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By Mark A. Ackerson, Kenneth E. Hjelmstad

An ideal fire warning alarm system for underground mines would be low cost, convenient, fast, reliable, and able to warn all underground workers. Present warning systems, such as phones, messengers, and stench, fail one or more of these criteria. The U.S. Bureau of Mines may have devised the ideal system. The one way communication system employs a large loop antenna and transmitter to create a 630 hertz (Hz) electromagnetic field to send information through-the-earth to cap lamp battery mounted micro- receivers worn by underground miners. Field tests of prototype equipment in 1986 resulted in through-the- rock signal transmission of over 762 m (2500 ft). Subsequent hardware upgrades for more recent tests resulted in transmissions of over one mile. Recently developed receiver circuitry employs phase- locked-loop detection circuitry responsive only to a specific series of pulses of given time duration, that eliminates false alarms from electromagnetic noise emitted by mine equipment, power lines, or lightning. A multichannel system can relay standard messages to miners

By R. D. Leitch

In the course of another investigation4 during 1926 and 1927, samples of water collected from a few abandoned coal mines indicated that their drainage was usually lower in acidity than water from active mines in the same locality. In order to determine whether this condition might have a bearing on the advisability of sealing abandoned mines, a number of such mines were visited, samples of drainage were collected, and as much information as possible was obtained from officials of the mining companies and older residents of the district. The results of this work are the basis of the present report. ACKNOWLEDGMENTS The authors are indebted to E. W. Robertson, F. F. Spowart, J. H. Nagle, and W. D. Adams of the Northwest Mining & Exchange Co.; E. M. Fasset, Fred Lane, Wm. Humphreys, and Dr. T. A. Hutchison of Brockway, Pa.; C. W. Faulk of the Shawmut Mining Co.; James Hau of Kersey, Pa., and do others for information received; and to Dr, R. R. Sayers of the Bureau of Mines, under whose direction the work was conducted.

Jan 1, 1928

By R. Raines, S. P. Signer

Researchers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health installed 39instrumented, fully grouted bolts at six test sites in a trona mine retreat panel to study mine roof stability for the improvement of workplace safety. Variables at each test site included bolt spacing, bolt length, roof span, and location in the panel layout. At most test sites, two rows of instrumented bolts were installed, one in or near the intersection created during development and the other in or near the intersection created during second-pass mining. The most significant factor affecting bolt load was roof span. The highest loads were on the bolts installed in the intersections of the 6-m-wide entry. Mining-induced stress resulting from panel layout was the next most significant factor affecting bolt loading. Minor variations in bolt loading could be attributed to changes in bolt spacing and bolt length. Gas pressure release in the immediate roof contributed to some bolts showing compressional loading during gas bleed-off.

