Search Documents

By Boyd Davis, Brook Zaback

"Among the first published papers from Prof. Torstein Utigard was work on imaging the aluminum electrolysis process and in-situ measurements of aluminum in cryolite melts. He and Prof. Jim Toguri used an x-ray radiographic technique to measure interfacial tension of aluminum drops. Publications using this equipment for aluminum electrolysis spanned from 1985 to 2006. As well, other methods were used to better understand electrolysis in molten salts, including hot-stage microscopy, direct observations from above the bath and water modeling techniques. For chloride systems (for magnesium and lithium), it is possible to see side-on the electrolysis using a quartz cell. In honour of Prof. Utigard’s contribution to this field, this paper presents a summary of work on visualization of molten salt electrolysis, including work done at the authors’ labs and others around the world. The paper will summarize key findings and their possible impact on molten salt electrolysis."

Jan 1, 2015

By Sakellariou M., Ferentinou M.

Determination of the nonlinear behavior of multivariate dynamic systems often presents a challenging and demanding task. Therefore, complex geomechanics systems are an ideal area for the application of intelligent methods. Often the physical problem is controlled by nonlinear equations, conveying to the use of neural networks. Hudson, (1992a), aiming at efficient engineering modelling and design, introduced and developed Rock Engineering Systems (RES) approach, through the implementation of generic interaction matrix GIM. This approach has been used for a wide variety of rock engineering and other problems, resulting in many case studies available, which illustrate the application of RES to rock engineering problems. Considering the spectrum of the coding methods for the Generic Interaction Matrix, we suggest an objective coding approach. Among the five proposed coding GIM methods, the coding method according to the slope of Pi and Pj relation is relatively accurate, but it might be difficult or impossible to establish or estimate the exact relation of Pi vs Pj for most of the variables involved within a rock engineering system. Self organising maps, are a special type of unsupervised artificial neural networks, which can learn from complex, multidimensional data, and transform them to visually decipherable clusters. The proposed, coding of the GIM, is performed through the combined use of scatter plots produced through, (SOM), and the coding according Pi vs Pj slope. Naghadehi et al., (2013) constructed a database of worldwide experience, in open-pit mine slope stability, the selection of the principal factors was based on Hudson (1992a) who proposed an ‘atlas’ of factors affecting the stability of rock slopes. Slope classification was performed according to status of stability. The rating of the GIM matrix was completed, coupling scatter matrix produced by SOM training, and Pi vs Pj slope plot. Results refer to the identification of clusters, according to status of stability within the original multivariate data set, and the rating of the principal factors according to the dominance and interaction intensity within the open pit mines RES.

Jan 1, 2015

By Kiyotaka Ohno, Nobushige Yasuoka, Yosuke Hioki

"The diameter of improved columns adopted by the original DJM Method had been 1000 mm, however, in order to comply with the social need for construction cost reduction, the Expanded Dry Jet Mixing (EX-DJM) Method with maximum column diameter expanded to 1300 mm was developed between 1998 and 2001 and has been widely applied since then. From the first application of EX-DJM in January 2002 for a first construction project, the total volume of improved soil has reached 325,000 m3 in 17 projects up to September 2014. Because of the advantages of the EX-DJM such as reduction of construction costs and periods leading to reduction in the number of improved columns, adoption of this method is expected to increase in the future. This paper describes the advantages of the EX-DJM, its construction results and case examples including those applied to restoration projects after the Great East Japan Earthquake, 2011.1. BACKGROUND OF DEVELOPMENTThe Dry Jet Mixing (DJM) Method is a soil stabilization method in which a powdery or granular binder is pneumatically fed into and mixed with soft soil to induce chemical reactions that stabilize and strengthen the soil. It was developed by government - private collaboration in Japan between 1977 and 1979. Up to March 2014, the total volume of soil improved by DJM method reached 33,500,000 m3. The initial diameter of improved columns of the original DJM Method was 1000 mm. In order to comply with the social need for construction cost reduction, the Expanded Dry Jet Mixing (EX-DJM) Method with maximum column diameter 1300 mm was developed between 1998 and 2001.2. ADVANTAGES OF EX-DJMThe construction equipment for the EX-DJM consists of two major parts, which are DJM machine and binder plant are shown in Fig. 1.The construction machine is of double mixing-shaft type with its column diameter expanded to 1200mm or 1300mm. In association with the increase in the column diameter, the binder feeder has also increased its discharge rate by approximately 1.69 times. Same as the increase rate of the area of original diameter 1000mm to diameter 1300mm are shown in Fig. 4."

