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By R. D. Alorro, B. Tadesse, E. Aghaei

Cinnabar (HgS) and native mercury (Hg) are the most common naturally occurring forms of mercury found in most gold ores subsequently released into the environment during processing. Mercury and its compounds are extremely toxic and recognised as serious health and environmental hazards. This research investigates the possibility of mercury (Hg) removal from waste solutions from gold processing using iron-aluminium (Fe-Al) bimetallic particles. The synthesis of Fe-Al bimetallic particles using zero-valent aluminium and ferric chloride as precursors were performed following the optimisation of influencing factors. The presence of both metals in the prepared bimetals was confirmed by XRD analysis. The experiments for mercury removal by bimetals were designed using the central composite design and Minitab software based on two variables including contact time and adsorbent dosage. The best result of Hg(II) removal (>90%) was achieved using 4 g/L bimetals and contact time of 75 min. However, the statistical analysis of results indicated that these parameters have only a minor contribution to the removal of Hg(II) by Fe-Al bimetals. Higher bimetal dosage and contact time resulted in a higher Fe dissolution from the Al surface which can be attributed to the presence of nitrate (# $) ions in the solution. However, adding 0.1 M NaCl to the Hg solution had a positive impact on Hg removal by improving the conductivity and electron transfer within the solution. The Fe-Al bimetallic particles are promising substances for further testing of Hg removal from gold processing waste solutions with different conditions and constituents. Keywords: Mercury removal, gold processing, Fe-Al bimetals, optimisation

Jan 1, 2020

By P Ridley

EnergyAustralia’s Sydney Central Business District (CBD) cable tunnel network will form a loop 6.2 km in length. The 3.2 km long, 3.5 m, diameter city east cable tunnel (CECT) currently in design, will complete the loop in 2014. This paper discusses the ventilation design of the CECT, considering operation for four functions:1. normal (unmanned),2. access (manned),3. purge, and4. emergency fire modes.The dominant design criterion which determines the required ventilation capacity for CECT is the specification of an upper air temperature limits of 35°C (dry bulb) and 24°C (wet bulb) for manned access, during all ambient weather conditions and cable heating loads. Simplistic static heat transfer analyses do not yield a sufficiently accurate calculation of tunnel air temperature and humidity to provide a safe and yet economical design. The primary refinement in the analysis discussed in this paper is associated with modelling of the system’s dynamic behaviour.Our means of analysis is through a thermo-fluid-dynamic simulation of the interactions between the diurnally and seasonally varying loads (cable heat generation, ambient air conditions and groundwater inflow), tunnel airflow and the resulting tunnel air temperature and humidity. These simulations are validated using experimental data from the existing city south and city west cable tunnels.Fire life safety scenarios are also analysed and discussed in association with the ventilation design. Ventilation strategies are developed for dealing with such emergency fire situations.The understanding and insight provided by the work offers the ability to optimise ventilation plant provisions in future cable tunnels, particularly long and high energy density tunnels.

Mar 8, 2011

By D. I. Hoyer

A preliminary model has been developed for autogenous pebble milling using information obtained from studies on ball milling and SAG milling. The model treats the breakage as the weighted sum of first-order breakage of smaller particles by tumbling pebbles, non-first order breakage of larger particles which are too large to be nipped properly by pebbles, autogenouS fracture and chipping of larger lumps to form pebbles, and autogenous fracture and abrasion of pebbles. The model includes the effects of residence time distribution, classification through the exit grate, and a mass transfer relation which describes the accumulation of fine material in the mill. Example simulations are given, based on breakage parameters determined from batch grinding tests in laboratory mills. fracture breakage and abrasion. In the development of these preliminary mass balance equations it will be assumed that breakage by fracture is first-order, but this assumption will be modified later in the paper. It will also be assumed that the residence time distribution of a long autogenous mill can be described by an equivalent series of m fully-mixed mills, with a classification action imposed on the mill contents by the discharge grate. Size distributions are expressed as a v2 geometric series, numbered 1 for the top size down to n for the fines, or "sink" interval. If the holdup in the mill is W then the rate of breakage of material in size interval i is given by SiwiW, where wi is the fraction of material in size interval i, and Si is -the overall specific breakage rate of size i material (fraction per unit time).

