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ALABAMA Aldrich.-Lloyd, T. W. Ashland.-Downs, F. G. Geary, E. S. Auburn.-Brown, R. L. Bessemer.-Abbott, C. E. Ball, T. L. Ferguson, V. Salmon, H. S. Stuart. Q. W. Birmingham.-Adams, J. H. Aldrich, T. H. Aldrich, T. H., Jr. Allen, A. W. Armstrong, W. D. Ball, E. M. Bonnyman, J. Bush, M. W. Crawford, G. G. Davis, C. B. Ellis. E. E.

Jan 1, 1923

[EDMUND M. WISE, Chairman ROBERT H. LEACH, Past-Chairman D. K. CRAMPTON, Vice-Chairman CARL E. SWARTZ, Vice-Chairman W. M. CORSE, Treasurer LOUIS JORDAN, Secretary 29 West 39th St., New York, N. Y. Executive Committee 1941 1942 E. A. ANDERSON FRANCES H. CLARK D. L. COLWELL W. L. FINK W. P. SYKES J. T. NORTON 1943ERIC R. JETTE LOUIS W. KEMPF GEORGE SACHS]

Jan 1, 1940

Institute of Metals - Iron and Steel - Mineral Industry - Industrial Minerals Year ?Division - Petroleum Division ? Division - Coal Division - Education Division -Division 1918 W M CORSE 1919 1920 W. H BASSETT 1921 1922 W B PRICE RALPH ARNOLD 1923 E DEGOLYER 1924 G K ELLIOTT 1925 F JULIUS FOHS 1926 PAUL D MERICA 1927 JOHN M LOvEJOY 1928 S SKOWRONSKI A W AMBROSE RALPH H SWEETSER

Jan 1, 1952

By Andrew Port, Ali Ghandeharioon

Nonlinear seismic deformation analyses using the finite difference program FLAC were performed for a wastewater treatment plant to estimate foundation displacement and performance of two proposed trickling filters during the 2475-year event design earthquake. The effective stress based constitutive model UBCSAND, which captures the cyclic behavior of both the “sand-like” and “clay-like” materials, was used to model the dynamic response of the soil strata. Dynamic analyses of the site indicated that in absence of ground improvement or deep foundations beneath the proposed trickling filters, those structures would undergo horizontal displacements in excess of 1 m and short-term differential settlement gradient of about 400 mm over 50 m as a result of seismic and post-seismic settlements. Three mitigation options were considered for limiting the seismic displacements and differential settlement gradients of the proposed trickling filters. These alternatives include vibro-replacement stone columns, vibro-replacement stone columns plus supplementary cutter soil mixing (CSM) configurations, and pile foundations. Various layouts for each mitigation option were considered including the lateral extent of the ground improvement, CSM walls and pile spacing. Seismic horizontal and vertical displacements of the proposed structures as well as post-earthquake consolidation settlements due to dissipation of excess pore water pressures in soil layers were assessed in all the analysis alternatives. The analyses indicate that all the alternatives considered have the potential to provide a comparable level of seismic and post-seismic performance. However, for similar performance levels, the ground improvement options need to extend well beyond the edges of the proposed structures, while the piles can be limited to just beneath the footprint of the structures. INTRODUCTION Annacis Island Wastewater Treatment Plant (AIWWTP) is owned and operated by Greater Vancouver Sewerage and Drainage District and services a population of approximately 1 million people in Vancouver, British Columbia. Wastewater is generated by residential, commercial, and industrial sectors and the treated effluent is discharged to Annieville Channel of Fraser River on the south side of Annacis Island. AIWWTP is located on a 51-hectare site and was commissioned in 1975 as a primary treatment plant, but has had two major expansions to meet the population growth needs, and to improve the treatment process efficiency through the provision of secondary treatment of the liquid stream. The current expansion includes construction of additional solids contact tanks and secondary clarifiers. Future expansions include the construction of proposed additional trickling filters. New expansion structures are required to be designed for post-seismic operation after the 2475-year event design earthquake.

