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By Frank van der Meer, Lea Quincke

"High Pressure Grinding is applied to achieve size reduction of the particles by inter-particle breakage and to generate micro-cracks in the product particles as a contributing factor in e.g. leaching or mineral liberation. As alternative to classification, a closed circuit operation for HPGR can be established by product recycling, where a proportion of the coarser edge material and parts of the center material are split-off to be recirculated to achieve a finer final (center) discharge product for subsequent processing steps as ball mill grinding or beneficiation. As a result of the product recycling, the content of fines in the feed material increases and may affect the grinding efficiency in terms of production of fines and the generation of micro-cracks in the particles. In the scope of this paper, the effects of the proportion of fines in HPGR feed on grinding efficiency and micro-crack generation were evaluated. Grinding tests were executed with different feed size distributions, from a fines-void situation (truncated feed) to a fines-abundant situation (high product recycle). The evaluation of grinding efficiency and generation of micro-cracks was done by particle size analysis, Bond Work Index tests, impact tests on HPGR feed and products, and X-ray computed tomography of single product particles. This publication summarizes the main aspects of the outcome of these investigations."

Jan 1, 2014

By Shuji Owada, Yang Geng, Natsuko Kuroki

Micro-bubble flotation is considered to be an ideal method for the separation of fine or ultra-fine particles, which are difficult to be separated with conventional flotation and other solid separation technologies. Micro-bubble flotation can increase the probability of bubble-particle collision more than conventional milli-bubble flotation. However, there are also some problems. For example, it is known that the rising velocity of micro-bubble is quite low; therefore, the flotation rate reduces. And also, the bubble-particle adhesion probability becomes lower than that of milli-bubble flotation, which is proved in our prior research. In this paper, we applied ultrasonic irradiation to the micro-bubble flotation system in order to solve the above problems and focused on the bubble-bubble and bubble-particle interactions. For clarifying the behavior of bubble-bubble interaction, bubbles behavior was recorded by high-speed camera under irradiation of various ultrasonic frequencies. As a result, in the case of bubble-bubble interaction, it is proved that bubbles are highly coalesced by ultrasonic irradiation especially in the lower frequency and it can enhance more precise separation. In the case of bubble-particle behavior, it is found that the floatability become higher with the ultrasonic irradiation of higher frequency, and it is indicated that ultrasonic irradiation might improve the bubble-particle adhesion probability. Additionally, it is also found that the apparent CMC of the micro-bubble flotation under the ultrasonic field become much lower with higher frequency than with lower frequency, and it is suggested that the dramatic improvement of hydrophobization is achieved.

Jan 1, 2014

By Gabriel C. Aguilera, Juan Arismendy

"The effect of rheological factors inside of a hydrocyclone is very relevant for the fluid mechanics and for the classification of materials on suspension, since parameters such viscosity and thixotropy are intrinsic variables that depend of the particulate system and the continuous phase; they determine the efficiency of classification. Nevertheless, the exact knowledge of the main characteristics and magnitudes of them inside the hydrocyclone is very difficult because of the geometry of the hydrocyclone, even more if the hydrocyclone is of small diameter. Hence is not possible to make a hydrodynamic study with effects over classification regarding these variables. This work studies the rheological variables inside a small diameter hydrocyclone that works at high pressures, using the information given by a model of Computational Fluid Dynamics (CFD). The model used includes the Reynolds Stress Model (RSM) for the evaluation of turbulence, and the Volume of Fluid (VOF) to study the interaction between water and air, which is very important to obtain regarding the effect of the air core over the performance of the equipment. The validation of the CFD model was done with a kaolin suspension at several conditions of solids contents below the critical volume fraction, without chemical additive aid. These conditions are representative of current work parameters on plant. As result it could be established the ranges of evaluation of rheological variables on specific regions inside the hydrocyclone, and through a rheometric study, based on the mechanic characteristics previously obtained, the main rheological characteristics of the mineral suspensions were determined."

