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By P. O. Akinseye, F. T. Cawood

Mineral royalties are one of the oldest forms of mining taxation, and were initially introduced to extract economic rents from mining. Over time, the royalty regime has become more complex as it was identified as an important policy instrument that can achieve more multi-faceted outcomes. Such a multi-tiered approach in the use of the royalty instrument is also the case with South Africa. With South Africa’s new mineral royalty regime now in place for ten years, it is perhaps time to assess its impact and effectiveness. To carry out this assessment, an econometric evaluative study was undertaken using four major commodities in South Africa, namely gold, platinum, iron ore, and coal. The study explored five different policy options for government to consider and tested them to determine the most favourable one that will realize the regime’s policy objectives. After the assessment, two major options stood out. Hence, this paper seeks to highlight which of the two options is the most favourable for consideration by policymakers. Based on that study, we find that the current structure is effective, but also recommend that the factors in the formula for refined minerals be ‘modified’ to reduce the capped profitability ratio from the current 60% to 30% and the maximum royalty rate for refined minerals from 5% to 3%. The minimum rate of 0.5% during times of depressed mineral prices and no or low profitability will not be affected.

Dec 1, 2021

By H. Schunnesson, H. Fredriksson, D. Johansson, E. Söderström, S. Manzoor, A. Gustafson, M. Danielsson

Fragmentation analysis is an essential part of the optimization process in any mining operation. The costs of loading, hauling, and crushing the rock are strongly influenced by the size distribution of the blasted rock. Several direct and indirect methods are used to analyse or predict fragmentation, but none is entirely applicable to fragmentation assessment in sublevel caving mines, mainly because of the limitations imposed by the underground environment and the lack of all the required data to adequately describe the rock mass. Over the past few years, measurement while drilling (MWD) data has emerged as a potential tool to provide more information about the in-situ rock mass. This research investigated if MWD can be used to predict rock fragmentation in sublevel caving. The MWD data obtained from a sublevel caving mine in northern Sweden were used to find the relationship between rock fragmentation and the nature of the rock mass. The loading operation of the mine was filmed for more than 12 months to capture images of loaded load-haul-dump (LHD) buckets. The blasted material in those buckets was classified into four categories based on the median particle size (X50). The results showed a stronger correlation for fine and medium fragmented material with rock type (MWD data) than coarser material. The paper presents a model for prediction of fragmentation, which concludes that it is possible to use MWD data for fragmentation prediction.

Mar 2, 2022

By F. Rosenblum, K. E. Water, J. A. Finch, S. Moon, Y. H. Tan

Previous work has shown that sulphide self-heating occurs in three distinct stages referred to as Stage A, Stage B and Stage C. In this paper the focus is on the transition from Stage A to Stage B, which occurs at ca. 100OC. Background literature hints that the transition corresponds to the transformation of the rhombic form of elemental sulphur to the more reactive monoclinic form that occurs at 96OC. A test apparatus is modified for adiabatic heating to track the transition. The results support this transformation of sulphur as being key to the transition, and the transition temperature is thus modified to 96OC. Variations in a sample’s response under adiabatic conditions are observed and possible reasons are discussed. Testing in adiabatic mode provides new insights into the sulphide self-heating process that complement the test designed to identify propensity to self-heat. Keywords: Self-heating; Stage A/Stage B; transition; rhombic/monoclinic elemental sulphur; adiabatic heating

Jan 1, 2020

By T. Wallmach

Heavy mineral deposits are a source of the economic important element titanium, which is contained in minerals such as ilmenite, pseudorutile and rutile. In the Ranobe heavy minerals deposit these minerals occur not only as primary unaltered minerals but also display various degrees of alteration resulting in an increased titanium content of the deposit. The presence of the various FeTi-oxide minerals? textural relations is a reflection of geological processes and may ultimately be used to unravel the geological history of the deposit. These minerals have different chemical and physical properties that influence metallurgical tests and the quality of products produced from various mineral beneficiation streams. It is therefore of metallurgical importance that the minerals are well characterized, defined and monitored during preliminary beneficiation tests.

