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By Hans Strack

Electroluminescence of GaAs p-n junctions fabricated by simultaneous diffusion of sulfur and iron was investigated at 77°K. A narrow emission peak with a half width of about 4 kT in the energy range between 1.14 and 1.155 eu was attributed to iron. Other transition elements exhibited light emission in the vicinity of the iron peak, namely nickel between 1.15 and 1.16 ev and cobalt between 1.16 and 1.17 ev. The efficiency of the doping with iron depended on the amoz~nt of arsenic present. A weight ratio of arsenic to iron of 4:l was sufficient to observe the emission lines associated with transition elements. The presence of oxygen reduces the intensity of the light emission. In addition to the levels associated with transition elements, levels at 1.05 and 1.28 ev, probably due to lattice defects, are observed except in diodes fabricated in solution-grown GaAs. THE near band edge emission of GaAsp-n junctions has been studied extensively in the past.' GaAs devices utilizing spontaneous and stimulated near band edge emission are of considerable practical importance. Typical junctions are fabricated by diffusion of a heavily doped p region into degenerate n-type GaAs. Much less work has been done on investigating the radiative recombination via deep levels in lightly doped p-type material. This area is of interest in understanding the performance of GaAs n-p-n transistors. GaAs transistors show remarkable improvement in high-frequency performance and current-gain stability at high temperatures, when iron is added to sulfur during the emitter diffusion process. The present work was initiated to investigate deep-level electroluminescence of iron-doped GaAs p-n junctions fabricated on vapor-phase epitaxial GaAs and on solution-grown GaAs. For comparison several diodes doped with cobalt and nickel were studied. Iron, cobalt, and nickel have an electron configuration of the type

Jan 1, 1968

I would like to congratulate the authors on an interesting paper and, in particular, on their justification of the use of superposition in treating gas wells. They state, however, that no theory has previously been developed lor treating the variable rate drawdown case. In a paper published a few years ago by my colleagues and myself, a method is described which allows a constant rate drawdown curve to be derived for any well. regardless of real rate variations. This method has the great advantage that it is not necessary to make any assumptions regarding the form or uniformity of the reservoir, and the derivation suggested by the present authors is simply an idealized case of our more general treatment. In the light of several years' experience in the derivation of constant rate drawdown curves: I would like to point out that the method proposed by Odeh and Jones may lead to confusing answers, particularly if applied over an appreciable time interval. The reason is that, if pressures are measured when a well is flowing, non-linearities in plots like Figs. 1 and 2 can arise due to either (1) changes in the skin factor with time and/or flow rate, or (2) an inhomogeneous reservoir. Separation of these two effects is only possible if some of the pressures used in the analysis are measured when the well flow rate is 0 or, in other words. during brief shut-in periods. REFERENCES 1. Arthur, K. B.. Metunomski, Z. G. and Ruche, Ms "Intetet ct methode d'utilisa tion des mesures de pression [)our Petude des gisemonts" Revue de T'I.F.P. (Nov., 1962) XVII, 1299. 2. Thomere, R. and Arthur, K. R.: "Analysis of the Pressure Bet~avior of a Production Well Subject to Interterence and Its Application to Reservoir Models", Paper SPE 1189 presented at SPE :Amund Fall Mecting Ireld in Denwer, Colo. (Oct. 3-6, 1965).