Jan 1, 1985

By David Oliveira

"INTRODUCTIONOne of the key drivers for the selection of a mechanized tunneling method in good quality rock masses is a good excavation advance rate. In order to achieve satisfactory advance rates, a good geotechnical performance of the rock grippers in main beam open tunnel boring machines (TBM) is required, besides other factors related to ground support and the performance of the cutter head.One well known potential issue of main beam gripper TBM is associated with the bearing capacity of the tunnel side walls while crossing fault zones or poor rock masses in general. Such a mechanism is similar to that of footings on rock and perhaps the most common problem associated with gripper performance. Depending on the quality of the rock, the rock under the gripper contact may experience significant damage and crushing (Figure 1), eventually affecting the TBM advance rate due to a lack of tunnel wall reaction/support. Such a mechanism is primarily dependent on rock quality, applied loads and gripper size.In the case of large diameter TBMs (e.g., D > 12 m), a second potential failure mechanism may arise associated with the loss of confinement within a rock pillar between twin tunnels, even in good quality rock but particularly in bedded sedimentary strata. Punching of the rock pillar may develop due to excessive shear along bedding partings and sub-vertical joints (Figure 2), particularly under a low stress environment. As a result, this mechanism is dependent on both the rock pillar width between twin tunnels and stress conditions around the tunnels, in addition to the previous factors described for the first failure mechanism."

Jan 1, 2016

By C. D. Litton, I. E. Perera

Experiments were conducted to evaluate the response characteristics of commercially available gas, smoke and flame sensors to fires of common combustible mine materials. The experiments were conducted in the large-scale fire gallery located at the National Institute for Occupational Safety and Health (NIOSH) Lake Lynn Laboratory in Fairchance, PA, using ponderosa pine, red oak, Douglas fir, high and low volatile coals, polyvinyl chloride (PVC) and styrene butadiene rubber (SBR) conveyor belts, No. 2 diesel fuel and diesel exhaust. All the experiments (except those using No. 2 diesel fuel and the diesel exhaust tests) were conducted in a similar manner, with combustible materials heated rapidly by electrical strip heaters, producing smoldering fires that quickly transitioned into flaming fires. The sensors included a diffusion-type carbon monoxide (CO) sensor, photoelectric- and ionization-type smoke sensors, a video smoke/flame detector and an optical flame detector. Simultaneous measurements were obtained for average gas concentrations, smoke mass concentrations and smoke optical densities in order to quantify the levels of combustion products at the alert and alarm times of the sensors. Because the required sensor alarm levels are 10 ppm and 0.044 m-1 optical density for CO and smoke sensors, respectively, the different sensor alarms are compared to the time at which the CO and smoke reached these alarm levels (Litton et al., 1991). In addition, the potential impact of using smoke sensors that have met the performance standards from accredited testing laboratories is also evaluated using the response of an Underwriters’ Laboratory (UL)-approved combination photoelectric/ionization smoke detector. The results are discussed relative to fire sensor needs that can have a positive impact on mine fire safety.