Jan 1, 2018

By Gerald T. Homce

Accidental contact of overhead electrical power lines by mobile equipment is a leading cause of occupational fatalities in the United States, accounting for 20% of on-the-job electrocutions. Overhead electrical power line proximity warning devices (PWDs) are intended to warn personnel if mobile equipment moves within some preselected minimum distance of an energized overhead electrical power line. Two commercially available PWDs were tested at the National Institute for Occupational Safety and Health?s (NIOSH) Pittsburgh Research Laboratory (PRL). The objective of the tests was to document performance capabilities and limitations for these PWDs by identifying factors that can influence their operation. The two PWDs evaluated in this research are the SIGALARM Model 210 marketed by Allied Safety Systems, LLC, and the ASE Model 2100 from Allied Safety Engineering. Both of these devices operate by measuring the electric field present around energized power lines. The PWDs were installed on a government-owned 22-st (20-mt) rough terrain crane. A purpose-built test site used for this research at PRL allowed operation of the crane near a variety of power line configurations operating at up to 25 kV. Most of the tests involved positioning the crane adjacent to one or more overhead power lines, adjusting sensitivities of the PWDs to alarm when the crane boom was approximately 20 ft (6.1 m) from the power lines, swinging the crane boom toward the lines under a wide variety of test conditions, and finally, for each unique set of test conditions, documenting the deviation from 20 ft (6.1 m) for actual alarm activation. Test results show that several factors can adversely affect PWD performance. PWD alarm accuracy generally deteriorated when operating with a boom position significantly different than that used for the device?s last sensitivity adjustment. Another factor that can affect PWD performance is configuration of the overhead power line(s) involved. Accuracy of alarm activa­tion distances was best for simple single-circuit installations, but degraded for multiple circuits on the same poles. This degradation was slightly greater for installations with different voltage levels and/or a combination of vertical and horizontal conductor arrangements. Performance also degraded for crane operation between two intersecting power line installations, especially for intersecting lines at different voltages. An additional aspect of power line configuration shown to influence PWD accuracy was phase sequence on the power line circuit(s). Specific phase con­ductor arrangements and combinations, particularly in multiple circuit installations, resulted in either improved or degraded accuracy.

Jan 1, 2008

By K R. Brentley

"Tshepong Mine, Harmony’s largest gold producing mine, is situated in the Free State portion of the Witwatersrand Basin, east of Odendaalsrus and north of Welkom, South Africa. The Basal reef is a narrow tabular conglomerate and is the main gold bearing ore body. The strata strikes mainly in a northsouth direction with an average dip of 22 degrees. Currently mining takes place at depths of between 1 690m and 2 150m below surface. The Basal reef unit consists of a conglomerate ranging between a few and 30cm in thickness. Some 80-90% of the gold occurs in the lower portion of the conglomerate. Directly above the conglomerate is a quartzite placer unit, the Basal quartzite, which is a clean, hard competent rock and varies in thickness between 50cm and 200cm. The Basal unit is overlain by the Khaki shale which can vary between 30cm and 500cm in width. It is weak and incompetent khaki coloured chloritic shale.A method of stoping, termed “undercut”, is practiced in order to remove the lower 15-20cm of the gold rich strata. The method entails removing this portion along with some 70-80cm of footwall host rock which is a strong competent quartzite. The hard competent quartzite overlying the conglomerate is left in-situ to form a competent hangingwall which can stabilize and prevent exposure of the weak Khakishale. This method of extraction was developed through trial and error and has been used reasonably successfully since its inception in the early 1960’s where the method was developed to extract the Basal reef at the Western Holdings Mines. Recently prospect drilling and a number of localised hangingwall failures indicated that the residual quartzite beam could be less than 60cm and in some instances as thin as 30cm in certain areas of the mine. The result of this is a less stable hangingwall which not only poses a safety risk to workers in these areas but also had the potential of locking up some 840 000 Tonnes of gold bearing ore. At the present gold price this amounts to revenue of approximately ZAR1.5 billion (U.S. $143 million).This paper discusses the method of “undercut stoping” and existing practices in place at Tshepong Mine. It also explores new initiatives such as the use of a simple freely-supported elastic beam solution to perform back analysis, on-site data capturing of beam thickness and support geometries in order to develop empirical design charts and numerical modelling to assist in the verification of the empirical design method."

Jan 1, 2015

By S. L. Weber, V. Castranova, D. E. Banks, J. K. H. Ma, Y. Rojanasakul, J. Y. C. Ma, M. Bhat

"The mechanism of bleomycin-induced pulmonary fibrosis is not ye: clear. Recent studies have shown that alveolar macrophages (AM) can be stimulated by bleomycin in vitro releasing inflammatory cytokines, suggesting that the interaction of bleomycin with AM is an important step in the drug-induced fibrotic process. Bleomycin is known to bind DNA and generate oxygen radicals through complexation with Fe2+ and oxygen. To provide,more insight into the cellular oxidative property of bleomycin, v.s have developed a fluoromicroscopic method using 2',7'-dichlorofluorescin diacetate (DCFHDA) as an oxidative fluorescence probe to study the deomycin-induced intracellular oxidation in rat AM and the inhibition of the oxida¬tion by taurine, a compound known to inhibit the bleomycin-induced fibrosis. Bleomycin at 5 to 20 ug/ml has a moderate stimulatory effect (1.87- to 2.66-fold) on the secretion of superoxide anion. A high concentration of bleomycin (20 ug/ml), however, inhibits cell response to zymosan-induced secretion of superoxide anion. At 4 ug/ml, bleomycin has no effect on cell membrane integrity or morphology but results in a significant increase in intracellular oxidation. This oxidative process is Fe2-,-dependent and is accompanied by an increase in intracellular calcium (35 nM). Both the intracellular oxidation and calcium rise induced by internalized bleomycin are inhibited by pretreatment of cells with varying concentrations of taurine (25, 125, and 187.5 uM). The inhibitory effect on intracellular oxidation .vas found to be 36, 57, and 60%, respectively. These results demonstrate a stimulation-inhibition relationship between bleomycin and taurine on re cellular oxidation at a subcytotoxic dose of bleomycin, suggesting that the oxidative effect of the intracellular bleomycin-Fe2 complex is important in the initiation of the fibrotic process. — Environ Health Perspect 102 (Suppl10):91-96 (1994) IntroductionThe pulmonary system is most susceptible to oxygen radical-induced diseases due to its constant exposure to the highest oxygen tension, and the potential encounters with oxidant gases such as ozone, nitrogen oxides, and toxic doses of dust particles. The lung is also a well-perfused organ and thereby vulnerable to the effect of circulating xenobiotics such as paraquat, and, bleomycin, which is known to cause pulmonary injuries (1). Alveolar macrophages (AM), which act as a means of defense by phagocytizing inhaled dust particles and microorganisms while increasing production of reactive oxidative species, have been shown to play an important role in mechanisms leading to oxidative lung injury and fibrosis (2-4)."

