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By D. Tao, R. Honakey, B. K. Parekh

The dewatering of stable phosphatic clay suspensions generated from phosphate beneficiation in the central Florida is an issue of practical and theoretical importance. Because of its tiny particle size and surface charge, the phosphatic clay takes up to 20-30 years to settle in water and causes environmental, aesthetic, economic, and handling problems. An efficient and cost-effective dewatering/consolidation process for phosphatic clay is of great interest to the phosphate industry in Florida. In this paper, the consolidation and dewatering behavior of phosphatic clay was studied by use of anionic flocculants with and without sand addition. The effects of pH, initial polymer concentration, polymer dosage, polymer addition steps, and metal cations (K+, Ca2+, and Al3+) on the flocculation of phosphatic clay have been studied. Experimental results indicated that clay suspensions were well flocculated at pH 10.5 by DPW-1-1355 and Magnafloc 5250 flocculants acquired from Ciba Specialty Chemicals. Sand particles from phosphate flotation added to the clay slurry promoted flocculation and increased clay consolidation. K+ showed good performance to improve the flocculation characteristics by neutralizing clay surface charge. The adsorption mechanisms of flocculants on clay particles were also discussed in this paper.

Jan 1, 2006

By Andrzej M. Wala

A knowledge of the friction factor (K-factor) is necessary in planning and designing mine ventilation systems for least cost and highest effectiveness. The friction factor used must be accurate and reliable for correct estimation of airway resistances. At present, the friction factors are determined by using tables of published values. These values were established principally for metal-mine openings having small effective areas. This presents a problem to the ventilation design engineer whose responsibilities center around the design of effective ventilation systems for large room-and- pillar mechanized underground coal mines. Friction factors selected from these tables could be excessively conservative for large scale room-and- pillar operations. With only limited data on the K-factor (which are considerably site dependent) for Kentucky's coal mines and for all the above mentioned reasons, it was concluded that there is a need for field investigations to determine these values in-situ for existing mining conditions in Kentucky. The author describe the study carried out in ten coal mines located in eastern and western Kentucky and present the results of the investigation in both tabular and graphical form.

Jan 1, 1991

By B. K. Sternberg

Since 1986, we have developed a series of electromagnetic (EM) sounding systems at the Laboratory for Advanced Subsurface Imaging (LASI). These may be categorized by their frequency ranges: low frequency (LF, 30 Hz to 30 kHz), medium frequency (MF, 1 kHz to 1 MHz), and high frequency (HF, 30 kHz to 30 MHz). We have applied these EM systems to a variety of targets, including: mapping of plumes of contaminated groundwater, tracing leachate for an in-situ leaching operation, locating buried hazardous waste, identifying subsidence-prone zones and detecting buried voids. These systems are also applicable to exploration for ore bodies. Currently, our sounding system uses a vertical magnetic field vector. Previous systems of this type required a slow and relatively inaccurate manual rotation of the sensing coils. The systems also used occasional calibrations of the measuring system. We have developed a 3-dimensional mathematical rotation procedure for the data, as well as a simultaneous, high-accuracy, calibration method. These new developments have greatly increased the speed of the measurements, as well as improving the accuracy of the ellipticity data. We use stepped-frequency measurements along with narrow-band filtering to allow accurate measurements, even in high-noise areas. We typically obtain ellipticity measurements at eleven frequencies and along densely sampled profile lines. We use neural networks to help interpret the measured ellipticity patterns. Neural networks can be trained to relate the measured ellipticity patterns to earth resistivities or to discrete targets buried in the earth. The neural network training may use theoretical EM responses calculated from computer codes for relatively simple structures. The theoretical EM response for many complex targets that are of interest cannot currently be reliably calculated, even with the largest supercomputers available. We have therefore chosen to do some of the training using theoretical EM responses generated in a full-scale modeling tank located at our Avra Valley Geophysical Test Site. We have also developed data-visualization software to help interpret the large data sets produced by this system.