Part Two of this report is based upon six working memoranda prepared during the first half of 1972 at an early stage in our work for the Bureau of Mines. This work presents preliminary performance estimates of baseband voice and narrowband through-the-earth electromagnetic communications systems of principal interest to the Bureau for operational/ emergency mine communications applications. The calculations were prepared to obtain early indications of the feasibility and governing parameters of such communications systems. They are based on limited, but pertinent, coal mine electromagnetic noise data acquired to-date by Bureau of Mines contractors; on theoretical signal-attenuation characteristics for two transmitter antenna types of present interest to the Bureau and on semi-empirical models which describe the intelligibility of voice communications as a function of the frequency variations of the signal-to-noise ratio across the voiceband. This work examines the cases of baseband voice and narrowband communications for uplink and downlink transmissions, for frequencies up to 3kHz. Downlink transmissions are via a horizontal wire antenna, and uplink transmissions via a vertical-axis loop antenna, for typical mine depths of 300, 600, and 1000 feet. Representative coal-mine overburden conductivities of 10-2 mhos/meter (moderate and common) and 10-1 mhos/ meter (high) were used; the former figure for both voice and narrowband calculations and the latter for narrowband calculations only. Examples of high, moderate, and low, surface and subsurface, harmonic and broadband-impulsive noise conditions were taken from NBS and Westinghouse (WGL) mine noise data, together with examples of high- and low-levels of ELF atmospheric noise taken from M.I.T. Lincoln Laboratory data. The effects of simple voice spectrum shaping techniques on the intelligibility of through-the-earth voice communications are examined, and indexes of intelligibility more broadly based than signal-to-noise ratio are discussed. Finally, a means of overcoming the affects of 60 Hz noise and its harmonics which are the largest contributors to typical audio frequency in-mine noise, is suggested. These feasibility calculations are not intended to serve as definitive and complete treatments, but as a starting point: to establish first-order estimates of the magnitude and variability of transmitter power requirements under different noise, overburden conductivity, and mine depth conditions; to identify relationships, conditions, or frequencies that are likely to limit or enhance system performance; to reveal items requiring further investigation and data still required; and to suggest practical methods for optimizing system performance. These objectives were met by the calculations. Simple experiments to support these calculations can and should be carried out; together with more detailed investigations of specific modulation, coding, noise-suppression, voice-compression and signal-conditioning techniques, aimed at producing through-the-earth operational/emergency mine-communication systems that are not only effective, but practical and economically sound.

Jan 1, 1974

By S. L. Crouch

An important class of mining problems involves excavations in planar seam or vein-type deposits. In many instances it can be assumed that the seam is at 'infinite' depth in a homogeneous, isotropic or transversely isotropic, linearly elastic rock mss, and that the normal to the plane of the seam is a principal stress direction. Rational planning of excavations in such deposits requires a knowledge; of the stresses and displacements induced by complicated, irregular excavation geometries in the plane of the seam. This problem previously has been solved either numerically or by means of an electrical resistance network analog. Both of these methods effectively simulate the mined portions of the seam as a dislocation in an otherwise continuous mass, and determine the complete solution in terms of the stresses and displacements at the seam. In both cases, the plane of the seam is divided into a number - say, M x N - of squares, and the solution to the problem is determined in terms of the solution to an M x N system of equations. The numerical approach requires that these equations be solved explicitly, while the analog; solves them instantaneously with current analogous to stress and voltage to displacement. A purely numerical solution of practical problems can require a substantial amount of computer time, particularly in situations that demand some sort of sequential analysis, either due to successive mining or to nonlinear behavior of the seam material. This report describes a combined analog-digital computer system for solving problems that are impractical when either device is used separately. The digital computer and the analog are interfaced so that the digital computer can receive information from the analog via a switching matrix and an analog to digital converter, and can activate points of the analog via another switching matrix and a set of digital to analog converters. The resulting hybrid system can be used to simulate arbitrary "stress-strain" characteristics for any portion of the seam by an iterative procedure similar to the initial strain method used in nonlinear finite element analysis. Thus, the hybrid system combines the speed of analog computation with the decision-making capability of the digital computer: the analog instantaneously solves the set of equations, and the digital computer decides how the initial strains must be altered for the solution to be compatible with the prescribed "stress-strain" characteristics for the seam material. The hybrid computer system has many implications for rational planning of underground excavations, since it allows practically any type of inelastic seam behavior or artificial support characteristics to be simulated. Inelastic seam behavior, for example, might be due to either rock failure or to time-dependent deformation.

