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By I. B. Schalamuk, R. E. de Barrio, M. J. Pons, M. B. Franchini, L. Meinert

"Several Fe, Fe-Cu, and Cu-Ag prospects hosted by Mesozoic carbonate-rich sedimentary rocks that were intruded by diorite stocks define an approximately 20 × 200 km belt along the Andes Cordillera of southwest Mendoza province, Argentina (34°-36°S). This belt includes the Hierro Indio and Vegas Peladas Fe skarns, Las Choicas, and several other Cu-(Ag) prospects.The main features of the Fe skarns include: association with mantle-derived middle Miocene (~15-11 Ma) diorite stocks and sills; widespread alteration including epidote ± amphibole ± magnetite endoskarns, and zoned garnet (Grs0-66 Adr32.5-100) ± magnetite ± pyroxene (Di24-50 Jo2-9 Hd74-41) exoskarns formed from oxidized, saline, high-temperature brines (530º-660ºC; 60-70 wt.% NaCl equiv.); and magnetite-hematite orebodies associated with quartz ± epidote ± calcite ± actinolite formed at lower temperatures (290º-436ºC) from saline fluids (32-50 wt.% NaCl equiv.) of magmatic origin.West of the Fe skarn belt, the Valle Hermoso district covers more than 300 km2 and hosts several poorly known Cu-(Ag) prospects (estimated 30 Mt with 1.5% Cu and 20 g/t Ag). These prospects share many characteristics with the iron oxide copper-gold-type systems and manto-type Cu deposits of northern and central Chile. One of the prospects (Las Choicas) is located at the apex of a regional 015°-trending anticline, along the contact of stratified calcareous sandstone and limestone (Neocallovian-Oxfordian) with a diorite pluton. This pluton has positive Ta and Nb anomalies (on normalized diagrams) and a high Ti content, features uncommon in Miocene diorites associated with Fe skarns and of magmas derived from sub-arc mantle sources. Alteration at Las Choicas includes early widespread chlorite + calcite ± albite ± scapolite ± ilmenite or titanite ± apatite, and local actinolite ± hematite ± biotite alteration of diorite and sedimentary rocks along contacts. Later Cu mineralization (1%-10% Cu) is associated with calcite ± albite ± quartz alteration in fractures, vein networks, and crackle breccias. Mineralization is zoned from bornite ± chalcopyrite ± millerite with Zn, As, Mo, Ag, and U anomalies in the main orebody, through chalcopyrite-rich breccias with Zn anomalies, and chalcopyrite ± tetrahedrite vein networks with Sb, As, Ag, and Zn anomalies in the uppermost zone, to a Cu-depleted pyrite-rich envelope with Co anomalies, and finally to late, barren calcite veins in distal zones."

Jan 1, 2007

By V. I. Lakshmanan, R. Roy

"Zinc is the fourth most widely used metal in the world after iron, aluminum and copper. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing the steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Process Research ORTECH Inc. has developed an efficient energy-saving sustainable technology for the recovery of zinc from secondary sources such as galvanized steel scrap, dross, dusts etc. The process consists of treating the zinc containing scrap in an alkaline solution to remove the zinc and thereby producing a zinc free steel scrap for recycle. The zinc containing leach liquor is subjected to a solvent extraction process to recover value added zinc oxide as the final product. In this paper, important industrial processes for the recycling of zinc including the PRO process will be discussed. BACKGROUNDZinc is the fourth most widely used metal in the world after iron, aluminum and copper. Global refined zinc output increased by 2.7 per cent to 13.16 million tonnes in 2011 and is expected to increase by an additional 2.4 per cent to 13.48 million tonnes in 2012 [1]. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Other major usages of zinc are in the production of brass and bronze, die casting and zinc-air batteries. The additional demand for zinc could come from its addition to fertilizers to increase crop yield.While the demand for zinc is increasing, many mines are scheduled to close in near future after being depleted of ore. The mines set to close between now and 2015 are Teck Resources’ Red Dog Mine in Alaska, Minmetals’ Century Mine in Australia and Vedanta Resource’s Skorpion Mine in Namibia [1]. The depletion of resources due to continued use and exploitation is becoming a great concern for the zinc industry. As a result, the sustainability of natural resources for continued societal care has become extremely important. Resource conservation and recovery by recycling with minimal environmental impact is a key element for sustainable development. In this paper, important industrial processes for the recycling of zinc including the PRO process are presented."

