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By Larry Southwick

This Peirce-Smith Converting Centennial symposium is celebrating the contributions of two men, William Peirce and E.A.C. Smith, in advancing technology allowing the copper industry to realize its full potential. However, theirs is representative of a larger story: New, simpler technology releasing the stranglehold of older, more complicated technology, new developments in vessel configuration and design finding alternate routes around dead ends in operability, advances in technique and concepts removing roadblocks of cycle time and capacity, and overall innovation opening up vast new reserves around the world to those companies willing to embrace those improvements. Our story is also one of personalities, stubborn smeltermen versus the innovators, those inside the industry versus those from outside. It is a story of an initial borrowing from the steel industry, but also Peirce and Smith, from the refining end of the copper business, taking the ideas of Baggaley from Pittsburgh’s steel and airbrake industry, who built on what Hollway, Manhès and David, Douglas, and others had done in smelter tests, further to compete with the previous primacy and closely held expertise of the copper smeltermen in Wales. These advances have been well recorded in photographs taken over the last 150 years. A number were submitted especially for this symposium. Many others were published in the mining and metallurgy press of the times. Several mining schools also retained copies of photos either taken during field trips, or donated to the school by alumni and operating companies. This presentation will provide a selection and discussion from these sources of “converters in action”, describing the various designs, operations and developments depicted. The focus here will be on the first roughly 60 years of copper converter development, from Bessemer’s days at the dawn of this new idea, up to and slightly past the time of initial adoption of Peirce and Smith’s designs.

Jan 1, 2009

By S. Y. Tan

As CMOS devices are scaled down into nano-region, SiO2 dielectric is approaching its physical and electrical limits. High-k material has been investigated widely in recent years, and gate oxide take place growth oxide with Hf-based below 45nm gate length technology node has been shown. The phenomenon of interfacial property between bulk silicon and gate dielectric materials (HfO2 and HfSiO) was focused. A comparison of capacitance-voltage (C-V) characteristic of gate insulator was presented. Furthermore, the electrical property and thermal stability of high-k dielectric materials at various post deposit anneal (PDA) temperatures were established. The X-Ray diffraction technique was (XRD) utilized to analyze crystallization of the thin films, and the X-ray photoelectron spectroscopy (XPS) was applied for surface chemical bounding energy to identify the silicon and dielectric layers. Results show that HfSiO films have exhibited a superior performance on both thermal stability and electrical performance.

Jan 1, 2009

By P. M. Tyroler

Inco operates a hydrometallurgical plant to treat the residue from the pressure carbonylation process. The main constituent in the residue is cop¬per. The residue is leached under pressure in an acid sulphate solution in two stages and the copper is recovered via electrowinning. The electrowinning tankhouse is fully integrated into the overall plant flowsheet as spent elect¬rolyte is required in upstream leaching steps. In recent years, the amount of residue had increased and copper removal capacity became the rate limiting factor for the entire plant. Consequently, a major program was undertaken to upgrade the tankhouse with regards to capacity, efficiency, cathode quality, working environment and structual integrity and appearance. This paper will describe current facilities and operation, and detail progress in our up¬grading efforts.

