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By S Hapugoda

Iron ore oxide and oxyhydroxide minerals such as haematite (eg various types of martite and microplaty haematite), different forms of goethite, magnetite, hydrohaematite and kenomagnetite were analysed using optical microscopy, scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) techniques, to determine the type and proportion of deleterious elements present and the chemistry of associated gangue minerals. The aim was to characterise elements potentially deleterious for agglomeration and steelmaking, eg sulfur, phosphorus, aluminium and silicon and correlate their distribution with mineral texture and association, to provide feedback on downstream processing performance and product quality.Examples of characteristic mineral associations are shown from various genetic styles of iron ores, including magnetite banded iron formation (BIF), BIF-derived martite-goethite and skarn-type magnetite ores.A number of examples are presented demonstrating the benefits of the use of combined techniques of reflected optical microscopy, SEM and EPMA data to reliably identify ore and gangue minerals and their associations in different types of iron ores.

Jul 11, 2011

By K G. Fleetwood

This paper proposes an approach to determine the influence of non-ideal detonation characteristics related to the charge diameter, explosive type and confinement conditions on the available shock energy of ANFO and a representative chemically-sensitised (gassed) emulsion. The proposed degrees of non-ideality of the two different blasting agents are indicated by the Gurney ratios, determined from existing cylinder expansion testing data. The influence of the non-ideal detonation properties on blast design and performance are also compared using a series of theoretical, equal powder factor open pit blasting patterns with hole diameters ranging from 102 mm to 270 mm. The non-ideal shock energy factor (NSEF), which is the available shock energy per tonne of blasted material (MJ/t), is used to compare the different blasting patterns as charged with either ANFO or the gassed emulsion of equal charge density (0.85 g/cm3). The intended purpose of this investigation is to provide explosive users with an approach to compare different explosive types or charge diameters in the absence of dedicated non-ideal detonation modelling, which is generally not available to explosives users.The results of the comparisons suggest that at low charge densities, the example gassed emulsion displays a higher velocity of detonation (VOD) than ANFO in smaller charge diameters but similar degrees of non-ideality (based on proposed Gurney ratios). The results also suggest that the confined, non-ideal gassed emulsion VOD at hole diameters greater than 270 mm can be less than ANFO due to the low density effects on the emulsion matrix. The differences in non-ideal detonation properties and Gurney ratios between the ANFO and gassed emulsion resulted in gassed emulsion NSEF values ranging from 15 per cent lower to 65 per cent higher than ANFO for equal powder-factor patterns in blasthole diameters from 102 mm to 270 mm.

Nov 8, 2011

By N Steenkamp, L Furstenberg, W Cele, M Richter

Managing productivity and improving efficiency for a healthy return on capital employed have become key mining industry strategies under prevailing tough global market conditions. However, achieving this in a multisystem environment such as a mining operation can be daunting. The field of discrete event simulation offers some relief, giving engineering teams insight into multivariable systems and stochastic processes. It allows for integrated system thinking and domain expertise to be woven into project thinking fibre. Directed system optimisation and therefore improved efficiency becomes possible. Furthermore, capital discipline accrues from optimal upgrade investments. This paper illustrates the practical application of this approach by reviewing a typical case study for a direct shipping iron ore operation. Dynamic simulation was used to establish maximum processing plant capacity under varying material characteristics and identify capital-efficient upgrades for increasing production.The study started with descriptive statistical analysis of existing data. Discrete equipment and system capacities were defined, followed by static plant mass balance calculations to establish bottlenecks and overall static capacity. Equipment ‘uptime’ and ‘downtime’ analyses established system and overall plant availability and utilisation. From this information, a dynamic simulation model could then be developed and initially calibrated against actual plant performance to verify its robustness. Once confirmed to accurately represent existing plant dynamics, system capacity response to variable changes could be tested to ultimately determine maximum plant capacity. Additionally, plant optimisation was incorporated to arrive at optimal upgrade points. Maximum capacity and necessary upgrades were established as a function primarily of feed size distribution. Additionally, the interfacing effects of rehandling feed material to the final product grade and potentially to life-of-mine were established as important outcomes. The results of the study illustrate the value of using dynamic simulation models to realistically and cost-effectively increase throughput.CITATION:Cele, W, Furstenberg, L, Richter, M and Steenkamp, N, 2015. Capacity evaluation of iron ore processing facilities utilising dynamic simulations, in Proceedings Iron Ore 2015, pp 597–604 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By S Utili, A Agosti

