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By Jinjing Dua, Jun Zhua, Kuiren Liub, Bin Wang, Xiaolei Wua

V-Ti-Fe as hydrogen storage alloy was prepared by reducing metal oxides with a metallothermic reduction method. The deoxidation process of the V-Ti-Fe alloy was performed by electro-deoxidation and vacuum induction melting method, respectively. The results showed that the content of oxygen impurity can be controlled at about 0.2wt% after electrolyzing for 240min. Both the maximum values of hydrogen absorption capacity and the effective hydrogen desorption capacity are 2.65wt% and 1.01wt%, respectively. The deoxidization effect of vacuum induction melting process is more remarkable, with Ce as the reducing agent. It is found that Ce addition is beneficial for reducing the componential segregation, promoting the hydrogen absorption activation of V-Ti-Fe alloy. When m(Ce)/m(alloy) is up to 5%, the oxygen content has been reduced to 0.05wt% and the maximum hydrogen absorption capacity and the effective hydrogen desorption capacity are up to 3.36wt% and 1.85wt%, respectively.

Jan 1, 2015

By Adolfo Pillihuaman, Alberto Nogueira, Cyro Takano, Marcelo Mourão

The organic household waste has a growing disposal problem, requiring costly disposal systems. It is necessary to find new applications for these materials; one could be the steelmaking raw material production. In this paper is studied the development of self-reducing pellets from the organic waste pyrolysis, where is generated carbon and condensable and non-condensable volatiles. Non-condensable volatiles were burned and condensable volatiles were recovered. The resulting tar was mixed with iron ore, coal powder and flux (CaO), to then be pelletized together. Compression, falls and tumbler tests were conducted to characterize the pellets before and after heat treatment and reduction processes. The reduction curve and their physical and morphological characterization were measured. The results were as was expected, the fluidized coal create sufficient adhesion that pellets earned resistance with an equivalent resistance of common pellets, showing a good feasibility of this process.

Jan 1, 2015

By Qingwei Qin, Ping Xue, Guangqiang Li

Ausmelt furnace slag contains about 0.9% Cu (mass %). With increasing the amount of Ausmelt furnace slag, the recovery of copper from it will produce an enormous economic yield. The recovery of copper by floatation from slow cooled Ausmelt furnace slag was studied in this paper. The phases and composition of the slow cooled slag were analyzed. The factors which affected the copper recovery efficiency such as grinding fineness, pH value of flotation medium, different collectors and floating process were investigated. It was shown that the size distribution of the primary grinding and secondary grinding of middling were 75% for particles less than 0.074mm and 82% for particles less than 0.043mm respectively. The closedcircuit experimental results with butyl xanthate as collector in laboratory showed that the copper grade reached 16.11% and the recovery rate of copper reached 69.90% and the copper grade of tailings was only 0.2%.

Jan 1, 2015

By Xuling Chen, Zhiyun Ji, Min Gan, Tao Jiang, Liang Yin, Xiaohui Fan

Straw char exhibited considerably faster burning speed than coke breeze for its porosity, which significantly degraded sinter quality when it replacing coke breeze as sintering fuel. In this investigation, preforming technology has been employed to densify raw straw. The properties of straw char preformed show that its density was increased, and the structure was also densified, which made the difference of combustibility between the straw char and coke breeze smaller. The proper preforming temperature, residence time and pressure were 200℃, 1min and 120MPa respectively. Sinter pot trials show that the product carbonized from preformed straw made the proper replacement ratio to coke breeze increase from 20% to 40%, and the emission reduction of SOx, NOx in flue gas increase from 11.50%, 14.15% to 37.85%, 23.60% respectively, compared with non-preformed straw char.

