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By J. C. Vreugdenburg, B. A. Dippenaar, J. Muller, T. L. de Vries

Iron ore fines are agglomerated in the sintering process to produce sinter: an important feed material for blast furnaces worldwide. A model of the iron ore sintering process has been developed with the objective of being representative of the sinter pot test, the standard laboratory process in which the behaviour of specific sinter feed mixtures is evaluated. The model aims to predict sinter quality, including chemical quality and physical strength, as well as key sinter process performance parameters such as production rate and fuel consumption rate. The model uses the finite difference method (FDM) to solve heat and mass distributions within the sinter pot over the sinter bed height and time dimensions. This method can further be used for establishing empirical relationships with measured sinter properties. Inputs into the model include the feed material physical properties, chemical compositions, and boundary conditions that vary over time. Sub-models describe relationships between applied pressure differential and gas flow rate through the bed of granulated fine ore particles, combustion of carbonaceous material, calcination of fluxes, evaporation and condensation of water, and melting and solidification. Four sinter pot tests were performed and the model predictions validated against temperatures measured at depths of 100, 230, and 420 mm. Differences between predicted and measured temperatures indicated the need for optimization of some model parameters that are uncertain. Optimization resulted in an improvement in the correlation between the predicted and measured temperatures for all tests, although an acceptable level of agreement was not achieved in all cases. Using these parameter values, reasonable agreement was found in terms of typical performance parameters for three out of the four tests.

Jan 1, 2014

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

Recycling has become an important part of the lithium-ion battery (LIB) life cycle due to the growing demand for energy storage in applications like electric vehicles and renewable energy. Recycling spent LIBs provides a secondary source for strategically scarce metals, like lithium and cobalt, helping to reduce the environmental impact of LIBs. Organic acids have been proven to be effective lixiviants with the benefit of reduced environmental impacts, amongst which citric acid has shown to exhibit similar extraction performance when compared to mineral acids. Leaching LCO and NMC batteries with 1.5M citric acid and 2 vol.% H2O2 at 95°C, 20 g/L for 20 minutes achieved 93% Al, 90% Co, 96% Li, 94% Mn and 94% Ni dissolution. The strong chelating property of citric acid affects the separation of the metals, providing unique extraction opportunities. The first extraction uses 12 vol.% D2EHPA at a pH of 2.5 and O/A ratio of 2 to separate 96.4% Mn and 100% Al from the PLS in two counter-current stages. Stripping the loaded organic with 1.25M citric acid at an A/O ratio of 3 allows for up to 91% stripping of the manganese in a single stage. The second extraction then separates 96.5% Li from the PLS in three counter-current stages using 20 vol.% D2EHPA at a pH 5.5 and O/A ratio of 5. The raffinate remaining after the second separation contains 48.4 wt.% Co and 50.3 wt.% Ni. Keywords: Hydrometallurgy, lithium-ion batteries, metal recycling, citric acid, solvent extraction

Jan 1, 2020

By M. Handley

The Witwatersrand Basin contains by far the most gold ever found, and has hosted mining from its discovery in 1886 to the present. For many years, South Africa was the world’s largest producerof gold, nearly all of which came from the Witwatersrand. Since 2000, South Africa has fallen back several positions because of declining gold output. There are many complex and varied reasons for this; however, declining gold resources in the Witwatersrand Basin are not one of them. As far as the author knows, there are no qualified estimates in the literature of gold remaining in the Witwatersrand Basin. This paper collects mining data from several sources and then, using elementary gold accounting and error analysis, attempts to estimate the amount of gold remaining in the Witwatersrand Basin. It includes gold underground in existing and defunct mines, in evaluated ore resources, and dumps. Compiled data from 1887 to 2019 shows that 50 200 t of gold were produced by Witwatersrand mines, while it is estimated that a further 48 100 t remainunderground, both within and outside of mine leases, a further 1 600 t on the surface in tailings,and an unknown amount in rock dumps. Nearly all of this gold will remain inaccessible with current mining methods, and major technical developments in mining will be necessary before any of the gold can be categorized as a code-compliant resource or reserve. To win this prize, the mining industry will have to rethink its approach to mining, both in old mining leases and in the unexploited ground. It will also have to find effective means of preventing gold theft and informal mining, which are on the rise.