Jan 1, 2007

By Frank Johnson

Between 2000 and 2006, platinum production from the South African mines expanded from 206 to 307 tonnes (DME, 2007). Most of this additional metal has come from traditional ?narrow? reef stoping, generally taken to mean stoping in working places with a mining height of less than 1,5 metres. It is well known that narrow-reef stoping presents safety, technological and ergonometric challenges (Pickering, 2007). In planning for the expansion, which is still continuing, the platinum mining industry realized that it could not simply continue with traditional methods of narrow-reef mining. Particular issues identified were: ? High labour-intensivity: caused by use of hand-held rock drilling machines, labour-intensive support installation and stope cleaning; ? Dependence on rock-drillers: this occupation is no longer an attractive one and there is a reducing flow of new recruits; ? Safety: most of the work is performed close to the new faces, where there is the greatest exposure to the hazards of falling rock.

Jan 1, 2008

By V. Sheikhzadeh, M. R. Sheikhzadeh, A. Haratian, M. Zare

High Pressure Grinding Roll (HPGR) as an efficient grinding technology plays a major role in mineral processing plants. Investigating the effects of this technology on different parts of mineral processing circuits reveals this technology’s capability. In this paper, HPGR grinding effects on an iron ore beneficiation circuit, in comparison with conventional crushing systems were studied. A representative feed sample was taken from an iron ore beneficiation plant, then crushed to minus 6 mm in a laboratory by two methods: HPGR and cone crusher, and finally a concentrate plant circuit was simulated. Plant simulation was performed by doing laboratory tests consisting of grinding, magnetic separation, flotation and filtration on HPGR and cone crusher products, respectively. According to comminution tests results, in particle sizes smaller than 6 mm, a cone crusher product is coarser than an HPGR product. Also, the Bond ball mill work index of the HPGR product was 10% less than the crusher product. Therefore, based on the Bond formula in applying HPGR, ball mill power consumption decreased by 12%. After ball milling to minus 100 microns, magnetic separation tests results showed that the recovery of the cone crusher circuit output was 90.8% and the product Fe grade was 66.4%. For the HPGR circuit these figures were 87.6% and 67.3%, respectively. Therefore, by using an HPGR, a higher Fe grade of the final concentrate was achieved. A flotation test was then performed on the magnetic separation concentrate, where the results showed that the crusher circuit recovery and the sulfur grade of the product were 96.5% and 0.192%, respectively; whereas the HPGR circuit recovery was 97.2% with a sulfur content of 0.185%. Findings revealed that flotation performance in the HPGR circuit was more efficient than the crusher circuit. Vacuum filtration tests on concentrate produced through the HPGR circuit resulted in a moisture content of 12% that was 2% higher than the crusher circuit’s concentrate in the same condition. Keywords: High pressure grinding roll, power consumption, magnetic separation, flotation, filtration

Jan 1, 2020

By J. H. van Laar, L. J. van der Walt, P. L. Crouse, H. Bissett, G. J. Puts

"SynopsisSilicon carbide nanopowders were produced using a microwave-induced plasma process operating at 15 kPa absolute and at atmospheric pressure. Methyltrichlorosilane (MTS) served as precursor, due to its advantageous stoichiometric silicon-to-carbon ratio of unity, allowing it to act as both carbon and silicon source. Argon served as carrier gas, and an additional hydrogen feed helped ensure a fully reducing reaction environment. The parameters under investigation were the H2:MTS molar ratio and the total enthalpy. The particle size distribution ranged from 20 nm upwards, as determined by SEM and TEM micrographs. It was found that an increase in enthalpy and a higher H2:MTS ratio resulted in smaller SiC particle sizes. The adhesion of particles was a common occurrence during the process, resulting in larger agglomerate sizes. SiC layers were deposited at 15 kPa with thicknesses ranging from 5.8 to 15 µm.IntroductionIt is well known that methyltrichlorosilane (CH3SiCl3 or MTS) decomposes to form silicon carbide (SiC) and hydrogen chloride (HCl) as shown in Equation [1]. The reaction kinetics and mechanisms for this reaction are thoroughly reported in the literature (Sone et al., 2000; Papasouliotis and Sotirchos, 1999; Kaneko et al., 2002; Wang et al., 2011)."

