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Utilizing a very large database from a mined-out area on a South African gold mine, the relative efficacy of a method to mitigate the smoothing effect introduced by the algorithmic constraints imposed by kriging was investigated. Smoothing effects arising from limited data availability are differentiated from the smoothing arising from the application of estimation algorithms. Very little can be done to ameliorate smoothing of estimates because of too little data, barring additional drilling or sampling. However, the smoothing effects resulting from the kriging process are shown to be mitigated by use of an alternative algorithm. The primary criterion in the development of the new algorithm was to avoid re-introducing conditional bias. This paper examines firstly the smoothing effects introduced into estimates via the kriging covariance matrix, secondly the process for ameliorating the smoothing effect, and finally it uses a case study to demonstrate the effectiveness of the new algorithm on a very large database. The database was used to introduce a 60 m by 60 m drilling pattern which in turn was used to model the semi-variogram and produce 30 m by 30 m kriged block estimates. The follow-up database was then re-introduced (roughly 5 m by 5 m grid spacing) and averaged into 30 m by 30 m blocks to provide a direct comparison with the initial estimates. In this way the extent of smoothing and accuracy of the estimates before and after the corrections was tested.

Jan 1, 2014

J. L. CHRISTIE, Chairman T. S. FULLER, Past-chairman W. M. PEIRCE, Vice-chairman W. A. SCHEUCH, Vice-chairman E. M. WISE, Secretary International Nickel Co., Bayonne, N. J. W. M. CORSE, Treasurer Executive Committee H. A. BEDWORTH G. O. HIERS D. K. CRAMPTON R. H. LEACH E. H. DIX, JR. R. F. MEHL J. A. GANN J. WALTER SCOTT' JEROME STRAUSS Finance Committee T. S. FULLER, Chairman W. M. CORSE H. S. RAWDON C. H. MATHEWSON SAM TOUR

Jan 1, 1934

By J. S. Lee, R. K. Massarsch

"A 3.2 km long immersed road tunnel forms part of the Busan-Geoje Fixed Link in South Korea, which connects Korea's second largest city Busan, with the island of Geoje. To ensure the water tightness of the joints of the segmental tunnel structure and to limit the forces in the shear keys, the differential settlements have to be limited. This was achieved by extensive soil improvement of the marine clay below the tunnel with cement deep mixing (CDM) and sand compaction piles (SCP). This paper focuses on the characteristics of the marine clay, the basic design principles, layout and constructional issues of the CDM soil improvement, and numerical and numerical analyses to predict settlement and stability.INTRODUCTIONThe Busan-Geoje Fixed Link consists of two short cut & cover tunnel access ramps, a 3.2 km long immersed tunnel (Figure 1) and two long span cable stayed bridges. The tunnel consists of eighteen concrete elements each of 180 m length having a rectangular cross section of 26.5 m in width and 10 m in height. The tunnel elements are cast in a dry dock on shore and floated out to the sea, immersed in their final positions on a gravel bed in pre-excavated trench and connected to each other by a dual gasket system. The water depth was up to 50 m making the tunnel of the deepest yet constructed. After immersion, the tunnel is protected by backfill material at the sides and rock armour on top. Each tunnel element consists of eight 22.5 m long segments. The joints between the segments and between the tunnel elements are equipped with EDPM water stops, Omega seals and concrete shear keys. The longitudinal displacement behaviour of the segmental tunnel structure in the varying ground conditions represents a complex soil-structure interaction problem which has been modelled with a FEM structural model representing the tunnel, the joints and with springs to represent the soil that are derived from the PLAXIS soil/foundation models. In order to ensure the water tightness of the joints which have limited opening capacity and to limit the forces in the shear keys, differential longitudinal settlements have to be limited. This is achieved by limiting the variations in subgrade modulus along the alignment and it in practice means that differential settlements are limited to a few tens of millimetres. Without soil improvement of the marine clay below the tunnel, long-term tunnel settlements of up to 400 mm were predicted when taking into account the likely variations in the trench profile, backfilling and uncertainties in the soil properties. Such large total settlements led to large variations in the sub-grade reaction along the alignment, which in turn resulted in significant differential settlements, unacceptable joint opening and large shear key loading. It was therefore decided to carry out extensive soil improvement with cement deep mixing (CDM) (CDIT, 1999) and sand compaction piles (SCP) (Kitazume, 2005) after studying a number of foundation alternatives."

