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The Annual General Meeting of the South African Institute of Mining and Metallurgy was held in Kelvin House on Wednesday, 23rd August, 1978. Mr P. A. von Wielligh (President) was in the chair and declared the meeting open at 16h00. Obituaries The President: It is my sad duty to announce the death of the following members of the Institute : T. K. Prentice and W. E. Gooday, Honorary Life Fellows and Past Presidents; B. S. Allen, J. A. Becking, L. H. Mellor, C. A. Pratt and W. T. Stobart, Life Fellows; J. P. Burls, E. Cameron, M. L. Fitzgerald, C. G. Hinds, A. J. Patrick, H. O. Reisener, N. D. Shuttleworth, N. Soldan and J. Whitehouse, Fellows; T. Gemmell, J. S. A. Oelofse, W. D. Rowe, R. L. J. Shearman and G. M. Thain, Associates. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. Welcome The President: It is now my very pleasant duty to welcome our distinguished guests and visitors. We are pleased to have with us Mr D. A. Etheredge, Vice¬President of the Chamber of Mines of South Africa, and Mrs Etheredge. Mr Etheredge this afternoon represents the mining industry at our meeting. The importance of the close link that over the years has been maintained between the industry and our Institute speaks for itself. We are, therefore, grateful that he and Mrs Etheredge have managed to find the time to be with us this after¬noon.

Jan 1, 1979

By P. J. Kinver

This paper deals with the development of backfilling methods and systems at the Broken Hill orebody of Black Mountain Mineral Development Company (Pty) Limited, at Aggeneys in the north-western Cape Province. Production started in 1979, being confined to large diameter blasthole stoping methods in the upper, steeply dipping areas of the orebody. This blasthole reserve is now depleted and the production tonnage, 100000 tons per month, is produced from eight cut and fill stopes in the flatter dipping areas of the orebody. The fill methods of the blasthole stoping area evolved prior to the pillar extraction are briefly discussed together with the resulting experiences gained that enabled virtually 100% extraction to be achieved. The original cut and fill mining used costly hydraulic cemented fill; this was replaced partly by unconsolidated river sand and later by dune sand which occurs in abundance. The paper describes the planning, research work and commissioning of a cycloning plant that now enables dune sand to be used successfully as an unconsolidated hydraulic fill. The development of drainage, placement and control methods are also reviewed.

Jan 1, 1988

By G. S. Littlejohn

In anticipation of the flooding of an adjacent dolomitic groundwater compartment, five rough parallel sided boundary plugs at 58 and 50levels have been designed to resist safely hydrostatic heads of 1500and 1250 metres, respectively, over a service life of 100 years. Following a description of the engineering properties of the surrounding rocks, the paper details the design considerations relating to structural length and strength, hydraulic gradient, rock mass watertightness, constituent materials of mortar intruded concrete, pregrouting of permeable discontinuities within the surrounding rock mass, a bentonite barrier to resist aggressive mine water, plug tightening and design performance requirements. Routine quality control tests include permeability of the rock mass, fluidity, bleed and strength development of the intruded mortar, and temperature of the intruded concrete during curing. A special test programme includes determination of strength and stiffness of cored concrete and rock samples, shear strength of the rock/plug interface and associated in situ contact stress in order toe stimate the load safety factor against plug failure by shear.

Jan 1, 2006

By N. Birtek, R. P. King

The washability characteristics of fine South African coals were measured and were found to be well characterized by an M-curve having the equation Z = aQb exp(cQ) x dQ, where Z is the ash content per 100 units of total feed and 0 is the mass yield. Parameters a, b, c, and d were determined for 23 different samples of coal from important coal seams in the main South African coalfields in the size range 0,0025 to 1 mm. The relationship between ash content and relative density was determined and correlated by means of two linear relationships. This characteristic behaviour was explained in terms of the liberation of macerals and the different association between the mineral mater and the two major macerals vitrinite and inertinite. The results obtained in this study can be used to calculate the expected performance of an ideal separation process, and can also be used as input for the simulation of real beneficiation plants. An example is worked through in detail to illustrate the method of calculation.