Jan 1, 2015

By Yuanbo Zhang, Zhaokun Tang, Mingjun Rao, Guanghui Li

The ballability of hematite ore with addition of a certain amount of pulverized anthracite and the induration features of anthracite–containing hematite pellets were studied. The results indicate that adding a certain proportion of anthracite can improve the quality of green pellets as well as the roasting performance of roasted pellets. The suitable mass dosage of anthracite is 1.0%–1.5%. Under the conditions of roasting temperature 1280 oC–1350 oC and roasting time 15 min–20 min, the compressive strength of roasted pellets is found to be more than 2500 N/P. Compared with hematite pellets in the absence of anthracite, the proper induration temperature is diminished by 20 oC, whereas optimal induration temperature range expands by 50 oC, and induration time is shortened by 5 min–10 min. Adding anthracite is an effective measure to improve the pelletization of hematite.

Jan 1, 2015

By D. I. Davidov, D. A. Shishkin, M. B. Rigmant, E. P. Romanov, N. N. Stepanova, N. V. Kazantseva

The Co-19 at.%Al-6 at.%W alloy was prepared by two methods of casting. We used arc melting under an argon atmosphere with casting into a copper water-cooled casting mold and induction melting furnace with casting into a ceramic Al2O3 mold. According to the X-ray and SEM analyses, phase compositions depend on the cooling rate of the ingot after melting. After arc melting, the cast alloy has a three-phase structure, consisting of  cobalt (FCC), intermetallic phases CoAl (B2) type, and Co3W (DO19) type. After the induction melting, the alloy has a three-phase structure, consisting of  cobalt (FCC), intermetallic phases CoAl (B2) type, and Co7W6 () type. All phases in the investigated ternary alloy at the room temperature are ferromagnetic. Curie temperatures of all obtained phases were defined. It is shown that the magnetic properties of the studied alloy are typical for soft magnetic materials.

Jan 1, 2015

By José Brant, Douglas Torres, Rogério Navarro, Rodrigo Souza, Eduardo Brocchi

The steelmaking process requires the input of ferro-alloys to implement the adjustment of some elements composition in the final product. In the particular case of stainless steel production, the high carbon FeCr alloy stands out as one important precursor. However in the production of this material a certain quantity of fine powder with remarkable chromium and carbon content is also generated, which, in turn, could be processed through alkaline roasting in order to selectively recovery this element in a subsequent aqueous route. In the present work, this process is investigated, using excess of NaOH as oxidizing agent, and H2O2 for precipitating chromium as Cr(OH)3, which is next calcinated to Cr2O3. According to the results, the global achieved recovery has shown to be around 98%, suggesting that the proposed route can be seen as a potential process for chromium oxide production from the mentioned fine powder.

Jan 1, 2015

By Run-boWang, Fan-yi Meng, Jian-Liang Zhang, ZheWang

To elucidate the influence of high Al2O3 content on sinter softening and melting behavior, heating-up reduction test under load was carried out. In addition, microstructure study of sinter bed structure change at a different temperature was also made and the mechanism that the effect of Al2O3 content on sinter softening and melting property was discovered. SEM results showed that the increase of Al2O3 content favored the formation of Al2O3-rich slag phase, such as the eutectic (2CaO·SiO2-2CaO·Al2O3·SiO2-FeO) and gehlenite (2CaO·Al2O3·SiO2), resulting in the decrease of sinter Ts temperature. Further, high Al2O3 content improved the concentration of metallic iron and lowered the dripping temperature due to the decrease of slag liquidus temperature and viscosity. At a fixed basicity, it was indicated that there was a relationship between Al2O3 content and sinter softening-melting property. Based on the results, counter strategies to cope with the adverse effect of high Al2O3 content on the cohesive zone property were also proposed. It could provide guidance for the blast furnace operation of sinter with high Al2O3 content.

Jan 1, 2015

By Grant Wallace, Rod James, Larry Twidwell, Ed Rosenberg, Courtney Young, Sean Dudley, Hsing-Hsin Huang, William Gleason, Jerome Downey

The use of applied chemistry in the production and optimization of leach solutions from Rare Earth Element (REE) ores and concentrates is being investigated. Ore and concentrate samples were characterized using scanning electron microscopy/mineral liberation analysis (SEM/MLA), X-ray diffraction (XRD), and Atomic emission inductively-coupled plasma spectroscopy (ICPAES). Multiple leach tests were performed to analyze the effects of temperature, residence time, and reagent concentration on the leaching of REEs. Analysis of leach solutions was carried out using ICP-AES. Modeling and statistical analysis of extraction behavior was carried out using DesignExpert 9. Modeling data for cerium extraction indicates that extraction is greatly influenced by temperature and reagent concentration, while leaching time plays a much less important role. Experimental design techniques are being utilized to optimize REE recovery. Results, conclusions, and directions for future studies will also be discussed.