Jan 1, 2015

By L. A. Cramer

There are a couple of dozen junior platinum mining companies coming into existence in Southern African and most intend to mine, concentrate the PGM?s in a flotation product and sell the concentrate to one of the major producers in South Africa. The price they will receive for their product and hence the return they achieve for their investment will depend upon the large number of factors that influence the market for such a product. Unfortunately the number of buyers is severely limited as it is dominated by the two major local producers, Impala Platinum and Anglo Platinum. Furthermore the current smelting technology has limited capacity for UG2 concentrates and high nickel concentrates will quickly fill any available base metal refining capacity. Few if any overseas buyers can compete for the bulky flotation concentrate produced. This paper will explore those factors such as metal recoveries, metal prices, operating costs, capacity constraints, deleterious elements, transport issues, metal premiums and discounts that are in play, types of flotation concentrates, processing capital costs, PGM grades, etc and their impact up on what smelters and refiners might be prepared to pay for such PGM concentrates. Ultimately simple graphs and equations can be developed for probably payment terms for such concentrates. Those who negotiate well will move to the higher return section of the envelope and those who use the concentrator facilities to produce the most saleable combination of flotation concentrates will enhance their returns. A deep and firm understanding of the issues surrounding this market is necessary in order to negotiate the best possible price for the seller.

Jan 1, 2008

By P. van der Westhuyzen

Gone are the days of stock-standard diamond beneficiation and final recovery circuits that could, with minor modifications, be adapted to treat any diamond-bearing ore source. A new era has dawned, offering the opportunity to streamline existing diamond processing operations or develop simpler, more efficient, and economical diamond processing plants, with the focus on more efficient comminution, beneficiation, and final recovery. This change in scene has been brought about by: ? The introduction, rapid development, and maturation of multiple comminution, sorting, and recovery technologies ? The need to adapt to a new standard of project approach post the commodity super-cycle phase, where optimizing existing operations and developing scalable, ?fit for purpose? new mines are fast becoming the norm in diamond processing plants in both primary and alluvial operations ? The quest for energy efficiency and lower labour costs ? More remote and inaccessible reserves (under lakes, tops of mountains etc.). This paper serves to identify some technology advances and demonstrates how these could be considered as replacements for or in combination with conventional technologies to arrive at an optimum techno-economic solution. To name a few applications/technologies: ? Comminution: conventional cone crusher, modified/specialized cone crusher, and the high-pressure grinding roll (HPGR). Although significant advances have been made in recent years, this paper only briefly covers comminution within the beneficiation circuit design ? Waste sorting: NIR (near-infrared) sorting, optical (colour) sorting, XRF (X-ray fluorescence) ? Primary concentration by combining dense media separation (DMS) with either XRT (X-ray transmissive), pulsed X-ray, jigs, or pan plants depending on the application, scale, and economics ? Final recovery of diamonds with either conventional X-ray technology, pulsed X-ray technology, or XRT. From recent studies, it can be concluded that there is no longer a standard solution, but rather the ?right? or appropriate solution. Through combining a sound knowledge of the ore source (ore dressing studies or onmine data gathering) and leveraging off the advances in technologies, one is able, through trade-off studies, to arrive at the ultimate techno-economic configuration, the ?right? solution. Emphasis is placed on maximizing diamond recoveries through appropriate technology selection and minimizing the associated costs in an effort to de-bottleneck or improve efficiencies of existing diamond processing plants, or to arrive at the ideal new diamond process plant design..

Jan 1, 2014

By D. He, A. Yaacoubi, A. Baçaoui, K. Boujounoui, A. Abidi, K. El Amari

The effects of utilizing recycled tailings pond water from the flotation plant at the Mining Company of Guemassa (MCG) on galena recovery and selectivity towards chalcopyrite (RPb-Cu) , sphalerite (RPb- Zn), and pyrrhotite (RPb-Fe) were studied at bench scale. The results showed that recycling the tailings pond water in the lead circuit without addition of fresh water gave a good flotation performance in terms of lead recovery (Rpb) (75%) and selectivity towards the other metals: RPb-Cu (54%), RPb-Zn (60%) and RPb-Fe(65%). This allows the water to be recycled at least four times. However, increasing the d80 from 100 μm to 160 μm currently used at the MCG plant had a negative effect on the lead flotation performance.