Jan 1, 2015

By Bo Kyung Sim, Dae Young Kim, Jae Won Lee, Ebrahim Farrokh

"The contract C931 of the downtown line 3 (DTL3) mass rapid transit system of Singapore includes half a kilometer twin tunnels running between Mattar and Macpherson stations. An EPB TBM of 6.6 m diameter was used to excavate both of these tunnels. The tunnels pass predominantly through a very stiff silty/clayey fine to coarse sand from the Old Alluvium Formation. In this paper, TBM selection procedure, TBM performance evaluation, and some of the tunneling operation challenges with the TBM in the Old Alluvium Formation are discussed. In this regard, soil conditioning trial tests were performed to resolve the clogging issue and low TBM performance. Thorough TBM operational data analysis was performed to detect high soil abrasivity, backfill grout leakage, and foam nozzle clogging. The results of some of the applied modifications are also discussed to show their effects on the TBM performance improvement. Finally, some of the challenging TBM design specifications are also discussed. INTRODUCTION Tunneling and underground construction in Singapore has been increased in the last 30 years due to the demand for public transportation systems and the limited space above the ground for the infrastructure development. Downtown Line Stage 3 (DTL3) Mass Rapid Transit (MRT) system has 21 km total route length and consists of 16 stations. DTL3 Contract C931 runs between Mattar station and MacPherson station. The construction works in this contract include twin bored tunnels of 6.6 m diameter and 450 m length and a TBM launch shaft of nearly 30 m depth. The tunnels run in urban area below Kallang Paya Lebar Expressway tunnel (KPE), Kallang River Canal, and Circuit Link. Figure 1 shows the alignment of the tunnels in between two subway stations. The tunnels were excavated by an earth pressure balance (EPB) tunnel boring machine (TBM) through the Old Alluvium (OA) formation, a challenging geological formation in the sense of its abrasivity and stiffness. The Old Alluvium Formation mostly includes stiff to very stiff clayey and silty sand. The soil is un-weathered cemented to semi-cemented dense, mainly with a low permeability coefficient of 10-7 m/s and high SPT values (almost 100). The soil is classified as “very high abrasive” according to NTNU SAT test classification (SAT value of 15 to 42). The construction of the first tunnel drive was slowed down due to a number of factors related to soil conditioning and TBM operation. In this regard, a thorough analysis of the TBM operational parameters from the excavated sections was performed to identify the problems in time to prevent unwanted construction delays in the subsequent sections. In the following sections, a brief overview of the criteria used for TBM selection is presented at first. Then, the results from the analyses and tests performed to assess soil conditioning, grout leakage, and soil abrasion are presented. The last section discusses some of the tunneling design features that challenged the TBM operation in this project."

Jan 1, 2016

By J. Noll, E. Cauda, T. Barone, S. Vanderslice

Measuring diesel particulate matter (DPM) for underground metal/nonmetal mine compliance samples is done by collecting DPM onto quartz fiber filters and analyzing the samples via NIOSH method 5040 for elemental carbon (EC) and total carbon (TC). As part of the sampling train, two quartz fiber filters in tandem are housed inside an SKC DPM cassette that includes an impactor. The impactor segregates DPM and mine dust, and the second filter is used to correct for adsorption of vapor phase organic carbon (OC). Since the value of the second filter is subtracted from the first, the pre-existing carbon on the filter media for both filters needs to be comparable. In addition, the pre-existing carbon on the media should be low for accurate and sensitive results. However, there have been some reports of elevated OC on the filter media of the SKC DPM cassettes, which would cause the limit of detection (LOD) to be higher than reported at times. In this study, blank SKC DPM cassettes from different batches and with different expiration dates were analyzed to quantify the amount of carbon on the filter media and to determine the LOD and limit of quantification (LOQ) associated with these samplers. It was found that the organic carbon and total carbon on the media was about five times higher than quartz media used in samplers from other studies. The average TC on the blanks was 2.57 μg/cm2 with a standard deviation of 0.70, resulting in a LOD of 21 μg/m3 TC, 8-hr Time Weighted Average (TWA), and LOQ of 69 μg/m3 TC, 8-hr TWA, when using these samplers for collecting DPM. The LOD and LOQ may be improved through some sample preparation techniques. INTRODUCTION Exposure to diesel exhaust (DE) is associated with an increased risk for lung cancer and other adverse health effects (Attfield et al. 2012, Silverman et al. 2012, Ping and Guang 2017, IARC 2012). Pronk et al. 2009 reported that the highest exposed groups to elemental carbon (EC) from DE worked in underground sites in mining and construction and they were exposed to concentrations between 27–658 μg/m3. At concentrations (1–25 μg/m3 EC) well below those observed in mining, diesel particulate matter (DPM) exposures were estimated to increase the risk of cancer by levels exceeding those typically acceptable for occupational risk in the United States and Europe (Vermeulen et al. 2014). This suggests that underground miners are especially at risk because of their more substantial exposures in confined working spaces. As a protective measure, in 2001, the Mine Safety and Health Administration (MSHA) promulgated a rule to limit exposures of metal/nonmetal underground miners to DPM to an 8-hr time-weighted average (TWA) of 160 μg/m3 total carbon (TC) (MSHA 2001, 2006).