Jan 1, 1990

By J. Kunze, R. Degal

During the last 100 years, the submerged arc furnace has been one of the most amazing diversified melting units. These furnaces have found their application in more than 20 different main industrial areas such as iron, ferro alloy, chemical industry, lead, zinc, copper, refractory, titanium oxide, recycling, phosphorus etc. Such an evolution was only possible because of tremendous efforts in research and development and due to the large range of design solutions. The worldwide strong competition also forced the industry and plant suppliers to develop highly efficient, economically balanced units in optimized sizes and with long lifetimes, to adapt to the market conditions. Regarding the environment, the plants improved significantly in terms of water treatment plants and off-gas treatments as well as on site recycling units. This paper will give a short overview regarding the history of the furnace and the latest developments in today?s main application fields: ferro alloys, non-ferrous, special application and recycling. In addition new activities in research and developments are briefly discussed.

Jan 1, 2004

By Martin Banda, Gift C. Chisakuta, Moses Chabinga

KCM made a major modification to the Nchanga Tailings Leach Plant (TLP) changing the circuit from feeding post leach thickeners in parallel with leach discharge for solid ?liquid separation to a Counter Current Decantation (CCD) configuration utilising most of the existing equipment. The new circuit is aimed at improving copper recovery from approximately 70% to 79% through enhanced wash efficiency. The re-introduction of CCD circuit at elevated throughput of 46 000-tpd design was made possible due to the EIMCO E-Duc technology design which is an auto-dilution system that enhances solids settling rate. Commissioning (manual operation) which accommodated on-going operational requirements was phased and completed in January 2004. The circuit stabilised in subsequent months and in March alone an all time record copper recovery of 81.8% was achieved which contributed an extra 779 tonnes copper above the plant?s projected production plans. 100% of the project cost was paid back by end of April 2004 This paper discusses the work involved and the challenges faced during the re-commission

Jan 1, 2005

By G. Panopoulos, R. P. King, A. H. Juckes

The flotation characteristics of two South African coals were investigated: one from the Dumacol Colliery in Natal, and the other from Landau Colliery in the WitbankCoal Field. Samples of fine coal (smaller than 1 mm)were studied, the Dumacol coal showing significantly better ash-liberation characteristics than the Landau coal. Neither coal was found to produce satisfactory flotation concentrates, except at very fine sizes. The poor flotation performance can be ascribed to the non-selective flotation of unliberated particles that may contain considerable quantities of ash. Flotation recoveries were greatest for particles between 100 and 200 µ m, and fell of rapidly as the size increased above 200 µ m. Very fine particles were found to float adequately, and acceptable concentrates can be made at comparatively high yields from materials smaller than 75 µ m. The flotation of ultrafine coal was demonstrated successfully in a continuous pilot plant. This result opens the way to a potentially viable industrial process for the beneficiation of ultrafines from the Witbank No. 2 seam, which for decades has been regarded as non-floatable.

Jan 1, 1986

By Bjørn Nilsen, Werner Stefanussen

The construction of the Guaigui Multipurpose Project includes a 74 metre high concrete face rock fill dam, a 350 metre long diversion tunnel and a 350 metre long spillway tunnel. The topography in the project area is very steep, and the rock masses are characterized as soft rocks. The stability of the 80 to 100 metre high dam abutments and the excavation of the tunnels in soft rock conditions have caused various challenges and problems to be solved. Limited pre-investigations have called to a great extent for estimation of parameters for the stability calculations based on experience. The preliminary calculation of the stability of the planned rock slope above the spillway intake platform has been carried out by conventional partial factor methods and by use of a computed based Slide Program. The two methods of calculation give different results , and that rock support is necessary to obtain an acceptable factor of safety for a slope inclination of 52o. The input parameters for the rock mass characteristics need to be verified for the permanent calculations.