Jan 1, 1997

By Larissa Koroznikova, Steve Durkin, Bradley Drake, Michael Tuck

This paper presents the results from the investigation of the application of thermal fragmentation in Australian hard rock underground narrow-vein mining. Two geologically similar samples from an underground narrow-vein hard rock gold mine were collected to obtain a measure of the technology’s ability to recover ore by the creation of large thermal openings to assess the applicability of the thermal method. Particle size distribution showed a higher generation of fine product, − 2 mm, by thermal fragmentation compared with selective blasting by 31%. The Bond work index for thermal ore (12.62 kWh/t) is half to that of the blasted ore value (25.32 kWh/t). The average grindability obtained for the thermal ore sample was greater than the blasted sample by a factor of 2.44, a higher value indicating a decrease in the energy required to grind. The thermal fragmentation method generates product with higher dissolution of gold in cyanide, by 14% for the − 9.5 + 2 mm size fraction samples. Additionally, the thermal fragmentation results in higher production of − 9.5 + 2 mm material by 15 % compared with selective blasting.

By Larissa Koroznikova, Steve Durkin, Bradley Drake, Michael Tuck

This paper presents the results from the investigation of the application of thermal fragmentation in Australian hard rock underground narrow-vein mining. Two geologically similar samples from an underground narrow-vein hard rock gold mine were collected to obtain a measure of the technology’s ability to recover ore by the creation of large thermal openings to assess the applicability of the thermal method. Particle size distribution showed a higher generation of fine product, − 2 mm, by thermal fragmentation compared with selective blasting by 31%. The Bond work index for thermal ore (12.62 kWh/t) is half to that of the blasted ore value (25.32 kWh/t). The average grindability obtained for the thermal ore sample was greater than the blasted sample by a factor of 2.44, a higher value indicating a decrease in the energy required to grind. The thermal fragmentation method generates product with higher dissolution of gold in cyanide, by 14% for the − 9.5 + 2 mm size fraction samples. Additionally, the thermal fragmentation results in higher production of − 9.5 + 2 mm material by 15 % compared with selective blasting.

By F. Burat

Large reserves of feldspar ore exist in the Aegean region of Turkey. The main colored impurities in these ores are iron- and titanium-bearing minerals such as anatase, rutile, sphene and ilmenite. In this study, a potassium feldspar ore containing mainly quartz and coloring impurities was subjected to beneficiation tests involving magnetic separation and flotation, which were applied either separately or in combination. Bench-scale flotation experiments using cationic collectors G-TAP and Flotigam V-4343 and using HF and H2SO4 as modifiers were employed to separate feldspar from quartz and to remove part of the titanium impurities. The best results were achieved with a combination of high-intensity wet magnetic separation and flotation. A feldspar concentrate containing 16.28% Al2O3, 10.75% K2O, 2.84% Na2O, 69.97% SiO2 and 0.16% Fe2O3 was produced. A quartz concentrate containing 2.30% Al2O3, 0.48% K2O, 0.42% Na2O, 0.07% Fe2O3 and 96.20% SiO2 was also obtained

Jan 1, 2007

By P. R. Taylor

A reaction is evaluated by which heated and pressurized water is used to precipitate metal oxides from loaded Kelex 100 complexes. Pure copper oxide (CuO) and pure nickel (Nio) in powder form, and ranging in average size from 12 to 25 micrometers, were found to precipitate from copper and nickel loaded Kelex 100/kerosene complexes, by water heated and pressurized to between 374 and 400 °c and 2170 psig (148 atm) and 3500 psig (238 atm). The precipitation is suggested to result from hydrolysis of the metal, following exchange for the hydrogen in the phenolic hydroxyl of the Kelex 100 structure, enhanced by the conditions provided by heated and pressurized water. The reaction is believed to have the characteristics of homogeneous nucleation and heterogeneous growth. The effects of temperature, pressure, initial metal concentration and seed addition on the kinetics of the process were studied. In addition, characterization studies were performed on the reaction products. A detailed discussion of the experimental results is presented.