Dec 1, 1995

By H. Huang, R. N. Gow

"The reactivity of an enargite mineral electrode was investigated spectroelectrochemically under conditions typically found in alkaline sulfide leach solutions, with pH 11-13 and Na2S additions of 50 and 250 gL-1. A bulk enargite electrode was cycled between 0 and -1,000 mV for each set of solution conditions. Raman spectroscopy was used to determine and compare surface formations against species in mass-balanced EH-pH diagrams generated using STABCAL. Previously, it was determined that arsenic could be selectively leached under alkaline conditions at an average solution potential of -300mV, across the pH range 11-13. Operating under such conditions allowed for the selective leaching of arsenic with elemental sulfur formation. From several of the voltammograms obtained during this current testing, the formation of elemental sulfur appeared at increasingly reducing conditions with increasing sulfide concentration. At high concentrations, copper started to dissolve, possibly as a bisulfide complex, reducing the selectivity of the leach, unlike previous studies. However, the presence of the higher sulfide concentration is also anticipated to prevent passivation by consuming any surface formation of elemental sulfur. This study provides insight into the operating parameters of alkaline sulfide leaching in regards to the selectivity of arsenic leaching, as well as guidance for control of reagents and solution potential and, of course, the need for water treatment afterwards.IntroductionEnvironmental limitations on the pyrometallurgical processing of arsenic-bearing concentrates have forced operations to consider other solutions. Attempts to hydrometallurgically process enargite (Cu3AsS4) fall into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under basic conditions. The authors believe that the selective leaching of arsenic is more amenable because it produces a solid copper phase, preferably chalcocite (Cu2S) or covellite (CuS) that could then be processed using conventional methods already in place in the copper and gold industries. Potential leaching methods include alkaline sulfide leaching (Achimovicovica et al., 1999; Anderson and Twidwell, 2008a,b; Tongamp et al., 2009 and 2010), hypochlorite leaching (Vinals et al., 2003; Curreli et al., 2005; Mihaljovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and acid leaching (Gow et al., 2014b) with or without fine grinding to mechanically activate the enargite surface and increase normally slow leach reaction kinetics (Achimovicova et al., 1999; Balaz et al., 2000; Balaz and Achimovicova, 2006). In this study, the reactivity of enargite under alkaline sulfide leach conditions was examined."

Jan 1, 2015

By Stephen C. Tadolini, John P. McDonnell

"High-strength cable bolts have been used for ground support in underground coal mines for many years. Cable bolts are routinely used as secondary ground support in numerous longwall gateroad support applications, areas that possibly experience the most severe conditions in current underground coal mining. Additionally, when mining ground conditions deteriorate, engineers oftentimes recommend cable supports as a principal solution because of the established credibility for successful ground control. Nevertheless, there is still a reluctance to utilize non-tensioned cable supports as an effective primary roof support alternative.This paper provides historical and recently documented examples of non-tensioned cable supports utilized as an effective primary ground support method in a western U.S. underground coal mine, and it will continue the technical discussion between the differences of various degrees of tension in cable supports with respect to ground behavior and reactions.INTRODUCTIONResin-grouted cable supports are widely used to support difficult ground conditions throughout the world. Through the use of innovative applications and configurations they have proven to be a major paradigm shift in roof support and ground control technology in the U.S. (Tadolini and Koch, 1993; McDonnell et al., 1995; Tadolini and Gallagher, 1994; Tadolini and Trackemas, 1994)Today, the basic cable bolt support consists of a high-strength steel cable installed in bore holes that range in diameter from 25 to 50 mm (1 to 2 in) depending on the strand size and drilling equipment. Cables are offered in both bright and galvanized, for corrosion protection, and range in capacity from about 30 to 60 tons. An example of a resin-grouted cable bolt and the key components is shown in Figure 1. The steel cables are flexible and the support length is not limited by the height of the opening. Lengths of up to 10 m (32 ft) have been supported with high pattern densities when standing supports were not operationally feasible. The most common lengths are 3 to 5 m (10 to 16 ft). An important physical characteristic is that PC-strand has an ASTM minimum elongation requirement of 4%. For comparison purposes, the ASTM 432-08 Standard Specifications for Roof and Rock Bolts and Accessories specifies elongation requirements for traditional roof bolts are a minimum of 12% for grade 40, 9% for grade 60, and 8% for grade 75 materials, respectively. Traditional roof bolts can stretch and elongate twice the length that cable bolts can, which makes design considerations challenging."