Apr 5, 2023

By S. Banisi, S. Zare, M. Mahmoudi, M. Maleki-Moghaddam, M. Yahyaei

As the orebodies become more complex and lower grade, there is an increasing demand from crushing circuits for a finer product. When the product from a crushing circuit does not satisfy the requirements of the downstream processes, the cost of production increases. Thus, enhancing the performance of cone crushers through optimisation of their operating factors becomes important. One of the key factors affecting performance of cone crushers is the filling of the crushing chamber during the operation. The effect of varying the filling of the crushing chamber of a cone crusher was investigated. To assess the crusher performance, parameters such as crusher capacity, power utilisation, and reduction ratio were used. Extensive plant trials were conducted to obtain samples and operational data when the crusher chamber was 50% full (half-full) and 100% full, which is 300 mm above the top of the crusher chamber (super-choked condition). The results indicated a 62% difference in the crushing capacity when the crusher was operated in a super-choked condition compared to the half-full chamber level. In the super-choked condition, the size-specific energy at 12.7 mm was 20 % lower than that of the half-full condition. The Bond ball mill work index (BBWI) of crusher product indicated that the BBWI of the product of the super choked condition is 5.6% less than that of the product of half-full condition. This can be attributed to the generation of micro cracks in particles due to increase in the interparticle breakage when the crusher was operated in the super-choked mode. Keywords: Cone crushers, crushing efficiency, crushing chamber filling

Jan 1, 2020

By H. F. Niemand, C. J. Postma, P. L. Crouse

"SynopsisThe separation of zirconium and hafnium is essential in the nuclear industry, since zirconium alloys for this application require hafnium concentrations of less than 100 ppm. The separation is, however, very difficult due to the numerous similarities in the chemical and physical properties of these two elements.Traditional methods for separation of zirconium and hafnium rely predominantly on wet chemical techniques, e.g. solvent extraction. In contrast to the traditional aqueous chloride systems, the AMI zirconium metal process developed by Necsa focuses on dry fluoride-based processes. Dry processes have the advantage of producing much less hazardous chemical waste.In the proposed AMI process, separation is effected by selective sublimation of the two tetrafluorides in an inert atmosphere under controlled conditions, and subsequent selective desublimation. Estimates are made for the sublimation rates of the two tetrafluorides based on the equilibrium vapour pressures. A sublimation model, based on the sublimation rates, was developed to determine if the concept of separation by sublimation and subsequent desublimation is theoretically possible.IntroductionZirconium requires several purification steps to conform to nuclear-grade specifications. Little information is available on the sublimation separation of Zr and Hf compounds, especially in the fluoride form, the majority of which deals with sublimation under vacuum conditions. On the industrial scale, only vacuum sublimation of ZrF4 has been reported. No records were found for the sublimation of ZrF4 in an inert atmosphere. Information on the sublimation rate of ZrF4 or HfF4 in an inert atmosphere is also limited. The rate is assumed to be dependent on several factors, of which temperature, area, and composition are considered the most important."

Jan 1, 2015

If an orebody has been drilled to achieve some level of regulatory compliance, then a number of associated geological databases will exist, representing 10 000 to 100 000 m plus of core intervals. The databases usually contain data about assays, lithology, mineralisation and geophysical attributes. They will also include location information such as collar positions and downhole surveys. Obviously this data is collected by geologists for, predominantly, geologists and mining engineers. However, from a process design viewpoint process engineers usually ignore the geology where possible and rely on a small number of metallurgical test samples. Typically these test samples are sourced from convenient and available cores or from a small number of specially drilled metallurgical holes. One of the worst instances known to the author was the design of a SAG mill using only two SAG specific test results (one for each of the major ore types) while, geologically, the orebody was defined by more than 30 000 m of drilling. This paper sets out a philosophy to maximise the use of the geological data, both for process design and in preparation for the commissioning phase of projects. Geological data is used in the identification of preferred locations for metallurgical test samples, for checking the metallurgical validity of the geological ore-type definitions, where necessary developing new ore-type definitions (geometallurgical domains) and developing mathematical relationships for the estimation of important metallurgical factors across the geological database. If the estimation of factors (for example ore competence) is considered reliable enough then there is also the possibility of feeding calculated data back into the block modelling process to allow the generation of metallurgically relevant outputs in the mine plans.