Jan 1, 2015

By C. Pichler, A. Ressler, D. Gregurek, A. Spanring

In order to improve the refractory lining life at one of the RHI key customer test procedures were developed within a two years collaboration project. In the first year of cooperation detailed refractory corrosion work in the rotary kiln with Ca-ferritic slag was performed. The main results of the second year of cooperation, reported in this article, involve a detailed testing work with nickel matte and pre-selected refractory brands which was performed in TBRC. A first part of this work was a complete chemical and mineralogical characterization as well as FactSage calculations carried out on provided matte samples. According to these results testing in the TBRC was realized at different process temperatures with several magnesia-chromite bricks. Based on the mineralogical investigation a high chemothermal load caused by sulfidic matte resulted in a deep reaching infiltration of the brick microstructure and partly corrosion of main brick components.

Jan 1, 2015

By Xun Hu, Jian Pan, Hongbin Yu, Deqing Zhu, Yanhong Luo

Lump ores are one kind of important burdens for blast furnace (BF), their metallurgical properties have significant influence on BF performance. In this paper, the relationships between the mineralogy of five natural lump ores and the metallurgical performance have been studied. The mineralogy study includes mineral compositions, microstructure and porosity, and the metallurgical performance covers reducibility index (RI), low-temperature reduction degradation index (RDI) and decrepitation index (DI). The results show that the complex lump containing hematite, and goethite has better overall metallurgical performance. For single lump, the RI of goetihte ores is higher, the RDI and the DI is strongly influenced by porosity. The hematite and magnetite ores have good anti-decrepitation and anti-RDI, but generally the RI is lower due to lower porosity, and the RI is related to the grain size, the smaller grain size is, the better reduction will be.

Jan 1, 2015

By Jing Zhan, Gui Li, Wei-feng Li, Li-Hua Jiang, Chuan-fu Zhang, Jian-yang Hwang

Thermodynamics analysis for processing the charge with lead concentrate and lead sulfate-containing materials in bottom blowing smelting furnace was conducted. The results show that the technology of large-scale processing PbSO4- containing materials with PbS concentrate in bottom blowing furnace under the condition of using high-iron slag type, batch heat supplement, high temperature and rich oxygen is thermodynamically feasible. The exploration test and industrial experiment confirm the results. When S content in mixed ore is 16~17% with coke foam content of about 5%, the lead paste amount can be increased up to 40%.

Jan 1, 2015

By Ayşe Ece Yıldızçelik, Mehmet Buğdaycı, Onuralp Yücel

ZrB2 and TiB2 are significant metal borides. They are being used in various industrial areas from space technology to nuclear industry owing to their physical properties such as high melting point, high thermal/electrical conductivity and low density. Present study was conducted in two main stages: self-propagating high-temperature synthesis (SHS) reactions and leaching. ZrO2, TiO2, B2O3 were used as starting material and Mg was used as a reductant to produce ZrB2-TiB2 powders via SHS. Therefore, it was aimed to determine production parameters, leaching conditions and comprehensive examination of final product features. The samples were characterized by using chemical analysis (AAS), XRD, XRF and SEM/EDS techniques.