Jan 1, 2014

By M I. Pownceby, M A. Rhamdhani, S Purohit, G Brooks

The use of concentrated solar flux for high temperature metallurgical applications is a wellresearched area with several reported literatures on solar calcination and metal oxide reduction. This paper presents two such processes with potential to reduce the carbon footprint from ironmaking through using concentrated solar flux. The first process involves solar flux incorporation to the recently developed lime-magnetite pellet (LMP) route of magnetite ore agglomeration. The second process is a hybrid solar-smelting route for iron ore-coal composite pellets that utilises solar flux to provide process heat. Both the concepts of solar agglomeration and solar smelting process were investigated using a solar simulator-hybrid reactor set-up at Swinburne University of Technology. Results from solar agglomeration experiments at 950°C suggested no change in the reaction mechanism of the LMPs under solar irradiation compared to electrical heating. The percentage and morphology of the primary phases (mainly CaFe3O5) appeared similar for both solar and electric heated LMPs. The solar-smelting of magnetite concentrate-lignite coal composite pellets at 1130°C showed a maximum metallisation of 55 per cent after 1.5 hrs of reaction. The solar-smelt process has about 25 to 35 per cent lower CO2 emission compared to the blast furnace ironmaking. Technoeconomic analysis of implementing a CST facility in an existing composite pellet process suggested a payback period of about ten years at a heliostat cost of $A100/m2 and natural gas cost of A$10/GJ. The economics of CST implementation can be further enhanced by decreasing the thermal losses from the heliostat field and reactor.

Nov 8, 2021

By J Siliézar

The Ernest Henry Mine (EHM) is situated 38 km north-east of Cloncurry in the Mount Isa – Cloncurry mineral district of northwest Queensland. The EHM orebody is an iron oxide copper gold deposit with an average grade of one per cent copper, 0.5 g/t gold and 23 per cent magnetite, with current reserves of approximately 88 Mt.The copper concentrator is a single line plant with a nominal throughput rate of 1300 tonnes per hour. An average of 350 000 tonnes of concentrate is produced each year containing around 100 000 tonnes of copper metal and 120 000 troy ounces of gold.In December 2009, Xstrata Copper announced approval of a $589 M investment to extend the life of EHM to at least 2024, through the transformation of open pit mining operations to a major underground mine together with the construction of an associated magnetite extraction plant.The EHM magnetite plant extracts the magnetite from the copper concentrator’s tailings stream. It will produce approximately 1.2 Mt of magnetite concentrate per annum at full capacity for export to Asia, making EHM Queensland’s first iron ore concentrate exporter. Construction of the magnetite extraction plant commenced in July 2010 and was completed in January 2011.This paper gives an overview of the development of the EHM magnetite extraction plant flow sheet from the early mineralogy and laboratory test work through to the plant commissioning and early operation of the base plant. It has a major focus on the commissioning learnings from the plant start-up and includes a review of the operational performance of the plant versus original design and expectations.

Jul 11, 2011

By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016

By K. Burke, K. L. Myers, R. Espell

Barrick's Goldstrike AA heap leach pad is an HDPE-lined facility that was used for gold recovery from low-grade ores using conventional cyanide heap-leach technology. The pad was operated from 1987 through 1999. Goldstrike prepared a unique reclamation plan for the AA leach pad facility to provide for a cost-effective, environmentally sound facility closure and to fulfill the State of Nevada's closure requirements. The traditional Nevada leach pad closure procedure involves rinsing to reduce the cyanide concentration to an acceptable level followed by reclamation. However, rinsing does not typically reduce certain metals and compounds, and some constituents may increase in concentration with rinsing. A closure scenario to effect limited infiltration through installation of a capillary cover for the leach pad was developed. The capillary cover was constructed by placing a fine-grained layer above the coarse-grained spent leach material to create a capillary break. In an arid climate such as in Nevada, the fine-grained layer will rarely reach saturation, and the cover will be able to store water during precipitation events and will allow removal of water through evaporation and transpiration (ET) during the growing season. A 1.22-m (4 ft) cover thickness was selected as the optimum design cover thickness. The drainage network on the surface of the recontoured AA heap leach pad was specifically designed to enhance the re vegetation, reclamation and sediment yield control aspects of the AA heap leach pad closure, while resulting in a natural looking surface that is compatible with the surrounding topography. Adjacent natural topographic features were used to establish target design parameters for recontouring and erosion-control design.