The Overall Slope Angle (OSA) of pitwalls plays a crucial role in the financial return of an open pit mine. In current practice, pitwall profiles are designed to be planar in cross-section within each rock layer, ie the profile inclination across each layer tends to be constant. A new slope design software, OptimalSlope, has been recently proposed to determine the geotechnically optimal profile shapes for the pitwalls of mines. OptimalSlope seeks the solution of a mathematical optimisation problem where the overall steepness of the pitwall to be designed is maximised for an assigned stratigraphy, rock properties (unit weight and strength) and Factor of Safety. The geometry of the benches is provided as input to OptimalSlope. The results obtained so far on three mine case studies in isotropic rock masses (Utili et al, 2022; Agosti et al, 2021a, 2021b) show that optimal profiles are up to 5° steeper than their planar counterparts – ie the planar profiles exhibiting the same FoS – leading to realising significant saving on waste rock and as a consequence Net Present Value increments and carbon footprint reductions. OptimalSlope algorithms have been modified to deal with anisotropic rock masses characterised by direction dependent shear strength. In the paper, the case of rock masses in banded iron formations (BIF) is tackled. A data set of anisotropic rock shear strengths typical of Western Australia is considered. The Snowden modified nonlinear model was employed to characterise the anisotropy of the rock mass shear strength. From the OptimalSlope simulations performed emerges that optimal pitwall profiles can increase significantly the Overall Slope Angle in comparison with planar profiles featured by the same Factor of Safety. LEM stability analyses of all the profiles were also performed by Rocscience Slide 2 to independently verify the FoSs of the optimal profiles obtained.

Nov 29, 2022

Zinc sulphide concentrate from Mount lsa, Australia, was leached in acidic sulphate-chloride solutions using ferric ions as oxidants under atmospheric pressure. The parameters of temperature, particle size and concentrations of ferric and chloride ions were evaluated.The shrinking core model can be used to describe the leaching which is limited by the electrochemical processes in the initial leaching stage, and by both surface reaction and pore diffusion processes subsequently. The apparent activation energy measured in the initial leaching stage is 49 kJ/mole over the temperature range 60 to 90°C.About 99 per cent of the contained zinc in the -45+38 µm particle sample dissolved at 90°C in a 0.5 M H2SO4/0.1 M Fe2(SO4)3/0.8 M NaCI solution within two hours. Some nine per cent of sulphide sulphur was oxidised through to sulphate; the remainder was convened to elemental sulphur.The mixed sulphate-chloride system has advantages over separate chloride and sulphate systems due to the low reagent cost, high leaching rate and possible selective leaching of zinc sulphide concentrate with high lead contents.

Jan 1, 1994

Successful management is ultimately measured by return on shareholders' funds. This is the inescapable and inexorable discipline that ultimately rules every investment. Shareholders today are predominantly, and increasingly, the superannuation funds and insurance funds of almost all of us. We have already reached the situation in Australian investment history in which the best interests of employees can be very directly identified with the best interests of the owners of the capital invested.