Jan 1, 2010

By Verne S. Mutton, William A. Slivensky, Eric S. Weiss, Kenneth L. Cashdollar, Deepak R. Kohli

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory, cooperated with Tecrete Industries Pty. Ltd. and BHP Australia Coal in a research program to evaluate the strength characteristics and air leakage of four seal and two stopping designs for use in underground coal mines. A fundamental safety research area for NIOSH is to eliminate the occurrence of coal mine explosions or to mitigate their effects. One approach to achieve this goal is to develop new and innovative seal designs that provide increased explosion isolation protection for the mining personnel against ignitions that originate from within the gob or. other worked-out areas of the mine Full-scale seals and stoppings were constructed in the Experimental Mine at Lake Lynn Laboratory near Fairchance, Fayette County, PA. They were ail--leakage tested, then subjected to a series of explosions with average pressure pulses ranging from 25 to 500 kPa (3.5 to 72 psi). Instrumentation measured seal displacement and acceleration as a function of time, providing data to assist in the development of numerical models 1'01- future seal design. All three seals designed with Meshblock wire forlnwo~-k ant1 a lnonolithic shotcrete core withstood the first explosion test, which generated an avcr-age rnaximu~n pressure of - 140 kPa (-20 psi) while maintaining acceptable air leakage rates. These seals I-anged from 175 to 325 mm thick. They included a 2.7-m-high by 325-mm-thick seal that was tesled 27 hr after completion against this - 140-kPa explosion pressure, a special requirement of the test program. This seal survived explosions with pressure pulses up to 300 kPa (43 psi). The 2.3-m-high by 325-mm-thick Meshblock seal survived three explosion tests with overpressures up to 455 kPa (66 psi) and satisfied the air leakage criteria. A I ,200-mm-thick plug seal was constructed of two Gunmesh formwork walls in-filled with shotcrete and a 3,450-kPa (500-psi) strength Aquablend core. This plug seal survived three explosions with pressure pulses ranging 11-om 150 lo 430 kPa (-22 to 62.5 psi) with no measurable postexplosion air leakage. Two Gunmesh stoppings with thicknesses 01' 40 and 75 inln withstood explosion overpressures of 23 and 115 kPa, respectively. Anchoring all seal and stopping designs into the roof, ribs, and floor with steel "rootbolts" provided very effective boundary constraint that is critical to the performanceofstructures subject to explosion overpressures.

Jan 8, 1999

By D. McElhinney, J. Winfield, G. Buchan, B. Slaker, A. Iannacchione, T. Minoski, G. Rashed, M. Van Dyke, M. Murphy

"The National Institute for Occupational Safety and Health (NIOSH) has previously established pillar design guidelines for the underground stone mining industry. These guidelines were created from an empirical database of pillar observations and were largely drawn from shallow, flat-lying mining operations. Current trends forecast a great amount of underground stone mines developing under deeper cover, higher seam dips, and more frequent multiple-seam mining configurations than in the past. The complex loading conditions and limited experience in these environments presents a substantial increased risk of ground failure. To investigate these loading conditions, NIOSH has installed a pillar and roof monitoring system at an underground limestone mine in central Pennsylvania. The mine is operating in a seam with dips ranging from 13 to 18 degrees and overburdens ranging from 275 m (900 ft) to 425 m (1,400 ft). Instrumentation installed in an undeveloped pillar and in surrounding strata is currently measuring pillar and roof behavior in response to stress redistribution during excavation. Laser scans are being used to measure ground displacement and changes in conditions associated with local mining conditions and significant geological features. Initial stress measurements show a gradual increase in stress in response to mining, and stress changes that correspond with blasts. The seismic system is operational, with calibration events signaling on each of the 18 sensors. INTRODUCTION Improving mine-wide ground control stability can help reduce the potential for catastrophic failure of underground structures. The National Institute for Occupational Safety and Health (NIOSH) has conducted prior research in stone pillar design and has established fundamental pillar design guidelines for the underground stone mining industry, which resulted in the development of the S-Pillar program (Esterhuizen et al., 2011; Esterhuizen and Murphy, 2015). The data that constitute the S-Pillar program were derived from past mining experience that was almost exclusively drawn from shallow, flat-lying, single-level mining operations1. Stakeholder interactions with NIOSH researchers have indicated that increased numbers of underground stone operations are expected to mine under significantly deeper cover, with greater seam dips, and under multi-level operating conditions (Slaker and Murphy, 2016). The complex loading conditions and limited experience in these challenging environments present a substantial increased risk of ground failure. Inadequate pillar design in these new and challenging environments could result in catastrophic wide-area pillar collapses and an increased safety burden to miners working in the U.S. limestone mining industry. To develop design guidelines and prevent inadequate pillar designs for these challenging environments, NIOSH is currently conducting detailed pillar response investigations at case-study mine sites operating in challenging environments."

