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By B. E. Eakin, A. L. Lee, M. H. Gonzalez

Expeximental viscosity and density data of lour natural gases are presented for temperatures from WO to 340F and pressures from 100 to 8.000 psia. A correlation is also discussed and results reported. INTRODUCTION This investigation is one of several efforts by the authors to provide viscosity data for pure hydrocarbons and mixtures. Results of some pure hydrocarbons and their mix tures have been presented." Several predictive methods and correlations have also been reported.'," This paper presents the experimental viscosity and density data of four natural gases and confirms a correlation in a previous study. APPARATUS The viscometer was described previously. 2,6 A bank of stainless steel pycnometers was included to determine density in conjunction with the viscosity measurements (Fig. I). DATA AND MATERIALS The natural gases were furnished by the Atlantic Richfield Co. (Samples 1 and 21, the Continental Oil Co. (Sample 3) and the Pan American Petroleum Corp. (Sample 4). Table 1 shows the composition of these gases obtained by mass spectrometer analysis. The pure component viscosity data used in the correlation have been published."".'"', '" Experimental and calculated viscosity data for the natural gases are presented in Tables 2 through 5. CORRELATION Starling and Ellington"' have reported several semi-empirical expressions based to a certain extent on the theory of viscosity advanced by Born and Green.' The final expression presented by Starling and Ellingto'n is: i'. (micropoise) -- /t,, exp rX(7') p ..... (I) Eq. 1 was modified by Lee et 01." to represent mixture and pure component data simultaneously. This equation has the form: F = K exp [XpY] :.........(2) where K=- (7.77 i 0.0063M)Ti 122.4 + 12.9M +T .................(3) ' ' ' X= 2.57 + ---1914.5+ 0.0095M .... (4) Y = 1.11 -r 0.04 X ........(5) Over the pressure and temperature range studied in this investigation, this equation represents the data on methane, ethane, propane, n-butane and four methane-n-butane mixtures with a standard deviation* of ? 1.89 per cent. Density data by Sage and Lacey" were used to fit the equations. Eq. 2 gives reliable values of the viscosity of light hydrocarbons without prior knowledge of experimental viscosity values, but accurate density data must be available. Eq. 2 was used to predict viscosity values for the natural gases studied in this paper. The particular set of parameters contained in Eqs. 3 through 5 gave values that reproduced experimental data within 25 per cent. Needless to say, in using Eq. 2 better density values will give better viscosity results. However, those engineers who do not have accurate density values at hand or the time, or such facilities as a library, computer, etc. readily available, may feel uneasy in using Eq. 2. Therefore, the authors sought the easiest but by no means best density prediction method, which was reported by Kaf 30 years ago. A set of density values, which were calculated based on Kay's method, and a generalized compressibility factor chart were used to fit Eq. 2. The results are:

Jan 1, 1967

By Claud Johnson, Kristine M. Krajnak

Vibration transmitted to the upper limb by the chronic use of hand tools can result in cold-induced vasospasms finger blanching and cyanosis, similar to that seen with Raynaud’s phenomenon (4). These vasospasms, commonly referred to as vibration white finger (VWF), are in part the result of an increased sensitivity of peripheral arteries to the vasoconstricting effects of norepinephrine (e.g., (1-3)). However, alterations in vasodilating factors could also contribute to vasospasms. The goal of these studies was to determine if exposure to a single bout of vibration alters concentrations of the vasodilator, nitric oxide (NO), in a rat tail model of vibration. To determine if vibration exposure alters NO, we exposed animals to a single bout of vibration and measured concentrations of the synthetic enzymes, nitric oxide synthetase (NOS)-1 and NOS-3 in the ventral tail artery. We also directly assessed arterial concentrations of NO using a nitrate/nitrite assay. Methods General apparatus. Animals were placed in Broome-style restrainers, and their tail was secured to a vibrating or stable platform. Rats were exposed to a single 4 h bout of tail vibration (125 Hz, acceleration of 49 m/sec2 r.m.s.) or restraint control. Animals were euthanized with an overdose of pentobarbital (100 mg/kg) and the ventral tail artery was dissected and frozen. Experiment 1: Male Sprague Dawley rats (6 weeks old, n = 32) were used for all exposures. All animals were maintained in AAALAC accredited facilities, and all procedures were approved by the NIOSH Animal Care and Use Committee, and were in compliance with the CDC Regulations for the Care and Use of Laboratory Animals. Animals were euthanized 1 or 24 h after the completion of the exposure. Western analyses were performed on total proteins (80 µg/lane) isolated from the C16-18 artery segments. Band densities were detected by chemiluminescence and quantified using Scion Image, and analyzed using 2-way ANOVAs. Experiment 2. Nitrate/nitrite concentrations.. Male Sprague Dawley rats (n = 24, 6 weeks of age) were maintained and exposed as described above. All animals were euthanized 24 h after the exposure and the ventral artery was collected. Nitrate/nitrite concentrations were measured in ventral artery tissue homogenates using the nitrate/nitrite colormetric Assay Kit (Caymen). Results Analyses of band densities revealed that there was an effect of time (F(1, 17) = 6.03, p < 0.03) on NOS-1 protein in arteries exposed to vibration, with NOS levels being lower in arteries collected 24 h after the exposure than arteries collected 1 h after the exposure. Although NOS-1 proteins concentrations were slightly lower in control arteries collected 24 h after an exposure than arteries collected 1 h after exposure, post-hoc contrasts indicated they were not significantly different than 1 h controls. In contrast, NOS-1 band densities from arteries collected 24 h after the exposure were lower than those collected 1 h after the exposure (p < 0.01; Figure 1). NOS-3