Jan 1, 2019

By W. H. Pomroy

In its 2001 diesel particulate matter (DPM) rule for metal and nonmetal underground mines, MSHA established an interim concentration limit of 400 micrograms of total carbon (TC) per cubic meter of air (400TCµg/m3), and a final concentration limit of 160TCµg/m3, to be phased in over five years. Following a court challenge to the 2001 rule, MSHA, industry and organized labor reached a partial settlement of the litigation under which the agency agreed to issue a proposal to amend the 2001 rule by, among other things, changing the surrogate from TC to elemental carbon (EC), applying MSHA's traditional hierarchy of controls, and revising requirements for one-year special extensions for complying with the final DPM exposure limit. MSHA issued a final rule in 2005 converting the interim concentration limit from 400TCµg/m3 to 308 micrograms of EC per cubic meter of air (308ECµg/m3) based on a miner?s personal exposure. Pending further rulemaking, MSHA retained the final concentration limit of 160TCµg/m3. In May 2006, MSHA issued a final rule that clarified that the final limit of 160TCµg/m3 would be based on a miner?s personal exposure rather than as a concentration limit. The 2006 rule also phased in the final DPM limit in three steps over two years, beginning in May 2006 at 308ECµg/m3, followed eight months later in January 2007 with a limit of 350TCµg/m3, and finally reaching 160TCµg/m3 in May 2008. Also in the 2006 rule, MSHA committed to converting the 160TCµg/m3 limit to an EC limit in future rulemaking. This paper reviews the DPM exposure limits in the context of the MSHA rulemakings and discusses the DPM engineering controls that were utilized by mine operators to attain compliance with each progressively lower limit.

Jan 1, 2009

By Hidekatsu Takeuchi, Masaru Sakakibara, Shigeo Tanabe, Kenji Harada, Akihiko Suzuki, Shoji Morihana

"Deep mixing (DM) method, one of the most commonly used solidification methods, is based on the principle of solidifying soft ground. It can be classified into two categories such as Cement Deep Mixing (CDM) method and Dry Jet Mixing (DJM) method which apply hardening agent in slurry condition and in powdery condition respectively. In recent years, DM methods have undergone changes that have evolved them from the traditional method to meet the needs of the diversifying market. Among them, the Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method is a DM method which mixes a cement-type hardening agent in slurry condition mechanically with soils in situ and incorporates the innovative technique, “atomized ejection” that has been developed to allow faster installation of larger diameter columns without sacrificing quality compared with conventional methods. At this technique, the atomized hardening agent is discharged together with compressed air through a device incorporated into the mixing blade. It also has advantages of performing the works with low-displacement of the surrounding soils in consideration of environmental friendliness and with higher penetration capability against hard ground.This paper presents the technological outline of the above-mentioned CI-CMC method, focusing on the atomized-ejection technique, followed by some construction examples, applied to the self-earth-retaining wall, to the hard ground and the area adjacent to the existing structures.INTRODUCTIONAccording to the accumulation of its case histories, Deep Mixing method has been receiving the demands of its application to more challenging conditions, such as harder ground condition, and requirement of lower displacement of the surrounding ground during its operation. In addition, to match its price against the other cheaper methods and widely receive its benefit of higher quality, the cost reduction of Deep Mixing is also one of the major challenges. For the cost reduction, higher productivity and lower consumption of the material to obtain the equivalent strength and homogeneity with the conventional method are required.The Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method has been developed to meet these demands. CI-CMC incorporates the mist ejection that has been developed to achieve faster installation of larger diameter columns without sacrificing quality compared with the existing methods. Normally, we obtain cement columns of about 1.0 m in diameter by using Deep Mixing method. To increase the productivity, it is not preferable to drastically increase the penetration and withdrawal speed of the mixing blades because of the hardness of the ground and restriction by minimum number of passage of rotating blades per a certain height of the soil cement. Instead, the expansion of diameter of the columns will simply increase the productivity. The development of the new mist ejection system, as shown in Photo 1, has enabled the diameter of soil cement columns to 2.0 m on single axis while 1.6 m on double axes. Mist ejection means that the hardening agent slurry is sprayed into the ground in mist form together with compressed air thereby achieving homogeneous mixing and reducing the resistance on rotating blades."

Jan 1, 2015

By R. K. Mehta, S. K. Dhar, R. R. Mallepali

Introduction The incentives for developing a distributed form of the comminution model include: • for describing the heterogeneous comminution behavior of multiphase mineral systems (i.e. realistic ore bodies, such as complex sulfide ores consisting of chalcopyrite, galena, sphalerite, pyrite and siliceous minerals) and •for generating, for various locked and free particles, in situ, microscopic, breakage behavior such as the mode of fracture (intergranular vs. transgranular), the relative rates of breakage and the breakage distribution. However, the computational difficulty and the effort made in estimating a large number of parameters (Andrews and Mika, 1975; Wiegel, 1976; Herbst et al., 1985, 1988) do not justify the utility of this approach. Also, obtaining the results experimentally is very tedious and time consuming if using this approach. Although recent work in this area (Choi, Adel and Yoon, 1987; Mehta, Adel and Yoon, 1989, 1990) showed good results for liberated particles, the quality of the estimation and prediction was poor for locked particles. Attributing this to the complex breakage behavior of locked particles, it was concluded that additional constraints, and possibly modification in the breakage distribution functional form for locked particles, were necessary. However, further mathematical analysis revealed that the method previously used was in error. The purpose of this technical note is to present the correct solution methodology used in solving the general model equations of a multicomponent mineral system containing multiple classes of locked particles. Previous work and connection The general form of the comprehensive, distributed-component comminution model has been described as (Herbst et al., 1985) [d (m (0) -[ I - B ] S_ m(t) = A m(t) (1)] where [A] is the fundamental matrix/state companion matrix, commonly referred to, in the comminution literature, as the "mill matrix." Note that for a distributed-component comminution model, this is a full, general, real matrix, unlike a lower triangular matrix for a simple grinding model or a lumped-binary grinding model with one locked-particle class (Herbst et al., 1985, 1988). Also note that all of the underlined letters refer to matrices. Herbst et al. addressed the difficulty in arriving at a closed form of the analytical solution of Eq. (1) via similarity transformation [IT J inv (T)]]. This difficulty occurs for several reasons: •[A], as a general real matrix, may have complex eigenvalues and complex eigenvectors. •More importantly, there is no guarantee that a set of eigenvectors of [A] will turn out to be independent. An attempt was made to solve this problem by implementing a decomposition method. With this technique, the mill matrix was decomposed into a sum of lower and upper triangular matrices [(i.e., A = L + U)]. Then the solution was obtained using similarity transformation (Mehta, Adel and Yoon, 1989, 1990). [e(At) = e(L+U)t = e(Lt).e(Ut) _ [ TL Jt- (t) inv(T_L)] [-Tu Ju (t) inv(Tu)]] [But, unfortunately, e 1+U = e t . eu is true only for scalars and not for matrices (i.e., eL+u# eL- eU) unless they commute. In other words. eAt = e(L+u)t= ekt - eU' if LU = UL. Hence, this decomposition scheme must be replaced by a mathematically acceptable method known as the "splitting method"]