Jan 1, 2014

By S. K. Pan, M. P. Srivastava, N. Prasad

"Dalli mines of Bhilai Steel Plant, India is fully mechanized iron ore mine having wet processing system. It has a capacity to treat 5 Mt of ROM. In processing circuit of Dalli mines, scrubbing, wet screening and classification operation is being carried out. Average slime generation for the last five years is about 14% of ROM. As the mining has reached to the lower benches, fines generation is more. As a result, very fine and heavy particles, which settle fast, are being discarded with the slime to tailing pond. These heavy and faster settling particles were causing jamming in the thickeners.Laboratory investigations were carried out at Research and Development Centre for Iron and Steel (RDCIS) to suggest a suitable scheme to recover high quality fines so that the availability of thickener can improve. The slime samples were first treated in a floatex density separator. The concentrate obtained from the floatex density separator was treated in hydrocyclone. Laboratory investigations indicated that the slime with 49% Fe, 12.7% silica and 10.7% alumina can be upgraded to 62.1% Fe, 3.3% silica and 2% alumina with 36% material recovery. Based on the laboratory studies ,a system was installed at Dalli minesThe general arrangement of the system is shown in Fig. below."

Jan 1, 2003

By Christopher Greet, Alfred Van den Bosch

"A range of media alloys with different chromium content has been developed for different milling applications. When selecting the grinding media alloy for a specific application, consideration must be given to the mineralogy of the ore as well as the water chemistry and mill operating conditions. The paper describes the influence of the microstructure of the alloy on the wear resistance and the influence of the chrome content on the pulp chemistry and downstream processing. It also provides information about the in-house tools which Magotteaux have developed to predict the media wear rate with different chromium content alloys and predict their flotation efficiencies that can be expected when the right alloy is selected for a particular application."

Jan 1, 2014

By William Skinner, Ishmael Quaicoe, Jonas Addai-Mensah, Ataollah Nosrati

To date, intractable ore specific operational challenges such as poor heap geotechnical stability, permeability and high acid consumption rates associated with low grade (~1 wt%) nickel (Ni) laterites still makes the adoption of heap leaching processing unattractive. This paper presents some highlights of drum agglomeration, column leaching and characterization studies undertaken to foster the understanding and knowledge of some of the desirable product attributes of -2 mm and -15 mm, low grade saprolitic (SAP) and goethitic (G) Ni laterite feed ores and their blends (SAP/G). For column leaching, 5-40 mm agglomerate beds were continuously irrigated with 200 g/dm3 H2SO4 solution at 8.5 dm3/m2/h rate over 100 days. Ni, Co, Fe, Al and Mn extraction rates, free acid concentration, agglomerate bed slump and structural changes were determined as a function of time. The results show that at equivalent feed masses, except -15 mm G which displayed slower, pseudo-layering based behaviour, all the feeds (single and blends) displayed coalescence controlled agglomeration behaviour at varying binder dosages. Whilst the agglomerate compressive strength of the G ore was markedly higher than that of SAP ore, those of the blends were substantially similar. At fixed column leaching conditions, the Ni/Co extractions and acid consumption were higher for SAP ore whilst the agglomerate bed slump was lower than those for G ore. The bed of agglomerates produced from -2 mm G/-15 mm SAP blend was more stable than that for the -2 mm G/-2 mm SAP blend agglomerate, the latter experiencing blockage within 24 h of acid irrigation due to agglomerates breakdown. The Ni/Co extractions and acid consumption rates obtained for agglomerates of -15 mm G/-2 mm SAP blend were lower than expected based on the ratios of the SAP and G ores within the blend composition. The findings suggest that judicious saprolitic and limonitic ores’ blending could reduce acid consumption rate, improve the agglomerate bed robustness and enhance bed percolation behaviour under prolonged acid irrigation periods during heap leaching of lateritic ores of variable mineralogy.

Jan 1, 2014

By Sergey Gudkov, Yuri Yemelianov, Stanislav Balikov, Andrey Boldyrev, Andrey Bogorodsky

"The results of POX of refractory gold-bearing concentrates using halide-ion as a lixiviant for precious metals and activated carbon as an adsorbent are given. It was found that gold did not recover to the solution when halide was added during POX. Silver partially dissolved in the solution. When halide-based reagents and activated carbon were added during POX, gold dissolved and loaded onto the activated carbon. The degree of sulfides oxidation was 99.3-99.6%. The recovery of gold onto granulated carbon was 94.7-94.8% when using chlorine-bearing lixiviants: NaCL, CaCL and carnalite and 98-99% when using KJ and KBr. This treatment process of refractory gold-bearing concentrates combines sulfide oxidation, dissolution and adsorption of precious metals. The results of the metals recovery achieved using this process can be compared with the recovery during POX-cyanidation. In this case, sodium cyanide was not used. This allows the reduction of capital and operational costs due to the absence of cyanidation, CIL and detoxification of leaching tailings circuits."