Jan 1, 1966

By Otto W. Nuttli

THE magnetic method of prospecting is well suited to determination of faulting in the basement rock. In addition to establishing the horizontal position of the fault, it often furnishes valuable information concerning the depth and amount of faulting. Consider a simple case of a vertical fault, represented in cross-section in Fig. 1. Let A A' represent the plane of observation (ordinarily the surface of the earth), and BB'B"B"' the upper surface of the basement. Assume that the sedimentary rocks are nonmagnetic, so that the magnetic susceptibility of the material above the basement is zero. Let k indicate the susceptibility of the basement rock, c the density contrast between it and the neighboring sedimentary rocks, and the amount of vertical displacement. Fig. 1 shows the material, indicated by cross- hatching, which gives rise to the magnetic anomaly. In most cases it can be assumed that is small compared to the thickness of the sedimentary rocks. The semi-infinite, rectangular slab of rock of susceptibility k, density contrast , and thickness t may then be replaced by a semi-infinite sheet CC' of mass t per unit area at depth 2 (the mean depth of the slab). Nettleton 1 states that this approximation results in an error of less than 2 pct for the computed gravitational field intensity when t is as great as 2/2 and decreases rapidly for smaller values of t. By a theorem of Poisson, the magnetic field intensity can be determined readily from the gravitational field. The theorem states that W = (I/) • (U/i) i1 [1] where W is the magnetic potential associated with the structure, I is the intensity of magnetization which is assumed to have the direction of the inducing field, ? is the constant of gravitation, the density contrast, U the gravitational potential associated with the structure, i the direction of the inducing magnetic field, and i1 a unit vector in that direction. The multiplication indicated in Eq. 1 is

Jan 1, 1956

By George L. Heath

This paper is devoted chiefly to the coal-fields of the western part of the province of Chili and the eastern part of the province of Shansi; but the outline of this belt will give some idea of the extension of the coal-fields over northeastern China. This part of China is topographically divided into: (1) the mountainous peninsula of eastern Shantung; (2) the coastal plains, extending W. and SW. from the gulf of Pechili; and (3) the mountains and table-lands N. and W. of the coastal plains. The plains extend N. and W. from the gulf to within from 10 to 25 miles of the Great Wall, while their SW. extension covers western Shantung and reaches W. along the Yellow river almost to the southern boundary of Shansi. A line joining the mapped coal-fields, shown in Fig. 1, almost gives the western boundary of the plains; since these areas lie on the border of the plains—except the Tsê Chou field, which is on the table-land, 20 to 25 miles from that border. The coal-fields which have been mapped and investigated by the author are shown in Fig. 1. The one at and around Tongshan is known as the K'ai-p'ing coal-field; the one W. of Peking has been called the Wang-p'ing coal-basin; the one SW. of Pao-ting and N. of Chêng-ting may be called the Lingshan coal-field; and the one at and around Tsê Chou is known as the Tsê Chou coal-field. I. The K'ai-p'ing Coal-Field. As is shown in Fig. 2, most of this field lies in the coastal plains, and is therefore covered by alluvium and loess, which have buried the older rock-beds, and the more gentle and older topographic outlines, to such an extent that most of the re-

Jan 1, 1902

Institute of Metals Iron and Steel Mineral Industry Industrial Minerals Year Division Petroleum Division Division Coal Division Education Division Division 1918 W. M. CORSE ' 1919 " 1920 W. H. BASSETT 1921 1922 W. B. PRICE RALPH ARNOLD 1923 E. DEGOLYER 1924 G. K. ELLIOTT 1925 " F. JULIUS FOHS 1921; PAUL D. DIERICA " 1927 JOHN M, LOVEJOY 1928 S. SKOWRONSKI A. W. AMIBROSE RALPH Fl. SWEETSER 1929 " J. B. UMPLEBY G. B. WATERHOUSE 1930 ZAY JEFFRIES C. V. MILLIKAN \V. J. MACKENZIE HOWARD N. EAVENSON 1931 SAM TOUR C. E. BEECHER F. AT. BECRET 1932 C. H. MATHEWSON EARL OLIVER F. N. SPELLER THOMAS G. FEAR , C. H. FULTON 1933 T. S. FULLER W. E. WRATHER JOHN JOHNSTON ELI T. CONNER 1934 .J. L. CIIIRISTIE H. D. WILDE, .JR. L. F. REINARTZ T. T. READ 1935 W. M. PEIRCE HARRY H. POWER A. B. KINZEL JOHN T. RYAN SAMUEL H, DOLBEAR 1936 E.H. DIX,JR. HALLAN, N. MARSH C. E. WILLIAMS EUGENE McAULIFFE WILLIAM B; PLANK' OLIVER BOWIES 1937 A. J. PHILLIPS AL ALBERTSON FRANCIS B. FOLEY J. B. Moscow " CHESTER A.. FULTON 1938 R. F. MEHL G. B. CORLESS J. T. MACKENZIE PAUL WEIR FRANCIS A.THOALSON J. R. THOENEN 1939 R. H. LEACH W. I-1. G E I S J. HUNTER NEAD C. A. GIBBONS " AT. M. LEIGHTON 1940 C. A1. WISE T. V. MOORE F. T. SISCO C. E. LAWALL W. R. CHEDSEY W. M. WEIGEL 1941 D: K. CRAJIPTON E. A. STEPHENSON C. H. HERTY, JR. JULIAN E. TOBEY " . PAUL AT. TYLER 1942 CARL E. SWARTZ HARRY P. STOLZ E. C. SMITH NEWELL G. ALFORD A. F. GREAVES-WALKER B. L. MILLER 1943 CYRIL STANLEY SMITH C. A. WARNER HERBERT W. GRAHAM CADWALLADER EVANS, JR. " HOWARD 1. SMITH 1944 ARTHUR PHILLIPS W. S.-MORRIS WILLIAM A. HAVEN A. W. GAUGER A. C. CALLEN C. H. BEHRE, JR