Jan 1, 1987

By S. C. Sharma, M. Krishna, N. Sanmukha

"The oxidation behavior of an aluminium composite with 0, 2, 4, and 6% by weight of hematite at 200 to 500 °C has been investigated. Within the experimental temperature ranges a parabolic weight gain was observed. The, weight gain as a function of oxidation time becomes linear after an initial period on oxidation formation, an oxide scale was found whose morphology depends on temperature, cooling rate and sub-scale formation at the interface between the matrix and reinforcement. The presence of hematite particulate reinforcement has very little effect on the oxidation behavior. The interface oxidization rate was found to be higher than that of other regions. The, oxidation products were either metallic oxides or ceramic oxides. The exposure time of specimens to oxidation was 1000 minutes at various temperatures. In the present work key principles of alloy oxidation were discussed. Also the paper emphasizes various reactions taking ' place and the activation energies involved in the oxidation reactions.IntroductionMetal matrix composites (MMCs) reinforced with ceramic particulate, whiskers, or fibers have received increasing attention due to their potentially high fracture toughness and strength 1-5. Particle reinforced Aluminium MMCs find potential application in several thermal environment, especially in the automobile engine parts, space applications, such as drive shafts, cylinders, pistons, and brake rotors6.With the exception of gold, no metal or alloy is stable at room temperature, they tend to form their respective oxides. Most of the metals in the solid or liquid state are morphologically unstable when exposed to air at higher temperatures. An investigation relating to the temperature profiles of the piston area in a diesel engine has shown that the temperature can reach as high as 500¬800 K in certain regions of the piston. As the piston and cylinder areas are exposed to high temperature environment, the MMCs should have sufficient stability on both mechanical and chemical strength (oxidation). Oxidation occurs at grain boundaries in alloys and at the interface of the particulate and matrix in MMCs, which usually enhances intergranular fracture, resulting in premature failure and severe brittleness 8-10. Therefore for high-temperature applications, it is essential to have a thorough understanding of the oxidation behavior of aluminium MMCs."

Jan 1, 2000

By A. E. Isaacson

Bureau of Mines researchers developed and tested equipment to measure corrosion rates on a commercial-scale mill as an aid in predicting the effect of corrosion on minerals and how this effect relates to downstream processing. Bench-scale experiments were designed for duplicating ore grinding conditions closely enough that realistic rate determinations can be made in laboratory tests. Rates measured in a laboratory system compared favorably with those measured in the field. Cast steel was found to have corrosion rates in a copper mill and laboratory test cell of 22 and 21 mpy, respectively. Corrosion was found to account for less than 5% of the total grinding media wear in the operations studied.

Jan 1, 1987

By P. D. Nolan

Smelters operating under pollution control orders have become increasingly dependent upon the reliable operation of sulphuric acid plants and no factor affects the long term reliability of those plants more than efficient gas cleaning. The sources and characteristics of contaminants in smelter of fgases and the conventional approaches to removing these contaminants to accepted levels are discussed. New technology is described which offers advantages of lower capital cost, lower operating cost and reduced space requirements over the conventional approaches. This new technology has been developed by LAB s.a. and is licensed for metallurgical gas applications by Chemetics International Company.

Jan 1, 1983

By F. M. Nakla

Various methods of Applied Mineralogy were used for determining the nature and composition of products yielded by flotation tests for Maghara coal beneficiation. Coal samples obtained from the Sa fa mine in Northern Sinai, Egypt, were crushed, sieved, &apos;and <32 mesh size fraction was cleaned by froth flotation. Experiments were conducted to determine the effect of certain parameters on beneficiation of Maghara coal by flotation. The investigated factors included nature of frothing and/or collecting reagents, pH value of the medium, particle size distribution in the head sample, and pulp density of the coal slurry. The quality of head samples, coal concentrates, and tailing products were determined by chemical analysis, microscopic study, x-ray diffraction analysis, and occasionally by infrared (IR) absorption spectroscopy.

Jan 1, 1989

By Fangqing Yin, Qingyu Deng, Zhengfeng Qu, Mengjun Hu, Meilong Hu

Titanium bearing blast furnace slag, which contains 20%-30% TiO2, is a valuable secondary titanium resource. Based on the thermodynamics calculation effect of the temperature on the reduction of the slag in vacuum were studied at certain vacuum degrees. The results show that magnesium vapor and silicon monoxide vapor can be obtained at the condition of high temperature and low pressure. The purity of TiC increases with temperature increasing. When the temperature arrives at 1623K TiC can be obtained besides the reductant carbon. XRD result of the powder collected from the furnace cover show that magnesium and silicon in the titanium bearing BF slag leave the slag system during carbothermal reduction in vacuum. From the above it can be concluded that TiC can be obtained from the titanium bearing BF slag and silicon and titanium in the slag can be separated by carbothermal reduction in vacuum and acid leaching.