Jan 6, 2006

By S. McMurray

INTRODUCTION Towards the end of the 1890s the attention of a prospector by the name of Thomas Cullinan was drawn to the occurrence of alluvial diamonds east of Pretoria. Persistent prospecting work by Cullinan led to the loca¬tion of the source of these diamonds-a kimberlite pipe on the Elandsfontein farm. Cullinan eventually acquired the property in 1902, and during an extensive evaluation program outlined the largest diamondiferous pipe in South Africa on which the Premier mine was established. Worldwide attention was drawn to this mine in 1905 when the Cullinan diamond, which weighed 3106 carats and is by far the largest gem diamond ever discovered, was recovered. Premier mine operated with varying success until 1932 when the worldwide depression forced it to close. In 1945 the mine was reopened and since then has been a major producer of gem and industrial diamonds. During the early 1950s exploratory drilling revealed that below the 370-m level the pipe had been completely cut off by a younger gabbro sill. This sill has created major mining and metallurgical problems but the existence of vast reserves of high grade ore below it justi¬fied the establishment of virtually a new mine below the sill. Detailed planning of below-the-sill mining is nearing completion and the development of the first mining block (the L1 block) is well advanced. A full discus¬sion of this block follows. GEOLOGY OF PREMIER MINE Pipe Morphology and Country-Rock Geology As can be seen in Fig. 1, Premier mine is an elon¬gated oval shape with a long axis of 900 m on the surface and a short axis of 450 m. The pipe has a surface area of 32 hectares which decreases progres¬sively with increasing depth, so that 500 m below the surface the area is reduced to 22 hectares. The contact between the kimberlite and the surrounding country rock is sharp, with an average angle of dip of 1.48 rad (85°). From the surface down to approximately 350 m, the country rock is a felsite which grades downwards into a norite. In general both rock types are hard and massive, the felsite in particular being poorly jointed. This characteristic combined with other factors results in an extremely stable open pit, and near-vertical side¬walls are currently being maintained. The norite in general is competent but is heavily jointed in some areas resulting in very blocky ground which creates localized tunnel support problems. In the southeastern area below the sill a zone of highly altered and very unstable norite, which has also created localized sup¬port and development difficulties, lies adjacent to the pipe contact. Kimberlite Geology The Premier pipe is a complex multiple intrusion which contains in the region of 15 separate types of kimberlite, most of which are volumetrically insignifi¬cant. On a simplified basis three major types can be identified which correspond to three separate phases of intrusion. They are: Brown Kimberlite: This represents the first phase of intrusion and now occupies the eastern part of the pipe. In plan the brown kimberlite has a crescentric shape resulting from the intrusive relationship with the younger gray kimberlite which lies to the west. The brown kimberlite increases in relative area with increas¬ing depth which is a favorable factor for future mining operations since this kimberlite is the richest area of the mine, having an average grade of 70 carats/ 100 t. Below the sill this rock disintegrates extremely rapidly when exposed to air or water, to form a fine gravel-like material. This characteristic is due to a high montmorilonite clay content. As is common with clay minerals of this type, water can be absorbed into the crystal lattice with a resultant increase in volume which causes the physical decomposition of the rock. The presence of this decomposing kimberlite was a major factor governing the choice of a mining method, as well as development and tunnel support techniques. Gray Kimberlite: This is the most abundant type and represents the second major phase of intrusion. The diamond content is variable depending on the amount of waste rock dilution, and in general the rock is stable and non-decomposing. At the time of formation of Premier, the surface rock type was Waterberg quartzite, a rock formation which has subsequently been removed from this area by erosion. The explosive extrusion of the gray kimberlite caused extensive brecciation of this rock and while the kimberlite was in a mobile state huge masses of quartz¬ite, amounting to tens of millions of tons, slumped into the pipe. This quartzite became concentrated in the central area of the mine and has been a major mining problem throughout the history of Premier since, due to the irregular distribution of the quartzite, effective selective mining has never been possible. The quartzite is therefore extracted with the ore and has a significant dilution effect on the overall grade. Black Kimberlite: In the western part of the pipe a circular, pluglike body of kimberlite is intruded into the gray kimberlite. This plug consists mainly of a hard, dark-colored rock known as black kimberlite, but also contains a number of minor kimberlite variet.ies as well as nonkimberlite carbonate dikes. The Gabbro Sill The sill averages 75 m in thickness and within the confines of the pipe consists of 52 million t of rock. On average the major dip is 0.34 rad (20°) to the northeast which is across the short axis of the pipe, the range of dip being from near horizontal up to 0.52 rad (30°). Due to the pronounced dip, the sill is encount¬ered over a vertical distance of 175 m with the highest upper contacts on the 355-m horizon and the lowest bottom contact on the 530-m horizon.

