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By Irina Melekestseva, Beltenev. Victor, Victor Ivanov

"One of the major problems discussed over the last years is a possibility of mining of seafloor massive sulfide deposits. In spite of the pessimistic points of view on their commercial development, they are still of great interest and continue to be studied (Hannington et al., 2011). Recently, Barriga (2012) paid special attention to the underestimated amount of massive sulfide hydrothermal fields and pointed to the importance of the buried fields and subseafloor mineralization.This study examines the geochemistry of seafloor and subseafloor precipitates collected at the Peterburgskoe (19°52´ N) and Irinovskoe (13°20´ N) hydrothermal fields (MAR) during the 34th cruise of the R/V Professor Logatchev in 2011. These fields were discovered by the Polar Marine Geosurvey Expedition in 2010 and 2011, respectively (Shilov et al., 2011; Beltenev et al., 2012). The Peterburgskoe field, associated with basalts, is located 16 km west of the main rift valley at the depth of 2800-3100 m at the junction of a large non-transform discontinuity with the second rift ridge parallel to the rift valley. The Irinovskoe field occurs at depths of 2700-2850 m and has a northwestern satellite sulfide site, both confined to an oceanic core complex (MacLeod et al., 2009), which includes mafic and ultramafic rocks. The details of geological structure of the fields may be found in the relevant papers.Diverse samples were collected from the hydrothermal fields: seafloor massive sulfides, Fe-hydroxide crusts, SiO2-rich sulfide-bearing precipitates, and subseafloor mineralized rocks (Melekestseva et al., 2014a). Massive sulfides may be subdivided on the Fe-rich and Cu-rich types. The marcasite-pyrite, pyrite, hydroxide-marcasite, and chalcopyrite-pyrite (Fe-rich) mineral types are dominant in the Peterburgskoe field at lesser amounts of sphalerite-hydroxide-chalcopyrite and pyrite-covellite-chalcopyrite (Cu-rich) massive sulfides. The mineralized sulfide-talc-carbonate-chlorite, chlorite-sulfide-quartz, and hematite-sulfide-quartz rocks host stringer-disseminated sulfides including chalcopyrite, covellite, and pyrite."

Sep 1, 2014

By H. Y. Yang, L. L. Tong

Semicontinuous-flow, multistage biooxidation experiments of a Chinese refractory, high-sulfur gold concentrate were conducted with different pulp densities for gold recovery. The maximum iron, sulfur and arsenic oxidation rates of 90.0, 88.8 and 96.4 percent, respectively, were obtained in the experiments with 5 percent pulp density. The highest gold and silver recoveries of 96.1 and 68.9 percent, respectively, were achieved by cyanidation. The negative effect of high pulp density on biooxidation was related to the decrease of free and adsorbed cell concentrations with increasing pulp density. The data of iron oxidation from the semicontinuous biooxidation experiments were best fitted by a shrinking core model in which the chemical reaction controlled the rate. The dissolution kinetics of sulfur and arsenic were therefore analyzed by a shrinking core model in which the internal diffusion controlled the bioleaching rates. For the quantitative description of biooxidation efficiency, two parameters — mass dissolution rate and volume dissolution rate — were proposed. In the first stage, the mass dissolution rates of minerals were negatively correlated while the volume dissolution rates were positively correlated with the actual pulp density. The iron and sulfur mass dissolution rates decreased with increasing actual pulp densities in the third and fourth stage, while linear increasing relationships between the volume dissolution rates of minerals and the actual pulp density were observed from the second to fourth stage. The highest mass dissolution rates of minerals were obtained in the first stage with 5 percent pulp density. The highest volume dissolution rates of minerals were obtained in the first stage with 15 percent pulp density. Compared to the volume dissolution rate, the mass dissolution rate was more intuitive to reflect the negative effect of high pulp density on biooxidation efficiency.

By F. B. Henderson III

Since the "end" of the Cold War, revolutionary new research and commercial remote sensing capabilities are being developed that will dramatically change the way we map the earth and address its environmental problems. The technology challenge is not the growth of new environmental remote sensing technologies themselves. It is, rather, how these new innovative observing systems can be accepted and used to the benefit of both the regulatory and the mining communities in the light of present concerns about unknown risks of discovery and liability. The basis for this paper is an unpublished technology primer prepared for the industry-government Workshop on Advanced Measurement and Site Characterization for Mining Impacts held at Colorado School of Mines, Golden, Colorado, July 14-17, 1997

Jan 1, 1999

By Craig M. Sams

Phosphate mines in Florida are continuing to encounter higher dolomitic content host rock with the phosphate pebbles(1) necessitating a change in grinding conditions and/or circuits, One of these changes is to install hydrocyclones and close circuit the mill as opposed to the traditional open circuit grinding plant. Close circuiting of the grinding mill with hydrocyclones allows one to take advantage of reduced process mill power requirements by circulating the coarse mill discharge back into the mill for multiple chances of particle breakage. Additionally, as in this case, the hydrocyclones de-slime the pebbles, allowing for more efficient use of grinding power by reducing the amount of dolomitic material recycled to the mill.