Jan 1, 2014

By Kobus (J. J. ) Rossouw, P. Chris Pistorius, Johannes Sono

"Different coal properties are important in SL/RN (coal-based rotary kiln) direct reduction of iron ore, and in electrical smelting of prereduced iron ore. Laboratory simulation was used to evaluate two candidate coals, which were similar in volatile content and rank, but differed in reactive maceral content. The tests served to evaluate both the reduction rate (during direct reduction) and the dissolution rate of carbon from the coal into an iron bath.Reduction rates of mixtures of magnetite and devolatilised coal were assessed isothermally, using samples of 55 grams. The off-gas analysis was used to follow the extent of reduction. Results are shown in Figure 1 a). Coal B was expected to be more reactive, based on its higher content of reactive macerals (77%, compared with 61% for Coal A). In line with this, Figure 1 a) does show a higher reduction rate with this coal. However, increasing the reduction temperature increases the reduction rate substantially,especially for the less-reactive Coal A.For the dissolution experiments, samples (mass: 250 g) were melted in an alumina crucible (under a nitrogen atmosphere), to give a starting composition around 1%C. When the desired temperature was reached, 25 g of char was added on top of the melt, through a feeding port. Results are shown in Figure 1 b). The more-reactive Coal B was less crystalline (the graphite crystallite size estimated from X-ray diffraction was 4.6Å, compared with 11.4Å for Coal A). This is associated with a lower dissolution rate in iron."

Jan 1, 2003

By P. Banerjee, P. Dash, S. Sriramoju, A. Suresh, R. Lingam, T. Ray

"One single property that influences the quality and market value of coal to the maximum extent is the ash content. The lower the coal ash higher is the energy utilization and potential for different applications. Even though Indian coal washeries aspire to produce coal with low ash, the intimate distribution pattern of ash bearing minerals in the coal matrix becomes the real bottleneck, as it brings down the clean coal yield to the impractical value. Because of this fact, most of the Indian washeries are operated to produce coal with 14-15% ash content at the yield of around 40%. In this context, with an objective to produce low ash coal at higher yield, a novel chemical beneficiation route has been explored to demineralize the high ash containing Indian coals. In this present work, the production of low ash clean coal from high ash Indian coals using chemical leaching process has been studied at pilot plant level. The leaching process parameters such as reaction temperature, reagent concentration, reaction time, coal-liquid ratio and agitator speed have been optimized for the flotation tailings sample from a captive washery of Tata Steel. The results obtained show that 67% demineralization could be achieved in a single stage of leaching process with a product yield of more than 65%. For further demineralization, multistage leaching was carried out and the results showed that 75-85% demineralization could be achieved with significant reduction in alumina to silica ratio. Additionally, the phosphorus content is also significantly reduced from 0.20 % to 0.022 %. Further, it is interesting to note that there is no increment of sodium content in the product coal after chemical treatment."

Jan 1, 2014

By Fedotov Pavel

"Today the main objective of improving the process of ore dressing is to reduce energy consumption and performance of the basic rule of auxiliary enrichment processes. One of the modern means of ore destruction with a minimum of energy consumption is the interparticle fracturing, for example in the roller press. There still remain the unsolved problems of the energy consumption determination and the particle size distribution of the crushing product .Existing methods for determining these parameters are empirical and require considerable expenses and time. The improved finite element was developed to solve these problems using finite element contact interaction of the rock. Also it was developed to clarify the stress-strain and the rock fracture energy in a layer. These elements are used to study ore destruction in the layer and allows to create a model taking into account the interaction of crushing particles surfaces. The same algorithm was developed determining crushing product particle size distribution in the layer on the base of the Bond’s theory of crushing. The presented finite element model allows to determine the quantity of strain energy and particle size distribution of crushed product during the destruction processes of the material in the roller press with fair accuracy."