Jan 1, 2012

By M. F. Almeida

"Due to the randomness of all factors influencing the sintering operation, a two-stepped procedure is proposed to find the best way of using stocked fines at a plant producing Fe-Mn alloys for the steelmaking industry. The approach is based on the following: (1) predict the result of the sintering operation by establishing the best multilinear regression model using some of the characteristics of the loaded material; and (2) find the best solution under a minimizing cost criteria by solving a linear optimization problem using the regression equation plus constraints on the feed and product. IntroductionSome tests carried out using 20% to 30% of sinter in the material loaded into a 60 000 KVA Tysland-Hole electric furnace producing Fe-Mn alloys for the steelmaking industry indicated: (1) a meaningful decrease in the off-gas temperature and, consequently, a better energy use due to the material higher porosity; (2) more uniform heat distribution as a consequence of the electrode reaction zone enlargement; (3) an improved furnace control resulting in a smoother operation; and (4) a decrease in gas production facilitating the off-gas treatment. For some years, this plant used only the coarse fraction of the Mn ores, thus stocking all the received and own-generated fine particles. In view of the mentioned results, a strategy for increasing the use of stocked fines was formulated, including a step where it was necessary to decide which components and respective quantities should be used in the blends to be sintered (Almeida, 1984).It is well known that several factors affect productivity and energy consumption in sinter production, also influencing the product quality. Raw materials characteristics, namely chemical and size composition, affect permeability to gases and may or may not allow a deeper bed. In general, finer ores decrease permeability, increasing electricity consumption by fans, but due to their higher specific surface area, react more completely with other components in the mixture. For coke granulometry, a compromise must be obtained in order not to burn it too quickly nor to widen the flame front, therefore decreasing productivity. Decreasing coke in the blend also acts in sinter bonding, decreasing its consistency and increasing crushing and return fines. Moisture addition also influences components mixing, pre-agglomeration, bed permeability and, consequently, sintering productivity. Therefore, optimum conditions must be established for both a given sintering plant and the components in the feed (Dawson, 1993)."

Jan 1, 1998

By H. Henao, E. Kohnenkamp, L. Rojas

The slags generated in the copper conversion process are mainly composed of Cu2O-Fe2O3-SiO2 with the compounds CaO and Al2O3 in concentrations up to 10 wt%. The present work contributes to the knowledge of the conversion process, generating experimental data for the diagrams of phases Cu2O-Fe2O3- SiO2-Al2O3 and Cu2O-Fe2O3-SiO2-CaO. The experiments were carried out in a tubular furnace at temperatures of 1150°C and 1200°C under a condition of saturation with tridymite. Once the equilibrium was reached, the samples were fast quenched in water. The phases in the samples were observed in a Scanning Electron Microscope (SEM) and the elemental composition of the phases analyzed by means of Energy-dispersive X-ray spectroscopy (EDS) detectors. The addition of Al2O3 and CaO into the Cu2O-Fe2O3- SiO2 system resulted in an appreciable displacement of the liquidus lines, corresponding to an expansion of the liquid in the tridymite primary phase field. INTRODUCTION The conversion process of copper consists of oxidizing Fe and S present in mattes with 60 to 65wt% Cu (up to 16wt% Fe). This process is separated into two stages: 1- Slag blowing: Fe is oxidized, the addition of a flux such as SiO2 (silica) forms a second liquid phase called slag, this phase is removed from the furnace; 2-Copper blowing: in this stage, the matte with low concentration of Fe (<1% w/w) is again oxidized to remove S as SO2 in the exhaust gases. The product of these two processes is the formation of Copper Blister (> 98wt% Cu) (Schlesinger et al., 2011). Unlike the aforementioned conventional processes, in most Chilean smelters, conversion Peirce- Smith Furnaces are loaded with high copper matte (70–75wt% Cu) (Henao & Moyano, 2016). Due to the low concentration of iron in these matte (up to 5wt%), it is considered that separating the conversion process in two stages is neither operational nor environmentally convenient. Therefore, the process is carried out in a single stage (Pradena et al., 2006), generating a slag phase with a high percentage of Cu2O (wt%Cu>40).

Jan 1, 2019

By E. Pallumbo, N. Szwedska, R. Asselin

"This paper highlights the results of collaboration between geology, mining and mineral processing teams during the restart of the North American Lithium Project, located near La Corne, Quebec, Canada. This collaboration was central in ensuring a cross discipline harmonization of design parameters and key inputs, all of which allowed for the development of an optimized life of mine plan suited to the particular needs of the operation.INTRODUCTION In July 2016, North American Lithium Inc. (NAL) began the process of restarting operations at the former Quebec Lithium Mine, located in the municipality of La Corne, Quebec, Canada. The North American Lithium Project (the Project) as it is known today, is the latest chapter in the history of this property. In order to provide a robust foundation for the project, multidisciplinary collaboration was instituted between the geology, mining and metallurgy teams. Despite the intrinsic link between these departments, in many instances their work is completed separate from one another; in silos. This collaboration highlighted specific drivers in the mining value chain that could be exploited to ensure that a saleable product could be produced effectively. This paper explores some of the concepts and strategies that were developed during the feasibility study that supported the project restart (excerpts from the study technical report have been used throughout this paper). PROJECT HISTORY In 1942, prospectors identified the presence of numerous spodumene-bearing pegmatite dykes on the Property. This led to additional interest and exploration drilling campaigns. In 1955, Quebec Lithium Corp. (QLC), who had acquired the property, began construction of an underground mine with mill facilities located on the surface. Operations began the following year at a production rate of 1,100 tonnes per day. A historical cross-section view of the underground mine is shown in Figure 1. In 1959, QLC began the construction of an on-site lithium refinery to produce lithium hydroxide. The refinery was finally operational by 1963. Mining and processing operations continued until 1966 when activities were halted due to a labour dispute. The property was sold and a few years later attempts to resume production were unsuccessful. Property ownership changed several times again until being acquired by Cambior in 1987. In the early 1990’s the existing mine and mill facilities were sold and the mine site rehabilitated"