Jan 1, 2006

The Annual General Meeting of the South African Institute of Mining and Metallurgy was held in Kelvin House on Wednesday, 25th August, 1976. Dr R. E. Robinson, (President) was in the chair, and declared the meeting open at 16h00. Obituaries The president: It is my sad duty to announce the death of the following members of the Institute : P. A. Creewell, Life Fellow; A. S. Davis, J. S. Hay, P. O. Large, N. McCaskell, and H. G. M. McKerrow, Life Members; C. L. Bererge, Fellow; T. Bulloch, G. Douglas, R. W. Forrester, and C. G. P. Sack, Members; P. R. Garcia, W. A. Naude, and J. P. Slager, Associates. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. Minutes The President: May we confirm the minutes of the General Meeting held on March 17th, 1976, as published in the June issue of the Journal? Agreed. Welcome The President: It is my pleasant duty to welcome a number of guests and distinguished visitors this evening. First, I would like to welcome Mr R. Plumbridge, the President of the Chamber of Mines, and Mrs Plumbridge. We have had very close co-operation with the Chamber of Mines, and it is particularly gratifying that Mr Plumbridge has had time to be with us this evening in spite of very heavy engagements. Ook 'n spesiale woord van verwelkomirg aar mrr. N. Orsmord, die Staatsmyringerieur, en mev. Orsmord. Ors wil hierdie geleertheid gebruik om mrr. Orsmord geluk to wens met sy aarstellirg as die Staatsmyrirgerieur en die hoop uitspreek dat dit baie jare van samewerkirg met hierdie Irstituut sal beteker. We also welcome guests who, in one way or another, have been able to attend most of our Annual General Meetings, the Honourable I. B. Dillon, the Minister of Mines of Rhodesia, and Mrs Dillon. Once again we welcome them most heartily to our Annual Meeting. I would also like to welcome the representatives of many of our sister institutions : the Honorary Treasurer of the AS & TS, Mr D. G. Maxwell; the President of the South African Institution of Mechanical Engineers, Mr A. R. Adams; the Vice-President of the South African Institute of Electrical Engineers, Mr K. A. H. Adams, and Mrs Adams; the President of the Institute of Certificated Mechanical and Electrical Engineer s, Mr Martin and Mrs Martin; a member of the Executive of the South African Institute of Civil Engineers, Professor G. Bright ; the President of the South African Chemical Institute, Mr Vic Shuller, and Mrs Shuller; the President of the Institute of Welding, Professor F. P. A. Robinson, and Mrs Robinson; the President of SACPE, Mr M. R. Gericke ; the President of the Institution of Metallurgists, South African Branch, Mr D. R. Allen; the President of FSPE, Dr P. J. D. Lloyd, and Mrs Lloyd ; Mr A. J. H. Pole of the Association of Mine Managers, and Mrs Pole; and Mr M. D. Hoskin of the South African Institute of Foundrymen. A special word of welcome to Mr G. C. Young of our Orange Free State Branch, and Mrs Young ; and to Mr E. J. Jackson of our Witbank/Middelburg Branch. We have great pleasure in welcoming Dr F. M. Naude, the Scientific Adviser to the Prime Minister, and Dr W. C. J. van Rensburg, Technical Director of the Minerals Bureau. The latter is a new organization, and we hope their attendance here this afternoon forecasts a long period of co-operation between the Minerals Bureau and this Institute. Ook wil ek hartlik hier verwelkom die Rektor van Die Randse Afrikaanse Universiteit, professor G. van N. Viljoen. Ors het baie noue samewerking met die Universiteit gekry, en ek wil ook bier verwelkom die twee verteenwoordigers van die Geologiese-afdeling en die Chemie-afdeling, naamlik, dr C. Roering en professor G. W. Holzapfel. Last, but by no means least, a word of welcome to a very old friend, Mr Eric Boden, the Manager of AS & TS. To all our guests, a very hearty welcome to this our Annual General Meeting. Membership The President: It is required by our Constitution that I announce the names of a number of candidates who have been elected to various grades of membership. The list is a very long one, and I suggest that we simply record that these names will be published in the Journal. Any one who wishes to comment on these members should do so in writing to our Secretary. Agreed. Fellows: G. Paterson, P. H. Adler, F. W. G. Schoning, J. P. de Villiers, F. I. de Waal, J. R. H. Shaw. Members: C. J. Slavin, P. J. Perkins, R. J. I. Butler, A. M. Hattingh, C. E. Alvey, J. A. Engelbrecht, P. L. Gouws, J. P. Martin, J. F. Taylor, K. A. G. Blendulf, A. R. Gibb, W. E. Smith. Associate Members: D. R. Broderick, D. F. Cilliers, D. N. Stuart, P. Kraus, B. G. Pinder. Associates: D. E. Gibbon, D. F. Jacobs, R. F. W. Swanepoel, R. D. H. Bebb, H. H. Vernall, R. D. Gibson, J. P. van Wyk. Graduates : A. N. Morris, D. J. Payne, G. S. Worthington, A. S. Dennison, A. R. Godfrey, N. Holloway, W. J. Rankin, G. S. Lyndon, R. J. van Proctor, J. J. Versluis, G. M. Miller. Students: B. J. Rabie, G. D. Webber, W. L. Blair, I. D. Mathews, K. McVey, S. W. Beer, R. W. J. Bentley,

