by the automotive customer requirements for a roughness with high peak density (RPc > 75 peaks/cm) on steel sheet surfaces to maintain a good strip surface finish after painting. For that purpose, a new approach is utilized to compute roughness transfer and predict final roughness on uncoated steel sheets (average roughness, skewness, peak density) as a function of temper rolling conditions. The approach is based on the Monte Carlo method combined with the Abott curves and an auto-correlation function to numerically generate roughness profiles for roll and strip respectively. To compute the roughness transfer due to the interaction between roll and strip surfaces during rolling, a composite Abott curve that combines roll and strip Abott curves is used with an asperity crushing model integrated with a rolling model. This enables simulating two roughness transfer mechanisms in the roll bite: the strip asperity crushing mechanism by roll roughness and the strip asperity ploughing mechanism due to roll-strip interfacial sliding speed. The model shows the importance of considering the two mechanisms to predict roughness transfer correctly when strip elongation is high, typically a few percent, and roll bite friction is low. In these conditions, the forward slip at the exit of the roll bite tends to erode strip roughness significantly and decrease considerably the peak density on the strip. For lower elongation levels (~1%) and high roll bite friction, the ploughing mechanism becomes negligible and roughness transfer is controlled by the crushing mechanism only. With these two mechanisms, the model reasonably predicts the evolution of average roughness and peak density over a wide range of temper rolling conditions (new/worn work rolls, hard/soft grades, various elongations), but skewness is more difficult to predict for some trials.

Oct 1, 2019

By Jorge Madias

Se analizan las distintas alternativas para la producción de barras de refuerzo de hormigón: endurecimiento por solución sólida (“dureza natural”); endurecimiento por temple y autorevenido en línea (Tempcore, Thermex, etc.) y endurecimiento por precipitación (microaleación con niobio, vanadio o titanio) y su influencia sobre la performance de las barras, en lo que hace a la resistencia a la corrosión, al fuego y a los sismos.

Aug 17, 2017

By Emanuele Osto

In late 2013, the installation of the world's first application of a break-through technology for rail hardening was started at Baogang Iron & Steel (Group) Co. Ltd. in Inner Mongolia, China, one of world's leading rail producers. The "Injector Dualphase Rail Hardening" (idRHa+) system was developed by Primetals Technologies and Centro Sviluppo Materiali S.p.A. (RINA-CSM) a Technical Center headquartered in Rome, Italy. Baogang was a key partner, providing its large expertise of premiumrail producer, including its experience with existing offline technologies. With a design based on thermal, mechanical and metallurgical models, idRHa+ can apply customized cooling protocols, so to obtain the desired microstructure and hardness distribution across the rail head, with a high degree of accurateness and operation flexibility. idRHa+ can be installed in inline or offline configurations. During 2014, the system was successfully commissioned at rail mill #2 in the city of Baotou, Inner Mongolia, and entered the regular commercial production. This paper gives an overview of the key concepts behind idRHa+'s design, the progression of its commissioning and testing till the ramp-up to consistent industrial operation. Derived from idRHa+ research and experience, other water-cooling technologies are available for different applications such as: quenching & tempering of medium-large sections, control of distorsion of merchant bars, quenching of stainless grades for improving the resistance to corrosion.

Aug 16, 2017

By Marcos Paulo da Silveira, Carolina Conter Elgert, Messias Prado de Almeida, Rafael Stella Galdino

Microalloyed steels have been intensely studied as an alternative to increase strength by grain refinement and/or precipitation hardening. Long steel products have a wide range of opportunities to apply well-defined principles of controlled rolling (CR) in order to increase strength and toughness with reduced costs. To evaluate the effect of microalloying elements as Nb and Ti with thermomechanical treatment, three conditions were tested: DIN 16MnCrS5 with hot rolling (HR), DIN 16MnCrS5 with Nb and CR and DIN 16MnCrS5 with Nb+Ti and CR. Austenitic grain size, obtained by direct quenching after rolling, has shown a decrease 32% with Nb addition, and 29% when Nb and Ti was added. Controlled rolling generated higher grain refinement and pancacked grains near the surface. When comparing ferritic grain size, controlled rolling plus niobium and titanium additions resulted in significant reduction of 35%. Yield strength increased 15% with microalloying and CR and more than 270% in impact toughness, even at -40°C.

Oct 1, 2019

By Sidmar Aparecido Ceresani

O presente estudo tem como objetivo demonstrar a cinética de recristalização e o amolecimento da liga C272000 processada na laminação a frio com uma deformação de 75%. Para determinar o modelo cinético Johnson, Mehl e Kolmogorov (JMAK) foi adotado a temperatura de 450° entre 5min. a 50min. Restaurando totalmente a microestrutura deformada plasticamente sendo progressiva a elevação do tempo e da temperatura. A caracterização microestrutural das amostras foi utilizado microscopia óptica e metalografia. Conclui-se que o modelo JMAK satisfaz a forma de nucleação da recristalização da liga C272000.

Oct 30, 2017

By Alberto Eloy Anduze Nogueira

O lixo orgânico doméstico gera um problema de eliminação crescente, exigindo sistemas de processamento dispendiosos. É necessário encontrar novas aplicações para estes resíduos; uma poderia ser como matéria prima metalúrgica. Neste trabalho é estudado o desenvolvimento de pelotas auto-redutoras usando a pirólise de resíduos orgânicos, onde é gerado carbono e voláteis condensáveis e não condensáveis. O alcatrão resultante foi misturado com minério de ferro, pó de carvão e fluxante (CaO), para produzir as pelotas. O carvão fluidizado cria uma forte aderência dos elementos, mostrando uma boa viabilidade do presente processo.

Aug 16, 2017