Jan 1, 1944

By D. T. MacRoberts

A simple disturbance in a gas reservoir travels with a finite velocity which is nearly independent of the amplitude of the disturbance. As a result very complex transients may be set up which seriously affect observation at a well. The time of transient is much longer than commonly supposed. INTRODUCTION A change in pressure at a gas well is not propagated through the reservoir instantaneously but with a definite fin- ite velocity. Knowledge of the period ! of this transient is of value because: 1. Observations of pressure and flow-rate during the transient may affect interpretation of back-pressure tests. 2. Interference effects between wells may be used to determine continuity of formation. 3. Additional information concerning the physical characteris- tics may possibly be deduced from the behavior of a well during the transient. MATHEMATICAL DEVELOPMENT It will be assumed that the well is initially closed in and that the pressure is constant throlughout the reservoir. As the initial disturbance passes outward from the well it is further assumed that a logarithmic pressure distribution is established between the most distant point reached and the well, so that: <l> = ((/)r-<t>w) I ------------ + (/) . (1) Manuscript received at office of the Branch September 15. 1948. Paper presented at Branch Fall Meeting, Dallas. Texas. Oct. 4-6, 1948. r. = distance to any point between r and rw r = radius of drainge iw= radius of well (/) = potential (P for incompressible fluids, P2 for perfect gases) Up to the time the effect reaches the point r the production from the well will be: W= (Pr-P,,,) . (2) i b W = volume produced t = sand thickness F = fractional porosity Pr = reservoir pressure Pm = average pressure between r and rw Pb = atmospheric Pressure All pressures will subsequently be stated in atmospheres and the constant Pb will be omitted. This will be produced at a rate: dw t k (Pr³-PW2) do d 0 - . (3) log — Pw = pressure at the well k = permeability 0 = time = viscosity

Jan 1, 1949

By J. B. Mackintosh

In a recent paper read before the Institute on this subject, Mr. G. C. Stone advances the theory that the precipitate obtained in Williams&apos;s volumetric process,* by treating the boiling nitric acid solution of a manganese salt with potassic chlorate., is not pure MnO2, but approximates more closely to the composition 10Mn02+Mn0. As the value of the process and the accuracy of our results mould depend on whether this was the fact or not, it has seemed to me, and to my associates, Messrs. Beebe and Colly, that it would be of importance to ascertain the composition of this precipitate, and to that end the following series of experiments has been undertaken. These experiments have all been based on the considerations: 1. That potassic permanganate has an oxidizing power equivalent to five atoms of oxygen for every two of manganese : K2Mn2O8 = K2O.2MnO.O5. 2. That the same amount of manganese in the state of binoxide has an oxidizing power equivalent to two atoms of oxygen : 2MnO2 = 2MnO.O2. If, then, we take a solution of permanganate of unknown strength, and reduce it to binoxide, the oxidizing power of the binoxide formed will be equal to that of two-fifths the quantity of the permanganate solution originally taken. While, if the precipitate obtained should not be binoxide, but an indefinite or definite mixture of bin- and mon- oxides, then, from its equivalent oxidizing power, we can calculate its composition. The analyses were conducted in the following manner. The amount of permanganate taken was decomposed with hydrochloric acid, and concentrated to expel the excess of water. Sufficient excess of nitric acid was now added, and the solution was boiled until all the hydrochloric acid was destroyed. The manganese was then precipitated by potassic chlorate; and, after standing some time to cool—a pre-