Jan 1, 1992

By S Jeffrey, S Mundell, F Arboleda

In the current cycle of low commodity prices and rising costs, mine managers continue to focus on optimising mine performance and productivity. A critical component of strengthening performance and productivity is ensuring material is routed correctly and efficiently through the core mine production activities of drilling, blasting and grade control.By the time a blast is planned, an enormous amount of intellectual property has been invested in the exploration, resource development, feasibility studies and mine planning activities. The value of that knowledge is either realised or diminished during mine production. Efficient execution of the process is critical and is reflected by the quality and timeliness of the information produced.Multiple teams are involved in the mining extraction process. These teams are all under time pressure to keep the mine equipment operating. One of the root causes of this pressure is the dependency between the teams. They do not operate in isolation, but are a link in a chain depending on the outcomes of each activity. It is essential communication is efficient so tasks can be completed according to the production schedule. Unfortunately, communication fails when unintegrated systems are used because of:- different teams seeing different data, hence there is not an overall, up-to-date view of progress and priorities- lack of cross-functional visibility of data leading to failure to identify errors in time to address or correct issues- teams tending to be siloed and focusing on their part of the process rather than the overall objective.With different systems used for the parts of a common goal, supervisors and managers lack visibility of the process. This makes it difficult to identify process improvement opportunities.Streamlined communications help consolidate all data and activities resulting in improved cooperation between mine production teams. This outcome increases the confidence and efficiency of material routing decisions. It also reduces potential impact to mine performance from errors in early stage tasks like drilling and grade control. Having everyone collaborating off the same trusted data, helps teams identify with common goals and find business improvement opportunities as they appear.CITATION:Arboleda, F, Mundell, S and Jeffrey, S, 2016. Driving mine performance through communication, in Proceedings International Mine Management Conference, pp 117-124 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

In considering the organization of research, it is necessary to know just what research is, what objects are in mind when setting out to conduct research, and what are the functional units which are required to enable a coordinated effort in research to proceed.The dictionary defines research in the following terms: Laborious and patient search, as for truth, diligent inquiry or examination in seeking facts or principles; inquiry, scrutiny; to search or examine with continued care; to seek diligently; to search again; to examine anew.This is, of course, simply a formal definition, but the reference to "labour", "patience" and "diligence" should be noted.The following quotation from an answer to the question "What is Research?", published recently in a technical journal, puts some life into the formal definition:- Essentially, it (Research) is nothing but a state of mind a friendly, welcoming attitude toward change. Going out to look for a change instead of waiting for it to come. Research, for practical men, is an effort to do things better... The research state of mind can apply to anything: personal affairs or any kind of business, big or little. It is the problem-solving mind as contrasted with the let-well-enough-alone mind . . . It is the "to-morrow" mind instead of the "yesterday" mind. Note the statements that: Essentially, it (Research) is nothing but a state of mind, and the research state of mind can apply to anything.

Jan 1, 1950

By R Osterman

As mining companies have to go deeper in search of ore and coal, the importance of protecting the highwall increases. Wall fatigue also increases with importance of the long life expectancy of a highwall, in particular the impact of fatigue influenced by resonance. Resonance is the tendency of a material to oscillate with greater amplitude at certain frequencies when exposed to a periodic force. Until recently, only dominant frequencies, either natural or induced, were all that could be measured through the fast Fourier transform of the blast-induced wave form.This paper presents a novel method to accurately predict the resonant frequency of a highwall. In fact, the method can predict the natural frequencies between any two monitoring points placed in line with the source of impact, and as such it can be used to determine the resonant frequencies of any physical object. The method not only predicts the resonant frequencies of the material; it predicts the structural response of the total frequency spectrum. This method helps describe the response of a mechanical structure to excitation. It describes the structure’s efficiency in the use of energy, that is, whether energy is dampened or consumed in resonance.The initial predictions have been so accurate that it made it possible to determine the fundamental frequency and the first six harmonics of a highwall in a northern Queensland coalmine. With the use of electronic detonators, the blast can be timed with a repeating delay to create an induced artificial frequency that has been determined to retain the least amount of energy.CITATION:Osterman, R, 2015. Transfer function – new method to accurately predict resonant frequencies of a highwall, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 233–244 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By I Sucholutsky, D M. First, D Mogilny, F Yusufali