Jan 1, 2007

By I. Serepa, N. C. Steenkamp

Investigations were conducted to determine the condition and stability of the existing decline at amine in the Kalahari Manganese Field, Northern Cape Province, South Africa. During the inspection of the decline, voids were identified behind the concrete lining on the hangingwall and sidewalls over a total linear distance of 230 m. The voids did not provide confinement and, as a result, self-mining was occurring behind the lining. Water was flowing into the decline, over a total linear distance of 100 m, at areas where the decline intersected incompetent rock units, causing softening of the concrete lining and deterioration of the surrounding rock mass. Further damage to the concrete lining was caused by expansion and contraction of the wet red clay unit. Remedial work comprised void filling and water sealing to prevent further deterioration of the decline and ensure that it remained operable for the remainder of the life of mine. Void filling was accomplished by drilling rows of holes along the decline to access the voids and filling the voids with foam. This was followed by the sealing with polymer fluids. Telescopic pipes were also installed to allow water to drain off. A visual inspection was conducted and check-holes were drilled to assess the quality of the remedial work. The void filling material had penetrated cracks in the concrete lining, and areas where voids were intersected by check-holes were re-filled. Additional holes were drilled to re-seal areas that were still wet. The remedial work was completed successfully, as all voids were filled and stability achieved without compromising the concrete lining. The ingress of groundwater was also reduced to some residual dampness.

Mar 2, 2022

If an orebody has been drilled to achieve some level of regulatory compliance, then a number of associated geological databases will exist, representing 10 000 to 100 000 m plus of core intervals. The databases usually contain data about assays, lithology, mineralisation and geophysical attributes. They will also include location information such as collar positions and downhole surveys. Obviously this data is collected by geologists for, predominantly, geologists and mining engineers. However, from a process design viewpoint process engineers usually ignore the geology where possible and rely on a small number of metallurgical test samples. Typically these test samples are sourced from convenient and available cores or from a small number of specially drilled metallurgical holes. One of the worst instances known to the author was the design of a SAG mill using only two SAG specific test results (one for each of the major ore types) while, geologically, the orebody was defined by more than 30 000 m of drilling. This paper sets out a philosophy to maximise the use of the geological data, both for process design and in preparation for the commissioning phase of projects. Geological data is used in the identification of preferred locations for metallurgical test samples, for checking the metallurgical validity of the geological ore-type definitions, where necessary developing new ore-type definitions (geometallurgical domains) and developing mathematical relationships for the estimation of important metallurgical factors across the geological database. If the estimation of factors (for example ore competence) is considered reliable enough then there is also the possibility of feeding calculated data back into the block modelling process to allow the generation of metallurgically relevant outputs in the mine plans.

Jan 1, 2007

By G-L. Wu, X-B. Liu, C-Y. Zhou

"The static recrystallization behaviour of Ti-Nb microalloyed high-strength steel during hot deformation was studied by conducting double-hit hot compression experiments using a Gleeble-3500 thermomechanical simulator. The effects of deformation temperature, strain rate, strain, and initial austenite grain size on the static recrystallization fraction are discussed. The static recrystallization kinetics were modelled, and the results show that the static recrystallization fraction increased with deformation temperature, strain rate, and strain and interpass time. The static recrystallization activation energy Qs was 326.05 kJ mol-1. Comparison of the experimental results and predicted results indicates that the effects of deformation parameters on the static recrystallization in multistage hot deformation are significant. The predicted results are in good agreement with the experimental results. IntroductionIn hot-forming processes, complex microstructures are often induced by multiple hot deformation mechanisms (Zhang et al., 2014; Liang et al., 2015). The softening behaviour during hot processing has generated considerable interest because component properties are influenced significantly by the corresponding microstructural evolution (Wu et al., 2010). It is well known that dynamic recrystallization (DRX); metadynamic recrystallization (MDRX), which occurs by the growth of DRX nuclei during intervals of deformation; and static recrystallization (SRX), which occurs by nucleation and growth during the intervals of deformation, can significantly alter the austenite grain size (Chen et al., 2015. Chen, Sui, and Cui, 2014; Mao et al., 2014). The long interpass times allow complete SRX to take place if the steel is being rolled above the interpass recrystallization stop temperature (Tnr), i.e. in the absence of carbonitride precipitation (Siciliano, 2000). In recent research, microalloying technology coupled with new-generation thermomechanical control processing (NG-TMCP) has proved efficient in achieving the proper balance between strength, toughness, ductility, and formability by means of a suitable combination of chemical composition and thermomechanical treatment parameters (Shukla et al., 2012; Bandyopadhyay et al., 2011). The alloying elements Nb, V, Ti are widely used in high-strength low-alloy (HSLA) steel to achieve the desired strength and toughness properties with solid-solution strengthening, precipitation hardening, grain refinement, and dislocation strengthening (Opiela, 2014; Chen and Yu, 2012). The wide applicability of alloying elements in HSLA steel is due to the fact that heat treatments are not required after forming of the parts, which results in time and cost savings."

