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By F. P. A. Robinson, J. W. Fourie

Austenitic stainless steels are welded using low-heat inputs. However, owing to differences in the physical metallurgy of austenitic stainless steels and duplex stainless steels, low-heat inputs should be avoided for duplex stainless steels. This paper highlights the differences in solidification mode and transformation characteristics of these two types of alloys. Recent work on the effect of heat input on the properties of weldments of duplex stainless steels is reviewed.

Jan 1, 1990

By Scott A

The object of most blasting operations is to destroy the insitu structure of the rock mass so that mechanical equipment can efficiently excavate the rock fragments. In achieving this objective the blasting engineer is also concerned with minimising damage to the adjacent rock which forms the mine structure relied upon to provide support. Damage to this "structural" rock is undesirable but usually occurs as a result of two distinct processes: ò readjustment of stresses around the excavation as a result of the mining process itself ò impact of vibration and high pressure gases from blasting operations. Gross damage to mine structures from either cause is observed as visible alteration to the appearance of the rock structure in the form of cracking, slabbing, back or over break and visible displacement. Recent work at the Julius Kruttschnitt Mineral Research Centre (JKMRC) has shown that significant reduction in the strength of a rock mass can take place well before the onset of these obvious signs of damage. It has been demonstrated that the effect of blast damage on the behaviour of the rock mass can be many times more prominent than the effect of stress redistribution. This offers the blast design engineer the opportunity to significantly reduce blast induced damage to rock structure by modifying blasting practices. This paper introduces the current JKMRC postgraduate research projects investigating the evaluation and control of blast damage.

Jan 1, 1990

By Thomas J. Albin

This U.S. Bureau of Mines report identifies potential causes of slip-and-fall accidents occurring during surface mine equipment maintenance and describes the relative roles of direct worker behavior and machine design. The relative roles of human behavior and machine design in the causation of slip-and-fall accidents were determined through analysis of accident records, observations of maintenance worker behavior, and evaluation of mine machinery. From these data, relative risk ratios were calculated. Behavior had a relative risk ratio of 1.5; machine design, specifically access systems design, had a relative risk ratio of 2.2. Of the access systems, ladders had the highest relative risk ratio, 7.0. This study suggests that accident intervention would be most profitably made in improving the design of systems used to access maintenance worker areas of mining equipment.

Jan 1, 1990

By Lijun Xu, Jan M. Mutmansky

"Mutmansky, J.M. and· Lijun Xu, 1989. Some observations on particulates collected in underground coal mines using diesel and non-diesel equipment. Min. Sci. Technol., 9: 207-218.The results obtained when sampling twenty underground coal mine sections, each in a different mine, are outlined. The sampling effort was oriented toward a detailed characterization of coal mine dusts and thus eight-stage Anderson Model 298 impactors were used as the primary collection instrument. This instrument allowed a fairly detailed size distribution for each of the particulates sampled. Because four of the mines used diesel outby equipment and/or diesel shuttle cars at the face, it is possible to make some comparisons of the particulate distributions in diesel versus non-diesel mines.One of the more interesting results is the pattern that exists in mines lising diesels only for outby utility haulage. Particulates in these mines seem to be consistently heavy in the fine size ranges, perhaps being of significant concern to the industry. While no definite conclusions can be drawn from the limited data, a more detailed study of particulates may provide a better picture of particulate loadings.IntroductionThe subject of particulate emiss1ons from underground diesel equipment is currently a very important topic as health concerns and regulation of diesel particulate emissions have created new environmental problems for mine operators. The amount of particulate matter originating from diesels has not been extensively measured and problems of differentiating coal and mineral dust from diesel particulates make existing data questionable.However, it is necessary to make an assessment of the problem in order to solve it. It is known that particulates from diesel engines are solid aerosols formed in the combustion process. Technically, this places the particles in the category of fumes. It is also known from tests where no mineral dust could be a factor in the measurements that about 90% of diesel particles are less than 1 µm in aerodynamic diameter [3]. To measure the diesel component of a coal/diesel particulate to measure, Johnson et al. [2] have developed procedures for utilizing laser Raman spectroscopy. The determination of diesel content in a coal/diesel mixture is difficult due to the chemical similarity of the two organic materials. However, laser Raman spectroscopy, which is often used for identification of organic materials, has potential if the Raman spectra for the two materials are different and unique. The study concluded that an accuracy of ±~% could be achieved for mixtures containing up to 55% diesel particulate. The method is relatively complex and would need further development for routine application."