Jan 1, 2019

By W. C. Risley

IN the year 1933, workings at the No. 12 colliery, New Waterford, of the Dominion Coal Company, Limited, had advanced to a point where additional ventilation would soon be required. Furthermore, development of the mine was being .made to practically double the output of coal. Consequently, authorization was given to sink a shaft to the workings. The location selected is on the west side of the mine, about one and a half miles from the slope mouth and on the Low Point shore, some 250 feet from high-water mark. The cliff at this point is 40 feet high, with the land rising on a slope of about 5 per cent to the shaft. Figure 1 shows the location with reference to the colliery workings. The strata through which the shaft was to be sunk were pretty well known from diamond-drill borings previously made, and it was believed that water would be encountered to a depth of at least 250 feet to 300 feet. It was planned, therefore, to seal-off the water by the pumping of cement grout under high pressure. This method was considered to be the most economical means of handling the water during sinking, and would also result in a permanently dry shaft. Figure 2 shows a cross-section of the strata. The permanent shaft hoist and fan were to be electrically driven, which would necessitate the construction of a transmission line between the colliery and the shaft; therefore, it was arranged that the sinking equipment would have electric drive. As all equipment, materials used in construction, and supplies were to be hauled by truck, a roadway 1,800 feet long was required from the main highway to the site, and as heavy loads would be hauled during the fall, winter, and succeeding spring, this road was ballasted with 18 inches of clinkered material obtained from a burned culm bank one and a half miles distant. Actual field work was begun by the Company&apos;s own forces early in October. Work preparatory to sinking-in addition to the roadway and trans-mission line-included the construction of the reinforced-concrete shaft collar and fan drift connection; the permanent timber headframe (which was to be used also as the sinking headframe); the permanent reinforced-concrete building to house the shaft hoist and fan drive; and the erection of temporary buildings and installation of all equipment for sinking and lining the shaft and for cementation.

Jan 1, 1936

By D. C. Brady

"Within six months from award of a project management contract, Les Mines Dumagami Limitée, Cadillac, Quebec, was operating its new hoisting facility. This was accomplished with less than a six-week shutdown of mine production while still maintaining shaft access for underground maintenance.The work involved installing a refurbished /3.5 ft diameter double drum hoist, replacing a timber headframe with a newsteel headframe, increasing the ore bin capacity from 500tons to 1000 tons, constructing a new substation, and upgrading related facilities.This paper describes the work and methods used by various contractors, Les Mines Dumagami Limitée and J.S. Redpath Mining Consultants Limited to bring this project to a successful completion. It discusses the history of the project from proposal stage through to the design, procurement, scheduling, and construction management. The paper also comments on problems that were encountered and the methods used to overcome them.IntroductionThe Donald J. Laronde Mine of Les Mines Dumagami Limitée (Dumagarni), a gold and copper producer, is located in northwestern Quebec, approximately half way between Val d&apos;Or and Rouyn. The mine started production in the spring of 1988 and the first gold bar was poured in June 1988.Following a request by Dumagami, on February 22, 1989, J.S. Redpath Mining Consultants Limited(Redpath) delivered a proposal to increase hoisting capabilities from 1500 tpd to a minimum of 2500tpd. Although various concepts were considered, Redpath proposed a new hoist house along the same shaft axis as the existing hoist, and located on the site of the existing substation. They would then provide a new substation, replace the headframe with a largersteel structure , gain extra storage capacities by increasing the bin heights, and raising the roof of the bin house accordingly.Although underground mining would have to be stopped for a month, the mill production would be maintained by feed from Dumagami&apos;s open pit.Figure 1 shows the original plant layout and Figure 2 represents the general arrangement after the project was completed . Table 1 compares the original hoisting facilities to the new facilities.On March 2, Dumagami awarded Redpath a contract that included preliminary engineering, detailed engineering, procurement and contract administration, and later added construction management. The preliminary engineering refined the initialconcept, selected major equipment, and prepared schedules and capital cost estimates for the total project."