Jan 1, 2017

By T. A. Muhlare

"Large quantities of slag are produced every year and dumped on slag heaps around the world, posing a potential environmental threat due to contained heavy metals content. Slags are waste minerals produced during furnace smelting of minerals. The contained values of base metals may be released into the environment under natural weathering conditions polluting ground and underground water. Copper losses into slag are a continuous problem in pyrometallurgical smelting operations. Due to shortage of ore concentrate, various mining operations have initiated the recovery of copper from dumped slag. The typical process uses crushing, milling and flotation. These operations create excessive liner wear rates during crushing and milling because the bond work index of copper slag is 22 kWh/t and this is considered a very hard slag. The process also has reduced flotation recoveries and requires high flotation reagent consumption. The present work shows that digestion of the milled copper slag slurry with concentrated sulphuric acid at a temperature of 250oC forms a solid cake and leaching of the solid cake with water is a possible option. However, the consumption of sulphuric acid can have a considerable cost on the recovery process. This can be limited by producing a leach residue containing gypsum and silicate materials as amorphous silica which are suitable for use as an additive for Portland cement. Laboratory results show that 90% copper recoveries can be achieved. The leaching is conducted to prevent silica gel formation and iron co-extraction. Leaching is optimum if silica gel-free solutions and good filterable residue are obtained. INTRODUCTION Slag is a waste by-product of smelting and converting operations in metallurgical plants. Both smelting and converting operations are aimed at iron separation from base metal sulphides in non-ferrous metallurgy. The iron sulphide component of the ore or concentrate is oxidized to iron oxide at higher temperatures in the molten form, and then fluxed with silica and other oxide rock minerals to produce fayalite (2FeO•SiO2) slag (Schlesinger et al., 2011). Slags are generally deposited on dumps and considered to be unreactive materials. Smelter copper slag contains significant concentrations of several potentially toxic elements, including arsenic, lead, cadmium, barium, zinc and copper. These elements can be released into the environment under natural weathering conditions and cause pollution of soils, surface waters and groundwater (David, 1998)."

Jan 1, 2015

By J. W. van der Merwe, C Strydom, D. C. Odendaal, M. I. Sampson

Keywords: Sphalerite, Bio leaching, Chemical leaching Sphalerite concentrates were prepared from tailings dam samples obtained from Rosh Pinah Mine in Namibia. The samples were subjected to froth flotation and concentrates containing between 7% and 14% Zn were prepared. Leaching of these froth flotation concentrates were studied in ferric chloride solutions at different Fe3+ concentrations for different times at different temperatures with the influence of other species on the kinetics in mind. Complementary to this research, GeoBiotics, LLC and Exxaro Resources have developed proprietary bioleaching technology for the oxidation of base metals concentrates using GEOCOAT bio heap leaching technology in a sulphate medium. The ferric chloride laboratory work was performed in a fluidising leach reactor. The studied material was obtained from flotation concentrate produced during an investigation into the recoverability of a tailings pile at Rosh Pinah mine in Namibia. The optimum conditions for the laboratory investigation were found to be a Fe3+ concentration of 0.3 mol/dm3 at 80°C. A control was performed by using synthetic zinc sulphide. GEOCOAT evaluation tests are performed for the purpose of evaluating the bioleaching of ore and flotation concentrates by means of mesophilic bacteria, Column tests were carried out on the flotation scavenger concentrate from Rosh Pinah to assess the application of the GEOCOAT® process for the oxidation of a low grade zinc concentrate. In this study an attempt was made to demonstrate the relationship between the Kinetic models and the experimental data by plotting the fraction of Zinc leached against time and applying the different equations to the data. The kinetic models were applied to the data obtained from both the test regimes. Habashi (1999) proposed that if a process is controlled by a chemical reaction at the interface (phase boundary controlled reaction), the following equation applies. kCt =1 ? (1-R) 1/3 Alternatively a process is controlled by diffusion through the product layer the following equation applies: [kt = 1 23- X (1 ? X) 2/3] As the anodic dissolution reaction progresses, reaction product forms either a more or less dense reaction product layer on surface As this product layer forms, a diffusion problem develops governed by the nature of the product layer. The conclusion from the study was that the kinetics is very dependent on the type of ore processed relating to the mineral composition of the ore body.