Jan 1, 2018

By G. Bulut, Ü. Yenial

"The use of recycled water in flotation has significant effects on flotation and selectivity because the recycled water contains many dissolved compounds and ions that alter the chemistry of the system. In this study, the effects of calcium, magnesium and sulfate, which are abundant components in recycled water, were investigated on galena, sphalerite and pyrite flotation using pure minerals and a complex sulfide ore by conducting bench-scale flotation, microflotation and zeta potential measurements. The bench-scale flotation tests indicated that higher recoveries of galena and sphalerite are obtained when water is recycled, due to higher concentrations of ions in recycled water. However, there was a critical ion concentration for galena recovery. The microflotation tests showed that galena recoveries at different pHs in recycled water are lower than in tap and distilled water. Pure sphalerite recoveries improved in recycled water in the bench-scale test with ore. Pure pyrite was depressed with recycled water as well. Zeta potentials became less negative with increased calcium and magnesium ion concentrations due to their adsorptions, and the presence of sulfate ions was seen to increase the negative charges of sphalerite and pyrite, conversely for galena. IntroductionWater is among the most important elements for mining and mineral processing. The distance to water sources is one of the major factors for mine site selection. The mining and mineral processing sector needs and consumes large quantities of water. In Chile in 2014, the copper mining sector alone consumed 12.7 m3/s fresh water for 1.189 tons of ore processing, and recycled 74 percent of the consumed water (Chilean Copper Commission, 2015). A plant that does not reuse or recycle any water will require 1.9 to 3.0 m3 of water per ton of ore processed (Gunson et al., 2012). Many stages of mineral processing, such as grinding, gravity concentration, dense medium separation, wet magnetic separation, flotation and hydrometallurgical operations, use large volumes of water (Schumann, Levay and Ametov, 2009).In mineral processing plants, the process water is recycled from the tailings dams, thickener overflows, and dewatering and filtration units. Wet concentration processes can require large quantities of water. Flotation, the most common process, typically takes place at 25 to 35 percent solids by mass. Most flotation plants practice at least some water reuse and recycled. Modern mines and mineral processing operations generally aim for zero water release (Levay, Smart and Skinner, 2001). In most cases, water quality has been found to affect flotation performance, and this interaction remains under investigation."

Jan 1, 2016

By Patrick J. Hannigan, Frank Rausche, Rozbeh B. Moghaddam

Large diameter open-end pipe piles are increasingly used as deep foundations to support heavy onshore and offshore structures. During the driving process, several factors such as subsurface conditions, hammer type, hammer efficiency, pile type, plug conditions, temporarily increased base resistance, and loss of shaft resistance have direct impact on the driveability of large diameter open-end pipe piles. In a uniform subsurface condition, the unit shaft resistance increases with depth. Consequently, more resistance is accumulated as piles penetrate to greater depths which results in higher driving resistance. However, according to the friction fatigue analysis, the greater the number of shearing cycles occurring on a soil segment along the pile shaft, the greater the reduction of its shear resistance. As a consequence, since upper soil layers are subjected to a greater number of blows than those at greater depths, they have a relatively lower resistance compared to what would be calculated with standard geotechnical analysis methods. As a result of this progressive and nonuniform loss of shaft resistance with driving, blowcounts tend to increase at a lower rate than expected from traditional analyses. This paper discusses one of the approaches to the driveability analysis with the geotechnical friction fatigue consideration. It also shows comparisons between predicted driveability obtained from wave equation analysis and field driving records. All analyses were performed for a 2.134 m (7.0 ft) diameter open-end pipe pile installed at a total depth of 192.90 m (554 ft). Two separate static resistance and wave equation analyses were completed for the case study presented in this paper: 1) Friction Fatigue analysis based on the recommendations of Alm and Hamre (2001), subsequently referred to as the FF model, and 2) Standard Driveability analysis based on soil set- up factors, hereafter referred to as the SD model in this paper. Results from analyses included the shaft resistance distributions compared to the result of the signal matching analyses determined from the pile dynamic measurement. Furthermore, predicted blowcounts were compared to observed blowcounts during the pile driving. The comparison analyses indicated a 54.4 percent resistance loss of the Static Resistance during Driving (SRD) due to the geotechnical friction fatigue corresponding to a 46 percent reduction in total resistance. The analyses also showed that average predicted blowcounts using the friction fatigue were 6.4 percent lower than measured blowcounts, whereas, the standard driveability approach showed 42.1 percent higher blowcounts compared to the blowcounts shown in the driving log values.