Jan 1, 1986

By Paul M. Jr. Musgrove, Thomas D. Henderson, Mark B. Nesbitt

Introduction History. Vat leaching operations began in October 1953. Since that time, about 4.2 million tpy of oxide ore averaging 0.72% copper have been treated. Economic conditions, improved operating methods, and increased production facilities have allowed the ore grade to be reduced over the years. The average ore grade was 0.84% Cu during the 1950s, 0.68% in the 1960s, and was 0.50%, or below, during the 1970s. By 1961 some 35 million tons of oxide ore had been removed from the mine, exposing the underlying sulfide ore body. A 5,000¬ tpd concentrator was constructed and put into operation to treat the sulfide ore in November 1961.1 The original crushing plants were used for both oxide and sulfide ores, but by adding a third crushing shift, six days per week, the total ore treated was raised from 12,000¬17,000 tpd. Dwindling oxide ore reserves prompted expansion of the concen¬trator to 13,500 tpd in 19672 so that exhaustion of known reserves of both ores would occur at nearly the same time. Again, no additional crushing facilities were added during the expansion. It was anticipated that the treatment rate of oxide ore would be reduced from 12,000 to about 9,000 tpd. Instead, the addition of two crushing shifts per week and improved operating procedures have increased the treatment rate to 26,500 tpd-13,000 tpd to the leaching plant and 13,500 tpd of sulfide ore treated in the concentrator. Geology. The Yerington ore body is a disseminated porphyry copper deposit where a quartz monzonite porphyry intrusive contains the major part of the ore values, with some copper mineralization found in the adjacent granodiorite and other rocks. The geology of the Yerington Mine was aptly described by J. R. Wilson (Mining Congress Journal, June 1963). The ore body is one of few porphyries where geologic conditions were optimum for the formation of an important concentration of oxidized ore with minimum economic effect of secondary enrichment. The principal mineral in the oxidized zone is chrysocolla, which irreg¬ularly occurs dispersed throughout the rock and as narrow seams along fissures. The grade of the ore in the oxidized zone is generally the same as in the primary sulfide below, although some massive concentrations do occur as vein-like fissures and as filling of breccia zones. Cuprite, tenorite, melaconite, malachite, and azurite occur but are not abundant. Lying between the chrysocolla horizon and the primary sulfide is a transition zone whose limits are irregular but seldom with vertical range exceeding 50 ft. Chalcocite, cuprite, melaconite, native copper, and chrysocolla occur superimposed on the primary sulfides. Chalcocite replacement of chalcopyrite, as well as secondary chalcocite, do occur. The primary sulfide minerals are chalcopyrite and pyrite, with minor amounts of bornite and covellite. There are no appreciable gold or silver values, and molybdenite has rarely been noted.

Jan 1, 1985

By Corale L. Brierley

The effect of hydrogen peroxide (H2O2) on growth and respiration of Thiobacillus, thiooxidans, and Thiobacillus ferrooxidans, organisms involved in acid leaching of copper sulfide minerals and uranium oxides, was examined. Oxygen uptake and growth by T. thiooxidans were inhibited after contact with 0.82 mM H2O2. Inhibition of oxygen uptake by T. ferrooxidans occurred at 8.24 mM H2O2, and growth was inhibited after 6 hours exposure to 2.06 mM H2O2. Higher concentrations of H2O2 can be used without detriment to thiobacilli if it is dissipated prior to reaching the oxidation pond or dump surface. INTRODUCTION In recent years, hydrometallurgical processes for recovery of metal values from low-grade ore minerals have played an increasingly important role. Dump leaching of low-grade copper waste materials in the western United States now yields 11.5% of the total U. S. copper production. Although scavenger operations in uranium leaching have been successful, the state-of-the-art of in-situ

Jan 1, 1977

Application of flotation for the removal of hydrophobic compounds from soils was studied. Bench scale flotation tests were conducted on artificially contaminated soil, using both conventional mechanically agitated machine and flotation column. Flotation parameters tested include surfactant collector type, conditioning time, flotation time, surfactant dosage, pulp pH, solid/liquid ratio in conditioning and pulp temperature. It is found that with conventional flotation 74% removal of the contaminant was achieved from soil particles in the range of 75-830 µm; with column flotation up to 80% of oil could be removed from the 250-830 µm soil fraction, and 65% from the 75-830 µm fraction. Flotation was found to have considerable potential for cleaning up contaminated soils.