Machine learning is creating value in all facets of the mining industry, from exploration to production. The authors provide an accessible, high-level introduction to artificial intelligence (AI), machine learning (ML), and deep learning (DL); the latter being widely recognised as one of the most powerful forms of ML. In particular, the authors will introduce deep learning models known as convolutional neural networks (CNNs), how they are applied, and the economic considerations necessary for determining when DL may be the right solution to de-risking complex block modelling problems. The authors present preliminary results from the mineral resource modelling study of the Jundee orogenic gold deposit, Yandal belt/gold province, Western Australia. The primary goal was to identify the direction and location of the narrow gold veins more accurately and demonstrate how non-linearly correlated elements are used as direct inputs to the resource model to assist with the target element’s grade prediction. This demonstrates that: (1) existing techniques for finding correlations between assayed elements do not adequately reflect the complex geology of the asset, (2) nonlinear correlations that are difficult to model as simple mathematical functions are representative of geological patterns in a deposit, and (3) non-linearly correlated assayed data, fed as inputs, increase the performance of the resource model as reconciled through blind tests. To conclude, the authors hypothesise that the patterns represented by the DL block models may be revealing the results of overprinting geological processes that generated mineral deposits. For example, the primary hydrothermal processes that deposited metals created depositional patterns that become particularly complex as a result of being overprinted, in part or in whole, by secondary physicochemical processes. This may explain why non-linear geochemical relationships have the capacity to generate more accurate block models of mineral deposits.

May 24, 2023

By D Anderson, W Timms

"A geotechnical centrifuge can characterise and model the interaction of tailings and fluids over very long time periods by accelerating drainage and consolidation processes. This technology can be considered an environmental ‘time machine’ for designing and evaluating tailings storage projects and verifying numerical models. The Broadbent G-18 geotechnical centrifuge (2 m diameter, up to 875 rev/min) and associated equipment is a unique facility commissioned in 2011 at UNSW Australia for applied research in low-permeability materials such as mine tailings. Two centrifuge modules are available: the permeameter module for characterisation and physical modelling and the strongbox module for physical modelling.This paper presents examples of geotechnical centrifuge applications for the: consolidation of slurries and dewatering design of earthen barriers compatible with tailings chemistry prediction of contaminant mobility. The specifications and capability of the UNSW Australia geotechnical centrifuge and associated instrumentation is also presented, along with preliminary analysis of the confidence intervals associated with permeability testing of a set of samples of varying heterogeneity. Drainage velocity through a mine tailings sample increases linearly with g-level in the centrifuge permeameter until tailings consolidation occurs. Alternatively, geotechnical centrifuge experiments can be designed to limit consolidation so as to quantify permeability changes that may occur with geochemical interactions between fluids and mine tailings or earthen containments. Reactive solute transport through mine tailings can be simulated at realistic solid:liquid ratios when chemical equilibrium is maintained during geotechnical centrifuge testing. Carefully designed physical models of tailings disposal tested at accelerated gravity can therefore provide a realistic evaluation of tailings consolidation and drainage and the potential for subsurface migration of contaminants from mine tailings over long time periods.CITATION:Timms, W and Anderson, D, 2015. Geotechnical centrifuge technology for characterising the interaction of tailings and pore water over decadal time periods, in Proceedings Tailings and Mine Waste Management for the 21st Century, pp 247–252 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 27, 2015

By A B. Richards

Time window analysis that limits the explosive mass fired within a specified time window (commonly eight milliseconds) has been used for many years in blast design by explosives engineers. Despite several warnings in the past that this technique has limited practical or scientific basis and, in many cases, does not effectively control vibration, almost every textbook and blasting manual refers to time window charge mass limits as a primary vibration control technique. It has become entrenched in some blast vibration management plans, despite being inappropriate for the particular situation. With the flexible initiation timing available with electronic detonation almost a practical reality, and the 8 ms constraints in-built into the signal tube initiation system thereby lifted, it is timely to review the significance of the 8 ms time window in controlling blast vibration. This paper re-visits the original research that led to the development of the 8 ms criteria and the non-supportive conclusion of the original researcher. Because airblast was not measured, the 8 ms time window was never intended to be applicable for airblast control. Examples of blast designs are given in this paper that comply with the 8 ms time window limit that result in substantially increased air and ground vibration, together with examples of blast design that does not satisfy time window considerations, which results in reduced air and ground vibration. Techniques that identify wavefront reinforcement, due to the combined effect of drilling pattern and delay sequence, can assist explosives engineers to avoid high blast vibration situations that result from the inappropriate application of time window techniques and other adverse delay combinations.