Jan 1, 2015

By N. Depountis, Th. Rondoyanni, N. Sabtakakis, K. Kavoura, G. Tsiambaos

"Some typical landslide phenomena in Western Greece, in terms of the geological composition and structure of the affected materials, induced by heavy rainfalls are thoroughly studied and analyzed. The studied cases involved composite landslides on Flysch and Neogene weak rock materials that constitute the most critical landslide prone geological formations in Greece. The studied cases named Platanos, Platanitis and Karya include representative landslide sites as regards to the geological composition and structure of the displaced formations. Thus: (a) flysch formation includes different lithological units as shales, marls, siltstones, sandstones and conglomerates and is closely related to the Alpine orogenesis, suffering intense past tectonic movements and (b) the Plio-Pleistocene sediments include clayey marls, marlstones and siltstones. The investigated landslides , affecting mainly transportation routes, are closely related to heavy rainfalls induced by extreme meteorological events and are controlled by active fault tectonics. Long term movement monitoring using borehole inclinometers and surface benchmarks showed that landslides control was effective only when the proper stabilization measures were taken.INTRODUCTIONLandslides represent a major threat to human life, property, infrastructure and natural environment in most regions of the world. They are recognized by the scientific and politic authorities as having a major socio-economic impact and they represent a significant hazard for the population and the properties in particular locations. Landslide hazard expressed as the probability of occurrence within a reference time period and is a function of the spatial and temporal probability (Varnes, 1984; Guzzetti et al. 1999; Lee and Jones, 2004). The spatial probability of landslide initiation (susceptibility) is mainly related to static causal factors (slope inclination, material properties, etc.), while temporal probability is mainly related to dynamic causal factors such as rain input, increased groundwater levels and drainage, earthquakes, etc. (Van Westen et al. 2005)."

Jan 1, 2015

By F. P. Hassani, M. Hefni, M. F. Kermani

"This study is part of large and an ongoing investigation into the development of a light-weight and highly fluid mine fill for various applications in mining and civil operations. Foam mine fill is the new material proposed for backfilling mines, and is fabricated by mixing stable foam into a mixture of tailings, binders, and water. This paper investigates the effects of both binder dosage and the amount of foam used upon the mechanical and physical properties of foam fill, mainly in regards to compressive strength, porosity and density.Samples were prepared using tailings from a copper mine as the inert material, Normal Portland Cement as the main binding agent, and a foaming agent with a foam generator. Samples were cured for 7, 14 and 28 days and were then subjected to unconfined compressive strength (UCS) testing. Select samples were subjected to mercury intrusion porosimetry, so as to study the microstructural properties. An empirical model was then developed, using a response surface methodology to establish a relationship between the investigated parameters. INTRODUCTION AND BACKGROUNDThe disposal of mine tailings is a significant issue in the mining industry, particularly as mine production increases. Many mines re-use mine tailings for backfilling, which is a method for reducing environmental exposure to tailings, maintaining underground stability, and increasing ore recovery (Benzaazoua, Belem & Bussière, 2002).This paper introduces a new type of backfill called ‘foam mine fill’. This proposed backfill material is similar to cellular concrete, as air bubbles are entrained in cement or lime mortar, resulting in a cellular structure (Narayanan & Ramamurthy, 2000). Air voids can occupy up to 70% of the volume of concrete, which makes it light- weight, and thus can be used for a wide range of civil applications, including backfilling (Tarasov et al. 2010; Panesar, 2013). Unlike cellular concrete, the incorporation of air bubbles into a mixture of tailings, binder and water makes foam fill a potential new backfilling material. Furthermore, a preliminary investigation on foam fill samples found that pulp densities should be optimized before adding the foam, in order to produce consistent samples without foam segregation or losses (Hefni et al., 2014)."