Jan 1, 1998

By Richard W. Cannon

INTRODUCTION The authors, by means of this paper, will attempt to show the role of Induced Polarization and Resistivity surveys in the discovery of the orebodies of Gibraltar Mines Limited (N.P.L.). In this paper, we will also attempt to show the importance of conducting large enough surveys in order to properly evaluate the results obtained from these surveys. LOCATION The orebodies of Gibraltar Mines Limited (N.P.L.) are located on the western slope of Granite Mountain, central British Columbia (52°30' north, 122°16' west) (See Fig. 1). The property lies approximately 28 miles north of Williams Lake, B.C. and can be reached by way of 10 miles of newly improved road from McLeese Lake, on the Cariboo Highway. The area in and around Gibraltar Mines has a moderate topographic relief with elevations between 3,500 and 4,100 feet. {EARLY HISTORY AND GEOLOGY The present Gibraltar Mines property before amalgamation consisted of the Pollyanna property (Duval-Canex) and the Gibraltar property (original Gibraltar Mines) as well as some Coast Silver and McLeese Lake Copper claims (See Fig. 2). The Pollyanna property was first described in the 1917 B.C. Minister of Mines Report which referred to it as the "Rainbow Group". The development at that time consisted of several open-cuts on copper bearing quartz veins.

Jan 1, 1972

By Y. A. Attia

A study was performed on selective flocculation and dispersion for ultrafine coal cleaning. A totally hydrophobic polymer, FR-7A, was employed as the selective flocculent for coal, sodium metaphosphate (SMP) as the general dispersant for shale and a synthetic polymeric product, polyacrylic acid-xanthate (PAAX), as the selective dispersant for pyrite. In the adsorption tests, nephelometry and spectrophotometry were employed for determining the concentration of FR-7A and PAAX in the solutions respectively. The adsorption tests indicated that: a) FR-7A has a higher affinity toward coal and pyrite than that for shale; and b) PAAX has a much higher affinity toward pyrite than toward coal and shale. In the selective flocculation tests, the ash-forming minerals can be efficiently rejected using sedimentation as the separation method. However, due to their relatively high specific gravity, pyrite particles co-settle with the coal flocs. To reject fine pyrite, a froth flotation was used for floc separation. The one-step flocculation-flotation process could reject more than 70% of each of the pyritic sulfur and ash minerals, while recovering more than 85% of the coal.