Jan 1, 2003

By Richards BG, Komdeur W

Instability in spoil piles and in high wall slopes in natural overburden has been ex- perienced at Utah's Goonyella Mine since com- mencement of operations in early 1971. Annual production targets, although gener- ally met since the commencement of operations, required modifications to stripping and mining techniques and the rapid re-scheduling of oper- ations around unstable areas, but culminated in the earlier than planned acquisition of addit- ional stripping equipment. An understanding of failure mechanisms was developed within a collaborative study of pitwall instability between Utah Development Company and the C.S.I.R.O. Division of Applied Geomechanics. Results showed that pitwall instability occurs as structurally controlled deformations along planar failure surfaces; spoil pile failures are precipitated by moist- ure ingress and subsequent loss of strength of base layer materials; highwall failures de- velop over areally extensive bedding planes in conjunction with inclined and subvertical fractures caused by overburden blast damage.

Jan 1, 1978

As this district is so far distant from the other mining centres and its mode of approach so circuitous, I am afraid that many residents of other portions of the Commonwealth never think of paying this" Australia's Silver City" a visit, to learn personally the many and various lessons everywhere available, and to become familiar with the really wonderful and interesting features and deposits (which pature has so lavishly bestowed in the mineralogical world) yet seemed to almost ignore or overlook when disposing of topogr,aphical beauties of landscape and vegetation) unless professional or business duties require their presence here. So it is to those whose life is necessarily spent in other parts of the States where they answer their call of duty, and yet feel an interest, either for business or other reasons, that my paper is specially addressed and prepared, and for that reason I witl endeavour to make my remarks more of an explanatory than a dictatorial nature. I feel sure that there. are many members of our Institute who are much more familiar, and have had many more years' experience in the various methods of timbering, filling, and ore extraction, etc., than myself, but I hope that over I6 years' experience in connection with mines and engineering works, the last six of which have been spent in Broken Hill, where, I have been very closely connected.

Jan 1, 1903

By G van Niekerk, M Wortley

Screening is a critical part of many mineral processing circuits and keeping the aperture of the screening media within specification is vital to ensure efficient performance of the processing plant. Typical ways of estimating and/or measuring the wear of the screening media vary from very subjective methods (for instance, using the human eye) to manually checking the width of a few of the more severely worn gaps with a measurement device. Subjective methods can be flawed by human error while manual checking can distort the polyurethane or rubber materials that are used in several types of screening media. All of these errors can cause either premature replacement of panels or, even worse, poor screening of the material.Metso Process Technology and Innovation (PTI) and Metso Screening Media Solutions (SMS) have developed an innovative method that measures screen aperture using advanced image processing techniques. Field trials of the device are presented in this paper, which shows the comparison between the different methods of measuring apertures. Case studies demonstrate how the system, when combined with ScreenTrack, MetsoÆs industry leading maintenance system, and screening media, is providing users with the best possible screening solutions.

Sep 26, 2011

By Dunlop A. C

A brief study from the Mt. Bulga prospect com- pares the chemistry and mineralogy of different soil fractions and other materials to suggest a sequence of surficial metal dispersion from adjacent gossans, which may have relevance for geochemical exploration in semi-arid terrains. v v v v v JIV-- v v v v a o v o/ v v v v 1 v v lv ./v '' 1 v 16400N ..I v 1635014 v 1630014 .:1 ò.t SILURIAN sillstone " lelsic volcanic sillstone -sandstone ORDOVICIAN Eandesite o quartz float gossanò pits doOP Iv o shalt v _--'fault v 1---1 soil traverse v v v v 0 100 200 mm e Fig. I Local geology and location of soil traverses, Mt. Bulga (compiled from Chisholm, 1976). The Mt. Bulga prospect in central New South Wales is a small but well documented volcano- genic massive sulphide occurrence (450,000t of 0.8% Cu, 1.3% Pb, 5% Zn and 0.45 g/t Au) Cambrell and Kirk (1974), and Chisholm, (1976). Mineralization is localised near the interface of felsic pyroclastics with overlying silt- stones and along adjacent faults (Fig. 1). In this area with a Koeppen type cf6 climate, soils are thin and skeletal along ridges with thicker and better differentiated profiles with a colluvial component up to 2m thick developed