Jan 1, 2019

By Stephen Mansfield, Nathan West, El Khalil Seyed

In October 2017, a multi-bench failure occurred in the east wall of the Guelb Moghrein copper and gold mine in Mauritania. The failure extended 100 m (328 ft) vertically and horizontally and resulted in the sterilisation of ore, but no equipment or personnel were put in danger. The remediation plan successfully removed the failed material and the cutback resumed to a modified pit design, leaving ore reserves behind. In 2021 after completion of mining in another part of the pit, a plan was formulated to develop a narrow cutback behind the failed wall and recover the sterilised ore. Infill drilling defined a resource of approximately 2.9 Mtonne (3.2 Mton) of ore at 0.78% Cu and 0.67 g/t Au at a strip ratio of 5.5:1. The high strip ratio meant that it was necessary to mine thirteen benches of waste, or 156 m (512 ft) vertically, over a two-year period before reaching the first ore, with the cutback only being economically viable if all ore could be depleted at the end of the third year. The high economic risk of the project required a holistic approach to mitigate the risk of another wall failure, by addressing the following areas: 1. Pit Design: with help from an external Geotechnical Consultant, the pit design was optimised to include increased factors of safety, reduced stress points, lower overall slope angles and straight lined walls were replaced with curved walls. 2. Geotechnical Management: the site Geotechnical Superintendent worked closely with an external Geotechnical Consultant to better understand the structural geology. Slope monitoring was improved through an expanded network of prisms, regular in field inspections and the use of a slope monitoring radar. 3. Drill and Blast: new drill and blast designs were developed from first principles, consisting of production, wall control and presplit designs. Blast master polygons and bench development sequences were developed with consideration of the structural geology and the influence of the initiation designs. 4. Mine Operations: improving operational discipline was a critical factor that ensured the accurate execution of drill and blast designs and excavation to bench levels and pit limits. This holistic approach has enabled the safe development of the cutback down to the 936 RL (relative level), two benches below the point at which the previous wall failure occurred. Extraction of ore has occurred from the 960 RL, and due to faster than planned excavation rates, the cutback is expected to be completed ahead of schedule.

Jan 21, 2025

By Patricia Pride, Kurt Bettger, Jack Raymer

"INTRODUCTION The Jefferson Barracks Tunnel is in the final stages of design and is expected to go out to bid in the summer of 2016. The project is located in south St. Louis County along the west bank of the Mississippi River, about 13 km downstream of the St. Louis Gateway Arch. The project consists of a deep sanitary sewer tunnel, a deep pump station and several intakes. The intakes will divert sanitary flows into the tunnel and the tunnel will convey the flows by gravity to the Lemay No. 3 Pump Station, which will pump them up into the Lemay Waste Water Treatment Plant. The tunnel is about 5.4 km long and will be lined with 84-inch (2.1 m) fiberglass pipe. It drops at a gradient of 0.1 percent from south to north and will be bored through strong limestone using a hard-rock tunnel boring machine (TBM). The diameter of the TBM is anticipated to be about 3.4 m. The Owner’s original concept was for a relatively shallow tunnel so as to minimize construction and pumping costs. The preferred alignment ran close to the river, next to the existing force main, which was to be abandoned. Keeping the tunnel close to the force main would reduce the amount of shallow sewer work needed to connect the existing feeder sewers to the new tunnel. Several geotechnical investigations were performed, with shallowly focused geophysics and the borings all going exactly down the conceptual tunnel depth. Limestone bluffs run along the Missouri side of the river. These bluffs are pockmarked by sinkholes and riddled with karst. Large, well-known caves occur both north and south of the alignment. Karst features, including deep crevices and possible caves, were found in those early geotechnical investigations. Many of these features extended well below the level of the Mississippi River and would have been encountered by the tunnel. If a large crevice or cave were encountered, then the inflow of mud and water into the tunnel could have been large and possibly uncontrollable. Something had to be done to mitigate this situation. Pre-excavation grouting was considered, but the program would have been huge and extremely expensive. Using a closed-face TBM with bolted and gasketed lining was also considered, but that too was both risky and extremely expensive. The Owner could have abandoned the tunnel altogether and built a new force main, but that would have brought a whole new set of problems and was undesirable to the Owner. The last option was to move the tunnel away from the karst."