Jan 1, 1990

By Donald S. Bubar

The Separation Rapids property, located approximately 60 km (37 miles) north of Kenora, Ontario, Canada, is host to one of the largest rare metal pegmatite deposits in the world. This pegmatite was named the Big Whopper by its discoverer, Dr. Fred Breaks of the Ontario Geological Survey, because of the exceptional length and width of the surface exposure. The property is readily accessible from a main, all-weather road via a network of secondary logging roads. The main line of the Canadian National Railway passes through the village of Redditt, just 40 km (24 miles) south of the property. The Big Whopper is one of the complex-type (petalite sub-type) class of rare metal pegmatites that are geochemically the most highly evolved in the spectrum of granitic pegmatites. Such deposits are economically important as resources for the rare metals lithium, tantalum, cesium, and rubidium. While complex-type pegmatites are found in many areas of the world, most are too small to be profitably mined, however, with an inferred resource in excess of 15 million metric tons (mt) (17 million short tons [st]), the Big Whopper is only the fourth deposit of its type in the world with the size required to be of major economic importance. The other three deposits, which are currently in production, are the Tanco mine in Manitoba, the Bikita mine in Zimbabwe, and the Greenbushes mine in Western Australia. The Big Whopper is situated in the eastern continuation of the Archean Bird River greenstone belt which also hosts the Tanco pegmatite, approximately 60 km (37 miles) to the west. The principal commodities identified in the portions of the Big Whopper pegmatite explored to date are petalite (LiAlSi4010) and rubidium-rich K-feldspar. These are industrial minerals with important applications in the glass and ceramics industries. The Big Whopper also contains substantial quantities of lepidolite, a lithium, rubidium-mica which is the principal ore mineral for rubidium metal. Tantalum and cesium occur in anomalous levels with the petalite mineralization, and the possibility of finding zones of high enrichment in these valuable high-tech metals elsewhere in the deposit is excellent. Such enriched zones are typical of pegmatites as highly evolved as the Big Whopper. To date, the geological mapping and diamond drilling work completed by Avalon have delineated the Big Whopper pegmatite system over a strike length exceeding 1.5 km (0.9 miles), over widths ranging from 10 m to 80 m (30 feet to 260 feet) in thickness, and to a vertical depth of close to 300 m (1,000 feet), where it remains open. The pegmatite system consists of a vertically oriented massive petalite pegmatite dyke striking 280 degrees that is flanked by amphibolites containing a swarm of narrower albite and petalite dykes which have all undergone intense deformation in a high strain zone resulting in folding and intense shearing. The Big Whopper exhibits a mineralogical zonation pattern which is complicated by the superimposed deformation that has both folded and stretched the deposit. Drilling has defined a dilute geological resource totaling 7.1 million mt (7.8 million st) grading 1.283 percent Li20, 0.346 percent Rb20, and .007 percent Ta205 over a strike length of 600 m (2,000 feet), and to a vertical depth of 250 m (820 feet), where it remains open. The petalite and rubidium-rich-K-feldspars contained in the Big Whopper all appear to be of superior quality. The grades are consistent with a petalite content averaging 25-30 percent and a rubidium-rich-K feldspar content averaging 15-20 percent. The remainder of the rock consists mainly of albite, several types of mica, and quartz. Accessory minerals include columbitetantalite, cassiterite, apatite, garnet, and gahnite. Market studies show that the deposit is located close enough to existing transportation infrastructure to access rapidly growing, major markets in the glass and ceramics industries, both in the northeastern U.S. and Europe. There are only three competing lithium minerals producers in the world with the Bikita mine in Zimbabwe being the only major producer of petalite. The other lithium deposits produce spodumene, a less desirable lithium mineral. Lakefield Research Limited has successfully designed a process to produce an ultra-pure petalite concentrate containing up to 4.65 percent lithium oxide, and as little as 0.014 percent iron oxide, low levels of soda and potash, and negligible amounts of other trace elements. With these specifications, Avalon will have an excellent quality product for glass-ceramics applications such as Corningware®, CERAN® stove tops, and other thermal shock-resistant products. Lakefield is presently designing the balance of the flowsheet to produce separate concentrates of rubidium-rich K-feldspar, albite, mica, tantalum, tin, and high-purity quartz. Initial test work indicates that the feldspar products will be of exceptional quality. The K-feldspar concentrates contain 11-12 percent K20 and 1 percent Rb20, while the sodaspar contains over 10 percent Na20, and both have very low iron (0.01 percent Fe203). A preliminary economic model shows that with an initial production rate of 90,000 mt (100,000 st) per year, expanding to 170,000 mt (190,000 st) per year over 5 years, the project is capable of generating over CDN $10 million per year in pre-tax cash flow by year 5 on a capital cost of approximately CDN $30 million.

Jan 1, 2001

By A. Anani, K. Awuah-Offei

"Accounting for changing duty cycles in equipment matching maximizes equipment utilization and productivity. The objective of this study is to investigate if the optimal number of shuttle cars for a particular panel width is optimal in different segments of the panel. In this study, discrete event simulation (DES) is used to determine the optimal number of cars that maximizes productivity in each segment. Data from a real-life mine is used to validate the model. The study shows that the optimal number of cars for the entire panel may not be optimal for some of the defined segments. INTRODUCTION Fleet optimization is important for efficient mine management. Deploying the optimal fleet minimizes the capital and operating expenditure for particular operating conditions and production targets. In an operating mine, with an already existing fleet, deploying the optimal fleet maximizes productivity or minimizes production cost with the available resources. Hence, a lot of research has focused on how to determine the optimal fleet size for a mining operation, given particular operating conditions. Mine managers and engineers have successfully used discrete event simulation (DES) to determine the optimal fleet size in mines (Michalakopoulos, Roumpos, Galetakis, & Panagiotou, 2015; Awuah-Offei, Osei, & Askari-Nasab, 2011; Ben-Awuah, Kalantari, Pourrahimian, & Askari-Nasab, 2010; Govinda Raj, Vardhan, & Rao, 2009; Yuriy & Vayenas, 2008; Kwame Awuah-Offei, Temeng, & Al-Hassan, 2003). In most cases, the published work on this topic involves determining the number of hauling units to be matched to a loading unit. Many of these examples involve truck-shovel optimization. There are, however, some underground mining examples. For instance, we recently concluded work that involves fleet optimization in underground room and pillar (R&P) coal mining (Awuah-Offei & Anani, 2015). Generally, when DES is used in fleet optimization it involves three steps: (1) Build a valid model of the mining system capable of predicting the required outputs with varying fleet composition; (2) Design and conduct experiments that vary the fleet composition across all feasible options; and (3) Determine the optimal fleet based on the results of the simulation experiments. A major decision in the first step is which outputs should be modeled. Some examples in the literature include productivity, unit cost, loader utilization, queue length, and hauler waiting times (Awuah-Offei et al., 2011; Govinda Raj et al., 2009; Kwame Awuah-Offei et al., 2003). Often, more than one of these outputs are simulated and considered as the objective function of the optimization."