Jan 1, 1990

By E. M. Weenink

One of the new direct smelting technologies for the production of lead from sulfide concentrates that has reached the commercial stage is the Outokumpu lead flash/electric furnace ?smelting process. Using data from pilot plant test work, energy and mass balances for a commercial plant were initially calculated by hand. To optimize process conditions, a large number of such balances had to be generated and a computer program using Lotus 123 was developed which provided an excellent opportunity for computer simulation. Operating parameters can be calculated by iteration using input values for feed composition, feed rate, smelting temperature, and lead content of the slag'" The output is presented by means of various views of the appropriate process steps, or in 68 different graphs.

Jan 1, 1990

As an Inspector of Mines in Queensland, my main responsibilities include the enforcement of the Mining Act 1968 - 1986, the Mines Regulation Act 1964 - 1989 and the Metalliferous Mining regulations 1989 to promote the safe and responsible exploitation of the States' mineral wealth.An important adjunct to this task is the offering of an advisory service to the mining industry. However, in the pursuit of my duties to this regard, I have sadly observed in some cases, numerous wrong doings and negative activities by miners which have led to their ultimate demise, not to mention that of others. Despite what I consider corrective advice, I have witnessed, again in some cases, disregard and blind pursuit for the wrong end.This then is a novel approach to get the message home in the form of a light hearted cartoon presentation relating the saga of an average Aussie battler entering the mining game unprepared, making the wrong decisions due to his own ignorance and the cleverness of others, leading finally to his and possibly others' downfall.

Jan 1, 1990

By Lyle Avey

For the purpose of this paper, testwork and general pre-splitting practice will be discussed for the Chimney Creek Mine.

Jan 1, 1990

By Kerr I. D, Kennedy M

Flash X-radiographs were obtained of commercial electric No 6 and No 8* strength aluminium tube detonators in small-diameter cartridges of emulsion explosive at various times after fusehead operation. The trigger system for the radiography was based on the detection of light following fusehead firing via optical fibres inserted into the fusehead cavity during detonator assembly. These experiments were simulated using a finite element hydrocode with realistic treatment of the non-ideal reaction kinetics. Excellent agreement was demonstrated for the shape and position of the shock waves. In both cases, initiation of the emulsion was predominantly forward from the detonator. For the No 8* strength detonator, this initiation resulted from the shockwave delivered through the sides of the detonator, while for the No 6 strength detonator, initiation was the result of a complex interaction between shockwaves originating both from the sides and from the endcap. In the reverse direction (towards the crimped end of the detonators), initiation was only weakly dependent on detonator strength, being controlled mainly by the competing processes of rarefaction from the cartridge boundaries and comer turning of the detonation wave from the forward initiation. The consequences for field performance of small-diameter emulsions will be discussed.

Jan 1, 1990

By Gray J, Krouse HR, Changkakoti A, Kwak TAP

The Dachang tin field with more than one hundred million tonnes of ore at 1% tin and 3% Zn is one of the largest tin fields in the world. It comprises five carbonate replacement tin deposits, of which the Changpo deposit containing about 80 million tonnes of ore at about 1% tin is the largest deposit. The deposit, hosted by middle Devonian limestone, argillaceous limestone and black shale, is genetically related to the Longxianggei granite.The oxygen, hydrogen and carbon isotope data of minerals, rocks and fluids suggest a magmatic fluid which evolved during the crystallization of the Longxianggei granite. Mass balance calculations show that the depletions observed in 180 and 13C values of calcites from the ore bodies to the country rocks were due to continous isotopic exchange reactions between the magmatic fluid and the marine limestones at different W/R ratios and between 300 and 600¦C.