Jan 1, 1884

By D. T. MacRoberts

A simple disturbance in a gas reservoir travels with a finite velocity which is nearly independent of the amplitude of the disturbance. As a result very complex transients may be set up which seriously affect observation at a well. The time of transient is much longer than commonly supposed. INTRODUCTION A change in pressure at a gas well is not propagated through the reservoir instantaneously but with a definite fin- ite velocity. Knowledge of the period ! of this transient is of value because: 1. Observations of pressure and flow-rate during the transient may affect interpretation of back-pressure tests. 2. Interference effects between wells may be used to determine continuity of formation. 3. Additional information concerning the physical characteris- tics may possibly be deduced from the behavior of a well during the transient. MATHEMATICAL DEVELOPMENT It will be assumed that the well is initially closed in and that the pressure is constant throlughout the reservoir. As the initial disturbance passes outward from the well it is further assumed that a logarithmic pressure distribution is established between the most distant point reached and the well, so that: <l> = ((/)r-<t>w) I ------------ + (/) . (1) Manuscript received at office of the Branch September 15. 1948. Paper presented at Branch Fall Meeting, Dallas. Texas. Oct. 4-6, 1948. r. = distance to any point between r and rw r = radius of drainge iw= radius of well (/) = potential (P for incompressible fluids, P2 for perfect gases) Up to the time the effect reaches the point r the production from the well will be: W= (Pr-P,,,) . (2) i b W = volume produced t = sand thickness F = fractional porosity Pr = reservoir pressure Pm = average pressure between r and rw Pb = atmospheric Pressure All pressures will subsequently be stated in atmospheres and the constant Pb will be omitted. This will be produced at a rate: dw t k (Pr³-PW2) do d 0 - . (3) log — Pw = pressure at the well k = permeability 0 = time = viscosity

Jan 1, 1949

COLUMBIA SECTION J. C. HAAS, Chairman W. J. HALL,. Vice-chairman LYNDON K. ARMSTRONG, Secretary-Treasurer, 720 Peyton Bldg., Spokane, Wash. W. H. LINNEY J. F. MCCARTHY At a meeting of the members of Columbia Section, which was held in the Davenport hotel, Spokane, Wash., Jan. 31, 1919, at noon, there were present&apos; about twenty members and guests. The chairman being absent, Mr. Frederick Keffer presided. The Secretary announced the personnel of the executive committee of the section, which is: J. C. Hass, Spokane, Chairman; W. J. Hall, Wallace, Ida., Vice-chairman; S. S. Fowler, Riondel, B. C., Past Chairman; L. K. Armstrong, Spokane, Secretary-Treasurer; R. M. Betts, Cornucopia, Oregon. It was stated that the geological survey and report on Stevens Co., Wash., has been completed and will be printed soon. The geologic survey of Colville Indian reservation, by J. T. Pardee, U. S. G. S., has been published as Bulletin No. 677 and is available for distribution, The Miner&apos;s Almanac, Miners Circular No. 24, U. S. Bureau of Mines. is also available upon request. There was considerable discussion on the program for meetings during the year. It was informally agreed that, if agreeable to Coeur d&apos; Alene members, that one meeting should be held in that district, preferably at the time of the annual visit of Institute officials. It was also proposed to hold at least one open-air meeting in Spokane with suitable program. The activities of other sections were noted with favorable comment. In this connection there was much general discussion on the subject of closer relations between the national engineering societies. It was agreed that cooperation was desirable and imperative if the greatest measure of value be realized from the profession. It was not the sense of the members, however, that complete amalgamation is desirable. This expression of local sentiment is to be presented to the Institute