Jan 1, 1994

By J. P. Rider, T. W. Beck, J. A. Organiscak

"The National Institute for Occupational Safety and Health (NIOSH), Office of Mine Safety and Health Research (OMSHR) has recently developed a series of models utilizing Computational Fluid Dynamics (CFD) to study gas distribution around a continuous mining machine with various fan-powered flooded bed scrubber discharge configurations. CFD models utilizing Species Transport Model without reactions in FLUENT were constructed to evaluate the redirection of scrubber discharge toward the mining face rather than behind the return curtain. The following scenarios are considered in this study: 100% of the discharge redirected back towards the face on the off-curtain side of the continuous miner; 100% of the discharge redirected back towards the face, but divided equally to both sides of the machine; and 15% of the discharge redirected toward the face on the off-curtain side of the machine, with 85% directed into the return. These models were compared to a model with a conventional scrubber discharge where air is directed away from the face into the return. The CFD models were calibrated and validated based on experimental data and accurately predicted sulfur hexafluoride (SF6) gas levels at four gas monitoring locations. One additional prediction model was simulated to consider a different scrubber discharge angle for the 100% redirected, equally divided case. These models identified relatively high gassy areas around the continuous miner which may not warrant their use in coal mines with medium to high methane liberation rates. This paper describes the methodology used to develop the CFD models, and the validation of the models based on experimental data.INTRODUCTION Methane gas and respirable dust are two hazards frequently encountered at continuous miner (CM) operations. An accumulation of both methane gas and coal dust may lead to massive explosions underground [1], and overexposure to respirable coal dust can result in pneumoconiosis (commonly referred to as “Black Lung Disease”) in coal workers [2]. Current U.S. federal coal mine regulations limit concentrations of methane gas to below 1% at the face area and require exposures to respirable coal dust to be at or less than 2.0 mg/m3 for an 8 h shift average. Begin on August 1, 2016; the overall respirable dust standard in coal mines is reduced from 2.0 to 1.5 mg/m3 for full shift sampling. If the quartz content of the dust exceeds 5% by weight, the dust standard becomes more stringent, reducing the allowable concentration to the value of 10 divided by the % quartz."

Jan 1, 2015

By A. J. Sinclair, N. Champigny

"The Cinola gold deposit in the northern Queen Charlotte Islands, British Columbia, is in a clastic sequence consisting of a lower shale of the Late Cretaceous Haida Formation and an overlying interbedded sequence of pebble conglomerate and coarse-grained sandstone of the Middle Miocene Skonun Formation. Both formations are intruded by a stock and dykes of porphyritic rhyolite. Two K-Ar model ages indicate mineralization and probably porphyritic-rhyolite intrusion at about 14 Ma (middle Miocene). A splay of the Sandspit fault system constitutes the footwall on the west of the deposit.The Cinola deposit can be classed as Carlin-type based on features such as (1) small particle size for gold, (2) Tertiary age of mineralization, (3) element abundances (e.g. high Hg), (4) dominantly argillic alteration, (5) a structural setting associated with major faults, (6) porosity of the host rock and (7) spatial and possibly genetic association with felsic intrusions. Gold is widespread and occurs mainly as grains of< 0.5 11-m in silicified sedimentary rock, and in quartz veins. Locally, coarse > 100 11-m particles of native gold occur in quartz veins, especially in strongly brecciated porphyritic-rhyolite. Ore minerals are mainly pyrite and marcasite, but include small amounts of chalcopyrite, sphalerite, galena, pyrrhotite, cinnabar, tiemannite (HgSe), rutile, magnetite, hematite and limonite in addition to native gold and electrum. No silver minerals have been found; silver was found in gold particles in amounts varying from 6.2 to 24.2 weight per cent. Alteration products are sericite, illite, kaolinite and chlorite, with abundant quartz of several stages.The host rocks, specifically the Skonun Formation, formed as an alluvial plain facies in a braided river system discharging into a marine basin in early Middle Miocene time. During the Middle Miocene, this sequence was intruded by a rhyolitic stock. The highly porous and permeable Miocene clastic sequence apparently provided an optimum setting for the development of a large geothermal system, the energy for which probably derived from the rhyolite stock. Mineral deposition followed a well-defined paragenesis, which, from oldest to youngest, is: (1) precipitation of iron sulphide minerals, and early quartz; (2) several stqges of quartz veins, with deposition of sphalerite succeeded by galena, chalcopyrite and visible gold. Micron-size gold was precipitated throughout these two stages of mineral deposition. Argillitization of the host rocks probably in part coincided with the mineralization and continued during cooling of the geothermal cell.In-situ reserves have been estimated at 41.1 million metric tons averaging 1.85 g Au/tonne using a cutoff grade of0.86 g Au/ tonne."