Jan 1, 2007

The annual General Meeting of the Branch was held in the St. Helena Club on Wednesday, 4th August, 1971 at 8.00 p.m. Mr N. A. Honnet (Immediate Past Chairman) was in the chair. There were also present Mr V. C. Robinson, President of the South African Institute of Mining and Metallurgy. Nine Fellows: Messrs J. R. F. Handley, C. J. Isaac, J. Lorenzon, J. M. Meyer, C. Mostert, D. A. Smith, S. L. S. Swart, I Thomas and R. G. Williams. Five members: Messrs R. Campbell, A. H. Edwards, K. Pearce, G. P. Rundle and R. B. Sutherland. Five graduates: Messrs J. E. Andrews, E. J. Shillaber, M. H. Smith, T. R. Stromsoe and D. J. van Niekerk. Two associates: Messrs A. Paschalides and D. S. Robinson. Eight visitors. Total present: Thirty-one. MINUTES OF THE PREVIOUS GENERAL MEETING As the minutes of the General Meeting held on the 16th June, 1971, had not been published in the Journal, the Chairman moved that the adoption and discussion thereof be deferred to the next General Meeting. This motion was adopted unanimously. The minutes of the General Meeting held on the 10th February, 1971, were taken as read. The adoption, which was proposed by Mr D. A. Smith and seconded by Mr J. M. Meyer, was carried unanimously. At Mr Honnet's request, Mr V. C. Robinson took the chair during the presentation of the Chairman's Annual Report. CHAIRMAN'S ANNUAL REPORT 1970/71 1970/71 Committee-Office Bearers: Chairman - J. N. Saunders Vice Chairman - G. Y. Nisbet Immediate Past Chairman- N. A. Honnet. Due to the sudden retirement of Mr J. N. Saunders, the committee, at a meeting on the 3rd February, 1971 elected Mr G. Y. Nisbet as Chairman with Mr J. M. Meyer as Vice Chairman. After the transfer of Mr Nisbet to C.D.M., the committee, as a meeting on the 12th May, 1971, decided that Mr Meyer hold the Chair in an acting capacity for the remainder of the year. Committee members: Messrs C. J. Isaac, J. G. Kirchener, L. O. W. Leimer, R. S. Pearson, I. G. Thomas and A. von Holdt. Transfers of several office bearers and committee members resulted in Messrs J. M. Meyer, D. N. Smith and G. C. J. Young being co-opted onto the committee.

1. Mintek publications The folowing are available from Mintek (Private Bag X3015, Randburg, 2125 South Africa) at R35 (including GST) per copy to purchasers in South Africa and US$30 (including airmail postage) to purchasers elsewhere. Report M402 The preparation of synthetic fusion standards for use in the X-ray-fluorescence analysis of rocks and minerals, by RT. Eddy and J.J. Jacobs. Apr. 1990. 19 pp. Report M405 Slag-metal equilibria in the system Fe-Cr-Si-C-Ca-Mg-AI-O, by R.H. Eric and M. Akyizli. Aug. 1990. 29pp. Application Report no. 8 The development of a process for the recovery of gold from gold-bearing solutions by means of activated carbon or resin in a NIMCIX column. 1990. 19 pp. 2. New publications from Trans Tech The folowing are available from Trans Tech Publications Ltd, Old Post Road, Brookfield VT05036, USA. Efect of iron and silicon in aluminium and its aloys, edited by I. Kovacs. 1990. 450 pp. $124. Martensitic transformations, edited by B'.C. Muddle. 1990. 714 pp. $190. Ferites, edited by C.M. Srivastava. 1989. 2 vols. 1280 pp. $254. Properties and characterization of amorphous carbon films, edited by J.J. Pouch and S.A. Alterovitz. 1990. 714 pp. $152. Synthesis and properties of boron nitride, edited by J.J. Pouch and S.A. Alterovitz. 1990.426 pp. $192. Electronic structure and latice defects in aloys, edited by R. W. Siegel and F .E. Fujita. 1989. 320 pp. $78. 3. A new edition Tomorow's materials, by K.E. Easterling. London, The Institute of Metals (1 Carlton House Terace, London SWIY 5DB, England), 1990. 2nd ed. 170pp. US$29. 4. Books for exploration geologists The folowing books are obtainable from Elsevier Science Publishers, P .0. Box 211, 1000 AE Amsterdam, The Netherlands. Lateritic bauxites, by G. Bardossy and G.J.J. Aleva. 1990. 624 pp. DFL. 295. Platinum-group element exploration, by D.L. Buchanan. 1988. 186pp. DFL 150. Lead isotopes in mineral exploration, by B.L. Gulson. 1986. 246 pp. Dfl. 160. Prospecting and exploration of mineral deposits, by M. Kuzvart and M. B6hmer. DFL. 285. 5. Journal for earth scientists . Ore Geology Reviews, published by Elsevier Science Publishers, P.O. Box 211, 1000 AE Amsterdam, Netherlands. 6 issues per year. Annual subscription DFL 453 including postage.