Jan 1, 1991

By The Staff

Development of the Eldorado Mine THE pitchblende-silver deposits of Great Bear lake, Northwest Territories, were discovered by Gilbert LaBine in 1930. The property owned by Eldorado Gold Mines, Limited, consists of 53 claims situated, for the most part, on LaBine point, on the northeast shore of the lake. The Company also holds a group of 10 claims on Dowdell point, 7 miles to the southeast of the main group and across Echo bay. The fractures traversing the ridge on LaBine point can be readily seen from the air. Lack of overburden and the scantiness of vegetation leave rock exposures which are visible for miles. The years 1931 and 1932 were spent largely in staking, prospecting, and examination of the outcrops. A small Diesel plant was shipped to the property in 1932 and underground operations were started. Entry was made into the ore-body by means of an adit. A 20-ton mill was completed in the winter of 1933-34, and since then operations have been continuous, except for temporary shut-downs for additions to the mill. TRANSPORTATION The mine is situated 28 miles south of the Arctic Circle and is reached by an air route of 1,140 miles from Edmonton. The water route follows the course of the Mackenzie River system from Waterways, Alberta, the end of steel, and is approximately 1,450 miles in length. Two portages, at Fort Smith and on the Bear river, respectively, are necessitated by the occurrence of fast water. Transportation was one of the major problems to be solved, and Eldorado Gold Mines, Limited, found it necessary to embark upon both water and air freighting on its own account. The Company now operates a Bellanca &apos;plane with a payload of 4,400 pounds, and a complete water transportation system. The latter was established some years ago by the Northern Transportation Company and it is still operated under that name, but the Company is now a subsidiary of Eldorado. Modern steel boats, oil tankers, and barges were added to the fleet this season. The greater part of the ore shipments are made by water, aircraft being used for this purpose only when occasion demands. Freight rates have been greatly reduced by direct ownership of carriers. For example, water-borne freight is now quoted &apos;to the mine at $ll0 per ton, as compared with $240 per tan four years ago.

Jan 1, 1938

By M. L. Smith

"In the Phosporia formation of SE Idaho, ore quality varies by depth, seam and distance along strike; phosphorus recovery is sensitive to these variations. Plant ore feed can be blended over time to minimize this fluctuation by using a combination of mine production and inventory stockpile scheduling. Mixed-integer and goal programming has been used to optimize short-term mine production, but the seasonal nature of mine haulage requires the use of stockpiles both at the mill and the mine. The contents of the stockpiles can also be optimized as part of the production scheduling problem, but introducing inventory control introduces a nonlinear term into the formulation. A solution using a piecewise linear formulation is modelled and solved using AMPL/Cplex, and solution strategies are discussed for similar large-scale problems. IntroductionIdaho’s minable deposits of phosphate rock are found in the Meade Peak member of the Phosphoria Formation; two separate zones of this formation are mined with a combined thickness of 30 ft to 60 ft. A generalized stratigraphic section of the Phosphoria section is shown in Figure 1, illustrating the degree of complexity encountered when scheduling mine production. Alteration of the formation results in higher grade ore zones near the surface and variable in P2O5 levels between seams and along strike. This variability is seen as well in other quality characteristics critical to the production of acid and elemental phosphorus. Further, plant recovery and nodule quality are sensitive to variations in ore feed; variability in SiO2, carbonates, moisture, organics (carbon), P2O5 and other constituents of the ore can strongly affect plant recovery. Because ore quality characteristics can vary as a function of the alteration zone (or seam) being mined as well as the depth and distance along the strike of the formation, scheduling of mine production can have a highly significant effect on recovery in the plant. As illustrated in Figure 1, there are nine seams containing 20% to 35% P2O5. Phosphoric acid and elemental phosphorus production requires an ore content of 30% and 25% P2O5, respectively. Variability between numerous beds that are mined and quality variation within a seam due to alteration greatly complicates production scheduling with the result that erratic mill feed characteristics greatly decrease recovery."