Nov 30, 2022

By D. Kumar, B. Rai, S. G. Srinivasan, V. Jain

Chalcopyrite and pyrite are among the major gold bearing minerals in the world. The gold content in chalcopyrite and pyrite varies from 0.02 to 200 ppm and 0.01 to 20 ppm, respectively. Apart from gold, chalcopyrite is also the primary source of copper. Thus, the recovery of gold and copper are often associated with the recovery of chalcopyrite and pyrite. Flotation is one of the most successful methods applied to beneficiate chalcopyrite and pyrite. The success of a flotation process depends on an appropriate choice of the flotation collector used to achieve the desired selectivity. A thorough understanding of the atomic structure of the predominantly exposed mineral surfaces can immensely aid in developing highly selective collectors that can exploit both the physical and chemical characteristics of these surfaces. In the present study, density functional theory calculations within the plane wave framework are used to understand the surface structure and reconstruction of the most stable chalcopyrite (001), (100), (110) and (112) and most stable pyrite (100) surfaces. The chalcopyrite (001) and (100) metal-terminated surfaces undergo significant reconstruction and result in metal-metal bond formation in the sub-surface layer while the surface layer is replaced by S-atoms. On the other hand, the (001) and (100) S-terminated surfaces show S—S disulfide bond formation upon relaxation, which are consistent with literature reports. The chalcopyrite (110), (112) surfaces and pyrite (100) surface undergo rearrangement, but no reconstructions in terms of metal-metal or disulfide bond formation are observed on these surfaces. Keywords: DFT, surface reconstruction, pyrite, chalcopyrite, adsorption

Jan 1, 2020

By A. Pareek, V. S. Masampally, V. Runkana

Mineral processing plants, in general, consist of comminution and separation circuits. Rougher flotation is considered as the heart of the separation circuit with concentrate grade and mineral recovery being the key productivity and quality parameters that affect the downstream operations and profitability. Online prediction of these parameters can help improve process performance in real-time. Past efforts to predict flotation cell performance have focused on building physics-based or machinelearning (ML) based models. Although physics-based models are popular in process design applications, ML models are more appropriate for online monitoring, control and optimisation due to their lower computational requirements. Deep learning (DL) is gaining prominence nowadays for application in industrial operations where a large amount of data is available. We have developed a DL model based on long short-term memory (LSTM) neural networks to forecast the two key performance indicators (KPIs), namely, mineral recovery and concentrate grade in a mineral processing plant. Rougher feed characteristics such as mineral grade and particle size distribution, upstream measurable disturbances such as throughput of the comminution circuit and pulp density, and control variables such as aeration rate, pH, and collector addition rate are considered as explanatory variables to train the model. The model was tested with data from an industrial mineral processing plant. For real-time dynamic predictions, the trained model appropriately accounts for mismatch in measurement frequency of real-time process data and off-line laboratory analysis data. Such a time series model can be used as a state observer in model predictive control techniques for optimal control of unit operations in a mineral processing plant. Keywords: Mineral processing, flotation, time-series, dynamic modelling, deep learning

Jan 1, 2020

By M. Abdellatif

"SynopsisCalcined basic nickel carbonate (BNC) concentrate was smelted in a pilotscale DC arc furnace to produce a nickel metal. The furnace was continuously operated for 12 days (24 hour/day), during which twelve different smelting conditions were investigated, with the major variables being reductant type and feed rate, flux composition and addition, and BNC feed rate.The 200 kW DC arc furnace was operated at power levels between 110 and 165 kW and at a total feed rate of 78 to 96 kg/h, resulting in an average slag and metal tapping temperature of about 1650°C. A total of 7.2 t of BNC were smelted, producing about 5.44 t of nickel metal and 2.94 t of slag. Nickel recoveries of 96.4% and higher were achieved, and the slag nickel content was as low as 0.1%. The major impurities in the metal were iron (mostly from oxygen lancing) and carbon. The calculated feed carry-over was less than 0.85% and the graphite electrode consumption was between 2.8–3.3 kg/MWh.IntroductionOne of the most distinctive advantages of DC open-arc smelting is the ability to process fine raw materials without any major issues with regard to the operability of the furnace, metal recovery, and metal quality. This has been demonstrated in Mintek’s DC arc pilot plant facilities over a period of about three decades (Curr et al., 1983). The materials that have been processed include laterite (Kotze, 2002), chromite fines (Curr et al., 1983), manganese fines (Lagendijk et al., 2010), PGM concentrates (Shaw et al., 2013), electric arc furnace (EAF) dust (Denton et al., 2005; Abdellatif, 2002a) and stainless steel (SS) dust (Denton et al., 2005; Abdellatif, 2002a; Goff and Denton, 2004), and petroleum fly ash (Abdellatif, 2002b). The top particle size of such materials can vary from a few millimetres (e.g. laterite) to micrometres (EAF and SS dust). Dusting, whether due to physical carryover of feed or to the arc side reactions, has been proven to be a non-issue. As such, the applications of DC open-arc furnaces have the potential to be extended to other raw materials such as particulate nickel oxide, which has a particle size much less than 100 µm.Nickel oxide is typically produced from laterite ore by sulphuric acid leaching, purification, and precipitation as basic nickel carbonate (BNC) (Rhamdhani, Jak, and Hayes, 2008) or as mixed hydroxide precipitate (MHP) (Mackenzie, Virnig, and Feather, 2006), and finally calcining at moderate temperatures (800–1200°C). The NiO product is very fine, with an average particle size in the range of 10–20 µm and a NiO content of more than 99%."