Jan 1, 1982

By K. S. Raja, M. Misra, S. K. Mohapatra

"Ordered arrays of TiO2 nanotubular photocatalysts were prepared by a simple anodization process. Band gap states of the TiO2 were altered by controlling the anodization electrolyte composition and thermal annealing conditions that resulted in enhanced photo activity. These nanotubes were used for reducing CO2 to methanol either by photochemical or photo electrochemical routes. Pd nano-particle loaded TiO2 nanotubes were employed for photochemical reduction of CO2 to methanol that showed a conversion rate of 12 x 10-3 mol m- 2h-1. Carbon modified TiO2-xCx type nanotubes were used as photo anode and Ti as cathode for photo electrochemical reduction of CO2. The potential of Ti cathode was maintained at -0.5 V SCE. The formation rate of methanol was determined as 13 x 10-3 mol.m-2h-1.1. IntroductionGlobal warming due to emission of carbon dioxide is a serious environmental concern. The atmospheric concentration of CO2 is about 384 ppm by volume and about 3 x 1012 tonnes by weight. Burning of fossil fuels and deforestation are the leading causes for increase in the anthropogenic CO2. More than 32 x 109 tonnes of CO2 are released per year (based on 2006 data) worldwide from the fossil fuel. Pumping CO2 from the fossil fuel power plants into deep ocean basin is one of the most discussed disposal options. The other potential option is converting this green house gas into valuable fuels.Carbon dioxide feed stock can be converted into fuels of solid, liquid or gas phase by chemical, electrolytic, photocatalytic and photo-electrocatalytic methods. Reduction of CO2 to fuel form of any phase requires energy. The reduction process should be energy efficient so that we do not spend more energy and emit more (indirect) CO2 in the process of converting CO2. From this point of view, conversion processes occurring at room temperature look attractive.Electrolytic conversion of CO2 into various forms such as methane1, ethane2, ethylene3, methanol4,5, ethanol6, n-propanol, formic acid7, and formaldehyde has been widely reported. The standard equilibrium potential (at pH: 0) for reduction of CO2 to methanol is 0.14 VSHE and to methane is 0.2 VSHE which is thermodynamically more favorable than hydrogen reduction. However, the gas phase reduction is kinetically complex requiring effective electrocatalyst. The major issues with electrolytic conversion of CO2 to useful products are:"

Jan 1, 2010

"This study examines the problems faced by open pit mine superintendents who make choices about how to direct their materials, either to the waste dump or to the mill. The paper explores the effects of introducing a 10% sampling error and a 0.9-times to 1.1-times sampling bias on positively skewed distributions for precious and base metals, negatively skewed distributions in the case of bulk commodities, and normal distributions as is the case for coal deposits. Parent distributions for each commodity were created on a 25 x 25 m grid using transformations of gold, iron ore, and coal data-sets, spatially based on a nonconditional Gaussian simulation. Ordinary kriging of grades for the three commodities into a 10 x 10 m grid provided the reference case against which the distributions with the sampling error and sampling bias for the commodities were compared. Imposing cut-off grades on the actual-versus-estimated scatterplots of the three commodities allowed the distributions to be classified into components of waste, dilution, ore, and lost ore. Ordinary kriging of values for each deposit type acted as the reference data-set against which the effects and influence of 10% sampling error and 0.9-times to 1.1-times sampling bias are measured in each deposit type. Indications are that the influence of error and bias is not as significant in gold deposits as it is in iron ore and coal deposits, where the introduction of small amounts of error and bias can severely affect the deposit value.IntroductionThe effects of poor sampling and the financial implications for mining companies, traders in mineral assets, and sellers of metal as dore or commodities is documented in a number of studies, the most notable of which is that by Carasco (2004). He examined the financial impact of poor sampling practices in the Chilean copper industry and found that finacial losses due to poor sampling amounted to hundreds of millions of dollars over the life of a mining operation. Holmes (2004) examined the effects of correct sampling and measurement as the foundations of metallurgical balances, and found that revenues from the sales of large iron ore shipments may be profoundly affected by poor sampling practices. In South Africa the way in which sampling of in situ gold-bearing reefs affects the mine call factor has been an ongoing study since the disparity between the estimation of gold in the reef and the actual gold bullion produced was noted by early investigators such as Beringer (1938), Jackson (1946), Sichel (1947), Harrison (1952), and a number of others."