Jan 1, 1999

By John G. Kelly

"In 1982 an extensive study was carried out to determine the best means of size reduction for the ore to be hoisted through the borehole hoisting system at Sherritt Gordon&apos;s Fox Mine.The study examined three alternatives:1. a jaw crusher,2. pneumatic rockbreaker(s) at a grizzly, and3. hydraulic rockbreaker(s) at a grizzly.The final decision was a compromise between alternatives 2 and 3. Two rockbreakers, one pneumatic and one hydraulic, were installed over a single grizzly. Some modifications have been made to the system, but over-all it has operated at acceptable levels since its installation in July 1983.As all the ore passes through a jaw crusher before being hoisted to surface, an evaluation of the relative performance and cost-effectiveness of the jaw crusher and the two types of rockbreakers is possible. This paper outlines the initial study, and compares the three breaking systems in operation at Fox Mine.IntroductionThe Fox Mine of Sherritt Gordon Mines Ltd. is located 800 kilometres north of Winnipeg near Lynn Lake in Northern Manitoba. Production at the copper-zinc orebody began in 1970 at a rate of 3,000 tons per day. Over 12.5 million tons will have been hoisted from the underground mine when the ore reserves are depleted in October 1985.The mining method at Fox Mine is sub-level open stoping with delayed backfilling are from the upper level stopes, above the 2000 level, is mucked on the main levels established at 400-ft elevation intervals, and is fed through a central orepass to the crusher located on 2100 level. Production in the lower levels commenced in 1975, and ore from the 2200 and 2400 level stopes was hauled up a 15010 ramp by 26-ton trucks to the 2000 level orepass dump. Projected production rates from the 2600 and 2800 levels using the trucking system were too low, and therefore, in 1983 a borehole hoisting system was commissioned to hoist that ore&apos;!&apos;. One thousand tons per day of ore are skipped through an 8-ft diameter borehole from the 2650 level loading pocket and dumped on the 2000 level. The ore is transferred by LHD to the main orepass for crushing before being conveyed to the main shaft for hoisting to surface (Fig. 1)."

Jan 1, 1986

By Shintaro Takamiya, Kazunari Yoshida

"Recently, small sized micro-needles for medical are required more frequently by patients. The biggest reason is that it presents great burden on the patients, due to the size of the needle injection. People need to use a very small needle to lower the pain, but the downfall is that it makes them more expensive due to their complicated manufacturing method. Therefore, we need to fabricate a needle by wire-drawing to decrease its price. Tube-drawing is beneficial for its production value; however, in conventional tube-drawing it is difficult of control the wall thickness of the tube and makes it 1mmor lower in diameter. That is why, we propose fluid-mandrel drawing for new tube drawing. This method allows fabrication of a fine tube by using the pressure of the fluid in the tube. In this research, the goal is the fabrication of a fine tube by fluid-mandrel drawing and its evaluation. Finally, the fabrication of a fine tube by fluid-mandrel drawing was conducted and in result a tube with a diameter of 0.2mm, high strength and thin wall and fine inner surface was drawn, which can be used as a lesser pain micro-needle.INTRODUCTIONThe main manufacturing method of the current medical needles is roll forming. With this method, it is difficult to make a tube with a diameter lower than 1mm. Deep drawing has been proposed and used as method to further reduce the diameter, but this method is costly and the injection needle obtained by this method is several times more expensive.Therefore, we need to obtain a fine medical needle by drawing process that can be mass-produced and inexpensively manufactured. However, with the conventional drawing process, it is not possible to obtain a syringe needle with a reduced diameter easily, that is why, a fluid-mandrel drawing has been proposed which can reduce the diameter without damaging the inner surface. The methodology of the method is, a fluid is filled in the sealed tube and the pressure inside the tube during drawing is responsible for the good inner surface and wall thickness. It is also expected that the fluid can be easily discarded and that the tube can be manufactured on a long scale."

Jan 1, 2017

By Haipeng Li, Jacob Masliyah, Barun Gorain, Jian Huang, Qingxia Liu, Zhenghe Xu, AuTec Innovative Extractive Solutions Ltd.

"Froth flotation is widely used to selectively separate one or more minerals from an ore over a wide range of particle sizes with high efficiency. Bubble–particle attachment is one of the most critical steps in flotation. The objective of this project is to demonstrate the need for an innovative dual bubble generator to improve flotation efficiency. This dual bubble generator was designed to generate two different sizes (micron size and typical flotation size) bubbles. The micron size bubbles generated on the crevices of particle surfaces in venturi type of cavitation tubes enhanced the attachment of fine particles to the bubbles in conventional flotation systems. They also acted as a secondary collector, which has the potential to reduce operation cost and improve flotation recovery. The dual bubble generator was evaluated for a double refractory gold ore with 3g/t Au, 1.5 wt% TCM (total carbonaceous matter) and 0.7 wt% sulfides. The results were compared with those obtained using a commercial bubble generator. Compared with the commercial bubble generator, the dual bubble generator showed not only a higher gold recovery, but also an improved separation efficiency, demonstrating the potential of dual bubble generator in fine particle flotation.INTRODUCTIONFroth flotation has been widely used in mineral processing and waste water treatment. However, flotation has been proven inefficient for fine particle recovery although it becomes increasingly inevitable to process fine particles with the depletion of easy processing ores. The critical problem of fine particle flotation is the low attachment of fine particles to flotation size bubbles due to their low collision rate. Based on a commonly acceptable flotation model given by R =F*[Pc*Pa*(1-Pd)], the probability of bubble–particle collision (Pc), attachment (Pa) and particles detachment from air bubbles (Pd) collectively determines fine particle recovery (R) (Yoon and Luttrell, 1986). Since Pc = (3Dp/Db) where Dp and Db are diameters of particles and bubbles, respectively, bubble size and particle size impact the bubble-particle collision in opposite directions. It is evident that the probability of bubble–particle collision decreases with decreasing the size of particles, leading to a low recovery of fine particles. In this case, reducing the bubble size and/or increasing the apparent size of particles by fine particle aggregation are clear means to improve fine particle recovery."