Jan 10, 1976

By P. C. Pistorius, M. P. Maphutha, J. D. Steenkamp

Advanced high-strength steels (AHSS) are sophisticated materials being developed by the steel industry to mitigate challenges related to the performance of motor vehicles. To meet the requirements of AHSS, the ferromanganese alloys (FeMn) utilized in the production of the steel are required to contain acceptable levels of unwanted impurities, i.e. P, S, N, H, and C. The focus of the current study was to investigate dephosphorization of ferromanganese to produce a low-P alloy that could be effectively utilized in the production of AHSS. The study involved conducting laboratory-scale testwork to study the efficiency of CaO-based slag systems to dephosphorize FeMn alloys. The addition of Na2O, CaF2, and BaO to MnO-CaO-SiO2 slag was considered. The test work was carried out in a 25 kW induction furnace at temperatures of 1350°C, 1400°C, and 1450°C. The P partition coefficient (Lp) remained small at <1, which is an indication that dephosphorization had not been achieved. The baseline slag, comprising 40%CaO-40%SiO2-20%MnO, reported higher Lp values. Addition of Na2O and CaF2 did not show any further benefit. Substituting half of the CaO by BaO, resulted in similar Lp values to those of the baseline slag under conditions of 1350°C and 1450°C at 30 minutes. In summary, based on the Lp values obtained, the conditions investigated with the CaO-based slags appeared to have been unfavourable for dephosphorization of FeMn alloys, as most of this impurity element remained in the alloy.

Sep 1, 2021

By J. D. de V. Louw

Introduction Zircon is a natural occurring mineral and may exhibit natural low level radioactivity. It contains trace levels (90 to120 pCi/g and 110 to 115 pCi/g respectively or 3.3 to 4.4Bq/g and 4.1 to 4.3 Bq/g) of naturally occurring radioactive uranium and thorium. This mineral is often found in a suiteof minerals (rutile, ilmenite and monazite) Due to the overlap in physical properties of monazite (containing 4–7% thorium) with some of the zircon (slight magnetic susceptibility) it often contaminates the zircon, adding to the levels of thorium in the product. Hazards associated with the products from zircon and its processing is inhalation of respirable dust (generated by milling) containing radioactive uranium and thorium which may cause cancer of the lungs. Legislature regulates the transport, use, workplace environment exposure and storage of radioactive material. In America the general regulation for the unlicensed use of low levels of radioactive materials limits the concentration to 500 ppm (U plus Th). Europe (IAEA) specifies a limit of10 Bg/g (Bequerels per gram) on the parents for transport only which is a higher level of U+Th. Companies selling into these markets need to comply with these regulations and certification is therefore required, not only of the major constituents determining the price, but of the U and Th levels as well. Exceeding the limits for U and Th may result in material being returned to the country of origin. However, for the analyst the requirement is to analyse for these elements throughout the production process as well as the analysis of the ‘tails’ that is returned to the mine area. This requires a wide range of concentration to be analysed. Methods of analysis A wide variety of methods exist for the analysis of U and Th in a range of matrices. (Table I) All these methods have been used with varying degrees of success in terms of accuracy. Overall precision for the different techniques varies from 5 to 25% relative. Time to produce results from these methods vary from a few minutes to several days. The Production Chemist is expected to produce between5 and 10 analyses per hour for process control purposes. A suitable technique that fits this requirement is X-Ray Fluorescence. Both Wavelength Dispersive (WDXRF) and Energy Dispersive X-Ray (EDX) instruments are suitable. X-Ray analysis in general has a few major advantages over competitive techniques. •It is fairly simple to set up and interferences are known and easy to correct •It has multi-element analysis capabilities •Clean spectral lines for U and Th (in zircon specifically) •Uncomplicated and easy to measure background •Low detection limits (3 to 5 ppm) •A very high degree of precision •Sample preparation is uncomplicated and fast (pressed powders and fused beads). In Zircon (ZrSiO4) processed sands the matrix is constant(>99% ZrSiO4) and the background is thus essentially constant. A typical set up for the analysis of U and Th by WDXRFis given below: X-Ray Tube Tungsten (W) Target, 2.5 to 3kW operated at 50mA/50kV Crystal LiF200 (or LIF220 for higher resolution) Analytical Lines (2?)U La1,226.14Th La1,227.47 Detector Scintillation Counter Analysis time, depending on the concentration can vary from as little as 20 seconds up to 5 minutes. Standards As with any other comparative technique XRF analysis relies heavily on the quality of the standards used. Assuming proper set-up and operation of the instrumentation as well as consistent sample preparation, accuracy is determined by the quality of the initial calibration standards. A search for the available zircon certified reference materials (CRMs) shows that there are only a few CRMs