Jan 1, 2015

By M. A. Halim, V. I. Lakshmanan

Recycling is one of the key elements for sustainable process development for the recovery of value-added products and reducing environmental impact. Process Research ORTECH Inc. has developed several innovative and sustainable technologies, which minimizes the use of water, and chemicals for the recovery of gold, vanadium and gallium from secondary sources by maximizing the recycling of reagents, and reuse of water from process effluents.

Jan 1, 2015

By M. Deutsch, E. González, M. Williams

"Uncertainty exists in ultimate-pit limits due to geologic variation and unpredictable economic landscapes. In this work, we show how this uncertainty affects the ultimate pit and how it can be analyzed to improve the mine planning process. A stochastic framework using geostatistical simulation and parametric analysis was used to model the effects of geologic and economic variations on ultimate-pit limits and overall project economics. This analysis was made possible by a new pit optimization implementation that can be automated and set up to calculate ultimate pits for hundreds of different scenarios in a matter of hours. Quantifying ultimate-pit uncertainty early in the mine planning process allows mining engineers to make informed decisions regarding infrastructure placement and to mitigate the possibility of incurring substantial costs to relocate critical mine facilities. Resumen ¦ Existen dudas sobre los límites del pit final por causa de la variación geológica y lo impredecible de los paisajes económicos. En este trabajo les mostramos como esta incertidumbre afecta el pit final y como puede ser analizada para mejorar el proceso de planificación de la mina. Se usó un marco estocástico con simulación geoestadística de análisis paramétrico con el fin de poder hace la modelación de los efectos de las variaciones geológicas y económicas en los límites de pit finales y proyectos económicos en general. Este análisis fue posible gracias a una nueva implementación de optimización de pits que puede ser automatizada y configurada para calcular pits finales para cientos de escenarios diferentes en cuestión de horas. La cuantificación temprana de la falta de certeza en pits finales durante el proceso de planificación permite a los ingenieros de minas tomar decisiones informadas en lo que respecta a la ubicación de infraestructura y en la mitigación de posibles costos sustanciales por causa de la reubicación de instalaciones clave de la mina."

Jan 1, 2015

By Jamie N. Burdeski, Susan E. Hartfield-Wünsch

Aluminum sheet use has been steadily increasing in the automotive industry to achieve mass reduction and improve fuel economy. One significant manufacturing challenge for aluminum sheet implementation is the reduced formability compared to the steel alloys it replaces. This paper includes friction results from the draw bead simulator (DBS), twist compression (TCT) and strip draw (SDT) tests, for two oil based lubricants and four hot melt lubricants. Formability testing was done with the same lubricants and materials, testing in pure stretch with a hemispherical punch, and in draw with a breadpan shaped die.

Jan 1, 2015

By C. Derek Martin

"Predicting the ground response for tunnels in weak shales remains challenging. Predicting the ground response is challenged by difficulties in characterising the material, and our ability to predict deformations that are driven by coupled hydromechanical processes, when this material yields. The techniques that are used for characterizing weak shales are reviewed, and three case histories are examined that demonstrate the behaviour of these weak rocks during tunnelling. A general framework is provided for assessing the squeezing potential for weak shales.1 INTRODUCTIONGeologically, shale is an argillaceous fine-grained sedimentary rock that forms from the compaction of silt and clay-size mineral particles commonly referred to as ""mud"". Because of this grain size, the material is generically classed as Mudstone (Figure 1). Shale is distinguished from other mudstones because it is made up of many thin layers (laminated) and readily splits into thin pieces along the laminations (fissile). While the geological classification of shale appears straightforward, the classification for engineering purposes is often confusing. Underwood (l967) provided the first description of shale that made the distinction between “soil-like” compaction shales and “rock-like ""cemented"" shales. He coined the term ‘clay shale’ to capture the characteristics of hard clay yet recognizing its origin as a shale. In this paper weak shale is synonymous with clay shale and have strengths that typically range from R1 to R2 (1 to 25 MPa). Characterising these materials draws on methods from both soil and rock mechanics."