Jan 1, 2016

By T. Crivits, I. Bellemans, K. Verbeken

In the metallurgical industry, furnace cooling is often employed to enhance furnace lifetime. Hence, the pyrometallurgical phase comes in close contact with a non-air coolant. The proximity of the pyrometallurgical phases to the coolants may lead to dangerous situations. In case of a breach of the cooling circuit, the contact between a hot and a cold liquid may cause a vapour explosion. The outcome of this vapour explosion includes a pressure wave which could result in damage to the furnace, bodily injuries or even casualties. To prevent such dramatic events, the origin of vapour explosions is currently being studied in more detail. For this purpose, OpenFOAM was used to perform Computational Fluid Dynamics (CFD) simulations. In a first step, simulations were run to get a better idea of the influence of the compressibility on the simulations. The obtained results help in getting a better insight on the need of computational power, and possible numerical errors using compressible or incompressible solvers in future simulations. In a second step, systems without vapour explosions were simulated and compared to experimental results with mercury and aluminum. INTRODUCTION Humanity started using metals for tools around the Chalcolitic (~7400 cal BC), when copper was melted in small furnaces (Radivojevic, Rehren, Farid, Pernicka, & Camurcouglu, 2017). Nowadays, metallurgy has grown into a major industry and it has become impossible to imagine society without metals. In the pyrometallurgical industry, coolants (low temperature liquids, for example water) and pyrometallurgical phases (high temperature liquids, such as slags, mattes and alloys) are typically present in close proximity of each other. The interaction between these two phases can have catastrophic consequences (Tveit et al., 2008; Ferguson & Zsamboky, 2017). A vapour explosion may occur as the consequence of the rapid evaporation and expansion of the coolant. Whereas the volume of a gas increases linearly with the temperature (approximately a factor four by heating from 100°C to 1300°C), a simple calculation of the ratio of the two specific volumes shows that evaporation causes the volume of water to increase by a factor of 1700 at 100°C and ambient pressure (Table 1 and equation (1)), a number that was also found in literature (George, Nexhip, George-Kennedy, Foster, & Walton, 2006). The volume change occurs so fast that it resembles an explosion, hence the name vapour explosion. Such an explosion at industrial scale can cause economical losses, bodily injuries or even fatalities.

Jan 1, 2019

In the past decade, the increased engagement of business in debates around sustainable development has prompted recognition of the importance of biological diversity at the local, national and global scales. Driven by increasing populations that demand rising real incomes, a range of human induced pressures are modifying natural habitats and diminishing their ability to support life. Public policy changes have struggled to arrest the loss of habitats such as wetlands or tropical forests, and the related extinction of plant and animal species. Although conservation legislation and regulation were once the exclusive responsibility of government, new partnerships are now being forged that increase the role of the private sector and non-government organisations (NGOs) in developing and delivering conservation initiatives. Since the mid 1990s Rio Tinto has had to adapt to meet the demands of a rapidly changing conservation landscape. When Rio Tinto adopted its statement of business practice in 1998 The way we work, it explicitly recognised the need to take account of relevant environmental factors in obtaining access to lands, particularly in designated areas of high conservation value. With the revision of The way we work in April 2003, the policy on land access was strengthened through removal of the word ?designated?, thereby signalling recognition of the importance of biodiversity outside of protected areas. In addition, Rio Tinto?s revised land access policy explicitly refers to the use of land that is surplus to operational requirements for habitat protection and biodiversity conservation, subject to social considerations. In late 2003 Rio Tinto further strengthened its commitment to biodiversity with the promulgation of its biodiversity strategy and related position statement, biodiversity principles? (See Appendix 1.1) and technical guidance documents. This commitment is also embodied in a variety of initiatives at the corporate and operational levels, which are reported on annually in Rio Tinto?s Social and environment review. This guide has been prepared to support the practical implementation of Rio Tinto?s biodiversity strategy. The purpose is to provide guidance on how to effectively integrate biodiversity into Rio Tinto?s operations. It is applicable to all Rio Tinto exploration, new development projects and operations, irrespective of whether they have been operational for some years or are at the beginning or end of their operational life cycles. This guidance has been developed to support the Rio Tinto Environment Standards and the Rio Tinto Community Standard and any additional supporting documents as they are developed.