Jan 1, 2003

1. Book reviews Tungsten: 1982. London, Mining Journal Books Ltd, 1982. 179 pp. Reviewer: G.A. Brown The geology of industrial minerals in Canada, edited by G.R. Guillet and Wendy Martin. Canadian Institute of Mining and Metallurgy, special volume 29. Reviewer: R.W.O. Kersten Foam flotation - theory and applications, by Ann N. Clarke and David J. Wilson. New York, Marcel Dekker, 1984. 418 pp. Reviewer: B.K. Loveday Industrial and financial indicators of the steel industry, by Patrick Genevaz. Paris, La Chambre des Cartes, 1982. 2 vols. Vol I: Analysis and conclusions, FF3500. Vol. 11: Tables, FF4000. Reviewer: R.J. Dippenaar An encyclopaedia of metallurgy and materials, by C.R. Tottle. Plymouth, Macdonald and Evans and The Metals Society, 1984. 481 pp. RI44,50. Reviewer: P. T. Wedepohl The role of crack growth in metal fatigue, by LP. Pook. London, The Metals Society. Reviewer: C.A. Boothroyd Hydraulic coalmining - new technology and its geological and industrial significance, by H.C. Siebert. Hamm, Zentraldruckerei BAG, 1984. 33 pp. Hydraulic coalmining - hydromining update: potential impact on coal deposits and coal mining industry, by H.C. Siebert. Hamm, Zentraldruckerei BAG, 1984. 130 pp. Victoria&apos;s brown coal. A huge fortune in chancery, edited by J .T. Woodcock. The Australasian Institute of Mining and Metallurgy, 1984. 204 pp. Reviewer: J.J. Versluis 2. Canadian publications The following reviews of the activity and developments during 1982 in respect to the chief minerals produced or consumed in Canada are now available. Zirconium. An important mineral commodity. Mineral Policy Sector, Mineral Bulletin MR 202, $6.60. Canadian minerals yearbook 1982. Mineral Policy Sector, Mineral Report 32, $40.75. Canadian reserves of copper, nickel lead, zinc, molybdenum, silver and gold as of January 1, 1983, by W.H. Laughin. $4.20. Mineral Policy Sector, Mineral Bulletin MR 201. Sulphur market profile, by B.W. Boyd. Mineral Policy Sector, MRI 84/5. 3. Mintek publications Report M123 The use of of activated charcoal in a NIMCIX column for the recovery of gold from cyanide solutions. Report M150 Energy transfer in the hearths of submerged-arc furnaces. Report M151 A preliminary investigation of the initiation of pitting corrosion in austenitic stainless steels and nickel-based alloys. Report M154 The reduction of Winterveld chrome spinel at 1300°C under an argon atmosphere in the presence of carbon. Report M165 The development of an improved on-line gold analyser. Report MI67 three nebulizers for use with an inductively coupled plasma spectrometer. 4. New publications Mineral Industry Consultants Association (as at 31st March, 1984). Parkville (Australia), The Australasian Institute of Mining and Metallurgy, 1984. 112 pp. Philosophical and procedural guidelines for the planning professions. Johannesburg, the Environmental Planning Professions Interdisciplinary Committee (EPPIC, P.O. Box 61019, Marshalltown 2107), R2.50. Directiona//y solidified materials for high temperature service, by M. McLean. London, the Metals Society, 1983. 337 pp. Tin and its uses no. 142. Greenford (England), International Tin Research Institute, 1984. Metals engineering International Symposia & Exhibitions Ltd - a subsidiary of Industrial Newspapers PLC - are pleased to announce that they will be organizing a mammoth engineering event, entitled Metals Engineering 86, comprising five important exhibitions in 1986:. Agglomeration A major symposium on agglomeration is being organized in Toronto for the 2nd to 5th of June, 1985. Speakers from around the world (Canada, U.S.A., Brazil, Australia, Japan, West Germany, Italy, India, China, Switzerland, Poland, Yugoslavia, and France) will address delegates on various aspects of agglomeration relative to iron ore, coal, coke, and fuels. Plenary theme papers will also be presented by speakers from Japan, the U.K., and the Netherlands.