Jan 1, 2015

By H. J. McQueen

About 1973 the abrupt decrease in crude oil shipments due to political action by Middle Eastern suppliers, caused a shortage and a steep price rise. In response, Canada had to develop strategies of diminishing consumption and increasing production in both traditional and environmentally friendly resources. To clarify the situation in Canada, there are brief histories of energy (discovery, pipelines), manufacturing and science development, 1800-1970. Energy strategies, both nationally and in Quebec, succeeded in curbing consumption and in expanding production while fostering research in renewable sources. The industry-sector committees provided free exchange of conservation techniques through the federal energy ministry, with progress reports issued annually. Pipeline history in North America is reviewed along with manufacture and construction plans in Canada. Considerable success in all the aspects provided long lasting benefits, but after the embargo was lifted, many research initiatives were gradually abandoned for political reasons. Sustainability is the goal; society must conduct conserver analysis, legislation and action to enhance it.

Jan 1, 2015

By Haibin Ma, Jie Song, Qingyou Han, Xiaoming Wang, Wei Vian

In the grain refinement of aluminum, Al3Ti and TiB2 particles are introduced to reduce the casting grain size down to 200 micrometer level, which makes cold working possible. The particles are brought in by the addition of Al-Ti-B type master alloys. It is generally believed that TiB2 particles are stable and nucleate a-Al grains in solidification in the presence of extra titanium than the stoichiometry of TiB2 from the dissolution of Al3Ti particle in the master alloys. Titanium in solution either form Al3Ti layers on the surface of TiB2 particles or as solute to promote the nucleation and to restrict the growth of a-Al grains. However, a consensus on a grain refinement mechanism is still to be reached due to the lack of direct observation. This paper presents finding on the TiB2/Al3Ti interfaces in an aluminum matrix. It demonstrates a strong epitaxial growth of Al3Ti on the surface of TiB2 particles, a sign of the formation of an Al3Ti layer on the surface of TiB2 particles in grain refinement practice. The Al3Ti layer has a crystal coherency with a-Al and hence offers a substrate for heterogeneous nucleation of a-Al grains.

Jan 1, 2015

By Arístides Sotomayor

El presente texto señala el comportamiento del mercado nacional de cobre en el período 2000- 2013, donde se analiza la evolución de la producción minera metalúrgica a través de la identificación de las tendencias anuales en el mercado peruano.

Jan 1, 2015

By Da-Qiang Cang, Qingde Wang, Wei Wang, Wen-Bin Dai, Min Guo, Yu Li

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.

Jan 1, 2015

By William Gleason

"It is safe to say that the coal industry, in the United States and globally, is currently suffering through one of the hardest times in its history.A perfect storm of competition, changing energy demands, politics and public perceptions have collided, inflicting significant harm to the industry that many say is irreparable. This, in turn, has led to massive job losses in some regions, heavy cuts in production and even bankruptcy filings from two of the largest coal mining companies in the nation.Cheaper natural gas can certainly take a large share of the blame for the struggle of coal, as utility companies switch from coal to natural gas for power generation. According to the U.S. Energy Information Administration (EIA) the amount of coal used for electricity generation in the United States is at a 45-year low.November 2015 marked the fifth consecutive month that natural gas was the leading source of power generation in the United States. EIA said generators produced 101,866 thousand megawatt hours (MWh) of electricity with gas in November versus just 87,789 thousand MWh with coal, the lowest monthly level since May 1980 when monthly coal use was 84,884 thousand MWh.According to Robert Godby, director of the Center for Energy Economics and Public Policy at the University of Wyoming, there are a number of factors playing a role in the decline of coal, but he points to the advances in fracking as the tipping point.“A lot of people will argue that regulation is the cause of the decline, and it has played a part, for sure, but the story of the recent past is more about what competition has done to the energy market,” Godby told Mining Engineering. “The war on coal was originally declared by natural gas in 2008.”The price of natural gas, which was at $13 per million Btu before the gas fracking boom, has fallen to as low as $1.68 in December 2015. Likewise, Godby said the cost of wind generation is now lower than the cost of generation from coal and the cost of solar generation is coming down as well. In addition to that, the demand for energy has changed in the past five years with more efficiencies in everything from building design to lightbulbs."