Jan 1, 2016

By Takeo Fujino, Nobuaki Sato, Junichi Hasegawa, Masato Nakazawa, Kohta Yamada

"Tantalum oxide thin films were deposited on quartz substrates by laser ablation of Ta2O5 target using Nd:YAG pulse laser. Deposition-was observed when a laser light energy higher than 200 mJ and its repetition rate higher than 3 Hz. A thin film of 0.1 µm thickness was obtained by the ablation using a laser light of 300 mJ and 6 Hz for 2 sec. The thickness of the film increased with increasing energy, repetition rate and irradiation time of laser. By the SEM observation, it was found that many island-like particles were deposited on quartz substrate forming a thin film. The obtained thin film, which was identified as ? Ta-O by X-ray diffraction, was oxidized to Ta2O5 by the heat treatment in air at I273 K for 3 h.IntroductionTransition metal oxides have a potential to show special characteristics in electrical, magnetic and/or optical properties. When such compounds are fabricated in the form of thin film, the special properties would be improved or new characters would appear in comparison with bulk materials. Tantalum penta-oxide is widely used as a capacitor since Ta2O5 shows high dielectric constants up to high temperatures. The tantalum solid capacitor has been fabricated by the electrical oxidation of sintered Ta metal cylinder followed by MnO2 film coating. However, further improvements, reduction and layered structure formation, are required for compacting the devices. The layered structure of thin films would be applicable for the above requirements. The formation ofTa2O5 film by low pressure CVD1), photo CVD2) and magnetron sputtering3l were reported. The laser ablation -method is one of the most convenient techniques for the deposition of thin films from their compounds, such as oxides. Formation of Ta2O5 film by pulse laser deposition (PLD) method using ArF excimer4), Nd:YAG (533nm)5) and TEA CO2 6 lasers was reported. In these PLD studies, ablation was carried out in relatively high oxygen pressures resulting in formation of Ta2O 5 film. In this paper, the deposition of tantalum oxide thin film by the laser ablation of Ta2O 5 using Nd:YAG pulse laser was examined at a viliety oxygen pressures ranging from 10-8 to 10 Torr. The morphology of the films was also investigated in relation with substrate temperature and oxygen pressure."

Jan 1, 2000

By Sevinc Yildirim, Cigdem Oruclus

"Metal-Porous Silicon (PS) based structures dipped in water show the direct hydrogen fuel cell behavior. The effect of the thickness of the cupper (Cu) film on the electrical properties of direct hydrogen fuel cell is studied by fabricating Cu/Porous Silicon/n-Silicon/Indium structures. PS samples were produced electrochemical etching of n-type single crystalline silicon with a resistivity of 1,25 Ocm and (111) orientation. The thin films of Cu with different thickness between 200 and 600 nm were deposited on PS surface by electron-beam technique. Investigation of the effect of Cu layer on the performance of the structure indicates that the performance parameters such as open circuit voltage (Voc) and short circuit current (Isc) strongly depend on the Cu layer thickness. It was observed that the divice with an 350 nm Cu layer exhibits the highest open circuit voltage (0,5 V), short circuit current (0,01 mA) and power density (10 W.m-2).IntroductionHydrogen is the most attractive and ultimate candidate for a future fuel and an energy carrier. Hydrogen is recognized as the environmentally desirable clean fuel of the future since it can be used directly in different types of hydrogen fuel cells [1]. In the past years, the rise in portable electronics requires the development of miniature fuel cells compatible with standard silicon micro fabrication technology. Most silicon micro-fuel cells have used the polyperfluo-rosulfonic acid membranes (Nafion R) as a proton exchange membranes (PEM) that is not really integrated with standard micro fabrication techniques [2-5]. The composite materials such as inorganicorganic hybrid materials (Nafion-silica, Nafion-borosiloxane etc) are next generation of proton conducting membrane [4-8]. But, fuel cells run on pure hydrogen gas, which can be produced with other energy resources. Hydrogen smallest atom and thus the H2 gas can leak easiliy. The application of hydrogen for power sources has been greatly restrained due to the lack of safe and convenient generation and storage methods.A kind of hydrogen fuel cells Metal-PS-Si structures used as an energy water directly. There is no need pure hydrogen. Cu-PS-Si Schottky-type fuel cells with as proton-conducting membrane and the thin-film cupper catalist and water as fuel, which are interesting for fabrication of lowcost miniature fuel cells. Generation of the open-circuit voltage and short-circuit current has been observed by Cu-PS-Si structure dipping in different hydrogen-containing solution."

Jan 1, 2014

By Maria Salazar-Villalpando, Todd H. Gardner

"Efficient utilization of CO2 can help to decrease global warming. Methane reforming using carbon dioxide has been of interest for many years, but recently that interest has experienced a rapid increase for both environmental and commercial reasons. The use of CO2 provides a source of clean oxygen, which eliminates the need for costly oxygen separation plants. The product of dry reforming is useful syn-gas, which can be used to generate electrical power in a SOFC or in the production of synthetic fuels (hydrocarbons and alcohols). Hexaaluminate catalysts prepared at NETL may represent a product that can be utilized for the conversion of CO2 to syn-gas. In this work, transition metals dispersed in barium hexaaluminate have shown to be promising new catalysts for dry methane reforming. In this investigation, a series of BaNixAl12-yO19-d catalysts with varying Ni content were prepared by co-precipitation followed by calcination at 1400°C. CO2 reduction by dry methane reforming was carried out to determine catalyst performance as a function of temperature and carbon formation was also quantified after the reforming tests. Results of catalysts characterization, dispersion and surface area, were correlated to catalytic performance.IntroductionEfficient utilization of CO2 can help to decrease global warming. Methane reforming using carbon dioxide has been of interest for many years, but recently that interest has experienced a rapid increase for both environmental and commercial reasons. The use of CO2 provides a source of clean oxygen, which eliminates the need for costly oxygen separation plants. The product of dry reforming is useful syn-gas, which can be used to generate electrical power in a SOFC or in the production of synthetic fuels (hydrocarbons and alcohols). The dry reforming reaction has been known for a long time. Recent publications have reported studies over several catalysts. For example, the CO2 reforming of CH4 over mesoporous nanocrystalline zirconium powders (ZrO2–3%M2Ox; M: Ce, La and K) at 700ºC have shown methane conversion up to 60% (1). Similarly, the effect of Ni content (1–12 wt%) on the surface and catalytic behavior of bimetallic PtNi catalysts supported on ZSM-5 for reforming of methane with CO2 has been studied and report shows a maximum conversion of 16% and catalyst deactivation was observed during the first hour of time on stream (2). In another report, (3) Ni/a-Al2O3 catalyst was tested for syn-gas generation at 750ºC. The maximum methane conversion was 25%."