Jan 1, 2016

Thermodynamics and kinetics? of the removal of Va elements (As,Sb,Bi) from copper were investigated 1n the fire relining by alkaline carbonate fluxes such as Li 2co3 , Na 2CO3 and K2CO3. The distribution coefficients of As, Sb and Bl between alkaline carbonate fluxes and mo) ten copper were ?obtained at 1200°C under the different oxygen potentials. As and Sb were easily removed from copper to fluxes as pentavalent oxide form. On the other hand, Bi was hardly removed except by a Ll2CO3 flux. The removal rates of Va elements from copper were also measured In the temperature range of 1150°C.- 1250°C. The removal rates of As and Sb were much higher than that of Bi. The removal rates of Va elements showed the same order of the distribution coefficients. The removal rate could be expressed by following equation. (1).

Jan 1, 1987

By William J. Mallio

Substantial differences between in situ and conventional technology require that in situ ore grade be established for deposit as distinct from the total contained metal value. Establishing an in situ ore grade involves determining the fraction&apos; of the contained metal that can be leached by the fluid. This depends on the proportion of the ore minerals that occur on fluid flow paths as defined by the permeability distribution. Mechanisms involved in the in situ mining of sulfides are: oxidation of the sulfur, solution of the metals, complexing of the released metals, and a transport to a recovery point. Metal ions may be delayed or lost due to inefficiencies in these pro-cess steps or by reactions of the metal ions in solution with the rock. These reactions can involve precipitation of new phases, exchange of the metals of the interest with Ca or Na in clays or zeolites, retention of metals in oxidized mineral grains, or secondary enrichment of other sulfides along the paths of the solution flow. The efficiency of solution of metals and potential loss or delay mechanisms are controlled by local equilibria (the Eh, pH conditions) present in different parts of the ore zone. Permeability distribution in the rock mass and the coincidence of ore minerais with flow channels must be determined before a deposit can be judged suitable for in situ mining. Laboratory studies indicate that the natural permeability system is dependent on the degree of cementation of veins by late generation hydrothermal activities. The major conclusions of the study are:, 1. Deposit selection is critical; suitable deposit types include deep lying sedimentary deposits, selected zones of porphyry systems and vein controlled hydrothermal deposits; 2. Adequate laboratory and geochemical analyses should be undertaken through quantitative petrographic study and permeability mapping; and 3. Economic incentives for in situ mining must consider limitations of recovery caused by inefficiencies in dissolution and transport associated with particular deposits.

Jan 1, 1981

By Zhou Jun

Water-quenched samples were taken from a commercial flash furnace at three levels along its reaction shaft during operation at high feed rate. The samples were subjected to a series of analysis and observation. Such processes of the feed in reaction shaft as oxidation, desulfurization, melting, slag and matte formation and etc., variations of particle size along axial and radical direction of the shaft are investigated. The following smelting mechanism in reaction shaft named as “Multi-particle and multi-phase fusion model” is proposed: (1) Fragmentation and collision of concentrate particles take place simultaneously in reaction shaft with particle size growing up. Collision produces large-size “unit melt” which falls into the reaction layer in the settler bath. (2) In the settler reaction layer below the shaft, weak bath smelting reactions take place among the shaft products, producing final matte and slag which separate into two layers. (3) The processes in the shaft are all progressive along the whole height of the shaft. The predominant reaction in the shaft is oxidation, not reduction.

By O. G. Rivera, R. D. Moser, P. G. Allison, W. R. Whittington, P. Rivera-Soto, Z. McClelland, D. Francis

This research examined the evolving microstructure of quasi-static and dynamically loaded fully annealed metastable 301 austenitic stainless steel (SS). Experiments were performed to an interrupted strain value of 20% and to failure using a tension Kolsky bar (1000/s) and an electromechanical load frame (0.001/s). Electron Backscatter Diffraction (EBSD) identified the microstructural evolution from the as-received condition to the 20% strain level for the high and low rate interrupted samples. This material achieved over 60% elongation to failure with increasing strength as strain rate increased, as expected. Fractography analysis using SEM showed particles in the microstructure and a ductile failure mode. The 301 SS exhibited a greater amount of phase transformation from parent austenite to -martensite at the dynamic strain rate when compared to the quasi-static strain rate during the interrupted experiments. This result is indicative of the increased propensity for austenite to -martensite phase transformations at the high strain rate.