Jan 1, 2016

By M. S. Davis

The Tek Process can produce masonry products such as bricks, roof or wall tiles, and block from virtually any inorganic waste. In the process the aggregate raw materials, portland cement, water and common chemicals are first mixed together; then mechanically subjected to several thousand pound pressure per square inch. This causes a novel chemical reaction between the cement, chemicals and water; producing the "patented" Tek adhesive binder which holds the aggregate together in a stone-like mix. Simultaneously, the desired product shape is formed. The building modules can have strengths of 8000 p.s.i. (pounds per square inch) with completely sound aggregates utilizing air curing for a period of 28 days. With most aggregates, 3000 p.s.i. is achieved within 24 hours. Eventual strengths usually exceed 5000 p.s.i. with almost any raw material. Water absorption ranges from 5-7.5 percent. Both absorption and strength figures are superior to the most rigid of any and all A.S.T.M. specifications for the highest quality bricks. In most locations, the product (when brick shaped is called Tekbrik) can be produced significantly more economically than can comparable grades of clay or other bricks, be- cause almost any inorganic waste materials or pollutant can be used as a raw material. The process results in a lower manufacturing cost as compared to clay bricks; fuel cost to operate a clay kiln represents a substantial portion of the total cost. Capital expenditure for a Tek plant also is lower due to the large investment in clay kilns. Transportation savings also are important, clay brick factories must be very large because the kilns are uneconomical unless they are large. Most bricks are manufactured at the sites of clay deposits in relatively uninhabited areas. The cost of transportation to the job site represents a considerable percentage of the selling price.

Jan 1, 1974

By Y. Guan

The adsorption of zinc species onto silica in ammonical solutions has been studied. Adsorption isotherms reveal that increasing adsorption occurs as the solution pH is made more alkaline. Fr-IR spectroscopy revealed that the adsorbed species is a zinc ammine complex.

Jan 1, 1993

By I. H. Gundiler

Although cyanidation has been universally applied in the processing of gold and silver ores, the search for less toxic alternatives continues. Difficulties encountered in processing ores containing oxidized copper minerals and the inherently slow kinetics of cyanidation have generated a renewed interest in thiosulfate leaching. This process, as well as the catalytic effects of copper ion, were well recognized and widely applied towards the end of the past century. In this study, the effects of copper, ammonia, and thiosulfate concentrations on gold dissolution were investigated using the rotating disk technique. Extraction of gold and silver from an oxidized copper-bearing ore was also studied utilizing a statistical experimental design, and these results were displayed in the form of contour plots.

Jan 1, 1993

Conventional logging tools such as density, neutron, and acoustic have ranges of investigation of tens of centimeters. The borehole gravimeter, however, has a range up to hundreds of meters. For example, from the center of a cylindrical orebody 0.22 g/cm3 denser than its surroundings, one can detect the boundary of the orebody at a radius as large as five times its height. More complex structures can be investigated with computer programs. We can predict the usefulness of proposed gravity surveys, or decide which suggested structure is most likely to have caused the results of existing surveys.

Jan 1, 1985

By H. Colijn

Vibratory or oscillatory conveyors can be found in all types of industry, handling virtually any granular bulk material, often at elevated temperatures. These conveyors can be combined with other process functions, such as screening, cooling, drying and dewatering, while conveying. Although construction and installation is relatively simple, the engineering and design analysis of the vibratory mechanics is fairly complex. This paper will discuss the basic types of vibratory conveyors and the analysis of the material movement along the carrying trough.