Jan 1, 2015

By Shantanu Patel, C. Derek Martin

"The objective of this work is to develop a practical numerical approach for applying the confining pressure to discrete element cylindrical triaxial tests. A layer of membrane particles with very low stiffness and extremely high contact bond strength was created around the lateral boundary of the cylindrical numerical specimen. To prevent the membrane particles from penetrating into the rock specimen on application of confining forces and to provide a smooth boundary surface, the space between the membrane and rock particles was filled using small-diameter packing particles. The results of this method were compared with those of rigid boundary method with confining pressure of 20MPa. The results obtained show that new approach gives both peak strength and post peak response that are in closer agreement with laboratory findings. BACKGROUNDThe discrete element method (DEM) has become the cornerstone for simulating both intact material and discrete fractures for low porosity strong rocks (ISRM Classes R3 to R6). Despite the advances in its application, simulating realistic behaviour of intact rock using the DEM remains a challenge. The bonded particle model was introduced as a potential solution for simulating the complex mineral grains in strong rock and other granular materials (Potyondy and Cundall, 2004; Utili and Nova, 2008; Salot et al., 2009). While some issues were resolved, a remaining challenge is the lack of the bonded particle model to simulate the brittle response commonly observed in strong rocks during the triaxial compressive test. Such behaviour is shown in Fig. 1 for Lac du Bonnet Granite at a confining pressure of 20MPa."

Jan 1, 2015

By K. Hanumantha Rao, A. Javadi Nooshabadi

"Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by chalcopyrite (CuFeS2), which is a copper iron sulfide mineral, during grinding, was investigated. It was observed that chalcopyrite generated H2O2 in pulp liquid during wet grinding and also in the solids when placed in water immediately after dry grinding. The generation of H2O2 during either wet or dry grinding was thought to be due to a reaction between chalcopyrite and water where the mineral surface is catalytically active in producing •OH free radicals by breaking down the water molecule. The effect of pH in the grinding medium or in the water in which solids are added immediately after dry grinding showed that the lower the pH value, the higher the H2O2 generation. When chalcopyrite and pyrite are mixed in different proportions, the formation of H2O2 was seen to increase with increasing pyrite fraction in the mixed composition. The results of H2O2 formation in pulp liquid of chalcopyrite and together with pyrite at different experimental conditions have been explained by Eh-pH diagrams of these minerals. This study highlights the necessity of revisiting the electrochemical and/or galvanic interaction mechanisms between the chalcopyrite and pyrite in terms of their flotation behavior.IntroductionHydrogen peroxide causes nonselective oxidation of sulfide minerals if present in pulp liquid. Oxidation of sulfide minerals takes place when they are exposed to atmosphere and during the grinding process when the particle size is reduced for flotation. The oxidation of chalcopyrite leads to iron dissolution from the particle surface and from a metal-deficient, sulfur-rich surface (Fairthorne et al., 1997). Other studies report the formation of iron hydroxide on the surface with the metal ion dislodged on the surface (Buckley and Woods, 1984; Chander, 1991). The chemical reactions for the oxidation of chalcopyrite in alkaline and in acidic solutions with the addition of oxidants, such as oxygen or hydrogen peroxide, are shown in Eqs. (1) and (2), respectively (Shi and Fornasiero, 2010)."