Jan 1, 2002

By J. D. Davis

THIS-report gives results of in investigation of the carbonizing properties of 18 coals, including 2 from Alaska, 12 from British Columbia, 3 from Washington, and 1 from Utah. Each coal was carbonized in the standard 13-inch Bureau of Mines-American Gas Association (BM-AGA) retort at 900° C. Plastic properties were determined by the Gieseler and Davis methods, and agglutinating and free-swelling properties were determined by standard methods. Expanding properties were measured in the Bureau of Mines sole-heated oven. From the results of the tests on these single coals, three coals from the Crowsnest area in British Columbia, representing Elk River Nos. 4, 9, and 10, were selected for blending with the Utah coal, which was from the Lower Sunnyside bed, Horse Canyon mine, Emery County. Lower Sunnyside also was blended with Wilkeson -Nos. 2 and 3 (Washington) coals, Pocahontas No. 3 from McDowell County, W. Va., and the Oklahoma low-volatile coal used in the blend carbonized at, the Provo, (Utah) coke plant at the time this investigation was started. Most of the blends contained 3 percent hard pitch, which is the proportion used at the Provo plant. The blends were also carbonized in 13-inch BM AGA retorts at 900° C. High-volatile B coal from the No. 3 bed, Evan-Jones mine, Lower Matanuska, Valley, Alaska, yielded poorly fused coke or char. M-bed coal from the Chickaloon mine, Upper Matanuska. Valley, Alaska, ranked as medium-volatile bituminous and coked strongly. It expanded 39.6 percent in the sole-heated oven at a. charge density of 55.5 pounds per cubic foot..

Jan 1, 1952

By L. Ya Agapova

Emissions from pyrometallurgical processing of copper concentrates are usually subjected to wet scrubbing. The washing sulphuric acid so produced contains up to 0.2 g/L of rhenium, which is recovered by solvent extraction in the form of crude ammonia permeate (NH4ReO4). The mother liquor, obtained from the sulfuric acid wash, contains up to 35 g/L of rhenium and significant amounts of impurities. Crude rhenium salt is commonly processed by double recrystallization to produce marketable salt. A ton of high grade NH4ReO4 can be produced using 3.0-3.5 m3 of mother liquor. We propose an efficient technology of mother liquor pre-treatment aimed at removal of water-soluble organics with subsequent electrodialysis. Electrodialysis of mother liquor in a multichamber electrodialyzer resulted in the production of pure rhenium acid, from which a marketable NH4ReO4 is precipitated using ammonia solution. Multiple steps of recycling consisting of dissolution of NH4ReO4 salt, rhenium acid production from NH4ReO4 salt by electrodialysis and precipitation of NH4ReO4 from rhenium acid made it possible to upgrade the purity of obtained rhenium compounds by 1-2 orders of magnitude. A rhenium metal powder of 99.997% purity was produced by high-temperature reduction of high-purity NH4ReO4 with gaseous hydrogen. Rhenium metal powder of high purity can be produced from sulfate solutions of NH4ReO4 by non-platinum anode-based membrane electrolysis processes also. Keywords: rhenium, mother liquors, membranes, electrodialysis, rhenium acid, ammonia perrhenate, reduction, powder, electrolysis

Sep 1, 2012

By Chris Ashton, Andreas Rädle, Taner Aydogmus

"The Contract C310 is part of the current biggest infrastructure project of Europe “Crossrail” which is a major new cross-London rail link project and comprises the construction of the North Woolwich Portal, Plumstead Portal and the twin tube Thames Tunnels with a length of approximately 2.6km. Two Mix-Shield TBMs (Diameter 7.12m) were driving through differing challenging ground conditions (Thanet Sand, Gravels, Flint and Chalk) below the ground water table. The two tunnels were underpassing several listed buildings, sensitive structures, operational railway tracks with low overburden and close to existing subway tunnels in an urban environment. Several additional measures as compensation grouting, micro piles and an intensive monitoring has been carried out to ensure a safe tunnelling process. PROJECT OVERVIEW CROSSRAIL Project Crossrail Crossrail is currently the biggest infrastructure project in Europe which has been developed to serve London and the southeast of England. The project includes the construction of twin-bore tunnels on a west-east alignment under central London and the upgrading of existing National Rail lines to the east and west of central London. The new rail track, as shown in Figure 1, starting in Shenfield/ Abbey Wood in the east of London and ending in Reading / Heathrow Airport in the west of London, includes the construction of nine central area stations, providing interchange with London Underground, National Rail and London Bus services, and the upgrading or renewal of existing stations outside central London.Altogether there will be 118km of new rail tracks, including 42km of tunnels and 40 train stations. After completion in 2018, Crossrail expects 200 million passengers per year (Tauriainen, Rädle, Ingram 2013)."