Jan 1, 1990

1. Book reviews Underwater tools, by Donald J. Hackman and Don W. Candy. Columbus (D.S.A.), Battelle Press, 1981. 152 pp. $32,95. Reviewer: B. Schmitz Uranium exploration case histories. Proceedings of Advisory Group Meeting Vienna, IAEA, 1981. Price: Austrian schillings 630. Reviewer: E. C. Kostlin Jet cutting technology, a review and bibliography, edited by Robin Brown. Published by BHRA Fluid Engineering, Cranfield, Bedford MK430AJ, England. Reviewer: D. O'Beirne 2. New Books Proceedings, Twelfth Congress of the Council of Mining and Metallurgical Institutions, by H. W. Glen (editor.) Johannesburg, The South African Institute of Mining and Metallurgy, 1982. 2 vols., 1060 pp. R78,85 (air-mail RI53,85). Amborite. Johannesburg, De Beers Industrial Diamond Division (P.O. Box 916), 1982. 6 pp. Free of charge. 3. New Journal BHRA Fluid Engineering has announced its new journal World Ports and Harbour Abstracts and the associated newsletter World Ports and Harbour News, which are issued from January 1983. The Abstracts is published bi-monthly and costs £60 in the V.K. and E.E.C., and £72 elsewhere. 4. Mintek reports Report 2134D On-line analysis, by X-ray diffraction, of fluorsparcontaining slurries. (First published 30th Sep., 1981.) Report 2135D A preliminary on-line analysis, by X-ray diffraction, of pyrite-containing slurries. (First published 30th Sep., 1981.) Report M28 The measurement of flow velocity distribution in fluids. Report M34 The determination, by atomic-absorption spectrophotometryusing electrothermal atomization, of platinum,palladium, rhodium, ruthenium, and iridium. Report M45 Two computer programmes for the calculation of massand heat balances in the production of high-carbon ferromanganese. Report M50 The development of an on-line gold analyser. Report M54 Major amounts of mercury in native gold from upper Witwatersrand sediments. Report M55 A new robust method for the treatment of analytical data. Report M57 The hydrometallurgical treatment of liquors generated by the leaching of a low-grade matte. Awards for inventions For inventing devices of exceptional value to the mining industry, two mining men were presented with awards in Johannesburg on 25th November, 1982, under the Chamber of Mines' Ideas and Suggestions Scheme. Mr W. W. Malan, President of the Chamber of Mines, made the presentations.

Jan 1, 1983

The June General Meeting of the Branch was held in the St. Helena Club on Wednesday, 18th June, 1969. Mr J. G. Kirchner (Chairman of the O.F.S. Branch) was in the chair. There were also present: Eight Members: Messrs A. F. Leger, J. N. Saunders, T. Zadkin (Committee Members), Messrs M. G. Cullen, M. S. Grobler, C. J. Isaac, S. L. S. Swart, P. S. Turner. Eight Associate Members: Messrs R. Campbell, D. E. Couperthwaite, J. D. Couperthwaite, A. Hepburn, P. A. Hoffman, H. J. Reeders, R. B. Sutherland, P. R. Wheeler. Two Graduates: Messrs M. T. G. Davies, B. D. Goodwin. Two Affiliates: Messrs L. D. Hulley, K. L. Wilson. Three Visitors. Total Present: 24. Apologies were received from Mr L. O. W. Leimer. The Chairman declared the meeting open and, after extending a welcome to all visitors, said that it was his sad duty to announce the recent death of Mr. R. Jack, Associate Member. As a mark of respect to the deceased and in sympathy with the bereaved, those present stood in silence for a few moments. MINUTES OF PREVIOUSGENERALMEETING The Minutes of the Previous General Meeting held on the 19th February, 1969, which were published in the April Journal, were taken as read and their adoption proposed by Mr J. N. Saunders and seconded by Mr D. E. Couperthwaite. MA TTERS ARISING FROM THESE MINUTES There were no matters arising from these minutes. ELECTION OF SCRUTINEERS Mr V. J. Isaac proposed and Mr M. S. Grobler seconded a motion that Messrs J. G. Kirchner, J. N. Saunders and M. G. Cullen be elected scrutineers in the forthcoming election of Committee Members. GENERAL BUSINESS The Chairman announced that a visit to the South African Railways Workshops in Bloemfontein had been arranged for the 23rd July, 1969 and expressed the hope that this would be well patronised. TALKS The Chairman called first on Mr D. E. Couperthwaite to present his paper on 'Heavy media separation' and then on Mr A. F. Leger to present his paper on 'Engineering plastics'. Both presentations, which were illustrated with diagrams, proved of great interest to all members. A vote of thanks to both speakers was proposed by Mr T. Zadkin. CLOSURE After thanking the speakers, the Chairman thanked all present for their attendance and declared the Meeting closed at about 9.30 p.m. Refreshments were then served.