Jan 1, 2015

By A. Perucho, J. P. Harrison, A. Bedi, L. Alejano, L. Lamas, A. Sofianos, A. M. Ferrero, R. Migliazza, R. Olsson, J-F. Mathier

"In 2010, the Eurocode for Geotechnical Design, EN-1997-1:2004 (CEN, 2004), informally known as Eurocode 7 or EC7, became the Reference Design Code (RDC) for geotechnical design – including rock engineering design – within the European Union (EU). EC7 is one standard within the comprehensive Structural Eurocode suite, which as a whole has been also adopted by a number of other countries beyond the EU. EC7 is thus becoming a key design standard for geotechnical engineering worldwide.As part of the Structural Eurocode suite, EC7 requires designs to adhere to the principles of Limit State Design. However, it is not clear that current rock engineering design practice can satisfy this requirement. In addition, evidence is accumulating that EC7 is currently difficult to apply to, and may even be inappropriate for, rock engineering design. These issues may be due to the fact that the development of EC7 to date took place without any formal input from the international rock mechanics and rock engineering community.In early 2011 under the auspices of CEN (Comité Européen de Normalisation / European Committee for Standardisation), EC7 entered a formal period of maintenance which was aimed at improving the applicability and ease-of-use of the Code. This maintenance cycle will conclude in 2020 with the publication of a revised version of EC7.This paper describes a number of critical aspects for rock engineering in the context of EC7, inparticular the following:– the history of the Structural Eurocodes and the concepts they embody;– the nature of Limit State Design and the challenges and opportunities it poses for rock engineering design;– the formal means by which the Structural Eurocode maintenance cycle proceeds;– the plans currently being developed for improving EC7 with regard to rock engineering design and construction;– the unique and vital opportunity for the entire international rock mechanics and rock engineering community to comment on the Code and make suggestions for its improvement."

Jan 1, 2015

By C. Zangerl, H. Lechner

"Large scale rock slides in deeply incised Alpine valleys are common hazards that can endanger human life, settlement areas and critical infrastructure such as highways, railways and reservoirs (Bonzanigo et al., 2007). In order to perform reliable forecasts of the behaviour of rock slides influenced by large dam reservoirs the geometry, the kinematics, the deformation behaviour and the hydrogeological situation need to be understood profoundly. Based on generic rock slide models the influence of the rock slide geometry on the stability as well as the impact of the buoyancy forces and water load of the reservoir at the toe of the slope are the main focus of this study. Various assumptions of hydraulic conductivity, groundwater conditions of the rock slide and impoundment depth of the reservoir are analysed using limit equilibrium approaches.Generally, deep seated rock slides are characterised by deformation along one or multiple shear zones where most of the measured total slope displacement localizes. Many large rock slides, especially those observed in foliated, mica-rich crystalline rock masses (e.g. paragneisses, mica schists, phyllites), do not fail suddenly or reach high velocities. Instead, many of them move slowly and reach velocities of centimetres per year or even less. Some show episodic accelerations, sometimes reaching alarming levels, but then subside to non-critical levels again. However, there is a potential that deep-seated rock slides fail rapidly, develop into far-reaching run-out rock flows, and cause catastrophic events. Whereas the role of triggers in promoting phases of acceleration is often understood, the same cannot be said regarding the kinematics and dynamic processes by which the rock slide mass decelerates, re-stabilises or accelerates to a catastrophic degree once the trigger impetus has been removed. Thus key questions of the presented work concern the geotechnical, geometrical and hydrogeological conditions under which a slowly moving rock slide is triggered to accelerate to irreversible, maybe dangerous velocities. The development of the sliding zone is generally influenced by pre-existing discontinuities such as brittle fault zones, shear and tensile fractures, foliation and bedding planes. These geological structures determine the geometry of the sliding zone which can either be rotational or translational. During the gravitationally induced failure process the geometry of the rock slide undergoes a change.Several observed post-failure geometries in metamorphic rocks show a concave topography in the middle to upper part of the rock slide and a typical convex or bulge-like topography at the toe of the slope (Zangerl et al., 2012). Whereas the sliding zone of the upper part of such a rock slide mass is rather steep and planar, the inclination of the sliding zone at the toe can be close to zero and act against the driving forces (Alonso et al., 2010). A shear zone that meets alluvial deposits at the foot of the slope encounters a stabilizing impact on the mechanical behaviour. This buttressing effect of alluvial sediments has a remarkable influence on the slope stability."