Jan 3, 1919

By W. L. DeMoulin

A rather detailed description of the entire plant and leaching process was given in a paper recently presented to the Institute,I so this paper will cover briefly only the crushing practice of the New Cornelia Copper Co. for the year 1918. The ore, which is mined by steam shovels and loaded in side-dump cars, passes through two crushing plants. These crushing plants were constructed to crush the ore required by a leaching plant of 5000 tons daily capacity, during a crushing period of 16 hours. The primary plant reduces to less than 3 in. (76 mm.) and the secondary plant, to 1/4 in. (6.35 mm.), which is sufficiently fine for satisfactory percolation of solution through the ore in the leaching tanks, and to give-good extraction. The ore is then conveyed to the leaching tanks by a system of 28-in. (71-cm.) belt conveyors. On the way to the leaching tanks, it passes through an automatic sampling plant, where a 1-per cent. sample is taken. From the primary crushing plant, the ore is conveyed by two 36-in. (91-cm.) belt conveyors to a 10,000-ton steel storage bin, with a reinforced-concrete flat bottom. The ore discharges from the bottom of this&apos; bin onto four 20-in. belt conveyors, which deliver it to the four units of crushers in the secondary crushing plant. There is no storage bin between the mine and the primary crushing plant. The ore breaks very coarse, is very hard, and contains a great many boulders, some as large as 4 1/2 by 4 1/2 by 10 ft. (1.3 by 1.3 by 3 m.). Jams form in the bowl of the coarse crusher in the primary crushing plant, as a consequence, and are freed by means of an immense steel hook operated from a 40-ton electric traveling crane. Primary Crushing Plant The primary plant consists of one No. 24 Gates, style K, gyratory crusher, followed by four Gates No. 8, style K, gyratory crushers. All

Jan 1, 1920

By R. S. Wagner, W. G. Pfann

If an electric field is applied to a conducting liquid solution, changes in concentration usually occur because of differences in ionic mobilities. A variety of ways of utilizing this effect in conjunction with the freezing process are discussed in principle. For example, if a column of binary eutectic liquid is maintained a few degrees above the melting point and a field is applied, the component solid solutions will crystallize at opposite ends of the column until the liquid is consumed. An expression for the effective distribution coefficient, k, is derived for the case of a direct current Passing through a solid-liquid interface. It is shown that k can be varied It is well known that solute distributions in crystalline substances can be controlled by careful freezing from melt or solution. It is also well known that an electric field can produce substantial changes of concentration in liquid solutions by virtue of differences over a wide range, including values outside the usual range between ko (the equilibrium value) and unity. Hence, for many systems: the efficiency of zone refining can be increased; a ko of unity can be made greater or less than unity; solutes that lower or raise the fretzing point can be concentrated at the same end of the ingot by zone refining; be made equal to unity; and the tendency toward constitutional supercooling can be reduced. The methods of field-freezing are applicable to a wide range of materials including metals, semiconductors, and ionic conductors. in ionic mobility. In this paper we discuss, in principle, some methods that combine these techniques in useful way&apos;s. The methods are designated by the general term, field-freezing. Topics discussed include separation of the components of a eutectic, crystal growth, and controlling the value of the effective distribution coefficient. The methods are applicable to a broad range of materials, including alloys, semiconductors, fused salts, and other liquid electrolytes.

Jan 1, 1962

By Charles Berkey

CONTENTS PAGE C. P. Berkey-Responsibilites of the Geologist in Engineering Projects (with discussion) 4 Kirk Bryan-Problems Involved in the Geologic Examination of Sites for Dams 10 0. E. Meinzer-Relation of Ground-water Conditions to Leakage of Reservoirs (with discussion) 19 Charles Terzaghi-Effect of Miner Geologic Details on the Safety of Dams (with discussion) 31 G. H. Matthes-More and Better Geologic Data for Use in Hydraulic Projects (with discussion) 47 L. W. Fisher and R. D. Ohrenschall-Geologic Examination of Dam Sites in the Tennessee and Cumberland River Basins 60 C. K. Wentworth-The Geology of Dam Sites (with discussion) 78 L. C. Glenn-The Geology of Dams and Reservoirs 97 H. T. Stearns-Success and Failure of Reservoirs in Basalt (abstract) 111