Jan 1, 1990

By R. J. Davidson

The chemistry related to the adsorption of gold, uranium, and transition-metal ions onto algal biomass (activated carbon) is related to the genesis of the Witwatersrand. Detrital gold being washed into the early basin, together with cyanide generated in the atmosphere, would have solubilized as the stable aurocyanide complex, the necessary oxygen being produced from the photosynthesis of carbon dioxide by primitive algae. Pebble-type conglomerates, while providing for the free movement of solutions containing the vital nutrients for prolific algal growth, would have screened of the sunlight, which would otherwise have degraded any free cyanide in solution. With the subsequent decomposition of the algal deposits, it is surmised that carbon-rich layers having adsorptive properties similar to those of activated carbon formed in the conglomerates. Under these conditions, gold (silver) in solution would have been adsorbed selectively as the cyanide complex, together with uranium as the carbonate complex. Any transition-metal ions present would also have been adsorbed onto such a substrate. The subsequent burial and compression of the gold-rich conglomerate with temperatures rising to about 400DC would then have reduced the adsorbed gold to the metal in a single segregated gold-silver metal phase (95 to 99 per cent of the contained gold), while leaving behind a sulphide phase rich in iron, base metals, and arsenic and containing some gold and silver. The recrystalization of this later phase may explain the presence of the rather consistent contents of secondary pyrite in the Witwatersrand conglomerates. Similarly, uranium minerals, some rich in titanium and carbon, may also have formed. An adsorption model would explain the very consistent trends in the gold-to-silver ratios of individual reefs in the Witwatersrand, which suggest an extensive hydrothermal system approaching isothermal equilibrium. Also, as gold grades increase, so silver grades generally decrease, indicating the sequential displacement of silver by gold as classically obtained with activated carbon.

Jan 1, 1990

By Gang Chen

This paper explores the possibility of using short-term time-dependent plate loading tests to estimate the elastic and viscoelastic parameters of the weak floor strata typically associated with coal seams in Illinois. Plate loading tests with incremental loads, similar to incremental creep experiments, were conducted until the floor failure occurred. For each increment, the load was held constant for a period ranging from 1-4 hours until a constant deformation rate was achieved. The deformation-time data were analyzed for viscoelastic parameters of weak floor strata assuming its behavior to be adequately represented by the standard Burgers model. The analysis required development of mathematical equations for the time-dependent deformation of the standard Burgers material under a three- dimensional state of stress. Time-dependent pillar settlement data at one mine were also analyzed for elastic and viscoelastic parameters of the weak floor strata using the developed equations. These parameters were compared with similar parameters estimated from plate loading tests.

Jan 1, 1990

Blasting, particularly bench blasting, uses finite length cylinders of explosive close to two free faces. The rock to be blasted is usually intersected by a complex 3-D system of joints. To fully simulate a blast, a 3-D dynamic model is required. It is shown that the static stress distribution around a long cylinder can be reproduced by superposing the static stress distribution of a suitable chain of spheres. Thus, the dynamic results for individual spheres given by Favreau (1969) can now be substituted for the static results to give a dynamic model of the stress distribution around a long cylinder. Comparison of measured and computed waveforms show that the measured waveforms are much more attenuated and dispersed than expected. The consequences for explosive evaluation and design are Discussed.