Jan 1, 2015

By G. Plenge, M. Brittan

"Plant design parameters for gold extraction, leach residence time and cyanide consumption are generally determined from standard bench-scale bottle roll or agitation leach tests. The application of laboratory data to process design has essentially evolved from the testing of oxide or low cyanide-consuming ores. Such scale-up factors may not be appropriate for ores that deplete cyanide and oxygen since this interferes with gold extraction kinetics. High cyanide-consuming ores also exacerbate the differences between the conditions applicable to small batch tests and large continuous operations. Testing a reactive high-sulfide South American ore deposit necessitated the re-evaluation of conventional bench-scale cyanidation procedures. Pulp density can be a major factor affecting the results for plant design purposes and should be treated as a test work variable. As with high clay-bearing ore, where pulp viscosity can hinder mass transfer, minimizing the influence of test equipment on gold extraction kinetics may require low pulp densities. This introduces interpretative complexity since cyanide consumption changes as a function of pulp density. Activated carbon also consumes cyanide, so its effect has to be accounted for in the case of carbon-in-leach (CIL) or carbon-in-pulp (CIP) plant flowsheets. Since cyanide is an expensive reagent, often a major component of plant operating costs, it is important that the scale-up of cyanide consumption from laboratory to plant be representative. The traditional method of reporting cyanide consumption in bench-scale testing is questioned since it takes credit for residual free cyanide in leach tails. The projected plant consumption may be better estimated by using the total cyanide addition in a laboratory test. We propose a test work protocol that categorizes the cyanide consumption into its components but requires more extensive testing to generate design data. The ultimate validation of scale-up factors used by project engineers requires rigorous bench-scale versus commercial plant comparative data. Such data are not readily available.IntroductionMajor factors in the design of a gold processing plant are gold recovery, leach residence time and cyanide consumption. These parameters are important determinants of project revenue and costs and, thereby, potentially of project financial viability. Estimates of the associated design criteria for a commercial plant are normally generated from laboratory cyanidation, carbon-in-leach (CIL) or carbon-in-pulp (CIP) tests using standard procedures (Angove, 2005). The key question is whether the standard laboratory test work procedures developed historically for low reagent consuming ores are appropriate for ores that are highcyanide and oxygen consumers.The present paper examines test procedural factors that can influence the test work results and, therefore, their interpretation for design scale-up purposes. The study refers in particular to a high cyanide-consuming sulfide ore. The ore was being tested to develop scoping level engineering design criteria for a proposed project in South America."

Jan 1, 2015

By L. Magne, M. Maldonado, R. Varela

Real-time optimization of flotation circuits demands for accurate and reliable measurements to support the decision making process. The collection zone gas holdup is an important variable in this context as integrates the effect of machine and chemical factors on the bubble size and velocity distributions. It has been demonstrated that gas holdup not only correlates with bubble surface area flux, which defines the particle collection rate and recovery in the collection zone, but also with water overflow, a variable which has been related to the froth zone recovery. Therefore, on-line gas holdup measurements provide a reliable alternative to judge efforts leading to the optimization of flotation cells and columns. Estimation of gas holdup in flotation from electrical conductivity measurements has been proposed and extensively used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the conductivity of the liquid medium and of the mineral pulp with and without air bubbles included. These measurements require a conductivity cell which covers a representative volume of the flotation cell, and creates a homogeneous electric field throughout this volume that ideally is not affected by the conductivity of the medium. The development of such a cell in the limiting space and geometry of a laboratory flotation cell has been problematic, but a multi-electrode arrangement offers a promising alternative. Electrodes were installed in the flotation cell of a Denver unit; the results of preliminary testing are discussed with a focus on its performance in the measurement of two- and three-phase dispersion conductivity.