Jan 1, 2014

By D. Szyszka

During passing gas bubbles through mineral suspensions, some mechanical carryover of fine particles to the froth layer always takes place. The entrainment of mineral particles is influenced by many parameters, mostly by the particle size and the concentration of the frother. The paper deals with influence of selected frothers (methylisobutylcarbinol (MIBC), a-terpineol, and hexadecane tricosaethyleneglycol ether (C16E23)), common laboratory flotation frothers, on the mechanical car-ryover of quartz, a typical gangue mineral component of ores. Entrainment tests were carried out in a laboratory Mechanobr flotation machine with quartz particles suspended in aqueous frother solu-tions. The mechanical recovery of quartz in the presence frother was increasing with time and reached plateau after about 20 minutes of flotation. The plateau level of quartz recovery depended on the frother concentration. Initially an increase of the plateau with frother concentration was observed until the plateau reached the highest level called the maximum recovery emax. The emax can be used as a parameter to characterize the ability of frothers to entrainment. In the studied quartz-frother flotation system the maximum entrainment was 32%, 50% and 80% for methylisobu-tylcarbinol (MIBC), a-terpineol, and monohexadecane tricosaethylene glycol ether (C16E23), re-spectively. A comparison of the maximum entrainment factor emax with other, known from literature, indices such as bubble critical coalescence concentration (CCC), dynamic foamability index (DFI), Jw, e =25%revealed, except DFI, their similarity.

Jan 1, 2014

By Venkataramana Runkana, Shantanu Maheshwari

As the world reserves of high quality ores are getting depleted at a rate higher than ever, the liberation of valuable minerals from low grade ores is becoming more and more relevant and imperative. But, liberation of minerals from low grade ores requires grinding of ore to extremely fine sizes. High energy milling in a planetary ball mill is one such option where one can produce particles in the nano-meter range. Although planetary mill is employed extensively for ultrafine grinding, dynamics of grinding inside the mill is not fully understood because of the dependency of grinding kinetics on many interconnected phenomena like collisions between media, particles and wall, time dependent rheology, adsorption and desorption of dispersant, abrasion of media, agglomeration of particles, etc. It was well articulated in literature that media motion and number of media collisions have strong effect on grinding kinetics and final product size distribution. Simulations were carried out using the discrete element method (DEM) to compare the performance of a planetary mill with a ball mill, with and without lifters, in terms of impact energy and number of collisions and it was found that number of collisions is considerably high in the planetary mill. The high number of collisions might be the reason for production of ultrafine particles in the planetary mill. We have also fitted a population balance model (PBM) to experimental data from a laboratory scale planetary mill for prediction of particle size distribution. Unlike previous models, we have incorporated functional forms for the selection function and the breakage distribution function so that the number of parameters in the PBM is just five. The predicted product particle size distributions at different grinding times are in reasonably good agreement with experimental data.

Jan 1, 2014

By Majid Saghaeian, Rasool Hejazi, Parisa Ghobadi

"Pulp handling in mineral processing circuits is very complicated due to its inherent different specifications compared with other fluids such as water. Because any variation in ore property (e.g. size and abrasion index) and pulp specification (e.g. density, solid content and pressure) causes problem in this part and reduces the plant availability and throughput as a result. The most common issues in the hose system are sumps and pipe-line blockage, wearing of the pumps impeller and liner, and pipe tearing specially at elbows and bends. High pressure grinding roll (HPGR) is employed in a closed circuit with a screen as the first stage of grinding in Zarand Iranian Steel Complex (ZISCO). Wearing of the pump and pipeline transferring the screen undersize stream was the main problem from the plant commissioning. The plant couldn't achieve to the design capacity because of this defect. Although various practical solutions such as improving the pipes and impeller material quality and eliminating the elbows, as much as possible, were done in order to downtime minimizing, but damages didn’t vanish. Since HPGR discharge contains somewhat rough and abrasive particles, the mentioned modifications didn't effective very much. Therefore, converting of the wet screen to dry and using of belt conveyor to the screen undersize handling was employed based on the plant capability evaluation and experimental and pilot trial results. Although this reformation imposed another additional cost (for conveyor system), but it had significant advantages such as increasing the plant availability up to 96%, reducing the operating costs of the wear parts, providing more stable operating condition for the HPGR performance and decreasing abrasion rate of the HPGR rolls liner because of the lower moist feed."

Jan 1, 2014

By P. Somasundaran, Tarun Bhambhani, D. R. Nagaraj, P. Patra

"Certain non-sulfide gangue minerals are known to have a detrimental impact on flotation performance. When present in large amounts, they can negatively affect recoveries, grades and throughput at current operations, and dictate the viability and economics of a greenfield project. While the problem has been investigated for a long period of time, a scientific understanding of the mechanisms by which these minerals affect performance has not been obtained, and no acceptable solutions have been developed. This study focused on the role of physical aspects (e.g. shape, size and morphology) of these minerals as the underlying factors for poor performance. Flotation tests were conducted using model mineral systems to understand the impact of one phyllosilicate mineral (muscovite) on flotation kinetics, recoveries and grades. The study reveals that there is minimal impact on flotation kinetics, no impact on recoveries, but a very strong detrimental impact on concentrate grade. The traditional mechanisms of transport such as true flotation and entrainment are not sufficient in describing the extent of transport. The transport is attributed to the unique platy morphology of muscovite, which allows for action of buoyancy forces. Data also shows that the muscovite transport to the froth phase depends on particle size; coarser sized muscovite (100-150@) report to the froth phase in much larger amounts than medium sized muscovite (50-100@). At finer size fractions (<50@) the transport is also increased, and this is likely due to entrainment."