Jan 1, 2017

By Rachel S. Prudhomme, Michael L. Jeremic

"The consolidation of mine backfill by free zing is a concept which has been under study in the mining engineering laboratories at Laurentian University during the past three years. The proposed underground application of freezing involves the artificial freezing of in-situ backfill by means of a refrigerated brine solution which would be circulated through a circuit off freeze pipes. The most interesting findings to date are: (I) The uniaxial compressive strength off frozen fill is considerably higher than that of cemented fill in a ratio of 20:1 (aggregate to cement), and (2) load deformation characteristics of the frozen fill suggest that a higher ice content results in more brittle failure and that samples which have initially failed can still support up 10 one-half the ultimate load without additional failure.Although at this early stage a derailed economic analysis of the procedure has not been possible, a general evaluation of the costs involved suggests that the method could be competitive with the hydraulic placement of cemented backfill. Results obtained from laboratory investigations indicate that the freezing of backfill is a structurally feasible option .IntroductionGround consolidation by freezing is based on the principle of transformation o f water contained in an aggregate-slurry into ice, which act s as a binding agent between the bulk particles, and which results in the transformation of a granular soil into a ""rock -type"" material. The abrasive nature of the particles enhance s the strength o f the ice by providing internal friction. As a result of this internal friction, the chances of plastic flow of the frozen mass when in a loaded condition are reduced(1). T he strength of a frozen aggregate is al so dependent on the grain shape of the aggregate particles which may or may not promote particle interlocking(2) and on the temperature since, below the freezing point of the water/aggregate mixture, the strength of the frozen mass increase s with decreasing temperatures.In the shaft sinking industry, artificial freezing of loose , unconsolidated soils has been in practice for several decades. Shafts for Saskatchewan &apos;s potash industry have been sun k to depths of 3000 feet by employing artificial freezing to stabilize the Blairmore Formation(3). The common procedure for freezing ground for shaft sinking is summarized as follows(4,5): I) 150 mm diameter bore holes spaced on 1.5 m centres are drilled in a circular pattern with a radius of 1.5 m outside the periphery of the proposed shaft."

Jan 1, 1985

Frontino operates three underground lode mines at Segovia in the area of northwest Antioquia, Colombia, which has been an important gold producing district since the late 1800s. Auriferous pyrite, the pre-dominent sulfide, carries very finely disseminated gold. Other minor sulfides are galena, pyrrhotite, and sphalerite in quartz gangue with the host rock being granodiorite. Silver is associated with the galena and also occurs as a sulfo-salt. In 1.973 and 1974, at an annual milling rate of 145,000 mt (160,000 st), average mill heads were 7.80 g per mt (0.23 oz per st) Au; 20.0 g per mt (0.58 oz per st) Ag; and 0.37% Pb; with a production of 1,150 kg (35,700 oz) Au and 4,500 kg (141,000 oz) Ag. Over 300 mt (330 st) of Pb concentrate were shipped. The ore is crushed to minus 16 mm (5 18 in. ) and fed to a rod mill with the discharge passing over a 1.07 m by 1.07 m (42 in. by 42 in. ) jig operating in closed circuit with the underflow from a cyclone in closed circuit with two ball mills. Cyclone overflow is bulk-floated for sulfide recovery from which the tailings are sent to the river as waste with the flotation concentrate joining the jig concentrate for cyanidation. The combined gold bearing concentrates, after cyclone classification, are reground to a very fine mesh in closed circuit with cyclone classification, with the overflow going to the primary thickener. Regrinding, classification, and thickening is done in cyanide solution, and the primary thickener produces a pregnant solution for Merrill -Crowe precipitation. The thickener underflow is the feed to the agitators, thickener, and filter from which the overflow and filtrate are sent to precipitation. The washed filter cake is repulped and floated for the recovery of a galena concentrate for shipment. About 40% of the recovered silver is in this concentrate. In the refinery the precipitate is melted into a dore bullion. This 600 mt (660 st) capacity mill employs several interesting techniques. Gold recovery of 85% to 90% from a complex sulfide denotes good practice. While total power at 42 kwh per mt (46 kwh per st) is high, it would be recognized that the grinding units are small in size and the flowsheet is complicated due to the gold occurring in the sulfide minerals. The extremely low-cost electric power is generated by

Jan 1, 1981

By Gilbert H. Cady

Extensive sampling of coal in Illinois during the past 10 or 12 yegrs by the State Geological Survey, in cooperation with various organizations, such as the U. S. Bureau of Mines, the University of Illinois, and the Illinois Cooperative Mining Investigations, has made possible the delineation of two areas of low-sulfur coal in the southern part of Illinois. The $fur content is less than 1.25 per cent., so that, if otherwise suitable, these coals can be employed for metallurgical uses and for the manufacture of water-gas and retort gas. One of these areas is small and lies in Jackson County, near Murphysboro, the other is much larger and includes a large part of the famous Franklin County field. A small area of No. 2, or Murphysboro, coal has been worked for many years near the town of Murphysboro, Jackson County, Ill. In two mines, at least, the coal has a sulfur content of less than 1.25 per cent. It is doubtful, however, whether this field will ever be a source of large tonnage as the total area underlain by low-sulfur coal in workable thickness is probably less than 15 sq. mi. (24.14 sq. km.), and a large part of it has already been worked out.. The location of the area of low-sulfur coal in the Franklin County field is shown in the accompanying map. The small area underlain by the Murphysboro low-sulfur coal is shown near the town of that name in the central part of Jackson County. The larger area lies in the west side of Franklin County, extending also about 6 mi. (9.65 km.) south into Williamson County, about 4 mi. (6.43 km.) west into northern Jackson and western Perry County, and northward an undetermined distance into Jefferson County. All but the northern limit of the area is fairly well defined by sampling in numerous mines. The inner cross-lined area is underlain by coal having less than 1 per cent. sulfur, the outer boundary surrounding the area underlain by coal having less than 1.25 per cent. sulfur. The coal mined in the district is No. 6 or Herrin coal, commonly known as the Carterville or Franklin County coal. The bed has a thickness varying from about 8 ft. (2.4 m.) on the border of the low-sulfur area up to more than 10 ft. (3 m.) in the central portion, locally having a thick-