Jan 1, 2015

By Akshay Sakhuja, M. S. Karthika, R. Vignesh

"The bridge across River Mandovi in Goa is a cable stay bridge structure proposed parallel, along existing bridges for regulation and reduction of vehicular traffic; the entire bridge structure is supported on pile foundation socketed in rock. This paper describes drilling related issue encountered during execution of pile where bed rock varies considerably from factual geotechnical investigation, which in turn affected the productivity of bored piles socketed in rock then chiseling is advocated for rock socketing with limited number of blows based on penetration resistance of rock encountered or equivalent energy principle to increase the productivity and also to avoid excess chiseling which otherwise would have fractured the rock mass below and around the pile tip resulting in increased settlement of pile subjected to design load. Contractor decision on socket length have been taken without compromising either quality or productivity; the paper presents various procedures and the equipment involved for installation of pile in rock along with the conclusion related to termination of pile in rock and also the lessons learned in process.INTRODUCTIONPile foundations are generally used to transfer heavy loads in deeper bearing stratum if the soil immediately beneath the base of the foundation does not have sufficient capacity. The bridge across River Mandovi, Goa is in its construction phase as a part of the development plan of Goa State Infrastructure Development Corporation Ltd (GSIDC). The project was awarded to M/s. L&T Construction, Heavy Civil Infrastructure; subsequently the geotechnical investigation was awarded to M/s L&T Geostructures.The client has specified the foundation of the bridge as rock-socketed. Rock socketing is generally done to achieve higher bearing pressure through concrete-rock shear interface which many building codes permit. The design and construction of rock socketed pile foundation entails a detailed analysis and judgement on the superstructure loads, predominant geological conditions as well as ground water levels. The termination of pile is normally based on thumb rule of half to three times the pile diameter into the rock. Quite often the criteria is based on chisel penetration rate (Gandhi,1990) In fact, this is the key factor to consider appropriate and economical depth of embedment of pile into rock stratum which necessitates enormous understanding on the type and quality of rock strata encountered which may significantly influence the selection of suitable rotary rig for pile installation. Such criteria are site specific and also applicable for the set of equipment used for the particular project."

Jan 1, 2015

By K. Bartholomew

The Functional Performance Equation for ball milling circuits provides plant staff with a new means to improve circuit performance. However, successful execution of a plant processing performance improvement project, with verifiable improvements, requires a significant number of accompanying steps beyond using this equation. In order to identify and articulate all these steps, a study was undertaken with the metallurgical staff from two milling operations and process application specialists from a grinding media manufacturing company. “Task analysis” of improving plant grinding performance was carried out. This analysis identified the required steps, and ultimately yielded a “Plant Grinding Circuit Processing Performance Management/ Improvement System.

Jan 1, 2015

By Filippo Maria Leoni, Wesley Schmutzler

"Deep Mixing Method (DMM) for the Rio Puerto Nuevo Project in San Juan was chosen by the Corps of Engineers to improve the soils adjacent to a 90 inch forced sewer main relocation and to improve the soils for the base of a new drainage channel. The project is located just east of San Juan and south of the Horizon Port. The soils to be improved consisted of fill, marine clay, organics (peat) and the foundation clay layer. A preconstruction soil investigation campaign was performed to assess soil properties and to retrieve samples of the different soil layers for the laboratory Bench Scale Testing program (BST). The BST was conducted using various binder contents and water/cement ratios in each of the soil types; the selection of the different combinations and dosages was based on past extensive experiences on similar materials. Following the laboratory program, a full scale Field Test (FT) was done installing several DMM elements to verify the results of the BST and fine tune the construction parameters. Each element consisted of two 5.5 feet diameter overlapping mixing augers installed simultaneously to a depth of approximately 60 feet using a SOILMEC SR-90 dual axis drilling rig. The FT construction and post-construction coring results showed significant differences between the lab study and the actual field conditions. This paper will highlight these differences and the importance of performing both pre-construction laboratory and field tests in order to ascertain the proper mixing parameters in the different soil layers.IntroductionThe Puerto Nuevo project consists of the stabilization of a major drainage channel using Deep Mixing Method (DMM) and the relocation of a 90 inch forced main sanitary sewer outfall. The first portion of this project was a 40 x 16 x 2,000 foot box culvert installed in 2004. In order for the drainage system to be completed and function properly, the 90 inch forced main needed to be lowered about 20 feet to allow for proper drainage.DMM was chosen by the US Army corps of Engineers to stabilize the drainage channel as well as improve the soil under the relocated sewer main. The overall layout of the project is shown in Figure 1. The DMM is arranged in different zones (A through E) with variable top and bottom design elevations as can be seen in the typical cross section for ZONE A and B as an example. (Figure 2) The total amount of soils to be treated by DMM is approximately 84,000 cubic yards up to a maximum depth of 57 feet from ground surface and an Area Replacement Ratio of 100%.The equipment used to perform the DMM is a Soilmec SR90 twin-shaft jet assisted deep mixing rig (Figure 3) coupled with a LODOS 30 grout plant and two Soilmec 7T-500J high pressure pumps."