Jan 1, 1974

By V. A. Marple, K. L. Rubow, B. A. Olson

"A virtual impactor personal aerosol sampler (VIPAS) bas been developed for use in diesel-equipped mines to collect size-separated samples or diesel exhaust and mine dust particles in the respirable size range. This sampler consists or three stages: a 10-mm cyclone, a 0.8- µm cutpoint virtual impactor and two filter cassettes. The large non-respirable particles are removed in a 10-mm cyclone. The respirable particles from the cyclone pass through a 0.8- µm cutpoint virtual impactor with the particles larger than and smaller than 0.8 JI.ID (mine dust and diesel exhaust particles, respectively) collected on two 37-mm filter cassettes. The sampling How rate is 2 L/min so as to be compatible with the standard respirable dust sampler and personal sampling pumps. INTRODUCTIONThe mining industry has been increasing its use of diesel-powered equipment in underground mines, especially in coal mines. With this increased usage has come an increased concern regarding the health effects associated with inhaling diesel exhaust particles since they are in the respirable particulate size range. A Mine Safety and Health Administration (MSHA) advisory committee directed MSHA to develop a sampling protocol for diesel exhaust particles to assess worker exposure (MSHA, 1988). In addition, the National Institute for Occupational Safety and Health (NIOSH) has recommended that ""whole diesel exhaust be regarded as a potential occupational carcinogen as defined in the Cancer Policy of Occupational Safety and Health Administration"" (NIOSH, 1988).Past work, with cascade impactors in both the laboratory and in underground coal mine studies, has shown that the diesel exhaust particles are primarily in the less than 0.8 µm aerodynamic diameter size range whereas the coal dust particles are primarily greater than 0.8 µm (Marple et al., 1986; Cantrell, 1987; Rubow and Marple, 1988; Rubow et al., 1990a, b; Cantrell and Rubow, 1991). This work has been jointly performed by the University of Minnesota and Bureau of Mines researchers over the last 8 years. Typical particle size distributions for a diesel-equipped coal mine and an all electric coal mine are shown in Figure l. Note that the particles in the < 0.8-µ.m mode are the diesel exhaust particles (seen only in diesel-powered mines) and the particles in the > 0.8-µ.m mode are coal particles (seen in both the electric-powered and diesel-powered coal mines). Chemical mass balance analysis was also performed on these two size fractions to determine the degree of particle cross-contamination in the two modes. This analysis showed less than 10% cross-contamination, i.e., in coal mines Jess than 10% of the diesel exhaust particulate was collected in the coarse fraction and Jess than 10% of the mine dust was collected in the fine fraction (Cantrell, 1987; Rubow et al., 1990a)."

Dec 1, 1996

By L. M. Demers, D. C. Kuhn

"Kuhn, Douglas C., and Laurence M. Demers. Effect of surfactant on basal and silica-induced eicosanoid production by the alveolar macrophage. Am. J . Physiol. 269 (Lung Cell. Mol. Physiol. 13): L165-Ll 70, 1995.-Infiammation and fibrosis subsequent to the inhalation of certain mineral dust particles has been suggested to result from the activation of eicosanoid synthesis by the alveolar macrophage (AM). To determine if surfactant modifies dust-induced generation of eicosanoids by the AM, we evaluated the effect of the surfactant lipid dipalmitoyl lecithin (DPL) on the production of eicosanoids by rat AM exposed to respirable silica dust in vitro. During the first 24-h exposure period, DPL alone significantly increased basal production of eicosanoids but completely inhibited silica-induced thromboxane A2 synthesis. In contrast, leukotriene B4 (LTB4 ) production was only partially reduced by DPL. During a second 24-h exposure period, LTB4 production in response to the highest dose of silica remained significantly elevated in the presence of DPL. Similar results were obtained when the surfactant preparation Survanta was evaluated. These results suggest that 1 ) DPL and Survanta independently activate AM eicosanoid production, 2) DPL and Survanta modulate the response of the AM to silica dust, and 3) L TB4 may be the most important eicosanoid mediator of the long-term effects of silica dust exposure on lung pathophysiology. THE OXYGENATED METABOLITES of arachidonic acid (AA) (here collectively termed eicosanoids) have been implicated as important regulators of lung physiology and are thought to be involved in pathophysiological sequelae such as acute respiratory distress syndrome, asthma, and the pulmonary complications of sepsis (20). This role is manifested through both direct effects on lung physiology as well as through an indirect modulatory effect on the release of other mediators of lung injury, in particular profibrotic cytokines such as the interleukins and tumor necrosis factor (15). Recently, exaggerated eicosanoid production by both the alveolar macrophage (AM) and the type II epithelial cell has been demonstrated to result from the exposure of these cells to several particulates, including crystalline silica (quartz) dust (5, 9, 17). These observations have led to the suggestion that eicosanoids play a major role in the etiology of pneumoconioses.Another secretory component of the pulmonary environment, surfactant, has been shown to modulate crucial AM functions, such as bactericidal activity and the recruitment of circulating immune cells (25). Indeed, an important feature of the lung's reaction to inhaled mineral dust is an increase in surfactant production, perhaps as a compensatory or protective response (1, 16). In addition, the alteration of the surface properties of mineral dust by surfactant or its components has been shown to influence the biochemical response of the AM to the dust, perhaps by altering the surface charge of the dust particle (11, 29, 32). And recently, Wallace et al. (28) have shown that the coating of mineral dust with surfactant, and its subsequent removal by lysosomal phospholipase, unmasks differences in dust cytotoxicity that are not apparent when AM are exposed to uncoated dust. Thus it appears that the inclusion of surfactant in in vitro exposure studies may be important in evaluating both the absolute levels of eicosanoid production by the normal and dust-exposed AM and the temporal relationship between dust exposure and the production of inflammatory mediators by the AM. Therefore, we characterized the effects of the surfactants dipalmitoyl lecithin (DPL; the primary lipid component of natural surfactant) and Survanta (a commercially available surfactant derived from bovine lung) on basal and silica-induced AM eicosanoid production during two 24-h periods after exposure to dust particles to both allow the enzymatic removal of surfactant from the particle surface and evaluate the k"