Jan 1, 1990

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) measurements provide direct evidence for the involvement of Cr(V) in the reduction of Cr(VI)· by NAD(P)H. Addition of hydrogen peroxide (H2 O 2) to NAD(P)H-Cr(VI) reaction mixtures suppresses the Cr(V) signal and generates hydroxyl (·OH) radicals (as detected via spin trapping), suggesting that Cr(V) reacts with H2O 2 to generate the ·OH radicals. Reaction between H2O 2 and a Cr(V)·glutathione complex, and between H2O 2 and several Cr(V)-carboxylato complexes also produces ·OH radicals. These results suggest that Cr(V) complexes catalyze the generation of ·OH radicals from H2O 2, and that ·OH radicals might play a significant role in the mechanism of Cr(VI) cytotoxicity. KEY WORDS: ESR. spin trapping, Cr(VI) reduction, Cr(V), hydrogen peroxide, free radicals.INTRODUCTIONThis communication reports an ESR spin trapping detection of hydroxyl ( OH) radicals.in reactions between some Cr(V) complexes containing biologically important ligands and hydrogen peroxide (H2O 2 ). This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step in the mechanism of Cr(VI) toxicity, the reaction· mechanism is not yet clear. 1 Mutagencity has been well documented for Cr(VI) via various bacterial assays, while Cr(III) has been shown not to be mutagenic.2 • 3 Since it has been reported that compounds containing Cr(VI) do not react with isolated DNA,4 the reduction of Cr(VI) by other cellular constituents has been thought to be important in the mechanism of Cr(VI) induced DNA alteration.1·4 • 5 For cellular systems earlier studies include those on the reduction of C~(VI) by microsomes,6-8 rat liver DT-diaphorase,9 and aldehyde oxidase. 10 Regarding the reduction mechanism, Jennette used ESR spectroscopy to show that a long-lived Cr(V) complex is formed as an intermediate in the microsomal reduction of Cr(VI) in the presence of NADPH.8 She postulated that Cr(V) is the ""ultimate"" carcinogenic form of chromium compounds. This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions.11 - 19 More recently, however, it has been suggested that oxygen-derived radicals generated during the Cr(VI) reduction are the species responsible for the DNA alteration.20.2• To the best of our knowledge, however, no information is available on the generation of such radicals in the reduction of Cr(VI) under biologically relevant conditions, except some preliminary results on the glutathionyl (GS·) radical formation in the reduction of Cr(VI) by glutathione (GSH). 11 - 19 We, therefore, undertook a systematic investigation of the reaction of Cr(VI) with NAD(P)H, GSH, ix-hydroxycarboxylic acids, and H2O 2 • NADPH was chosen as a model reductant because of its ubiquitous existence inside the cells, its critical role in the enzymatic Cr(VI) reduction,1·6-9 its representation of important cellular Cr(VI) reductants, and its ability to reduce other metal ions.22 GSH was chosen as another model Cr(VI) reductant because GSH also exists inside cells, it represents another important category of cellular Cr(VI) reductants, the thiols, and it also plays an important role in the Cr(VI) toxicity .1• 1 ""- 19.i3.i4 For further clarification, we also studied the reaction of Cr(VI) with several '1'.-hydroxycarboxylic acids in the presence of H2O 2 since these acids are definitively known to reduce Cr(VJ) to form stable, isolable Cr(V).25 .2 6 The results obtained indicate that Cr(V) complexes, produced in the reduction of Cr(VJ) by cellular reductants, react with H2 O 2 to generate ·OH radicals, which might be the initiators of primary events in Cr(VI) carcinogenicity."

Jan 1, 1990

Develop personal computer (PC) based software for analyzing and/or filtering time- and frequency-domain attributes of seismic and electromagnetic signals from geophysical surveys for the enhanced interpretation of rock masses and subsurface geologic structure. The Problem Both mining and petroleum geophysicists utilize seismic signals to characterize rock masses for delineating subsurface stratigraphy and structural conditions. However, a vast amount of information available in seismic project evaluation data often is unavailable for interpretation unless these data are enhanced. New processing technology increases the quality of these signals for analysis and interpretation. Comprehensive signal processing software is mostly written for petroleum exploration companies. Commercially available signal processing programs are often limited to a single application or are restricted for use with specific hardware, e.g., a digital oscilloscope or a mainframe computer. The programs may use computer codes that are proprietary, restrict user modification to expand capabilities, or may be hard to interface. They may have insufficient documentation for easy use and be support dependent.