Jan 1, 1985

Dr R. E. Robinson, Pr. Eng., obtained a B.sc. (Chem. Eng.) cum laude from the University of the Witwatersrand in 1950 and a Ph.D. (Eng.) from the same University in 1953, where he was awarded the Haikes Memorial Medal for Industrial Chemistry. Professor G. G. Garrett was appointed Professor of Physical and :Fabrication Metallurgy in the Department of Metallurgy at the University of the Witwatersrand in June 1980, and in January 1984 he became Head of the Department. Mr P. A. van Wielligh, Pr. Eng., climbed the mining ladder in the hard way, starting as a Mine Surveyor in 1936 and working his way up as Chief Surveyor, Underground Manager, Mine Manager, and Consulting Engineer, to Executive Director, including the intermediate steps. Mr H. E. James, Pr. Eng., is a graduate in Chemical Engineering from the University of the Witwatersrand. Both his B.sc. degree (1961) and his M.sc. degree (1964) were obtained on bursaries, the former from Gold Fields of South Africa and the latter from the Atomic Energy Board. Mr G. Pienaar, Pr. Eng., obtained a B.Eng. (Met) in 1967 and an M.Eng. in 1973, both from the University of Pretoria. Dr A. K. Haines, Pr. Eng., obtained all his degrees from the University of Natal, finishing with a. Ph.D. in 1971. Mr B. C. Alberts, Pr. Eng., obtained his academic training at the University of Pretoria, where he was awarded B.sc. degrees in both agricultural engineering (1963) and mining engineering (1965). Mr H. C. van Zyl, Pr. Eng., holds B.sc. degrees in mining engineering (1968) and civil engineering (1972), both from the University of Pretoria.

Jan 1, 1984

By S. Banisi, S. M. Mousavi, S. D. Tafvizi, Gh. A. Parsapour, M. Mahmoudi

Generally, regrind circuits are used to increase the degree of liberation of value minerals which are fed to flotation circuits. At the regrind circuit of the Sarcheshmeh copper complex, four ball mills are in closed circuit with their hydrocyclone clusters. In the initial design of the plant, feed and underflow percent solids, and pressure drop of the hydrocyclones were 39% and 65%, and 15psi, respectively. Over the years, due to a reduction in the feed grade from 1.17% to 0.67% and changes in the operational conditions, the feed rate to each hydrocyclone cluster has decreased from 401 to 70t/h and consequently the pressure drop, feed and underflow percent solids have reduced to 4psi, 17% and 25%, respectively. The main objective of this research was to audit the feed solids concentration and pressure drop of the hydrocyclones and make the necessary modifications based on the Plitt’s model. The results of sampling showed that water recovery to underflow was 59% which was higher than normal values. By reducing the number of operating regrind mills from 4 to 2, the feed rate to each mill increased. After this modification and taking necessary measures in the plant to implement the new operating approach, the pressure drop, feed and underflow percent solids increased to 18psi, 28% and 58%, respectively. The water recovery of the hydrocyclones underflow decreased from 59% to 12%. These changes in addition to increasing the circuit efficiency saved 1000 kWh energy and decreased ball consumption by 925 ton/year because of reduction in the number of operating ball mills. Keywords: Regrind mills, flotation, audit, troubleshooting