Jan 1, 1992

By Iga Trisnawati, Fitria Puspita, Himawan Tri Bayu Murti Petrus, Gyan Prameswara, Idi Amin, Andi Nurfaadhilah Ulfah

Laterite ores, rich in essential metals like nickel, iron and cobalt, are a crucial resource for modern technology. However, the extraction of nickel from laterite ores is a complex process due to their intricate mineral compositions and low nickel concentrations. This paper presents the results of a study to understand the leaching behavior of preroasted laterite ore and the impact of roasting on leaching kinetics. The ore was subjected to roasting at 280 and 610 °C for a duration of three hours, followed by leaching in sulfuric acid (H2SO4) under atmospheric conditions. The results show that preroasting the ore at 610 °C significantly improved the recovery of nickel during leaching, with recovery rate of up to 93 percent, and the leaching process of the preroasted ore was primarily controlled by diffusion through the ash layer. The activation energy values were found to be 20.97 kJ/mol for the ore roasted at 280 °C, and 18.97 kJ/mol for the ore roasted at 610°C. These findings suggest that preroasting can enhance the leaching performance of laterite ore, potentially paving the way for more efficient and sustainable nickel extraction processes.

Aug 1, 2024

By Paula N. Wilson, W. T. Parry

Carbonaceous and metalliferous black shales occur in close proximity to Mercur-type gold deposits in the southern Oquirrh Mountains, Utah. These shale units, the Manning Canyon shale and the Long Trail shale, have undergone regional hydrothermal alteration. Hydrothermal solutions oxidized organic matter and pyrite, replaced shale by hydrothermal phyllosilicates and silica, and replaced fossils by phyllosilicates. The shales are depleted in organic carbon, calcium carbonate, alkali and alkaline earth metals, and enriched in aluminum and hydrogen. Hydrothermal veins containing illite, chlorite, pyrophyllite, kaolinite, Fe-oxides, and sulfides are present throughout the study area.The illite in veins is an ammonium illite that contains up to 2 % NH4 and is correspondingly depleted in K. Correlations among Au, As, Hg, TI, Sc, and rare earth elements indicate that hydrothermal fluids responsible for formation of ammonium illite were gold bearing. K/Ar ages of illite veins and illite-rich, clay-size separates of altered shales indicate hydrothermal activity occurred in the time range 193 to 122 Ma. Several ages from clay-size separates within the Mercur district cluster near 160 Ma. These ages are coeval with thrust faulting recognized to the north and west.

Jan 1, 1990

By S. S. Cook, S. E. Paulson

The US Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and Asarco/Freeport Santa Cruz deposit in Arizona to further the understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/L (0.05 to 0.28 oz/gal) copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/L (0.02 to 0.08 oz/ gal) copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration up to 40 g/L - (0.39 oz/gal) while illite and sericite had minimal impact. Biotite, calcium-rich clay, and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentra¬tions increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1990

By Norbert Patzelt, Hans Knecht, Wolfgang Baum

Future ore reserves of major gold producers in North America and elsewhere will consist of refractory gold ores. About 60 % of the current U.S. gold production is mined in Nevada. Several of the large gold operations in this state indicate that 40 to 90 % of their future ore feeds will contain refractory gold. To compound problems, average head grades for refractory U.S. gold ores have fallen from 8 - 9 g/mt to about 4 g/mt by 1991. In Latin America, 52 % of the gold operations will require milling for optimal recovery. Deeper reserves are, like in North America, refractory. Particularly in hard, (semi)refractory sulfide ores, many operations may experience substantial decreases of gold recov­ery. For example, Martins et al. (1991) report that at an Austra­lian mine, sulfide ore treatment led to 4 - 10 % lower gold reco­veries as the work index increased from 8 kWh/t to 14 kWh/t and the grind coarsened. Many refractory ores should actually be classified as semirefractory since a fine sulfide fracturing and liberation would make 80 - 90 % of the gold cyanide leachable. However, conventional comminution is often prohibitively expensive for these ore types.