Jan 1, 1982

By Alicia Esther Ares, Carlos Enrique Schvezov, Alejandra Silvina Roman, Claudia Marcela Méndez

In this paper the structure of aluminum based alloys and their corrosion behavior by using different electrochemical techniques as characterization methods are considered. Currently, it becomes imperative to know the role of the Al2Cu against the susceptibility to corrosion of these alloys. The present work aims to studying the electrochemical behavior of aluminum base alloys with the following compositions: Al-1wt.%Cu, Al-4.5wt.%Cu and Al-15wt.%Cu (with different grain structures), in 1M NaCl solutions, at room temperature. Cyclic potentiodynamic polarization tests were performed and were found that the alloys with more than 1wt.%Cu in the matrix have an unstable behavior and without tendency to reach passivity. The equivalent circuits derived from electrochemical impedance spectroscopy technique (EIS) generally showed two capacitive contributions. The susceptibility to corrosion becomes a complex function, not only of copper concentration and structure, but also with interdendritic spacings and distribution of phases in the alloys.

Jan 1, 2015

By D. P. Schlick

As of June 30, 1970, Federal regulations required the operator of each underground coal mine to maintain the average concentration of respirable dust below legislative standards. As of March 1, 1971, over 152,000 respirable dust samples have been processed by the Bureau of Mines. Approximately 75 percent of underground working sections are being sampled in accordance with Federal regulations. Results indicate that 72 percent of the sections which have completed at least one basic sampling cycle are below 3.0 mg/m3, the standard in effect under the Federal Coal Mine Health and Safety Act of 1969 (P.L. 91-173). Notices of Violation were issued on 1,670 underground mines for failure to begin a sampling program; Withdrawal Orders were issued in 64 of these instances. Notices of Violation were issued on 1,121 sections where applicable dust levels were exceeded; Withdrawal Orders were issued in seven of these instances. There are 381 mining sections currently operating on permit; from the interim Compliance Panel.

Jan 1, 1971

The paper describes a practical methodology based on numerical modelling for the prediction of progressive failure of underground mine stopes with cable bolt support. A case study of the 40-761 stope at Kidd Creek Mine, Timmins, Ontario is presented. The stope was mined by blasthole open stoping in 1986 as a lead stope within a mining block between 36-1 and 38-2 levels. Initially designed to peak at 38-2 level, the stope back caved upwards approximately 40m towards 36-1 level. Cable bolts were installed above the stope from 36-1 level after caving had begun. The stope eventually stopped to cave when the falling rock mass encountered a sufficiently high cable density. The paper provides details of the geomechanical data and modelling results of the case study. Numerical modelling is carried out using a finite element package known as e-z tools which has, among other things, a special cable/rockbolt simulation capability.