Jan 1, 2015

By J. N. Van der Merwe

"The probability of survival of coal pillars is a more rational indicator of stability than the safety factor. Over time, pillars undergo reduction in size by progressive scaling of the sidewalls. The probability of survival is therefore not constant but reduces over time. The rate of scaling can be quantified, and the reduction of the probability of survival as a function of time can therefore also be quantified. The paper describes the link between the factor of safety, probability of survival, and reduction of the probability of survival. Using the safety factor, probability of survival, and the time at which the probability of survival will reduce to 50% is proposed as a more rational method of evaluating pillar stability than the safety factor alone.IntroductionCoal pillar strength has long been the subject of research in South Africa and several other coal-producing countries. However, it began receiving serious attention only after the Coalbrook disaster in 1960. The most important outcomes of the initial investigations were the groundbreaking research by Salamon and Munro (1967) that resulted in the well-known power formula for pillar strength, and the work by Bieniawski (1969) that resulted in a linear formula for strength. The former approach was based on empirical back-analysis of failed and stable pillar cases, and the latter on in situ strength tests on large specimens.The Salamon and Munro (1967) formula has been widely used in South Africa and even adapted for application to hard rock pillars by researchers such as Hedley and Grant (1972).At the time of the initial work by Salamon and Munro, there were only 27 failed pillar cases suitable for analysis. It was not possible at the time to determine site- or seam-specific strength, and the result was a general formula for use in all seams in all mining districts. Since that time pillars have continued to fail and the database continued to grow – as of 2013, there were 85 cases in the database. Using the additional data, there have been a number of re-evaluations of the strength formula and it has also become possible to differentiate between the different mining seams and areas."

Jan 1, 2016

By S. Ling, T. Liu, Y. Shang

A new copper-molybdenum flotation technology developed for a certain coppermolybdenum ore is introduced. We achieved copper-molybdenum bulk flotation in lowalkali conditions. Locked-circuit test results showed that the bulk concentrate contained 21.05% Cu and 1.10% Mo, with copper recovery of 87.37% and molybdenum recovery of 77.07%. For the copper–molybdenum separation process of the bulk concentrate, we use a new depressant, BK511, to replace the traditional sodium hydrosulfide. We achieved copper–molybdenum separation through one rougher, nine cleaner, and two scavenger processes. The results of locked-circuit tests showed that the molybdenum concentrate contained 46.19% Mo and 0.75% Cu, with molybdenum recovery of 93.80%; the copper concentrate contained 21.50% Cu and 0.069% Mo, with copper recovery of 99.92%. This new technology overcomes disadvantages of using large amounts of lime, sodium hydrosulfide, and other reagents in traditional copper–molybdenum flotation.

Jan 1, 2023

By NIM REPORTS

Notices CONFRRENCE ON COMPUTRRS IN ENGINEERING The above Conference, which is being organized by the Electrical and Electronics Board of the Institution of Engineer!!, Australia, ill to be held in Sydney on 16th and 17th May, 1974. It is being planned in conjunction with the Sixth Australian Computer Conference and will be held during the week immediately preceding the latter. NIM REPORTS Report No. 1495 A method for the determination of ekmental sulphur on the surface of sulphide minerals. Report No. 1500 The chromatographic separation and determination of nobk metals in matte-leach residues. Report No. 1505 The production of the refractory aluminium saicates, with special refererence to South Africa. Report No. 1517 Computer-controlled flotation plants in Canada and Finland. Report No. 1526 Heat of solution as a control of aqueous-ammonia concentration. Report No. 1529 South African costs of equipment for the metallurgical industry (197).