Jan 1, 2020

By J. -W. Kim, Y. -B. Kang, H. -G. Lee

The effect of SiO2addition on the decomposition of Li2CO3was investigated at temperatures up to 1000ºC. It was found that addition of SiO2greatly enhanced the decomposition of Li2CO3. The main decomposition reaction started at around 600ºC, and completed just above the melting point of Li2CO3. The major decomposition product was Li2O?SiO2irrespective of the Li2CO3to SiO2mixing ratio while both reactants were available. It was ascertained that a liquid layer betweenLi2CO3and SiO2particles formed and facilitated the decomposition reaction. The governing reaction of the decomposition was the one between the dissolved Li2CO3and SiO2in the liquid layer to form Li2O?SiO2. The decomposition rate was independent of the Li2CO3/SiO2mixingratio until either one had been completely exhausted. When excess Li2CO3existed, it further reacted with the initial product of Li2O?SiO2to form 2Li2O?SiO2. When SiO2was found in excess, on the other hand, no further reaction took place. This is attributed to the fact that uponLi2CO3exhaustion there is no liquid phase available to facilitate further reaction. The apparent activation energy of the decomposition of Li2CO3in existence with SiO2is 198 kJ mol-1.

Jan 1, 2004

By E. Kapilashrami, S. Seetharaman

Refractory/metal interactions and associated reactions are significant during casting as they can lead to inclusion formation. High-temperature interactions between aluminosilicate refractories and molten steel were studied in the present investigation using the sessile drop method. The changes in the contact angles between molten iron with well-defined oxygen levels and substrates of silica, mullite (3Al2O3?2SiO2) as well as commercial refractories were measured in the dynamic mode. In all cases, the reaction led to slag formation. The experiments were performed under isothermal conditions at 1823 and 1873 K. A known and constant oxygen partial pressure was imposed above the iron drop, through appropriate CO-CO2-Ar mixtures. For all substrates, the contact angles started decreasing due to the lowering of the surface tension of iron, as oxygen was imposed on to the system. When a critical level of oxygen was reached, slag started forming at the drop/substrate interface and at this stage, the contact angle dropped suddenly. Subsequent behaviour of silica and mullite was observed to be different, with SiO2showing a non-wetting behaviour. In the case of SiO2substrate, there were also deep erosions along the periphery of the drops and there was slag accumulation at the sides of the metal drop, probably due to Marangoni flow and/or SiO(g) formation. SEM and EDS analysis of the substrates revealed that the formed slag was fayalite. The thermodynamic criteria for slag formation and possible mechanisms of the reaction are discussed in the light of the experiments. Key words: silica, mullite, fayalite, corundum, slag formation, sessile drop.

Jan 1, 2004

Mixtures of MnO and graphite were reacted under argon at temperatures ranging from 1200 to 1425°C, and the loss in mass of the mixture was recorded continuously. The results showed that the rate of reduction of MnO increased as the temperature increased and the ratio of MnO to C decreased. The effect of the particle size of MnO and of graphite on the rate of reduction at I350°C was very small in the range 63 to 250 µm for MnO and 45 to 355 µm for graphite. The rate of reduction at I350°C was increased markedly by the addition of Na2CO2 and K2CO3, was slightly increased by the addition of Fe2O3, was unaffected by the addition of CaO, MgO, and AI2O., and was decreased by the addition of SiO2. Some CO2 was always present in the effluent gas, and this was taken as evidence that the reduction of MnO occurred by way of CO2 as an intermediate product. The activation energy of the ratecontrolling step was 57,5 kcal, and this was similar to the measured activation energy for the gasification of graphite by CO., namely, 61,S kcal per mole of graphite. A simple kinetic model was derived on the assumption that the gasification of graphite was the ratecontrolling step, and the results over the temperature range 1200 to I425°C, when plotted in the appropriate form, yielded straight lines as predicted by the model.