Jan 1, 1988

By S McEachern, J Lowe

An important issue currently facing the mining industry in Australia is the management and cost to the industry and other stakeholders of entry into and exit from towns and their communities. These costs can be environmental, social, economic, political or reputational. The ability of companies to engage the trust of stakeholders, including: communities, governments and investors, is critical, and corporate reputation plays a significant role in this. For the industry to secure a long-term and sustainable future, it must have the technical, business and reputation assets to proceed in a cost-effective, environmentally acceptable and socially supportive way. This research assesses reputation as a critical competitive issue for mining companies, as technology and information make mining more predictable; the physical and human assets of mining companies are less likely to be the critical resource in a Resource Based View model of competitive advantage. The proposition is that in mining today, reputation as it facilitates day-to-day operations, regulatory zeal and access to new mine sites will become the rare, inimitable and valuable resource for mining companies. This paper reports on an ongoing research program to evaluate the impact a mining companyÆs reputation(s), with its various stakeholder groups, has on a companyÆs ability to sustain competitive advantage. Integral to this study is to develop an understanding of the relationships between mining companies and their stakeholders, and the importance of corporate citizenship polices to reputation and hence to corporate sustainability. Through the identification of the drivers of reputation for the various stakeholder groups, a model of reputation formation will be developed and also reputation measures for the mining industry in Australia. The preliminary findings of this research, the results of an industry focus group conducted with representatives from regional mining operations, are reported. The industry focus group was designed to enable a better understanding of who are the main stakeholder groups and how they regard mining companies and to inform the second stage of the research project a Delphi Study of the drivers of reputation by stakeholder groups. The aim of this research is to further the understanding of the relationship between corporate citizenship, reputation and performance in the mining industry, thus assisting companies to strategically manage their corporate citizenship investments.

Jan 1, 2006

By B H. Yin, S Mendoza, M Nusheh' C W Bumby, A Zhang

Hydrogen-direct-reduction of iron ore in a vertical shaft furnace is a potential process that could significantly reduce CO2 emissions from the steel industry. This approach requires the pelletisation of iron ore fines, which then undergo high temperature induration to strengthen the pellets before they can be fed into the shaft furnace. Here we report on investigations into the disc-pelletisation behaviour of New Zealand titanomagnetite ironsand, and its subsequent induration and hydrogenreduction behaviour. Initial studies focused on the effect on pellet strength of varying ironsand particle size and induration conditions using bentonite and a commercially sourced carboxymethylcellulose binder. Green pellets formed with ironsand of average particle size of 65 μm exhibited optimal strength. The compressive strength of these pellets after induration at 1200°C for 2 hrs in air was measured to be 976 N. Interparticle bonding within the indurated pellets occurs due to a combination of titanohematite recrystallisation (from oxidation of titanomagnetite), and the formation of a liquid bonding phase due to interdiffusion with the bentonite and subsequent melting. Further investigation with various binders showed that a combination of both organic and inorganic binders was essential to achieve optimal pellet strength. Carboxymethyl-cellulose binders provides green strength, whilst inorganic binders such as bentonite promoted high indurated pellet strength. Hydrogen reduction tests in a thermogravimetric furnace showed that all the pellets could achieve a maximum reduction degree of 97 per cent at 1100°C, indicating that the different pellet preparation procedures had no significant effect on reducibility. Pellet recipes developed in this work are now being used to investigate vertical shaft hydrogen-DRI processing of NZ ironsand in a kg-scale laboratory reactor.