Jan 1, 1990

By K. E. Harrison

Acid rain legislation as proposed by President Bush [1], if enacted, will immediately refocus current thinking on the economic decision-making as related to coal preparation facilities. Unit operations currently ignored because of their costs, will become mandatory to coal plant designers and operators to ensure maximum energy recovery and sulfur reduction in the entire coal stream. In anticipation of this need, the U.S. Department of Energy, The Ohio Coal Development Office, EPRI and others are sponsoring research in several areas of coal preparation, and coal plant designers are beginning to consider more innovative techniques as they configure their flowsheets for plants of the future. Preparation plants then will have recleaning

Jan 1, 1990

By Albert Hofstra, Joel Leventhal

The gray, dark gray and black colors of the sediments and the presence of pyrite in the Carlin, Jerritt Canyon, Horse Canyon, Betze, and Gold Acres sediment-hosted disseminated gold (SHDG) deposits indicate that these rocks are not oxidized with respect to carbon and iron sulfide. Both ore and non-ore host rocks generally are dark colored. Analyses for noncarbonate carbon (usually called organic carbon) in samples from SHDG deposits and related unmineralized rocks indicate that these rocks contain from a few tenths to a few percent carbon. We use the term noncarbonate carbon because, strictly speaking, organic carbon denotes carbon that is bound to hydrogen. However, the carbon present in SHDG deposits and related rocks has very little hydrogen chemically bound to it. Rocks with less than 2% organic carbon are usually gray in color. The dark colors in our samples are due to the relatively high temperatures that these rocks have experienced relative to organic matter maturation. We confirm the results of Nelson et al. (1982) that previous reports (for example, Radtke and Scheiner, 1970) were incorrect in reporting significant amounts of humic acids, extractable hydrocarbons (bitumen) or "carbonaceous" material. We believe these reports had problems with contamination or misdirected emphasis. Our samples consisted of unweathered rocks, collected mainly from mine cuts (benches, trenches, cores) and put into glass containers or wrapped in aluminum foil to avoid contamination. Only a few samples were collected from natural outcrops. We were careful to avoid samples in proximity to blast holes that were packed with ammonium nitrate and diesel fuel ("ANFO"). Contamination by ANFO may explain some of the previous reports of hydrocarbons, pyrobitumens, humic acids and anomalous nitrogen. When we were collecting samples, it was apparent that in addition to lithologic and color differences, the surface appearance of the rocks was distinguishable: "preg robbing" material that had a sooty surface; "graphitic" rock with a shiny surface; and more ordinary rocks that had a flat gray or black appearance. [Preg robbing is a term for ores that adsorb gold from the milling circuit; the graphitic material had not been x-rayed to actually identify graphite.] We hoped that laboratory study of these samples would show some fundamental differences that we could relate to ore genesis. Even though these sample types appeared different in the field, we could not distinguish any differences in thermal maturity (see below). Normal petroleum/organic geochemical laboratory procedures (solvent extraction, Rock-eval, pyrolysis-gas chromatography) failed to yield much information because the carbon was over-mature relative to oil and gas generation. Rock-eval results show less than 20 (± 20) mg of pyrolizable hydrocarbons per gram organic carbon (and an indeterminate Tmax) indicating that the organic matter in these deposits is burned-out relative to petroleum generation [with an H/C (atomic) ratio of less than 0.41. Because of the non-definitive results from standard organic geochemical methods, x-ray diffraction (XRD) and Raman spectroscopy were used to characterize the carbon. Prior to XRD, samples were treated with HCl and HF acids (1) to remove quartz that has a peak near 26° [20] at the position of the 002 peak of graphite and (2) to concentrate the carbon to a level detectable by XRD. The residue was put on a colodion mount and analyzed by XRD. The XRD analyses yielded a broad peak at 26° [20]. The shape of this peak indicates that the carbon is more thermally mature than anthracite rank coal but less mature than crystallized graphite. Based on XRD results from the literature (Landis, 1971) that are calibrated to metamorphic facies, results from our samples correspond to pumpellyite-actinolite to lowermost greenschist facies conditions, probably