Apr 1, 2005

By R. Stauber, B. Friedrich, S. Hilgendorf, G. Homm, C. Gellermann

Due to recent regulations limiting tolerated lead concentrations in copper alloys, new recycling strategies have to be considered. This study investigates the suitability of technical approaches in order to recycle leaded copper alloys exemplified by CuZn39Pb2 and produce an alloy in compliance with future lead regulations in the European Union. Three pyrometallurgical methods are considered to achieve this goal, namely vacuum distillation, intermetallic precipitation and fractional crystallisation. The impact of essential process parameters i.e. pressure, temperature, time, atmosphere and quantity of additives are identified using thermochemical and kinetic modelling. An experimental implementation reveals a general suitability of all three refining processes. However, the individual efficiency of the different methods strongly differs. Thus, a detailed assessment is carried out in order to provide an evaluation on the efficiencies of these methods from a technological, economical and environmental point of view. Taking a possible industrial realisation into account, the authors recommend the approach of vacuum distillation, although the energy demanded is comparatively high due to the enthalpy of evaporation for zinc, or rather, lead. However, required lead concentrations can be reached quickly without introducing an external element to the material. The prediction of selectivity and evaporation speed, which are immanent variables for a successful implementation, can be validated experimentally. INTRODUCTION In 2016 approximately 1 million tonnes of leaded copper alloy semi-finished goods with an average lead content of 2.1 Ma% have been produced in the European Union (EU). The global production in the same period exceeded 5.5 million tonnes, while the lead concentration has stayed constant at around 2.4 Ma% for the last 50 years. Up to 80 % of the current production volume is covered with end-of-life scraps, which are used for direct re-melting, depending on the alloy composition. Lead has been a popular alloying element in copper alloys in general, and in particular in brass due to its positive impact on various mechanical, physical and chemical properties, especially machinability. Health and environmental concerns were drivers for many governments to implement limitations on lead. In order to further utilise the resource potential of leaded copper scrap, it is inevitable to develop methods to efficiently eliminate lead from circulation as far as possible. (Glöser, Soulier, & Tercero Espinoza, 2013; Soulier, Glöser-Chahoud, Goldmann & Tercero Espinoza, 2018)

Jan 1, 2019

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By Jean-François Lagueux

Goldex Mine is an underground mine located near the town of Val-d?Or. Multiple innovations were required to work the mine. Due to its low grade, it was important to develop a bulk mining method to economically extract the ore. The method used is a combination between shrinkage stope and long hole stope methods. This modified method is more than adequate; however, all of the ore body must be liberated in a very short period of time. Therefore, to bring down 23 Mt of ore, large blasts up to 1.8 Mt are required. The situation is also complicated by the fact that the mine is located in a residential area. No less that 40 homes are built within a 1 km radius of the mine site. In addition to managing mass blasts, means must also be found to mitigate the vibrations produced by the blast to diminish the disturbance to the neighbourhood. Therefore, the mine used numerous tools to properly plan the blasts and reduce the impacts. A program to control vibrations was one of the first tools put in place. The program?s aim was to draw up an action plan to ensure a follow-up of the homes by inspecting them. The second tool was to develop a methodology to plot a reliable attenuation curve and to adequately determine the maximum charge weight for each blast. Finally, effective communication tools were developed to inform the neighbourhood. There was a huge amount of work to be done in relation to the bench. Reliable and fast loading techniques had to be found to load large blasts in a very short period of time. Adequate logistics had to be developed to send underground more than 20,000 kg of emulsion per day while performing the daily underground operations. Technology had to be developed to adapt the i-kon electronic blasting system to large blasts. Since the control of the charges was the major factor to reduce surface vibrations, it was important to employ loading techniques that would permit decking of the long holes to reduce the charge weight per delays without adversely affecting the loading. All of this work requires an enormous amount of energy but also close collaboration between the different stakeholders (various departments, suppliers and consultants).

May 1, 2011

By R. Dawes, B. R. Davis, T. LeBel, C. Pelow

Settling of copper, lead, and other metals in slags is an important part of overall recovery of metals, both in primary and secondary operations. The impact of slag reduction on settling is not well known. This is important since the cycle time for slag cleaning can be significantly changed with reduction of slag, through a decrease in slag viscosity and growth of metal/sulphide particles. KPM has worked with a number of primary and secondary recyclers to better understand how reduction of slag can improve overall operation. In this presentation, we describe the type of test work and analysis done and how this information can be used to guide improvements in metal recovery from slags. INTRODUCTION Typically, copper smelter slags contain about 1-2% copper, both in the form of copper and copper sulphide beads and dissolved copper oxide in the slag (converter slags are recycled to the smelter). With the average grade of world copper deposits close to 0.7%, it is practical to recovery copper from these slags. This is done routinely by one of two methods. The first method uses slow cooling in large ladles or beds to grow particles of copper sulphide. The slag is then crushed, milled, and floated for copper recovery. The slow cooling promotes precipitation and growing of the sulphide particles from the solution and then, the slag can then be milled to recover the copper through froth flotation. A consideration of this process includes the energy cost related to grinding, the use of water, capital cost for ladles, and the availability of tailing dumps. At the same time, the retreatment of the Cu concentrate produced in the mill will displace fresh concentrate, which ultimately results in a reduction of the throughput. The second method is the so-called “slag cleaning” and is based on the settling of copper and copper sulphides particles dispersed in the slag. This is achieved by decreasing its viscosity by increasing the slag temperature and reducing the iron spinel solid phases (magnetite) that increase the apparent viscosity of the slag. Typically, the reduction does not extend to the reduction of copper, and soluble copper (mainly as oxide) and fine matte particles remain at concentrations typically at or above 0.5% (Cardona et al., 2011; Cardona, 2011). This is an improvement on 20 years ago when slag was sent to dumps at 1% or less (Demetrio et al., 2000).