Jan 1, 2015

By Seth H. Hamblin, John E. Regan, Dimitrios Palantzas

"Through reliability-based calibration of larger pile load test databases, recent developments of the Load Resistance Factor Design (LRFD) methods, which include geotechnical load and resistance factors for deep foundations design, have advanced the state of practice for geotechnical engineering. These load test databases upon which the current geotechnical load and resistance factors have been developed are limited, however, and do not provide sufficient data to support the development of resistance factors for uplift (tension) pile capacity. As such, some recommended resistance factors for uplift capacity estimation methods are simply derived by reducing the recommended resistance factors for piles in compression by a factor of 0.10.The results of three (3) tension loading tests performed to failure on 508 mm (20- in) square precast, prestressed concrete piles, driven though granular soil in southeastern Massachusetts, are presented and compared to static pile capacity calculations and dynamic analyses performed using the Pile Driving Analyzer (PDA) during installation. These results are presented along with current recommended LRFD resistance factors for driven piles under uplift (tension) loading conditions. These comparisons offer an assessment of the applicability and limitations of current resistance factors methods for piles under uplift loading and may be useful additions to the existing database for future calibrations of LRFD resistance factors for driven prestressed concrete piles in sand.IntroductionIn 2010, two (2) natural draft cooling towers were constructed by Kiewit (Kiewit) Construction Company of Woodcliff Lake, New Jersey at the Brayton Point Power Station in Somerset, Massachusetts. These massive 500 foot tall, 400 foot diameter cooling towers were designed to convert the existing “open loop” system into a “closed loop system” thereby dramatically reducing the thermal impact to Mt. Hope Bay.Based on design guidance from the German VBG Design Code and the Massachusetts State Building Code (MSBC), tension (i.e. uplift) and lateral loads due to wind loads and design seismic events represented the critical loading conditions.Weighing approximately 190,000 kips upon completion, the cooling tower loads are transferred to 44 foundation nodes (i.e. pile caps) evenly spaced along ring beams which run the circular perimeter of each tower base. Each pile cap node was designed to resist a 2,000 ton compression load, 200 tons in tension (i.e. uplift), and 600 tons in the lateral direction."

Jan 1, 2015

By Deepak Pappusetty, Miguel A. Pando

This study is motivated from the increased interest in recent years to explore use of Ocean Energy Converters (OEC’s).OEC’s can be tidal or generate electricity from wave or current action. Design of foundation systems for these OEC’s is a key consideration as it can represent about 35% of the initial installation cost. The primary focus of this paper is related to foundation systems involving monopiles where a key design consideration includes gradual accumulation of pile head deformations beyond serviceability limits of the OEC. This design consideration is important since these foundation systems are often subjected to more than 108 low amplitude repetitive dynamic load cycles during a normal 30 year design life. Research on single model piles installed in sand and subjected to over 104 low amplitude lateral load cycles have shown that pile head displacements and rotations tend to increase gradually with increasing load cycles. This gradual development of pile head deformation is related to plastic strain accumulation in the soil in the vicinity of the monopile. Analytical methodologies based on conventional p-y curves typically cannot predict these accumulated pile head rotations and displacements. Even 3D dynamic Finite Element Analyses may not capture this response for several conventionally used soil constitutive models. This manuscript presents predictions using p-y based methods as well as 3D dynamic finite element analyses. The different numerical predictions are compared to available experimental data. Results from this study show that conventional p-y methods do not predict the gradual pile head displacements observed experimentally. Modified p-y curves, developed for cyclic loading, do a better job than conventional p-y curves but tend to greatly under predict deformation. This is believed to be related to the cyclic load test data used to develop these cyclic p-y curves which involved at most up to 500 cycles and did not include high frequency contents or partial unloading cycles. The 3D FEA captured reasonably well the general observed trends of gradual accumulation of pile head rotation and lateral deformation with increasing constant amplitude lateral load cycles.

Jan 1, 2015