Jan 1, 2016

By M Hedley

Tracking plant and personnel in underground environments provides multiple potential benefits for a mine including increasing safety, better monitoring of production, traffic control, and in the future monitoring and control of autonomous vehicles. The main techniques for wireless tracking are to use radio frequency identification (RFID), signal strength based techniques, and time of arrival (TOA) based techniques. RFID does not provide continuous tracking and signal strength techniques have poor accuracy in the complex radio propagation environment present in mines. TOA based techniques are potentially the most accurate, but most current equipment does not realise the potential of the technique. CSIRO has been developing the wireless ad-hoc system for positioning (WASP) system for wireless tracking in a range of challenging environments including underground mines. WASP has been licensed for sporting applications and has delivered encouraging results in early trials for a surface and an underground mining application. The system utilises a number of ‘anchor nodes’ that are placed at surveyed fixed locations within the mine, and tags attached to plant or personnel to be tracked. The system provides an ad hoc data communication network, thus wired data connections are not required to the anchor nodes. WASP uses transmissions in the 5.8 GHz ISM (instrumentation, scientific and medical) frequency spectrum to perform highly accurate ranging between nodes, hence tracking of tags. The localisation performance of the system depends upon the radio propagation environment, ranging from 0.1 m in low multipath conditions. In this paper we describe the WASP system and provide results of initial testing in an underground mine that shows that the system achieves high ranging accuracy, hence localisation accuracy.

Mar 21, 2011

By Pierre Dosmond

In ore mining technology, the loading and hauling operations are undoubtedly the area where the most spectacular progress has been made during the last twenty years. I shall draw some examples from the Eastern France iron ore mines which I how well and whose production of 62 million tons for 1962 and 1963 constitute a worthwhile experience worldwide. The iron ore deposits of Lorraine are of sedimentary origin. They contain many mineralized horizons with workable seams situated from 330 to 830 ft. in depth. The dip of these seams is generally less than six percent. Their thickness varies from 6 to 23 ft. All seams are not workable throughout the whole area of occurrence, but in some mines there are five mineable seams in the same vertical section, with from 5 to 20 ft. of barren ground intervening between them. The iron content of the mineral varies from 28 to 36 percent. Specific gravity of the ore is 156 lb. per cu. ft. m place and 100 lb. per cu. ft. blasted. Reserves of iron ore in the Lorraine region are estimated at six billion tons with an iron content of more than 28 percent. These mines operate by means of rooms and pillars process, with pillar robbing; the final recovery is very good and averages 90 percent. Some years back, competition from richer, imported ores incited these mines to make constant efforts to increase their productivity and reduce mining costs, thus placing them in a leading position in mining technology, as evidenced by the dramatic evolution of their output per manshift (Figure No. 1).