Jan 1, 1994

By Edwin de Jesús Deveaux

After 32 years of operations beneficiating lateritic nickel ore in a fully integrated pyrometallurgical complex, Falconbridge Dominicana (FALCONDO), situated at Bonao and La Vega Provinces, Dominican Republic, has become profitable with one of the lowest nickel grade content processing plants in the world, and literally without any by-product (granulated slag, will be utilized in the future as a post-processing subproduct). To December 2002, mineral reserves were 64.1 million tonnes containing laterite grading as low as 1.15 % Ni when full dilution is applied. At a cut-off grade of 1.20% Ni, the reserves will provide 15-20 years of production. The mineralized thickness over the seven active deposits averages 6 m. Development of very selective and unique mining practices, together with improvements in the process plant, are key to achieving the production goal (30 kt Ni/yr) and to meet the quality standards for the ferronickel produced. Keywords: Laterites, grade control, mining methods, environment

Jan 1, 2004

By G. B. Atkinson

The Bureau of Mines investigated a method for increasing the leaching rate of bulk superalloy scrap to facilitate recycling and recovery of critical metals such as Ni, Co, and Cr. Three superalloys were investi- gated, the cast-nickel-base superalloy IN-738, the wrought-nickel-base superalloy Rene-41, and the cast-cobalt-base superalloy Mar-M-509. Superalloys melted with 20, 30, 40, and 50 pct Al metal to form inter- metallic compounds were easily crushed to a convenient particle size and reacted rapidly with acid solutions which dissolved the metals. For example, leaching 1/2-in pieces of unalloyed IN-738 with excess 6N HC1 at 95° C for 2 h dissolved about 0.5 pct, while leaching 10 g of minus 20-mesh 30 pct Al-70 pct IN-738 with excess 6N HC1 at 95° C for 2 h dis- solved 96.2 pct.

Jan 1, 1983

By E. D. Gardner

About five minutes after 3 o&apos;clock on Thanksgiving morning, November 24, 1927, smoke was discovered coming up No. 2 shaft of the Magma Copper Co.&apos;s mine at Superior, Pinal County, Arizona. Of the 49 men in the mine at the time, 42 were able to make their way to the outside unassisted, but 7 perished. Six bodies were recovered, and the seventh, that of an Apache Indian cage-tender at No. 2 shaft, is thought to be in the caved section between the 1,600 and 2,250 foot levels A second and independent fire broke, out in No. 1 shift about 2 a.m., November 27, burning .out the shaft timbers from the surface to the 200-foot level and destroying the surface fan and structures. About 20 men were underground fighting the fire in No. 2 shaft, but all were safely withdrawn, aril the fire in No. 1 haft was quickly controlled.

Jan 1, 1928

By R. Stanevich

Studies by the National Institute for Occupational Safety and Health (NIOSH) and the Bureau of Mines (BOM) have demonstrated that: (1) 90% of diesel particulate is less than one (1) micrometer in aerodynamic diameter; (2) more than 90% of the respirable mass in electric coal mines was greater than one (1) micrometer in aerodynamic diameter; and (3) in coal mines using diesel equipment, average diesel concentrations can represent up to 53% of the MRE respirable coal dust standard. For mines approaching the 2 mg/m3 standard, compliance may be easier to attain by controls directed at diesel exhaust particulate as opposed to coal dust control. First, however, a Simple instrument is needed to measure diesel exhaust particulate concentrations. This paper describes such a sampler, its construction, and use. While results from this sampler are primarily utilized to identify control areas, NIOSH is also using the sampler for estimating worker exposures in epidemiologic studies.