By R. J. Davidson, W. D. Douglas, J. A. Tumilty

SYNOPSIS Two pilot plants operating on different types of carbon were used to generate steady-state adsorption data in the treatment of gold-plant solutions of high and low tenor. A pilot plant comprising three 4 m long columns and using 3 mm extruded activated carbon was used to treat pregnant solutions with a gold concentration of 5 to 8 g/t at pH 10 to 11,5. Column influent was pumped at a super¬ficial flow velocity of 0,5 m/min while the carbon was moved daily so as to effect gold loadings on the carbon of 5 to 10 k /t. With a carbon-bed depth of 12 m, an adsorption efficiency of 99,9 per cent was obtained in a bed depth of 9 m, which was subsequently reduced to 8 m when the depth of the carbon bed was reduced to 8 m. This improvement in efficiency was attributed to the reduced residence time of the carbon from 12 to 8 days. A corresponding decrease in adsorbed silica indicated that some silica fouling of the carbon had occurred. A second pilot plant, comprising a single column 6 m in length and using coconut-shell carbon of 1,0 to 2,4 mm, treated a solution with a gold concentration of 0,7 g/t at pH 8,0. Feed solution was pumped at a superficial flow velocity of 1,0 m/min while carbon was moved every 8 hours to give gold loadings of more than 5 kg/t. An adsorp¬tion efficiency of 99,5 per cent was indicated at steady state. Intermittent washing of the column with dilute hydrochloric acid was shown to have a beneficial effect on the gold adsorption and to reduce the pressure drop across the column. Intermittent washing with dilute sulphuric acid indicated that there had been some passivation of the car¬bon during the treatment of a solution with a gold concentration of only 0,2 g/t. Compared with other adsorption systems, the countercurrent moving bed appears to offer significant advantages in terms of metallurgical efficiency and capital investment. The inability normally associated with moving-bed systems to treat solutions containing suspended solids may be overcome to a degree by the use of relatively coarse extrud¬ed carbon.

Jan 1, 1985

By J. P. Coetzee

Dr. K. Gebhard In his excellent and comprehensive survey on the future development of the Iron and Steel Industry in South Africa, Mr. Coetzee has also mentioned the direct reduction processes as a possible method of converting iron ore to iron. Mr. Coetzee has made it quite clear that at this stage one should not consider these processes as a 'magic formula' which herald a 'break through'. I agree entirely with this point of view. Once upon a time I held the opposite view, but in the meantime I have revised my views. To do so, I had 40 years at my disposal. In 1930 I had the privilege of being connected with the first commercial sponge iron plant in Germany1 - a plant which was capable of producing 40 tons of sponge iron a day. We were determined to prove that the blast furnace would become obsolete in the near future. We considered it as an unnecessary detour to convert iron ore first into an iron-carbon alloy, which contained further quite a number of undesirable elements, and to remove this carbon by an endothermic process. Direct iron-making seemed to be a logical short cut. Unfortunately, we were not able to establish this 'short cut,', but the life of our sponge iron plant was cut short. We had solved all technical but not the economic problems. Basically the positon is still the same today - mainly economic and to a lesser degree technological aspects determine the rate at which sponge iron plants are installed. More has been said and written than done about direct reduction plants. I think that there are two main reasons for this stagnation in the introduction of direct reduction processes. The first reason is that modern blast furnaces are just too good and too economic ever to be replaced by direct reduction processes on a large scale. This, of course, already limits the field of application for direct reduction plants. The second reason is that sponge iron production and utilisation is based on technical considerations, which increase not only the production cost of sponge iron but also the conversion cost to steel to such an extent that under special conditions only are direct reduction plants an economic proposition. Are these technical considerations still as forceful and valid today as they were when 'direct steelmaking' was first contemplated? The development of sponge iron production as a method of direct