Jan 1, 1970

By Mohammad Noaparast, Hamed Haghi

"In this research work, it was attempted to reduce the iron contents (Fe2O3) in relatively low grade silica sample which was obtained from Shenin silica mine, using magnetic separation. The prepared sample contained 93.75%SiO2, 0.44%Fe2O3, 2.78%Al2O3, and 0.08%TiO2 and the Fe2O3 had to be reduced to less than 0.08%. Mineralogical studies and XRD analysis indicated the presence of Hematite, Pyrite, and Goethite as the major iron impurity phases. Mineralogical studies of polished and thin sections demonstrated that the degree of freedom of silica is more than 80% in -300+212 ?m size fraction. After primary stages including crushing, milling, scrubbing and de-sliming, various methods such as low intensity magnetic separation (LIMS), high gradient magnetic separation (WHGMS) and dry high intensity magnetic separation (DHIMS) were applied to find out that which process would be appropriate for the elimination of iron impurities from this sample. Different experiments were carried out on the product of wet rod mill and scrubber. However the magnetic field intensity of WHGMS was increased down to 2Tesla, and there was not any acceptable result in reduction of Fe2O3 content lower than 0.08%. Thereafter the product of wet rod mill and scrubber were dried and reported to DHIMS. In these experiments, maximum magnetic field intensity was 1.4Tesla. In this case very significant results were achieved, and Fe2O3 content of final product were reduced to less than 0.05% which meets glass manufacturing standards."

Jan 1, 2014

By J. L. Jambor, H. W. Nesbitt

Oxidative dissolution of pyrrhotite and pyrite is largely responsible for the sulfate-rich waters of the vadose zone in the Waite Amulet tailings. Although the shallowest of the sulfate-rich waters are of the Fe-SO4 type, they change to Mg-SO4-type, near-neutral waters within 1-2 m of the tailings surface. Phyllosilicates and amphiboles are the only minerals present in sufficient quantity to ameliorate the amount of acidity produced. X-ray diffraction and microscopic studies of bulk sample indicate that quartz, chlorite, talc, amphiboles, magnetite, albite, and micas are the major and minor non-sulfide minerals, but their variations with depth do not give clear indications of depletion in the vadose zone. Mineralogical and bulk chemical compositions of the tailings confirm that Fe2O 3 has accumulated in large quantity in the vadose zone, with the Fe having been derived from Fe sulfides. When the effect of Fe2O3 is accounted for, the bulk compositions suggest that SiO2 is slightly more abundant in the vadose zone than in the saturated zone. This may be the result of residual enrichment of siliceous minerals such as quartz and albite in the vadose zone. Weathering of the tailings since the cessation of deposition in 1962 has resulted in a well-defined zone of sulfide depletion and secondary sulfate-mineral development. Although some silicate dissolution is indicated by pore-water compositions, the role of silicates in providing neutralization seems to have been minimal. The contribution by silicate minerals in laboratory tests of neutralization potential may be excessive relative to that in natural settings.

Jan 1, 1999

By ROBERT. RICHARDS

I. INTRODUCTION The object of this paper is to enlarge the field of settling velocities treated by me in my former papers, Close Sizing Before Jigging, and Sorting Before Sizing.' There seemed need of work both on coarser and on finer sizes. Messrs. A. Sidney Warren and M. L. Nagel undertook the investigation for the coarser sizes, from 12.85 mm. down to 2.05 mm. diameter. Their work, because of the closer spacing and because of the increased number of observations and consequent stronger averages, called for a revision of the former work. Messrs. G., A. Barnaby and Ralph Hayden undertook this part of the work, from 2.49 mm. down to 0.28 mm., which is near the limit of sifting. Their work covers the ground much more minutely and comprehensively than the former papers. There remained to be covered the portion of the field too fine for investigation with the sieves. This part, covering the range of grains from 0.48 to 0.03 mm., was undertaken by Mr. E. S. Bardwell. For it he used the elutriation method. II. THE FIRST, OR COARSEST, SECTION OF THE FIELD. The first desideratum in this investigation was a series of sieves for sizing the sands preparatory to making the tests. It became necessary, therefore, to decide on a sieve-scale for this purpose. A sieve-scale is a series of sieves in which the dimensions of the holes of the successive members form a series increasing by a. definite ratio. There are three natural sieve-scales : 1, progressing by doubling the width of the hole for each suc-