Jan 1, 1929

By R. E. Ogilvie, N. L. Peterson

Diffi-lsion measurements were conducted at all compositims in the bcc solid solution of the U-Nb system employing incremental couples at composition intemals of 10 at. pct. Diffusion coefficients were determined by the Matano method from concentration gradients obtained with the electron-probe microanalyzer. The activation energy for inter-diffi-lsion as a function of compositim shows three distinct regions: 1) 80 to 100 pct U.6= 30 kcal per mole; 2) 20 to 80 pct U, $ - 70 kcal per mole; 3) Oto 20 pet U, Q = i40 kcal per mole. The frequency factor, fi0 and the activation energy $ were found to be roughly related by the following equation: log Do ^9.7 X IO-5Q -6,6. The Kirkendall marker movement indicates that DU is larger than DNb between 16 and 100 pct U and DNb is larger than DU from 0 to 4 pct U. FOR practical as well as fundamental reasons, the rates of diffusion in alloys are of considerable consequence. Most solid-state reactions are largely dependent upon the diffusion of atoms through the lattice structure and along grain boundaries. The high-temperature strength and reasonable nuclear properties of niobium have prompted its use as a reactor material in contact with uranium fuel. Hence, diffusion data for the U-Nb system are of considerable importance. In the previous diffusion study1 on the U-Nb system using pure element couples, reliable data were obtained only in the range of 0 to 10 at. pct Nb due to the large variance of the diffusion coefficient with composition. Also, a large Kirkendall effect and considerable porosity in the uranium-rich areas of the specimen were reported, which suggests that the true diffusion coefficients are somewhat larger. The purpose of the present study was to obtain reliable diffusion coefficients at all compositions using incremental diffusion couples with intervals of 10 at. pct. In view of the abnormal self-diffusion be- havior of y uranium2-4 and some other bcc transition elements,&apos;-&apos; it was felt that a comparison of the interdiffusion coefficients in the bcc U-Nb system with those of Reynolds et al.9 for the fcc gold-nickel system might shed some light on the diffusion mechanism involved. Both systems have similar phase diagrams, in that complete solid solubility exists above a miscibility gap. EXPERIMENTAL PROCEDURE The uranium used in this investigation was obtained through the courtesy of Argonne National Laboratory. An analysis of this material detected only Si-30, A1-7, C-6, N < 10 and 0-18 ppm. The niobium was electron-beam melted material obtained from Stauffer-Temescal. The gaseous impurities were less than 50 ppm, and the spec troc hemical analysis showed Ta-500 and W-200 ppm. U-Nb alloys were prepared at composition intervals of 10 at. pct by melting the appropriate amounts of the pure elements in an arc furnace. The buttons were inverted and remelted 6 times to assure complete mixing. The buttons were then wrapped in molybdenum foil, canned in Zircaloy-2 or stainless steel, and hot rolled 30 pct reduction in thickness at temperatures between 850" and 1100°C. Alloys with 10, 20, 30, 40, and 90 at. pct Nb rolled quite easily under these conditions, but the 50, 60, 70, and 80 pct alloys remained brittle. After melting and rolling (when possible), the alloys were annealed for 24 hr at a temperature within 100°C of their melting point in a dynamic vacuum of better than 4 x 10-8 mm Hg. These treatments produced alloys which were homogeneous on a 1 p scale within the detectability limits of the electron probe. During fabrication, the alloys picked up as much as 100 ppm Mo and 100 ppm Zr. Other elements checked for but not found were Co, Cr, Fe, Mn, Ni, and Ti. The grain size of the annealed samples ranged from 3 mm for the uranium-rich alloys to 0.3 mm for the niobium-rich alloys. This permitted measurements of the concentration gradients in the diffusion samples without crossing more than one or two grains, thereby eliminating any grain boundary effects. The specimens were bonded by theU&apos;picture frame" technique as reported by Kittel.10 Specimens of composition b)U + (100 - x)Nb were sandwiched between two specimens of composition (x + 10)U + (90 - x)Nb after they were ground flat and parallel