Jan 1, 2014

By F. S. Hoseinian, K. Filho, D. Deglon, T. Souza, M. Safari

"This paper investigates the reverse flotation of hematite in three laboratory flotation cells with very different contacting environments. The main objectives are to investigate the recovery of coarse quartz by flotation and fine hematite by entrainment. The laboratory flotation cells used were the mechanical, oscillating grid and pneumatic cells. The effect of froth height and solid concentration were investigated in the mechanical and pneumatic cells. The effect of impeller speed and energy input were investigated in the mechanical and oscillating grid cells. Froth height results show that coarse quartz particle recovery decreases almost linearly with increasing froth height due to increased detachment of coarse quartz particles in the froth. Fine hematite particle recovery also decreases almost linearly with increasing froth height due to decreased water recovery and associated entrainment. Agitation/energy input results show that coarse quartz particle recovery increases with increasing impeller speed to an optimum, after which this decreases dramatically. The increase is due to improved gas dispersion, generation of smaller bubbles and increased bubble-particle collision and attachment. The decrease is due to significantly increased bubble-particle detachment at higher impeller speeds. The recovery of coarse quartz particles in the OGC is higher than that in the mechanical cell with an optimum at a much lower energy input. Solids concentration results show that both mass recovery and water recovery increase with increasing solid concentrations. The pneumatic cell achieves higher mass recoveries and lower water recoveries than those in the mechanical cell at equivalent solids concentrations and operating conditions. INTRODUCTIONFlotation is a selective process for separating different minerals from each other. The flotation separation efficiency depends on the recoveries of the mineral species by both true flotation and entrainment (Neethling and Cilliers 2009; Wang et al. 2015). Both chemical variables and hydrodynamic conditions within the flotation cell affect the recovery and selectivity of the flotation process. Cationic reverse flotation of hematite is a common method for selective separation of quartz from iron ores to produce pellet feed. The presence of coarse quartz particles in the tailings and fine hematite particles in the concentrate are two major challenges in the reverse flotation of hematite (Vieira and Peres 2007)."

Jan 1, 2018

By Luís Marcelo Tavares, Daniel Francioli, Malcolm Powell, Mohsen Yahyaei

"Mathematical modeling of the comminution process requires understanding of all breakage mechanisms occurring in this mechanical environment. Modeling of high energy impact breakage is well established, however, modeling low energy breakage including incremental damage breakage, attrition and abrasion is still under development. Free fall incremental impact tests were carried out to investigate the surface fragmentation of a copper-gold ore. This process was achieved by dropping particles individually from a height of four meters onto a metallic plate. The impact specific energy was 0.01KWh/t. The setting of the metallic plate was changed to test the impact angles of 0°, 45°, and 60°. Tests were carried out using fresh angular rocks as well as smoothed particles. Changes to the plate angle and particle shape enabled the study of the influence of the tangential component of the impact energy along with particle shape on superficial breakage. By studying the fractional mass loss variation in each impact, two distinct stages of surface fragmentation were clearly determined: high fractional mass loss dominated in the first 10 impacts and was attributed to chipping, whereas low fractional mass loss occurred for the remainder of the impacts and was attributed to abrasion. Smoothed particles demonstrated higher resistantance to breakage and their surface fragmentation behavior indicated a closer relationship to abrasion, especially when lower impact angles were used."

Jan 1, 2014

By Francisco Vicuña, Miguel Becerra, Nelson Iglesias

"The following article presents the development of a dynamic tool for the estimation of Jb/Jc rate (ball filling level / total load filling level) of a SAG mil operating in a single stage mode. Using the methodology detailed in this article, it is now possible to have a dynamic estimation tool in the operation, which enables strategic decision making and achieving a continuous development in process optimization. The estimating of the load filling level (Jc) was conducted using a power model, which in this case corresponds to the C-Model developed by (Morrell, 1993) that was calibrated by measuring the load filling levels (Jc) and balls (Jb) using the FARO laser scanning technology by means of Grind-Out and Crash-Stop procedures during the year 2013 and 2014. Finally, to estimate the dynamic filling level of full charge, Jc, three independent models were developed that allowed to feed the adjusted power model: •,SAG mill discharge grate slot wear model •,SAG mill internal volume wear model •,Ball filling level estimation model."