Jan 9, 1973

The key functions of project evaluation are to assess potential profitability and to develop an effective operational design. For mining projects, design aspects include mining methodology, ore treatment methodology and production rates. All of these characteristics impact on project economics and overall value. Resource models, which form the ultimate basis of project evaluation, typically consist of tonnes above cut-off, grade above cut-off and the spatial distribution (connectivity) of tonnes/grade above cut-off, for one or more variables. Dilution, ore loss and metallurgical recovery are all modifying factors applied to the resource model during evaluation and determination of profitability. A key issue is: how is the value determined? In addition to traditional combination of in situ tonnes/grade, the following merit serious consideration: the concentration of deleterious elements, throughput rates, mining/processing costs and - importantly - metallurgical recovery. Geometallurgy is an emerging field targeted at integrating these issues by identifying either direct measures or proxies for throughput (hardness, grindability), recovery (liberation, mineral shape/texture, etc) and concentrate quality from easily collected macro-, meso- and microscopic data. These 'geometallurgical variables' drive project costs and revenues in a fundamental way. For geometallurgical characterisation to have a real impact on business design, it must enable improved mine planning. When creating spatial estimates for such variables, it is preferable to find proxies that can be measured as close to the intact rock mass as possible. However, spatial estimation of proxies for geometallurgical properties and responses is complex and requires special consideration. Unlike grades, both proxies and absolute measures of geometallurgical variables are not necessarily linear or additive and therefore require very careful geostatistical consideration. In some cases, models must predict extreme values of geometallurgical attributes rather than averages. Incorrect characterisation of metallurgical recovery/throughput can (and has) led to misspecification of the scale of projects, and thus can be seriously value destructive. Aspects of geometallurgy have long been important in iron, bauxite, manganese and coal deposits and are increasingly on the radar for base and precious metal miners. However, as more metallurgically complex deposits are developed and mining of large-scale, low-grade deposits becomes more commonplace, the importance of characterising the metallurgical response in order to generate properly optimised projects will rapidly increase. It is possible that in many `traditional' (ie grades and tonnes) reserve models, the variables that drive the project are missing!

Jan 1, 2007

By O. Dahl, B. Musuku, N. Schreithofer

Recovery of fine pentlandite is proving to be a challenging task in the Kevitsa sequential flotation operations, with over 60% of the nickel losses reporting into the -25μm size fraction. Since commissioning, the Kevitsa process has undergone major changes to address throughput and flotation performance. Major changes were implemented in the configuration of the milling and flotation circuits as well as in the operating conditions and reagent regime. Some of these changes improved nickel flotation while others deteriorated flotation performance. Most of the changes have had a direct impact on nickel flotation. This paper reviews the systematic analysis, laboratory testing and salient changes done to the process with special focus on the impact on the fine pentlandite flotation. Keywords: Blending, Flotation, Chalcopyrite, Pentlandite, Fines