Dec 1, 1996

By Steven J. Page, John A. Organiscak

Laboratory crushing experiments were conducted on a range of low- to high-volatile bituminous coals to investigate the various factors influencing airborne respirable dust (ARD) generation. This research was conducted to identify the principles of ARD liberation from the coal product. Five U.S. bituminous coals were uniformly prepared and processed through a double roll crusher located in a low-velocity wind tunnel. Experimental factors studied included inherent coal seam constituents, coal grind ability, specific energy of crushing, product size characteristics, dust cloud electrostatic field, and specific ARD generated. The results of this investigation indicate that a combination of several factors are associated with ARD generation. One factor is the effect of coal rank, described by the inherent moist fuel ratio, on the product size characteristics, defined by Schuhmann size function parameters. Another key factor is the effect of air dry loss(ADL) moisture in the coal seam on the breakage-induced electrostatic field of airborne dust. The effect of these factors is that different percentages of <10-m coal particles are dispersed as ARD. A discussion of electrostatic field principles, coal ADL, and its effect on ARD generation is presented.

Jan 10, 1998

By Lance R. Barron

Over the past decade, the U.S. Bureau of Mines (USBM) has studied longwall gate road stability at four mines in the Book Cliffs and Wasatch Plateau Coalfields of Utah. These operations are characterized by multiple-seam mining, abruptly varying cover depths to 914 m (3;000 ft), and massive rigid, sandstone units in the main roof or floor. Such conditions encourage severe bumping, roof instability, and occasional floor heave problems.&apos; Various gate road configurations have been employed to alleviate&apos; these problems. Although the mines have comparable basic conditions, the lithologies and qualities of the immediate roof, floor; and seam ate different in each mine and often vary in a single mine. Gate road systems that mitigate hazards in one mine may prove inappropriate in another or for different areas of the same mine. This report relates the geology of the coalfields; describes the location, geologic setting, specific mining conditions, operating history, and the USBM field study and results or conclusions for each mine; summarizes the relative performance of the gate road systems; and emphasizes the need for site-specific geotechnical data to evaluate gate road conditions and performance.