May 1, 1907

By M Rankin, F Medina, R Verburg

We conducted a preliminary assessment of an extensive deposit of historic tailings discharged over a period of 40 years to the shoreline along a Southern Peruvian coastline. The tailings formed an extensive beach approximately 2.4 km long and 300 m wide. The tailings consist principally of pyrite (37 to 59 per cent), hematite (nine to 20 per cent), magnetite (three to 13 per cent) and quartz (11 to 36 per cent). The present operating company was required to evaluate the feasibility of capping the ocean side tailings deposit, however, given the size of the undertaking and the potential to reclaim residual minerals from the tailings, it was prudent to first evaluate whether capping would in fact reduce the impacts to the marine environment. Therefore this preliminary assessment examined: 1. metals contamination in tailings, shoreline porewater and marine sediments; 2. reactivity of tailings and acid generation potential; and 3. the potential for biological effects from metal contamination in the uplands tailings (solid phase) and beach porewater. Based on mineralogy, column leach studies and chemical results, the upland tailings have a high geochemical potential to acidify and release metals, especially copper, nickel and zinc, should they be subject to oxygenated and aqueous conditions. But, the extreme arid climate results in very low potential for precipitation and virtually precludes the transport of acid drainage reaction products from the upland tailings towards ocean. Wind erosion caused by offshore winds is likely a small source of tailing transport to the ocean. Since some potential exists to reprocess the tailings in the future, capping does not seem justified at present.

Jan 1, 2003

By Dai Xi

In the present work, the viscosities of molten FenO-MgO-Si02 and FenO-MgO-CaO-Si02 semi-synthetic slags for nickel flash smelting were measured in the temperature range from 1473 to 1723K by a rotational viscometer. The ratio of Fe to Si02 was fixed at 1.2, calcium and magnesium oxide contents varied in the range from 2 to 8 mass% and 9 to 12 mass%, respectively. The results showed that silicate anions became smaller by increasing CaO content, which results in a decrease of the viscosity of the slag. In the case of MgO addition the viscosity behavior was complicated. At MgO content below 11 mass%, the viscosity increased with the increase of MgO at all temperatures tested. However, when the MgO content was above II mass%, the viscosity decreased slightly for FenO-MgO-CaO-Si02 system. At higher MgO contents, low-viscosity slags can be obtained by adding CaO. At a given composition, the viscosity decreased with increasing temperature. The higher the temperature, the more MgO can be added before saturation. The effect of Fe304 on the viscosity was quite significant. The viscosity of slag increased by 300mPa's at l573K when Fe304 content varied from 3 to 9 mass%. The viscosity values are presented as the functions of temperature and composition. A comparison between FenO-MgO-Si02 and FenO-MgO-CaO-Si02 systems is given in this study.

Jan 1, 2003

By Yosep Han

Mechanically-induced chemical reactions between natural beach ilmenite (FeTiO3) and silicon (Si) have been examined by a combination of X-ray diffraction (XRD) and scanning electronic microscopy (SEM) analyses. The effect of various milling time on the phase transformation, crystallite size, and lattice strain of a beach sand ilmenite with silicon, and on their leaching behavior in hydrochloric acid (HCl) has been investigated. For mechanically activated FeTiO3, the crystallite size decreased and lattice strain increased monotonically with time of milling. However, the mechanochemically synthesized ilmenite with silicon showed a relatively smaller crystallite size and greater lattice strain compared with the mechanically activated ilmenite under the same milling condition. In accordance with the elapse of milling time, the intensity of both pure FeTiO3 and mechanically activated FeTiO3 gradually decreased. However, in case of the mechanochemically synthesized ilmenitereduction of FeTiO3 by silicon resulted in formation of rutile TiO2 at the milling time of 20 h and afterwards. Additional leaching experiments were carried out at an HCl/ilmenite (wt%) ratio of 20:1. The concentration of HCl was 3 M and the reaction temperature ranged from 70 to 90 oC. Mechanical activation was observed to significantly enhance the dissolution rates of both iron (Fe) and titanium (Ti) in HCl. Particularly, effects of both milling time and silicon addition on the dissolution rates of titanium and iron were significant, while those of temperature were relatively minor under the conditions investigated in this study. Keywords: mechanochemical treatment, natural beach ilmenite, silicon, leaching behavior

Sep 1, 2012