Jan 1, 2008

By R. Priestner, R. F. Krause

Solid, cylindrical crystals of a iron have been fractured at 10°K by the simultaneous application of tension and torsion stresses. Thus, a complex distribution of normal (sN) and shear (ss) stresses existed in a cleavage plane at fracture. In every crystal the clearage-plane normal was inclined to the specimen axis, so that a unique point, M*, in the operative cleavage plane was defined where the quantities sn and s2 N + s2 S) were maximized. It is shown that the maxirrzum resolved normal stress on the cleavage plane at fracture decreased as the resolved shear stress in the cleavage plane at M* increased. Thus, a normal stress la?*! for fracture was not satisfied. A fracture law which takes shear stress into account. and which predicts that (s2 N +s2S) should be constant, is to be preferred. However, the data is best represented by a linear dependence of sN on sS, sS which 110 physical significance can be attached. It is suggested that the fracture-nucleating -mechanism is a short-range one. A critical stress law has not yet been unequivocally established for the propagation of cracks in metals. Measurements of the tensile fracture stresses of variously oriented zinc single crystals1 failed to establish the normal stress law expressed by In Eq. [1], sN is the fracture stress, P, resolved normal to the fracture plane, and 0 is the angle between the fracture -plane normal and the stress axis. Similarly, a comprehensive investigation failed to verify the normal stress law for the tensile fracture of a-iron single crystals.' However, a subsequent investigation,3 using iron from the same ingot, presented fracture data which obeyed the normal stress law. It has been shown previously4,5 that the Griffith criterion for fracture6 does not predict such a normal stress law. This result is of particular significance in considering the fracture of metals, such as zinc and iron, which may fail by cleavage. In these metals fracture propagates in a well-defined "cleavage" plane, whether or not an applied stress is normal to it. When the cleavage-plane normal deviates from the direction of application of a uniaxial stress, for example, the crack propagates under the combined action of normal (sN) and shear (ss) stresses. When the presence of a resolved shear stress in the crack plane is taken into account, the Griffith criterion is expressed by4

Jan 1, 1967

By Frank L. Nason

The complete statistics of zinc-ore production in the United States for 1916 are not yet available. The following figures are, therefore, only approximate. The total production of concentrates for this year, including New Jersey and Tennessee, amounts to 1,280,000 tons. Of this tonnage, five mines produced approximately 536,000 tons, or about 42 per cent. The remaining concentrates came mainly from the "Valley States," Missouri, Wisconsin, Kansas, Oklahoma, and Arkansas. The 1,280,000 tons of concentrates represent about 25,000,000 tons of crude or run-of-mine ore. Of the five mines producing the 42 per cent., the dimensions of three are approximately 25 by 1500 by 2000 ft. (7.6 by 457 by 610 m.) or more: Four of the five mines are undoubtedly veins in the common acceptance of the term. They are located in great vein systems. The mines of "Valley States" have not, so far, been classed as veins; simply as "secondary deposits." The origin of these secondary deposits has been a warmly debated subject. Many geologists contend that they are the results of leaching from overlying and adjacent rocks carrying but traces of zinc, these traces leached out and deposited in favorable places. If this theory is correct, deposition is strictly limited to shallow depths. No volume of ore comparable to that of "true fissure veins" is to be expeeted. Just what this means to the future of zinc mining in these States is here indicated. The total zinc-bearing areas of these States amount to about 9124 sq. miles (23,631 sq. km.). Assuming that 10 per cent. of this total will be more or less productive, there are 912 sq. miles (2,362 sq. km.) of "mineral" ground. The average depth of the operated mines is something like 100 ft. or less. In Bulletin 606, U. S. Geological Survey (1915), p. 202, Siebenthal makes the following statement: "The writer is informed by William Waugh, one of the drillers of the Stone City well, that cuttings from other wells which he drilled in the vicinity of Pittsburgh, Kan., have shown galena and sphalerite taken from a depth of 591 ft. (180.14 m.) and that the showing of ore at some places would be considered good enough to justify the sinking of a shaft had it been found in the Joplin district and at shallower depths." Leaving out of the question the prohibitive cost of such a shaft, there is

Jan 1, 1918