Jan 1, 1920

By T. Saburi, C. M. Wayman

The massive and martensitic transformations in ß Cu-Ga alloys were studied by optical microscopy and by transmission electron microscopy and diffraction. These types of transformation are distinct and do not merge into one another. An internal fine structure due to stacking faults was found in both the massive phase (m) and the martensite, but the origin of the faults is believed to be different in each case. The faults in the martensite are due to the lattice invariant or "second" shear of the phenom-enological theory, while those in the are probably growth faults and deformation faults arising from the transformation volume change. Evidence is presented for ordering in the ß phase prior to transformation into martensite, and the crystal structures of and ß&apos; and ßi martensites are discussed. THE results from some previous investigations1,2 have led to the suggestion that martensitic and massive transformations have certain common characteristics. It presently seems established that massive transformations like martensitic transformations are essentially diffusionless,1,2 but unlike martensitic transformations, when a new phase forms massively there is no shape change or surface relief.= If the massive-type transformation is crystallographically similar to martensitic transformations, one would expect a fine structure as a result of the lattice invariant shear4 which is a part of the transformation mechanism. The existence of such a fine structure (i.e., slip, twinning, or faulting), if any, can be verified by transmission electron microscopy, and thus the present investigation was undertaken to compare the internal structure of massively and martensitically formed phases in Cu-Ga alloys which were derived from a parent of the same composition. The transformation characteristics of ß Cu-Ga alloys were also studied. The bcc ß phase in the Cu-Ga system, Fig. 1, is stable above 616oc.&apos; Depending upon the cooling rate, ß Cu-Ga alloys can undergo three different types of phase transformations. The ß phase of eutectoid composition (23.7 at. pct Ga) decomposes into the ? phase (hcp) and the phase (complex cubic) by means of a eutectoid reaction. When the cooling rate is increased so that the decomposition of 0 into [ and ? is suppressed, the ß phase transforms into a nonequilibrium hcp phase, herein denoted ?m by a process of very rapid growth called a "massive" transformation. At even faster quenching rates the massive transformation can be suppressed and the ß transforms martensitically. Massive transformations, apparently similar to those in the Cu-Ga system, have also been studied in the Cu-Zn2,6-8 and Ag-Cd systems.9 Definitive characteristics if the Massive Transformations in 0 Cu-Ga Alloys1 1) The most remarkable feature of the massive transformation in Cu-Ga is that there is no bulk composition change on transformation. According to Massalski,1 the resulting [, phase is a supersaturated extension of the equilibrium [ phase. The lattice parameters continue the trend exhibited

Jan 1, 1965

By C. O. Tarr, G. V. Smith, R. F. Miller

METALLURGISTS have long recognized that the Fe3C type of carbide is not a stable phase in steel and that, given sufficient time, it will decompose with formation of graphite, at least at temperatures below about 2050°F.1 This slow graphitization has never been of much concern to users of hypoeutectoid steels, for in such steels it occurs only during prolonged exposure at elevated temperature. In 1935, Kinzel and Moore2 reported complete graphitization of the carbide of a 0.1 5 per cent carbon steel that had been in senrice for about 26,000 hr. at a temperature of about 1100° to 1200°F. In discussing this paper, both Mathews and Sauveur reported graphitization of slightly hypereutectoid steels. In an extensive investigation of graphitization of high-purity iron-carbon alloys, Wells1 produced graphite at 7o0°C. (1290°F.) in an alloy containing as little as 0.13 per cent carbon, and showed that graphite may precipitate either directly from austenite or from decomposition of Fe3C, also that the rate of graphitization tends to increase with increase of temperature, at least up to a certain point, and with the presence of graphite nuclei. Jenkins, Mellor and Jenkinson,3 studying the structural changes in carbon steels ranging from 0.17 to 1.14 per cent carbon during stress-rupture tests at elevated temperature, obsenred graphite in an aluminum-killed 0.40 per cent carbon steel after fracture in 4340 hr. under a stress of 17,900 lb. per sq. in. at 840°F. and in many of the steels after stress-rupture test at 1200°F. Unstressed samples of 0.60, 0.86 and 1.14 per cent carbon steels graphitized almost completely in 360 hr. at 1200°F., while samples of 0.90 and 1.10 per cent carbon steels were somewhat graphitized, and steels containing 0.24, 0.40 and 0.57 per cent carbon showed no sign of graphite. Their results indicate that graphite precipitates the more readily the higher the carbon content, though this tendency is influenced to some extent by deoxidation practice, and that graphitization is accelerated by plastic deformation. In a recent study of the graphitization of 0.4 and 0.6 per cent carbon steel strip, made by M. A. Hughes,4 it was found that at 1200°F. graphite appeared after 72 hr. in aluminum-killed but not in silicon-killed steel, and that the rate of graphitization was increased by slow cooling from 1600°F. and by cold-working prior to annealing. In creep tests of normalized o. I 5 per cent carbon steel killed with 2.5 lb. of aluminum per ton, at the U. S. Steel Corporation laboratory at Kearny, spheroidization and some graphitization were found after 3000 hr. at 1000°F. under a stress as low as 15m lb. per sq. inch.