Jan 1, 2016

By I. Gaballah

The kinetics of oxychlorination of pure CI-2O3 with C12+02 gas mixtures is studied by ThermoGravimetric Analysis (TGA) in non and isothermal conditions up to 1000 °C. The reaction of Cr2O3 with C12+O2 chlorination gas mixtures starts at about 550 °C and the reaction product is CrO2Cl2. The oxychlorination rate of Cr2O3 is almost proportional to the chlorine partial pressure and to the fourth root of the oxygen partial pressure in the chlorinating gas mixtures. At 800 °C, the maximum chlorination rate is obtained using a gas mixture having a C12/O2 ratio equal to 4. The apparent activation energy of the oxychlorination reaction of Cr2O3 is 87 and 46 kJ/mol at temperatures lower and higher than 650 °C, respectively. By varying the chlorine and the oxygen partial pressures of the oxychlorinating gas mixtures at temperatures higher than 550 °C, it is possible to extract selectively the chromium chlorinated compounds from the chromium bearing materials. a. Laboratoire Environnemem et Minéralurgie, BP 40, 54501 Vandceuvre, France, b. École Nationale Supérieure de Géologie, Rue du Doyen Marcel Rouhault, 54501 Vandoeuvre Cedex, France, c. Centre National de la Recherche Scientifique, 3 rue Michel - Ange, 75794 Paris Cedex, France, d. Insritut National Polytechnigne do Lorraine, Rue de la Font de Haye. 54501 Vandceuvre Cedex, France.

Jan 1, 1997

By Tobias Pröll, Bernhard Kronberger, Joachim Rohovec, Werner Hölt, Hermann Hofbauer

"As this is only a first draft, more precise explanations as well as detailed schemes, figures and plots will be included in the final draft. The description og the 100 kW test rig will also be mor detailed as construction is ongoing and will be finished during the summer. Furthermore simulations are to be finished shortly; so details on combustibles and gas concentrations will also be included in the final draft.AbstractOxyFuel combustion is a key technology for the efficient separation of CO2 from fuel combus¬tion (especially coal). Since coal plays a minor role in the Austrian energy mix the application of OxyFuel towards other fuels (biomass, waste fuels) is interesting to reduce greenhouse gas emissions from Austrian energy sector. The investigation of OxyFuel technology for alter¬native fuels is also interesting from a strategic point of view in order to generate knowledge for operation of capture ready cofiring and waste/sludge-incineration plants. OxyFuel uses a synthetic mixture of 02 and recycled exhaust gas where the 02 content may vary. This supplementary degree of freedom allows improved operation especially for low calorific fuels. Heavy fuel oil addition for low calorific combustibles can be omitted when using OxyFuel combustion. Application of alternative fuels (wood, waste wood, municipal waste, sewage sludge) in a 100-kW CFB plant is investigated in combination with process simulation.IntroductionOxyFuel combustion is discussed as one of the key technologies for the efficient separation of CO2 from combustion of fossil fuels (especially coal). Since coal plays only a minor role as primary energy source in Austria, the broadening of the scope towards OxyFuel of other fuels like biomass or waste fuels is necessary to reduce greenhouse gas emissions from Austrian energy sector. The investigation of OxyFuel technology for alternative fuels besides the large coal-oriented projects is interesting also from the strategic point of view. The presented project aims at the generation of knowledge in order to design and operate capture ready cofiring and waste/sludge incineration plants."