Jan 1, 1995

By G. T. Lineberry, R. S. Mateer

Often only after years of "technical dormancy" do errors in published literature become apparent and meaningful. To prevent duplication of effort for future generations, the fol¬lowing corrections are offered. These errors were discovered during a recent study in which a computer program for mine hoist rope selection was developed (Lineberry and Mateer, 1988). In order of increasing gravity: Captions for Figs. 3 and 4 are transposed. • Purported to be a more accurate method of rope selection than the process of successive approximation, the direct method assumes linearity between a given rope's minimum breaking strength, T, and unit rope weight, Wv. Because of the sensitive location of the constant, K, in equation (8) for breaking strength, the significance of this nonlinearity is magnified. For a typical 6 x 37 class fiber core wire rope (Wire Rope Corp. of America, 1985), K actually varies from 43,650 to 52,190, depending upon rope diameter. Although the direct solution permits a rapid selection of hoist rope, an indirect (iterative) solution procedure is favored because of its im¬proved accuracy and ease of computerization. • Equation (8) for minimum breaking strength is in error. It should read:

Jan 1, 1989

By G. T. Lineberry, R. S. Mateer

Often only after years of "technical dormancy" do errors in published literature become apparent and meaningful. To prevent duplication of effort for future generations, the following corrections are offered. These errors were discovered during a recent study in which a computer program for mine hoist rope selection was developed (Lineberry and Mateer, 1988). In order of increasing gravity: Captions for Figs. 3 and 4 are transposed. Purported to be a more accurate method of rope selection than the process of successive approximation, the direct method assumes linearity between a given rope's minimum breaking strength, T, and unit rope weight, WV. Because of the sensitive location of the constant, K, in equation (8) for breaking strength, the significance of this nonlinearity is magnified. For a typical 6 x 37 class fiber core wire rope (Wire Rope Corp. of America, 1985), K actually varies from 43,650 to 52,190, depending upon rope diameter. Although the direct solution permits a rapid selection of hoist rope, an indirect (iterative) solution procedure is favored because of its improved accuracy and ease of computerization. Equation (8) for minimum breaking strength is in error. It should read:

Jan 1, 1990

By D. Sotiropoulos

In the recent years, the mining sector is looking for specific indices, taking into account economic, environmental and social criteria, in order to meet the sustainable development requirements. In the present study traditional and environmental sustainable indices used in the Agios Dimitrios Power Plant, Northern Greece, are compared to those of ESKOM Company, South Africa, taken as reference. These indices are referred to, a) the solid fuels consumption, such as lignite, and, b) the emissions to the atmosphere, such as SO2, NO2 and dust. Last five years data show a remarkable improvement of all indices in the Agios Dimitrios Power Plant. Although the lignite used in this Power Plant is by far of poorer quality than that used by ESKOM - net calorific value 1272 and 4638 kcal/kg, respectively - dust emissions in both Power Plants are similar (52 and 31 g/kWh, respectively). The SO2 and NO2 emissions are very low in Agios Dimitrios compared to those of South Africa, respectively 1.92 and 7.91, and 1.74 and 3.61 g/kWh. This is mainly due to natural desulfurization (by the lignite?s calcium content) and the low NOx burners.

Jan 1, 2003

By Zhuang Jianming, Liu Qinxia, Yuan Mingliang, Mei Xiangong, Chen Jin

Up to now, the leaching of manganese carbonate ore is usually performed at high temperature of 363K and the leaching rate is lower than 90%. Although in laboratory test, the leaching rate is only 90%. This paper introduced an improved method for leaching of manganese carbonate ore. Certain ammonium salt was added to the pulp to raise the solubility of Mn2+ and reduce the adsorption quantity of Mn2+ on the ore surface. Experimental results show that a leaching rate over 95% can be obtained at the temperature >273K. The activation energy is calculated to be 7.15 KJ/mol and is lower than that of normal leaching technique. The effects of the parameters, such as particle size, pulp density and initial acid concentration on the process results are investigated. A leaching rate higher than 95% can be obtained under the following conditions: particle size below 0.25mm, leaching time 60 min, stirring speed higher than 960 r.pm. H2SO4:MnCO3>1 .2, pulp density 105-205 g.L-l. A kinetic model was deduced, verifying with actual experiments. It showed that the model can describe the leaching process successfully.