Jan 1, 1944

NORTH AMERICA ALASKA Anchorage.-Ames, M. B. Culver, H. W. Fiedler, H. L. Geehan, R. V. Langneas, O. O. Layfield, R. A. Parent, A. Saarela, L. H. Strandberg, H. Candle.-Robbins, J. S. Chichagof.-Russell, J. C. College.-Fox, E. F. Joesting, H. R. Lyman, R. F. Smith, M. C. -Wilcox, H. G. Douglas.-Cahill, W. E. Fairbanks.-Adams, J. M. CANADA Canadian Army Overseas.¬Ball, H. D. Bridges, O. Butterill, H. J. M. Lane, H. C. Millar, W. A.

Jan 1, 1942

By S. R. B. Cooke, W. Philippoff, Donald E. Cadwell

[THE importance of contact angles in flotation has long been recognized, but little has been done to get quantitative relationships between the surface coverage of the mineral by the reagent, the length of the hydrocarbon chain, and the contact angle. It is well known that for a complete monolayer on the surface of a mineral the contact angle ? is determined only by the reagent&apos; and principally by the chain length of the hydrocarbon radical. Although for flotation the monolayer usually is regarded as being complete, early experiments of Wark and Cox2 showed that at very small concentrations of potassium ethyl xanthate the contact angle on galena changed in a continuous way from 0° to the equilibrium value of 60°. Further, Gaudin and Vincent&apos; showed a similar continuity using heptylic acid and sphalerite. This shows that with probably incomplete monolayers, ? varies with the degree of surface coverage. At the time these experiments were made it was impossible to measure the actual amount of surface coverage, especially since the decrease of the collector concentration in the liquor could be influenced by chemical side reactions. Through the use of the radioactive tracer method for the measurement of the amount of collector adsorbed on the surface of the mineral, Gaudin and Bloecher4 were able to determine accurately the actual surface coverage of dodecylamine acetate on quartz, but they did not measure any contact angles. It is believed that the relationship between the surface coverage and the contact angle is extremely important in flotation, especially as Gaudin and Bloecher showed that a 95 pct recovery is possible with a coverage of only 5 pct. Theoretical Considerations The work of adhesion W is the energy bound (in ergs per sq cm) when an interface is formed. It is determined by, the difference of the free surface energies (surface tensions) of the respective phases ?1 and ? 2 before contact and the interfacial free surface energy ?12 after contact. The definition of the contact angle permits the elimination of the unknown surface energy of the solid and hence the calculation5 of W from the surface tension of the liquid ? and the contact angle ?: [W = y (1 + cos ?)[1]] Consider a surface consisting of two components, identified as 2 and 3, 1 being the liquid. The amount of 2 in the composite surface is x, where 0 < x < 1. The respective contact angles with 1 and air are ? and ?3. The total work of adhesion of such a surface is the sum of the values of the components multiplied by their respective areas. A formal relation can be written: [W,,,=x•W2+ (1-x).WR[2] .] in which Wm is the work of adhesion of the composite surface. Eq 1 can be introduced into W2 and W3 but in the case of Wm some discussion is needed. If the two components are segregated, each component forming an integral part of the composite surface there is no physical meaning for a contact angle ?m, calculated from Wm, by using eq 1. If, on the other hand, the area of each patch of the components is small in comparison with, say, the diameter of the bubble used in measuring, it could be expected that ?m would have aphysical significance, because of the action of the surface tension of the liquid-gas interface tending to smooth out sharp corners. How small these patches would have to be is difficult to predict, but by using composite surfaces with microscopically]

Jan 1, 1952

[ARIZONA Established July 10, 1915 CHARLES R. KUZELL, Chairman GILBERT C. DAVIS, First Vice-Chairman ALBERT MENDELSOHN, Second Vice-Chairman MORRIS G. FOWLER, Secretary-Treasurer Phelps Dodge Corporation, Douglas, Ariz. LYLE M. BARKER P. D. I. HONEYMAN A. T. BARR H. M. LAVENDER T. G. CHAPMAN WALTER C. LAWSON GEORGE M. COLVOCORESSES W. H. LOERPABEL EDWIN H. CRABTREE, JR. CARL F. MILLS WALTER I. GARMS P. M. MOSIER WESLEY P. Goss J. A. RICHARDS 11. C. HENRIE JOSEPH A. WILCOX C. F. WILLIS]

Jan 1, 1946