Jan 1, 2008

By Jordan Mayorga, Joseph Kopp, Robert Boehm, Daniel P. Cook

"Solar generated power has long been considered a useful energy source only for low-energy density and non-mission critical use, such as providing electricity for residential applications. The success of Concentrating Solar Power (CSP) facilities, such as the 64 MW Nevada Solar- 1 near Las Vegas, have demonstrated that solar does have application to high energy density industries such as materials and chemical production. This paper will discuss the current operating con_guration of the Solar-1 facility and show how proposed modi_cations, such as addition of thermal storage and use of liquid salts as the working uid, can further improve the e_ciency and energy production of the plant.IntroductionThe United States as a nation is the largest consumer of energy in the world at an estimated 29 trillion kWh per year[1], which is roughly 15% of total global energy consumption[2]. On a per capita basis, the United States also leads most of the world, using an average of 96,000 kWh per person[3]. Roughly 40% of the energy consumed in the United States was produced from petroleum, 23% from coal, 23% from natural gas, 9% from nuclear and the remaining 5% from renewable sources such as solar, geothermal, wind, and hydroelectric[1].Energy demands associated with the industrial-scale production of chemicals and materials is a signicant portion of the United States total energy consumption. Roughly 33% of the energy consumed in the United States is used by the industrial sector, with 22% of this amount used in chemical production, 16% used in petroleum rening, and 14% used in the smelting and rening of metals[1]. Energy costs are also a signicant, if not the most signicant, portion of the total production costs for many materials. For example, roughly 30% of the cost of producing aluminum is the electricity used in the Hall-Heroult process [4], while the cost of energy is roughly 15% of the total cost of producing steel products [5].The primary sources of power for the industrial sector have been coal, petroleum, hydro- electric and nuclear. The use of alternative energy sources, e.g. solar, wind, geothermal, for industrial materials production has been slow in coming because they are intermittent and low-energy density sources, i.e. no solar power at night, no wind power when the air is still, etc. The success of Concentrating Solar Power (CSP) facilities, such as the 64 MW Nevada Solar-1 (NS-1) near Las Vegas, have demonstrated that solar can have application to high energy density industries such as materials and chemical production.This paper will discuss the current conguration of the NS-1 facility, and potential modications to the facility that will increase both its power e_ciency and power density."

Jan 1, 2010

By A. J. Williams, T. N. Croft, M. Cross

"The computational modelling of extrusion and forging processes is now well established. In this work a novel approach is described which utilises finite volume methods on unstructured meshes. This technique can be used to solve simultaneously for fluid flow, heat transfer and non-linear solid mechanics and their interactions. The approach involves the solution of free surface non-Newtonian fluid flow equations in an Eulerian context to track the behaviour of the workpiece and its extrusion/forging, and the solution of the solid mechanics equations in the Lagrangian context to predict the deformation/stress behaviour of the die. Some preliminary examples of this approach will be discussed.IntroductionThe computational modelling of extrusion and forging processes is now well established. Within the last 20 years the finite element method has become the most commonly used technique to simulate metal forming processes [1]-[4]. The Lagrangian and Eulerian type of formulation have been the two major approaches to this problem.Lagrangian methods are efficient and suitable for handling non-linear problems in which small strains prevail, boundary conditions do not change with the course of deformation, and where mesh distortion is not a critical factor in the analysis. Unfortunately, the above points are essential to any accurate metal forming analysis. The problems of mesh distortion and element entanglement pose a serious drawback on the use of such methods. Some automatic remeshing techniques have been developed for Lagrangian finite element analyses of metal forming problems [5]-[7]. However, these methods are not robust and efficient enough to remedy the mesh distortion problems in general. An alternative is to update the mesh manually but this is not always possible, and even when it is feasible it involves major interaction by the user. In addition, remeshing is usually applied to the whole domain which is not necessary and increases CPU time. The complexities associated with remeshing also affect the ability to parallelise the code."

Jan 1, 2001

By D. V. Hughes, J. R. Nyberg

"Since 1985, a comprehensive automation system has been installed at the Outokumpu Oy Zinc Plant, Kokkola, Finland. In leaching and solution purification special sample handling equipment, on-line analyzers and instruments, and a computer-based control system with duplicated supervisory stations have been installed. The system has enabled closer control of the process and more efficient use of labor. Since its installation recovery of zinc has improved, and use of zinc dust, steam, and water have decreased. The system has performed reliably. It includes optimizing programs and process study tools, which facilitate improving process performance. An expert system has been built-up to prompt process personnel to take appropriate action on the basis of process data. In electrolysis a similar system, based on extensive monitoring of the process and of production of zinc cathodes, is used to maximize- current efficiency by maintaining optimum conditions in the process. It is planned that in the future the control systems will be integrated and extended to cover the roasting plant and effluent control.IntroductionThe Zinc PlantThe Zinc Plant of Outokumpu Oy Metallurgical Division at Kokkola, on the West Coast of Finland, has grown from a 90,000 t/a plant founded in 1969 to become, with its present capacity of 170,000 t/a, one of the world's ten largest zinc plants. Especially since the completion in 1988 of a thorough modernization programme, it is also among the world's most modern.The Kokkola plant takes its raw materials from Outokumpu's own mines, Vihanti and Pyhasalmi in Finland, and Tara in Ireland, and from outside sources. Concentrates are roasted in two Lurgi fluid-bed furnaces, and the calcine is leached and iron removed by the Conversion process. Following this copper, cobalt, and cadmium are removed, and zinc is refined by electrowinning. The leaching and purification, and the cell-house are automated under computer-based control, and anode and cathode handling in the cell-house are mechanized and fully automatic."