Jan 1, 1995

By J. Roth

PROLOGUE Nowadays, where production costs and energy costs are increasing and at the same time requirements in fineness and purity of industrial mineral products are getting higher and higher, industry has to look for more efficient grinding systems and developments to produce these products more economically. Therefore lots of new developments in high energy jet mill pulverizing have been made. In the main, however, these developments involved more or less just the new principle of fluidized bed jet pulverizers but not the older spiral jet mill principle. In some cases, especially in the filler industry where laminar minerals are used and higher aspect ratios are required, the spiral jet mill principle has advantages in a better delamination of these minerals. To comminute minerals down to products with a d97 < 3 µm, the specific energy consumption increases up to 2,000 kWh/t – 3,000 kWh/t or even more, depending on the grindability of the mineral. So the production of these fine materials is quite an expensive task. But jet mill grinding is and will be the most favorable method to produce micro-products and in the near future nano-products, despite the high energy consumption.

Jan 1, 2000

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

This study investigated the performance of citric acid as lixiviant for cathode material from end-of-life lithium-ion batteries (LIBs). Black mass containing 84.2 weight percent MNC (LiNi0.45Mn0.4Co0.15O2) and 15.8 weight percent LCO (LiCoO2) material was leached at solid-to-liquid ratios of 20, 50 and 100 g/L. Leaching with 1.5 M citric acid, 2 volume percent H2O2 and a solid-to-liquid ratio of 20 g/L at 95 °C extracted 90 percent Co, 95 percent Li, 94 percent Mn and 94 percent Ni within 20 min. At the highest solid-to-liquid ratio of 100 g/L with 1.5 M citric acid, 10 volume percent H2O2 and 95 °C, 84 percent Al, 84 percent Co, 87 percent Li, 86 percent Mn and 96 percent Ni were leached after 40 min, producing a leach solution containing 0.68 g/L Al, 20.0 g/L Co, 6.0 g/L Li, 13.6 g/L Mn and 19.3 g/L Ni. Using stepwise addition of H2O2, instead of initial bulk addition, did not significantly improve the leaching efficiency but did reduce the required leaching time. Temperature control of the reactor was also more manageable with stepwise addition of H2O2, and evolution of gas was less vigorous. It was observed that the leaching efficiencies of Co, Li and Mn decreased slightly at solid-to-liquid ratios of 50 and 100 g/L, while the leaching of Ni increased slightly. The solution leached at 20 g/L could be stored for six weeks without any spontaneous precipitation. However, solutions leached at 50 and 100 g/L showed changes in concentration after one month of storage, suggesting that processes that have a large material throughput and use high solid-to-liquid ratios around 100 g/L must ensure that the solutions are not stored for extended periods of time.