Jan 1, 1980

1. New books P. Sarnoff. Trading in gold. Cambridge, Woodhead- Faulkner, 1980. 136 pp. £3.50 by airmail. Environmental Planning Professions Interdisciplinary Committee (EPPIC). Proceedings: Joint EPPIC/Habitat Symposium: Shaping Our Environment. Johannesburg, EPPIC (P.O. Box 61019, Marshalltown 2107), 1980. R3 per set of 2 issues. H. P. Patra and K. Mallick. Time-varying geoelectric sounding. Amsterdam, Elsevier, 1980. 420 pp. D.S. $87.75. Die Suid-AfrikaanseSteenkoolverwerkingsvereniging. Steenkoolvoorbereidingskursus. J ohannes burg, die Vereniging, 1930. 335 pp. Members of Chamber of Mines of South Africa R15, nonmembers R40. D. R. Derry. A concise world atlas of geology and mineral deposits. London, Mining Journal Books, 1980. HO pp. £26.25 byairmail. 2. Journal Remote sensing of environment (RSE). 3. NIM reports Report No. 2064 The on-line monitoring of gold in barren solutions. Report No. 2065 The determination, by X-ray-fluorescence spectrometry, of gold, silver, and base metals on activated carbon. Report No. 2068 The determination of platinum, palladiuim, rhodium, and gold in ores and concentrates by the fusion technique with lead as the collector. Report 2061 The determination, by anodic-stripping voltammetry, of copper and lead in silicate reference materials. Report 2062 The reduction by computer of photoplate data obtained by spark-source mass spectrornetry. Report 2071 The determination, by X-ray-fluorescence spectrometry, of tin and tungsten in scheelite and ca8siterite ores and concentrates. Tunnelling Tunnelling &apos;82, the third international symposium in the series, is being organized by the Institution of Mining and Metallurgy, with the co-operation of the British Tunnelling Society, the Institution of Mining Engineers, and the Transport and Road Research Laboratory.

Jan 1, 1980

By K. Barani, S. M. S. Ganji

Creatine was used as a lixiviant for gold dissolution from gold ore. The effects of creatine concentration, temperature, leach time, and pH were examined for their influence on extent of gold dissolution. The results show that at a temperature of 75°C and pH 11.5, gold dissolution increased from 51% to 88% on increasing creatine concentration from 25 to 50 g/t. Further increase in creatine concentration showed a negative effect on the gold dissolution. Gold dissolution increased from 47% to 87% by increasing the temperature from 25°C to 55°C, and from 61% to 89% by increasing pH from 10 to 11.5. Under the optimum conditions of solids’ content of 30%, pH 11.5, creatine concentration of 100 g/t, temperature of 75°C, and hydrogen peroxide addition of 2%, about 90% of the gold could be dissolved from the ore after 24 h. A comparison between creatine and cyanide leaching showed that 90% gold dissolution was achieved at a cyanide concentration of 300 g/t, which is three times higher than the creatine concentration under optimal conditions.

Apr 14, 2024

By F. T. Cawood, M. N. M. Cudjoe

The ability to conduct real-time material tracking in mines has been a long-standing challenge. Technological innovations such as radio frequency identification technology (RFID) have over the years contributed to the effective tracking of material flow and reporting of metal content. This paper outlines the laboratory procedures and results from testing the suitability of microdot technology as a viable technique for real-time material tracking in mining. The paper clarifies the reasons for conducting the test and presents the material safety data sheet (MSDS) from a South African and Canadian perspective. Microdots from three aerosol systems were immersed in water, heated to 100°C, and crushed into coarse and fine material. These tests were used to ascertain if the technology could withstand mining conditions. A strength, weakness, opportunity, and threat (SWOT) analysis was used to evaluate and compare microdot technology with RFID. It was shown that microdot technology has some potential to track ore parcels because data integrity was retained after exposure to post-blast mining conditions. However, more improvement is required to digitally detect microdots before the technology can be implemented at scale in the mining industry.

Apr 2, 2022