Sep 18, 2023

By K J. McDonald

All commercially available zircon sands contain radioactivity sourcing from the decay of trace amounts of contained uranium (U) and thorium (Th). The fine particle size zircons of the Horsham area in the Murray Basin region of Victoria, Australia, contain significantly more (about twice) Th+U than those commercial zircon sands. The marketability of these fine-grained zircon sands is likely to rely on the removal of these radioactive impurities. CSIRO Minerals have been working for some time to develop processes for the removal of the radioactive impurities from zircon. It is generally agreed that it is quite impossible to leach U and Th from zircon, however, the Heat and Leach (HL) process, described in detail in Aral and McDonald (1999), reduces the radionuclide levels significantly. The identified (HL) process aims to leach uranium and thorium selectively from a decomposed zircon. The novelty of the process is that a large part of the leached product can be reconstituted to a low radiation zircon by a subsequent heat treatment. The HL process uses a flux mixture of sodium carbonate and calcium borate to decompose the zircon at relatively low temperatures (900 to 1150¦C) and a weak acid (0.5M HNO3; 80¦C/0.5 h; pulp density ten per cent) to leach the radionuclides selectively. The process leaves the major components (ZrO2 and SiO2) behind with little loss. The HL process for example lowers the U+Th content of a Murray Basin zircon from 1000 ppm to 400 ppm U+Th. Among the radionuclides more U progeny is removed than the Th series radionuclides. This is very significant as the radioactivity of U series is 2.5 times more that from the Th series. Therefore the reduction in the radioactivity level of zircon is more than the reduction in Th+U indicated by XRF analysis. A schematic flow sheet of the HL process is shown in Figure 1. Although the HL process successfully lowers the radionuclide levels in zircon sands, the final product contains significant amounts of sodium (up to 14 per cent Na2O) and small amounts of CaO. By comparison, the sodium content of the commercial zircon sands is in general 2O. Zircon is used mainly as an opacifier in tile glazing where the addition of ten to 15 per cent zircon to a translucent base glaze gives the sanitary white colour to the tile surface. Opacification is the result of the refractoriness of zircon particles at the glaze firing temperatures that is generally around 1050¦C.

Jan 1, 2001

By N Bezuidenhout

The performances of ten field-scale experimental final covers were evaluated over an eight-year period. The covers were evaluated as part of the rehabilitation of acid generating coarse coal reject dumps and opencast coalmines in the Northern KwaZulu Natal province in South Africa. The main purpose of the experimental covers was to restrict rainfall infiltration into acid generating coal discard. The mean average rainfall over the monitoring period was 839 mm with 84 per cent occurring between October and April. The average evaporation was 2100 mm. The site is described as a ædry siteÆ since the evaporation exceeds rainfall by a significant margin. Approximately 30 per cent of rainfall infiltrated the uncovered cells. Rainfall infiltration into the fine coal discard was reduced to 20 per cent and 15 per cent for a 300 mm and 500 mm cover respectively. Infiltration was reduced to ten and 12 per cent of rainfall for fine coal discard provided with a 1000 mm double soil cover and a compacted bottom layer. This relatively high infiltration was probably caused by moisture being entrapped in the bottom retentive layer, and not being released by evapotranspiration. The best performing cover comprised 1000 mm single soil with a compacted bottom layer and infiltration was reduced to four per cent of rainfall. Rainfall infiltration into sloped cells varied between seven per cent and 14 per cent of rainfall. The computer software, SoilCover, was used to predict infiltration and moisture content in the cover. Predictions of rainfall infiltration were accurate, but were less accurate for covers where the hydraulic properties of field compacted soils were not adequately characterised. Oxygen ingress was significantly reduced for cells provided with a 1000 mm cover. Oxygen concentrations were generally below one per cent, with the exception during exceptionally dry periods when the cover dried out, resulting in increased oxygen ingress. For other covers, and the uncovered cells, oxygen concentrations were close to atmospheric concentrations. During the eight-year monitoring period, acid breakthrough occurred in five of the cells, including three uncovered cells, one cell with a 300 mm cover and one sloped cell. In contrast, cells covered with 1000 mm, bottom compacted soils shows a marked improvement of leachate quality, indicating that sulfide oxidation processes have been slowed. There was a distinct relationship between oxygen ingress and leachate quality for all of the cells. No cover degradation was evident over the eight-year period, except for some erosion observed on a sloped cell. The results indicate that the onset of acid drainage can be delayed by perhaps hundreds of years and salinity loads can be reduced by more than 90 per cent, if coarse coal reject dumps in the KwaZulu-Natal provinces in South Africa are provided by an adequate cover system. These research outcomes can be extrapolated and applied to other dry site regions where similar materials are being considered.

Jan 1, 2003