Jan 1, 1990

By Y. Ye, J. D. Miller

Certain bituminous coals are known to contain appreciable quantities of natural fossil or subfossil resin. Such resinous coals are found in the western US, particularly the Wasatch Plateau coalfield of UT. Some of the seams in this field contain an average of 5% resin. This fossil resin has been recovered by gravity and/or flotation processes since 1929. Resin concentrates thus produced are of low quality and are usually refined by solvent extraction. The purified resins are of commercial importance in the adhesive, coating, rubber. and ink industries, etc. An improved flotation technique has been developed which involves ozone conditioning to selectively float resin from high-volatile bituminous coal. With this flotation process, a concentrate product which contains 95%

Jan 1, 1990

By K. W. Falconer

The Witbank-Middelburg Branch of The South African Institute of Mining and Metallurgy celebrated 100 years of coal mining in the Witbank area with a function held at Douglas Colliery on the 5th December, 1989. Two hundred guests associated with the industry attended the occasion, at which Mr A.A. Sealey, Chairman of Rand Mines, Coal and Base Minerals Division, unveiled a plaque presented to the municipality.

Jan 1, 1990

By Joseph Gersic

In 1989-90, the Bureau of Mines appraised selected high resource potential areas containing gold, rare-earth-element, or pegmatite deposits in or near the Black Hills National Forest. Available mineral resource data were used to construct mine and mill models and to compute discounted cash-flow rate-of-return analyses. Using this information, the economic feasibility of possible operations and probability (in the nonmathematical sense) of exploration and development within the next decade were assessed. High exploration and development probabilities are forecast for gold deposits around existing and permitted mine areas near Lead-Deadwood and west of Galena. The area east of Galena has low to moderate exploration and development probability; the Rochford area has low to high exploration probability and low to moderate development probability; the Keystone area has low to moderate exploration probability and low development probability; the Medicine Mountain area has moderate to high exploration and low to moderate development probabilities. Exploration probability in the Bear Lodge Mountains area is high for rare-earth elements and gold; development probability is low. Exploration probability for gold in the Mineral Hill area is low to moderate; development probability is low. The current level of activity associated with pegmatite mining in the Black Hills would probably not change significantly in the next decade; both exploration and development probabilities are low to moderate.

Jan 1, 1990

The mining industry in Australia frequently uses the services of specialist engineering and managing contractors and consultants for a majority of the work required for project development, from feasibility studies to project commissioning. The project owner's prime objectives are to achieve predictability and competitive advantage for their project. As the majority of this work will be carried out by contractors, the effective evaluation, selection and management of these contractors in the most appropriate forms of contracts is an essential ingredient to project success. The first stage to project development should be for the owner to examine its own resources to establish the role that it will fill and thereby identify the role and scope of contractors' involvement. Once the owner has developed this work plan, the selection of contractors and consultants should be structured to ensure that the owner acquires the appropriate expertise and experience to achieve its project objectives. The sequence of selection procedures is: 1. Pre-qualification of prospective contractors according to the owner's adopted criteria, through the use of a pre-qualification questionnaire. 2. Evaluation by the owner tender board according to predetermined mandatory criteria. 3. Preparation of tender documents for submission to qualified contractors. 4. Evaluation of tender submissions by the owner tender board using a pre-determined, weighted matrix of technical and commercial criteria. 5. Final selection and contract negotiation.

Jan 1, 1990