Jan 1, 1994

By Lance R. Barron

The U.S. Bureau of Mines (USBM) conducted ground pressure analysis of a wide abutment-type chain pillar in a two-entry gate road of a Western U.S. coal mine with an extremely weak immediate roof. About 15 m of fragile, low-strength mudstone lies between the seam and the lowest competent roof member. Three-and two-entry gate road designs with several pillar sizes and various secondary support systems have been employed to improve tailgate-entry stability, with varying results. This report discusses gate road layout and performance and secondary support effectiveness. The results of the pillar pressure study are compared to pillar loading predicted by a widely used pillar design method and to similar studies in other mines. A stability evaluation of the most recent longwall headgate, using the USBM Analysis of Longwall Pillar Stability (ALPS) method, indicates marginal stability in first-panel mining and instability in second-panel mining. The ALPS method and the USBM Coal Mine Roof Rating system are used to evaluate tailgate-mining stability of the previous gate roads and to determine pillar and entry width and top coal thickness criteria for tailgate stability in future panels.

Jan 1, 2010

By P. M. Ambrose, C. Travis Anderson, Cresap Moss, R. S. Dean

"MANGANESE METALMethods of PreparationMethods of preparing the manganese metal that has been used in chemical and metallurgical investigations have passed through a cycle. Most of the investigations made before the turn of the century used Moissan's pyrophoric manganese. 5/ This material was made by electrolysis into a mercury cathode and distillation in vacuo. It was essentially a pure material, and investigations in which it was employed (with proper precautions against oxida¬tion) led to accurate results concerning the intrinsic behavior of metallic manganese.An early investigation of the properties of ""Manganese-by-Mercury"" was made by M. Guntz. 6/ He prepared manganese by electrolysis of a concentrated MnCl2 solution with a mercury cathode. The manganese amalgam was pressed through chamois and distilled in vacuo (2 to 3 cm. of mercury) at 200°0., slowly rising to 250°0. Guntz recognized especially the decreased reactivity of manganese with increased temperature of mercury distillation. The most careful and com¬prehensive study of manganese made by this method is that of Kuh 7/ whose work unfortunately was never published in an accessible journal.Royce and Kahlenberg 8/ studied the electrode potential of manganese made by this method."

Nov 1, 1939

By A. C. Smith

The U.S. Bureau of Mines conducted a study to evaluate the effect of underground mining conditions on the activation of automatic sprinkler heads. Sprinklers were exposed to liquid fuel fires in a rectangular tunnel at airflows of 0, 45, 90, 150, and 250 m/min to determine the effect of ventilation and fire size on the time to activation. As the airflows were increased, the time to activate the sprinklers for a given fire size increased. Also, as the fire size increased, the activation time decreased. Temperature profiles of the tunnel showed that the maximum temperature near the roof was shifted downstream as the airflow increased. Experiments to determine the effect of rated activation temperature and response time index (RTI) value on activation time showed that the time to activate increased with increasing activation temperature, and decreased with decreasing RTI value. Exposure to the mine environment showed little effect on the activation times in large-scale experiments, and no significant effect in laboratory experiments. The results showed that airflow can have a significant effect on the activation times of automatic sprinklers. This needs to be considered in the design of effective sprinkler suppression systems for ventilated areas.

Jan 1, 2010

By Richard C. Barth

Fourteen field plots were established at active coal mines in the Northern Great Plains. A wedge was cut into spoil and backfilled with soil; soil depth ranged from 0 to 152 cm over a linear distance of 15 m. Perennial grasses were planted in each plot, and production was measured from 1978 to 1981. Based on spoil traits and biomass response patterns, plots were grouped into four types. Spoil for Type I plots was near neutral, slightly saline, nonsodic, and clay loam in texture. Perennial grasses reached maximum production with approximately 50 cm of soil depth. Spoil for Type II plots was characterized as sodic and fine textured; soil-depth requirements averaged 83 cm for maximum production. Spoil for Type III plots was characterized as strongly acid, and production increased throughout the soil depth range tested. Spoil for Type IV plots was similar to soil in chemical and physical traits; there was no production response to soil depth. Soil depth requirements were also dependent upon precipitation and species. In general, soil-depth requirements decreased in dry years and with use of introduced species. An appendix contains data evaluations on an individual plot basis.