Jan 1, 2020

By M. H. Dehghanpoor, M. Zivdar, M. Torabi

"A hydrometallurgical route was developed to extract metals such as gold, silver, copper, and selenium from anode slime from Sarcheshmeh Copper Complex in Iran. For the extraction of copper by leaching, the anode slime was heated and stirred with 4 M sulphuric acid in the presence of oxygen. Optimal conditions for recovery of copper were temperature 80°C, mixing time 5 hours, and oxygen flow rate 2 L/min, resulting in a copper recovery of 94.47%. Silver and selenium were dissolved by leaching anode slime from which the copper had been removed with nitric acid. For gold extraction, anode slime was heated with aqua regia at 90°, and the gold then extracted with 2-ethyl-hexanol at a concentration of 0.5 M and phase ratio of 4. The extract was then stripped with soda solution at pH=10.5 and a phase ratio of 5. Finally, gold was recovered by precipitation with oxalic acid at a ratio of mass to volume 10 g/L. Total gold recovery was 80%. IntroductionDuring the electrorefining of copper, some metals are accumulated in the byproduct anode slime, which is an important source for recycling and recovery of these metals (Petkova, 1994). In this paper, a hydrometallurgical route is described for the recovery of precious metals from copper anode slime of Sarcheshmeh Copper Complex, which is located in southeastern Iran .Copper anode slime is black or gray powder with a particle size less than 200 mesh. Approximately 2 to 20 kg of anode slime is produced per ton of copper cathode. The slime is characterized by higher amount of Ag, Se, Pb, and Cu compared to other metals and a very low Au content (Khaleghi and Ghader, 2013).The copper anode slimes are composed of 11.69% selenium, 3.93% copper, 5.26% silver, 0.13% gold, and 45% barite, plus lead, tellurium, antimony, sulphur, and silica with small amounts of nickel, iron, zinc, and bismuth. Gold is one of the most important noble metals due to its wide applications in industry and economic importance, so recovery of gold from slime is more appealing than that of other metals. According to the World Gold Council (2013), the demand for gold has increased during the last decade. This increase is due not only to the increasing demands of the jewellery market, but also to the increasing demand for gold in industrial as well as medical applications (Ranjbar et al., 2014)."

Jan 1, 2016

By W. Bleloch

Published in the Journal, September 1970, and presented at a colloquium on 'Future of the Steel Industry', 17th March, 1971. Errata (a) The final sentence in the penultimate paragraph, left hand column p. 34 of the text should read: 'In the hot regions of the bosh and stack the C+CO2=2CO reaction proceeds to CO from coke carbon and carbon dioxide generated by reduction of iron oxides by CO (the so-called solution loss of carbon)'. The italicised words have been omitted in the text. (b) Temperature in Fig. 3 is K not C. (c) In Fig. 9, connection from top plate of column 10 to heat exchanger 9 has been omitted. DISCUSSION J. B. BEEDON AND C. J. JONKER* Dr Bleloch's paper has outlined the advantages of recycling stack-gas of low nitrogen content in the blast furnace. In the first instance it would appear to be extremely beneficial in controlling the hearth temperature and allowing a 100 per cent oxygen-blast to be used. On a second point however we have to disagree. It is claimed that heat is liberated in the combustion zones by the oxidation of CO to CO2 near the tuyeres and in the subsequent reduction of the CO2 by CO. The author has hypothesized as follows, and we quote: 'The C+CO2=2 CO reaction in the outer combustion zone at about 1 700°C is no longer endothermic due to loss of stability of CO2 and its consequent dissociation into CO and free oxygen.' This statement requires closer examination. If we consider the individual events occurring with the CO in the recycled topgas, with the oxygen in the blast and with the coke in the burden, as done by Dr Bleloch, the following heat considerations emerge. All heats of reaction are calculated from the enthalpy values of each reactant and product, as well as the temperature dependence of their molar heat capacities. (a) At the tuyeres: CO+1/2 O2-+CO2 . . . . . (1) CO, CO2 at 500°C; O2 at 25°C. ?H reaction = -65 000 cals/mole CO The reaction (1) is exothermic. (b) In the outer combustion zone: CO2+C?2 CO . . . . . . . . (2) C, CO at 1 700°C; CO2 at 500 0C. ?H reaction = -56 000 cals/mole CO Reaction (2) is endothermic. The overall heat gain of reactions (1) and (2) is ?H=+56 000 - 65 000= -9000 cals/mole CO i.e. the overall reaction is slightly exothermic, the amount of heat liberated is however smaller than suggested by Dr Bleloch. (c) The dissociation CO2+CO+1/2 O2 . . . . . (3) is a highly endothermic reaction at 1 700 0C, requiring 82 000 cals/mole CO2 to proceed to completion. Furthermore, this reaction (3) is energetically not favoured to proceed, as can be observed from the free energy-temperature relationship of figure (3), which favours the formation of CO2 at 1 700 0C. Hence direct dissociation of CO2 at 1 700 0C appears to be unlikely.* The concept of recycling topgas is however still intriguing from many other points of view. Apart from providing a very efficient method of hearth temperature control, it will create a much higher CO partial pressure in the stack. Whether the rate of indirect reduction in the stack will be proportional to this partial pressure or not is un-

Jan 9, 1970