Jan 1, 1988

By E. Açma

In this study, the production of Cu, Co, and magnetic iron oxide from the ancient copper, slags, located in Küre-Turkey, is investigated. In the process under development, fayalitic slags containing 1% Cu, 0.43% Co are reduced in a D.C. arc furnace with coke or graphite additions. A metallic alloy, consisting of 3.8% Cu, 3.3% Co, 2.1% S, and the rest being Ice, is produced by granulation of the liquid metal. About 85% recoveries of Cu and C:o are achieved by hot sulfuric acid leaching of these granules followed by H2S precipitation. The, production of magnetic iron oxide is possible from the discarded leach solution, loaded v:ith FeS04, by using a method with geothite precipitation, dehydration, controlled reduction, and re-oxidation steps. The magnetic oxides produced have 20 m2Jg surface area, 1:8.3 aspect ratio, and the coercivity of 330-380 Oersted.

Jan 1, 1993

By J. G. Henning, R. Edrissi

This paper describes a practical methodology, based on numerical modeling, for the prediction of progressive failure of underground-mine stopes having cable-bolt support. A case study of the 40-761 scope at the Kidd Creek mine, Timmins, Ontario, Canada is presented. Scope 40-761 was mined by blast hole open sloping in 1986 and was a lead scope within a mining block located between levels 36-1 and 38-2. Initially designed to peak at level 38-2, the scope back caved upwards =40 m towards level 36-1. After caving began, cable bolts were installed above the stope from level 36-1. The stope eventually stopped caving when the falling rock mass encountered a sufficiently high cable density. This paper provides details of the geomechanical data and modeling results of the case study. Numerical modeling of cable bolts around the mine stoke was carried out using a finite-element modeling software. The software, known as e-z tools, was developed by the first author.

Jan 1, 1996

By Rod Samuels, Rupert Allen, Thomas Harper

"Viceroy Resource Corporation of Vancouver, B.C., has recently developed and brought into production the Brewery Creek Mine, an open-pit heap leach gold mine, located 55km east of Dawson City in Yukon, Canada. Mineable reserves are 15.2 million tonnes of ore grading 1.45 grams/tonne, containing 22 tonnes (707,315 oz) of gold. Ore processing employs the heap leach technology using run-of-mine ore. Highlights of 1996 activity included construction of a 158,000 m2 of leach pad, placing 1.9 million tonnes of ore at a grade of 1. 46 gpt to the leach pad, construction and successful commissioning of the ADR plant, and pouring of the first gold bar on November 15th.Permitting of this mine has drawn significant attention because of the innovated heap leach technology; although this technology has been proven in other jurisdictions, it has not been used at such extreme northern sites where winter temperatures routinely reach -45°C for extended periods.ABSTRACT ONLY"

Jan 1, 1997

By Robert Davis Longyear

In diamond-drill work, a true sample consists of all the material cut by the bit—both core and cuttings. As the recovery of this sample is the object of diamond drilling, the utmost care should be taken to secure it. Speed of drilling and low costs are of little value if an inaccurate sample is obtained. The engineer in charge must study his material and lay out the plan of sampling, and then see that the drill runner follows his instructions; for the runner may be more interested in obtaining a large footage than in developing accurate methods of sampling. When the core has been removed from the core barrel, it should be placed in a core box in the exact order in which it is taken from the ground. This box, Fig. 1, is usually a shallow tray 4 or 5 ft. (1.2 or 1.5 m.) long, with partitions running lengthwise between which the core

Jan 1, 1923

[Adams, Douglas K General Electric Co., P.O. Box 2331, Denver 1, Colo. Adams, Kenneth L Peabody Coal Co., 301 N. Memorial Dr., St. Louis, Mo. 63102 Ahlborg, William Joy Mfg. Co., 1400 17th St., Denver, Colo. Allen, Dr. Harry C U. S. Bureau of Mines, Washington, D. C. 20242 Anderson, Robert Mine Safety Appliances Co., 1881 West N. Temple, Salt Lake City, Utah Archer, Bryan J., Jr Peabody Coal Co., 421 Glenwood St., Grand Junction, Colo. Arentzen, E. M W. RD 1, Charleroi, Pa. Arentzen, L. E. Lee-Norse Co., 6030 55th Pl., Arvada, Colo. Arentzen, Rolf F Lee-Norse Co., Box 582, Charleroi, Pa. Arnston, E. K Standard Oil Div. American Oil, Rt. 1, Box 504, Golden, Colo. Artis, Cliff E Big Horn Coal Co., 247 Sherman Ave., Sheridan, Wyo. Atchison, Lee Atchison Construction Co., Drawer D, Aztec, N. Mex. Audin, Clement, Jr Champion Coal Mining Co., Paonia, Colo.]