Jan 1, 1982

By David E. Siskind

The U.S. Bureau of Mines and the State of Indiana cooperated with AMAX Coal Co. and its consultants to determine the effects of coal mine overburden blasting on nearby pipelines. Five pressurized 76-m pipeline sections were installed on the Minnehaha Mine highwall near Sullivan, IN, for testing to failure. Four 17-to 51-cm-diameter welded steel pipes and one 22-cm PVC pipe were monitored for vibration, strain, and pressure for a period of 6 months while production blasting advanced up to the test pipeline field. In contrast to previous studies of small-scale, close-in blasting for construction, these tests involved overburden blasts of up to 950 kg per delay in 31-cm blastholes. Analyses found low pipe responses, strains, and calculated stresses from even large blasts. Ground vibrations of 120 to 250 mm/s produced worst case strains that were about 25 pct of the strains resulting from normal pipeline operations and calculated stresses of only about 10 to 18 pct of the ultimate tensile strength. No pressurization failures or permanent strains occurred even at vibration amplitudes of 600 mm/s.

Jan 1, 2010

By N. Greninger

The Bureau of Mines examined the possibility of a seasonal variation of respirable dust concentration in U.S. coal mines. The first step was to review company and MSHA-inspector dust samples that had been collected during the past several years in 14 selected mines for compliance purposes. Results indicated severe scatter in data; most standard deviations of the dust concentrations measured in winter and summer months were comparable in magnitude with the mean values of dust concentrations for the seasons. Therefore, a detailed statistical analysis was conducted. At the 90% confidence level, the company samples of three mines had winter means 0.15 to 0.54 mg/m3 higher than the summer means; six mines had negligible seasonal variations; and five mines had winter means that ranged from higher to lower than the summer means. Inspector data, however, were too sparse for analysis. In view of both the low frequency of occurrence of a seasonal effect and its wide scatter in several of the mines, the study was ended with the conclusion that seasonal varia-tion in respirable dust levels, in general, is an insignificant factor.

Jan 1, 1986

By Alan R. Buehler

The Bureau of Mines conducted a mineral investigation of the 10,500-hectare Cache Peak study area in 1992; the area had been proposed as wilderness. Bureau personnel examined and sampled prospect workings; 14 rock and 20 placer samples were taken during the investigation. The study area is centered about 40 km south-southeast of Burley. Idaho, in the Sawtooth National Forest. There were seven mining claims located inside the study area, and one additional historical mining claim location. Gold, silver, copper, lead, zinc: Possible resource, poor exposure precludes estimate. Marble: Several million tonnes may be suitable for a variety of uses; markets too distant to favor mining. Sand and Gravel: Several million m3, but markets and transportation costs do not favor mining. Quartzite: Several million tonnes may be suitable for metallurgical purposes; however, markets are too limited to mine. Slabs have been quarried at three localities adjacent to the study area, for decorative stone. Production: In 1979, two tonnes of ore were produced and a plan of operations was submitted calling for approximately 5 km of access road for the Last Chance mine. Decorative stone production was not recorded.

Jan 1, 1993

By John A. Johnson

"INTRODUCTION The use of wet drilling with adequate ventilation has largely controlled production of dust in drilling rock; however, in some operations, such as shaft sinking and modern tunnel driving, when each of a number of drills is operating in a small cross-sectional area, it is at times difficult to ventilate well enough to keep the dust concentration within desired limits.Some chemical compounds, known as wetting agents, when added to water in small quantities reduce the interfacial tension and make it possible for the solution to wet dust particles more effectively than water alone.This report presents results of tests on the effectiveness of two wetting solutions in reducing the amount of dust produced by wet drilling in basalt.ACKNOWLEDGMENTSThe tests were conducted the Bureau's Mount 'Weather Testing Adit,Mount Weather, The author acknowledges the assistance and cooperation of Wing G. Agnew, superintendent; Marvin M. Revelle, mining-engineering aide; and the rest of the crew at Mount Weather in conducting the tests. C. W. Owings, mining engineer, Safety Division, assisted in conducting some of the first tests and gavel valuable advice and guidance throughout the work and in preparing this report."