Jan 1, 2015

By O. Hungr, V. Gischig, G. Preisig

Deep-seated landslides are characterized by slow time-dependent movements induced by constant gravitational creep, and periods of acceleration associated with stress changes within the rock and the preexisting fracture network. Natural stress changes are typically caused by seasonal variations in surface temperatures and groundwater pressures, but also by rare and more violent events such as earthquakes. These processes are responsible for cyclic loading and unloading that leads to rock mass damage, fatigue and progressive failure with time, and may explain sudden, unexpected rock slope acceleration phases. In this work, we present a set of distinct-element models to investigate and compare the role of hydromechanical fatigue and seismic fatigue in the history of a deep-seated landslide. Hydromechanical fatigue arises from the fluctuation of pore pressure in fractures accompanying periods of significant groundwater recharge. In alpine areas, there are usually one or two cycles per year associated with snow melt and intense rainfall periods. In the presence of a deep confined aquifer within the rock slope, the amplitude of pressure fluctuations may reach values of 0.25-0.5 MPa. Hydromechanical models considering such pressure changes are able to reproduce observed slope accelerations-decelerations phases. Substantial accelerations may occur even in the absence of a cycle of exceptional amplitude, depending on the current state of fatigue. At a given time, one or more fractures may be critically-stressed, and a small change in applied stress is enough to cause local failure and induce a crisis of enhanced slope acceleration. This is augmented if the rock slope contains planes of weakness associated with its tectonic history, glacial debuttressing, etc. The corresponding behaviour is analogous to laboratory experiments on rock and metal fatigue. Similar fatigue effects have also been proposed for repeated earthquake events in seismically active regions. Unlike hydromechanical stress changes that occur in a more localized portion of the rock slope, those induced by passing seismic waves involve the entire rock mass. Moreover, the frequency and amplitude of stress perturbations due to earthquakes are different than those induced by pore pressure variations, although both likely contribute in combination to the degradation and progressive failure of large deep-seated landslides when both are present. The results presented illustrate that: (1) assessment of slope stability near critical infrastructure (e.g., hydroelectric reservoirs) should not only consider static stability, but also failure mechanisms related to fatigue that evolve over time and may result in an apparently stable slope progressing towards a critical state due to relatively small but repetitive stress changes; and that (2) characterization of fatigue processes affecting a deep-seated landslide requires multiparametric continuous monitoring at different observation points.

Jan 1, 2015

By S. Usui, Y. Shinohara, C. Tokoro, K. Horiuchi, S. Owada

Process optimization of heating and physical separation for Cobalt (Co) recycling from spent lithium ion battery (LIB) was investigated. LiCoO2 in spent LIB was transformed to LixCoO2 which was more easily decomposed than LiCoO2 by heating. Coexisting materials of aluminum and carbon, and sealed atmosphere of the LIB promoted LixCoO2 decomposition. In an atmosphere of Argon, 95 % of LixCoO2 in the spent LIB was decomposed to 76 % of Co oxide and 19 % of Co metal in 10 min at 823 K; a lower temperature than the theoretical value for LiCoO2. The Co oxide and Co metal exhibited magnetic properties and could be recovered by wet magnetic separation. Furthermore, slow heating was effective for grain growth of Co oxide and Co metal. At 2 K/min rate of heating, average grain size of Co oxide and Co metal were 239 µm and 28 µm respectively, whereas at 30 K/min they were 190 µm and 15 µm respectively. Therefore, separation efficiency for Co recovery by wet magnetic separation was increased when spent LIB was slowly heated at 2 K/min.

Jan 1, 2015