Jan 3, 1971

By J. Yianatos, P. Vallejos

In the last decades, the exponential increase in the cells’ volume resulted in significant advantages such as investment costs, footprint and energy savings. However, in larger size cells, despite the increased diameter/height ratio, new constraints arose related to the need for decreasing the larger froth transport distances to enhance the froth recovery. Thus, the use of froth crowders and internal launders became compulsory to maintain the froth transport distances but decreasing the ratio between gas and collected mineral flowrates. Consequently, the bubble load will increase until reaching a critical bubble surface coverage. In this paper, the concentrate carrying capacity (tph/m2) is described in terms of the bubble surface coverage (bubble loading) at the pulp-froth interface and the froth recovery (froth transport) and is evaluated as a function of the cells’ volume and operating variables. A sensitivity analysis, based on industrial operating and design conditions, such as superficial gas rate, particles size, froth crosssectional area and cells’ volume, was developed for evaluating the metallurgical performance of cells from 100 to 630 m3. Results show that limiting carrying capacity can arise for the whole range of cells’ volume, depending on critical operating conditions, particularly in first rougher cells and cleaning stages of industrial flotation circuits. The increase in cells’ volume consistently increases the bubble loading (bubble surface coverage) under all conditions, approaching the limiting conditions more rapidly in the case of cells without internal launders. Otherwise, the limiting condition was achieved when the particle size DPS decreased from 50 to 20 (μm) and for superficial gas rates significantly less or larger than 1 (cm/s). The use of internal launders allows for increasing the range of the operating conditions needed to reach a certain carrying capacity. Keywords: Bubble carrying capacity, flotation cells, bubble surface coverage, cells’ volume

Jan 1, 2020

By S. Lohmeier, D. Gallhofer, B. G. Lottermoser, T. Schirmer

At a time of resource consumption, it is important to study the chemical composition of mining and metallurgical wastes to prevent the dissipative loss of metals and metalloids from the mining value chain. In particular, the recovery of critical elements from wastes is an option to increase the resources of such materials that are economically significant and have an overall supply risk. In this paper we report on the chemical composition, in particular the critical element content, of granulated slag originating from historical smelting activities in the Tsumeb area, Namibia. Laboratory-based inductively coupled plasma–mass spectrometry (ICP-MS) and X-ray fluorescence (XRF) analyses as well as portable X-ray fluorescence (pXRF) demonstrate that the slags are on average enriched in base metals (Cu 0.7 wt%, Pb 2.7 wt%, Zn 4.7 wt%), trace metals and metalloids (Cd approx. 50 mg/kg, Mo approx. 910 mg/kg) as well as critical elements (As approx. 6300 mg/kg, Bi approx. 3 mg/kg, Co approx. 200 mg/kg, Ga approx. 100 mg/kg, In approx. 9 mg/kg, Sb approx. 470 mg/kg). While metals and metalloids such as As, Mo and Pb can be determined reliably using pXRF instruments, the technique has inherent limitations in evaluating the contents of certain critical elements (Ga, Sb). However, there are positive correlations between the As, Mo, and Pb contents determined by pXRF and the Ga and Sb contents obtained through ICP-MS and XRF. Thus, quantitative pXRF analysis for As, Mo, and Pb allows calculation of Ga and Sb abundances in the slags. This work demonstrates that pXRF analysers are a valuable tool to screen smelting slags for their chemical composition and to predict the likely contents of critical elements.

Mar 1, 2021

By C. Debek, A. Wasilewicz, T. Czysz

"Both Polish and European hard coal mining nowadays faces the need of deepening shafts (significantly in some cases) or extending mining hoists, due to the exploitation of deeper coal deposits.In order to protect the crew working within a shaft, rope safety platforms (artificial shaft bottoms) are employed. Old solutions, based on rigid steel constructions with the external damping layers made of e.g. slag and up to several tens of metres long, are intended to absorb the energy of approximately 5 t mass falling a distance of 700 m. However, current requirements often assume a drop of 20 t to a depth of 1000 m or even more.More modern safety platform structures, made of one or more support rings with steel ropes stretched on them (rope platforms), are more compact (up to 3 m high) and lighter than traditional solutions. Multi-ring rope platforms with additional damping layers filling the empty spaces between the ropes are able to absorb sufficient energy to meet the current requirements.Single- and double-ring platforms have been employed in Poland to absorb the energy of approximately 5 t dropping to a depth of 900 m. They have been developed (and some have already been implemented) by SADEX Ltd. and are protected by various patents and patent applications.This paper presents a design for a triple-ring platform structure with six rope nets. FEM analysis was used to model the performance of the platform. According to the simulation, a 20 t mass falling from 1000 m (>100 m/s) will destroy all the nets, breaking most of the ropes and deforming the support steel boards placed on the nets, but will ultimately be stopped by the platform, as its kinetic energy falls to zero."

Jan 1, 2017