Jan 1, 2019

By Chris G. Dobson

Introduction The Britannia mine is at Britannia Beach, on Howe sound, approximately thirty miles from Vancouver. The first claims were staked in 1898, and a local company was formed at that time to develop them. In 1904, Mr. Grant B. Schley became actively interested in the property and in the following year the Britannia Mining and Smelting Company, Limited, was incorporated to operate it. This Company was taken over a few years later by the Howe Sound Company, Limited. The mine comprises five more or less separate ore-bodies, which have produced approximately 20,000,000 tons of ore to date. The East Bluff ore-body, with which the present paper deals, is well suited to large-scale mining by means of carefully placed powder blasts. It covers approximately an acre and lies in the slate footwall, in a bay produced by a fault. The hanging-wall side, on the west, forms the face of the Bluff glory-hole, which extends to the 1,200 level. A portion of this ore was available for breaking into this old glory-hole, below which four bulldoze chambers could quickly be built. Mining of this block is complicated by a very soft footwall, which &apos;runs&apos; badly when broken. In stoping, care is taken to guard against the hazard of dilution by deliberately leaving a small portion of ore on the footwall. Some of this will undoubtedly be lost, but it is hoped to recover a fair amount of it after the major drawing is completed. The deposit occurs in a greenstone which has been highly silicified following brecciation. The chief minerals are chalcopyrite, sphalerite, and pyrite. Concentrates of copper, zinc, and pyrite are made at the mill. The average grade of ore runs 0.7 per cent copper, 1.5 per cent zinc, and 0.03 oz. gold per ton. The rock, which is practically a chert, is extremely hard, but shatters well. Both in stoping and drifting, holes must be closely spaced and powder used generously. Development When development work started in the East Bluff, there were no raises and only one drift on each level in this section of the mine. After blocking out the ore by thorough diamond drilling, a production of two thousand tons per day was set as a goal. To obtain this tonnage from so small an area required a great deal of carefully planned and well timed development work.

Jan 1, 1935

By Gilles Carrière

"The Huntingdon mine of Quebec Copper Corporation is situated 3 miles south of the village of Eastman, in the Eastern Townships of Quebec. The copper deposit consists of several pyrrhotite-chalcopyrite replacement bodies or bands.The first mining operations on the conspicuous surface gossan of the Huntingdon deposit started in 1865. They were suspended in 1883. The .mine was again active from 1890 to 1893 and from 1912 to 1924. These operations were carried to a depth of 500 feet, and it is estimated that some 150,000 tons of ore were extracted, of a grade reported as varying between 3 Yi and 7 per cent copper.In 1950 a program of exploration was initiated in the area of the old mine, and resulted in the finding of 500,000 tons of ore with a grade of 2 per cent copper. A new shaft was sunk to a depth of 1,160 feet, and by February 1954 the mine was extracting 800 tons of ore daily.General Geology and StructureThe mineralized zones are on the west side of a band of altered volcanic rock, locally called andesite, adjacent to a sill-like body of serpentinized peridotite which lies west of the andesite. The bands of andesite and serpentine extend several miles north and south of the mine. Their strike is generally north 15 degrees east, and they dip steeply east. Their widths vary very considerably along the strike, but in the mine area each is about 450 feet wide on surface. They are enclosed in sediments of the Caldwell series, consisting of greywackes, quartzites, slates, and shales. The andesite belongs to the same series, which is thought to be of Cambrian age (1). The ultrabasic intrusive is post-Ordovician.At p\aces along the serpentine contact the andesite shows a pronounced schistosity; it is parallel to the contact and rarely extends farther than a hundred feet from it. No evidence of strong folding or faulting has been found so far in the mine workings. Some apparent distortions and irregularities in the strike of the contact may all be due to the intrusive nature of the serpentine. In the mine area, transgressive tongues of serpentine point southward in the andesite.A few vertical lamprophyre dykes, not more than five feet thick, cut the other formations at right angles."

Jan 1, 1949