Apr 1, 2025

By B. Berg, J. Stephenson, J. Mansanti, C. Nyikos

"Intrepid Potash, Inc.’s Carlsbad East facility has refined sylvite and produced muriate of potash (MOP) since 1965. In addition to MOP, Intrepid Potash began recovering the mineral langbeinite from a mixed ore reserve in 2005. In 2011 a new langbeinite recovery process for the coarse (+850 micron) size fraction was constructed to enhance the overall langbeinite recovery. Based on the limited mixed ore reserve and an abundance of langbeinite ore reserves the transition of the East plant to a langbeinite only facility was targeted for 2021. Due to a decreasing grade of the mixed ore reserve, declining sales pricing, and high sylvite operating costs a strategic decision was made to accelerate this transition into 2016. To enable a successful transition, a fines recovery system needed to be developed, constructed and implemented. This paper describes the advancement of langbeinite processing at Intrepid Potash and the planning, development and successful execution of the transition to a langbeinite only operation. BACKGROUND Langbeinite (K2SO4·2MgSO4) is a double salt containing potassium sulfate (K2SO4) and magnesium sulfate (MgSO4). It is used as fertilizer and in the industry is described as Sulfate of Potash Magnesia. It is attractive as a specialty fertilizer and in addition to containing a ready source of a primary nutrient potassium, it also provides two secondary essential nutrients, magnesium and sulfur. It is especially attractive for chloride sensitive crops. Langbeinite has a specific gravity of 2.8, a Mohs hardness of 4.2, and is brittle thus very friable. It is the hardest of the saline minerals, and despite its relative softness on the Mohs scale can be very abrasive in process environments and in field applications, probably due to its conchoidal cleavage. Its solubility at 240 g/l is less than the solubility of sylvite (KCl) or halite (NaCl) and due to even slower relative dissolution kinetics washing with cold water has been a common practice for upgrading langbeinite ores. The solubilization/crystallization relationship for langbeinite is different from the majority of other evaporite minerals in that once langbeinite is solubilized it does not form langbeinite again. Instead it gives up one mole of magnesium sulfate, takes on various waters of hydration and precipitates out as either schoenite (K2SO4·MgSO4·6H2O) or leonite (K2SO4·MgSO4·4H2O) depending on temperature. Due to its partial solubility and phase transitions at its surface when exposed to moisture, there is strong cohesion between wetted particles; the resulting stickiness of the upgraded products can create significant materials handling issues unless processed in slurry form or at relatively low moisture levels. Langbeinite has been produced commercially from two locations, the Kalush and Stebnik regions in the Cartpathian Mountains of former Poland and now the Ukraine and from the Permian Basin in New Mexico (Garrett, 1996; Smith 1949). Current production is from two operators in the U.S., Mosaic and Intrepid Potash."

Jan 1, 2017

By David Runnels

In September 1970, the Quebec Cartier Mining Company, started development of the Mount; Fright iron ore mine. The estimated ore reserve is in excess of 1,000,000,000 long tons with an average grade of 31.5% Fe. The run of mine ore is crushed, ground and concentrated to a product having 66% Fe and 5% silica at an annual concentrate production rate of 18.4 million long tons. The daily production rate of over 50,000 long tons of concentrate necessitates a daily mine output of approximately 250,000 long tons of material of which 50% is waste. The mine is located in the Province of Quebec, close to the Labrador border approximately 600 miles north-east of Montreal. The development of the mine necessitated the construction of an all electric one thousand housing unit townsite along with associated services such as a shopping center, swimming pool, arena, school, etc... A one-hundred mile long, 315 K.V. Dower line was built between the mine site and the Hydro-Quebec 735 K.V. existing power line between Churchill Falls and the Montreal area. The construction near the mine of a beneficiation plant was necessary to upgrade the 31.5% iron ore to a marketable product of 66% iron.

Jan 1, 1977

By Fulvio Tonon

And Rabcewicz said ?tunnels should be driven full face whenever possible.? ADECO, which stands for ?Analysis of Controlled Deformations in tunnels,? now allows us to fulfll Rabcewicz?s dream in any stress-strain condition. In order to achieve that dream and its consequent control over cost and schedule, however, NATM must be abandoned for the ADECO. The paper presents the basic concepts in the ADECO approach to design, construction and monitoring of tunnels together with some case histories, including: full face excavation for Cassia tunnel (width of 22 m, height of 14 m) in sands and silts under 5 m cover below an archeological area in Rome, Italy; Tartaguille tunnel (face area > 100 m2) advanced full face in highly swelling and squeezing ground under 100 m cover where NATM led to catastrophic failure, France; and 80 km of tunnels (face area > 100 m2) advanced full face in highly squeezing/swelling ground under 500 m cover for the high-speed railway line between Bologne and Florence, Italy (turnkey contract).