Jan 1, 1989

By William Petruk

A fully automatic image analysis system that consists of a microprobe, an energy dispersive x-ray analyzer, and an image analyzer was developed at CANME:I&apos; to determine mineral behaviour that affects beneficiation. The interlacing between the instruments permits automatic identification and characterization of minerals in samples of unbroken ore pieces and of mill products. Different types of information are obtained for minerals in samples of unbroken ore pieces than in samples of mill products, and are used differently. For unbroken ore pieces size distributions are determined for discrete mineral grains to predict a grind at which they might be liberated, and other measurements are Irade to predict the percentage of mineral that occurs as nonrecoverable grains. For mill products the minerals are analysed to determine percentages that (1) are free, (2) are likely to be recovered in concentrates, (3) are likely to be lost to tailings, and (4) could be liberated with regrinding. The image analysis data for mill products are processed by a mineral-metals balance program to determine the distributions of free and unliberated mineral grains at each point in a concentrator, pilot plant or bench test. For samples containing trace minerals, such as gold, an automatic search technique is used to scan the entire area of the polished section for the trace mineral grains. The identified trace mineral grains are characterized with regard to size, liberation, and other properties.

Jan 1, 1988

By Xiangwen Wang

Electrodeposition of lead metal from high purity brine electrolytes containing lead chloride (PbCI,) was conducted so as to assess the feasibility of electrowinning lead-metal directly from aqueous chloride electrolytes. Tests were performed at 65 and 80°C (338 and 353°K). Characteristic features of the deposits, on both lead and graphite substrates, were correlated to operating parameters associated with: electrolyte temperature, current density and total lead- concentration. Photomicrographs of these morphological features were obtained by use of Scanning Electron Microscopy (SEM).

Jan 1, 1993

By L. Klinger, T. Werber, LA Levin, A Katsman

"The process of catastrophic carburization known as ""metal dusting"", whereby a solid metallic material is converted into fine particles in a carburizing atmosphere, was analyzed. It was shown that this conversion is the result of plastic deformation and subsequent fracture accompanying diffusional phase formation in the near-surface layer. The process is controlled by internal stresses arising during phase transformation. Competition between stress generation and relaxation may result in the attaining the ultimate strength in the near-surface layer and its fracture. Such a mechanism of metal disintegration may occur in a certain temperature interval depending on the kinetic and geometrical parameters of the system - the diffusivities of the alloy's components, the ratio between specific volumes of the new and the old phases, and the ultimate plastic strain. The temperature interval for disintegration of carbon steel, the rate of disintegration, and the period of the disintegration cycle, were evaluated and compared with experimental data. IntroductionCatastrophic carburization, known as ""metal dusting"", consists in conversion of a solid metallic material into fine particles. The process occurs in a carburizing atmosphere at elevated temperatures. The corrosion product, usually named ""coke"", consists of metallic particles dispersed in a loose carbon matrix. Under industrial conditions metal dusting takes place, for example, in a gas mixture of CO and H2 or in hydrocarbon environments. Steels, nickel- and cobalt alloys are susceptible to this kind of wastage in the temperature range 400-800°.A mechanism of metal dusting in steels was proposed by Hochman [1] and later developed by Grabke and coworkers [2-5]. According to the proposed model, the process consists of the following reaction steps:"

Jan 1, 1996