Jan 1, 1985

By J. E. Brownhill

This paper does not deal with the typical start-up issues of equipment, production capacity or work force. This is a description of the challenges faced and the changes made by the project team to bring to fruition the reconstruction of Port Inland. Many honored traditions and norms had to be overturned to find the winning combination that provided the productivity, flexibility and cost necessary to survive in today's competitive minerals environment. This paper covers the innovation in terms of machinery, operations, and management philosophy that permitted the renovation and reopening of Port Inland as a commercial limestone producer in the spring of 1992. Port Inland, constructed by Inland Steel in 1930, operated as a captive source of metallurgical grade limestone for the steel industry until its closure in 1989. Located in the Upper Peninsula of Michigan on the north edge of Lake Michigan, the operations consist of a deep water port facility with crushing, screening and stockpile storage for 500,000 tons of finished product at the port. Ninety-nine percent of the stone is shipped via lake boat to ports within the Great Lakes. The operation is unique in that both metallurgical Dolomite and Limestone are produced on site. In 1930, Port Inland was at the fore front of technological advancement. It was the first major mining operation to use roller bearings and other equipment innovations. Over the 60 years of operation, Inland Steel placed emphasis on steel making technology and iron ore mining at the detriment of the limestone operation. By the early 80's, Port Inland was no longer a leading competitor. Inland Steel, unable or unwilling to spend the capital to modernize, closed the facility in the fall of 1989.

Jan 1, 1994

? World industrialization, increased urbanization, and population growth are driving a sustained demand for minerals, metals and coal. Energy demand is expected to increase significantly in the coming decades - placing even more emphasis on supply, security and environmental impact issues. ? Several countries are taking steps to nationalize their own resources thus safeguarding their supplies and reducing exports of natural resources. ? Understanding the future availability of critical minerals requires a global perspective. It is essential to know where deposits are located, their reserves and resources, the technologies necessary for production, and the costs of producing and transporting the products to consumers. ? As mining companies look to maintain or increase their operating capabilities and increase their mineral resource bases, the search for commodities expands beyond developed terrestrial regions of the world, to include marine resources. (Figure 1) Operating challenges in these locations include finding skilled workers, building infrastructure, improving recovery technologies and practicing sustainable development.

Jan 1, 2011

By J. Luo

A major design problem for upper seam longwall gate roads that are to be constructed in a multi-seam environment is to predict the effects of stress field changes created by interaction. To quantify these effects, case study data were analyzed to develop empirical stress transfer relationships between seams for both longwall and room and pillar mining. Data analysis showed vertical movement and roof characterization in the upper seam to be controlling factors in damage prediction and, therefore, gate road planning and design. CMRR (Coal Mine Roof Rating) was correlated with the multi-seam roof characterization systems previously used. A WINDOWS-based software package named UGLY (Upperseam Gateroad Longwall Stability) was developed. Results from selected case studies were correlated with upper seam stress predictions.

Jan 1, 1997

By Martin G. Casto

Mixer-settler extractors, among the oldest forms of extraction equipment, have been used since the beginning of this century. Over the past years, a very large number of mixer-settler devices have been designed and operated. Both batch and continuous flow mixer-settlers have been used. The continuous flow mixer-settler extractor offers a great number of advantages over other extraction equipment. The main advantage of the continuous flow mixer-settler is that it is a compact device. A large number of stages can be assembled in a relatively small area, and more stages can be added fairly easily. Many improvements have been made in the design of mixer-settlers. These improvements occurred in almost every phase of mixer-settler' operation; interface control, mixer design, intrastage pumping, interstage flow of the two liquid phases, and stage construction. It is believed that Barstow1 used one of the first continuous mixer-settler extractors. This mixer-settler had concurrent flow within each stage and countercurrent flow overall. The flow for both phases took place by gravity. The Barstow device and other early mixer-settlers had no separate interface control for each stage, therefore, "tilting" of the stages was necessary. In 1934 Holley and Mott2 designed a mixer-settler in which the heavy phase was recirculated within each stage by the use of a valve controlled central line instead of by a pump. Gordon and Zeigler3 in 1939 were among the first to use an adjustable valve to control the interface levels in a mixer-settler, making tilting of the extractor unnecessary. In 1952 Coplan et al. 4 used a modification of the Holley-Mott idea to build a highly improved mixer-settler with flat common walls, and with the

Jan 1, 1971