Jan 1, 1963

By C. W. Sherman, N. J. Grant

The correlation of the high temperature chemical properties of slag-metal systems with some easily measured property of either slag or metal at room temperature has been the goal of both process metallurgists and melting operators for many years. There are several rapid methods for estimating various constituents in steel in addition to the conventional chemical methods which are quite fast, but these do not reveal the nature of the slag as a refining agent, which is of primary interest to the steelmaker. Furthermore, there are several methods for examining slag, the three principal ones being slag pancake, petrographic examination, and the previously mentioned chemical analysis. The main objection to the last two is the lime required to make a satisfactory estimate of the mineralogical or chemical components. The objection to the first is the inadequacy of the information obtained. A new technique has been developed by Philbrook, Jolly and Henry1 whereby the properties of slags are evaluated from an aqueous solution leached from a finely divided sample of slag. It is known that the pH or hydrogen ion concentration (of saturated solutions that have dissolved certain basic oxides, notably calcium oxide) will indicate a pronounced basicity. Philbrook, Jolly and Henry devised the pH measurement technique in order to supply open hearth operators with a fast, reasonably accurate method of estimating slag basicity. They offered the method as an empirical observation and made no claims as to its theoretical justification. The results were presented as an experi-metally observed relationship which applied over an important range of basic open hearth slags. They found that, in plotting the measured pH against the basicity, the best relationship existed between the pH and the log of the simple V ratio, CaO/SiO2. Extensive investigation also showed that there were several variables in the experimental technique that influenced the results and necessitated following a standard procedure to obtain reproducible pH readings. These variables were: 1. Particle size of the slag powder used. 2. Weight of sample used per given volume of water. 3. Time of shaking and standing allowed before the pH was measured. 4. Exclusion of free access of atmospheric carbon dioxide to the suspension. 5. Temperature of the extract at the time the pH was measured. In subsequent investigations of the pH method by Tenenbaum and Brown2 and by Smith, Monaghan and Hay3 the general conclusions of Philbrook&apos;s work were reaffirmed. It was the object of the present investigation to extend the technique to a point where it could be used to evaluate slags of all types. Experimental Results PARTICLE SIZK OF SLAG POWDER A large sample of commercial blast furnace slag of intermediate basicity (V-ratio 1.15) was selected for the study. The slag had been put through a jaw crusher until all of it passed through a 20 mesh screen. Five fractions of this crushed material were separated, -20 to +40, -40 to +60, -60 to +100, -100 to +200, and -200 mesh. A representative sample of 0.5 g was removed from each fraction and the pH determined using the method of Philbrook. Check pH analyses on the sample fractions varied due to the different amounts of shaking. To eliminate this variable, a mechanical shaker was employed. In order to know the exact time of contact between the slag and water, it was found necessary to filter the extract at the end of the shaking period. Using the mechanical shaker and a filtering apparatus, similar runs were made on the five fractions for contact times of 5, 10, 20, and 40 min. Random checks gave reproducible results within 0.02 pH. The data are plotted in Fig 1. It can be seen from the plot that each slag fraction is hydrolyzed to an extent that is roughly proportional to the surface area exposed to the water. The (—100 to +200) mesh material changed very little in pH after 10 min. shaking time. The curves are symmetrical and lie in proper relation to one another. The —200 mesh curve appears to be somewhat flatter than the others, but this can be attributed to the portion of very fine material that is not present in the other fractions. The closeness of the (-100 to +200) mesh curve to the —200 mesh curve and the fact that a —100 mesh sample would contain amounts of slag down to 1 or 2 microns in diam were considered sufficient reasons for selecting a —100 mesh sample as representative of the whole sample of slag for the purposes of this investigation.

Jan 1, 1950

By Harold M. Mooney

The most significant trends appear to be an increased use of electromagnetic and geochemical methods. The most promising instrumental developments are airborne electromagnetic equipment, a magnetometer based on nuclear resonance, and reflection seismic equipment operable to depths less than 100 ft. Work in progress may lead to a one-man magnetometer capable of high precision and continuous recording.