Jan 1, 1943

By Jos. R. Guiteras

This paper describes the pumping operations at the Ajax, Cresson, and Vindicator dines in the Cripple Creek mining district of Colorado during the summer of 1936. At that time the three mines wore pumping 6,500 gallons of water per minute into the Roosevelt drainage tunnel. Cripple Creek is the most important gold district in the State; it has yielded gold valued at over $365,000,000. The mines engaged in pumping are among the largest producing properties in the district. ACKNOWLEDGMENTS The author wishes to acknowledge the friendly cooperation of mine officials at the properties visited. At the. Ajax mine information was courteously given by Clayton Kissel, mine superintendent, and his staff; R. Y. Roby contributed the drawings. For information on the Cresson mine, thanks are expressed to Al H. Bebee, mine superintendent, and his staff, especially to Guy Rorabaugh, master mechanic, and to engineer Carlton. At the Vindicator mine, J. S. Anderson; mine superintendent, and Robert Welch, master mechanic, assisted; the latter furnished most of the information about that mine. Acknowledgment is also made of the cooperation of M. H. Salsbury, engineer at the Portland mine, who supplied technical data on the Roosevelt drainage tunnel.

Jan 1, 1937

By Earl L. Hastings

Although the principal market for diatomite in the United States is in the East,4 production of the material is presently restricted to the West, because the deposits are larger, mining costs are cheaper, and the quality of product is better than that obtained from other domestic deposits. However, Tallahatta diatomite, occurring in Choctaw and Clarke Counties, Ala., has a freight rate advantage, which should encourage competition for those market that are now being supplied with the purer diatomites from the western deposits. For this reason, diatomite occurrences in the Tallahatta formation were examined by the Bureau of Mines and physical properties of samples from the deposit were determined to obtain additional data for use by any potential producer who wished to evaluate the material for its commercial possibilities. In 1894 K. M. Cunningham5 found that the buhrstone formation (now known as the Tallahatta formation) contained "siliceous shells of marine diatoms, radiolaria and foraminifera, thus being rather of the nature of tripoli or diatomaceous earth than of a true clay." Cooke6 and Semmes7 also reported the Tallahatta formation to be composed principally of diatomaceous earth with accompanying beds of sand, clay, and sandstone.

Jan 1, 1963

By S. P. Sandoval

Several researchers have shown that the surface of chalcopyrite becomes hydrophobic under oxidizing conditions. Because dissolution of copper from chalcopyrite in dump leaching occurs under oxidizing conditions, the U.S. Bureau of Mines studied the effect of surfactants on chalcopyrite leaching under dump chemical conditions. Surfactants were selected for study because they can lower interfacial tension. The tests were conducted in shaking water baths using 250-mL Erlenmeyer flasks in statistical experimental design formats. The addition of nonionic surfactants increased copper extraction in the fernc sulfate leaching of chalcopyrite when sufficient Fe3+ was present. A positive interaction between Fe3l+ concentration and surfactant concentration was demonstrated. Copper concentration in the leachhing solutions was increased by as much as 100 pct at 25° and 50° C by adding nonionic surfactants. ionic surfactants decreased leaching. The structure of the nonionic surfactants and their hydrophile-lipophile balance (HLB) influenced surfactant performance. The branched hydrophile of an ethoxypolyol was beneficial to surfactant performance. The ethoxypolyol was the superior surfactant at 25° C, but became unstable at 50° C. Four surfactants, an ethoxyalchohol and three block copolymers, performed best at 50° C.

Jan 1, 1990