Jan 1, 2014

By Sebastian Fredes, Williams Calderon, Mauricio Toledo, Gonzalo Montes-Atenas

The influence of the temperature on leaching kinetics of copper-bearing minerals has been widely acknowledged: the leaching of copper oxide ores is generally described as exothermic reactions while copper sulfide ores are associated with endothermic reactions. Reports studying the influence of temperature on leaching kinetics at laboratory scale frequently involve the implementation of either fully flooded isothermal systems or jacketed column setups. Nevertheless, at industrial scale controlling or monitoring the temperature or temperature changes is almost impractical. In fact, leaching process is usually a large tonnage operation and changing the temperature of vast amounts of material would require an enormous amount of energy and highly specific heat transfer equipment. Preliminary computations on the amount of energy required to increase the temperature of a heap or dump in 1°C indicates that it would be impossible to find an energy source able to accomplish the task. In order to provide a solution to this matter it is suggested to create an energy managing protocol (EMP) that permits heat up or down the porous body locally taking advantage from the temperature gradients and from the reactivity of different regions within the material as a function of the leaching cycles. The aim of this study is to evaluate different heat transfer regimes in a 1 ton pilot column leach operation. It was found that best results of copper recovery are obtained when heating up the column in horizontal bands starting from the top of the column moving downwards as the leach cycle evolves. The system is expected to be suitable for industrial applications, but further development of the technique is required, particularly in the design of the heat transfer dispositive.

Jan 1, 2014

By Julian Dimitrov, Kremena Dedelyanova

"The paper presents research on hydrodynamic processes occurring at the elementary act of flotation. Discussed existing models to determine the effectiveness of conflict of bubbles with particles in vibration column flotation machine. The paper presents a disperser for a column flotation machine, in which the dispersion of the gas phase is carried out using vertical vibration with defined frequency and amplitude. The paper presents research of mechanism for the creation of air bubbles in vibratory column flotation machine. The factors influencing the increase in the duration of the bubble in the area of contact with the mineral particles are discussed. Research was carried out on the effect of frequency and amplitude of vibrations on speed of precipitation of mineral grains of different density. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in vibratory column flotation machine is determined. The vibrations of the hydrated layer allow for cost-effective implementation of the elementary act of flotation by providing larger relative velocities at the contact point between the bubble and the solid phase. It is proposed to complement the model more accurate representation the mechanism of attachment of the particles to the bubble."

Jan 1, 2014

By Stuart Simpson

The biggest environmental challenge in mining is the management of mine tailings. Deep----sea tailings placement (DTSP) is practiced where the environmental impacts are predicted to be less than the impacts of tailings storage facilities on land. However, DSTP is often highly controversial owing to the challenges in assessing the impacts in deep water environments and potential long----term impacts beyond the proposed tailings footprint. It is well recognized that total contaminant concentrations are often poor predictors of the risk posed by contaminants in sediments. Metals within tailings are mostly present in highly mineralised forms that are typically much less bioavailable to organisms when compared to other common anthropogenic metals. Thus while metal concentrations in tailings can often appear alarmingly high, when compared to sediment quality guidelines (SQGs) used for assessing common urban and industrial impacts, the bioavailability is typically low. Although now well----embedded within risk----based sediment quality assessment frameworks, contaminant bioavailability is still often overlooked in the management of contaminated sediments. In this presentation, we assess and demonstrate the low bioavailability and chronic ecotoxicology of mineral----rich tailings to two benthic invertebrates, recognized for their sensitivity to metals: impairment of reproduction of the amphipod, Melita plumulosa, and the harpacticoid copepod, Nitocra spinipes. We demonstrate that the metal exposure from mine tailings is low when total concentrations are considered, and that the dose to the organism and toxic response observed is highly dependent on contaminant bioavailability. We discuss a range of approaches for the effective incorporation of metal bioavailability when applying SQGs or setting site-specific management limits for mine tailings in marine environments. While proposed DSTP operations require a high level of environmental scrutiny and monitoring during operation and post-closure, environmentally sustainable operations may be achieved when the bioavailable forms of metals within tailings remain below suitable management limits.

Jan 1, 2014