Jan 1, 1969

By Robert Davis Longyear

In diamond-drill work, a true sample consists of all the material cut by the bit—both core and cuttings. As the recovery of this sample is the object of diamond drilling, the utmost care should be taken to secure it. Speed of drilling and low costs are of little value if an inaccurate sample is obtained. The engineer in charge must study his material and lay out the plan of sampling, and then see that the drill runner follows his instructions; for the runner may be more interested in obtaining a large footage than in developing accurate methods of sampling. When the core has been removed from the core barrel, it should be placed in a core box in the exact order in which it is taken from the ground. This box, Fig. 1, is usually a shallow tray 4 or 5 ft. (1.2 or 1.5 m.) long, with partitions running lengthwise between which the core

Jan 1, 1923

By Roberto Parra

The selective reduction smelting of Cu2O in Cu2O-FeOx-SiO2 melts has been studied at laboratory level, using as a feed a dead roasted calcine from a copper concentrate. The purpose of the study was to evaluate the kinetic and mechanisms of the indirect reduction with CO and the direct reduction with graphite from 1260°C to 1350°C. The reduction rate by CO was found to be 10-2 to 10-1 mole Cu2O m-2s-1. The graphite reduction macrokinetics for FeO and. Fe2O3 containing melts, was found to be a first order reaction with respect to the Cu2O concentration, with a kinetic constant of 104 to 10-3 s-1. The reduction rate was not sensitive to temperature nor to stirring, in the range studied. The measured reduction rate is almost one order of magnitude larger than the observed rate for the direct reduction of FeO.

Jan 1, 1999

By David Hall

IN October, 1926, the Inspiration Consolidated Copper Co. began the operation of its new leaching plant, which has a capacity to handle 8600 dry tons of ore daily and produce therefrom approximately 160,000 lb. of electrolytic copper per day. (See Fig. 1.) The energy for the leaching process is supplied by three motor generator sets (Fig. 2), each set consisting of one 5450-hp., 6600-volt, three FIG. 1.-LEACHING PLANT OF INSPIRATION CONSOLIDATED COPPER CO. AT INSPIRATION, Ariz. phase, 25-cycle, 500-r.p.m. synchronous motor and two 1920-kw., 150 to 320-volt, 6000-amp.,12-pole, d. c. generators, and one 70-kw., 125-volt d, c. exciter. The capacity of the three sets is 36,000 amp. at 320 volts. A description of the metallurgical processes of this plant was. given in a paper by H. W. Aldrich,1 and from his paper we quote the following figures for the month of July, 1927:

Jan 1, 1928

The company was formed in 1926 to exploit tin bearing veins adjacent to Aberfoyle Creek in north-east Tasmania. In 1928 a 923ft tunnel was driven to explore and develop the mine 150ft below surface. This put the company on a path to become Australia&apos;s second largest tin producer by the late 1960&apos;s. Recently, Aberfoyle Resources Limited completed a 1.1km tunnel to access the major Hellyer zinc, silver, lead orebody at 300m depth. Production at 1 million tonnes a year is likely, and will make the company a significant world supplier of zinc by the late 1980&apos;s. The intervening 20 year history of survival and diversification illustrates principles of mineral exploration which proved valid in the Australian context. The objective of exploration should be to develop mines which can survive rigorous competition and downturns in commodity prices. Such mines will be based on orebodies with many of the following characteristics described by Richards (1986).

Jan 1, 1987

By William J. Campbell

The purpose of this investigation was to extend the analytical services which are required for Bureau of Mines programs in developing and evaluating high-purity materials. Determination of trace elements in minerals and ores as an aid in geochemical evaluation and prospecting was considered. Serious consideration should be given to the merits of using the avail- able fluorescent X-ray spectrographic instrumentation and techniques for determining trace elements. Limits of detectability for trace elements in metal, oxide, solution or mineral samples range from 0.1 to 100 p.p.m, depending on the element being determined, overall sample composition, and the complexity of the X-ray spectra; limits of detectability range from 0.01 to 1 microgram for elements that have been preconcentrated by a chemical or physical process, for example, by ion-exchange membrane.

Jan 1, 1962