Jan 3, 1955

NEW MEMBERS The following list comprises the names of those persons who became members during the period of July 10, 1917, to Aug. 10, 1917. ARNOT, STANLEY L., Engr., Plymouth Cons. Gold Mines; Ltd., Plymouth, Amador Co .2 Cal. BARRETT, LESLIE PARK, Asst. Geol.... Michigan Geological Survey, Lansing, Mich. BENNIE, JOHN WILLIS Gen&apos;l. Mgr., Shannon Copper Co., Clifton, Ariz. BRINTON, OWEN FUGATE Mgr., Admiralty Zinc Co., Quapaw, Okla. BRODERMANN, JORGE, Civil Engr., Compania Minera San Francisco, Havana,Cuba. BROWN, RICHARD HENRY JR., Sales Engr., Ingersoll Rand Co., 300 N. Broadway, St. Louis, Mo. BROWN, STANLEY Chile Exploration Co., Chuquicamata, Chile. BUDDECKE, WILLIAM A Pres., Point Milling & Mfg., Co. Mineral Point, Mo. BURGESS, GEORGE K., Physicist and Chief, Division of Metallurgy, Bureau of Standards, Washington, D. C.

Jan 9, 1917

By T. E. Scott, O. G. Koepke

DURING research currently in progress the need arose for interplanar angles and planar spacings to analyze crystallographic data obtained from hcp yttrium. In the absence of such existing information, a program was written in Fortran-11 language and processed on an IBM 7074 computer. The program and results have been assembled in report form to make them generally available.&apos; Of the possible combinations of, only those most frequently encountered were employed. The ranges of h, k, and 1 involved were: However, not all combinations and permutations of the above appear in the tabulation because redundancies occur in several cases. Nevertheless, fifteen types of planes and all their equivalent planes have been included, giving a total of 109 sets of Miller-Bravais indices.

Jan 1, 1967

By Otto W. Nuttli

The magnetic method of prospecting is well suited to determination of faulting in the basement rock. In addition to establishing the horizontal position of the fault, it often furnishes valuable information concerning the depth and amount of faulting. Consider a simple case of a vertical fault, represented in cross-section in Fig. 1. Let AA&apos; represent the plane of observation (ordinarily the surface of the earth), and BB&apos;B"B"&apos; the upper surface of the basement. Assume that the sedimentary rocks are nonmagnetic, so that the magnetic susceptibility of the material above the basement is zero. Let k indicate the susceptibility of the basement rock, a- the density contrast between it and the neighboring sedimentary rocks, and t the amount of vertical displacement.

Jun 1, 1955

Electrowinning U.S. 4,066,520 - Recovery of copper from copper sulfide ore. Finely divided ore concentrate is leached with moderately strong sulfurous acid to solubilize copper ions, the leach solution treated with calcium sulfite to reduce the copper ion concentration by forming copper-precipitate solids therein, the solids filtered off, and and the filter cake dewatered to obtain a slurry of copper-precipitate solids amenable to direct electrowinning of copper therefrom using a described electrolysis apparatus which utilizes high current flow with a minimum of mechanical agitation. R. C. Emmett, Jr., J. K. Dicksa. B. C. Wojcik and F. A. Baczek, assigned to Envirotech Corp. Jan. 3, 1978. 14 pp. (204- 108). Filed: 9- 1-76 (7 19,867).

Jan 1, 1979

By E. C. Harder

HERBERT K. SCOTT, London, England (communication to the Secretary*).-I am acquainted with the manganese-ore deposits of Russia, India and Brazil, and agree generally with the statements contained in the paper regarding those deposits. The information given by Mr. Harder regarding the Chilean deposits is very welcome. When examining the Caucasian deposits, I endeavored to determine the quantity of ore originally contained in the deposit, and by deduction, the amount remaining for extraction. These calculations were rendered possible by the great extent of the outcrop and the extensive work that had been carried on in the deposit. In making the first estimate, the quantity of manganese ore and associated sterile material in the bed was measured in a large number of

Jan 12, 1916